02_41_00_MSDS_FOR_v-766e_Gray_Vinyl_.AMEND_0003.pdf

HMIS Codes Health 2*

Flammability 3 Reactivity 0

DATE OF PREPARATION

Jul 11, 2012

MATERIAL SAFETY DATA SHEET

B64A300 10 00

SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NUMBER

B64A300

PRODUCT NAME

Corps of Engineers Formula V-766E Vinyl Topcoat Impacted Immersion Coating, Gray

MANUFACTURER'S NAME

THE SHERWIN-WILLIAMS COMPANY

101 Prospect Avenue N.W.

Cleveland, OH 44115

Telephone Numbers and Websites Product Information (800) 524-5979

Regulatory Information (216) 566-2902 www.paintdocs.com

Medical Emergency (216) 566-2917 Transportation Emergency* (800) 424-9300 for Chemical Emergency ONLY (spill, leak, fire, exposure, or * accident)

SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS

% by Weight CAS Number Ingredient Units Vapor Pressure 35 108-88-3 Toluene

ACGIH TLV 20 PPM 22 mm OSHA PEL 100 ppm (Skin) OSHA PEL 150 ppm (Skin) STEL

32 108-10-1 Methyl Isobutyl Ketone ACGIH TLV 50 PPM 16 mm

ACGIH TLV 75 PPM STEL

OSHA PEL 50 PPM

OSHA PEL 75 PPM STEL

13 13463-67-7 Titanium Dioxide ACGIH TLV 10 mg/m3 as Dust OSHA PEL 10 mg/m3 Total Dust OSHA PEL 5 mg/m3 Respirable Fraction

0.4 1333-86-4 Carbon Black

ACGIH TLV 3.5 MG/M3

OSHA PEL 3.5 MG/M3

SECTION 3 — HAZARDS IDENTIFICATION

ROUTES OF EXPOSURE

INHALATION of vapor or spray mist.

EYE or SKIN contact with the product, vapor or spray mist.

EFFECTS OF OVEREXPOSURE

EYES: Irritation.

SKIN: Prolonged or repeated exposure may cause irritation.

INHALATION: Irritation of the upper respiratory system.

May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death.

Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems:

the liver the urinary system the cardiovascular system the reproductive system

SIGNS AND SYMPTOMS OF OVEREXPOSURE

Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists.

Redness and itching or burning sensation may indicate eye or excessive skin exposure.

B64A300

UEL

7.5

LEL

1.0

FLASH POINT

50 °F PMCC

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE

None generally recognized.

CANCER INFORMATION

For complete discussion of toxicology data refer to Section 11.

SECTION 4 — FIRST AID MEASURES

EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention.

SKIN: Wash affected area thoroughly with soap and water.

Remove contaminated clothing and launder before re-use.

INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet.

INGESTION: Do not induce vomiting. Get medical attention immediately.

SECTION 5 — FIRE FIGHTING MEASURES

FLAMMABILITY CLASSIFICATION

RED LABEL -- Flammable, Flash below 100 °F (38 °C)

EXTINGUISHING MEDIA

Carbon Dioxide, Dry Chemical, Foam

UNUSUAL FIRE AND EXPLOSION HAZARDS

Closed containers may explode when exposed to extreme heat.

Application to hot surfaces requires special precautions.

During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention.

SPECIAL FIRE FIGHTING PROCEDURES

Full protective equipment including self-contained breathing apparatus should be used.

Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat.

SECTION 6 — ACCIDENTAL RELEASE MEASURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED

Remove all sources of ignition. Ventilate the area.

Remove with inert absorbent.

SECTION 7 — HANDLING AND STORAGE

STORAGE CATEGORY

DOL Storage Class IB

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE

Contents are FLAMMABLE. Keep away from heat, sparks, and open flame.

During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition.

Consult NFPA Code. Use approved Bonding and Grounding procedures.

Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally.

Keep out of the reach of children.

SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION

PRECAUTIONS TO BE TAKEN IN USE

Use only with adequate ventilation.

Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.

Wash hands after using.

This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction).

VENTILATION

Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108.

RESPIRATORY PROTECTION

If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2.

When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive.

PROTECTIVE GLOVES

Wear gloves which are recommended by glove supplier for protection against materials in Section 2.

EYE PROTECTION

Wear safety spectacles with unperforated sideshields.

OTHER PRECAUTIONS

Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal.

SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES

PRODUCT WEIGHT 8.36 lb/gal 1002 g/l

SPECIFIC GRAVITY 1.01

BOILING POINT 222 - 242 °F 105 - 116 °C

MELTING POINT Not Available

VOLATILE VOLUME 80%

EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air

SOLUBILITY IN WATER N.A.

VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)

5.56 lb/gal 666 g/l Less Water and Federally Exempt Solvents

5.56 lb/gal 666 g/l Emitted VOC

SECTION 10 — STABILITY AND REACTIVITY

STABILITY — Stable

CONDITIONS TO AVOID

None known.

INCOMPATIBILITY

None known.

HAZARDOUS DECOMPOSITION PRODUCTS

By fire: Carbon Dioxide, Carbon Monoxide

HAZARDOUS POLYMERIZATION

Will not occur

SECTION 11 — TOXICOLOGICAL INFORMATION

CHRONIC HEALTH HAZARDS

Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage.

IARC's Monograph No. 93 reports there is sufficient evidence of carcinogenicity in experimental rats exposed to titanium dioxide but inadequate evidence for carcinogenicity in humans and has assigned a Group 2B rating. In addition, the IARC summary concludes, "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium is bound to other materials, such as paint."

Carbon Black is classified by IARC as possibly carcinogenic to humans (group 2B) based on experimental animal data, however, there is insufficient evidence in humans for its carcinogenicity.

TOXICOLOGY DATA

CAS No. Ingredient Name 108-88-3 Toluene

LC50 RAT 4HR 4000 ppm LD50 RAT 5000 mg/kg

108-10-1 Methyl Isobutyl Ketone LC50 RAT 4HR Not Available LD50 RAT 2080 mg/kg

13463-67-7 Titanium Dioxide LC50 RAT 4HR Not Available LD50 RAT Not Available

1333-86-4 Carbon Black LC50 RAT 4HR Not Available LD50 RAT Not Available

SECTION 12 — ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION

No data available.

SECTION 13 — DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHOD

Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.

Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers.

Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution.

SECTION 14 — TRANSPORT INFORMATION

Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport.

US Ground (DOT) 5 Liters (1.3 Gallons) and Less may be Classed as LTD. QTY. OR ORM-D Larger Containers are Regulated as:

UN1263, PAINT, 3, PG II, (ERG#128)

DOT (Dept of Transportation) Hazardous Substances & Reportable Quantities Methylisobutyl ketone 5000 lb RQ Toluene 1000 lb RQ

Bulk Containers may be Shipped as (check reportable quantities):

UN1263, PAINT, 3, PG II, (ERG#128)

Canada (TDG)

UN1263, PAINT, CLASS 3, PG II, (ERG#128)

IMO

5 Liters (1.3 Gallons) and Less may be Shipped as Limited Quantity.

UN1263, PAINT, CLASS 3, PG II, (10 C c.c.), EmS F-E, S-E, ADR (D/E)

IATA/ICAO

UN1263, PAINT, 3, PG II

SECTION 15 — REGULATORY INFORMATION

SARA 313 SUPPLIER NOTIFICATION(40 CFR 372.65C)

CAS No. CHEMICAL/COMPOUND % by WT % Element 108-88-3 Toluene 35 108-10-1 Methyl Isobutyl Ketone 32

CALIFORNIA PROPOSITION 65

WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.

TSCA CERTIFICATION

All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory.

SECTION 16 — OTHER INFORMATION

This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.

The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information.