Purge Fluid MIL-PRF-38299E SDS.pdf

Safety Data Sheet

(MIL-PRF-38299E)

1 – PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: ...................... MIL-PRF-38299E

CHEMICAL NAME/

CLASS/SYNONYMS: Aliphatic hydrocarbon, Paraffins, Cycloparaffins

PRODUCT NUMBER: ................ MIL-PRF-38299E

UN/NA NUMBER: ....................... None CHEMICAL FAMILY: ............... Aliphatic Solvent

CAS NUMBER: ............................ 64742-47-8

FORMULA: Mixture

COMPANY: .................................. JMN Specialties, Inc.

1100 Victory Drive – Westwego, Louisiana USA 70094 Phone (504) 341-3749, Fax (504) 341-5868 www.jmnspecialties.com EMERGENCY PHONE: ............. CALL CHEMTEL: Toll Free US & Canada: (800) 255-3924, Outside

USA +01-813-248-0585.

DATE PREPARED: ..................... February 28, 2019

2 – HAZARDS IDENTIFICATION

GHS HAZARD CLASSIFICATION:

Physical Hazards Flammable Liquids: ................. . Category 4 - Combustible liquid Health Hazards Acute Toxicity (Oral): ............. . Category 4 - Harmful if swallowed, in contact with skin, inhaled Skin Corrosion/Irritation: ...... . Catagory 2 - Causes skin irritation Serious Eye Damage/Irritation: Catagory 2A - Causes eye irritation Aspiration Hazard: .................. . Catagory 1 - May be fatal if swallowed and enters airways

WARNING LABEL ITEMS INCLUDING PRECAUTIONARY STATEMENTS:

Pictograms:

SIGNAL WORD: .......................... DANGER!

GHS HAZARD AND PRECAUTIONARY STATEMENTS:

H303 H313 H333: May be harmful if swallowed, in contact with skin or if inhaled H305: May be harmful if swallowed and enters airways

P101+102+103: If medical advice is needed, have product container or label at hand. Keep out of the reach of children. Read label before use.

P202+270+280+281: Do not handle until all safety precautions have been read and understood. Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required.

http://www.jmnspecialties.com/

P501: Dispose of contents/container: Treatment, storage, transportation and disposal must be in accordance with Federal, State/Provincial and Local Regulations. Regulations may vary in different locations.

Characterization and compliance with applicable laws are the responsibility solely of the generator.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

TOTAL VOC’s: None

3 – COMPOSITION / INFORMATION ON INGREDIENTS

HAZARDOUS INGREDIENT PERCENT CAS NUMBER

Paraffinic Naphthenic Solvent

> 99.0 64742-47-8

4 – FIRST-AID MEASURES

BREATHING (INHALATION): Remove from exposure area to fresh air immediately. If breathing has stopped, perform artificial resuscitation. Keep person warm and at rest.

Treat symptomatically and supportively. Seek medical attention immediately. Qualified medical personnel should consider administering oxygen.

SWALLOWING (INGESTION): Give large amounts of fresh water or milk immediately. Do not give anything by mouth if person is unconscious or otherwise unable to swallow. If vomiting occurs, keep head below hips to prevent aspiration. Treat symptomatically and supportively. Seek medical attention immediately.

EYES: ............................................ Flush eye with copious quantities of water. If persistent irritation occurs, obtain medical attention.

SKIN (DERMAL):........................ Remove contaminated clothing and wash affected skin with soap and water. If persistent irritation occurs, obtain medical attention. When using high pressure equipment, injection of product under the skin can occur. If high pressure injuries occur, the casualty should be sent immediately to a hospital. Do not wait for symptoms to develop.

NOTE TO PHYSICIAN: ............. All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred. Material, if aspirated into the lungs, may cause chemical pneumonitis. Skin contact may aggravate an existing dermatitis. Treat appropriately.

5 – FIRE-FIGHTING MEASURES

GENERAL FIRE HAZARDS: .... This product has been determined to be a combustible liquid per the OSHA Hazard Communication Standard and should be handled accordingly.

AUTOIGNITION TEMP: 421°F (216°C)

EXTINGUISHING MEDIA: Determined by surrounding material. In case of fire, use water fog, dry chemical, CO2, or "alcohol" foam.

SPECIAL FIRE FIGHTING

PROCEDURES: Spilled product on ground may be slippery.

UNUSUAL FIRE AND

EXPLOSION HAZARDS: ........... Containers may explode from internal pressure if confined to fire. Cool with water spray. Vapor accumulation could flash or explode if in contact with an open flame.

6 – ACCIDENTAL RELEASE MEASURES

SPILL PROCEDURES: ............... Wear appropriate personal protective equipment before approaching spill site. For small spills, dilute with water to sewer if allowed by local and state regulations. If unable to wash product with water, absorb with inert material (sand or other approved material) and dispose of in accordance with applicable regulations.

