Attachment 2 NAVSEAHazMatAvoidProcess.pdf

T9070-AL-DPC-020/077-2

NAVSEA TECHNICAL PUBLICATION

NAVSEA HAZARDOUS MATERIAL AVOIDANCE

PROCESS

DISTRIBUTION STATEMENT A: Approved for public release; distribution is unlimited.

PUBLISHED BY DIRECTION OF COMMANDER, NAVAL SEA SYSTEMS COMMAND

28 SEPTEMBER 2015

A

LIST OF EFFECTIVE PAGES

Dates of issue for original and subsequent revisions:

Original T9070-AL-DPC-020/077-2 28 September 2015

TOTAL NUMBER OF PAGES IN THIS PUBLICATION IS 48, CONSISTING OF THE FOLLOWING:

Page No.

Title and A i-viii

1-1 through 1-2

2-1 through 2-2

3-1 through 3-2

A-1 through A-17/(A-18 blank)

B-1 through B-4

C-1 through C-5/(C-6 blank)

D-1 through D-2

TMDER

i/(ii blank)

CHENG’S INTENT

iii

TABLE OF CONTENTS

Chapter/Paragraph/Title Page

CHENG’s Intent .......................................................................................................................................................................... i Foreword ................................................................................................................................................................................... vii

Chapter 1 Introduction ...................................................................................................................................................................... 1-1

1.1 Purpose ............................................................................................................................................................................... 1-1

1.2 Applicable Documents........................................................................................................................................................ 1-1

1.3 Cancellation ........................................................................................................................................................................ 1-1

1.4 Background ......................................................................................................................................................................... 1-1

1.4.1 Exceptions ................................................................................................................................................................ 1-2

1.4.2 Formalizing the Approach for HM Elimination and Minimization .......................................................................... 1-2

1.5 Scope and Applicability ...................................................................................................................................................... 1-2

1.6 Non-Applicability ............................................................................................................................................................... 1-2

Chapter 2 HM Management and Identification Process ................................................................................................................... 2-1

2.1 Introduction ........................................................................................................................................................................ 2-1

2.2 HM Management Plan ........................................................................................................................................................ 2-1

2.3 HM Categories .................................................................................................................................................................... 2-1

2.4 HM Approval and Assessment ........................................................................................................................................... 2-1

2.5 NAVSEA List of Targeted Chemicals (N-LTC) ................................................................................................................ 2-1

2.5.1 Purpose of the N-LTC .............................................................................................................................................. 2-1

2.5.2 Determination of HM Severity Categories ............................................................................................................... 2-2

2.5.3 NAVSEA 05 Involvement ........................................................................................................................................ 2-2

Chapter 3 Responsibilities ................................................................................................................................................................ 3-1

3.1 NAVSEA Lead Activity Responsibilities ........................................................................................................................... 3-1

3.2 NAVSEA 05P5 TWH for Environmental Systems and Materials Engineering Responsibilities ....................................... 3-1

3.3 NAVSEA TDM Responsibilities ........................................................................................................................................ 3-2

3.4 NAVSEA CHIEF SYSTEMS ENGINEERS (CSE) Responsibilities ................................................................................ 3-2

3.5 Point of Contact .................................................................................................................................................................. 3-2

Appendix A NAVSEA List of Targeted Chemicals (N-LTC) ......................................................................................................... A-1 A.1 Introduction....................................................................................................................................................................... A-1 A.2 NAVSEA List of Targeted Chemicals (N-LTC) Application Exception Notes. .............................................................. A-7

A.2.1 Exception: Arsenic and Arsenic Compounds. ....................................................................................................... A-7 A.2.2 Exception: Beryllium and Beryllium Compounds. ................................................................................................ A-7 A.2.3 Exception: Cadmium and Cadmium Compounds. ................................................................................................. A-8 A.2.4 Exception: Nickel Compounds .............................................................................................................................. A-8 A.2.5 Exception: Sulfuric Acid ....................................................................................................................................... A-8 A.2.6 Exception: Vinyl Chloride ..................................................................................................................................... A-8 A.2.7 Exception: Cyanide Containing Compounds (includes Nitrile and Cyano Compounds) ...................................... A-9 A.2.8 Exception: Lead and Lead Compounds ................................................................................................................. A-9 A.2.9 Exception: Lithium and Lithium Compounds. .................................................................................................... A-10 A.2.10 Exception: Mercury and Mercury Compounds. ................................................................................................. A-10 A.2.11 Exception: Nickel .............................................................................................................................................. A-11 iv

Chapter/Paragraph/Title Page

A.2.12 Exception: Phenol .............................................................................................................................................. A-12 A.2.13 Exception: Styrene ............................................................................................................................................. A-12 A.2.14 Exception: Antimony and Antimony Compounds ............................................................................................. A-13 A.2.15 Exception: Chromium and Non-Hexavalent Chromium Compounds ............................................................... A-13 A.2.16 Exception: Cobalt and Cobalt Compounds ........................................................................................................ A-14 A.2.17 Exception: Copper and Copper Compounds ...................................................................................................... A-14 A.2.18 Exception: Selenium and Selenium Compounds ............................................................................................... A-16 A.2.19 Exception: Silver and Silver Compounds .......................................................................................................... A-16

