RFQ_Att_6_-_SOW_Encl_3_-_MSDS_SEAVOYAGE_Data.pdf

DATE OF PREPARATION

Jan 14, 2012

MATERIAL SAFETY DATA SHEET

N51B301 13 00

SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NUMBER

N51B301

PRODUCT NAME

SeaVoyage Copper Free Antifouling Paint, Black

MANUFACTURER'S NAME

THE SHERWIN-WILLIAMS COMPANY

101 Prospect Avenue N.W.

Cleveland, OH 44115

Telephone Numbers and Websites Regulatory Information (216) 566-2902 www.paintdocs.com Medical Emergency (216) 566-2917

Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or accident)*

SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS

% by Weight CAS Number Ingredient Units Vapor Pressure

0.4 100-41-4 Ethylbenzene

ACGIH TLV 100 PPM 7.1 mm

ACGIH TLV 125 PPM STEL

OSHA PEL 100 PPM

OSHA PEL 125 PPM STEL

3 1330-20-7 Xylene ACGIH TLV 100 PPM 5.9 mm

ACGIH TLV 150 PPM STEL

OSHA PEL 100 PPM

OSHA PEL 150 PPM STEL

5 64742-95-6 Light Aromatic Hydrocarbons ACGIH TLV Not Available 3.8 mm OSHA PEL Not Available

1 98-82-8 Cumene ACGIH TLV 50 PPM 10 mm

OSHA PEL 50 PPM

2 108-67-8 1,3,5-Trimethylbenzene ACGIH TLV 25 PPM 2 mm

OSHA PEL 25 PPM

8 95-63-6 1,2,4-Trimethylbenzene ACGIH TLV 25 PPM 2.03 mm

OSHA PEL 25 PPM

8 Proprietary Chlorophenyl-cyano-bromo-trifluoromethyl Pyrrole ACGIH TLV Not Available OSHA PEL Not Available

7 13463-41-7 Zinc Pyrithione ACGIH TLV Not Available OSHA PEL Not Available

11 471-34-1 Calcium Carbonate ACGIH TLV 10 mg/m3 as Dust OSHA PEL 15 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction

27 1314-13-2 Zinc Oxide ACGIH TLV 2 mg/m3 as Resp. Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction

2 1333-86-4 Carbon Black

ACGIH TLV 3.5 MG/M3

OSHA PEL 3.5 MG/M3

N51B301

UEL

7.0

LEL

0.7

FLASH POINT

102 °F PMCC

HMIS Codes Health 3*

Flammability 2 Reactivity 1

SECTION 3 — HAZARDS IDENTIFICATION

ROUTES OF EXPOSURE

INHALATION of vapor or spray mist.

EYE or SKIN contact with the product, vapor or spray mist.

EFFECTS OF OVEREXPOSURE

EYES: Irritation.

SKIN: Prolonged or repeated exposure may cause irritation.

INHALATION: Irritation of the upper respiratory system.

May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death.

Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems:

the liver the urinary system the reproductive system

SIGNS AND SYMPTOMS OF OVEREXPOSURE

Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists.

Redness and itching or burning sensation may indicate eye or excessive skin exposure.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE

None generally recognized.

CANCER INFORMATION

For complete discussion of toxicology data refer to Section 11.

SECTION 4 — FIRST AID MEASURES

EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention.

SKIN: Wash affected area thoroughly with soap and water.

Remove contaminated clothing and launder before re-use.

INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet.

INGESTION: Do not induce vomiting. Get medical attention immediately.

SECTION 5 — FIRE FIGHTING MEASURES

FLAMMABILITY CLASSIFICATION

Combustible, Flash above 99 and below 200 °F

EXTINGUISHING MEDIA

Carbon Dioxide, Dry Chemical, Foam

UNUSUAL FIRE AND EXPLOSION HAZARDS

Closed containers may explode when exposed to extreme heat.

Application to hot surfaces requires special precautions.

During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention.

SPECIAL FIRE FIGHTING PROCEDURES

Full protective equipment including self-contained breathing apparatus should be used.

Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat.

SECTION 6 — ACCIDENTAL RELEASE MEASURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED

Remove all sources of ignition. Ventilate the area.

Remove with inert absorbent.

SECTION 7 — HANDLING AND STORAGE

STORAGE CATEGORY

DOL Storage Class II

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE

Contents are COMBUSTIBLE. Keep away from heat and open flame.

Consult NFPA Code. Use approved Bonding and Grounding procedures.

Store container upright to prevent leakage. Avoid storage near feed or food products.

Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally.

Keep out of the reach of children.

SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION

PRECAUTIONS TO BE TAKEN IN USE

Use only with adequate ventilation.

Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.

Wash hands after using.

This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction).

VENTILATION

Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits.

