Ansulite_3%_(AFC-5A)_AFFF_Concentrate.pdf

Safety Data Sheet

This safety data sheet complies with the requirements of: 2012 OSHA Hazard Communication Standard ( 29CFR 1910.1200)

Product name ANSULITE 3% (AFC-5A) AFFF Concentrate

1. Identification

Product name ANSULITE 3% (AFC-5A) AFFF Concentrate

Product code 442503 Synonyms None Chemical Family No information available

Recommended use Fire extinguishing agent Uses advised against Consumer use

Contact point Product Stewardship at 1-715-735-7411 E-mail address psra@tycofp.com

Emergency telephone CHEMTREC 800-424-9300 or 703-527-3887

2. Hazards Identification

OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Serious eye damage/eye irritation - Category 2

Precautionary Statements

1.1. Product Identifier

1.2. Other means of identification

1.3. Recommended use of the chemical and restrictions on use

1.4. Details of the Supplier of the Safety Data Sheet

Company Name Tyco Fire Protection Products

One Stanton Street Marinette, WI 54143-2542 Telephone: 715-735-7411

1.5. Emergency Telephone Number

Classification

2.2. Label Elements

Signal Word

WARNING

hazard statements Causes serious eye irritation

Revision date 15-Jun-2015 Version 2

Product code 442503 / Product name ANSULITE 3% (AFC-5A) AFFF Concentrate

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Prevention Wash face, hands and any exposed skin thoroughly after handling. Wear eye/face protection.

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Not Applicable.

Unknown Acute Toxicity 5.8066% of the mixture consists of ingredient(s) of unknown toxicity

3. Composition/information on Ingredients

The following component(s) in this product are considered hazardous under applicable OSHA(USA)

Chemical name CAS No weight-% 2-(2-Butoxyethoxy)ethanol 112-34-5 10 - 30

Perfluoro Telomer Proprietary 1 - 5 Anionic Fluorinated Surfactant Proprietary 1 - 5

Octylphenoxypolyethoxyethanol 9036-19-5 1 - 5 Lauryl Imino Propionate, Sodium Salt 14960-06-6 1 - 5

4. First aid measures

Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.

Consult a physician.

Skin contact Wash skin with soap and water. Get medical attention if irritation develops and persists.

Inhalation Remove to fresh air. If breathing is difficult, give oxygen. (Get medical attention immediately if symptoms occur.).

Ingestion Rinse mouth. Do not induce vomiting without medical advice. If swallowed, call a poison control center or physician immediately.

Symptoms No information available.

Note to physicians Treat symptomatically.

5. Fire-fighting measures

2.3. Hazards Not Otherwise Classified (HNOC)

2.4. OTHER INFORMATION

Revision date 15-Jun-2015

3.1. Mixture

4.1. Description of first aid measures

Version 2

4.2. Most Important Symptoms and Effects, Both Acute and Delayed

4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed

(AFC-5A) AFFF Concentrate

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Hazardous Combustion Products

Carbon oxides, Fluorinated oxides, Nitrogen oxides (NOx), Oxides of sulfur

Sensitivity to Mechanical Impact None.

Sensitivity to Static Discharge None.

6. Accidental release measures

Personal Precautions Ensure adequate ventilation, especially in confined areas.

For emergency responders Use personal protection recommended in Section 8.

Environmental Precautions Prevent further leakage or spillage if safe to do so. Prevent entry into waterways, sewers, basements or confined areas. See Section 12 for additional Ecological Information.

Methods for Containment Prevent further leakage or spillage if safe to do so.

Methods for Cleaning Up Pick up and transfer to properly labeled containers.

7. Handling and Storage

Advice on safe handling Avoid contact with skin and eyes. Handle in accordance with good industrial hygiene and safety practice.

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.

Incompatible Materials

Strong oxidizing agents. Strong acids. Strong bases.

8. Exposure Controls/Personal Protection

5.1. Suitable Extinguishing Media

Product is extinguishing agent. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

5.2. Unsuitable Extinguishing Media

None.

5.3. Specific Hazards Arising from the Chemical

None known.

5.4. Explosion Data

5.5. Protective Equipment and Precautions for Firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

6.1. Personal precautions, protective equipment and emergency procedures

Revision date 15-Jun-2015

6.2. Environmental Precautions

6.3. Methods and material for containment and cleaning up

Version 2

7.1. Precautions for Safe Handling

7.2. Conditions for safe storage, including any incompatibilities

(AFC-5A) AFFF Concentrate

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Exposure guidelines Chemical name ACGIH TLV OSHA PEL NIOSH IDLH

2-(2-Butoxyethoxy)ethanol 112-34-5

TWA: 10 ppm inhalable fraction and vapor

ACGIH (American Conference of Governmental Industrial Hygienists) OSHA (Occupational Safety and Health Administration of the US Department of Labor) NIOSH IDLH Immediately Dangerous to Life or Health

Engineering controls Showers Eyewash stations Ventilation systems.

Eye/Face Protection Avoid contact with eyes. Tight sealing safety goggles.

Skin and Body Protection Wear protective gloves and protective clothing.

Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.

Ventilation Use local exhaust or general dilution ventilation to control exposure with applicable limits

9. Physical and Chemical Properties

Physical State Liquid

8.1. Control Parameters

8.2. Appropriate Engineering Controls

8.3. Individual protection measures, such as personal protective equipment

8.4. General hygiene considerations

Do not eat, drink or smoke when using this product. Handle in accordance with good industrial hygiene and safety practice.

