21.2.1.A - Exhibit A - Profile Waste Streams - 8-27-2023.pdf

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NREL: HAZARDOUS WASTE COLLECTION SERVICES: REGULATED WASTE PACKAGING, TRANSPORTATION, AND DISPOSAL/RECYCLING
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RFP-2023-23073
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This document profiles over 80 waste streams generated at the National Renewable Energy Laboratory. It provides detailed descriptions of each waste stream including constituents, container sizes, hazard classifications, and regulatory status.

The related federal contract opportunity is a solicitation from the Department of Energy Office of Science seeking hazardous waste collection, packaging, transportation, and disposal/recycling services. It involves the regular collection and proper handling of a wide variety of hazardous, non-hazardous, and recyclable waste streams outlined in the exhibit. Key waste streams include solvents, heavy metals, acids, bases, flammable and toxic chemicals, contaminated equipment and materials. Offerors should demonstrate the ability to manage these various waste types in compliance with all applicable regulations.

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EXHIBIT A - PROFILE WASTE STREAMS 8-27-2023

Profile Description Constituents Container Size(s) RCRA / Non-RCRA RCRA Code(s)

Catalyst Contaminated Lab Debris

Kimwipes, nitrile gloves, paper, weighboats, plastic pipette tips contaminated ruthinium on carbon catalyst, platinum on carbon catalyst, paladium, nickel, and molybdenum oxides 5, 15, 30, 55-gal RCRA D001

F131 Distillation Cleaning Solution Ethanol (90-100%), Methyl Isobutyl Ketone (1-5%), Wood Oil (1-5%) 30, 55-gal RCRA D001

Consolidated Inorganic Acids Hydrochloric Acid, Sulfuric Acid, Dilute Nitric Acid, Boric Acid, Fluorboric Acid, Water 30, 55-gal RCRA D002

Consolidated Inorganic Bases Potassium Hydroxide, Sodium Hydroxide Ammonium Hydroxide, Water 30, 55-gal RCRA D002

PGM Ink Waste Water (15-25%), 2-propanol (15-30%), 1-propanol (15-25%), Iridium Oxide (1-5%), Nafion (1-5%), Platinum (1-5%), Spent Carbon (1-5%) 15, 30, 55-gal RCRA D001

Cadmium Contaminated PPE Kimwipes, nitrile gloves, paper, weighboats, plastic pipette tips, sticky mats contaminated with cadmium 30, 55-gal RCRA D006

Gasoline Contaminated Media Soil, PPE, Booms, Pig Mats contaminated with gasoline (spill cleanup) 30, 55-gal RCRA D018

KOH Contaminated Equipment Plastic tubing and trays, small metal fittings, PPE, metal Unistrut contaminated with dry potassium hydroxide residue 55-gal Non-RCRA n/a

F131 Distillation Process Water

Water (80-95%), Acetic Acid (0-10%), Hydroxyacetone (0-5%), n-Butyl Acetate (0-1.5%), Glycolaldehyde (0-1%), n-Butyl Alcohol (0-0.5%), Furfural (0-0.1%) 55-gal Non-RCRA n/a

Arsine Scrubber Canister Non-pressurized arsine gas abatement canister with arsenic contaminated granular media DOT-rated vessel (approx 55-gal) RCRA D004

Potassium Nitrate and Sodium Nitrate Mixture Solid potassium nitrate (40%), sodium nitrate (60%), sand yd3 RCRA D001

EC329 Aqueous Waste Isopropyl alcohol (10%), -phenylene diamine (5%), dionized water (85%), polysulfone (trace), 1-methyl-2-pyrrolidine (trace) 30-gal Non-RCRA n/a

0.2 Hydrogen Selenide Balance Hydrogen CYME 0.2% hydrogen selenide balance hydrogen CYME RCRA D001, D010

CIGS Cluster Tool and Gatan Milling Tool

Research equipment (stainless steel bell jar, steel tubing) with internal contamination (copper, indium, gallium, selenium, gallium arsenide, silver, platinum, paladium, cadmium sulfide, cadmium stannate, zinc stannate, cadmium telluride) yd3, roll off RCRA D004, D006, D010, D011

Neutracit Caustic Neutralizer (solid) Citric acid (65-80%), Perilite (9%), silica, amorphous (2%) 55-gal Non-RCRA n/a

Neutrasorb Acid Neutralizer Sodium carbonate (35-55%), magnesium oxide (25-45%), calcium carbonate (5-25%) 55-gal Non-RCRA n/a

Glycol and Water Ethylene glycol and water 15,30, 55-gal, 275-gal IBC Non-RCRA n/a

