Attachment 9 - SDS (23 Jan 23).pdf

3M™ High Power Brake Cleaner, 08880 06/24/20

Safety Data Sheet

Copyright,2020, 3M Company.

All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 36-1997-0 Version Number: 2.01 Issue Date: 06/24/20 Supercedes Date: 10/22/18

SECTION 1: Identification

1.1. Product identifier

3M™ High Power Brake Cleaner, 08880

Product Identification Numbers ID Number UPC ID Number UPC 60-4550-8946-0 00051135088807 60-4550-9100-3 00051135088807

7100136846, 7100150166

1.2. Recommended use and restrictions on use

Recommended use Automotive, Brake Cleaner

1.3. Supplier’s details

MANUFACTURER: 3M

DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number

1-800-364-3577 or (651) 737-6501 (24 hours)

SECTION 2: Hazard identification

The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200.

This information may be different from the actual product label information for labels regulated by other agencies.

2.1. Hazard classification

Flammable Aerosol: Category 1.

Gas Under Pressure: Liquefied gas.

Acute Toxicity (oral): Category 4.

Serious Eye Damage/Irritation: Category 2B.

Skin Corrosion/Irritation: Category 2.

Aspiration Hazard: Category 1.

Reproductive Toxicity: Category 1B.

Carcinogenicity: Category 1A.

Germ Cell Mutagenicity: Category 1B.

ATTACHMENT #9

Safety Data Sheets as of 23 Jan 23

DRAFT

Specific Target Organ Toxicity (single exposure): Category 1.

Specific Target Organ Toxicity (single exposure): Category 3.

Specific Target Organ Toxicity (repeated exposure): Category 1.

2.2. Label elements

Signal word Danger

Symbols Flame | Gas cylinder | Exclamation mark | Health Hazard |

Pictograms

Hazard Statements Extremely flammable aerosol.

Contains gas under pressure; may explode if heated.

Harmful if swallowed.

Causes eye irritation.

Causes skin irritation.

May be fatal if swallowed and enters airways.

May cause drowsiness or dizziness.

May damage fertility or the unborn child.

May cause cancer.

May cause genetic defects.

Causes damage to organs:

sensory organs |

Causes damage to organs through prolonged or repeated exposure:

nervous system |

May cause damage to organs through prolonged or repeated exposure:

sensory organs |

Precautionary Statements General:

Keep out of reach of children.

Prevention:

Obtain special instructions before use.

Do not handle until all safety precautions have been read and understood.

Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

Do not spray on an open flame or other ignition source.

Pressurized container: Do not pierce or burn, even after use.

Do not breathe dust/fume/gas/mist/vapors/spray.

Use only outdoors or in a well-ventilated area.

Wear protective gloves.

Do not eat, drink or smoke when using this product.

Wash thoroughly after handling.

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Safety Data Sheets

Response:

IF INHALED: Remove person to fresh air and keep comfortable for breathing.

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.

Continue rinsing.

If eye irritation persists: Get medical advice/attention.

IF ON SKIN: Wash with plenty of soap and water.

If skin irritation occurs: Get medical advice/attention.

Take off contaminated clothing and wash it before reuse.

Rinse mouth.

Do NOT induce vomiting.

IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

IF exposed or concerned: Get medical advice/attention.

Specific treatment (see Notes to Physician on this label).

Storage:

Protect from sunlight. Do not expose to temperatures exceeding 50C/122F.

Store in a well-ventilated place. Keep container tightly closed.

Store locked up.

Disposal:

Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

Notes to Physician:

This product contains methanol. If there is a reasonable suspicion of methanol poisoning, intravenous (IV) administration with either fomepizole (preferred) or ethanol (if fomepizole is unavailable) should be considered as part of the medical management.

3% of the mixture consists of ingredients of unknown acute oral toxicity.

4% of the mixture consists of ingredients of unknown acute dermal toxicity.

4% of the mixture consists of ingredients of unknown acute inhalation toxicity.

