MSDS_MIL-PRF-38299.pdf

Safety Data Sheet

MIL-PRF-38299 (MIL-F-38299) Fluid

SDS Revision Date: 12/10/2014

1. Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product Identity MIL-PRF-38299 (MIL-F-38299)

Alternate Names (MIL-F-38299) MIL-PRF-38299, Fluid, Purging, For Preserving Fuel Tanks of Jet Aircraft.

1.2. Relevant identified uses of the substance or mixture and uses advised against

Intended use For Preserving Fuel Tanks of Jet Aircraft.

Application Method Project specific.

1.3. Details of the supplier of the safety data sheet

Company Name MACH-DYNAMICS

494 Main Street

Susquehanna, PA 18847

Emergency

24 hour Emergency Telephone No. 24 HR. EMERGENCY TELEPHONE NUMBER (US Transportation): +1 (570) 213-5603 ext.4 (International Transportation): +001 (570) 213-5603 ext.4

Customer Service: MACH-DYNAMICS

(570) 213-5603

2. Hazard identification of the product

2.1. Classification of the substance or mixture

Asp. Tox. 1;H304 May be fatal if swallowed and enters airways.

2.2. Label elements

Using the Toxicity Data listed in section 11 and 12 the product is labeled as follows.

Danger

H304 May be fatal if swallowed and enters airways.

[Prevention]:

No GHS prevention statements

[Response]:

P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor / physician.

P331 Do NOT induce vomiting.

[Storage]:

P405 Store locked up.

[Disposal]:

P501 Dispose of contents / container in accordance with local / national regulations.

3. Composition/information on ingredients

This product contains the following substances that present a hazard within the meaning of the relevant State and Federal Hazardous Substances regulations.

Ingredient/Chemical Designations Weight % GHS Classification Notes

Petroleum distillates, hydrotreated light CAS Number: 64742-47-8

100 Asp. Tox. 1;H304 [1]

[1] Substance classified with a health or environmental hazard.

[2] Substance with a workplace exposure limit.

[3] PBT-substance or vPvB-substance.

*The full texts of the phrases are shown in Section 16.

4. First aid measures

4.1. Description of first aid measures

General In all cases of doubt, or when symptoms persist, seek medical attention.

Never give anything by mouth to an unconscious person.

Inhalation Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give artificial respiration. If unconscious place in the recovery position and obtain immediate medical attention. Give nothing by mouth. If breathing is difficult, give oxygen. High vapor concentrations can cause headaches, stupor, irritation of throat and eyes. Aspirations into lungs can cause pneumonia or death.

Eyes Irrigate copiously with clean water for at least 15 minutes, holding the eyelids apart and seek medical attention.

Skin Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognized skin cleanser.

Ingestion If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. Have patient lie down & keep warm. Vomiting may lead to pneumonitis, which may be fatal.

4.2. Most important symptoms and effects, both acute and delayed

Overview Exposure to solvent vapor concentrations from the component solvents in excess of the stated occupational exposure limits may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness.

Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible damage. See section 2 for further details.

Inhalation May be fatal if swallowed and enters airways.

5. Fire-fighting measures

5.1. Extinguishing media

Recommended extinguishing media; alcohol resistant foam, CO2, powder, water spray.

Do not use; water jet.

5.2. Special hazards arising from the substance or mixture

Hazardous decomposition: High temperatures and fires may produce such toxic substances as carbon monoxide and carbon dioxide.

5.3. Advice for fire-fighters

SPECIAL FIRE FIGHTING PROCEDURES: Water spray may be ineffective on fire but can protect fire-fighters & cool closed containers. Use fog nozzles if water is used. Do not enter confined fire-space without full bunker gear. (Helmet with face shield, bunker coats, gloves and rubber boots). Use NIOSH approved positive-pressure self-contained breathing apparatus.

UNUSUAL EXPLOSION AND FIRE PROCEDURES SLIGHTLY COMBUSTIBLE! Keep container tightly closed.

Isolate from oxidizers, heat, & open flame. Closed containers may explode if exposed to extreme heat. Applying to hot surfaces requires special precautions. Continue all label precautions!

Cool closed containers exposed to fire by spraying them with water. Do not allow run off water and contaminants from fire fighting to enter drains or water ways.

ERG Guide No. ----

6. Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Put on appropriate personal protective equipment (see section 8).

6.2. Environmental precautions

Do not allow spills to enter drains or waterways.

Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse.

6.3. Methods and material for containment and cleaning up

GENERAL PROCEDURES:

SPILL or LEAK PROCEDURES: Secure area and remove all sources of ignition and heat. Prevent additional discharge of material. Absorb small spills with sand, filter-aid, vermiculite or other inert absorbent material. For large spills, prevent material from entering sewers and or water courses. Contain spill with sand, or earth dikes. Recover as much as possible by pumping. Treat remainder as small spill. Dispose of waste in accordance with applicable government regulations. Wear chemical goggles, gloves, boots, and protective clothing. Wear respirator if necessary.

ENVIRONMENTAL PRECAUTIONS:

WATER SPILL: Keep material out of storm sewers and ditches which lead to waterways.

