Chemtreat CL2250 SDS.pdf

SAFETY DATA SHEET

1. Identification CL2250Product identifier None.Other means of identification Cooling Water Microbiocide and Paper SlimicideRecommended use None known.Recommended restrictions

Manufacturer/Importer/Supplier/Distributor information Manufacturer

ChemTreat, Inc.

Address 5640 Cox Road Company name

Website Telephone 800-648-4579

Emergency phone number 800-424-9300 E-mail

United States chemtreat.com productcompliance@chemtreat.com

Glen Allen, VA 23060

2. Hazard(s) identification Not classified.Physical hazards

Category 1BSkin corrosion/irritationHealth hazards Category 1Serious eye damage/eye irritation Category 1Sensitization, skin Category 3Hazardous to the aquatic environment, acute hazard Environmental hazards

Category 3Hazardous to the aquatic environment, long-term hazard Not classified.OSHA defined hazards

Label elements

Signal word Danger

Hazard statement Causes severe skin burns and eye damage. May cause an allergic skin reaction. Causes serious eye damage. Harmful to aquatic life. Harmful to aquatic life with long lasting effects.

Precautionary statement Prevention Do not breathe mist/vapors. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection.

Response If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse.

Storage Store locked up.

Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.

Hazard(s) not otherwise classified (HNOC)

None known.

Supplemental information None.

1 / 7 Material name: CL2250 32 Version #: 03 Revision date: 06-08-2023 Issue date: 06-18-2021

SDS US

3. Composition/information on ingredients Mixtures

CAS number %Chemical name Common name and synonyms

98.54Other components below reportable levels

55965-84-95-Chloro-2-methyl-3(2H)-isothiazolo ne with 2-methyl-3(2H)-isothiazolone

1.46

4. First-aid measures Move to fresh air. Call a physician if symptoms develop or persist.Inhalation Remove contaminated clothing immediately and wash skin with soap and water. Call a physician or poison control center immediately. Chemical burns must be treated by a physician. Wash contaminated clothing before reuse.

Skin contact

Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician or poison control center immediately.

Eye contact

Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.

Ingestion

Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result.

Most important symptoms/effects, acute and delayed

Provide general supportive measures and treat symptomatically. Chemical burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. Keep victim under observation.

Symptoms may be delayed.

Indication of immediate medical attention and special treatment needed

Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse.

General information

5. Fire-fighting measures Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing media During fire, gases hazardous to health may be formed.Specific hazards arising from the chemical Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment and precautions for firefighters Move containers from fire area if you can do so without risk.Fire fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods No unusual fire or explosion hazards noted.General fire hazards

6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist/vapors. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.

Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.

Personal precautions, protective equipment and emergency procedures

Prevent product from entering drains.

Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.

Methods and materials for containment and cleaning up

Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground.

Environmental precautions

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7. Handling and storage Do not breathe mist/vapors. Do not get in eyes, on skin, or on clothing. Avoid prolonged exposure.

Provide adequate ventilation. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices.

Precautions for safe handling

Store locked up. Store in tightly closed container. Store away from incompatible materials (see Section 10 of the SDS).

Conditions for safe storage, including any incompatibilities

8. Exposure controls/personal protection Occupational exposure limits

The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.

At this time, the other constituents have no known exposure limits.

No biological exposure limits noted for the ingredient(s).Biological limit values Good general ventilation should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product.

Appropriate engineering controls

Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles) and a face shield. Face shield is recommended.

Eye/face protection

Skin protection Wear appropriate chemical resistant gloves.Hand protection

Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.Other

In case of insufficient ventilation, wear suitable respiratory equipment.Respiratory protection Wear appropriate thermal protective clothing, when necessary.Thermal hazards

Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the workplace.

General hygiene considerations

9. Physical and chemical properties Appearance

Liquid.Physical state Liquid.Form ColorlessColor MildOdor

Odor threshold Not available.

pH ≤3 (100% @ 20C) Melting point/freezing point 35.60 °F (2.00 °C) Initial boiling point and boiling range

Not available.

Flash point Not available.

Evaporation rate Not available.

Not applicable.Flammability (solid, gas) Upper/lower flammability or explosive limits

Explosive limit - lower (%) Not available.

Explosive limit - upper (%) Not available.

Vapor pressure Not available.

Vapor density Not available.

Relative density Not available.

Solubility(ies)

Solubility (water) Not available.

Partition coefficient (n-octanol/water)

Not available.

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Auto-ignition temperature Not available.

Decomposition temperature Not available.

Viscosity 0 - 200 cps Other information

Not explosive.Explosive properties Not oxidizing.Oxidizing properties

Pounds per gallon 8.57 Specific gravity 1.02 - 1.03 @ 20C VOC 0 %w/w

10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity Material is stable under normal conditions.Chemical stability Hazardous polymerization does not occur.Possibility of hazardous reactions Contact with incompatible materials.Conditions to avoid Strong oxidizing agents.Incompatible materials No hazardous decomposition products are known.Hazardous decomposition products

11. Toxicological information Information on likely routes of exposure

Inhalation May cause irritation to the respiratory system. Prolonged inhalation may be harmful.

Skin contact Causes severe skin burns. May cause an allergic skin reaction.

Eye contact Causes serious eye damage.

Ingestion Causes digestive tract burns.

Symptoms related to the physical, chemical and toxicological characteristics

Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result.

Information on toxicological effects Acute toxicity Not known.

