TOTAL CHLORINE SDS.pdf

SAFETY DATA SHEET

Issue Date 09-Dec-2020 Revision Date 09-Dec-2020

Version 4.4 Page 1 / 14

1. IDENTIFICATION

Product identifier Product Name DPD Total Chlorine Reagent

Other means of identification Product Code(s) 1406499

Safety data sheet number M00110

HMRIC # HMIRA Registry Number 9936 Filed 2016-04-11

Recommended use of the chemical and restrictions on use Recommended Use Water Analysis. Indicator for total chlorine.

Uses advised against Consumer use.

Restrictions on use For Laboratory Use Only.

Details of the supplier of the safety data sheet

Manufacturer Address Hach Company P.O.Box 389 Loveland, CO 80539 USA +1(970) 669-3050

Emergency telephone number +1(303) 623-5716 - 24 Hour Service

2. HAZARDS IDENTIFICATION

Classification

Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2

Hazards not otherwise classified (HNOC) Not applicable

Label elements

Signal word Warning

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Product Code(s) 1406499 Product Name DPD Total Chlorine Reagent Issue Date 09-Dec-2020 Revision Date 09-Dec-2020 Version 4.4 Page 2 / 14

Hazard statements H315 - Causes skin irritation H319 - Causes serious eye irritation

Precautionary statements P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P332 + P313 - If skin irritation occurs: Get medical attention P362 - Take off contaminated clothing and wash before reuse P280 - Wear protective gloves, protective clothing, eye protection, and face protection P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to

do. Continue rinsing P337 + P313 - If eye irritation persists: Get medical attention

Other Hazards Known May be harmful if swallowed

3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance Not applicable

Mixture

Chemical Family Mixture.

Chemical nature Mixture of inorganic salts.

Chemical name CAS No Percent Range

HMRIC #

Carboxylate Salt - 40 - 50% - Phosphoric acid, disodium salt 7558-79-4 20 - 30% -

Potassium iodide (KI) 7681-11-0 20 - 30% - Salt of N,N-Diethyl-p-Phenylenediamine - 1 - 5% -

4. FIRST AID MEASURES

Description of first aid measures

General advice Show this safety data sheet to the doctor in attendance.

Inhalation Remove to fresh air. Get medical attention immediately if symptoms occur.

Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Do not rub affected area.

Skin contact Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical attention if irritation develops and persists.

Ingestion Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. Do NOT induce vomiting. Call a physician.

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Self-protection of the first aider Avoid contact with skin, eyes or clothing.

Most important symptoms and effects, both acute and delayed

Symptoms Burning sensation.

Indication of any immediate medical attention and special treatment needed

Note to physicians Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable Extinguishing Media Caution: Use of water spray when fighting fire may be inefficient.

Specific hazards arising from the chemical

No information available.

Hazardous combustion products Carbon monoxide, Carbon dioxide. Iodine compounds. Phosphorus oxides. Potassium oxides. Sodium monoxide. Nitrogen oxides.

Special protective equipment for fire-fighters

Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Use personal protection equipment.

6. ACCIDENTAL RELEASE MEASURES

U.S. Notice Only persons properly qualified to respond to an emergency involving hazardous substances may respond to a spill according to federal regulations (OSHA 29 CFR 1910.120(a)(v)) and per your company's emergency response plan and guidelines/procedures. See Section 13, Special Instructions for disposal assistance.

Outside of the US, only persons properly qualified according to state or local regulations should respond to a spill involving chemicals.

Personal precautions, protective equipment and emergency procedures

Personal precautions Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal protective equipment as required.

Other Information Refer to protective measures listed in Sections 7 and 8.

Environmental precautions

Environmental precautions Prevent further leakage or spillage if safe to do so.

Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal.

Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.

Reference to other sections See section 8 for more information. See section 13 for more information.

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7. HANDLING AND STORAGE

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Precautions for safe handling

Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash before reuse.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.

Flammability class Not applicable

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Guidelines

Chemical name ACGIH TLV OSHA PEL NIOSH Potassium iodide (KI)

CAS#: 7681-11-0

TWA: 0.01 ppm inhalable fraction and vapor

NDF NDF

Appropriate engineering controls Engineering Controls Showers

Eyewash stations Ventilation systems.

Individual protection measures, such as personal protective equipment Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required.

Hand Protection Wear suitable gloves. Impervious gloves. Gloves must be inspected prior to use. The selected protective gloves have to satisfy the specifications of EU Directive 2016/425 and the standard EN 374 derived from it. Chemical resistant gloves made of butyl rubber or nitrile rubber category III according to EN 374-1:2016.

Eye/face protection If splashes are likely to occur, wear safety glasses with side-shields.

Skin and body protection Wear suitable protective clothing. Long sleeved clothing.

