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This document contains technical information on substances involved in lithium battery chemistry and reactions. Key substances described include electrolyte solvents, salts, and cathode and anode materials. The document provides molecular formulas and identifies various flammable and toxic compounds used in lithium-ion batteries.

The related federal contract opportunity is a multiple award construction contract for general construction services at Naval Support Activity Crane in Indiana. The solicitation seeks indefinite delivery/indefinite quantity construction services for renovations, repairs, and minor new work. The Navy is the contracting agency. No other salient details are provided in the opportunity description.

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Substance Molecular Formula for some of substances Diethyl Carbonate

(DEC)

C5H10O3

Dimethyl Carbonate

(DMC)

C3H6O3

1,2- Dimethoxyet hane (DME)

C4H10O2

Ethylene Carbonate

(EC)

C3H4O3

Ethyl Methyl Carbonate

(EMC)

C4H8O3

Propylene Carbonate

(PC)

C4H6O3

Tetrahydrof uran (THF) C4H8O Dimethyl ether C2H6O 1,3- Dioxolane

C3H6O2

1,2- Dimethoxyet hane (Ethylene Glycol)

C4H10O2

Acetonitril e (Methyl Cyanide)

CH3CN

Thionyl Chloride SOCl2 Bromine Chloride BrCl

SO2 SO2

Sulfuryl Chloride SO2Cl2 Lithium perchlorate LiClO4

Compound Molecular Formula Lithium tetrachloro aluminate

LiAlCl4

Lithium Bromide LiBr Lithium hexafluorop hosphate

LiPF6

Poly Vinylidene Flouride

(PVDF)

(CH2CF2)n

Lithium Cobaltite LiCoO2

Lithium Carbonate Li2CO3

Biphenyl (BP) C6H5C6H5

Propane Sultone C3H6O3S Dioxathiola ne 2,2- Dioxide

(DTD)

Some Substances involved in Lithium Batteries and Reactions

Molecular Formula for some of substances

Some Substances involved in Lithium Batteries and Reactions

Ethyl Acetate

C4H8O2

Lithium Nickel Oxide

LiNiO2

Lithium cobalt(III) oxide

LiCoO2

Lithium Manganese Spinel

LiMn2O4

Lithium Iron Phosphate

LiFePO4

Lithium Titanate Li4Ti5O12 Naphthalene Acenaphthylene Acenaphthene Fluorene Phenanthrene Anthracene Fluoranthene Pyrene Benzo(a)anthracene Chrysene Benzo(b)fluoranthene Benzo(k)fluoranthene Benzo(a)pyrene Benzo(g,h,i)perylene Dibenz(a,j)anthracene Indeno(1,2,3-cd)pyrene lithium thionyl chloride LiSOCl2 lithium sulfuryl chloride LiSO2Cl2 lithium sulfur dioxide LiSO2 lithium manganese dioxide LiMnO2 lithium carbon monofluoride LiCFX Sulfur S Water H20 Lithium Li Lithium Chloride LiCl Sulferous Acid H2SO3 Lithium foil hydrogen cyanide HCN Nitric oxide NO Nitrous oxide N2O Nitrogen N2 Carbon monoxide CO

Molecular Formula for some of substances

Some Substances involved in Lithium Batteries and Reactions

Carbon dioxide CO2 Lithium Sulfate Li2S2O4 Oxygen O2 Nitrogen Dioxide NO2 propylene carbonate C4H6O3 Manganese oxide MnO2 Carbon C Teflon C2F4

THF C4H8O

polycarbon monofluoride Carbon monofluoride lithium tetraborofluorate LiBF4 hydrogen fluoride HF Lithium tetrafluoroborate LiBF4 polyvinylidene fluoride PVDF Aluminum Al Nickel Ni Steel plastic lithium cobalt oxide LiCoO2 Lithium iron phosphate LiFePO4 Lithium ion manganese LiMn2O4, Li2MnO3, or LMO Lithium nickel manganese cobalt oxide LiNiMnCoO2 or NMC Lithium nickel cobalt aluminum oxide LiNiCoAlO2 or NCA lithium titanate Li4Ti5O12 or LTO Lithium Nickel Oxide LiNiO2 Lithium cobalt(III) oxide LiCoO2 Lithium Manganese Spinel LiMn2O4 Lithium Iron Phosphate LiFePO4 Lithium Titanate Li4Ti5O12 Manganese Dioxide MnO2 Nickel Oxide NiO fluoroethylene carbonate C3H3FO3 Acetylene Black C graphite C n-Methyl Pyrrolidinone C5H9NO Carbon Dioxide Carbon Monoxide Hydrogen Methane Ethylene Ethane Propylene Propane

