ATTACHMENT 4 - SDS-6 LIQUID CHLORINE-8080.pdf

LIQUID CHLORINE

Safety Data Sheet 8080 according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Date of issue: 05/27/2015

05/27/2015 EN (English US) SDS ID: 8080 Page 1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product form : Substance

Substance name : LIQUID CHLORINE

Product code : 8080

Synonyms : chlorine bleach, conc active chlorine=12.5% / Hypochlorite solution / hypochlorite, solution, conc active chlorine=12.5% / hypochlorous acid sodium salt, conc active chlorine=12.5% / javelle water, conc active chlorine=12.5% / sodium chloride oxide, solution, conc active chlorine=12.5% / sodium hypochlorite, solution, conc Cl active=12.5% / sodium oxychloride, conc active chlorine=12.5%

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.3. Details of the supplier of the safety data sheet

Brody Chemical 6125 W. Double Eagle Cr.

Salt Lake City, UT 84118 - USA T (801) 963-2436

1.4. Emergency telephone number

Emergency number : 1-800-424-9300

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (GHS-US)

Skin Corr. 1A H314 Eye Dam. 1 H318 Aquatic Acute 1 H400

Full text of H-phrases: see section 16

2.2. Label elements

GHS-US labeling

Hazard pictograms (GHS-US) :

GHS05

GHS09

Signal word (GHS-US) : Danger

Hazard statements (GHS-US) : H314 - Causes severe skin burns and eye damage H318 - Causes serious eye damage H400 - Very toxic to aquatic life

Precautionary statements (GHS-US) : P260 - Do not breathe fume, vapors P264 - Wash hands, forearms and face thoroughly after handling P273 - Avoid release to the environment P280 - Wear protective gloves, protective clothing, face protection, eye protection P301+P330+P331 - If swallowed: rinse mouth. Do NOT induce vomiting P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER P363 - Wash contaminated clothing before reuse P391 - Collect spillage P405 - Store locked up P501 - Dispose of contents/container to in accordance with all regulations

2.3. Other hazards

No additional information available

Safety Data Sheet

05/27/2015 EN (English US) SDS ID: 8080 2/1

2.4. Unknown acute toxicity (GHS-US)

Not applicable

SECTION 3: Composition/information on ingredients

3.1. Substance

Name Product identifier % Classification (GHS-US)

(Main constituent)

100 Skin Corr. 1A, H314 Eye Dam. 1, H318 Aquatic Acute 1, H400

3.2. Mixture

Not applicable

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures general : Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious with laboured breathing: half-seated. Victim in shock: on his back with legs slightly raised.

Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid physical strain. Depending on the victim's condition: doctor/hospital. Call a physician immediately.

First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service.

First-aid measures after skin contact : Wash immediately with lots of water (15 minutes)/shower. Remove clothing while washing. Do not remove clothing if it sticks to the skin. Cover wounds with sterile bandage. Consult a doctor/medical service. If burned surface > 10%: take victim to hospital. Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Call a physician immediately.

First-aid measures after eye contact : Rinse immediately with plenty of water for 15 minutes. Do not apply neutralizing agents. Take victim to an ophthalmologist. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician immediately.

First-aid measures after ingestion : Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do not induce vomiting. Do not give activated charcoal. Do not give chemical antidote. Immediately consult a doctor/medical service. Call Poison Information Centre (www.big.be/antigif.htm). Ingestion of large quantities: immediately to hospital. Take the container/vomit to the doctor/hospital. Rinse mouth. Do not induce vomiting. Call a physician immediately.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms/injuries after inhalation : Dry/sore throat. Coughing. Irritation of the respiratory tract. Irritation of the nasal mucous membranes. EXPOSURE TO HIGH CONCENTRATIONS: Possible laryngeal spasm/oedema.

Risk of lung oedema. Respiratory difficulties.

Symptoms/injuries after skin contact : Caustic burns/corrosion of the skin. Burns.

Symptoms/injuries after eye contact : Corrosion of the eye tissue. Permanent eye damage. Serious damage to eyes.

