Chemtreat CL5551 SDS.pdf

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Product Name: ChemTreat CL5551 Product Use: Cooling Water Treatment Supplier’s Name: ChemTreat, Inc.

Emergency Telephone Number: (800)424−9300 (Toll Free) Address (Corporate Headquarters): 5640 Cox Road

Glen Allen, VA 23060 Telephone Number for Information: (800)648−4579 Date of SDS: September 11, 2018 Revision Date: September 11, 2018 Revision Number: 18091101AN

Signal Word: WARNING

GHS Classification(s): Eye damage/irritation − Category 2b Skin corrosion/irritation − Category 2 Acute Toxicity Oral − Category 4 Specific Target Organ Toxicity − Single Exposure − Category 2

Hazard Statement(s): H320 Causes eye irritation.

H315 Causes skin irritation.

H302 Harmful if swallowed.

H371 May cause damage to organs.

Precautionary Statement(s):

Prevention: P264 Wash thoroughly after handling.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P270 Do not eat, drink, or smoke when using this product.

P260 Do not breathe dust/fume/gas/mist/vapors/spray.

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Response: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P337 + P313 If eye irritation persists, get medical advice/attention.

P302 + P352 IF ON SKIN: Wash with plenty of soap and water.

P332 + P313 If skin irritation develops or persists, get medical advice/attention.

P362 + P364 Take off contaminated clothing and wash it before reuse.

P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth.

P308 + P311 IF exposed or concerned: Call a POISON CENTER/doctor.

Storage: P405 Store locked up.

Disposal: P501 Dispose of contents and container in accordance with applicable local, regional, national, and/or international regulations.

System of Classification Used: Classification under 2012 OSHA Hazard Communication Standard

(29 CFR 1910.1200).

Hazards Not Otherwise None.

Classified:

Component CAS Registry # Wt.% 2−Phosphono−1,2,4−butane tricarboxylic acid 37971−36−1 1 − 5 Benzotriazole, sodium salt 15217−42−2 1 − 5 1−Hydroxyethylidene−1,1−diphosphonic acid 2809−21−4 1 − 5

Comments If chemical identity and/or exact percentage of composition has been withheld, this information is considered to be a trade secret.

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Inhalation: Call a POISON CENTER or doctor/physician if you feel unwell.

Eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists, get medical advice/attention.

Skin: Wash with plenty of soap and water. Take off contaminated clothing and wash before re−use. If skin irritation occurs, seek medical advice/attention.

Ingestion: DO NOT INDUCE VOMITING. Rinse mouth. Call a POISON CENTER or doctor/physician.

Most Important Symptoms: N/D

Indication of Immediate N/A Medical Attention and Special Treatment Needed, If Necessary:

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Flammability of the Product: Not flammable.

Suitable Extinguishing Media: Use extinguishing media suitable to surrounding fire.

Specific Hazards Arising from None known.

the Chemical:

Protective Equipment: If product is involved in a fire, wear full protective clothing including a positive−pressure, NIOSH approved, self−contained breathing apparatus.

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Personal Precautions: Use appropriate Personal Protective Equipment (PPE).

Environmental Precautions: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains, and sewers.

Methods for Cleaning up: Contain and recover liquid when possible. Flush spill area with water spray.

Other Statements: None.

Handling: Wear appropriate Personal Protective Equipment (PPE) when handling this product. Do not get in eyes, or on skin and clothing.

Wash thoroughly after handling. Do not ingest. Avoid breathing vapors, mist or dust.

Storage: Store away from incompatible materials (see Section 10). Store at ambient temperatures. Keep container securely closed when not in use. Label precautions also apply to empty container. Recondition or dispose of empty containers in accordance with government regulations. For Industrial use only.

Store above Freeze Point.

Exposure Limits

Component Source Exposure Limits 2−Phosphono−1,2,4−butane tricarboxylic acid N/E N/E Benzotriazole, sodium salt N/E N/E 1−Hydroxyethylidene−1,1−diphosphonic acid N/E N/E

Engineering Controls: Use only with adequate ventilation. The use of local ventilation is recommended to control emission near the source.

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Personal Protection

Eyes: Wear chemical splash goggles or safety glasses with full−face shield. Maintain eyewash fountain in work area.

Skin: Maintain quick−drench facilities in work area.

Wear butyl rubber or neoprene gloves. Wash them after each use and replace as necessary. If conditions warrant, wear protective clothing such as boots, aprons, and coveralls to prevent skin contact.

Respiratory: If misting occurs, use NIOSH approved organic vapor/acid gas dual cartridge respirator with a dust/mist prefilter in accordance with 29 CFR 1910.134.

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Physical State and Appearance: Liquid, Light Straw, Clear Specific Gravity: 1.092 @ 20°C pH: 2.3 @ 20°C, 100.0% Freezing Point: 35.6°F Flash Point: N/D Odor: Mild Melting Point: N/A Initial Boiling Point and Boiling Range: N/D Solubility in Water: Complete Evaporation Rate: N/D Vapor Density: N/D Molecular Weight: N/D Viscosity: <100 CPS @ 20°C Flammability (solid, gas): N/D Flammable Limits: N/A Autoignition Temperature: N/A Density: 9.11 LB/GA Vapor Pressure: N/D

% VOC: 0

Odor Threshold N/D n−octanol Partition Coefficient N/D Decomposition Temperature N/D

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Chemical Stability: Stable at normal temperatures and pressures.