Refer to OSHA Standards 1910.94, 1910.107, 1910.108.

RESPIRATORY PROTECTION

If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2.

When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive.

PROTECTIVE GLOVES

Wear gloves which are recommended by glove supplier for protection against materials in Section 2.

EYE PROTECTION

Wear safety spectacles with unperforated sideshields.

OTHER PRECAUTIONS

Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal.

SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES

PRODUCT WEIGHT 12.75 lb/gal 1527 g/l

SPECIFIC GRAVITY 1.53

BOILING POINT 281 - 360 °F 138 - 182 °C

MELTING POINT Not Available

VOLATILE VOLUME 37%

EVAPORATION RATE Slower than ether

VAPOR DENSITY Heavier than air

SOLUBILITY IN WATER N.A.

VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)

2.68 lb/gal 321 g/l Less Water and Federally Exempt Solvents

2.68 lb/gal 321 g/l Emitted VOC

SECTION 10 — STABILITY AND REACTIVITY

STABILITY — Stable

CONDITIONS TO AVOID

None known.

INCOMPATIBILITY

None known.

HAZARDOUS DECOMPOSITION PRODUCTS

By fire: Carbon Dioxide, Carbon Monoxide

HAZARDOUS POLYMERIZATION

Will not occur

SECTION 11 — TOXICOLOGICAL INFORMATION

CHRONIC HEALTH HAZARDS

Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage.

Ethylbenzene is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high ethylbenzene concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals exposed to lower concentrations. There is no evidence that ethylbenzene causes cancer in humans.

Carbon Black is classified by IARC as possibly carcinogenic to humans (group 2B) based on experimental animal data, however, there is insufficient evidence in humans for its carcinogenicity.

TOXICOLOGY DATA

CAS No. Ingredient Name 100-41-4 Ethylbenzene

LC50 RAT 4HR Not Available LD50 RAT 3500 mg/kg

1330-20-7 Xylene LC50 RAT 4HR 5000 ppm LD50 RAT 4300 mg/kg

64742-95-6 Light Aromatic Hydrocarbons LC50 RAT 4HR Not Available LD50 RAT Not Available

98-82-8 Cumene LC50 RAT 4HR Not Available LD50 RAT 1400 mg/kg

108-67-8 1,3,5-Trimethylbenzene LC50 RAT 4HR Not Available LD50 RAT Not Available

95-63-6 1,2,4-Trimethylbenzene LC50 RAT 4HR Not Available LD50 RAT Not Available

Proprietary Chlorophenyl-cyano-bromo-trifluoromethyl Pyrrole LC50 RAT 4HR Not Available LD50 RAT 28.7 mg/kg

13463-41-7 Zinc Pyrithione LC50 RAT 4HR Not Available LD50 RAT 177 mg/kg

471-34-1 Calcium Carbonate LC50 RAT 4HR Not Available LD50 RAT Not Available

1314-13-2 Zinc Oxide LC50 RAT 4HR Not Available LD50 RAT Not Available

1333-86-4 Carbon Black LC50 RAT 4HR Not Available LD50 RAT Not Available

SECTION 12 — ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION

No data available.

SECTION 13 — DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHOD

Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.

Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers.

Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution.

SECTION 14 — TRANSPORT INFORMATION

Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport.

US Ground (DOT) May be Classed as a Combustible Liquid for U.S. Ground.

UN1263, PAINT, 3, PG III, (ERG#128)

DOT (Dept of Transportation) Hazardous Substances & Reportable Quantities Xylenes (isomers and mixture) 100 lb RQ

Bulk Containers may be Shipped as (check reportable quantities):

UN1263, PAINT, COMBUSTIBLE LIQUID, PG III, (ERG#128)

Canada (TDG) May be Classed as a Combustible Liquid for Canadian Ground.

UN1263, PAINT, CLASS 3, PG III, (ERG#128)

IMO

5 Liters (1.3 Gallons) and Less may be Shipped as Limited Quantity.

UN1263, PAINT, CLASS 3, PG III, MARINE POLLUTANT, (39 C c.c.), (ZINC OXIDE), EmS F-E, S-E, ADR (D/E)

IATA/ICAO

UN1263, PAINT, 3, PG III

SECTION 15 — REGULATORY INFORMATION

SARA 313 SUPPLIER NOTIFICATION(40 CFR 372.65C)

CAS No. CHEMICAL/COMPOUND % by WT % Element 100-41-4 Ethylbenzene 0.3 1330-20-7 Xylene 3 98-82-8 Cumene 1 95-63-6 1,2,4-Trimethylbenzene 8

Zinc Compound 34 23.2

CALIFORNIA PROPOSITION 65

WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.

TSCA CERTIFICATION

All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory.

SECTION 16 — OTHER INFORMATION

This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.

The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information.