9.1. Information on basic physical and chemical properties

Odor Characteristic Color Light yellow odor threshold No data available

Property VALUES Remarks • Method pH 7 Melting point/freezing point No data available Boiling point / boiling range > 100 °C / 212 °F Flash Point > 100 °C / > 212 °F Evaporation Rate No data available flammability (solid, gas) No data available Flammability limit in air

Upper flammability limit: No data available

Lower flammability limit: No data available Vapor Pressure No data available Vapor Density No data available

Revision date 15-Jun-2015

Specific gravity

Version 2

No data available

(AFC-5A) AFFF Concentrate

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10. Stability and Reactivity

Stable under recommended storage conditions.

None under normal processing.

hazardous polymerization Hazardous polymerization does not occur.

Extremes of temperature and direct sunlight.

Strong oxidizing agents. Strong acids. Strong bases.

Carbon oxides. Nitrogen oxides (NOx). Oxides of sulfur. Fluorinated oxides.

11. Toxicological Information

Product information no data available

INHALATION no data available.

Eye Contact no data available.

Skin contact no data available.

INGESTION no data available.

Acute Toxicity

Chemical name Oral LD50 dermal LD50 Inhalation LC50 2-(2-Butoxyethoxy)ethanol 112-34-5

= 3384 mg/kg ( Rat ) = 2700 mg/kg ( Rabbit ) -

Water Solubility No data available Solubility in Other Solvents No data available Partition coefficient No data available Autoignition Temperature No data available Decomposition Temperature No data available

Kinematic viscosity No data available

10.1. Chemical Stability

10.2. Reactivity

No data available

10.3. Possibility of hazardous reactions

Revision date 15-Jun-2015

10.4. Conditions to Avoid

10.5. Incompatible Materials

Version 2

10.6. Hazardous decomposition products

11.1. Information on Likely Routes of Exposure

(AFC-5A) AFFF Concentrate

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Anionic Fluorinated Surfactant > 10,000 ppm (Rat) - -

Octylphenoxypolyethoxyethanol 9036-19-5

= 4190 mg/kg ( Rat ) - -

Symptoms No information available.

sensitization No information available.

Germ Cell Mutagenicity No information available carcinogenicity No information available.

Reproductive Toxicity No information available.

STOT - Single Exposure No information available.

STOT - Repeated Exposure No information available.

Aspiration Hazard No information available.

The following values are calculated based on chapter 3.1 of the GHS document mg/kg

12. Ecological Information

Not classified

0% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical name Algae/aquatic plants Fish Crustacea

2-(2-Butoxyethoxy)ethanol 112-34-5

EC50 96 h > 100 mg/L Desmodesmus subspicatus

LC50 96 h = 1300 mg/L Lepomis macrochirus static

EC50 24 h = 2850 mg/L Daphnia magna EC50 48 h > 100 mg/L

Daphnia magna 2-Methyl-2,4-pentanediol

107-41-5

- LC50 96 h 10500 - 11000 mg/L

Pimephales promelas flow-through LC50 96 h = 10000 mg/L Lepomis macrochirus static LC50 96 h = 8690 mg/L Pimephales promelas flow-through LC50 96 h = 10700 mg/L Pimephales promelas static

EC50 48 h 2700 - 3700 mg/L Daphnia magna t-Butanol 75-65-0

EC50 72 h > 1000 mg/L Desmodesmus subspicatus

LC50 96 h 6130 - 6700 mg/L Pimephales promelas flow-through

EC50 48 h = 933 mg/L Daphnia magna EC50 48 h 4607 - 6577 mg/L Daphnia magna Static Polyethylene Glycol

25322-68-3

- LC50 24 h > 5000 mg/L Carassius auratus

No information available.

No information available.

No information available

11.2. Information on Toxicological Effects

11.3. Delayed and immediate effects as well as chronic effects from short and long-term exposure

11.4. Numerical Measures of Toxicity - Product information

12.1. ecotoxicity

12.2. Persistence and Degradability

Revision date 15-Jun-2015

12.3. Bioaccumulation

12.4. Other Adverse Effects

(AFC-5A) AFFF Concentrate

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13. Disposal Considerations

Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations.

Contaminated Packaging Do not reuse container.

14. Transport Information

DOT NOT REGULATED

TDG NOT REGULATED

MEX NOT REGULATED

ICAO (air) NOT REGULATED

IATA NOT REGULATED

IMDG NOT REGULATED

15. Regulatory Information

TSCA Complies DSL/NDSL Complies ENCS Does not comply IECSC Does not comply KECL Does not comply PICCS Does not comply AICS Complies

Legend:

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances

SARA 313

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

Chemical name SARA 313 - Threshold Values % 2-(2-Butoxyethoxy)ethanol - 112-34-5

1.0 SARA 311/312 Hazard Categories

Acute Health Hazard No Chronic health hazard No

13.1. Waste Treatment Methods

Revision date 15-Jun-2015

15.1. International Inventories

15.2. US Federal Regulations

(AFC-5A) AFFF Concentrate

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Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No

CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40

CFR 122.42)

CERCLA

This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material

California Proposition 65 This product does not contain any Proposition 65 chemicals

U.S. State Right-to-Know Regulations

Chemical name New Jersey Massachusetts Pennsylvania 2-(2-Butoxyethoxy)ethanol

112-34-5 X - X

2-Methyl-2,4-pentanediol 107-41-5

X X X t-Butanol 75-65-0

X X X

16. Other information, including date of preparation of the last revision

Revision date 15-Jun-2015 Revision note No information available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

End of Safety Data Sheet

15.3. US State Regulations

NFPA Health Hazards 0 flammability 1 Instability 0 Physical and chemical properties -

HMIS

Revision date 15-Jun-2015

Health Hazards 0 flammability 1

Physical Hazards 0 Personal Protection X