Total Sequestrant SDS.pdf

World Headquarters Hach Company P.O.Box 389 MSDS No: M00196 Loveland, CO USA 80539

(970) 669-3050

SAFETY DATA SHEET

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Name: Total Sequestrant Reagent 2 Catalog Number: 4345097

Hach Company Emergency Telephone Numbers:

P.O.Box 389 (Medical and Transportation) Loveland, CO USA 80539 (303) 623-5716 24 Hour Service

(970) 669-3050 (515)232-2533 8am - 4pm CST

MSDS Number: M00196 Chemical Name: Not applicable CAS Number: Not applicable Additional CAS No. (for hydrated forms): Not applicable Chemical Formula: Not applicable Chemical Family: Inorganic Acid Intended Use: Laboratory Reagent Standard solution

2. HAZARDS IDENTIFICATION

GHS Classification:

Hazard categories: Corrosive to Metals: Met. Corr. 1 Skin Corrosion/Irritation: Skin Corr. 1B Specific Target Organ Toxicity - Single Exposure: STOT SE 3

GHS Label Elements:

DANGER

Hazard statements: May be corrosive to metals. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary statements: Do not breathe dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilated area. Wear eye protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove victim/person to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to

do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Absorb spillage to prevent material damage.

HMIS:

Health: 3 Flammability: 0 Reactivity: 1 Protective Equipment: X - See protective equipment, Section 8.

NFPA:

Health: 3 Flammability: 0 Reactivity: 1 Symbol: Not applicable

WHMIS Hazard Classification: Class E - Corrosive material WHMIS Symbols: Corrosive

Obtained by Global Safety Management, www.globalsafetynet.com, 877-683-7460

3. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous Components according to GHS:

Hydrochloric Acid

CAS Number: 7647-01-0 Chemical Formula: HCl GHS Classification: Met. Corr. 1, H290; Acute Tox. 4-Orl, H302; Acute Tox. 5-Inh, H333; Skin Corr. 1B, H314; STOT Single 3, H335 Percent Range: 50.0 - 60.0 Percent Range Units: weight / weight PEL: 5 ppm ceiling TLV: 5 ppm ceiling

WHMIS Symbols: Corrosive Hazardous Components according to GHS: No

Demineralized Water

CAS Number: 7732-18-5 Chemical Formula: H2O GHS Classification: Not a dangerous substance according to GHS.

Percent Range: 40.0 - 50.0 Percent Range Units: weight / weight PEL: Not established TLV: Not established

WHMIS Symbols: Not applicable

4. FIRST AID MEASURES

General Information: In the event of exposure, show this Material Safety Data Sheet and label (where possible) to a doctor.

Advice to doctor: Treat symptomatically.

Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician immediately.

Skin Contact (First Aid): Wash skin with plenty of water for 15 minutes. Remove contaminated clothing. Call physician immediately.

Inhalation: Remove to fresh air. Give artificial respiration if necessary. If you feel unwell, contact a physician If concerned contact a physician.

Ingestion (First Aid): Do not induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with plenty of water. Give large quantities of water. Call physician immediately.

5. FIRE FIGHTING MEASURES

Flammable Properties: Not Flammable, but reacts with most metals to form flammable hydrogen gas. During a fire, corrosive and toxic gases may be generated by thermal decomposition.

Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective gear. Evacuate area and fight fire from a safe distance.

Extinguishing Media: Water. Dry chemical. Carbon dioxide Alcohol-resistant foam Extinguishing Media NOT To Be Used: Not applicable Fire / Explosion Hazards: Contact with metals gives off hydrogen gas which is flammable May react violently with:

alkalies Hazardous Combustion Products: This material will not burn.

6. ACCIDENTAL RELEASE MEASURES

Spill Response Notice:

Only persons properly qualified to respond to an emergency involving hazardous substances may respond to a spill according to federal regulations (OSHA 29 CFR 1910.120(a)(v)) and per your company's emergency response plan and guidelines/procedures. See Section 13, Special Instructions for disposal assistance.

Containment Technique: Absorb spilled liquid with non-reactive sorbent material. Stop spilled material from being released to the environment.

Clean-up Technique: Cover spilled material with an alkali, such as soda ash or sodium bicarbonate. Scoop up slurry into a large beaker. Dilute with a large excess of water. Adjust to a pH between 6 and 9 with an alkali, such as soda ash or sodium bicarbonate. If permitted by regulation, Flush reacted material to the drain with a large excess of water.

