SDS POLYELECTROLYTE.pdf

Chlorine

Molecular chlorine; CHLORINE GAS; active chlorine released from chlorine; Dichlorine;

Dichlor; Diatomic chlorine; Chlorine molecule; Chlorine mol.; Chlor mol.; Chlorine, liquefied; Liquid chlorine

Gas.

SAFETY DATA SHEET

GHS product identifier

Other means of identification

Product type

Section 1. Identification

Chemical name : chlorine

Supplier's details :

Chlorine

Product use : Synthetic/Analytical chemistry.

Synonym : Molecular chlorine; CHLORINE GAS; active chlorine released from chlorine;

Dichlorine; Dichlor; Diatomic chlorine; Chlorine molecule; Chlorine mol.; Chlor mol.;

Chlorine, liquefied; Liquid chlorine

SDS # : 001015

Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253

1-866-734-3438:24-hour telephone

Section 2. Hazards identification

OXIDIZING GASES - Category 1 GASES UNDER PRESSURE - Compressed gas ACUTE TOXICITY (inhalation) - Category 2 SKIN CORROSION - Category 1 SERIOUS EYE DAMAGE - Category 1 AQUATIC HAZARD (ACUTE) - Category 1

Classification of the substance or mixture

Signal word : Danger

Hazard statements : May cause or intensify fire; oxidizer.

Contains gas under pressure; may explode if heated.

Causes severe skin burns and eye damage.

Fatal if inhaled.

Very toxic to aquatic life.

Hazard pictograms :

Precautionary statements

GHS label elements

General :

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200).

Read and follow all Safety Data Sheets (SDS’S) before use. Read label before use.

Keep out of reach of children. If medical advice is needed, have product container or label at hand. Close valve after each use and when empty. Use equipment rated for cylinder pressure. Do not open valve until connected to equipment prepared for use.

Use a back flow preventative device in the piping. Use only equipment of compatible materials of construction. Open valve slowly. Use only with equipment cleaned for Oxygen service.

Date of issue/Date of revision : 2/11/2021 Date of previous issue : 3/23/2017 Version : 1 1/12

Section 2. Hazards identification Prevention : Wear protective gloves. Wear protective clothing. Wear eye or face protection. In case of inadequate ventilation wear respiratory protection. Keep away from clothing and other combustible materials. Keep reduction valves, valves and fittings free from oil and grease. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Do not breathe gas.

Response : Collect spillage. In case of fire: Stop leak if safe to do so. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER or doctor. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Storage : Store locked up. Protect from sunlight. Store in a well-ventilated place.

Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations.

Hazards not otherwise classified

: None known.

Section 3. Composition/information on ingredients chlorine 100 7782-50-5

Ingredient name CAS number%

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Chemical name : chlorine

Other means of identification

: Molecular chlorine; CHLORINE GAS; active chlorine released from chlorine; Dichlorine;

Dichlor; Diatomic chlorine; Chlorine molecule; Chlorine mol.; Chlor mol.; Chlorine, liquefied; Liquid chlorine

CAS number : 7782-50-5

Substance/mixture

CAS number/other identifiers

Occupational exposure limits, if available, are listed in Section 8.

Substance

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

Product code : 001015

As this product is a gas, refer to the inhalation section.

Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician.

Get medical attention immediately. Call a poison center or physician. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes.

Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion :

Description of necessary first aid measures

Date of issue/Date of revision : 2/11/2021 Date of previous issue : 3/23/2017 Version : 1 2/12

Section 4. First aid measures

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Specific treatments : No specific treatment.

Most important symptoms/effects, acute and delayed

Inhalation : Fatal if inhaled.

As this product is a gas, refer to the inhalation section.:Ingestion

Skin contact : Causes severe burns. Contact with rapidly expanding gas may cause burns or frostbite.

Causes serious eye damage. Contact with rapidly expanding gas may cause burns or frostbite.

:Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation No specific data.

Adverse symptoms may include the following:, stomach pains

Adverse symptoms may include the following:, pain or irritation, redness, blistering may occur

Eye contact : Adverse symptoms may include the following:, pain, watering, redness

Potential acute health effects

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary

Frostbite : Try to warm up the frozen tissues and seek medical attention.

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Contact supplier immediately for specialist advice. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. If involved in fire, shut off flow immediately if it can be done without risk.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials:

halogenated compounds

Contains gas under pressure. Oxidizing material. This material increases the risk of fire and may aid combustion. Contact with combustible material may cause fire. In a fire or if heated, a pressure increase will occur and the container may burst or explode.