Appendix B NAVSEA 05 Hazardous Material Management Procedure ......................................................................................... B-1 B.1 Introduction. ...................................................................................................................................................................... B-1 B.2 Identification of HM. ........................................................................................................................................................ B-1 B.3 HM Applicability. ............................................................................................................................................................. B-1 B.4 Hazardous Components. ................................................................................................................................................... B-1 B.5 Chemical Identification. .................................................................................................................................................... B-1 B.6 Chemical Not Associated with Application Exception. .................................................................................................... B-2 B.7 Risk Assessment. .............................................................................................................................................................. B-2

B.7.1 Severity Categories. ................................................................................................................................................ B-2 B.7.2 Probability Level of Exposure. ............................................................................................................................... B-2 B.7.3 Quantitative Data. ................................................................................................................................................... B-2 B.7.4 Restricted Chemicals............................................................................................................................................... B-2

B.8 Risk Acceptance. ............................................................................................................................................................... B-2 B.8.1 Prohibited Chemicals. ............................................................................................................................................. B-2 B.8.2 Non-Prohibited Chemicals. ..................................................................................................................................... B-3 B.8.3 Application Exceptions. .......................................................................................................................................... B-3 B.8.4 Levels of Risk. ........................................................................................................................................................ B-3

B.9 Tracking. ........................................................................................................................................................................... B-3 Appendix C NAVSEA Hazardous Material Waiver Request Form Guidance ................................................................................ C-1

C.1 Introduction. ...................................................................................................................................................................... C-1 C.2 Administrative Information. .............................................................................................................................................. C-1

C.2.1 Requester Name* .................................................................................................................................................... C-1 C.2.2 Requester Organization* ......................................................................................................................................... C-1 C.2.3 Requester Phone Number* ...................................................................................................................................... C-1 C.2.4 Requester E-Mail* .................................................................................................................................................. C-1 C.2.5 Waiver Submission Date* ....................................................................................................................................... C-1 C.2.6 Government POC* .................................................................................................................................................. C-1 C.2.7 Government POC Phone Number* ......................................................................................................................... C-1 C.2.8 Government POC E-Mail* ...................................................................................................................................... C-1 C.2.9 Program Executive Office ....................................................................................................................................... C-1 C.2.10 Program* ............................................................................................................................................................... C-1

C.3 Product Information. ......................................................................................................................................................... C-1 C.3.1 Chemical on the N-LTC* ........................................................................................................................................ C-1 C.3.2 Percent Composition (%) ........................................................................................................................................ C-1 v

Chapter/Paragraph/Title Page

C.3.3 National Stock Number............................................................................................................................................ C-1 C.3.4 Attach SDS?* ........................................................................................................................................................... C-1 C.3.5 Product Vendor* ...................................................................................................................................................... C-1 C.3.6 Product Trademark Name* ...................................................................................................................................... C-1 C.3.7 Product Specification ............................................................................................................................................... C-2 C.3.8 Unit of Issue ............................................................................................................................................................. C-2 C.3.9 Unit of Measure ....................................................................................................................................................... C-2

C.4 Technical Information. ....................................................................................................................................................... C-2 C.4.1 Structural or Consumable* ...................................................................................................................................... C-2 C.4.2 Temperature(s) Where Product Will Be Used ......................................................................................................... C-2 C.4.3 Quantity of HM Within the System* ....................................................................................................................... C-2 C.4.4 Special HM Control, Training, Handling Measures, and Personal Protection Equipment (PPE) Needed* ............. C-2 C.4.5 System* .................................................................................................................................................................... C-2 C.4.6 Usage Information* ................................................................................................................................................. C-2 C.4.7 Maintenance Index Page(s) ...................................................................................................................................... C-2 C.4.8 Maintenance Requirement Card Number(s) ............................................................................................................ C-2 C.4.9 Allowance Part or Equipage List(s) ......................................................................................................................... C-2 C.4.10 Technical Manual(s) .............................................................................................................................................. C-2

C.5 Risk Assessment Information. ........................................................................................................................................... C-2 C.5.1 Mishap Severity Category* ...................................................................................................................................... C-2 C.5.2 Rationale for Mishap Severity Category* ................................................................................................................ C-2 C.5.3 Mishap Probability Level* ....................................................................................................................................... C-2 C.5.4 Rationale for Mishap Probability Level* ................................................................................................................. C-2 C.5.5 Risk Assessment Code ............................................................................................................................................. C-2 C.5.6 Discuss How Risk Will Be Mitigated and/or Managed Throughout Life-Cycle* ................................................... C-2

C.6 NAVSEA 05 Technical Community Recommendation(s) and PRogram Manager Decision. ........................................... C-2 Appendix D List of Acronyms ......................................................................................................................................................... D-1

D.1 List of Acronyms. ............................................................................................................................................................. D-1 vi

LIST OF ILLUSTRATIONS

Figure No. and Title Page

Figure B-1. NAVSEA Hazardous Material Risk Identification, Assessment, Acceptance, and Tracking Process. ....................... B-4 Figure C-1. NAVSEA Hazardous Material Waiver Request Form. ............................................................................................... C-3

LIST OF TABLES

Table No. and Title Page

Table A-1. Prohibited Chemicals on the N-LTC ............................................................................................................................ A-1 Table A-2. Restricted Chemicals on the N-LTC. ............................................................................................................................ A-1 Table A-3. Tracked Chemicals on the N-LTC ................................................................................................................................ A-6 vii

FOREWORD

This document is intended to formalize Naval Sea System Command’s (NAVSEA) process for the elimination or minimization of Hazardous Material (HM) used in delivered NAVSEA-sponsored systems, equipment, and processes by standardizing HM avoidance requirements. This document is organized as follows:

Chapter 1, Introduction

Chapter 2, HM Management and Identification Process

Chapter 3, Responsibilities

Appendix A, NAVSEA List of Targeted Chemicals (N-LTC)

Appendix B, NAVSEA 05 Hazardous Material Management Procedure

Appendix C, NAVSEA Hazardous Material Waiver Request Form Guidance

Appendix D, List of Acronyms

DISTANCE SUPPORT INFORMATION

Contact the Navy Distance Support (Anchor Desk) via the web (http://www.anchordesk.navy.mil/), e-mail (help@AnchorDesk.navy.mil), or via the toll free number (1-877-4-1-TOUCH [86824]).

