SDS Ennis 985202 Yellow.pdf

Date Printed: 5/13/2020 Product: 985202

Safety Data Sheet

Section 1. Identification

Product Code: 985202

Product Name: WB YEL FAST DRY 1952F 1/2

Product Type: WB Paint

Recommended Use: Traffic Markings

Supplied by: Ennis-Flint, Inc.

4161 Piedmont Parkway, Suite 370 Greensboro, NC 27410 T: 800.331.8118

Emergency Telephone: Chemtrec 1-800-424-9300

2. Hazards Identification

EMERGENCY OVERVIEW: This product contains a component suspected of causing cancer. However, it is in a non-respirable form and inhalation is unlikely to occur from exposure. This classification is relevant when exposed to dust or powder form only (e.g.

sanding, grinding).

GHS Classification Carc. 1B, STOT SE 1

Symbol(s) of Product

Signal Word Danger

GHS HAZARD STATEMENTS

Carcinogenicity, category 1B H350 May cause cancer.

STOT, single exposure, category 1 H370 Causes damage to organs.

GHS PRECAUTIONARY STATEMENTS

P201 Obtain special instructions before use.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P270 Do no eat, drink or smoke when using this product.

P281 Use personal protective equipment as required.

P307+P311 IF exposed: Call a POISON CENTER or doctor/physician.

P308+P313 IF exposed or concerned: Get medical advice/attention.

3. Composition/Information on Ingredients

Chemical Name CAS-No. Wt. % GHS Symbols GHS Statements Calcium Carbonate 1317-65-3 50-75 No Information No Information Methanol 67-56-1 1.0-2.5 GHS02-GHS08 H225-370 Titanium Dioxide 13463-67-7 1.0-2.5 No Information No Information Crystalline Silica, Quartz 14808-60-7 0.1-1.0 GHS08 H351 Paraffinic Oil 64742-65-0 0.1-1.0 GHS08 H350 Ammonium hydroxide 1336-21-6 0.1-1.0 GHS05-GHS07 H302-314-335 Magnesium silicate (talc) 14807-96-6 0.1-1.0 No Information No Information Petroleum distillates,solvent dewaxed lightparaffinic 64742-56-9 <0.1 GHS08 H350

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4. First-aid Measures

FIRST AID - GENERAL ADVICE: No hazards which require special first aid measures.

FIRST AID - INHALATION: Move to fresh air. Consult a physician if symptoms persist.

FIRST AID - INGESTION: Do NOT induce vomiting. If conscious, rinse mouth and drink plenty of water. Never give anything by mouth to an unconscious person. Consult a physician.

FIRST AID - SKIN CONTACT: Wash affected area immediately with soap and plenty of water. Remove contaminated clothing and launder before reuse. Consult a physician if symptoms persist.

FIRST AID - EYE CONTACT: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Consult a physician if symptoms persist.

MOST IMPORTANT SYMPTOMS AND EFFECTS: None under normal processing.

NOTES TO PHYSICIAN: Show this safety data sheet to the doctor in attendance.

5. Fire-fighting Measures

UNUSUAL FIRE AND EXPLOSION HAZARDS: None expected.

SPECIAL FIREFIGHTING PROCEDURES: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

EXTINGUISHING MEDIA: Alcohol Foam, Carbon Dioxide, Dry Chemical, Foam, Water Fog

6. Accidental Release Measures

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Use personal protective equipment. Ensure adequate ventilation. Dike far ahead of liquid spill for later disposal.

METHODS AND MATERIALS FOR CONTAINMENT AND CLEANUP: Soak up with inert absorbent material. Take up mechanically.

Keep in suitable and closed containers for disposal.

ENVIRONMENTAL PRECAUTIONS: Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water.

EMERGENCY ADVICE: Under normal usage or contained spills, this material should not pose a significant emergency risk.

PERSONAL PRECAUTIONS: Ensure sufficient ventilation. Use personal protective equipment. Use NIOSH approved respiratory protection if exposed to vapors, dust, mist or aerosols above the occupational exposure limits.

7. Handling and Storage

HANDLING: Ensure adequate ventilation. Avoid breathing vapor, mists or dust. Avoid contact with eyes, skin, and clothing. Wear appropriate personal protective equipment. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Observe good industrial hygiene practices.

STORAGE: Keep container tightly closed in a dry and well-ventilated place. Keep in properly labeled containers. MINIMUM RECOMMENDED STORAGE TEMPERATURE IS 34 F (1 C). MAXIMUM RECOMMENDED STORAGE TEMPERATURE IS 120 F (49 C).

8. Exposure Controls/Personal Protection

Ingredients with Occupational Exposure Limits Chemical Name ACGIH TLV-TWA ACGIH-TLV STEL OSHA PEL-TWA OSHA PEL-CEILING

Calcium Carbonate N.E. N.E. 15 mg/m3 N.E.

Methanol 200 ppm 250 ppm 200 PPM N.E.