This material is very toxic to aquatic life. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

Use an extinguishing agent suitable for the surrounding fire.

Extinguishing media

None known.

Suitable extinguishing media

Unsuitable extinguishing media

Special protective actions for fire-fighters

Date of issue/Date of revision : 2/11/2021 Date of previous issue : 3/23/2017 Version : 1 3/12

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof tools and explosion-proof equipment. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

: No action shall be taken involving any personal risk or without suitable training.

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe gas. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Ensure emergency procedures to deal with accidental gas releases are in place to avoid contamination of the environment. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage.

Large spill :

Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof tools and explosion-proof equipment.

Small spill :

Methods and materials for containment and cleaning up

For non-emergency personnel

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".

Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage, including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store in a segregated and approved area.

Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10). Cylinders should be stored upright, with valve protection cap in place, and firmly secured to prevent falling or being knocked over.

Cylinder temperatures should not exceed 52 °C (125 °F). Store locked up. Separate from reducing agents and combustible materials. Store away from grease and oil.

Keep container tightly closed and sealed until ready for use. See Section 10 for incompatible materials before handling or use.

Protective measures Put on appropriate personal protective equipment (see Section 8). Contains gas under pressure. Do not get in eyes or on skin or clothing. Use only with adequate ventilation.

Wear appropriate respirator when ventilation is inadequate. Do not puncture or incinerate container. Use equipment rated for cylinder pressure. Close valve after each use and when empty. Protect cylinders from physical damage; do not drag, roll, slide, or drop. Use a suitable hand truck for cylinder movement.

Avoid release to the environment. Empty containers retain product residue and can be hazardous. Keep away from clothing, incompatible materials and combustible materials.

Do not breathe gas. Keep reduction valves free from grease and oil.

Precautions for safe handling

Section 8. Exposure controls/personal protection Control parameters

Occupational exposure limits

Date of issue/Date of revision : 2/11/2021 Date of previous issue : 3/23/2017 Version : 1 4/12

Section 8. Exposure controls/personal protection chlorine ACGIH TLV (United States, 3/2019).

STEL: 2.9 mg/m³ 15 minutes.

STEL: 0.4 ppm 15 minutes.

TWA: 1.5 mg/m³ 8 hours.

TWA: 0.1 ppm 8 hours.

NIOSH REL (United States, 10/2016).

CEIL: 1.45 mg/m³ 15 minutes.

CEIL: 0.5 ppm 15 minutes.

OSHA PEL (United States, 5/2018).

CEIL: 3 mg/m³ CEIL: 1 ppm OSHA PEL 1989 (United States, 3/1989).

STEL: 3 mg/m³ 15 minutes.

STEL: 1 ppm 15 minutes.

TWA: 1.5 mg/m³ 8 hours.

TWA: 0.5 ppm 8 hours.

California PEL for Chemical Contaminants ( Table AC-1) (United States).

PEL: 0.5 ppm 8 hours.

STEL: 1 ppm 15 minutes.

Ingredient name Exposure limits

Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/ or face shield. If inhalation hazards exist, a full-face respirator may be required instead.

Eye/face protection

Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental exposure controls

: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Appropriate engineering controls

: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.

Appropriate techniques should be used to remove potentially contaminated clothing.

Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures :

Individual protection measures

Skin protection

Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Date of issue/Date of revision : 2/11/2021 Date of previous issue : 3/23/2017 Version : 1 5/12

Section 8. Exposure controls/personal protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Respiratory protection :

Section 9. Physical and chemical properties

Physical state

Melting point

Relative density

Solubility

Gas. [GREENISH-YELLOW GAS WITH SUFFOCATING ODOR]

-101°C (-149.8°F)

Not applicable.

Very slightly soluble in the following materials: cold water.

Pungent.Odor pH

Colorless. Green. Yellow.Color

Evaporation rate Not available.

Auto-ignition temperature

Flash point

Not available.

[Product does not sustain combustion.]

Not available.

Not available.

Viscosity Not applicable.

Not available.Odor threshold

Partition coefficient: n-octanol/water

Appearance

Boiling point : -34°C (-29.2°F)

Flammability (solid, gas) : Extremely flammable in the presence of the following materials or conditions: reducing materials, combustible materials, organic materials and alkalis.

Lower and upper explosive (flammable) limits

: Not available.

Decomposition temperature : Not available.

Solubility in water : 7.41 g/l

: 70.9 g/moleMolecular weight

Flow time (ISO 2431) : Not available.