Symptoms/injuries after ingestion : Vomiting. Burns to the gastric/intestinal mucosa. Possible esophageal perforation. Bleeding of the gastrointestinal tract. Shock. Disturbances of consciousness. FOLLOWING SYMPTOMS MAY APPEAR LATER: Tumours of the gastrointestinal tract. Burns.

Chronic symptoms : ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Fall of hair. Skin rash/inflammation.

Gastrointestinal complaints.

4.3. Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Adapt extinguishing media to the environment. Water spray. Dry powder. Foam. Carbon dioxide.

Unsuitable extinguishing media : No unsuitable extinguishing media known.

5.2. Special hazards arising from the substance or mixture

Fire hazard : DIRECT FIRE HAZARD. Non combustible. INDIRECT FIRE HAZARD. Reactions involving a fire hazard: see "Reactivity Hazard".

Explosion hazard : INDIRECT EXPLOSION HAZARD. Reactions with explosion hazards: see "Reactivity Hazard".

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Reactivity : On burning: release of toxic and corrosive gases/vapours (chlorine, hydrogen chloride).

Decomposes slowly on exposure to air: oxidation which increases fire hazard and release of toxic and corrosive gases/vapours (chlorine). This reaction is accelerated on exposure to light, on exposure to temperature rise and on exposure to (some) metals. Reacts violently with (some) acids/bases: release of toxic and corrosive gases/vapours (chlorine).

5.3. Advice for firefighters

Precautionary measures fire : Exposure to fire/heat: consider evacuation.

Firefighting instructions : Cool tanks/drums with water spray/remove them into safety. Do not move the load if exposed to heat. Dilute toxic gases with water spray. Take account of toxic fire-fighting water. Use water moderately and if possible collect or contain it.

Protection during firefighting : Heat/fire exposure: compressed air/oxygen apparatus. Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

Protective equipment : Gloves. Face-shield. Corrosion-proof suit. Large spills/in enclosed spaces: compressed air apparatus. Large spills/in enclosed spaces: gas-tight suit. Reactivity hazard: compressed air/oxygen apparatus. Reactivity hazard: gas-tight suit. See "Material-Handling" to select protective clothing.

Emergency procedures : Ventilate spillage area. Keep upwind. Mark the danger area. Seal off low-lying areas. Close doors and windows of adjacent premises. No naked flames. Wash contaminated clothes. Large spills/in confined spaces: consider evacuation. In case of reactivity hazard: consider evacuation. Avoid contact with skin and eyes. Do not breathe fume, vapors.

6.1.2. For emergency responders

Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection".

6.2. Environmental precautions

Avoid release to the environment. Prevent soil and water pollution. Prevent spreading in sewers.

6.3. Methods and material for containment and cleaning up

For containment : Contain released substance, pump into suitable containers. Consult "Material-handling" to select material of containers. Plug the leak, cut off the supply. Dam up the liquid spill. If reacting: dilute toxic gas/vapour with water spray. Take account of toxic/corrosive precipitation water. Heat exposure: dilute toxic gas/vapour with water spray. Collect spillage.

Methods for cleaning up : Take up liquid spill into absorbent material. Liquid spill: neutralize. Take up liquid spill into a non combustible material e.g.: sand, earth, vermiculite. Scoop absorbed substance into closing containers. See "Material-handling" for suitable container materials. Spill must not return in its original container. Damaged/cooled tanks must be emptied. Carefully collect the spill/leftovers.

Clean contaminated surfaces with an excess of water. Take collected spill to manufacturer/competent authority. Wash clothing and equipment after handling.

Other information : Dispose of materials or solid residues at an authorized site.

6.4. Reference to other sections

For further information refer to section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Ensure good ventilation of the work station. Comply with the legal requirements. Remove contaminated clothing immediately. Clean contaminated clothing. Keep the substance free from contamination. Thoroughly clean/dry the installation before use. Do not discharge the waste into the drain. Keep away from naked flames/heat. Observe strict hygiene. Keep container tightly closed. Measure the concentration in the air regularly. Carry operations in the open/under local exhaust/ventilation or with respiratory protection. Avoid contact with skin and eyes. Do not breathe fume, vapors. Wear personal protective equipment.