LAND SPILL: Contact applicable authorities and determine applicable regulations based on SDS information.

AIR RELEASE: Contact applicable authorities and determine applicable regulations based on SDS information.

7. Handling and storage

7.1. Precautions for safe handling

HANDLING: Isolate from oxidizers, heat, & open flame. Use only with adequate ventilation. Avoid breathing of vapor or spray mist. Avoid prolonged or repeated contact with skin. Wear OSHA Standard goggles or face shield. Consult Safety Equipment Supplier. Wear gloves, apron & footwear impervious to this material. Wash clothing before reuse.

Avoid free fall of liquid. Ground containers when transferring. Do not flame cut, braze, or weld. Continue all label precautions!

See section 2 for further details. - [Prevention]:

7.2. Conditions for safe storage, including any incompatibilities

Handle containers carefully to prevent damage and spillage.

Incompatible materials: Strong oxidizing agents and acids.

STORAGE TEMPERATURE: 40 - 90°F

SHELF LIFE: Recommended use within 24 months.

STORAGE: Store large amounts in structures made for OSHA Class IIIB liquids Keep container tightly closed & upright when not in use to prevent leakage.

MATERIALS: Carbon Steel is suitable COMMENTS: KEEP OUT OF REACH OF CHILDREN! Empty containers retain product residue and can be dangerous. Do not pressurize, cut weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks static electricity, or other sources of ignition.

SPECIAL PRECAUTIONS: None

See section 2 for further details. - [Storage]:

7.3. Specific end use(s)

No data available.

8. Exposure controls and personal protection

8.1. Control parameters

Exposure

CAS No. Ingredient Source Value

64742-47-8 Petroleum distillates, hydrotreated light OSHA No Established Limit

ACGIH No Established Limit

NIOSH No Established Limit

Supplier Recommended 300 ppm PEL

Carcinogen Data

CAS No. Ingredient Source Value

64742-47-8 Petroleum distillates, hydrotreated light

OSHA Select Carcinogen: No

NTP Known: No; Suspected: No

IARC Group 1: No; Group 2a: No; Group 2b: No; Group 3: No; Group 4: No;

8.2. Exposure controls

Respiratory Use NIOSH/MSHA approved respirator, following manufacturer's recommendations when concentrations exceed permissible exposure limits.

Eyes Use chemical safety goggles and/or full face shield where splashing is possible. Contact lenses should not be worn when working with this material. Maintain eye wash fountain and quick-drench facilities in work areas.

Skin Wear overalls to keep skin contact to a minimum. Wear resistant gloves (consult your safety equipment supplier). To prevent repeated or prolonged skin contact, wear impervious clothing and boots.

Engineering Controls Provide exhaust ventilation sufficient to keep the airborne concentration of this product below its exposure limits. Exhaust air may need to be cleaned by scrubbers or filters to reduce environmental contamination Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.

Other Work Practices Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse.

See section 2 for further details. - [Prevention]:

9. Physical and chemical properties

Appearance Water white Oily Liquid

Odor Mild hydrocarbon odor.

Odor threshold Not Measured pH NA

Melting point / freezing point <-59°F( -50.5C)

Initial boiling point and boiling range 242 254 276 C / 468 490 529 F

Flash Point 103 C / 218 F (PM)

Evaporation rate (Ether = 1) NA

Flammability (solid, gas) Not Applicable

Upper/lower flammability or explosive limits Lower Explosive Limit: 0.5

Upper Explosive Limit: 7.0

Vapor pressure (Pa) (mm of Hg)@20 C .03

Vapor Density 6-7

Specific Gravity (Water=1) .826

Solubility in Water Negligible

Partition coefficient n-octanol/water (Log Kow) Not Measured

Auto-ignition temperature 254 C / 490 F (Lowest Component)

Decomposition temperature NA

Viscosity (cSt) NA

VOC %

VOC'S (>0.44 Lbs/Sq In):0.0 Vol.

% / 0.0 g/L / 0.000 Lbs/Gal TOTAL VOC'S (TVOC): 0.0 Vol. %

0.0 g/L / 0.000 Lbs/Gal NONEXEMPT VOC'S (CVOC): 0.0 Vol. %

0.0 g/L / 0.000 Lbs/Gal

HAZARDOUS AIR POLLUTANTS (HAPS) 0.0 Wt. % / 0.0 g/L / 0.000 Lbs/Gal

Pounds Per Gallon 6.88

API 40.4 (Gravity @ 60 F)

9.2. Other information

No other relevant information.

10. Stability and reactivity

10.1. Reactivity

Hazardous Polymerization will not occur.

10.2. Chemical stability

Stable under normal circumstances.

10.3. Possibility of hazardous reactions

No data available.

10.4. Conditions to avoid

Excessive heat and open flame.

10.5. Incompatible materials

Strong oxidizing agents and acids.

10.6. Hazardous decomposition products

High temperatures and fires may produce such toxic substances as carbon monoxide and carbon dioxide.

11. Toxicological information

Acute toxicity

Exposure to solvent vapor concentrations from the component solvents in excess of the stated occupational exposure limits may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness.

Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin.

Splashes of liquid in the eyes may cause irritation and soreness with possible reversible damage.