Titanium Dioxide 10 mg/m3 N.E. 15 mg/m3 N.E.

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Crystalline Silica, Quartz 0.025 mg/m3 N.E. 0.05 mg/m3 N.E.

Paraffinic Oil N.E. N.E. N.E. N.E.

Ammonium hydroxide 25 ppm 35 ppm N.E. N.E.

Magnesium silicate (talc) 2 mg/m3 N.E. 2 mg/m3 N.E.

Petroleum distillates,solvent dewaxed lightparaffinic

N.E. N.E. N.E. N.E.

Further Advice: MEL = Maximum Exposure Limit OES = Occupational Exposure Standard SUP = Supplier's Recommendation Sk = Skin Sensitizer N.E. = Not Established

Personal Protection

RESPIRATORY PROTECTION: If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.

SKIN PROTECTION: Wear waterproof protective gloves.

EYE PROTECTION: Safety glasses with side-shields.

OTHER PROTECTIVE EQUIPMENT: Eyewash stations, safety showers, ventilation systems.

HYGIENIC PRACTICES: When using, do not eat, drink or smoke. Provide regular cleaning of equipment, work area and clothing. Wash hands before breaks and immediately after handling the product. Handle in accordance with good industrial hygiene and safety practice.

ENGINEERING CONTROLS: Use in a well ventilated area.

9. Physical and Chemical Properties

Physical State:Appearance: Yellow Liquid Liquid Odor Threshold:Odor: Slight, Ammonia Not Established pH:Density, g/cm3: 1.666 >9.6 Viscosity:Freeze Point, °C: No Information 85 Partition Coefficient, n-octanol/ water:

Solubility in Water: Insoluble No Information Decomposition temperature, °C No Information

Explosive Limits, %:Not Determined Not DeterminedBoiling Range, °C:

Flash Point, °C:Combustibility: Does not Support Combustion >94 Auto-Ignition Temperature, °CEvaporation Rate: Slower than Diethyl Ether No Information Vapor Pressure, mmHg:Vapor Density: Heavier than air No Information

(See "Other information" Section for abbreviation legend)

10. Stability and Reactivity

REACTIVITY: Stable under normal conditions.

STABILITY: Stable under recommended storage conditions.

CONDITIONS TO AVOID: Excessive heat. Do not freeze.

INCOMPATIBILITY: None known based on information supplied.

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HAZARDOUS DECOMPOSITION PRODUCTS: Carbon oxides. Nitrogen oxides.

11. Toxicological Information

Practical Experiences

MOST IMPORTANT SYMPTOMS AND EFFECTS: None under normal processing.

EFFECT OF OVEREXPOSURE - INHALATION: Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes). May cause central nervous system depression with nausea, headache, dizziness, vomiting, and incoordination.

Sanding and grinding dust may be harmful if inhaled.

EFFECT OF OVEREXPOSURE - INGESTION: Ingestion may cause irritation to mucous membranes. May cause gastrointestinal irritation, nausea, vomiting, and diarrhea. May cause gastrointestinal disturbances with dizziness and central nervous system depression.

EFFECT OF OVEREXPOSURE - SKIN CONTACT: Direct skin contact may cause irritation.

EFFECT OF OVEREXPOSURE - EYE CONTACT: Direct eye contact may cause irritation.

EFFECT OF OVEREXPOSURE - CHRONIC HAZARDS: This product contains titanium dioxide in a non-respirable form. Inhalation of titanium dioxide is unlikely to occur from exposure to this product. Inhalation exposure to respirable levels of crystalline silica may cause respiratory impairment and lung damage. This product contains crystalline silica (quartz) in a non-respirable form. Inhalation of crystalline silica is unlikely to occur from exposure to this product. Crystalline silica (quartz) has been classified by the International Agency for Research on Cancer (IARC) as a known human carcinogen. Inhalation, ingestion, or skin absorption of methanol can cause blindness.

CARCINOGENICITY: This product contains one or more substances which are classified by IARC as carcinogenic to humans (Group I), probably carcinogenic to humans (Group 2A) or possibly carcinogenic to humans (Group 2B).

PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Inhalation, Skin Absorption, Skin Contact

Acute Toxicity Values The acute effects of this product have not been tested. Data on individual components are tabulated below

CAS-No. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 1317-65-3 Calcium Carbonate > 2000 mg/kg > 2000 mg/kg >20001 ppm (Gas/Mist) 67-56-1 Methanol 6200 mg/kg Rat 15840 mg/kg Rabbit 22500 ppm Rat (Gas/Mist) 13463-67-7 Titanium Dioxide >10000 mg/kg Rat N.I. >20001 ppm (Gas/Mist) 14808-60-7 Crystalline Silica, Quartz >2000 mg/kg > 2000 mg/kg >20001 ppm (Gas/Mist) 64742-65-0 Paraffinic Oil >15000 mg/kg Rat > 2000 mg/kg >20001 ppm (Gas/Mist) 1336-21-6 Ammonium hydroxide 350 mg/kg Rat > 2000 mg/kg >20001 ppm (Gas/Mist) 14807-96-6 Magnesium silicate (talc) >2000 mg/kg > 2000 mg/kg >20001 ppm (Gas/Mist) 64742-56-9 Petroleum distillates,solvent dewaxed lightparaffinic >5000 mg/kg Rat >5000 mg/kg Rabbit N.I.