TMDER INSTRUCTIONS

Ships, training activities, supply points, depots, Naval Shipyards and Supervisors of Shipbuilding are requested to arrange for the maximum practical use and evaluation of NAVSEA technical manuals (TMs). All errors, omissions, discrepancies, and suggestions for improvement to NAVSEA TMs shall be submitted as a Technical Manual Deficiency/Evaluation Report (TMDER). All feedback comments shall be thoroughly investigated and originators will be advised of action resulting there from.

The NAVSEA/SPAWAR Technical Manual Deficiency/Evaluation Report form, NAVSEA 4160/1, is included at the back of the

TM.

Copies of form NAVSEA 4160/1 may also be downloaded from:

https://nsdsa.nmci.navy.mil/nsdsarepository/TMDER_BLANK_REV_9-2010-1.pdf

The following methods are available for generation and submission of TMDERs against unclassified TMs:

• For those with a Technical Data Management Information System (TDMIS) account, the most expedient and preferred method of TMDER generation and submission is via the TDMIS website at: https://mercury.tdmis.navy.mil.

• For those without a TDMIS account, generate and submit TMDER via the Naval Systems Data Support Activity (NSDSA) website at: https://mercury.tdmis.navy.mil/def_external/pubsearch.cfm. (TDMIS accounts may be requested at https://nsdsa.nmci.navy.mil.)

• When internet access is not available, submit TMDER via hardcopy to:

COMMANDER

CODE 310 TMDERs

NAVSURFWARCENDIV NSDSA

4363 MISSILE WAY, BLDG 1389

PORT HUENEME, CA 93043-4307

• TMDERs against classified/restricted (includes all NOFORN) TMs must be submitted using the hardcopy method cited above.

http://www.anchordesk.navy.mil/ https://nsdsa.nmci.navy.mil/nsdsarepository/TMDER_BLANK_REV_9-2010-1.pdf https://mercury.tdmis.navy.mil/ https://mercury.tdmis.navy.mil/def_external/pubsearch.cfm https://nsdsa.nmci.navy.mil/ viii

• Urgent priority TM deficiencies shall be reported by Naval message with transmission to Port Hueneme Division, Naval Surface Warfare Center (Code 310), Port Hueneme, CA. Local message handling procedures shall be used. The message shall identify each TM deficiency by TM identification number and title. This method shall be used in those instances where a TM deficiency constitutes an urgent problem, (i.e., involves a condition, which if not corrected, could result in injury to personnel, damage to the equipment or, jeopardy to the safety or success of the mission).

Complete instructions for TMDER generation and submission are detailed on the NSDSA website at:

https://nsdsa.nmci.navy.mil/tmder/tmder.asp?lvl=1.

https://nsdsa.nmci.navy.mil/tmder/tmder.asp?lvl=1

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CHAPTER 1

INTRODUCTION

1.1 PURPOSE.

The purpose of this document is as follows:

a. To formalize Naval Sea System Command’s (NAVSEA) process for the elimination or minimization of Hazardous Material (HM) used in delivered NAVSEA-sponsored systems, equipment, and processes by standardizing HM avoidance requirements in support of NAVSEAINST 5100.12.

b. To develop a comprehensive knowledge base of successful HM avoidance initiatives and to use this knowledge to share lessons learned regarding successful HM elimination/minimization initiatives, as well as provide a resource for HM risk assessment and mitigation efforts.

c. To formalize the process of integrating HM used in NAVSEA systems, equipment, and processes with the appropriate Authorized Use List (AUL) for life-cycle management.

d. To develop a comprehensive knowledge base of where and how NAVSEA continues to use HM to focus future Research, Development, Test, and Evaluation (RDT&E) activities related to HM avoidance.

e. To require in ship specification section 077 and general specifications for ships overhaul.

1.2 APPLICABLE DOCUMENTS.

The following are references found in this document:

a. NAVSEAINST 5100.12, System Safety Engineering Policy

b. OPNAVINST 5090.1, Environmental Readiness Program Manual

c. Executive Order (EO) 13693, Planning for Federal Sustainability in the Next Decade, of 19 Mar 15

d. OPNAVINST 5100.19, Navy Safety and Occupational Health (SOH) Program Manual for Forces Afloat

e. Environmental Readiness in Systems Acquisition, CNO(N4) Memorandum N4/8U156042, of 29 Jul 08

f. NAVSEAINST 5000.8, Naval SYSCOM Risk Management Policy

g. NAVSEA 5100.12-M, System Safety Engineering Manual

h. NAVSEA S9510-AB-ATM-010, Technical Manual for Nuclear Powered Submarine Atmosphere Control Manual

i. NSWCCD-63-TR-2012/140, Development of the Naval Sea Systems Command List of Targeted Chemicals, of 31 Oct