Otherwise, Decontaminate the area of the spill with a soap solution. Dispose of in accordance with local, state and federal regulations or laws.

Evacuation Procedure: Evacuate general area (50 foot radius or as directed by your facility's emergency response plan) when: a gallon or more of liquid is spilled. If conditions warrant, increase the size of the evacuation.

DOT Emergency Response Guide Number: 157

7. HANDLING AND STORAGE

Handling: Avoid contact with eyes skin clothing Do not breathe mist or vapors. Wash thoroughly after handling.

Maintain general industrial hygiene practices when using this product.

Storage: Store away from: alkalies metals Flammability Class: Not applicable

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering Controls: Have an eyewash station nearby. Have a safety shower nearby. Maintain adequate ventilation to keep vapor level below TWA for chemicals in this product. Maintain general industrial hygiene practices when using this product.

Personal Protective Equipment:

Eye Protection: chemical splash goggles Skin Protection: lab coat neoprene latex gloves In the EU, the selected gloves must satisfy the specifications of EU Directive 89/686/EEC and standard EN 374 derived from it.

Inhalation Protection: laboratory fume hood

Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: mist/vapor Wash thoroughly after handling. Keep away from: metals bases TLV: 5 ppm ceiling PEL: 5 ppm ceiling For Occupational Exposure Limits (OEL) for ingredients, see section 3 - Composition/Information on Ingredients.:

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Clear, colorless Physical State: Liquid Molecular Weight: 36.5 Odor: Pungent Odor Threshold: 10 ppm pH: < 0.5 Metal Corrosivity:

Corrosivity Classification: Classified as corrosive to metals.

Steel: 1.354 in/yr Aluminum: 849.30 in/yr

Specific Gravity/ Relative Density (water = 1; air =1): 1.093 Viscosity: 1.37 mPa.s Solubility:

Water: Soluble Acid: Soluble Other: Soluble in sodium hydroxide solutions

Partition Coefficient (n-octanol / water): Not applicable Coefficient of Water / Oil: Not applicable Melting Point: -59 °C (-74 °F) Decomposition Temperature: Not determined Boiling Point: 109 °C (228 °F) Vapor Pressure: 10.5 mm Hg at 20 °C (68 °F) Vapor Density (air = 1): 0.6 Evaporation Rate (water = 1): 0.34 Volatile Organic Compounds Content: Not applicable Flammable Properties: Not Flammable, but reacts with most metals to form flammable hydrogen gas. During a fire, corrosive and toxic gases may be generated by thermal decomposition.

Flash Point: Not applicable Method: Not applicable

Flammability Limits:

Lower Explosion Limits: Not applicable Upper Explosion Limits: Not applicable

Autoignition Temperature: Not applicable Explosive Properties:

Not classified according to GHS criteria.

Oxidizing Properties:

Not classified according to GHS criteria.

Reactivity Properties:

Not classifed as self-reactive, pyrophoric, self-heating or emitting flammable gases in contact with water according to GHS criteria.

Gas under Pressure:

Not classified according to GHS criteria.

10. STABILITY AND REACTIVITY

Chemical Stability: Stable when stored under proper conditions.

Mechanical Impact: None reported Static Discharge: None reported.

Reactivity / Incompatibility: May react violently in contact with: sodium nitrate metals strong bases Hazardous Decomposition: Contact with metals may release flammable hydrogen gas. Heating to decomposition releases toxic and/or corrosive fumes of: hydrogen chloride Conditions to Avoid: Contact with water or steam. Contact with oxidizers Excessive heat Extreme temperatures

11. TOXICOLOGICAL INFORMATION

Toxicokinetics, Metabolism and Distribution:

Low concentrations of hydrochloric acid solution do not seem to cause adverse effects to animals and its corrosivity may be greatly attributed to any acute deaths, therefore it is not classified for acute toxicity.

Toxicologically Synergistic Products: None reported Acute Toxicity: Toxicological Testing Route Data Given Below Based on classification principles, the classification criteria are not met.

Oral Rat LD50 = 234 mg/kg Dermal Rabbit LD50 > 5010 mg/kg; Dermal Mouse LD50 = 1449 mg/kg Inhalation Rat LC50 = 16.8 mg/L/4 hr

Specific Target Organ Toxicity - Single Exposure (STOT-SE): Target Organs Respiratory Tract Hydrochloric Acid: Inhalation Human TCLo = 50 mg/m3/Cough and respiratory depression.