SECTION 3: Composition/information on ingredients

Ingredient C.A.S. No. % by Wt Heptane, branched, cyclic and linear 426260-76-6 50 - 60 Trade Secret * Xylene 1330-20-7 15 - 30 Trade Secret * Ethylbenzene 100-41-4 1 - 11 Trade Secret * Methyl Alcohol 67-56-1 5 - 10 Trade Secret * Carbon Dioxide 124-38-9 1 - 5 Trade Secret * Dimethylcyclopentane 2532-58-3 0.5 - 1.5 Trade Secret * Benzene 71-43-2 < 0.5 Trade Secret * Cumene 98-82-8 < 0.5 Trade Secret * Toluene 108-88-3 < 0.5 Trade Secret * Naphthalene 91-20-3 < 0.05 Trade Secret *

*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation:

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Safety Data Sheets

Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:

Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention.

Eye Contact:

Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing. Immediately get medical attention.

If Swallowed:

Do not induce vomiting. Get immediate medical attention.

4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment required This product contains methanol. If there is a reasonable suspicion of methanol poisoning, intravenous (IV) administration with either fomepizole (preferred) or ethanol (if fomepizole is unavailable) should be considered as part of the medical management.

SECTION 5: Fire-fighting measures

5.1. Suitable extinguishing media

Use a fire fighting agent suitable for the surrounding fire.

5.2. Special hazards arising from the substance or mixture

Closed containers exposed to heat from fire may build pressure and explode.

Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Toxic Vapor, Gas, Particulate During Combustion

5.3. Special protective actions for fire-fighters

Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools.

Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions

For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water.

6.3. Methods and material for containment and cleaning up

If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Contain spill. Cover spill area with a fire-extinguishing foam. Working from around the edges of the spill

ATTACHMENT #9

Safety Data Sheets inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required.

7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component.

Ingredient C.A.S. No. Agency Limit type Additional Comments Ethylbenzene 100-41-4 ACGIH TWA:20 ppm A3: Confirmed animal carcin.

Ethylbenzene 100-41-4 OSHA TWA:435 mg/m3(100 ppm) Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human carcin Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm Carbon Dioxide 124-38-9 ACGIH TWA:5000 ppm;STEL:30000 ppm Carbon Dioxide 124-38-9 OSHA TWA:9000 mg/m3(5000 ppm) Xylene 1330-20-7 ACGIH TWA:100 ppm;STEL:150 ppm A4: Not class. as human carcin Xylene 1330-20-7 OSHA TWA:435 mg/m3(100 ppm) Methyl Alcohol 67-56-1 ACGIH TWA:200 ppm;STEL:250 ppm Danger of cutaneous absorption Methyl Alcohol 67-56-1 OSHA TWA:260 mg/m3(200 ppm) Benzene 71-43-2 ACGIH TWA:0.5 ppm;STEL:2.5 ppm A1: Confirmed human carcin., Danger of cutaneous absorption

Benzene 71-43-2 OSHA TWA:1 ppm;TWA:10 ppm;STEL:5 ppm;CEIL:25 ppm

29 CFR 1910.1028

Naphthalene 91-20-3 ACGIH TWA:10 ppm A3: Confirmed animal carcin., Danger of cutaneous absorption

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Safety Data Sheets

Naphthalene 91-20-3 OSHA TWA:50 mg/m3(10 ppm) Cumene 98-82-8 ACGIH TWA:50 ppm Cumene 98-82-8 OSHA TWA:245 mg/m3(50 ppm) SKIN

ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controls

Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended:

Full Face Shield Indirect Vented Goggles

Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.

Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.

Gloves made from the following material(s) are recommended: Fluoroelastomer Polymer laminate

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure:

Half facepiece or full facepiece supplied-air respirator Organic vapor respirators may have short service life.