12 (N-LTC)(Formerly the NAVSEA Prohibited and Controlled Chemical List (PCCL), of 26 Nov 08)

j. ASN (RD&A) Memorandum for Distribution, Department of the Navy Hexavalent Chromium Authorization Process, of

22 Dec 11

k. ASN (RD&A) Memorandum for Distribution, Equipment/Systems Requiring the Unplanned Use of Class I Ozone-

Depleting Substances (ODS), of 13 Nov 97

1.3 CANCELLATION.

NAVSEA letter Ser 05P/311 of 06 Aug 10 (NAVSEA Hazardous Material Avoidance Process) and NAVSEA letter Ser 04R/138 of 26 Nov 2008 (NAVSEA Prohibited and Controlled Chemical List) are hereby cancelled and superseded by this document.

1.4 BACKGROUND.

OPNAVINST 5090.1 defines HM as any material that, because of its quantity, concentration or physical, chemical, or infectious characteristics, may pose a substantial hazard to human health or the environment when incorrectly used, purposefully released, or accidentally spilled. This definition includes the following:

a. Flammable/combustible materials

b. Toxic materials

c. Corrosive materials (including acids and bases)

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d. Oxidizing materials

e. Aerosol containers

f. Compressed gases

1.4.1 Exceptions. For purposes of this procedure, the definition of HM does not include materials that require special handling and disposal procedures including ammunition, weapons, explosives and explosive-actuated devices, propellants, pyrotechnics, chemical and biological warfare materials, medical and pharmaceutical materials, medical waste and infectious materials, bulk fuels, and radioactive materials. These materials are hazardous, and exposure to personnel may occur during manufacture, storage, use, and demilitarization of these items. Risk assessment and approval/disapproval for the use of these materials is made by other Navy authorities.

1.4.2 Formalizing the Approach for HM Elimination and Minimization. Eliminating or minimizing the use of HM will reduce risks to human health and the environment; reduce weapon system life cycle costs associated with HM handling, storage, and disposal; help the Navy meet EO 13693 and OPNAVINST 5100.19 requirements to reduce the quantity of HM acquired, used, or disposed of; and support the Environmental Readiness in Systems Acquisition, CNO(N4) Memorandum N4/8U156042 requirement to minimize the use and quantity of HM used during manufacture and sustainment. Additionally, formalizing the approach for HM elimination or minimization supports the NAVSEAINST 5000.8 requirement for each acquisition and in-service program to have a defined risk management program. It also supports the NAVSEA 5100.12-M requirement for the Technical Warrant Holder (TWH) for Environmental Systems and Materials Engineering (NAVSEA 05P5) to provide cross-platform engineering and acquisition support for HM management and minimization efforts.

1.5 SCOPE AND APPLICABILITY.

This process applies to all of Corporate NAVSEA, encompassing NAVSEA Headquarters Directorates (NAVSEA HQ), NAVSEA Affiliated Program Executive Offices (PEOs) (including Program Managers Ships/Systems [PMS]), Supervisors of Shipbuilding (SUPSHIPS), Naval Surface Warfare Center (NSWC) Divisions, Naval Undersea Warfare Center (NUWC) Divisions, and other NAVSEA Field Activities (OFA), herein after referred to as “Lead Activities.” This process also applies to new ship and weapon system/equipment acquisition programs, modernization programs, logistics revisions, and system life-cycle management as of the date of this Technical Manual. Life-cycle management encompasses system/equipment manufacturing, installation, test and evaluation, operation, maintenance, modernization, repair, and disposal. This process does not apply to the laboratory use of analytical chemicals. This process will not be applied retroactively to existing acquisition programs and contracts unless directed by higher authority.

1.6 NON-APPLICABILITY.

This process does not apply to systems/equipment under the cognizance of Strategic Systems Program (SSP) or the Director, Naval Nuclear Propulsion (NAVSEA 08). This process also does not apply to maintenance executed at Naval Shipyards, Regional Maintenance Centers (RMCs), Depots, and Refit Facilities since compliance with this process will be completed by the lead activities developing the technical requirements.

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CHAPTER 2

HM MANAGEMENT AND IDENTIFICATION PROCESS

2.1 INTRODUCTION.

The use of HM in NAVSEA-sponsored systems, equipment, and processes poses a hazard and risk that must be addressed and minimized through proper management strategies. This document utilizes and expands upon practices from NAVSEAINST 5000.8 to properly manage HM. System safety practices must be applied to HM identified in NAVSEA applications to allow for proper risk assessment and hazard mitigation measures. When properly applied, the system safety requirements of NAVSEAINST 5000.8 and NAVSEAINST 5100.12, and procedures in NAVSEA 5100.12-M should enable the identification and management of HM and their associated risks during system development and sustaining engineering activities.

The hazard identification process shall consider the entire system life-cycle and potential impacts to personnel, infrastructure, defense systems, the public, and the environment.

2.2 HM MANAGEMENT PLAN.

The NAVSEA System Engineering Safety Manual (NAVSEA 5100.12-M) provides guidance on the development of a Hazardous Material Management Plan (HMMP), which is a critical component of integrating HM management into the systems engineering process. Through the HMMP, the Program can define contractor roles, responsibilities, and procedures to accomplish HM management and tracking.

