Attachment_0005___HCSDS_Index__Multiple_HCSDS__M739A1_Fuze.docx

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M739A1 Point Detonating/Delay (PD/DLY) Fuze
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This document is a Hazardous Component Safety Data Statement (HCSDS) for the NOL-130 Primer Composition, associated with the M739A1 Point Detonating/Delay (PD/DLY) Fuze. The HCSDS details the technical specifications, safety characteristics, and composition of the primer mixture used in the fuze, which includes components such as Lead Styphnate (40%), Antimony Sulfide (15%), Barium Nitrate (20%), Lead Azide (20%), and Tetracene (5%). The document provides comprehensive technical data on the primer composition's sensitivity to impact, friction, electrostatic discharge, heat, and flame, including detailed test results for various explosive comparisons and sensitivity measurements.

The safety data statement includes critical information about the primer composition's hazard classification, with specific details on detonation tests, thermal stability, impact sensitivity, and autoignition temperatures. The document emphasizes the need for careful handling and testing of the explosive components, noting that explosives must be tested for compatibility with other materials and that only sufficient composition should be prepared to avoid long-term storage. The HCSDS is part of the documentation for the M739A1 Fuze, which is used by the US Army, USMC, and SOCOM for artillery projectiles in both training and tactical operations, with a specific focus on providing precise technical safety information for manufacturing, handling, and potential procurement processes.

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M739A1 Fuze Hazardous Component Safety Data Statement (HCSDS) Index

#
Explosive
HCSDS
REV (DATE)
Higher Assembly
HCSDS Attachment
1
Barium Nitrate
4
G (May 1991)
NOL 130
2
Lead Styphnate
16
E (Nov 1992)
NOL 130
3
Antimony Sulfide
17
D (Nov 1992)
NOL 130
4
Tetracene
18
E

(Jul 1992)

NOL 130

5
Lead Azide Dextinated & Special Purpose)
66
E

(Apr 1993)

1. M99 Stab Det; 9272235G

2. NOL-130

6
M55, Detonator, Stab

8798331AC

72
M (Sept 2003)
S&A ROTOR ASSEMBLY

9258639D

7
RDX, Explosive (Type 1)
89
E (Nov 2008)
M55; STAB DET, 8798331AC
8
NOL-130, Primer

Composition, 9288649B

115
H

(March 25, 2008)

1. M55 STAB DET 8798331AC

2. M99 Stab Det; 9272235G

9
Lead Azide (RD1333 & special purpose)
128
D (Nov 2003)
1. M55; STAB DET; 8798331

2. M99 Stab Det; 9272235

3. NOL-130

10
HMX
129
E

(Apr 2007)

PBXN-5

11
Lead,PA508 2 pellets PBXN-5 12992295F
161
J

(Jan 2016) S&A Sub-assembly 9294833P

12
Pellet, Booster, PBXN-5

12992294D

162
G

(Jan 2016) M739A1 Fuze 9345332H New NSN 1390-01-600-4635

13
M99; Detonator, Stab,

9272235G

607
G

(Mar 1995) Firing pin Housing & Det Assembly 9258613C

14
Assy S&A Module & Retainer 9282958H
612
F

(Jul 1992) Fuze body 9345331G

15
PBXN-5, Explosive, Composition
622
E

(Apr 2007

1. Booster Pellet; 12992294

2. Lead; PA508, PBXN-5;

12992295F (2 Pellets)

16
M739A1 Fuze; 9345332H. New NSN 1390-01-600-4635
1787
F

(June 2012) 8 fuzes per M2A1 can 2 cans per wire bound

17
Safing and Arming Module, Sub Assembly, 9294833P
1887
D (June 2012)
Assy, S&A Module &

Retainer 9282958H

18
Assembly, Fuze Body,

M739A1 9345331G

2076
B (Jul 1992)
M739A1 Fuze; 9345332H

New NSN 1390-01-600-4635

HCSDS 17.pdf image4.emf

HCSDS 18.pdf image5.emf

HCSDS 66.pdf image6.emf

HCSDS 72.pdf image7.emf

HCSDS 89 .pdf image8.emf

HCSDS 115 .pdf

HAZARDOUS COMPONENT SAFETY DATA STATEMENT·

1. DATE PREPARED REPORT CONTROL SYMBOL

(YYYYMMDD)

(HCSDS) 20080325 DD-A&T(AR)1687

2. MATERIAUCOMPONENT/ASSEMBLY 3. NUMBER 4. REVISION

Primer Composition, NOL·130 115 H

5. APPLICABLE FEDERAL ACQUISITION REGULATION (FAR) SAFETY CLAUSE

DFARS 252.223-7002

PART I· SENSITIVITY (ApparatusandComparlson Values)

6. FRICTION TEST 7. IMPACT TEST B. ELECTROSTATIC DISCHARGE TEST

PA PA 0.0022·0.0028

SteellFiber; Explodes I Inch Joulei

PART I· HAZARDS

9. FIRE 10. AUTO IGNITION TEMP. 11. FLASH POINT 12. DECOMPOSITION PRODUCTS

Low-Detonates • NA Toxic, Avoid Inhalation and Ingestion

13. FLAMMABLE ANDIOR EXPLOSIVE LIMITS 14. EXPLOSION 15. EXPLOSIVE TEMP. 16. OUSTS

a. lOWER PERCENT b. UPPER PERCENT (5 Sec.)