Hygiene measures : Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product.

Always wash hands after handling the product.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions : Store locked up. Store in a well-ventilated place. Keep cool.

Heat-ignition : KEEP SUBSTANCE AWAY FROM: heat sources.

05/27/2015 EN (English US) SDS ID: 8080 4/1

Prohibitions on mixed storage : KEEP SUBSTANCE AWAY FROM: reducing agents. (strong) acids. (strong) bases. metals.

organic materials.

Storage area : Store in a cool area. Keep out of direct sunlight. Store in a dry area. Store in a dark area. Keep locked up. Provide for a tub to collect spills. Unauthorized persons are not admitted. Keep only in the original container. Meet the legal requirements.

Special rules on packaging : SPECIAL REQUIREMENTS: closing. clean. opaque. correctly labelled. meet the legal requirements. Secure fragile packagings in solid containers.

Packaging materials : SUITABLE MATERIAL: synthetic material. polyethylene. glass. stoneware/porcelain.

MATERIAL TO AVOID: aluminium. zinc.

7.3. Specific end use(s)

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

ACGIH ACGIH TWA (ppm) 0.50 ppm

ACGIH ACGIH STEL (ppm) 1 ppm

ACGIH Remark (ACGIH) URT & eye irr

OSHA OSHA PEL (Ceiling) (mg/m³) 3 mg/m³

OSHA OSHA PEL (Ceiling) (ppm) 1 ppm

8.2. Exposure controls

Appropriate engineering controls : Ensure good ventilation of the work station.

Materials for protective clothing : GIVE EXCELLENT RESISTANCE: No data available. GIVE GOOD RESISTANCE: neoprene.

PVC. GIVE LESS RESISTANCE: No data available. GIVE POOR RESISTANCE: No data available.

Hand protection : Gloves.

Eye protection : Face shield. Safety glasses.

Skin and body protection : Corrosion-proof clothing.

Respiratory protection : Wear gas mask with filter type B if conc. in air > exposure limit. High vapour/gas concentration:

self-contained respirator.

Environmental exposure controls : Avoid release to the environment.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Liquid

Appearance : Liquid.

Color : Light green-yellow

Odor : Irritating/pungent odour Characteristic odour

Odor threshold : No data available pH : 13.5 (15 %) pH solution : 15 %

Melting point : Not applicable

Freezing point : No data available

Boiling point : No data available

Flash point : Not applicable

Relative evaporation rate (butyl acetate=1) : No data available

Flammability (solid, gas) : No data available

Explosion limits : No data available

Explosive properties : No data available

Oxidizing properties : No data available

Vapor pressure : 17 hPa

Relative density : 1.2

Relative vapor density at 20 °C : No data available

Specific gravity / density : 1230 kg/m³

05/27/2015 EN (English US) SDS ID: 8080 5/1

Molecular mass : 74.44 g/mol

Solubility : Soluble in water.

Log Pow : No data available

Log Kow : No data available

Auto-ignition temperature : No data available

Decomposition temperature : > 40 °C

Viscosity : No data available

Viscosity, kinematic : No data available

Viscosity, dynamic : 0.0027 Pa.s (20 °C)

9.2. Other information

VOC content : Not applicable

Other properties : Gas/vapour heavier than air at 20°C. Clear. Substance has basic reaction.

SECTION 10: Stability and reactivity

10.1. Reactivity

On burning: release of toxic and corrosive gases/vapours (chlorine, hydrogen chloride). Decomposes slowly on exposure to air: oxidation which increases fire hazard and release of toxic and corrosive gases/vapours (chlorine). This reaction is accelerated on exposure to light, on exposure to temperature rise and on exposure to (some) metals. Reacts violently with (some) acids/bases: release of toxic and corrosive gases/vapours (chlorine).

10.2. Chemical stability

Unstable on exposure to light.

10.3. Possibility of hazardous reactions

No dangerous reactions known under normal conditions of use.

10.4. Conditions to avoid

None under recommended storage and handling conditions (see section 7).