General Hygiene Considerations Wear suitable gloves and eye/face protection. Do not eat, drink or smoke when using this product. Avoid contact with skin, eyes or clothing.

Environmental exposure controls Local authorities should be advised if significant spillages cannot be contained. Do not allow into any sewer, on the ground or into any body of water.

Thermal hazards None under normal processing.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Physical state Solid Appearance powder Color White to light pink Odor Odorless Odor threshold Not applicable

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Solubility(ies)

Water solubility

Solubility in other solvents

Other information

Metal Corrosivity

Steel Corrosion Rate 0.97 mm/yr / 0.04 in/yr Aluminum Corrosion Rate 0.15 mm/yr / 0.01 in/yr

Volatile Organic Compounds (VOC) Content Not applicable

Chemical name CAS No Volatile organic compounds (VOC) content

CAA (Clean Air Act)

Carboxylate Salt - No data available - Phosphoric acid, disodium salt 7558-79-4 No data available -

Potassium iodide (KI) 7681-11-0 Not applicable - Salt of

N,N-Diethyl-p-Phenylenediamine

- Not applicable -

Property Values Remarks • Method

Molecular weight Not applicable pH 6.35 1% @ 20°C

Melting point/freezing point 145 °C / 293 °F

Boiling point / boiling range No data available

Evaporation rate Not applicable

Vapor pressure Not applicable

Relative vapor density No data available

Specific gravity (water = 1 / air = 1) 1.79

Partition Coefficient (n-octanol/water) log Kow ~ 0

Soil Organic Carbon-Water Partition Coefficient log Koc ~ 0

Autoignition temperature No data available

Decomposition temperature No data available

Dynamic viscosity Not applicable

Kinematic viscosity Not applicable

Water solubility classification Water solubility Water Solubility Temperature Soluble > 1000 mg/L 25 °C / 77 °F

Chemical Name Solubility classification Solubility Solubility Temperature None reported No information available No data available

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No information available

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Explosive properties

Upper explosion limit No information available Lower explosion limit No information available

Flammable properties

Flash point Not applicable

Flammability Limit in Air Upper flammability limit: No data available Lower flammability limit: No data available

Oxidizing properties No data available.

Bulk density No data available

10. STABILITY AND REACTIVITY

Reactivity Not applicable.

Chemical stability Stable under normal conditions.

Explosion data Sensitivity to Mechanical Impact None.

Sensitivity to Static Discharge None.

Possibility of hazardous reactions None under normal processing.

Hazardous polymerization None under normal processing.

Conditions to avoid None known based on information supplied.

Incompatible materials Strong acids. Strong bases. Strong oxidizing agents.

Hazardous decomposition products None under normal use conditions. Carbon dioxide. Carbon monoxide. Iodine compounds. Phosphorus oxides. Potassium oxide.

Nitrogen oxides.

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Product Information

Inhalation May cause irritation of respiratory tract.

Eye contact Irritating to eyes. Causes serious eye irritation.

Skin contact Causes skin irritation.

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Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Symptoms Redness. May cause redness and tearing of the eyes.

Acute toxicity Based on available data, the classification criteria are not met

Product Acute Toxicity Data Test data reported below.

Oral Exposure Route

Inhalation (Gas) Exposure Route

Ingredient Acute Toxicity Data

Chemical name Endpoint type

Reported dose

Exposure time

Toxicological effects Key literature references and sources for data

Potassium iodide (KI) (20 - 30%)

Rat

LD50

2779 mg/kg None reported

None reported RTECS (Registry of Toxic Effects of Chemical

Endpoint type Rat

LD50

Reported dose 4700 mg/kg

Toxicological effects

Behavioral Flaccid muscle tone Lethargy

Prostration Eye

Chromodacryorrhe a

Ptosis Gastrointestinal Abnormalities of the gastrointestinal tract

Diarrhea Liver

Abnormalities of the liver

Lungs, Thorax, or Respiration Abnormalities of the lungs Dyspnea

Red or brown staining of the nose/mouth area Nutritional and Gross Metabolic

Soiling of the anogenital area Wetness of the anogenital area Reproductive

Skin and Appendages Piloerection

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Key literature references and sources for data Outside testing

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CAS#: 7681-11-0 Substances) Salt of

N,N-Diethyl-p-Phenyl enediamine

(1 - 5%)

CAS#: -

Rat

LD50

695 mg/kg None reported

None reported Outside testing

Reported dose Exposure time Toxicological effects Key literature references and sources for data Salt of

N,N-Diethyl-p-Phenyl enediamine

(1 - 5%)

CAS#: -

None reported

None reported

None reported

None reported No information available

Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity.