NA NA High 174oC(34oF) NA

17. HEALTHH~INFO~ATlON (Toxicity) 18. UNPACKED (In-Process) HAZARD CLASS

(Specify quantities Involved)

Moderately Toxic by Inhalation and Ingestion Class 1.1

19. SPECIAL REQUIREMENTS (If additional space Is needed, use plain bond paper)

Ref-I;lwg: •

There are no approved packagings: Only sufficient composition .hould be prepared as required to avoid long term .torage. [ntra-plant storage or movement of small or in-procell quanties of composition sufficient to ntect manufacturing rcquirementl .hould be packaged in accordance with Para 16·4, AMe-R 385· I00 dated 26 Sep 1995. Clusificationl listed below an: interim for intra-plant .torage only.

• (Sec Attached Sheet)

PART III • SHIPPING/STORAGE CLASSIFICATION OF ITEM WHEN PACKED

IN ACCORDANCE WITH APPROVED .pACKING DRAWINGS

20. DOD HAZARD CLASSIDIV 21. DOD STORAGE COMPATIBIUTY 22. DOT HAZARD CLASSIFICATION 23. DOT CONTAINER MARKING

GROUP

1.1 A Not Normally Shipped Not Normally Shipped

24. PREPARED BY (Initiator) .

•• TYPED OR PRINTED NAME b. SIGNATURE c•. ORGANIZATION

.JJ L .Ax •

EDWARD DAVILA 'A,

25. CONCURRED IN BY r )

a. TYPED OR PRINTED NAME b·W£ c. ORGANIZATION

HUNG-MINH TRAN 7/,W ~

26. SAFETY CHIEF OR AUTHORIZEP REPRESENTATI'hiV- '--

•• TYPED OR PRINTED NAME b,/:::''''' c. ORGANIZATION

CHAU L. NGUYEN \. j ~.~ "I~~ /

The Information relating to safety (herein referred to as "safety Ulth J.e procurement/production of the Item. No representation Is data") contained In this document Is limited to those Instances . made that compliance with the Information prOVided will prevent when the document Is provided as a part of a procurement/ any accident to persons or property or that additional warnings production package which Involves the development. testlng, may not be appropriate. Neither the foregoing nor any act or failure storage, manufacture, modification, renovation. demilitarization, to act by the Government In regard to alerting personnel to the packaging, transportation, handling, disposal, Inspection, repair or hazards of the Item shal! affect or relieve the contractor of any other use of the Item (material/component/assembly) whIch Is responsibility for the safety of contractor personnel or property and specified In the contract. The safety data contained herein are for the safety of the general public In connection with the examples which shall be used by the contractor to alert contractor performance of the contract, or Impose or add to any liability of the personnel as well as other personnel of hazards associated Government for such safety.

DO FORM 2357, APR 1999 PREVIOUS. EDITION MAY BE USED. APOPEv1.00

DISTRIBUTION STATEMENT C. Distribution authorized to U.S. Government Agencies and their contractors, Administrative or Operational Use, 09 May 2012.

Other requests for this document shall be referred to the Munitions Safety and Hazard Classification Branch, Picatinny, NJ 07806-5000.

H

2008 Mar 25

Primer Composition, NOL-13 0

HCSDS: 115

Dwg: (as applicable)

Alternate

Lead Styphnate Lead Styphnate (Normal)

HCSDS: 16 HCSDS: 16

(40%) (40%)

Antimony Sulfide Barium Nitrate

HCSDS: 17 HCSDS: 4

(15%) (20%)

Alternate

Lead Azide, RD-1333 Lead Azide, Special Purpose

HCSDS: 128

OR

HCSDS: 128

(20%) (20%)

Lead Azide, Type I Tetracene

HCSDS: 66 HCSDS: 18

OR

Dwg: 9287784

(20%) (5%)

1. The primer mixture is sensitive to impact, friction, electrostatic discharge, heat or flame. It should be protected from accidental exposure to these stimuli.

2. CAUTION: EXPLOSIVES MUST BE TESTED FOR COMPATIBILITY WITH ANY

MATERIAL NOT SPECIFIED IN THE PRODUCTION/PROCUREMENT PACKAGE WITH

WHICH THEY MAY CAME IN CONTACT. MATERIALS INCLUDE OTHER EXPLOSIVES,

SOLVENTS, ADHESIVES, METALS, PLASTICS, PAINTS, CLEANING COMPOUNDS,

FLOOR AND TABLE COVERINGS, PACKING MATERIALS AND OTHER SIMILAR

MATERIALS, SITUATIONS AND EQUIPMENT. EXPLOSIVES INCLUDE PROPELLANTS

AND PYROTECHNICS.