2.3 HM CATEGORIES.

Following contract award, a list of HM within the delivered hardware and/or required for system construction/manufacture, installation, operation and support, categorized as prohibited, restricted, or tracked, will be mutually agreed upon by the Government and contractor. These categories have been defined as follows:

a. Prohibited HM require the contractor to obtain Government approval before those materials can be included in the system, subsystems, and support equipment or planned for system construction/manufacture, installation, operation or support.

b. Restricted HM are those materials that the contractor will target for elimination or minimization.

c. Tracked HM are those materials that do not require specific contractor action other than tracking and reporting.

Additionally, the contractor will be required to track and report all prohibited, restricted, and tracked HM included in the delivered systems, subsystems, and support equipment or planned for system operation or support.

2.4 HM APPROVAL AND ASSESSMENT.

While only prohibited HM requires Government approval prior to use, all HM must be properly assessed through the system safety principles in NAVSEAINST 5100.12 and NAVSEA 5100.12-M. The identified risk and supporting analysis from this process must be accepted by the appropriate authorities as delineated in NAVSEAINST 5000.8.

2.5 NAVSEA LIST OF TARGETED CHEMICALS (N-LTC).

The NAVSEA List of Targeted Chemicals (N-LTC) was developed to support the HM management requirements of EO 13693, OPNAVINST 5100.19, and Environmental Readiness in Systems Acquisition, CNO(N4) Memorandum N4/8U156042.

2.5.1 Purpose of the N-LTC. The N-LTC identifies chemicals that may pose the greatest risk to Navy personnel, delivered hardware, and the environment. The chemicals in Appendix A have been categorized in accordance with the definitions of section 2.3. To assist in the system safety practices of NAVSEAINST 5100.12 and NAVSEA 5100.12-M, NAVSEA has assigned minimum severity categories to each of the chemicals based on the potential for death or injury, environmental impact, or monetary loss. If these chemicals are identified either as pure chemicals or as a constituent of a material for use in NAVSEA hardware and/or required for system operation and support, a proper risk assessment must be conducted by applying the provided severity category and determining the probability level of exposure based upon product application. Certain chemicals in Appendix A have identified application exceptions as discussed in section B.8. The risk assessment code (RAC) for these chemicals in the specific applications have already been determined and received the appropriate risk analysis approvals by SEA 05, per NAVSEAINST 5000.8.

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2.5.2 Determination of HM Severity Categories. The NAVSEA-provided severity categories, based upon the definitions of NAVSEAINST 5000.8, are minimum assignments and can be elevated at the discretion of a program. The NAVSEA activity will be responsible for determining the probability level of exposure for the chemical application when conducting a risk assessment.

Based upon the resultant RAC, use of the identified HM will require the appropriate level of risk acceptance per NAVSEAINST 5000.8, following the procedure discussed in Appendix B.

2.5.3 NAVSEA 05 Involvement. This procedure also formalizes the involvement of NAVSEA 05 in the Shipboard Hazardous Material List (SHML)/Submarine Material Control List Feedback Report (SFR) and Submarine Material Control List (SMCL) Certification Request processes in accordance with OPNAVINST 5100.19 and NAVSEA S9510-AB-ATM-010. These reports are used to request new material be added to the SHML and SMCL, which are the HM AULs for the respective communities.

The N-LTC has been integrated into these processes to further manage HM across NAVSEA platforms.

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CHAPTER 3

RESPONSIBILITIES

3.1 NAVSEA LEAD ACTIVITY RESPONSIBILITIES.

NAVSEA Lead Activities shall:

a. Invoke the requirements of this manual (items (b) through (g) below) via Contracts, Contract Data Requirements Lists (CDRLs), Statements of Work (SOWs), specifications, and Memorandums of Agreement (MOAs) upon all contractors, subcontractors, vendors, suppliers and Participating Area Responsible Managers (PARMs).

b. When applicable, include the requirements of the HM Avoidance Process and use of the N-LTC in the program’s

HMMP.

c. Evaluate systems, subsystems, equipment, associated installation, maintenance and repair processes, specifications, and standards to identify components, materials, products, and consumables with HM per procedures discussed in Appendix B.

d. Minimize the use of HM containing Prohibited and Restricted chemicals per Appendix A to the maximum extent possible based on evaluation of cost, performance, schedule, and programmatic risk analyses.

e. Perform risk assessments for all HM containing chemicals listed in the N-LTC in accordance with the requirements of NAVSEAINST 5000.8 per Appendix B. Document the risk assessment for all N-LTC Tables A-1 and A-2 chemicals in addition to Table A-3 chemicals that are assigned a serious or high residual risk.

f. Per Section B.4 of Appendix B, submit a NAVSEA 05 HM Waiver Request Form (Appendix C) to NAVSEA 05P5 for procurement or use of any HM containing a Prohibited chemical or application with a risk assessment code of high or serious.

g. Provide a copy of the approved/denied HM Waiver Request Form to NAVSEA 05P5.

3.2 NAVSEA 05P5 TWH FOR ENVIRONMENTAL SYSTEMS AND MATERIALS ENGINEERING

RESPONSIBILITIES.