Acute Toxicity Estimations (ATE)

ATEmix (oral) No information available ATEmix (dermal) No information available ATEmix (inhalation-dust/mist) No information available ATEmix (inhalation-vapor) No information available ATEmix (inhalation-gas) No information available

Skin corrosion/irritation Classification based on data available for ingredients. Irritating to skin.

Product Skin Corrosion/Irritation Data No data available.

Ingredient Skin Corrosion/Irritation Data Test data reported below.

Chemical name Test method Species Reported dose

Exposure time

Results Key literature references and sources for data Phosphoric acid, disodium salt (20 - 30%)

CAS#: 7558-79-4

Standard Draize Test

Rabbit 500 mg 24 hours Skin irritant RTECS (Registry of Toxic Effects of

Chemical Substances)

Serious eye damage/irritation Classification based on data available for ingredients. Irritating to eyes.

Product Serious Eye Damage/Eye Irritation Data No data available.

Ingredient Eye Damage/Eye Irritation Data Test data reported below.

Chemical name Test method Species Reported dose

Exposure time

Results Key literature references and sources for data Phosphoric acid, disodium salt (20 - 30%)

CAS#: 7558-79-4

Standard Draize Test

Rabbit 500 mg 24 hours Eye irritant RTECS (Registry of Toxic Effects of

Chemical Substances)

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Respiratory or skin sensitization Based on available data, the classification criteria are not met.

Product Sensitization Data No data available.

Ingredient Sensitization Data

Skin Sensitization Exposure Route

Chemical name Test method Species Results Key literature references and sources for data

Potassium iodide (KI) (20 - 30%)

CAS#: 7681-11-0

Patch test Human Not confirmed to be a skin sensitizer ERMA (New Zealands Environmental Risk Management Authority)

STOT - single exposure Based on available data, the classification criteria are not met.

Product Specific Target Organ Toxicity Single Exposure Data No data available.

Ingredient Specific Target Organ Toxicity Single Exposure Data

Reported dose

Exposure time

Toxicological effects Key literature references and sources for data

Potassium iodide (KI) (20 - 30%)

CAS#: 7681-11-0

Mouse LDLo

1862 mg/kg None reported

Lungs, Thorax, or Respiration

Dyspnea

RTECS (Registry of Toxic Effects of Chemical

Substances)

STOT - repeated exposure

Product Specific Target Organ Toxicity Repeat Dose Data No data available.

Ingredient Specific Target Organ Toxicity Repeat Exposure Data

Reported dose

Exposure time

Toxicological effects Key literature references and sources for data

Potassium iodide (KI) (20 - 30%)

CAS#: 7681-11-0

Rat

NOAEL

0.5 mg/kg 90 days None reported ECHA (The European Chemicals Agency)

Carcinogenicity

Product Carcinogenicity Data No data available.

Ingredient Carcinogenicity Data No data available.

Chemical name CAS No ACGIH IARC NTP OSHA

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Carboxylate Salt - - - - - Phosphoric acid, disodium salt 7558-79-4 - - - -

Potassium iodide (KI) 7681-11-0 - - - - Salt of

N,N-Diethyl-p-Phenylenedi amine

Legend

ACGIH (American Conference of Governmental Industrial Hygienists) Does not apply IARC (International Agency for Research on Cancer) Does not apply NTP (National Toxicology Program) Does not apply OSHA (Occupational Safety and Health Administration of the US Department of Labor)

Does not apply

Germ cell mutagenicity Based on available data, the classification criteria are not met.

Product Germ Cell Mutagenicity invitro Data No data available.

Ingredient Germ Cell Mutagenicity invitro Data Test data reported below.

Chemical name Test Cell Strain Reported dose

Exposure time

Results Key literature references and sources for data Potassium iodide (KI)

(20 - 30%)

CAS#: 7681-11-0

Cytogenetic analysis

Rat ascites tumor 500 mg/kg None reported

Positive test result for mutagenicity

RTECS (Registry of Toxic Effects of

Chemical

Product Germ Cell Mutagenicity invivo Data No data available.

Ingredient Germ Cell Mutagenicity invivo Data No data available.

Reproductive toxicity Based on available data, the classification criteria are not met.

Product Reproductive Toxicity Data No data available.

Ingredient Reproductive Toxicity Data

Reported dose

Exposure time

Toxicological effects Key literature references and sources for data

Potassium iodide (KI) (20 - 30%)

CAS#: 7681-11-0

Human TDLo

2700 mg/kg 39 weeks Specific Developmental Abnormalities

Endocrine System

RTECS (Registry of Toxic Effects of Chemical

Aspiration hazard

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12. ECOLOGICAL INFORMATION

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Ecotoxicity Based on available data, the classification criteria are not met.

Unknown aquatic toxicity 0 % of the mixture consists of component(s) of unknown hazards to the aquatic environment.

Product Ecological Data

Aquatic Acute Toxicity No data available.