Causes severe skin burns and eye damage.Skin corrosion/irritation Causes serious eye damage.Serious eye damage/eye irritation Respiratory or skin sensitization

Respiratory sensitization Not a respiratory sensitizer.

May cause an allergic skin reaction.Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

Germ cell mutagenicity

Carcinogenicity Risk of cancer cannot be excluded with prolonged exposure.

IARC Monographs. Overall Evaluation of Carcinogenicity Not listed.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) Not regulated.

US. National Toxicology Program (NTP) Report on Carcinogens Not listed.

This product is not expected to cause reproductive or developmental effects.Reproductive toxicity Specific target organ toxicity -single exposure

Not classified.

Specific target organ toxicity -repeated exposure

Not classified.

Aspiration hazard Not an aspiration hazard.

Chronic effects Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects.

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12. Ecological information Harmful to aquatic life with long lasting effects.Ecotoxicity

Product Test ResultsSpecies

CL2250

Aquatic LC50Crustacea 21 mg/l, 48 hoursCeriodaphnia dubia

LC50Fish 11.9 mg/l, 96 hoursFathead minnow (Pimephales promelas)

No data is available on the degradability of any ingredients in the mixture. Persistence and degradability Bioaccumulative potential No data available.Mobility in soil

Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations Dispose of this material and its container to hazardous or special waste collection point. Incinerate the material under controlled conditions in an approved incinerator. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations.

Disposal instructions

Dispose in accordance with all applicable regulations.Local disposal regulations D002: Waste Corrosive material [pH ≤2 or =>12.5, or corrosive to steel] The waste code should be assigned in discussion between the user, the producer and the waste disposal company.

Hazardous waste code

Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see:

Disposal instructions).

Waste from residues / unused products

Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal.

Contaminated packaging

14. Transport information

DOT

UN1760UN number CORROSIVE LIQUIDS, N.O.S. (5-Chloro-2-methyl-3(2H)-isothiazolone with 2-methyl-3(2H)-isothiazolone)

UN proper shipping name

8Class Transport hazard class(es)

-Subsidiary risk 8Label(s) PGIIPacking group

No.Marine pollutant Environmental hazards

Read safety instructions, SDS and emergency procedures before handling.Special precautions for user

IATA

UN1760UN number CORROSIVE LIQUIDS, N.O.S. (5-Chloro-2-methyl-3(2H)-isothiazolone with 2-methyl-3(2H)-isothiazolone)

UN proper shipping name

8Class Transport hazard class(es)

-Subsidiary risk 8Label(s) PGIIPacking group No.Environmental hazards Read safety instructions, SDS and emergency procedures before handling.Special precautions for user

IMDG

UN1760UN number CORROSIVE LIQUIDS, N.O.S. (5-Chloro-2-methyl-3(2H)-isothiazolone with 2-methyl-3(2H)-isothiazolone)

UN proper shipping name

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8Class Transport hazard class(es)

-Subsidiary risk 8Label(s) PGIIPacking group

No.Marine pollutant Environmental hazards

Not assigned.EmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Not established.Transport in bulk according to

Annex II of MARPOL 73/78 and the IBC Code

DOT

IATA; IMDG

15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.

US federal regulations

Toxic Substances Control Act (TSCA) TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.

CERCLA Hazardous Substance List (40 CFR 302.4)

Not listed.

SARA 304 Emergency release notification

Not regulated.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)

Not regulated.

SARA 302 Extremely hazardous substance Superfund Amendments and Reauthorization Act of 1986 (SARA)

Not listed.

YesSARA 311/312 Hazardous chemical Skin corrosion or irritation Serious eye damage or eye irritation Respiratory or skin sensitization

Classified hazard categories

SARA 313 (TRI reporting) Not regulated.

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Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

Not regulated.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Not regulated.

Not regulated.Safe Drinking Water Act

(SDWA)

US state regulations

California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. For more information go to www.P65Warnings.ca.gov.

International Inventories Country(s) or region Inventory name On inventory (yes/no)*

YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s).

Compliance Information: Halal

Compliance Information: Kosher This product is certified by the Orthodox Unionas Kosher pareve Ashland, VA Eldridge, IA Nederland, TX

Compliance Information: Biocide Regulation Registered pesticide under 40 CFR 152.10, Federal Insecticide, Fungicide and Rodenticide Act (FIFRA), EPA Registration Number: 15300-24.

16. Other information, including date of preparation or last revision 06-18-2021Issue date 06-08-2023Revision date

Version # 03 Health: 3 Flammability: 0 Physical hazard: 0 Personal protection: X

HMIS® ratings

ChemTreat, Inc. cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. Although the information and recommendations set forth herein (hereinafter "information") are presented in good faith and believed to be correct as of the date hereof, ChemTreat, Inc. makes no representations as to the completeness or accuracy thereof. Information is supplied upon the condition that the persons receiving same will make their own determination as to its suitability for their purposes prior to use. In no event will ChemTreat, Inc. be responsible for damages of any nature whatsoever resulting from the use or reliance upon information. No representation or warranties, either expressed or implied, of merchantability, fitness for a particular purpose, or of any other nature are made hereunder with respect to information or the product to which information refers.

Disclaimer

This document has undergone significant changes and should be reviewed in its entirety.Revision information Prepared by: Product Compliance Department; ProductCompliance@chemtreat.comOther information

7 / 7 Material name: CL2250