Molecular Formula for some of substances

Some Substances involved in Lithium Batteries and Reactions

Isobutane n-Butane Butenes Isopentane n-Pentane Hexanes + Benzene Toluene Ethyl-benzene lithium sulfuryl chloride Benzene Toluene Ethyl Benzene 1-Hexene Anthracene Fluoranthene Pyrene Benzo(a)anthracene Chrysene Benzo(b)fluoranthene Benzo(k)fluoranthene Benzo(a)pyrene Benzo(e)pyrene Benzo(g,h,i)perylene Retene Indeno(1,2,3-cd)pyrene Naphthalene Acenaphthylene Fluorene Phenanthrene SOx

CO

VOC (nonmethane) NOx Methane propene chloromethane 1,3-butadiene tetrahydrofuran benzene 1,4-dioxane toluene ethyl benzene stryrene

Molecular Formula for some of substances

Some Substances involved in Lithium Batteries and Reactions butyrolacetone isoprene 1,2-dimethoxyethane isobutene methylcarbonate ethanol acetaldehyde

C7H10 dimethyl ether methyl sulfite methylethylcarbonate chlorobenzene hexafluoropropene chloroform 1,2-dimethoxycyclopropene 1,4hexadene 1-heptene 2,4-dimethyl-l-heptene 2-methyl-1-pentene

C5H10

Dimethyl carbonate n-pentane pentadiene HBr HCl

HF

H3P04

H2S04 carbonyl sulfide dimethyl sulfide carbon disulfide

H2S Dimethyl disulfide

Li/Co02

Li/CFx

Li/Mn02 Li/FeP04

Li/Mn04

SOCl2 S02Cl2

Molecular Formula for some of substances

Some Substances involved in Lithium Batteries and Reactions

ALUMINUM

COBALT

COPPER

HYDROGEN CHLORIDE

LEAD

MERCURY

NICKEL METAL

SULFURIC ACID

ZINC OXIDE

HCl

H2SO4

nickel cobalt copper aluminum zinc oxide mercury soda ash NaOH

Zn Hg

ALUMINUM METAL, TOTAL DUST (As Al) COBALT & INORGANIC COMPOUNDS (As Co) COPPER DUST & MISTS (As Cu)

IRON

LEAD & INORGANIC COMPOUNDS (As Pb)

MANGANESE

NICKEL, INSOL CMPDS (As Ni)

ZINC

LITHIUM

CHROMIUM

IRON

MOLYBDENUM

Aluminum Antimony Arsenic Barium Cadmium Calcium Chromium Cobalt Copper Iron

Molecular Formula for some of substances

Some Substances involved in Lithium Batteries and Reactions

Lead Magnesium Manganese Nickel Potassium Silver Sodium Thallium Vanadium Zinc Mercury Benzo(a)pyrene Lithium Cobalt Oxide LiCoO2 Lithium Manganese Oxide LiMn2O4 Lithium Nickel Manganese Cobalt Oxide LiNiMnCoO2 Lithium Iron Phosphate LiFePO4 Lithium Nickel Cobalt Aluminum Oxide LiNiCoAlO2 Lithium Titanate Li4Ti5O12 Graphite Lithium hexafluorophosphate LiPF6

Hydrofluoric acid HF carbon LiNiCoO2 methane hydrogen carbon dioxide carbon monoxide Lithium cobalt oxide LiCoO2 Carbon Dioxide Carbon Monoxide Hydrogen Methane Ethylene Ethane Propylene Propane Isobutane n-Butenes Butenes Isopentane n-Pentane Benzene Toluene

Molecular Formula for some of substances

Some Substances involved in Lithium Batteries and Reactions

Ethylbenzene m+p Xylenes Hydrogen H2 Oxygen O2 Nitrogen N2 Carbon Monoxide CO Methane CH4 Carbon Dioxide C02 Nitrous Oxide N20 Hydrogen Sulfide H2S Acetylene C2H2 Ethene C2H4 Ethane C2H6, GC10 Ethane C2H6, GC8 Propane C3H8 n-butane C4H10 n-pentane C5H12 n-hexane C6H14 C6+ hydrocarbons

Sheet1

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