The NAVSEA 05P5 TWH for Environmental Systems and Materials Engineering shall:

a. Coordinate with NAVSEA 04R and other appropriate organizations to review and update, if appropriate, the N-LTC whenever there is a significant change to regulations or Navy Policy, or when significant environmental or human health and safety impacts arise that require immediate action. Revisions to the N-LTC will not be retroactive to existing acquisition programs. New directives and revisions to the N-LTC will not be applied retroactively to existing acquisition programs and contracts unless directed by higher authority.

b. Coordinate review of submitted NAVSEA 05 HM Waiver Request Forms with other NAVSEA 05 Technical Domain Managers (TDM) and provide the requesting Lead Activity and Program Office a consolidated recommendation for approval or denial per NAVSEAINST 5000.8. Coordination may be conducted electronically or via formal meetings chaired by NAVSEA 05P5.

c. Develop and maintain NAVSEA approved application exceptions for chemicals listed in Appendix A per the risk acceptance requirements of NAVSEAINST 5000.8.

d. Develop and maintain a database/repository for all HM Waiver Request Forms and associated documentation.

e. Coordinate with Lead Activities to ensure HM is integrated into the appropriate AUL.

f. Review all successful HM elimination/minimization initiatives for potential applicability to legacy systems and previously approved HM Waiver Review Forms.

g. Coordinate with appropriate TWHs, Life-Cycle Managers (LCMs), In-Service Engineering Agents (ISEAs), Subject

Matter Experts (SMEs), Fleet or end-users, Department of Defense (DoD) organizations, and other stakeholders.

h. Maintain a series of TWH Chemical Position Papers that highlight the concerns associated specific chemicals of interest on the N-LTC. The position papers are hosted on Navy Knowledge Online (NKO) on the Environmental, Safety, and Occupational Health (ESOH) in Acquisition sub-community of the Shipboard Environmental Information Clearinghouse (SEIC) (https://www.nko.navy.mil/group/esoh-in-acquisition/home).

https://www.nko.navy.mil/group/esoh-in-acquisition/home

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3.3 NAVSEA TDM RESPONSIBILITIES.

NAVSEA TDMs shall coordinate the review of submitted NAVSEA 05 HM Waiver Request Forms with NAVSEA 05P5 and provide the requesting Program Office a consolidated recommendation for approval or denial per NAVSEAINST 5000.8.

3.4 NAVSEA CHIEF SYSTEMS ENGINEERS (CSE) RESPONSIBILITIES.

NAVSEA CSEs shall coordinate the review of submitted NAVSEA 05 HM Waiver Request Forms with NAVSEA 05P5 and provide the requesting Program Office a consolidated recommendation for approval or denial per NAVSEAINST 5000.8.

3.5 POINT OF CONTACT.

The NAVSEA 05 point of contact for this Technical Manual is Mr. Peter McGraw (NAVSEA Technical Warrant Holder, Ship Environmental Systems and Materials Engineering) at (202) 781-2990 or Peter.McGraw@navy.mil.

mailto:Peter.McGraw@navy.mil

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APPENDIX A

NAVSEA LIST OF TARGETED CHEMICALS (N-LTC)

A.1 INTRODUCTION.

Tables A-1 through A-3 below comprise the N-LTC.

Table A-1. Prohibited Chemicals on the N-LTC.

Chemical CAS Severity Category

Asbestos (friable) 1332-21-4 Catastrophic Asbestos variation - Actinolite 77536-66-4 Catastrophic Asbestos variation - Amosite 12172-73-5 Catastrophic Asbestos variation - Anthophyllite 77536-67-5 Catastrophic Asbestos variation - Chrysotile 12001-29-5 Catastrophic Asbestos variation - Crocidolite 12001-28-4 Catastrophic Asbestos variation - Tremolite 77536-68-6 Catastrophic Hexavalent Chromium Compounds Multiple CAS Catastrophic Ozone Depleting Substances Class I Multiple CAS Catastrophic Chlordane 57-74-9 Critical Polychlorinated Biphenyls (PCB) Multiple CAS Critical

Table A-2. Restricted Chemicals on the N-LTC.

Chemical CAS Severity Category

1,3-Butadiene 106-99-0 Catastrophic 4,4'-Methylenebis (2-chloroaniline) (MBOCA) 101-14-4 Catastrophic 4-Aminobiphenyl 92-67-1 Catastrophic Acetaldehyde 75-07-0 Catastrophic Arsenic and Arsenic Compounds Note: Except when used in batteries, solder, and electronic applications (see A.2.1).

Multiple CAS Catastrophic

Benzene 71-43-2 Catastrophic Benzidine 92-87-5 Catastrophic Benzo[a]pyrene 50-32-8 Catastrophic Beryllium and Beryllium Compounds Note: Except when used in electronic applications (see A.2.2).

Multiple CAS Catastrophic beta-Naphthylamine 91-59-8 Catastrophic Cadmium and Cadmium Compounds Note: Except when used in batteries (see A.2.3).

Multiple CAS Catastrophic

Chlorambucil 305-03-3 Catastrophic Chlornaphazine 494-03-1 Catastrophic Chloromethyl Ether 542-88-1 Catastrophic

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Table A-2. Restricted Chemicals on the N-LTC (Continued).

Chemical CAS Severity Category

Chloromethyl Methyl Ether 107-30-2 Catastrophic Cyclophosphamide 50-18-0 Catastrophic Diethylstilbestrol 56-53-1 Catastrophic Ethylene Oxide 75-21-8 Catastrophic Formaldehyde 50-00-0 Catastrophic Melphalan 148-82-3 Catastrophic Mustard Gas 505-60-2 Catastrophic Nickel Compounds Note: Except when used in batteries (see A.2.4).