Sheet 2 of 6

Special Requirements: (cont'd)

3 Item Drawing associated with this HCSDS:

Drawing Rev Drawing Rev 1183503 U 9297873 -

66B10115 E 9298134 A 7548654 K 9298746 - 9223680 - 11005151 C 9236470 H 11722793** A 9243921 K 11730650 A 9276533 - 8798331 V 9287735 C 11834325 A

9288649 A 12708622 XO

9297865 - 9211019 - 11731363 A 8797793 C 9297836 A 9211957 B

9384809 A 821021**

Note: **Obso1ete

4. Hazard Classification Tests (TB 700-2) Department of Defense Explosives Hazard Classification procedures, Sep 82:

a. Detonation Test - Mushrooming (TNT mushrooming 0.868 inches).

b. Thermal Stability Test - No explosion, ignition or change in configuration.

c. Impact Sensitivity Test - 3.75 inches I 2 Kg weight (Minimum drop height as which a reaction occurred) .

5. Additional sensitivity Data:

a. Autoignition Temperature - 119°C (246°F) fast heating 227°C (441°F) slow heating 274°C (525°F) DTA heating rate D.loC

b. Friction (Rotary apparatus) :

0.5 x 10 8/D.3N/M2@msec

c. Impact Hammer Test:

Hso = 50-70mm (5-7cm)

d. Dust:

3.70g/m3 minimum energy 0.0028 Joules.

Sheet 3 of 6

Special Requirements: (Cont'd)

6. Sensitivity (Comparison Values):

a. Friction (Apparatus)

Explosive Lead Azide

PETN

TNT

RDX

RDX Type II, Class 5 Black Powder M1 Propellant M9 propellant M30 Propellant HMX Class 1 HMX Class 5

PA

Steel Shoe

Explodes Crackles Unaffected

Snaps

Snaps

Fiber Shoe

No Reaction in Pressure-

ABL Pendulum velocity of 8 ft/sec and 20 trials (psi)

b. Impact (Apparatus)

PETN

TNT

RDX

RDX Type II, Class 5 Black Powder Ml Propellant

M9 Propellant M30 Propellant family Comp B HMX Class 1 HMX Class 5 DXN-l

Ball Drop :Im;pact 50% Point (in)

15.7 + 1.0

4.6 + 0.5

J:nches

4-5

6 (grain)

4 (powder) 2-3

Bureau of

Mines, em

10-17

95-100+

ERL (PA

version)

Type 12, 50%, em

<12

28.8

-85

BOE :Impact @3 ~ and

10 trials

2 Explosions 8 Explosions

Sheet 4 of 6

Sensitivity (Comparison Values): (Cont'd)

c. Electrostatic Discharge, Bureau of Mines Apparatus

PETN

TNT

RDX

Black Powder M1 Propellant M9 Propellant M30 Propellant

Joules

0.007 Confined 0.21/Unconfined 0.06 Confined 4.4/Unconfined 0.06 >11.03 Confined 0.8/Unconfined >12.5

11. 03 5.2 >12.5

d. Electrostatic Discharge, Approaching Electrode

ESD 50% energy (joules)

DXN-1

0.12 0.12

e. Explosive Temperature (5 Seconds)

RDX 260° C (500° F)

Lead Azide 340° C (644° F)

PETN 225 0 C (437° F)

Black Powder 427 0 C (801° F)

f. Autoignition Temperature

RDX

PETN

Black Powder

197° C (387 0 F) 290° C (554° F) 1600 C (320° F) 464° C (867° F)

Note:

ERL - Energetic Research Lab PA - Picatinny Arsenal

Sheet 5 of 6

Sensitivity (Comparison Values): (Cont'd)

g. Thin Film Propagation Tests:

Donor Accepter - NOL-130 Cup Quantity

Thickness Depth of Expl Results Material (mills) (inches) (Grams) (propagation)

A(l) 10 ~(31 1~ No A 10 ~(41 21h Yes A 10 ~ 11A Yes A 5 1h(SI I1h No A 5 Ih(SI 11h No A 5 1h(SI I1h No A 5 WSI 1~ No A 5 1f.z(SI I1f.z No A 5 1f.z(41 2% No A 10 1f.z(SI I1f.z No A 10 W41 21f.z No A 5 1f.z(S)

1~ Yes B(2) 5 ~ 1~ Yes B 5 ~ 1~ No

Notes:

(liA = NOL-130 Primer Composition m B = Lead Styphnate

13) The ~ inch cup, when full, contains about 1~ grams of explosive.

(4)The 1f.z inch cup, when full, contains about 21f.z grams of

(S)The % inch cup, when Y.a fUll, contains about I1h grams of

Ref: Day & Zirnnermann, Inc., Technical Report #409, dated 1/9/86.

Sheet 6 of 6 image9.emf

HCSDS 128.pdf image10.emf

HCSDS 129.pdf image11.emf

HCSDS 161.pdf image12.emf

HCSDS 162.pdf image13.emf

HCSDS 607.pdf image14.emf

HCSDS 612.pdf image15.emf

HCSDS 622.pdf image16.emf

HCSDS 1787.pdf image17.emf

HCSDS 1887.pdf image18.emf

HCSDS 2076.pdf image1.emf

HCSDS 4.pdf image2.emf

HCSDS 16 .pdf image3.emf

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