Incompatibility with Various Strong oxidizers, Strong bases.

Substances:

Hazardous Decomposition Oxides of carbon, Oxides of nitrogen, Oxides of phosphorus.

Products:

Possibility of Hazardous None known.

Reactions:

Reactivity: N/D

Conditions To Avoid: N/D

Acute Toxicity

Chemical Name Exposure Type of Effect Concentration Species 2−Phosphono−1,2,4−butane tricarboxylic acid Oral LD50 >6500 MG/KG Rat 1−Hydroxyethylidene−1,1−diphosphonic acid Oral LD50 2400 MG/KG Rat

Dermal LD50 7940 MG/KG Rabbit

Carcinogenicity Category

Component Source Code Brief Description 2−Phosphono−1,2,4−butane tricarboxylic acid N/E N/E N/E Benzotriazole, sodium salt N/E N/E N/E 1−Hydroxyethylidene−1,1−diphosphonic acid N/E N/E N/E

Likely Routes of Exposure: N/D

Symptoms

Inhalation: N/D

Eye Contact: N/D

Skin Contact: N/D

Ingestion: N/D

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Skin Corrosion/Irritation: N/D

Serious Eye Damage/Eye N/D Irritation:

Sensitization: N/D

Germ Cell Mutagenicity: N/D

Reproductive/Developmental N/D Toxicity:

Specific Target Organ Toxicity

Single Exposure: N/D

Repeated Exposure: N/D

Aspiration Hazard: N/D

Comments: None.

Ecotoxicity

Species Duration Type of Effect Test Results Daphnia pulex 48h LC50 2588 mg/l Fathead Minnow 48h LC50 3415 mg/l Sheepshead Minnow 7d NOEC 2500 mg/l

7d IC25 5236 mg/l Mysid Shrimp 7d NOEC 625 mg/l

7d IC25 683 mg/l

Persistence and N/D Biodegradability:

Bioaccumulative Potential: N/D

Mobility In Soil: N/D

Other Adverse Effects: N/D

Comments: None.

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Dispose of in accordance with local, state and federal regulations.

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Controlling Regulation

UN/NA#:

Proper Shipping Name:

Technical Name:

Hazard Class:

Packing Group:

DOT

N/A

COMPOUND, INDUSTRIAL

WATER TREATMENT, LIQUID

TDG

ICAO

Note: N/A

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Inventory Status

United States (TSCA): All ingredients listed.

Canada (DSL/NDSL): All ingredients listed.

Federal Regulations

SARA Title III Rules

Sections 311/312 Hazard Classes

Fire Hazard: No Reactive Hazard: No Release of Pressure: No Acute Health Hazard: Yes Chronic Health Hazard: No

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Other Sections

Component

Section 313 Toxic Chemical

Section 302 EHS

TPQ

CERCLA RQ

2−Phosphono−1,2,4−butane tricarboxylic acid N/A N/A N/A Benzotriazole, sodium salt N/A N/A N/A 1−Hydroxyethylidene−1,1−diphosphonic acid N/A N/A N/A

Comments: None.

State Regulations

California Proposition 65: None known.

Special Regulations

Component States 2−Phosphono−1,2,4−butane tricarboxylic acid None.

Benzotriazole, sodium salt None.

1−Hydroxyethylidene−1,1−diphosphonic acid None.

Compliance Information

NSF: N/A

Food Regulations: N/A

KOSHER: This product has not been evaluated for Kosher approval.

Halal: This product has not been evaluated for Halal approval.

FIFRA: N/A

Other: None

Comments: None.

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HMIS Hazard Rating

Health: 1 Flammability: 0 Physical Hazard: 0

PPE: X

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Notes: The PPE rating depends on circumstances of use. See Section 8 for recommended PPE.

The Hazardous Material Information System (HMIS) is a voluntary, subjective alpha−numeric symbolic system for recommending hazard risk and personal protection equipment information. It is a subjective rating system based on the evaluator’s understanding of the chemical associated risks.

The end−user must determine if the code is appropriate for their use.

Abbreviations

Abbreviation Definition < Less Than > Greater Than ACGIH American Conference of Governmental Industrial Hygienists EHS Environmental Health and Safety Dept N/A Not Applicable N/D Not Determined N/E Not Established OSHA Occupational Health and Safety Dept PEL Personal Exposure Limit STEL Short Term Exposure Limit TLV Threshold Limit Value TWA Time Weight Average UNK Unknown

Prepared by: Product Compliance Department; ProductCompliance@chemtreat.com

Revision Date: September 11, 2018

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Although the information and recommendations set forth herein (hereinafter "information") are presented in good faith and believed to be correct as of the date hereof, ChemTreat, Inc. makes no representations as to the completeness or accuracy thereof. Information is supplied upon the condition that the persons receiving same will make their own determination as to its suitability for their purposes prior to use. In no event will ChemTreat, Inc. be responsible for damages of any nature whatsoever resulting from the use or reliance upon information. No representation or warranties, either expressed or implied, of merchantability, fitness for a particular purpose, or of any other nature are made hereunder with respect to information or the product to which information refers.