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance

Physical state Color

Liquid Colorless

Specific Physical Form: Aerosol Odor Solvent Odor threshold No Data Available pH Not Applicable

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Safety Data Sheets

Melting point No Data Available Boiling Point No Data Available Flash Point >=15 ºF [Test Method:Closed Cup] Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure 40 psi [@ 70 ºF] Vapor Density >=1.0 [Ref Std:AIR=1] Density 6.5 lb/gal Specific Gravity 0.78 [Ref Std:WATER=1] Solubility in Water Nil Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity No Data Available Hazardous Air Pollutants 39.3 % weight [Test Method:Calculated] Volatile Organic Compounds 749 g/l [Test Method:calculated SCAQMD rule 443.1] Volatile Organic Compounds 96 % weight [Test Method:calculated per CARB title 2] Percent volatile 96 % weight VOC Less H2O & Exempt Solvents 749 g/l [Test Method:calculated SCAQMD rule 443.1]

SECTION 10: Stability and reactivity

10.1. Reactivity

This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.

10.2. Chemical stability

Stable.

10.3. Possibility of hazardous reactions

Hazardous polymerization will not occur.

10.4. Conditions to avoid

Heat Sparks and/or flames

10.5. Incompatible materials

Strong acids Strong oxidizing agents

10.6. Hazardous decomposition products

Substance Condition None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be

ATTACHMENT #9

Safety Data Sheets relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:

May be harmful if inhaled.

Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.

May cause additional health effects (see below).

Skin Contact:

Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.

May cause additional health effects (see below).

Eye Contact:

Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.

Ingestion:

Harmful if swallowed. Chemical (Aspiration) Pneumonitis: Signs/symptoms may include coughing, gasping, choking, burning of the mouth, difficulty breathing, bluish colored skin (cyanosis), and may be fatal.

Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

May cause additional health effects (see below).

Additional Health Effects:

Single exposure may cause target organ effects:

Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears.

Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.

May cause blindness.

Prolonged or repeated exposure may cause target organ effects:

Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears.

Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate.

Reproductive/Developmental Toxicity:

Contains a chemical or chemicals which can cause birth defects or other reproductive harm.

Genotoxicity:

Genotoxicity and Mutagenicity: May interact with genetic material and possibly alter gene expression.

Carcinogenicity:

Contains a chemical or chemicals which can cause cancer.

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Safety Data Sheets

Ingredient CAS No. Class Description Regulation Benzene 71-43-2 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Benzene 71-43-2 Known human carcinogen National Toxicology Program Carcinogens Benzene 71-43-2 Cancer hazard OSHA Carcinogens Cumene 98-82-8 Grp. 2B: Possible human carc. International Agency for Research on Cancer Cumene 98-82-8 Anticipated human carcinogen National Toxicology Program Carcinogens Ethylbenzene 100-41-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Naphthalene 91-20-3 Grp. 2B: Possible human carc. International Agency for Research on Cancer Naphthalene 91-20-3 Anticipated human carcinogen National Toxicology Program Carcinogens

Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification.

Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Inhalation-

Vapor(4 hr) No data available; calculated ATE20 - 50 mg/l

Overall product Ingestion No data available; calculated ATE300 - 2,000 mg/kg Heptane, branched, cyclic and linear Dermal Rabbit LD50 > 2,920 mg/kg Heptane, branched, cyclic and linear Inhalation-

Vapor (4 hours)

Rat LC50 > 23.3 mg/l

Heptane, branched, cyclic and linear Ingestion Rat LD50 > 5,840 mg/kg Xylene Dermal Rabbit LD50 > 4,200 mg/kg Xylene Inhalation-

Vapor (4 hours)

Rat LC50 29 mg/l

Xylene Ingestion Rat LD50 3,523 mg/kg Methyl Alcohol Dermal LD50 estimated to be 1,000 - 2,000 mg/kg Methyl Alcohol Inhalation-

Vapor LC50 estimated to be 10 - 20 mg/l

Methyl Alcohol Ingestion LD50 estimated to be 50 - 300 mg/kg Ethylbenzene Dermal Rabbit LD50 15,433 mg/kg Ethylbenzene Inhalation-

Vapor (4 hours)

Rat LC50 17.4 mg/l

Ethylbenzene Ingestion Rat LD50 4,769 mg/kg Carbon Dioxide Inhalation-

Gas (4 hours)

Rat LC50 > 53,000 ppm

Dimethylcyclopentane Ingestion LD50 estimated to be 300 - 2,000 mg/kg Toluene Dermal Rat LD50 12,000 mg/kg Toluene Inhalation-