WASTE DISPOSAL: ................... Treatment, storage, transportation and disposal must be in accordance with Federal, State/Provincial and Local Regulations. Regulations may vary in different locations. Characterization and compliance with applicable laws are the responsibility solely of the generator. Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

RCRA STATUS: ........................... This product as produced is not specifically listed as an EPA RCRA hazardous waste according to federal regulations (40 CFR 261).

However, when discarded or disposed of, it may meet the criteria of an "characteristic" hazardous waste. This material could become a hazardous waste if mixed or contaminated with a hazardous waste or other substance(s). It is the responsibility of the user to determine if disposal material is hazardous according to federal, state and local regulations.

7 – HANDLING and STORAGE

STORAGE: Keep in a tightly closed container, stored in a cool, dry, ventilated area below 44°C (110°F). Protect against physical damage. Isolate from incompatible substances. Containers of this material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product. Drum must not be washed out or used for other purposes.

HANDLING: ................................. Avoid contact with eyes, skin and clothing. Do not inhale vapors and fumes. Wash thoroughly after handling. Use only with adequate ventilation. Do not take internally. For industrial use only.

8 – EXPOSURE CONTROLS / PERSONAL PROTECTION

OCCUPATIONAL EXPOSURE LIMITS

HAZARDOUS INGREDIENT PEL TLV-TWA

Paraffinic Naphthenic Solvent

100 ppm 100 ppm

EXPOSURE CONTROLS: Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.

RESPIRATORY PROTECTION: If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. In the United States of America, if respirators are used, a program should be instituted to assure compliance with OSHA Standard 63 FR 1152, January 8, 1998.

Respirator type: Air-purifying respirator with an appropriate, government approved (where applicable), air-purifying filter, cartridge or canister. Contact health and safety professional or manufacturer for specific information. Self-Contained Breathing Apparatus may be required for use in confined or enclosed spaces.

PROTECTIVE CLOTHING: Eye/face protection: Wear chemical goggles; face shield (if splashing is possible). Skin protection: Chemical resistant, impermeable gloves.

Gloves should be tested to determine suitability for prolonged contact.

Use of impervious apron or chemical suit and chemical resistant boots are recommended.

ADDITIONAL MEASURES: Handle in accordance with good industrial hygiene and safety practice.

Wash thoroughly with soap and water after handling and before eating, drinking, or using tobacco. Safety shower and eye wash should be available close to work areas.

9 – PHYSICAL / CHEMICAL PROPERITES

BOILING POINT: 464 - 528°F (239 - 276°C)

FREEZING POINT: -94°F (-70°C)

FLASHPOINT: 229°F (109°C), Average

UPPER FLAME LIMIT (%): ..... 7.0%

LOWER FLAME LIMIT (%): ... 0.5%

VAPOR PRESSURE: 0.02 mm Hg @ 20°C, 68°F

VAPOR DENSITY (AIR=1): ....... 6.7

SPECIFIC GRAVITY: ................ 0.82 - 0.83

pH: ................................................. NA SOLUBILITY IN WATER: ......... Negligible

VOLATILITY

INCLUDING WATER: 6.84 pounds per gallon MOLECULAR WEIGHT: .......... No data available (G/MOLE)

EVAPORATION RATE: ............. ND

PHYSICAL STATE: .................... Liquid COLOR: ........................................ Water-white to straw-yellow ODOR: ........................................... Mild Hydrocarbon Odor

10 – STABILITY and REACTIVITY

STABILITY: ................................. Stable HAZARDOUS DECOMP.: .......... Will not occur INCOMPATIBILITY: ................. Oxidizers or Oxidizing Materials.

HAZARDOUS REACTIONS: Not expected to be Explosive, Self-Reactive, Self-Heating, or an

Organic Peroxide under US GHS Definition(s).

11 – TOXICOLOGICAL INFORMATION

Cancer: Research shows that the Solvents used in the mixture are unlikely to cause cancer. Reproductive Effects: There are no indications that the Solvents used in the mixture causes damage to reproductive organs. Solvents may affect the development of unborn babies. Organ Systems: Damage to the brain, liver, bone marrow and kidneys can occur with repeated or excessive inhalation of any solvent vapors.

THRESHOLD LIMIT VALUE:.. 100 ppm OSHA PEL: ................................... 100 ppm LISTED CARCINOGEN: This product IS NOT listed in the National Toxicology Program (NTP)

Report on Carcinogens (latest edition) or has been found to be a potential carcinogen in the International Agency for Research on Cancer (IARC) Monographs (latest editions) or found to be a potential carcinogen by OSHA.

MEDICAL CONDITION

AGGRAVATED: Existing dermatitis.