Multiple CAS Catastrophic

N-Nitrosonornicotine 16543-55-8 Catastrophic o-Toluidine 95-53-4 Catastrophic Phenacetin 62-44-2 Catastrophic Sulfuric Acid Note: Except when used in sealed maintenance-free batteries (see A.2.5).

7664-93-9 Catastrophic

Thorium Dioxide 1314-20-1 Catastrophic Vinyl Chloride Note: Except when used in polyvinyl chloride (PVC) (see A.2.6).

75-01-4 Catastrophic

1,1,2,2-Tetrachloroethane 79-34-5 Critical 1,1,2-Trichloroethane 79-00-5 Critical 1,2-Dichloropropane 78-87-5 Critical 1,3,5-trinitro-1,3,5-triazine (RDX) 121-82-4 Critical 1,3-Dichloropropene 542-75-6 Critical 1,4-Dichlorobenzene 106-46-7 Critical 2,4,6-Trichlorophenol 88-06-2 Critical 2,4-Dinitrotoluene 121-14-2 Critical 2-Acetylaminofluorene 53-96-3 Critical 3,3'-Dichlorobenzidine 91-94-1 Critical 4,4'-Methylenedianiline 101-77-9 Critical Acrolein 107-02-8 Critical Acrylamide 79-06-1 Critical Aldrin 309-00-2 Critical Aziridine 151-56-4 Critical Benz[a]anthracene 56-55-3 Critical Benzo(a)phenanthrene 218-01-9 Critical Benzo(k)fluoranthene 207-08-9 Critical Benzo[b]fluoranthene 205-99-2 Critical Benzyl Chloride 100-44-7 Critical Bromoform 75-25-2 Critical

A-3

Table A-2. Restricted Chemicals on the N-LTC (Continued).

Chemical CAS Severity Category

Carbaryl 63-25-2 Critical Carbon Disulfide 75-15-0 Critical Carbonic dichloride 75-44-5 Critical Chlorobenzene 108-90-7 Critical Chloroform 67-66-3 Critical Cyanide Containing Compounds (includes Nitrile and Cyano Compounds) Note: Except when used in rubber (see A.2.7).

Multiple CAS Critical

Dibenz[a,h]anthracene 53-70-3 Critical Dibromochloropropane (DBCP) 96-12-8 Critical Dichlorodiphenyltrichloroethane (DDT) 50-29-3 Critical Dichloroethyl Ether 111-44-4 Critical Dichlorvos 62-73-7 Critical Dieldrin 60-57-1 Critical Dimethyl Sulfate 77-78-1 Critical Dimethylhydrazine 57-14-7 Critical Dinitrocresol 534-52-1 Critical Dioxin and Dioxin-Like Compounds Multiple CAS Critical Endrin 72-20-8 Critical Epichlorohydrin 106-89-8 Critical Ethylene Dibromide 106-93-4 Critical Ethylene Dichloride 107-06-2 Critical Ethylene Thiourea 96-45-7 Critical Ethylidene Dichloride 75-34-3 Critical Fluoranthene 206-44-0 Critical Heptachlor 76-44-8 Critical Hexachlorobenzene 118-74-1 Critical Hexachlorobutadiene 87-68-3 Critical Hexachloroethane 67-72-1 Critical Hydrazine 302-01-2 Critical Indeno(1,2,3-cd)pyrene 193-39-5 Critical Isocyanate Compounds Multiple CAS Critical Lead and Lead Compounds Note: Except when used in solder, sealed maintenance-free batteries, lead ballast for vessel stability, and industry standard metal alloys with lead ≤3% (see A.2.8).

Multiple CAS Critical

Lindane 58-89-9 Critical Lithium and Lithium Compounds Note: Except when used in batteries (per S9310-AQ-SAF-010) and greases (see A.2.9).

Multiple CAS Critical

A-4

Table A-2. Restricted Chemicals on the N-LTC (Continued).

Chemical CAS Severity Category

Mercury and Mercury Compounds Note: Except when used in batteries, LCD displays, and general purpose lighting (lamps and bulbs) (see A.2.10).

Multiple CAS Critical

Methoxychlor 72-43-5 Critical Methyl Chloride 74-87-3 Critical Methylene Chloride 75-09-2 Critical Naphthalene 91-20-3 Critical Nickel Note: Except when used in piping, electrical connectors, electronic applications, plating, and industry standard metal alloys (see A.2.11).

7440-02-0 Critical

Nitrobenzene 98-95-3 Critical Nitrosodimethylamine 62-75-9 Critical o-Anisidine 90-04-0 Critical Parathion 56-38-2 Critical Pentachlorophenol (PCP) 87-86-5 Critical Perchloroethylene 127-18-4 Critical Phenol Note: Except when used in phenolic resins (see A.2.12).

108-95-2 Critical

Phthalate Esters Multiple CAS Critical Styrene Note: Except when used in polymerized styrene (see A.2.13).