Vapor (4 hours)

Rat LC50 30 mg/l

Toluene Ingestion Rat LD50 5,550 mg/kg Cumene Dermal Rabbit LD50 > 3,160 mg/kg Cumene Inhalation-

Vapor (4 hours)

Rat LC50 39.4 mg/l

Cumene Ingestion Rat LD50 1,400 mg/kg Naphthalene Dermal Human LD50 estimated to be 2,000 - 5,000 mg/kg Naphthalene Inhalation-

Vapor Human LC50 estimated to be 20 - 50 mg/l

Naphthalene Ingestion Human LD50 estimated to be 300 - 2,000 mg/kg ATE = acute toxicity estimate

Skin Corrosion/Irritation Name Species Value

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Safety Data Sheets

Heptane, branched, cyclic and linear Rabbit Irritant Xylene Rabbit Mild irritant Methyl Alcohol Rabbit Mild irritant Ethylbenzene Rabbit Mild irritant Toluene Rabbit Irritant Cumene Rabbit Minimal irritation Naphthalene Rabbit Minimal irritation

Serious Eye Damage/Irritation Name Species Value

Heptane, branched, cyclic and linear Rabbit Mild irritant Xylene Rabbit Mild irritant Methyl Alcohol Rabbit Moderate irritant Ethylbenzene Rabbit Moderate irritant Toluene Rabbit Moderate irritant Cumene Rabbit Mild irritant Naphthalene Rabbit No significant irritation

Skin Sensitization Name Species Value Heptane, branched, cyclic and linear Guinea pig Not classified

Methyl Alcohol Guinea pig

Not classified

Ethylbenzene Human Not classified Toluene Guinea pig Not classified

Cumene Guinea pig

Not classified

Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification.

Germ Cell Mutagenicity Name Route Value

Heptane, branched, cyclic and linear In Vitro Not mutagenic Xylene In Vitro Not mutagenic Xylene In vivo Not mutagenic Methyl Alcohol In Vitro Some positive data exist, but the data are not sufficient for classification Methyl Alcohol In vivo Some positive data exist, but the data are not sufficient for classification Ethylbenzene In vivo Not mutagenic Ethylbenzene In Vitro Some positive data exist, but the data are not sufficient for classification Toluene In Vitro Not mutagenic Toluene In vivo Not mutagenic Cumene In Vitro Not mutagenic Cumene In vivo Not mutagenic

Carcinogenicity Name Route Species Value Xylene Dermal Rat Not carcinogenic Xylene Ingestion Multiple animal species

Not carcinogenic

Xylene Inhalation Human Some positive data exist, but the data are not sufficient for classification

Methyl Alcohol Inhalation Multiple animal species

Not carcinogenic

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Safety Data Sheets

Ethylbenzene Inhalation Multiple animal species

Carcinogenic

Toluene Dermal Mouse Some positive data exist, but the data are not sufficient for classification

Toluene Ingestion Rat Some positive data exist, but the data are not sufficient for classification

Toluene Inhalation Mouse Some positive data exist, but the data are not sufficient for classification

Cumene Inhalation Multiple animal species

Carcinogenic

Naphthalene Inhalation Multiple animal species

Carcinogenic

Reproductive Toxicity

Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure

Duration Heptane, branched, cyclic and linear Not

Specified Not classified for female reproduction Rat NOAEL Not available 2 generation

Heptane, branched, cyclic and linear Not Specified

Not classified for male reproduction Rat NOAEL Not available

2 generation

Heptane, branched, cyclic and linear Not Specified

Not classified for development Rat NOAEL Not available

2 generation

Xylene Inhalation Not classified for female reproduction Human NOAEL Not available occupational exposure

Xylene Ingestion Not classified for development Mouse NOAEL Not available during organogenesi s

Xylene Inhalation Not classified for development Multiple animal species

NOAEL Not available during gestation

Methyl Alcohol Ingestion Not classified for male reproduction Rat NOAEL 1,600 mg/kg/day