Ingredient Oral LD50, mg/kg

Skin LD50, mg/kg

Inhalation Vapor LD50, mg/L/4hr

Inhalation Dust/Mist LD50, mg/L/4hr

Inhalation Gas LD50, ppm

Petroleum distillates, hydrotreated light - (64742-47-8) 5,000.00, Rat - Category: 5

>2,000.00, Rabbit -

Category: 5

No data available

No data available

No data available

Note: When no route specific LD50 data is available for an acute toxin, the converted acute toxicity point estimate was used in the calculation of the product's ATE (Acute Toxicity Estimate).

Classification Category Hazard Description

Acute toxicity (oral) --- Not Applicable

Acute toxicity (dermal) --- Not Applicable

Acute toxicity (inhalation) --- Not Applicable

Skin corrosion/irritation --- Not Applicable

Serious eye damage/irritation --- Not Applicable

Respiratory sensitization --- Not Applicable

Skin sensitization --- Not Applicable

Germ cell mutagenicity --- Not Applicable

Carcinogenicity --- Not Applicable

Reproductive toxicity --- Not Applicable

STOT-single exposure --- Not Applicable

STOT-repeated exposure --- Not Applicable

Aspiration hazard 1 May be fatal if swallowed and enters airways.

12. Ecological information

12.1. Toxicity

No additional information provided for this product. See Section 3 for chemical specific data.

Aquatic Ecotoxicity

Ingredient 96 hr LC50 fish, mg/l 48 hr EC50 crustacea, mg/l ErC50 algae, mg/l

Petroleum distillates, hydrotreated light - (64742-47-8) Not Available Not Available Not Available

12.2. Persistence and degradability

There is no data available on the preparation itself.

12.3. Bioaccumulative potential

Not Measured

12.4. Mobility in soil

No data available.

12.5. Results of PBT and vPvB assessment

This product contains no PBT/vPvB chemicals.

12.6. Other adverse effects

No data available.

13. Disposal considerations

13.1. Waste treatment methods

Observe all federal, state and local regulations when disposing of this substance.

14. Transport information

DOT (Domestic Surface Transportation)

IMO / IMDG (Ocean Transportation)

ICAO/IATA

14.1. UN number Not Applicable Not Regulated Not Regulated

14.2. UN proper shipping

name

Not Regulated Not Regulated Not Regulated

14.3. Transport hazard

class(es)

DOT Hazard Class: Not Applicable DOT Label: ---

IMDG: Not Applicable Sub Class: Not Applicable

Air Class: Not Applicable

14.4. Packing group Not Applicable Not Applicable Not Applicable

14.5. Environmental hazards

IMDG Marine Pollutant: No

14.6. Special precautions for user

No further information

15. Regulatory information

Regulatory Overview The regulatory data in Section 15 is not intended to be all-inclusive, only selected regulations are represented.

Toxic Substance Control Act ( TSCA)

All components of this material are either listed or exempt from listing on the TSCA Inventory.

WHMIS Classification Not Regulated

US EPA Tier II Hazards Fire: No

Sudden Release of Pressure: No

Reactive: No

Immediate (Acute): Yes

Delayed (Chronic): No

EPCRA 311/312 Chemicals and RQs: (No Product Ingredients Listed)

EPCRA 302 Extremely Hazardous : (No Product Ingredients Listed)

EPCRA 313 Toxic Chemicals: (No Product Ingredients Listed)

Proposition 65 - Carcinogens (>0.0%):

(No Product Ingredients Listed)

Proposition 65 - Developmental Toxins (>0.0%):

(No Product Ingredients Listed)

Proposition 65 - Female Repro Toxins (>0.0%):

(No Product Ingredients Listed)

Proposition 65 - Male Repro Toxins (>0.0%):

(No Product Ingredients Listed)

N.J. RTK Substances (>1%) :

Penn RTK Substances (>1%) :

16. Other information

The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein.

We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our products. Customers/users of this product must comply with all applicable health and safety laws, regulations, and orders.

The full text of the phrases appearing in section 3 is:

H304 May be fatal if swallowed and enters airways.

This is the first version in the GHS SDS format. Listings of changes from previous versions in other formats are not applicable.

Disclaimer: : To the best of MACH-DYNAMICS knowledge, all information, recommendations, and suggestions appearing herein concerning this product are taken from sources or based upon data believed to be reliable. Although reasonable care has been taken in the preparation of this information, MACH-DYNAMICS extends no warranties or guarantees, express or implied, makes no representations and assumes no responsibility as to the accuracy, reliability or completeness of the information presented. MACH-DYNAMICS assumes no liability arising out of the use of the product by others. The conditions or methods of handling, storage, use and disposal of the product are beyond MACH-DYNAMICS control. The information provided herein may not be valid for this product if it is used in combination with any other materials or process. It is the user’s responsibility to determine the suitability of the product, review the information provided herein, assess the safety and toxicity of the product and to comply with all applicable laws and regulations. For this and other reasons, MACH-DYNAMICS does not assume responsibility and expressly disclaims liability for any loss damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product.

55-Gallon Drum UPC CODE:

End of Document