Specific Target Organ Toxicity - Repeat Exposure (STOT-RE): Based on classification principles, the classification criteria are not met.

Skin Corrosion/Irritation: Corrosive to skin.

Eye Damage: Corrosive to eyes.

Sensitization: Based on classification principles, the classification criteria are not met.

CMR Effects/Properties (carcinogenic, mutagenic or toxic to reproduction): Based on classification principles, the classification criteria are not met. Data insufficient for classification Summary of findings reported in the literature follow.

Cytogenetic Analysis Hamster Lung - 30 mmol/L; Cytogenetic Analysis Hamster Ovary - 8 mmol/L; DNA Repair

Escherichia coli - 0.025 mg/well;

Inhalation Rat TCLo = 450 mg/m3/1 hr/Fetotoxicity, Specific Developmental Abnormalities: Homeostatis IARC Group 3: Non-classifiable Hydrochloric acid NTP Listed: No O.S.H.A. Listed: No

Symptoms/Effects:

Ingestion: Causes: burns of the mouth and esophagus abdominal pain nausea vomiting Inhalation: Causes: burns choking teeth erosion Skin Absorption: None Reported Chronic Effects: Chronic overexposure may cause erosion of the teeth destruction of any tissue contacted lung damage

Medical Conditions Aggravated: Pre-existing: Respiratory conditions Skin conditions Eye conditions

12. ECOLOGICAL INFORMATION

Product Ecological Information: The environmental hazard for hydrochloric acid is caused by pH. A significant decrease in the pH of recieving water systems is not expected, therefore adverse effects on the aquatic environment are not expected.

Based on classification principles, not classified as hazardous to the environment. No bioaccumulation potential Mobility in soil: Highly mobile CEPA Categorization: Persistent, not bioaccumulative or inherently toxic to aquatic organisms.

96 hr Gambusia affinis LC50 = 282 mg/L; 48 hr Crustaceans LC50 = 240 mg/L; 48 hr Crustaceans EC50 = 100 mg/L; 48 hr Daphnia magna = 0.492 mg/L; 72 hr Daphnia magna LC80 = 56 mg/L; 72 hr Selenastrum capriornutum ErC50 = 0.492 mg/L Ingredient Ecological Information: -- Not applicable

13. DISPOSAL CONSIDERATIONS

EPA Waste ID Number: D002 Special Instructions (Disposal): Dilute to 3 to 5 times the volume with cold water. Adjust to a pH between 6 and 9 with an alkali, such as soda ash or sodium bicarbonate. If permitted by regulation, Open cold water tap completely, slowly pour the reacted material to the drain. Otherwise, Check with national, local municipal and state authorities and waste contractors for pertinent local information on the disposal of this article.

Empty Containers: Rinse three times with an appropriate solvent. Collect rinsate and dispose of according to local, state or federal regulations. In the US, rinsate from empty containers is classified as hazardous waste and should be disposed of at an E.P. A. approved facility. Rinsate from empty containers may contain sufficient product to require disposal as hazardous waste.

NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.

14. TRANSPORT INFORMATION

D.O.T.:

D.O.T. Proper Shipping Name: Hydrochloric Acid Solution

Hazard Class: 8 Subsidiary Risk: NA ID Number: UN1789 Packing Group: II

T.D.G.:

Proper Shipping Name: Hydrochloric Acid Solution

Hazard Class: 8 Subsidiary Risk: NA UN Number/PIN: 1789 Packing Group: II

I.C.A.O.:

I.C.A.O. Proper Shipping Name: Hydrochloric Acid Solution

Hazard Class: 8 Subsidiary Risk: NA ID Number: UN1789 Packing Group: II

I.M.O.:

Proper Shipping Name: Hydrochloric Acid Solution

Hazard Class: 8 Subsidiary Risk: NA ID Number: UN1789 Packing Group: II

Additional Information: There is a possibility that this product could be contained in a reagent set or kit composed of various compatible dangerous goods. If the item is NOT in a set or kit, the classification given above applies. If the item IS part of a set or kit, the classification would change to the following: UN3316 Chemical Kit, Class 9, PG II or III. If the item is not regulated, the Chemical Kit classification does not apply.