N.I. = No Information

12. Ecological Information

ECOLOGICAL INFORMATION: The environmental impact of this product has not been fully investigated.

PRESISTENCE AND DEGRADABILITY: No Information

BIOACCUMULATIVE POTENTIAL: No Information

MOBILITY: No Information

OTHER ADVERSE ECOLOGICAL EFFECTS: No Information

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13. Disposal Information

Product

DISPOSAL METHOD: This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). Dispose of contents/ container in accordance with the local/regional/national/international regulations. Do not re-use empty containers.

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Use personal protective equipment. Ensure adequate ventilation. Dike far ahead of liquid spill for later disposal.

CONTAMINATED PACKAGING: Dispose of contents/ container in accordance with the local/regional/national/international regulations.

14. Transport Information SPECIAL TRANSPORT PRECAUTIONS: None.

Road Transport

UN Number: Not Regulated

Shipping Name: Not Regulated

Transport Hazard Class: Not Regulated

Packing Group: Not Applicable

ERG No: Not Regulated

Sea Transport

UN Number: Not Regulated

Shipping Name: Not Regulated

IMDG Class: Not Regulated

Packing Group: Not Applicable

EmS-No: Not Regulated

Marine Pollutant: Not A Marine Pollutant

Air Transport

UN Number: Not Regulated

Shipping Name: Not Regulated

IATA Class: Not Regulated

Packing Group: Not Applicable

15. Regulatory Information

U.S. Federal Regulations:

CERCLA - SARA Hazard Category

This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories:

Carcinogenicity, Specific target organ toxicity (single or repeated exposure)

SARA SECTION 313:

This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:

Chemical Name CAS-No.

Methanol 67-56-1 Page 5 / 7

Ethoxylated Nonylphenol, Branched 68412-54-4

TOXIC SUBSTANCES CONTROL ACT:

This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States:

No TSCA components exist in this product.

U.S. State Regulations:

NEW JERSEY RIGHT-TO-KNOW:

The following materials are hazardous or among the top five components in this product.

Chemical Name CAS-No.

Calcium Carbonate 1317-65-3 Water 7732-18-5 Acrylic polymer 9003-01-4 Methanol 67-56-1 Titanium Dioxide 13463-67-7 Crystalline Silica, Quartz 14808-60-7 Paraffinic Oil 64742-65-0 Ammonium hydroxide 1336-21-6 Magnesium silicate (talc) 14807-96-6 Petroleum distillates,solvent dewaxed lightparaffinic 64742-56-9

PENNSYLVANIA RIGHT-TO-KNOW

The following non-hazardous ingredients are present in the product at greater than 3%.

Chemical Name CAS-No.

Calcium Carbonate 1317-65-3 Water 7732-18-5 Acrylic polymer 9003-01-4 Methanol 67-56-1 Titanium Dioxide 13463-67-7 Crystalline Silica, Quartz 14808-60-7 Paraffinic Oil 64742-65-0 Ammonium hydroxide 1336-21-6 Magnesium silicate (talc) 14807-96-6 Petroleum distillates,solvent dewaxed lightparaffinic 64742-56-9

CALIFORNIA PROPOSITION 65 CARCINOGENS

WARNING

Warning: The following ingredients present in the product are known to the state of California to cause Cancer:

Chemical Name CAS-No.

Titanium Dioxide 13463-67-7 Crystalline Silica, Quartz 14808-60-7 Magnesium silicate (talc) 14807-96-6

CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS

WARNING

Warning: The following ingredients present in the product are known to the state of California to cause birth defects, or other reproductive hazards.

Chemical Name CAS-No.

Methanol 67-56-1

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International Regulations: As follows -

CANADIAN WHMIS:

This SDS has been prepared in compliance with Controlled Product Regulations.

16. Other Information

Revision Date: 5/13/2020 Supersedes Date: 5/5/2020

Datasheet produced by: Regulatory Department

HMIS Ratings:

Health: 3 Flammability: 1 Reactivity: 0 Personal Protection: X

NFPA Ratings:

Health: 1 Flammability: 1 Reactivity: 0 Hazards: N.I.

Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined

The information on this sheet corresponds to our present knowledge. It is not a specification and it does not guarantee specific properties. The information is intended to provide general guidance as to health and safety based upon our knowledge of the handling, storage, and use of the product. It is not applicable to unusual or non-standard uses of the product where instructions and recommendations are not followed. Any use of the product not in conformance with this SDS or in combination with any other product or process is the responsibility of the user.

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