WAZER Water / Water and Synthetic Metalworking Fluid

Water (75-90%), alkanolamine (2-5%), aluminum, steel, stainless steel, copper particulate (1-2%), mineral garnet particulate (1-2%), plastic particulate (1-2%), synthetic metal cutting fluid (0-5%) 55-gal Non-RCRA n/a

Luperox Solids Empty metal cans, rags, clay absorbent with residues of Arkema Luperox AFR40 30, 55-gal Non-RCRA n/a

Carbon Tetrabromide Bubbler Carbon tetrabromide 100 grams non-pressurized stainless steel vessel in 5-gal pail Non-RCRA n/a

Triethylboron Bubbler Triethylboron, 100 grams non-pressurized stainless steel vessel in 5-gal pail RCRA D001, D003

Trimethylaluminum Bubbler Trimethylaluminum, 100 grams non-pressurized stainless steel vessel in 5-gal pail RCRA D001, D003

Dimethylhydrazine Bubbler Dimethylhydrazine, 809 grams non-pressurized stainless steel vessel in 5-gal pail RCRA D001, D002, U098

Diethylzinc Bubbler Diethylzinc, 100 grams non-pressurized stainless steel vessel in 5-gal pail RCRA D001, D003

STF 140 Belljar Stainless steel bell jar with trace sulfur residue yd3 Non-RCRA n/a

Diesel and Water Diesel fuel (80-100%), water (0-20%) 55-gal Non-RCRA n/a

NR Metals and Glass

Stainless steel and/or copper tubing, metal research and development reactor components, glass substrates, labware containing or contaminated with aluminum oxide, titanium dioxide, ruthenium oxide, palladium oxide, zirconium oxide, molybdenum, tungsten, nickel, platinum 30, 55-gal, yd3 Non-RCRA n/a

Biomethane Fermentation Broth

Distilled water (90-99%), Nutrient feed comprised of (concentrations in mmol/L): potassium dihydrogen phosphate (10), sodium chloride (10), magnesium chloride (1), sodium nitrilotriacetate (0.8), nitriloacetic acid (0.4), L-cysteine (0.5), iron sulfate (0.2), sodium tungstate (0.01), nickel chloride (0.005), cobalt chloride (0.003), sodium molybdate (0.003), Resazurin sodium salt (0.002), sodium selenite (0.001), M.

thermautotrophicus bacteria (killed/deactivated) 275-gal IBC Non-RCRA n/a

Solid Catalyst Waste Aluminum Oxide, Nickel Oxide, Zeolite Catalyst 15, 30, 55-gal Non-RCRA n/a Silver Laden Glass Mirrors 55-gal, yd3 RCRA D011

F207 TOC Waste

Water (75-90%), 1000 ppm potassium hydrogen phthalate (1-10%), 1000 ppm sodium bicarbonate (1-10%), 1000 ppm sodium carbonate (1- 10%), hydrochloric acid (0-1%), phosphoric acid (0-1%), sulfuric acid (0- 1%), 1000 potassium nitrate (1-10%), live microbes (Biosafety Level 1:

algal cultures and macroalgae harvested from fish digestive tract) 5-gal RCRA D002

NR Hydrated Lime (pH = 12) Calcium hydroxide; slaked lime;hydrated lime (25-50%), crystalline silica (0-0.1%), water 50-75% 275-gal IBC Non-RCRA n/a

Arkema Elium 188 Methyl methacrylate (50-55%), acrylic coplymers (10-50%), 2,6- Octandienal, 3,7-dimethyl- (1-5%) 55-gal RCRA D001

Rock and Sand Contaminated with Mineral Oil 55-gal Non-RCRA n/a

Soil and PPE Contaminated with Electrolyte

Soil, PPE, Booms, Pig Mats contaminated with battery electrolyte (vanadyl sulphate, divanadium sulphate, sulfuric acid, water (spill cleanup) 55-gal Non-RCRA n/a

Lead Perovskite Waste

Kimwipes, nitrile gloves, paper, weighboats, plastic pipette tips, cotton swabs, tape, plastic/glass jars and vials contaminated with dimethylformamide, isopropyl alcohol, lead iodide, lead bromide, lead chloride, methylammonium iodide, cesium iodide, copper gallium oxide, copper oxide, acetonitrile 30, 55-gal RCRA D008

Flow Battery Electrolyte Vanadyl sulphate (12-17%), divanadium sulphate (12-17%), sulphuric acid (9-16%), balance water 275-gal IBC RCRA D002

3D Printer Cleaning Bath

Sodium percarbonate (20-25%), sodium carbonate (8-15%), tetrasodium N,N-bis(carboxylatomethyl)-L-Glutamate (5-10%), citric acid (5-10%), water (15-20%), dissolved plastic (5-20%), mineral oil (5- 10%), benzene (1-5%), N-butyl acrylate (1-5%) 55-gal RCRA D002, D018