Aquatic Chronic Toxicity No data available.

Ingredient Ecological Data

Aquatic Acute Toxicity

Crustacea

Chemical name Exposure time

Species Endpoint type

Reported dose

Key literature references and sources for data

Salt of N,N-Diethyl-p-Phenyl enediamine (1 - 5%)

CAS#: -

48 Hours Daphina magna EC50 10.8 mg/L Internal Data

Aquatic Chronic Toxicity No data available.

Persistence and degradability

Product Biodegradability Data No data available.

Bioaccumulation

MATERIAL DOES NOT BIOACCUMULATE

Product Bioaccumulation Data No data available.

Partition Coefficient (n-octanol/water) log Kow ~ 0

Mobility

Soil Organic Carbon-Water Partition Coefficient log Koc ~ 0

Other adverse effects No information available

13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Waste from residues/unused products

Dispose of in accordance with local regulations. Dispose of waste in accordance with environmental legislation.

Contaminated packaging Do not reuse empty containers.

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US EPA Waste Number Not applicable

14. TRANSPORT INFORMATION

DOT Not regulated

TDG Not regulated

IATA Not regulated

IMDG Not regulated

Note: No special precautions necessary.

Additional information

15. REGULATORY INFORMATION

National Inventories TSCA Complies DSL/NDSL Complies

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List

International Inventories EINECS/ELINCS Complies ENCS Complies IECSC Complies Existing substances Complies PICCS Complies TCSI Complies AICS Complies NZIoC Complies

EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances TCSI - Taiwan Chemical Substances Inventory AICS - Australian Inventory of Chemical Substances NZIoC - New Zealand Inventory of Chemicals

US Federal Regulations

SARA 313

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Yes Fire hazard No Sudden release of pressure hazard No

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Reactive Hazard No

CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)

Chemical name CWA - Reportable Quantities

CWA - Toxic Pollutants CWA - Priority Pollutants

CWA - Hazardous Substances

Phosphoric acid, disodium salt 7558-79-4

5000 lb - - X

CERCLA

This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)

Chemical name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) Phosphoric acid, disodium salt

7558-79-4 5000 lb - RQ 5000 lb final RQ

RQ 2270 kg final RQ

US State Regulations

California Proposition 65 This product does not contain any Proposition 65 chemicals

IMERC: Not applicable

New Jersey Trade Secret Registry Number 80100131-5001 (Carboxylate Salt) New Jersey Trade Secret Registry Number 80100131-5002 (DPD Salt) New York Trade Secret Registry Number 478 (DPD Salt) New York Trade Secret Registry Number 479 (Carboxylate Salt) This product complies with Pennsylvania Trade Secret Regulations. This product is registered as a trade secret in the state of Illinois. This product is registered as a trade secret in the state of Massachusetts. This product is registered as a trade secret in the state of New York.

U.S. State Right-to-Know Regulations

This product may contain substances regulated by state right-to-know regulations.

Chemical name New Jersey Massachusetts Pennsylvania Phosphoric acid, disodium salt

7558-79-4 X X X

U.S. EPA Label Information

Chemical name FIFRA FDA Phosphoric acid, disodium salt 180.0910 21 CFR 182.1778,21 CFR 182.6290,21

CFR 182.6778,21 CFR 182.8778

Potassium iodide (KI) 180.0940 21 CFR 184.1634

16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION

Special Comments None

Additional information

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Global Automotive Declarable Substance List (GADSL) Not applicable NFPA and HMIS Classifications

Key or legend to abbreviations and acronyms used in the safety data sheet

NIOSH IDLH Immediately Dangerous to Life or Health ACGIH ACGIH (American Conference of Governmental Industrial Hygienists) NDF no data

Legend - Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Prepared By Hach Product Compliance Department

Issue Date 09-Dec-2020

Revision Date 09-Dec-2020

Revision Note None

Disclaimer

USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety programs in accordance with applicable hazard communication standards and regulations.

THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE

OBTAINED FROM THE USE THEREOF.

HACH COMPANYÓÓÓÓÓ2019

End of Safety Data Sheet

NFPA Health hazards - 2 Flammability - 0 Instability - 0 Physical and chemical properties -

HMIS Health hazards - 2 Flammability - 0 Physical hazards - 0 Personal protection - X

- I

TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit)

MAC Maximum Allowable Concentration Ceiling Ceiling Limit Value

X Listed Vacated These values have no official status. The only binding levels of contaminants are those listed in the final OSHA PEL. These lists are for reference purposes only. Please note that some reference state regulations of these "liberated" exposure limits in their state regulations.

SKN* Skin designation SKN+ Skin sensitization RSP+ Respiratory sensitization ** Hazard Designation C Carcinogen R Reproductive toxicant M mutagen

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