INFORMATION ON ACUTE TOXICOLOGICAL EFFECTS

ORAL

Product: .................................... Ingestion can cause gastrointestinal irritation, nausea, vomiting and diarrhea. Ingestion of this product may result in central nervous system depression including headache, weakness, dizziness, loss of coordination and judgement and coma. Small amounts of this product, if aspirated into the lungs, may cause mild to severe pulmonary injury, possibly death. Ingestion of this product may cause diarrhoea & stomach discomfort – not a route of industrial exposure.

DERMAL

Product: .................................... Considered to be practically non-toxic based on single contact testing with little immedate effect. Skin contact may aggravate existing dermatitis.

INHALATION

Product: .................................... Inhalation of mists or fumes at 400ppm or higher may cause burning sensation in nose & throat, intoxication dizziness, fatigue.

REPEATED DOSE TOXICITY

Product: .................................... Product is a colorless liquid with typical aliphatic solvent odor. Chronic exposure may be harmful by inhalation, when in contact with the skin and if it is swallowed. Liquid and vapor may be irritating to the eyes, skin and respiratory system. Product may cause central nervous system (CNS) depression characterized by nausea, dizziness, headache, lack of coordination, loss of consciousness and coma.

SKIN CORROSION / IRRITATION

Product: .................................... Repeated and prolonged exposure to concentrated material may cause dermatitis.

SERIOUS EYE DAMAGE / IRRITATION

Product: .................................... This product may cause severe burning sensation with temporary irritation and swelling of eyelids. Vapors may also produce eye irritation. Chronic exposure may result in cataracts and reduces visual reaction time.

RESPIRATORY OR SKIN SENSITIZATION

Product: .................................... Not expected to be sensitizing based on tests of this product, components, or similar products.

MUTAGENCITY

IN VITRO

Product: .................................... No Data Available

IN VIVO

Product: .................................... No Data Available Specified Substance(s) Information as provided by manufacturer

Aliphatic Hydrocarbons No Data Available

CARCINOGENICITY

Product: .................................... Based on available data, the classification criteria are not met.

REPODUCTIVE TOXICITY

Product: .................................... Based on available data the classification criteria are not met. Not classified as hazardous.

SPECIFIC TARGET ORGAN TOXICITY – SINGLE EXPOSURE

Product: GENERAL: Solvent vapors may be irritating to skin and eyes. INHALATION: High concentrations of vapor may cause irritation of the respiratory tract, experienced as nasal discomfort and discharge, possibly with chest pain and coughing. NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage.

Intentional misuse by deliberately concentrating and inhaling this product may be harmful or fatal. EYES:

May cause mild to severe rritation experienced as discomfort or pain, excess blinking and tear production, possibly with marked redness and swelling of the conjunctiva. SKIN: Brief contact may cause slight irritation with itching and local redness. Prolonged contact may cause more severe irritation, with discomfort or pain. SWALLOWING: May cause headache, dizziness, nausea, vomiting, diarrhea, coma, and death.

SPECIFIC TARGET ORGAN TOXICITY – REPEATED EXPOSURE

Product: .................................... The effects of long-term, low-level exposures to this product have not been determined. Safe handling of this material on a long-term basis should emphasize the avoidance of all effects from repetitive acute exposure. This product may aggravate existing eye, skin, and respiratory conditions.

ASPIRATION HAZARD

Product: .................................... Droplets of the product aspirated into the lungs through ingestion or vomiting may cause chemical pneumonia.

OTHER ADVERSE EFFECTS

Product: .................................... The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

12 – ECOLOGICAL INFORMATION

ACUTE TOXICITY

FISH

Product: .................................... Not toxic to aquatic organisms (fish, daphnia, algae) up to water solubility.

AQUATIC INVERTEBRATES

Product: .................................... 48hr EC50 (Daphnia magna): >100 mg/L (based on similar products / components)

CHRONIC TOXICITY

FISH

Product: .................................... NOEC/NOEL > 100 mg/l. (based on similar products / components)

AQUATIC INVERTEBRATES

Product: .................................... NOEC/NOEL > 100 mg/l. (based on similar products / components)

TOXICITY TO AQUATIC PLANTS

Product: .................................... Not toxic to aquatic organisms (fish, daphnia, algae) up to water solubility.

PERSISTENCE AND DEGRADABILITY

BIODEGRADATION

Product: .................................... Readily Biodegradable.

BIOLOGICAL OXYGEN DEMAND

Product: .................................... No data available

CHEMICAL OXYGEN DEMAND

Product: .................................... No data available

BOD / COD RATIO

Product: .................................... No data available

BIOACCUMULATIVE POTENTIAL

Product: .................................... Accumulation in terrestrial organisms is unlikely. Bioaccumulation is unlikely.