10.5. Incompatible materials

10.6. Hazardous decomposition products

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified

LD50 oral rat > 5000 mg/kg (Rat; Literature study)

LD50 dermal rabbit > 10000 mg/kg (Rabbit; Literature study)

Skin corrosion/irritation : Causes severe skin burns and eye damage.

pH: 13.5 (15 %)

Serious eye damage/irritation : Causes serious eye damage.

pH: 13.5 (15 %)

Respiratory or skin sensitization : Not classified

Germ cell mutagenicity : Not classified

Carcinogenicity : Not classified

IARC group 3 - Not classifiable

Reproductive toxicity : Not classified

Specific target organ toxicity (single exposure) : Not classified

Specific target organ toxicity (repeated exposure)

: Not classified

Aspiration hazard : Not classified

05/27/2015 EN (English US) SDS ID: 8080 6/1

Symptoms/injuries after inhalation : Dry/sore throat. Coughing. Irritation of the respiratory tract. Irritation of the nasal mucous membranes. EXPOSURE TO HIGH CONCENTRATIONS: Possible laryngeal spasm/oedema.

Risk of lung oedema. Respiratory difficulties.

Symptoms/injuries after skin contact : Caustic burns/corrosion of the skin. Burns.

Symptoms/injuries after eye contact : Corrosion of the eye tissue. Permanent eye damage. Serious damage to eyes.

Symptoms/injuries after ingestion : Vomiting. Burns to the gastric/intestinal mucosa. Possible esophageal perforation. Bleeding of the gastrointestinal tract. Shock. Disturbances of consciousness. FOLLOWING SYMPTOMS MAY APPEAR LATER: Tumours of the gastrointestinal tract. Burns.

Chronic symptoms : ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Fall of hair. Skin rash/inflammation.

Gastrointestinal complaints.

SECTION 12: Ecological information

12.1. Toxicity

Ecology - general : Classification concerning the environment: not applicable. Very toxic to aquatic life.

Ecology - air : Not classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009).

Ecology - water : Contains ground water contaminating component(s). Maximum concentration in drinking water:

200 mg/l (sodium) (Directive 98/83/EC). Highly toxic to fishes. pH shift.

LC50 fish 1 > 0.20 mg/l (96 h; Pimephales promelas; Solution <50%)

12.2. Persistence and degradability

Persistence and degradability Biodegradability: not applicable. Low potential for adsorption in soil.

Biochemical oxygen demand (BOD) Not applicable

Chemical oxygen demand (COD) Not applicable

ThOD Not applicable

BOD (% of ThOD) Not applicable

12.3. Bioaccumulative potential

Bioaccumulative potential Bioaccumulation: not applicable.

12.4. Mobility in soil

Ecology - soil May be harmful to plant growth, blooming and fruit formation.

12.5. Other adverse effects

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions.

Waste disposal recommendations : Remove waste in accordance with local and/or national regulations. Hazardous waste shall not be mixed together with other waste. Different types of hazardous waste shall not be mixed together if this may entail a risk of pollution or create problems for the further management of the waste. Hazardous waste shall be managed responsibly. All entities that store, transport or handle hazardous waste shall take the necessary measures to prevent risks of pollution or damage to people or animals. Remove for physico-chemical/biological treatment. May be discharged to company wastewater treatment plant.

Additional information : LWCA (the Netherlands): KGA category 02. Hazardous waste according to Directive

2008/98/EC.

SECTION 14: Transport information

Department of Transportation (DOT)

In accordance with DOT

Transport document description : UN1791 Hypochlorite solutions, 8, II

UN-No.(DOT) : UN1791

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Proper Shipping Name (DOT) : Hypochlorite solutions

Transport hazard class(es) (DOT) : 8 - Class 8 - Corrosive material 49 CFR 173.136

Hazard labels (DOT) : 8 - Corrosive

Packing group (DOT) : II - Medium Danger

Dangerous for the environment : Yes

Marine pollutant : Yes

DOT Packaging Non Bulk (49 CFR 173.xxx) : 202

DOT Packaging Bulk (49 CFR 173.xxx) : 242

DOT Special Provisions (49 CFR 172.102) : A7 - Steel packaging must be corrosion-resistant or have protection against corrosion.