Vapor pressure

Vapor density 2.5 (Air = 1)

85.3 (psig):

Specific Volume (ft 3/lb) : 5.4054

Gas Density (lb/ft 3) : 0.185

Critical temperature : 143.85°C (290.9°F)

Section 10. Stability and reactivity

Conditions to avoid No specific data.

The product is stable.Chemical stability :

Possibility of hazardous reactions

: Hazardous reactions or instability may occur under certain conditions of storage or use.

Conditions may include the following:

contact with combustible materials Reactions may include the following:

risk of causing fire

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Date of issue/Date of revision : 2/11/2021 Date of previous issue : 3/23/2017 Version : 1 6/12

Section 10. Stability and reactivity

Hazardous decomposition products

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Highly reactive or incompatible with the following materials:

combustible materials reducing materials grease oil

Incompatible materials :

Under normal conditions of storage and use, hazardous polymerization will not occur.Hazardous polymerization :

Section 11. Toxicological information

Acute toxicity chlorine LC50 Inhalation Gas. Rat 293 ppm 1 hours

Product/ingredient name Result Species Dose Exposure

Carcinogenicity

Not available.

Mutagenicity

Not available.

Teratogenicity

Not available.

Reproductive toxicity

Not available.

Irritation/Corrosion

Not available.

Sensitization

Not available.

Information on the likely routes of exposure

Inhalation : Fatal if inhaled.

As this product is a gas, refer to the inhalation section.:Ingestion

Skin contact : Causes severe burns. Contact with rapidly expanding gas may cause burns or frostbite.

Causes serious eye damage. Contact with rapidly expanding gas may cause burns or frostbite.

:Eye contact

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:, pain, watering, redness

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)

Not available.

Not available.

Aspiration hazard

Not available.

Information on toxicological effects

: Not available.

Potential acute health effects

Date of issue/Date of revision : 2/11/2021 Date of previous issue : 3/23/2017 Version : 1 7/12

Section 11. Toxicological information

Not available.

No known significant effects or critical hazards.General :

No known significant effects or critical hazards.Carcinogenicity :

No known significant effects or critical hazards.Mutagenicity :

No known significant effects or critical hazards.Teratogenicity :

Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Skin contact

Ingestion

Inhalation No specific data.

Adverse symptoms may include the following:, stomach pains

Adverse symptoms may include the following:, pain or irritation, redness, blistering may occur

Potential chronic health effects

Delayed and immediate effects and also chronic effects from short and long term exposure

Numerical measures of toxicity

Inhalation (gases) 146.5 ppm

Route ATE value

Acute toxicity estimates

Potential immediate effects

: Not available.

Short term exposure

Potential delayed effects : Not available.

Potential immediate effects

: Not available.

Long term exposure

Potential delayed effects : Not available.

Section 12. Ecological information

Bioaccumulative potential

Not available.

Toxicity chlorine Acute EC50 5.1 ppm Marine water Algae - Macrocystis pyrifera - Young

4 days

Acute EC50 930000 µg/l Fresh water Aquatic plants - Lemna minor 4 days Acute LC50 2.03 µg/l Fresh water Crustaceans - Asellus racovitzai 2 days Acute LC50 30 µg/l Fresh water Daphnia - Daphnia pulex 48 hours Acute LC50 14 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours

Product/ingredient name SpeciesResult Exposure

Persistence and degradability

Soil/water partition coefficient (KOC)

: Not available.

Mobility in soil

Not available.

Date of issue/Date of revision : 2/11/2021 Date of previous issue : 3/23/2017 Version : 1 8/12

Section 12. Ecological information Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.

Empty Airgas-owned pressure vessels should be returned to Airgas. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container.

:Disposal methods

Section 14. Transport information

CHLORINE

2.3 (5.1, 8)

CHLORINE

2.3 (8)

CHLORINE

UN1017

2.3 (8)

UN1017 UN1017

Toxic - Inhalation hazard Zone B This product is not regulated as a marine pollutant when transported on inland waterways in sizes of ≤5 L or ≤5 kg or by road, rail, or inland air in non-bulk sizes, provided the packagings meet the general provisions of §§ 173.24 and 173.24a.

Reportable quantity 10 lbs / 4.54 kg. Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements.

Limited quantity Yes.

Quantity limitation Passenger aircraft/rail: Forbidden. Cargo aircraft: Forbidden.

Special provisions 2, B9, B14, T50, TP19

DOT IMDG IATA

UN number

UN proper shipping name

Transport hazard class(es)

Packing group

Additional information

Environmental hazards

Yes. Yes. Yes. The environmentally hazardous substance mark is not required.

TDG

UN1017

CHLORINE

2.3 (5.1, 8)

Yes.

