ATTACHMENT 7 - Deltamethrin MSDS.pdf

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product label name Deltamethrin Supplier SUMITOMO CHEMICAL (UK) PLC

Horatio House 77-85 Fulham Palace Rd London W6 8JA United Kingdom Tel.: +44 208 600 7700

Emergency telephone + 31 570679211 (Fax. + 31 570679801) Akzo Nobel Chemicals-Deventer-NL

+ 44-1634280888 Akzo Nobel Chemicals-Gillingham-GB

2. COMPOSITION/INFORMATION ON INGREDIENTS

This product is to be considered as a substance in conformance to EC directives Information on hazardous ingredients Chemical description Deltamethrin Composition / information on ingredients Number % w/w CAS-number Chemical name 1 > 98% 52918-63-5 (S)-alpha-Cyano-3-phenoxybenzyl

(1R,3R)-3-(2,2-dibromovinyl)-2,2-dimethylcyclopropane carboxylate Number EC-number Annex-1 number Symbol(s) Risk-phrase(s) 1 258-256-6 T N R20 R25 R50/53

3. HAZARDS IDENTIFICATION

Harmful by inhalation.

Toxic if swallowed.

Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

4. FIRST AID MEASURES

Symptoms and effects Synthetic pyrethroids can produce paresthesias.

Typically, symptoms begin several hours after cutaneous exposure, peaks within about 12 hours and resolves within about 24 hours.

Extraordinary absorbed doses may rarely cause tremor, hyperexcitability, uncoordinated movements, salivation, nausea or vomiting and diarrhoea.

First aid General In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

Inhalation Move to fresh air. If symptoms persist, seek medical advice.

Skin Remove contaminated clothing. Wash immediately with soap and water.

Eye Rinse thoroughly with plenty of water. Eyelids should be held away from the eyeball to ensure thorough rinsing. Seek medical advice if irritation develops.

Ingestion Rinse mouth. Give water to drink. Induce vomiting. Never induce vomiting in unconscious or confused persons. Always seek medical advice.

Advice to physician Symptomatic treatment is advised.

Consult National Poison Center.

5. FIRE-FIGHTING MEASURES

Extinguishing media dry chemical powder, Carbon dioxide.

Large fires: waterspray or foam Unsuitable extinguishing media Water with full waterjet.

Special exposure hazards none known.

Hazardous decomposition/ combustion products

May emit toxic and irritating fumes under fire conditions.

Protective equipment Wear self contained breathing apparatus. Wear suitable protective clothing. See also Section 8.

Other information Keep away from heat.

Cool closed containers with water.

Water used to extinguish a fire should not be allowed to enter the drainage system or water courses.

SAFETY DATA SHEET

According to EC-directive 93/112/EC Pending

DELTAMETHRIN TG

Product code 923041 Date of last issue 2001/08/06 page 1 of 4 ics 409 GB - aEnglish

6. ACCIDENTAL RELEASE MEASURES

Personal precautions For personal protection see Section 8.

Environmental precautions Do not allow to escape into sewage system or water courses.

Methods for cleaning up Sweep up and put it into a container for disposal ( See Section 13). Rinse remnant with plenty of water. Do not allow to enter drains or water courses.

7. HANDLING AND STORAGE

Handling Keep away from food, drink and animal feedingstuffs. Avoid contact with skin and eyes.

For personal protection see Section 8.

Fire and explosion prevention No specific recommendations.

Storage requirements Store in a dry well ventilated place away from sources of heat and direct sunlight.

Store at ambient temperatures.

Other information Keep only in the original container.

To maintain quality: Store in polyethylene.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering controls Provide adequate ventilation.

Exposure limits No exposure limits have been established for this material.

Personal protection

Respiratory respirator with Filter P3.

Hand Wear protective gloves.

Eye Wear safety goggles.

Skin and body Wear suitable protective clothing.

Other information Launder clothes before reuse.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance crystalline solid Colour colourless Odour odourless Boiling point/range not applicable Melting point/range 98-101 °C Flash point not determined Flammability not determined Autoignition temperature not determined Explosive properties kST = 126 bar.m/s (st 1) Explosion limits not determined Oxidizing properties not relevant Vapour pressure 1.24 * 10-8 Pa (25 °C) Density not applicable Bulk density 500 kg/m³ Solubility in water Insoluble Solubility in other solvents Soluble ( in most organic solvents) pH value 5.9 (at 1% w/v water) Partition coefficient n-octanol/water

Log Pow = 4,6

Relative vapour density (air=1) not determined Viscosity not determined

10. STABILITY AND REACTIVITY

Stability Stable under recommended storage and handling conditions (see section 7).