B2 - MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks are not authorized.

B15 - Packaging must be protected with non-metallic linings impervious to the lading or have a suitable corrosion allowance.

IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.

IP5 - IBCs must have a device to allow venting. The inlet to the venting device must be located in the vapor space of the IBC under maximum filling conditions.

N34 - Aluminum construction materials are not authorized for any part of a packaging which is normally in contact with the hazardous material.

T7 - 4 178.274(d)(2) Normal............. 178.275(d)(3) TP2 - a. The maximum degree of filling must not exceed the degree of filling determined by the following: (image) Where: tr is the maximum mean bulk temperature during transport, tf is the temperature in degrees celsius of the liquid during filling, and a is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and the maximum mean bulk temperature during transportation (tr) both in degrees celsius. b. For liquids transported under ambient conditions may be calculated using the formula: (image) Where: d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 C (59 F) and 50 C (122 F), respectively.

TP24 - The portable tank may be fitted with a device to prevent the build up of excess pressure due to the slow decomposition of the hazardous material being transported. The device must be in the vapor space when the tank is filled under maximum filling conditions. This device must also prevent an unacceptable amount of leakage of liquid in the case of overturning.

DOT Packaging Exceptions (49 CFR 173.xxx) : 154

DOT Quantity Limitations Passenger aircraft/rail

(49 CFR 173.27)

: 1 L

DOT Quantity Limitations Cargo aircraft only (49

CFR 175.75)

: 30 L

DOT Vessel Stowage Location : B - (i) The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and (ii) ‘‘On deck only’’ on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded.

DOT Vessel Stowage Other : 26 - Stow ‘‘away from’’ acids

Additional information

Other information : No supplementary information available.

ADR

Transport document description : UN 1791, 8, III, (E)

Packing group (ADR) : III

Class (ADR) : 8 - Corrosive substances

Hazard identification number (Kemler No.) : 80

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Classification code (ADR) : C9

Hazard labels (ADR) : 8 - Corrosive substances

Orange plates :

Tunnel restriction code (ADR) : E

Transport by sea

UN-No. (IMDG) : 1791

Proper Shipping Name (IMDG) : HYPOCHLORITE SOLUTION

Class (IMDG) : 8 - Corrosive substances

Packing group (IMDG) : II - substances presenting medium danger

EmS-No. (1) : F-A

EmS-No. (2) : S-B

Air transport

UN-No. (IATA) : 1791

Proper Shipping Name (IATA) : Hypochlorite solution

Class (IATA) : 8 - Corrosives

Packing group (IATA) : III - Minor Danger

SECTION 15: Regulatory information

15.1. US Federal regulations

Listed on the United States TSCA (Toxic Substances Control Act) inventory Not listed on the United States SARA Section 313

RQ (Reportable quantity, section 304 of EPA's List of Lists) 100 lb

15.2. International regulations

CANADA

EU-Regulations

Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin Corr. 1B H314

Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] C; R34 R31

Full text of R-phrases: see section 16

National regulations

15.3. US State regulations

LIQUID CHLORINE()

State or local regulations U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List

05/27/2015 EN (English US) SDS ID: 8080 9/1

SECTION 16: Other information

Full text of H-phrases:

------ Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category 1

------ Eye Dam. 1 Serious eye damage/eye irritation Category 1

------ Skin Corr. 1A Skin corrosion/irritation Category 1A

------ H314 Causes severe skin burns and eye damage

------ H318 Causes serious eye damage

------ H400 Very toxic to aquatic life

NFPA health hazard : 3 - Short exposure could cause serious temporary or residual injury even though prompt medical attention was given.

NFPA fire hazard : 0 - Materials that will not burn.

NFPA reactivity : 2 - Normally unstable and readily undergo violent decomposition but do not detonate. Also: may react violently with water or may form potentially explosive mixtures with water.

SDS US (GHS HazCom 2012)

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product