Mexico

UN1017

CHLORINE

2.3 (5.1, 8)

Yes. The environmentally hazardous substance mark is not required.

DOT Classification :

“Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of the product.”

Date of issue/Date of revision : 2/11/2021 Date of previous issue : 3/23/2017 Version : 1 9/12

Section 14. Transport information

The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.

The environmentally hazardous substance mark may appear if required by other transportation regulations.

Quantity limitation Passenger and Cargo Aircraft: Forbidden. Cargo Aircraft Only:

Forbidden.

Special precautions for user

Transport in bulk according to IMO instruments

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

: Not available.

Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.13-2.17 (Class 2), 2.23-2.25 (Class 5), 2.40-2.42 (Class 8), 2.7 (Marine pollutant mark).

The marine pollutant mark is not required when transported by road or rail.

Explosive Limit and Limited Quantity Index 0 ERAP Index 500 Passenger Carrying Vessel Index Forbidden Passenger Carrying Road or Rail Index Forbidden

TDG Classification

IMDG

IATA

Section 15. Regulatory information U.S. Federal regulations

Clean Water Act (CWA) 311: chlorine

Clean Air Act (CAA) 112 regulated toxic substances: chlorine

SARA 313

Product name CAS number % chlorine 7782-50-5 100 chlorine 7782-50-5 100

Form R - Reporting requirements

Supplier notification

Clean Air Act Section 112

(b) Hazardous Air Pollutants (HAPs)

: Listed

Clean Air Act Section 602 Class I Substances

: Not listed

Clean Air Act Section 602 Class II Substances

: Not listed

DEA List I Chemicals (Precursor Chemicals)

: Not listed

DEA List II Chemicals (Essential Chemicals)

: Not listed

TSCA 8(a) CDR Exempt/Partial exemption: Not determined

SARA 302/304

SARA 304 RQ : 10 lbs / 4.5 kg chlorine 100 Yes. 100 - 10 -

Composition/information on ingredients

Name % EHS (lbs) (lbs)(gallons) (gallons)

SARA 302 TPQ SARA 304 RQ

SARA 311/312

Classification : Refer to Section 2: Hazards Identification of this SDS for classification of substance.

Date of issue/Date of revision : 2/11/2021 Date of previous issue : 3/23/2017 Version : 1 10/12

Section 15. Regulatory information

This material is listed.

This product does not require a Safe Harbor warning under California Prop. 65.

Massachusetts :

SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.

California Prop. 65

New York : This material is listed.

New Jersey : This material is listed.

Pennsylvania : This material is listed.

State regulations

International regulations

Chemical Weapon Convention List Schedules I, II & III Chemicals

Montreal Protocol

Not listed.

Stockholm Convention on Persistent Organic Pollutants

Not listed.

Rotterdam Convention on Prior Informed Consent (PIC)

Not listed.

UNECE Aarhus Protocol on POPs and Heavy Metals

Not listed.

Inventory list

Australia : This material is listed or exempted.

Canada : This material is listed or exempted.

China : This material is listed or exempted.

Europe : This material is listed or exempted.

Japan : Japan inventory (ENCS): Not determined.

Japan inventory (ISHL): Not determined.

Republic of Korea : This material is listed or exempted.

New Zealand : This material is listed or exempted.

Philippines : This material is listed or exempted.

Taiwan : This material is listed or exempted.

Turkey : This material is listed or exempted.

United States : This material is active or exempted.

Thailand : Not determined.

Viet Nam : This material is listed or exempted.

Not listed.

Section 16. Other information Hazardous Material Information System (U.S.A.)

/Health

Flammability

Physical hazards

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc.

Date of issue/Date of revision : 2/11/2021 Date of previous issue : 3/23/2017 Version : 1 11/12

Section 16. Other information

2/11/2021

History

Date of printing

Date of issue/Date of revision

Version

To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.

Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

Notice to reader

Date of previous issue

References : Not available.

Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations

2/11/2021

3/23/2017

National Fire Protection Association (U.S.A.)

Health

Special

Instability/Reactivity

Flammability

The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.

Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.

Procedure used to derive the classification

Classification Justification

OXIDIZING GASES - Category 1 Expert judgment GASES UNDER PRESSURE - Compressed gas According to package ACUTE TOXICITY (inhalation) - Category 2 On basis of test data SKIN CORROSION - Category 1 Expert judgment SERIOUS EYE DAMAGE - Category 1 Expert judgment AQUATIC HAZARD (ACUTE) - Category 1 Expert judgment

OX

Date of issue/Date of revision : 2/11/2021 Date of previous issue : 3/23/2017 Version : 1 12/12