Conditions to avoid Avoid direct sunlight.

Materials to avoid none known.

Hazardous decomposition products

Emits toxic fumes under fire conditions (See also Section 5).

SAFETY DATA SHEET

According to EC-directive 93/112/EC Pending

DELTAMETHRIN TG

Product code 923041 Date of last issue 2001/08/06 page 2 of 4

11. TOXICOLOGICAL INFORMATION

Name Deltamethrin Acute toxicity

Oral LD50 rat: 66.7 - 128.5 mg/kg Dermal LD50 rabbit: > 2000 mg/kg rat: 2940 mg/kg Inhalation LC50 rat (4 hours): 2.2 mg/l

Irritation Skin Non-irritating (rabbit).

Eye Slightly irritating to eyes (rabbit).

Sensitization Not sensitizing (guinea pig) Genotoxicity Not mutagenic.

Other toxicological information

Not teratogenic, not carcinogenic.

NOEL (No Observable Effect Level) = 1 mg/kg/day.

12. ECOLOGICAL INFORMATION

Name Deltamethrin

Ecotoxicity fish Acute toxicity, 96h-LC50: 0.001 - 0.01 mg/l daphnia Acute toxicity, 48h-EC50 ( Daphnia magna ): 0.0035 mg/l algae Acute toxicity, 72h-IC50: >9.1 mg/l Fate

13. DISPOSAL CONSIDERATIONS

Product According to local regulations. For further advice contact manufacturer.

Contaminated packaging According to local regulations.

14. TRANSPORT INFORMATION

Land transport (ADR/ RID)

ADR class 6.1 ADR item number 73c RID class 6.1 RID item number 73c Hazard Identification No. 60 Substance Identification No. 3349 TREM-Card CEFIC TEC(R)- 61G41c UN number 3349 Proper Shipping Name (Deltamethrin)

Sea transport (IMDG-code/ IMO) IMO/IMDG code Class 6.1 Packing group III UN number 3349

EMS 6.1-02 MFAG 510

Marine pollutant yes Proper Shipping Name Pyrethroid pesticide, solid, toxic (Deltamethrin)

Air transport (ICAO-TI/ IATA-DGR) ICAO-TI/IATA-DGR UN number 3349 Class 6.1 Packing group III Proper Shipping Name Pyrethroid pesticide, solid, toxic (Deltamethrin)

15. REGULATORY INFORMATION

Chemical description Deltamethrin

Labelling according to EC directives EC-number See section 2 Classification based on Annex-1 to directive 67/548/EEC

SAFETY DATA SHEET

According to EC-directive 93/112/EC Pending

DELTAMETHRIN TG

Product code 923041 Date of last issue 2001/08/06 page 3 of 4

Symbol(s) TOXIC (T) DANGEROUS FOR THE

ENVIRONMENT (N)

R(isk) phrase(s) R20: Harmful by inhalation R25: Toxic if swallowed R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment

S(afety) phrase(s) S28: After contact with skin, wash immediately with plenty of soap and water S36/37/39: Wear suitable protective clothing, gloves and eye/face protection S38: In case of insufficient ventilation, wear suitable respiratory equipment S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible) S60: This material and its container must be disposed of as hazardous waste S61: Avoid release to the environment. Refer to special instructions/Safety data sheets

16. OTHER INFORMATION

This information only concerns the above mentioned product and does not need to be valid if used with other product(s) or in any process. The information is to our best present knowledge correct and complete and is given in good faith but without warranty. It remains the user's own responsibility to make sure that the information is appropriate and complete for his special use of this product.

History

Other information This material is used for preparing insecticidal products for use by professionals and householders.

Date of printing/ pdf file generated

20-08-2001

Revision 0.00 Composed by Dr. D.J. Buckland Dr. R. Martin

SAFETY DATA SHEET

According to EC-directive 93/112/EC Pending

DELTAMETHRIN TG

Product code 923041 Date of last issue 2001/08/06 page 4 of 4