Steel Chambers with Internal Silver Contamination metal chambers with minimum dimensions of 12"x12"x12" yd3 RCRA D011

Acidic Pretreated Biomass Samples

Biomass (corn stover, sorghum, bagasse, etc) samples in sulfuric acid pretreatment solution with sugars and lignins contained in vials, jars, and Falcon Tubes 30, 55-gal RCRA D002

ESIF C321 PGM

Water (50-70%), nitrile gloves, kimwipes, sample vials, plastic pipette tips contaminated with used platinum, carbon, cobalt, iridium oxide (25-50%), ethanol, n-propanol, 2-propanol, Nafion fluid (2-5%) 30-gal Non-RCRA n/a

Therminol 62 Heat Transfer Fluid Diisopropybiphenyl (70-85%), triisopropylbiphenyl (10-25%) 55-gal Non-RCRA n/a

Zirconium Tertiary Butoxide Bubbler zirconium (IV) tertiary-butoxide, 100 grams non-pressurized stainless steel vessel in 5-gal pail RCRA D001, D003

Contaminated Bead Blaster Metal Table top bead blaster metal sheets contaminated with cadmium, tellurium, and dry sulfuric acid residue yd3 RCRA D006

Milled Oak Wood milled wood (Oak) - carcinogen 55-gal Non-RCRA n/a

Passivated Biochar wood based carbon, fixed (75-85%), wood based ash (3-8%), absorbed water (1-3%) 55-gal Non-RCRA n/a

Epikote Resin MGS RIMR 135 Hexion Epikote Resin with epoxide derivatives and 1,6-hexanediol diglycidyl ether 5, 55-gal Non-RCRA n/a

Epikure Curing Agent MGS RIMH 1366 alkyletheramine (50-70%), cycloaliphatic amine (30-50%), ethyleneamine (5-10%) 5, 55-gal RCRA D002

Granular Citric Acid 55-gal Non-RCRA n/a

Metal Contaminated with Sodium Bicarbonate_Neutralized Sulfuric Acid yd3 Non-RCRA n/a Elemental Mercury elemental mercury in various sized containers 5-gal RCRA D009 Mercury-Containing Schlenk Lines elemental mercury -containing apparatus 55-gal RCRA D009 Activated Alumina aluminum oxide (80-100%) 55-gal Non-RCRA n/a

Solids with Trace Mercury PPE (30%), cardboard boxes (30%), plastic bags (10%), HEPA vacuum with trace mercury contamination 20,30,55-gal RCRA D009

Antifreeze used antifreeze 55-gal Non-RCRA n/a

HPLC LCMS 140

Consolidated HPLC/LCMS output: 0.01N sulfuric acid (15-25%), water (50-75%), 0.1% acetic acid (1-3%), formic acid (1-3%), 4mM ammonium formate (5-10%), biomass hydrolysate (5-10%), acetonitrile (0-1%), methanol (0-3%), tetrahydrofuran (0-1%), ethanol (0-3%) 30-gal RCRA D002

F140 CLB

Consolidated laboratory analytical equipment output: sodium hydroxide (10-20%), potassium hydroxide (10-20%), sodium acetate (1- 10%), water (40-60%), biomass hydrolysate (5-20%) 30-gal RCRA D002

Chemical Fume Hoods Contaminated with RCRA Metals Disassembled chemical fume hoods roll off RCRA D004, D006, D008, D010 Gasoline Bad gas 10,30, 55-gal RCRA D001, D018 Acetone Wash Acetone (70-95%), water (0-10%), traces of resins (0-5%) 20,30,55-gal RCRA D001

Sodium Hydroxide with Pyrolysis Oil Sodium hydroxide (5-15%), pyrolysis oil (1-10%), water (75-90%) 30,55-gal RCRA D002 Quartz Glass with Thallium broken quartz tubes and glass contaminated with thallium 30,55-gal Non-RCRA n/a Ventilation Ducting Contaminated with RCRA Metals metal ventilation ducting 6" to 36" diameter 55-gal, yd3 RCRA D004, D006, D008, D010 Diesel Contaminated Soil and PPE 55-gal Non-RCRA n/a

Metal and Glass Containing RCRA Metals

Glass and metal solar panel components/samples with copper, indium, gallium, selenium, lead, cadmium, tellurium, arsenic, barium compounds. Stainless steel tubing, vessels, components with nickel, chrome, platinum catalyst residues 55-gal, yd3 RCRA

D004, D005, D006, D007, D008, D010

Vacuum Pumps with Internal Contamination Drained vacuum pumps with internal contamination 55-gal, yd3 RCRA D004, D006, D007, D008, D010