MOBILITY IN SOIL

Product: .................................... Not expected to partition to sediment and wastewater solids.

RESULTS OF PBT AND mPvB ASSESSMENT Product: .................................... Not fulfilling PBT (persistent/bioaccumulative/toxic) criteria. Not fulfilling vPvB (very persistent, very bioaccumulative) criteria.

OTHER ADVERSE EFFECTS

Product: ................................... No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this product.

13 –DISPOSAL CONSIDERATIONS

WASTE DISPOSAL: ................... Treatment, storage, transportation and disposal must be in accordance with Federal, State/Provincial and Local Regulations. Regulations may vary in different locations. Characterization and compliance with applicable laws are the responsibility solely of the generator. Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

RCRA STATUS: ........................... This product as produced is not specifically listed as an EPA RCRA hazardous waste according to federal regulations (40 CFR 261).

However, when discarded or disposed of, it may meet the criteria of an "characteristic" hazardous waste. This material could become a hazardous waste if mixed or contaminated with a hazardous waste or other substance(s). It is the responsibility of the user to determine if disposal material is hazardous according to federal, state and local regulations.

14 – TRANSPORTATION INFORMATION

Important Note: Shipping descriptions may vary based on mode of transport, quantities, package size, and/or origin and destination. Consult your company's Hazardous Materials/Dangerous Goods expert for information specific to your situation.

UN/NA NUMBER: ....................... None PROPER SHIPPING NAME: Non-Regulated HAZARD CLASS: ........................ None PACKAGING GROUP : .............. None LETTER:....................................... None ENVIRONMENTAL HAZARD: Because of modern treatment methods or method of use of this product, only an insignificant amount of the ingredients reaches the environment.

That amount is at such levels as to typically not cause any adverse effects.

REPORTABLE QUANTITY: ..... None

15 - REGULATIONS

This Safety Data Sheet conforms to ANSI Z400.5, and to the format requirements and the International Chemical Safety Cards of the Global Harmonizing System. This SDS complies with 29 CFR 1910.1200

(HAZARD COMMUNICATION STANDARD). IMPORTANT: Read this SDS before handling & disposing of this product. Pass this information on to employees, customers, & users of this product.

EPA SRA Title III Chemical Listings:

TSCA STATUS: ............................ This product is listed on the TSCA inventory. If this product is a blend, all ingredients in the product are listed on the TSCA Inventory List.

Any impurities present in this product are exempt from listing.

SECTION 302: .............................. None SECTION 304: .............................. None SECTION 312: .............................. None SARA SECTION 313: .................. None ACUTE: ......................................... Yes CHRONIC: ................................... No FIRE: ............................................. Yes PRESSURE: .................................. No REACTIVE: .................................. No CLEAN WATER ACT: ............... None

IMDG – International Marine Dangerous Goods Code Class Non Regulated - Possible Shipping Description(s): Non Regulated

IATA

Class Non Regulated - Possible Shipping Description(s): Non Regulated

DEA Chemical Trafficking Act: .. No

16 – OTHER INFORMATION

ND = No Data, NA = Not Applicable/Not Available, ≤ = Less than or equal to, ≥ = Greater than or equal to

REVISION STATEMENT: Changes have been made throughout this Safety Data Sheet (SDS). Please read the entire document. Prepared according to the OSHA Hazard Communication Standard (29 CFR 1910.1200) and The Globally Harmonized System of Classification and Labeling of Chemicals (GHS) by the Company Health and Risk Assessment Unit.

DISCLAIMER:

Although the information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed to be correct as of the date hereof, the Company makes no representations as to the completeness or accuracy thereof. Information is supplied upon the condition that the persons receiving this Safety Data Sheet (SDS) will make their own determination as to its suitability for their intended purposes prior to use. Since the product is within the exclusive control of the user, it is the user's obligation to determine the conditions of safe use of this product. Such conditions should comply with all Federal and State Regulations concerning the Product. It must be recognized that the physical and chemical properties of any product may not be fully understood and that new, possibly hazardous products may arise from reactions between chemicals. The information given in this data sheet is based on our present knowledge and shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. NO

REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF

MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE

ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH

INFORMATION REFERS.

***This is the last page of this SDS***

HMIS*

HEALTH 1

FLAMMABILITY 1

REACTIVITY 0

PERSONAL PROTECTION C

*HMIS®HAZARD INDEX: 0=Minimal Hazard, 1=Slight Hazard, 2=Moderate Hazard, 3=Serious Hazard, 4=Severe Hazard.

HMIS® rating involves data interpretations that may vary from company to company. They are intended only for rapid, general identification of the magnitude of the specific hazard. To deal adequately with the safe handling of this material, all the information contained in this SDS and product label must be considered.