21 days

Methyl Alcohol Ingestion Toxic to development Mouse LOAEL 4,000 mg/kg/day during organogenesi s

Methyl Alcohol Inhalation Toxic to development Mouse NOAEL 1.3 mg/l during organogenesi s

Ethylbenzene Inhalation Not classified for development Rat NOAEL 4.3 mg/l premating & during gestation

Carbon Dioxide Inhalation Not classified for male reproduction Mouse LOAEL 350,000 ppm not available

Carbon Dioxide Inhalation Not classified for development Rat LOAEL 60,000 ppm

24 hours

Toluene Inhalation Not classified for female reproduction Human NOAEL Not available occupational exposure

Toluene Inhalation Not classified for male reproduction Rat NOAEL 2.3 mg/l

1 generation

Toluene Ingestion Toxic to development Rat LOAEL 520 mg/kg/day during gestation

Toluene Inhalation Toxic to development Human NOAEL Not available poisoning and/or abuse

Cumene Inhalation Not classified for development Rabbit NOAEL 11.3 mg/l during organogenesi s

Lactation

Name Route Species Value

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Safety Data Sheets

Xylene Ingestion Mouse Not classified for effects on or via lactation

Target Organ(s)

Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure

Duration Heptane, branched, cyclic and linear

Inhalation central nervous system depression

May cause drowsiness or dizziness

Human and animal

NOAEL Not available

Xylene Inhalation auditory system Causes damage to organs Rat LOAEL 6.3 mg/l

8 hours

Xylene Inhalation central nervous system depression

May cause drowsiness or dizziness

Human NOAEL Not available

Xylene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification

Human NOAEL Not available

Xylene Inhalation eyes Not classified Rat NOAEL 3.5 mg/l not available

Xylene Inhalation liver Not classified Multiple animal species

NOAEL Not available

Xylene Ingestion central nervous system depression

May cause drowsiness or dizziness

Multiple animal species

NOAEL Not available

Xylene Ingestion eyes Not classified Rat NOAEL 250 mg/kg not applicable

Methyl Alcohol Inhalation blindness Causes damage to organs Human NOAEL Not available occupational exposure

Methyl Alcohol Inhalation central nervous system depression

May cause drowsiness or dizziness

Human NOAEL Not available not available

Methyl Alcohol Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification

Rat NOAEL Not available

6 hours

Methyl Alcohol Ingestion blindness Causes damage to organs Human NOAEL Not available poisoning and/or abuse

Methyl Alcohol Ingestion central nervous system depression

May cause drowsiness or dizziness

Human NOAEL Not available poisoning and/or abuse

Ethylbenzene Inhalation central nervous system depression

May cause drowsiness or dizziness

Human NOAEL Not available

Ethylbenzene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification

Human and animal

NOAEL Not available

Toluene Inhalation central nervous system depression

May cause drowsiness or dizziness

Human NOAEL Not available

Toluene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification

Human NOAEL Not available

Toluene Inhalation immune system Not classified Mouse NOAEL

0.004 mg/l

3 hours

Toluene Ingestion central nervous system depression

May cause drowsiness or dizziness

Human NOAEL Not available poisoning and/or abuse

Cumene Inhalation central nervous system depression

May cause drowsiness or dizziness

Multiple animal species

NOAEL Not available not available

Cumene Inhalation respiratory irritation May cause respiratory irritation Human LOAEL 0.2 mg/l occupational exposure

Cumene Ingestion central nervous system depression

May cause drowsiness or dizziness

Multiple animal species

NOAEL Not available not available

Naphthalene Ingestion blood Causes damage to organs Human NOAEL Not available poisoning and/or abuse

Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure

Duration

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Safety Data Sheets

Xylene Inhalation nervous system Causes damage to organs through prolonged or repeated exposure

Rat LOAEL 0.4 mg/l

4 weeks

Xylene Inhalation auditory system May cause damage to organs though prolonged or repeated exposure

Rat LOAEL 7.8 mg/l

5 days

Xylene Inhalation liver Not classified Multiple animal species

NOAEL Not available

Xylene Inhalation heart | endocrine system | gastrointestinal tract | hematopoietic system | muscles | kidney and/or bladder | respiratory system