15. REGULATORY INFORMATION

U.S. Federal Regulations:

O.S.H.A.: This product meets the criteria for a hazardous substance as defined in the Hazard Communication Standard.

(29 CFR 1910.1200)

E.P.A.:

S.A.R.A. Title III Section 311/312 Categorization (40 CFR 370): Immediate (Acute) Health Hazard Reactive S.A.R.A. Title III Section 313 (40 CFR 372): This product does NOT contain any chemical subject to the reporting requirements of Section 313 of Title III of SARA.

302 (EHS) TPQ (40 CFR 355): Not applicable 304 CERCLA RQ (40 CFR 302.4): Hydrochloric Acid 5000 lbs.

304 EHS RQ (40 CFR 355): Not applicable Clean Water Act (40 CFR 116.4): Hydrochloric Acid - RQ 5000 lbs.

RCRA: Contains RCRA regulated substances. See Section 13, EPA Waste ID Number.

State Regulations:

California Prop. 65: No Prop. 65 listed chemicals are present in this product.

Identification of Prop. 65 Ingredient(s): Not applicable California Perchlorate Rule CCR Title 22 Chap 33: Not applicable Trade Secret Registry: Not applicable

National Inventories:

U.S. Inventory Status: All ingredients in this product are listed on the TSCA 8(b) Inventory (40 CFR 710).

CAS Number: Not applicable Canadian Inventory Status: DSL Listed: Yes EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.

Australian Inventory (AICS) Status: All ingredients are listed.

New Zealand Inventory (NZIoC) Status: All components either listed or exempt.

Korean Inventory (KECI) Status: All components of this product are either listed, listed as the anhydrous compound or exempt.

Japan (ENCS) Inventory Status: All components either listed or exempt.

China (PRC) Inventory (MEP) Status: All components either listed or exempt.

16. OTHER INFORMATION

References: TLV's Threshold Limit Values and Biological Exposure Indices for 1992-1993. American Conference of Governmental Industrial Hygienists, 1992. The Merck Index, 11th Ed. Rahway, New Jersey: Merck and Co., Inc., 1989.

Technical Judgment. Sax, N. Irving. Dangerous Properties of Industrial Materials, 7th Ed. New York: Van Nostrand Reinhold Co., 1989. List of Dangerous Substances Classified in Annex I of the EEC Directive (67/548) - Classification, Packaging and Labeling of Dangerous Substances, Amended July 1992. In-house information. Fire Protection Guide on Hazardous Materials, 10th Ed. Quincy, MA: National Fire Protection Fire Protection Guide on Hazardous Materials, 10th Ed. Quincy, MA: National Fire Protection Association, 1991. CCINFO MSDS/FTSS. Canadian Centre for Occupational Health and Safety. Hamilton, Ontario Canada: 30 June 1993. CCINFO RTECS. Canadian Centre for Occupational Health and Safety. Hamilton, Ontario Canada: 30 June 1993. Air Contaminants, Federal Register, Vol. 54, No. 12. Thursday, January 19, 1989. pp. 2332-2983. 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). EU Occupational Exposure Limits On Line.

Complete Text of H phrases referred to in Section 3: H290 May be corrosive to metals. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation.

Revision Summary: . Substantial revision to comply with EU Reg 1272/2008, Reg 1907/2006 and UN GHS ( ST/SG/AC.10/36/Add.3). Updates in Section(s) 15, Date of MSDS Preparation:

Day: 19 Month: August Year: 2014

MSDS Prepared: MSDS prepared by Product Compliance Department extension 3350 CCOHS Evaluation Note: It is offered under exemption from WHMIS labeling as specified in the Controlled Products Regulation (CPR) Section 17. It is offered under the interim policy that was established by Health Canada permitting use of GHS-formatted safety data sheets in Canada prior to revision of CPR to GHS. This product has been classified and labeled in accordance with the requirements of GHS (ST/SG/AC.10/36/Add.3). This SDS has been prepared in accordance with the requirements of GHS (ST/SG/AC.10/36/Add.3).

Legend:

NA - Not Applicable w/w - weight/weight ND - Not Determined w/v - weight/volume NV - Not Available v/v - volume/volume

USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety programs in accordance with applicable hazard communication standards and regulations.

THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.

HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA

OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.

HACH COMPANY ©2015