100-42-5 Critical

Sulfur Hexafluoride 2551-62-4 Critical Toluene 108-88-3 Critical Toxaphene 8001-35-2 Critical Trichloroethylene (TCE) 79-01-6 Critical Vinylidene Chloride 75-35-4 Critical 1,2,4-Trichlorobenzene 120-82-1 Marginal 1,2-Dichlorobenzene 95-50-1 Marginal 2,4-Diaminotoluene 95-80-7 Marginal 2,4-Dichlorophenoxyacetic Acid (2,4-D) 94-75-7 Marginal 2,4-Dinitrophenol 51-28-5 Marginal 2,6-Dinitrotoluene 606-20-2 Marginal 2-Ethoxyethanol 110-80-5 Marginal 2-Nitropropane 79-46-9 Marginal 3-Methylcholanthrene 56-49-5 Marginal 4-Nitrophenol 100-02-7 Marginal 7,12-Dimethylbenz[a]anthracene 57-97-6 Marginal 7H-Dibenzo(c,g)carbazole 194-59-2 Marginal Allyl Alcohol 107-18-6 Marginal

A-5

Table A-2. Restricted Chemicals on the N-LTC. (Continued)

Chemical CAS Severity Category

Allyl Chloride 107-05-1 Marginal alpha-BHC 319-84-6 Marginal Aniline 62-53-3 Marginal Anthracene 120-12-7 Marginal Antimony and Antimony Compounds Note: Except when used in batteries and solder (see A.2.14).

Multiple CAS Marginal

Benomyl 17804-35-2 Marginal Benzo(j)fluoranthene 205-82-3 Marginal Benzotrichloride 98-07-7 Marginal Beta-Propiolactone 57-57-8 Marginal Carbofuran 1563-66-2 Marginal Chlorine 7782-50-5 Marginal Chloroprene 126-99-8 Marginal Chromium and Non-Hexavalent Chromium Compounds Note: Except when used in plating, industry standard metal alloys, and trivalent chromium coatings and surface treatments (see A.2.15).

Multiple CAS Marginal

Cobalt and Cobalt Compounds Note: Except when used in industry standard metal alloys (see A.2.16).

Multiple CAS Marginal

Copper and Copper Compounds Note: Except when used in batteries, solder, piping, electrical and electronic applications, plating, antifouling hull coatings and industry standard metal alloys (not including copper beryllium alloys) (see A.2.17).

Multiple CAS Marginal

Cresol (mixed isomers) 1319-77-3 Marginal Dibenz(a,h)acridine 226-36-8 Marginal Dibenz(a,j)acridine 224-42-0 Marginal Dibenz[a,i]pyrene 189-55-9 Marginal Dibenzo(a,e)pyrene 192-65-4 Marginal Dibenzo(a,h)pyrene 189-64-0 Marginal Dichlorodiphenyldichloroethane (DDD) 72-54-8 Marginal Dimethylaminoazobenzene 60-11-7 Marginal Dinitrobutyl Phenol 88-85-7 Marginal Dinitrotoluene (mixed isomers) 25321-14-6 Marginal Ethyl Chloride 75-00-3 Marginal Ethylbenzene 100-41-4 Marginal Furan 110-00-9 Marginal Hexachlorocyclopentadiene 77-47-4 Marginal Hexamethylphosphoramide 680-31-9 Marginal Hydrazobenzene 122-66-7 Marginal Hydrofluoric Acid 7664-39-3 Marginal

A-6

Table A-2. Restricted Chemicals on the N-LTC. (Continued)

Chemical CAS Severity Category

Kepone 143-50-0 Marginal Maleic Anhydride 108-31-6 Marginal m-Cresol 108-39-4 Marginal Methanol 67-56-1 Marginal Methyl Hydrazine 60-34-4 Marginal Nicotine 54-11-5 Marginal Nitrogen Mustard 51-75-2 Marginal o-Cresol 95-48-7 Marginal o-Tolidine 119-93-7 Marginal Ozone Depleting Substances Class II Multiple CAS Marginal p-Cresol 106-44-5 Marginal Pentachlorobenzene 608-93-5 Marginal Phosphine 7803-51-2 Marginal Phosphorus 7723-14-0 Marginal Propylene Oxide 75-56-9 Marginal Propyleneimine 75-55-8 Marginal Quinone 106-51-4 Marginal Selenium and Selenium Compounds Note: Except when used in electronic components (see A.2.18).

Multiple CAS Marginal

Silver and Silver Compounds Note: Except when used in electrical and electronic applications, plating, and solder (see A.2.19).

Multiple CAS Marginal

Sodium Fluoroacetate 62-74-8 Marginal Strychnine 57-24-9 Marginal Thallium and Thallium Compounds Multiple CAS Marginal Thiomethanol 74-93-1 Marginal Tin Compounds Multiple CAS Marginal Urethane 51-79-6 Marginal Warfarin 81-81-2 Marginal Xylene (Mixed Isomers) 1330-20-7 Marginal Zinc Compounds Multiple CAS Marginal

Table A-3. Tracked Chemicals on the N-LTC

CHEMICAL CAS Severity Category

All hazardous materials containing chemicals not listed on the Prohibited and Restricted Tiers (Tables A-1 and A-2) TBD by Lead

Activity

A-7

A.2 NAVSEA LIST OF TARGETED CHEMICALS (N-LTC) APPLICATION EXCEPTION NOTES.

The following Notes provide rationale for the determination of N-LTC Application Exceptions. The Notes are referenced in Tables A-1 and A-2.

A.2.1 Exception: Arsenic and Arsenic Compounds.

A.2.1.1 Batteries.

a. Severity Category: Catastrophic

b. Probability Level: Improbable

c. Rationale: During normal use, arsenic is fully contained in the battery. However, if the battery cell were to be opened or exposed to heat, exposure to arsenic could be harmful to personnel.

d. Risk Assessment Code: Medium

e. Rationale for Exception: Some lead-acid batteries contain…