Not classified Multiple animal species

NOAEL 3.5

mg/l

13 weeks

Xylene Ingestion auditory system Not classified Rat NOAEL 900 mg/kg/day

2 weeks

Xylene Ingestion kidney and/or bladder

Not classified Rat NOAEL 1,500 mg/kg/day

90 days

Xylene Ingestion liver Not classified Multiple animal species

NOAEL Not available

Xylene Ingestion heart | skin | endocrine system | bone, teeth, nails, and/or hair | hematopoietic system | immune system | nervous system | respiratory system

Not classified Mouse NOAEL 1,000 mg/kg/day

103 weeks

Methyl Alcohol Inhalation liver Not classified Rat NOAEL 6.55 mg/l

4 weeks

Methyl Alcohol Inhalation respiratory system Not classified Rat NOAEL 13.1 mg/l

6 weeks

Methyl Alcohol Ingestion liver | nervous system

Not classified Rat NOAEL 2,500 mg/kg/day

90 days

Ethylbenzene Inhalation kidney and/or bladder

Some positive data exist, but the data are not sufficient for classification

Rat NOAEL 1.1 mg/l

2 years

Ethylbenzene Inhalation liver Some positive data exist, but the data are not sufficient for classification

Mouse NOAEL 1.1 mg/l

103 weeks

Ethylbenzene Inhalation hematopoietic system

Not classified Rat NOAEL 3.4 mg/l

28 days

Ethylbenzene Inhalation auditory system Not classified Rat NOAEL 2.4 mg/l

5 days

Ethylbenzene Inhalation endocrine system Not classified Mouse NOAEL 3.3 mg/l

103 weeks

Ethylbenzene Inhalation gastrointestinal tract Not classified Rat NOAEL 3.3 mg/l

2 years

Ethylbenzene Inhalation bone, teeth, nails, and/or hair | muscles

Not classified Multiple animal species

NOAEL 4.2

mg/l

90 days

Ethylbenzene Inhalation heart | immune system | respiratory system

Not classified Multiple animal species

NOAEL 3.3

mg/l

2 years

Ethylbenzene Ingestion liver | kidney and/or bladder

Not classified Rat NOAEL 680 mg/kg/day

6 months

Carbon Dioxide Inhalation heart | bone, teeth, nails, and/or hair | liver | nervous system | kidney and/or bladder | respiratory system

Not classified Rat LOAEL 60,000 ppm

166 days

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Safety Data Sheets

Toluene Inhalation auditory system | eyes | olfactory system

Causes damage to organs through prolonged or repeated exposure

Human NOAEL Not available poisoning and/or abuse

Toluene Inhalation nervous system May cause damage to organs though prolonged or repeated exposure

Human NOAEL Not available poisoning and/or abuse

Toluene Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification

Rat LOAEL 2.3 mg/l

15 months

Toluene Inhalation heart | liver | kidney and/or bladder

Not classified Rat NOAEL 11.3 mg/l

15 weeks

Toluene Inhalation endocrine system Not classified Rat NOAEL 1.1 mg/l

4 weeks

Toluene Inhalation immune system Not classified Mouse NOAEL Not available

20 days

Toluene Inhalation bone, teeth, nails, and/or hair

Not classified Mouse NOAEL 1.1 mg/l

8 weeks

Toluene Inhalation hematopoietic system | vascular system

Not classified Human NOAEL Not available occupational exposure

Toluene Inhalation gastrointestinal tract Not classified Multiple animal species

NOAEL 11.3

mg/l

15 weeks

Toluene Ingestion nervous system Some positive data exist, but the data are not sufficient for classification

Rat NOAEL 625 mg/kg/day

13 weeks

Toluene Ingestion heart Not classified Rat NOAEL 2,500 mg/kg/day

13 weeks

Toluene Ingestion liver | kidney and/or bladder

Not classified Multiple animal species

NOAEL

2,500 mg/kg/day

13 weeks

Toluene Ingestion hematopoietic system

Not classified Mouse NOAEL 600 mg/kg/day

14 days

Toluene Ingestion endocrine system Not classified Mouse NOAEL 105 mg/kg/day

28 days

Toluene Ingestion immune system Not classified Mouse NOAEL 105 mg/kg/day

4 weeks

Cumene Inhalation auditory system | endocrine system | hematopoietic system | liver | nervous system | eyes