Sharps Contaminated with RCRA Metals Needles, metal syringe tips, razor blades contaminated with arsenic, cadmium, chromium, lead, selenium compounds

5,15-gal (material contained in sharps containers) RCRA D004, D006, D007, D008, D010

Oily Water 55-gal Non-RCRA n/a Chemical Glovebox Contaminated with RCRA Metals yd3, roll off RCRA D004, D006, D008, D010 Biodiesel and Diesel Fuel Blend fp<140 F 30,55-gal RCRA D001 Biodiesel and Diesel Fuel Blend fb=>141 F 30,55-gal Non-RCRA n/a Sugarcane Bagasse for Incineration Incineration in accordance with APHIS permit 30,55-DF,yd3 Non-RCRA n/a Sugarcane Bagasse for Certified Landfill Certified landfill in accordance with APHIS permit roll off Non-RCRA n/a

WHF Solids

Plastic bags, wipes, disposable nitrile gloves, Q-tips, plastic pipette tips, paper towels, weigh boats, granular absorbent, glass/plastic bottles, PPE contaminated with or containing residues of: pump oil, titanium dioxide, tin oxide, diesel fuel, ethylene glycol, isopropyl alcohol, latex paint, sulfuric acid, silicon adhesive, photoresist, magnesium chloride, biomass char, grease, pyrolysis oil, spent catalyst (copper, indium, gallium, nickel. aluminum, molybdenum), spent activated carbon, molecular sieves, colloidal silica, epoxy resin, cellulose powder, industrial quartz granules. 55-gal, yd3 Non-RCRA n/a

Water and Simple Green 30,55-gal Non-RCRA n/a

WHF Solvents

Consolidated laboratory solvent waste: acetone (20-40%), methanol (10-20%), ethyl acetate (10-20%), isopropyl alcohol (20-40%), chloroform (0-10%), chlorobenzene (0-10%), ethanol (5-15%), toluene (0-10%), trichloroethylene (0-5%), methylene chloride (2-5%), tetrahydrofuran (0-5%), hexanes (0-5%), ethyl ether (0-1%) 30, 55-gal RCRA D001, D022, F002, F003, F005

Aluminum Oxide / Nickel Oxide Catalyst 30,55-gal Non-RCRA n/a

Flammable Pyrolysis Oil Loosepack Sample vials and jars containing: pyrolysis oil (80-90%), acetone (5- 15%), methanol (5-15%), water (0-10%), sulfuric acid (0-0.1%) 30,55-gal RCRA D001 (F003)

Flammable / Corrosive Pyrolysis Oil Loosepack Sample vials and jars containing: pyrolysis oil (80-90%), acetone (5- 20%), methanol (5-20%), water (0-10%), sulfuric acid (5-10%) 30,55-gal RCRA D001, D002, F003

Non RCRA Regulated Nanomaterial-Bearing Solids for Incineration

Kimwipes, nitrile gloves, paper, weighboats, plastic pipette tips, glass centrifuge tubes, glass substrates contaminated with bound and unbound nanoparticles of silicon, tin, molybdenum, titanium, cobalt, antimony, carbon, copper, indium, gallium, tellurium and organic residues of poly(styrenesulfonate), [6,6]-phenyl C61 butyric acid methyl ester, poly(3,4-ethylenedioxythiophene), pump oil 30,55-gal, yd3 Non-RCRA n/a

RCRA Regulated Nanomaterial-Bearing Solids for Incineration

Kimwipes, nitrile gloves, paper, weighboats, plastic pipette tips, centrifuge tubes and caps contaminated with bound and unbound nanoparticles of lead oxide, cadmium oxide, selenium, tellurium, trioctylphophine, oleic acid, zinc oxide, lead selenide, cadmium selenide, lead sulfide, lead tellurium, chloroform 30,55-gal, yd3 RCRA D006, D008, D010, D022

Solar Panels with RCRA Metals intact and broken solar panels 30,55-gal, yd3, pallet RCRA D004, D006, D010

F131 Non-RCRA Regulated Solids Industiral filters, rags, PPE contamintaed with biomass residues, nickel catalyst, pyrolysis oils 55-gal Non-RCRA n/a

Non RCRA Regulated Nanomaterial-Bearing HEPA Filters for Incineration HVAC HEPA filters with trace nanomaterial contamination: single-walled carbon nanotubes, titanium dioxide, tungsten oxide yd3, pallet, roll off Non-RCRA n/a

Ethylene Glycol / Propylene Glycol Mixtures Ethylene Glycol / Propylene Glycol Mixture with high molybdenum content 15,30,55-gal Non-RCRA n/a

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