Not classified Rat NOAEL 59 mg/l

13 weeks

Cumene Inhalation kidney and/or bladder

Not classified Rat NOAEL 4.9 mg/l

13 weeks

Cumene Inhalation respiratory system Not classified Rat NOAEL 59 mg/l

13 weeks

Cumene Ingestion kidney and/or bladder | heart | endocrine system | hematopoietic system | liver | respiratory system

Not classified Rat NOAEL 769 mg/kg/day

6 months

Naphthalene Dermal blood Causes damage to organs through prolonged or repeated exposure

Human NOAEL Not available poisoning and/or abuse

Naphthalene Dermal eyes Not classified Human NOAEL Not available occupational exposure

Naphthalene Inhalation respiratory system Causes damage to organs through prolonged or repeated exposure

Rat LOAEL 0.01 mg/l

13 weeks

Naphthalene Inhalation blood Causes damage to organs through prolonged or repeated exposure

Human NOAEL Not available poisoning and/or abuse

Naphthalene Inhalation eyes Not classified Human NOAEL Not available occupational exposure

Naphthalene Ingestion blood Causes damage to organs through prolonged or repeated exposure

Human NOAEL Not available poisoning and/or abuse

Naphthalene Ingestion eyes May cause damage to organs Rabbit LOAEL 500 15 days

ATTACHMENT #9

Safety Data Sheets though prolonged or repeated exposure mg/kg/day

Aspiration Hazard Name Value Heptane, branched, cyclic and linear Aspiration hazard Xylene Aspiration hazard Ethylbenzene Aspiration hazard Toluene Aspiration hazard Cumene Aspiration hazard

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.

SECTION 12: Ecological information

Ecotoxicological information

Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components.

Chemical fate information

Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components.

SECTION 13: Disposal considerations

13.1. Disposal methods

Dispose of contents/ container in accordance with the local/regional/national/international regulations.

Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.

SECTION 14: Transport Information

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.

SECTION 15: Regulatory information

15.1. US Federal Regulations

Contact 3M for more information.

EPCRA 311/312 Hazard Classifications:

Physical Hazards Flammable (gases, aerosols, liquids, or solids) Gas under pressure

Health Hazards

Acute toxicity

ATTACHMENT #9

Safety Data Sheets

Aspiration Hazard Carcinogenicity Germ cell mutagenicity Reproductive toxicity Serious eye damage or eye irritation Skin Corrosion or Irritation Specific target organ toxicity (single or repeated exposure)

Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):

Ingredient C.A.S. No % by Wt Methyl Alcohol 67-56-1 Trade Secret 5 - 10 Xylene 1330-20-7 Trade Secret 15 - 30 Ethylbenzene 100-41-4 Trade Secret 1 - 11 Benzene 71-43-2 Trade Secret < 0.5 Cumene 98-82-8 Trade Secret < 0.5

15.2. State Regulations

Contact 3M for more information.

15.3. Chemical Inventories

The components of this material are in compliance with the provisions of Philippines RA 6969 requirements. Certain restrictions may apply. Contact the selling division for additional information.

The components of this product are in compliance with the chemical notification requirements of TSCA. All required components of this product are listed on the active portion of the TSCA Inventory.

Contact 3M for more information.

15.4. International Regulations

Contact 3M for more information.

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: Other information

NFPA Hazard Classification Health: 2 Flammability: 4 Instability: 0 Special Hazards: None

Aerosol Storage Code: 3

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

Document Group: 36-1997-0 Version Number: 2.01 Issue Date: 06/24/20 Supercedes Date: 10/22/18

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, ATTACHMENT #9

Safety Data Sheets some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M.

3M USA SDSs are available at www.3M.com

ATTACHMENT #9

Safety Data Sheets