PPG Flooring 2550 WB SDS Part A Gray.pdf

2550 WB URETHANE GLOSS GRAY - A

Not available.

Liquid.

SAFETY DATA SHEET

Product name

Other means of identification

Product type

Section 1. Identification

Product code : 00462398

Date of issue/Date of revision 15 January 2024

Version 3

Relevant identified uses of the substance or mixture and uses advised against

Uses advised against Not applicable.

Product use : Industrial applications, Professional applications, Used by spraying.

Use of the substance/ mixture

: Coating.

Manufacturer PPG Industries, Inc.

One PPG Place Pittsburgh, PA 15272

(412) 434-4515 (U.S.)

(514) 645-1320 (Canada) SETIQ Interior de la República: 800-00-214-00 (México) SETIQ Ciudad de México: (55) 5559-1588 (México)

Emergency telephone number

Technical Phone Number : 888-977-4762

Section 2. Hazards identification

CARCINOGENICITY - Category 2Classification of the substance or mixture

GHS label elements

Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 37.9% (oral), 40.2% (dermal), 40.2% (inhalation)

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200).

This product contains TiO2 which has been classified as a GHS Carcinogen Category 2 based on its IARC 2B classification. For many products, TiO2 is utilized as a raw material in a liquid coating formulation. In this case, the TiO2 particles are bound in a matrix with no meaningful potential for human exposure to unbound particles of TiO2 when the product is applied with a brush or roller. Sanding the coating surface or mist from spray applications may be harmful depending on the duration and level of exposure and require the use of appropriate personal protective equipment and/or engineering controls (see Section 8).

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2550 WB URETHANE GLOSS GRAY - AProduct name

3Product code Date of issue Version00462398 15 January 2024

Section 2. Hazards identification

Signal word : Warning

Hazard statements : Suspected of causing cancer.

Hazard pictograms :

Precautionary statements

Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection.

Response : IF exposed or concerned: Get medical advice or attention.

Storage : Store locked up.

Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations.

Supplemental label elements

: Avoid contact with skin and clothing. Wash thoroughly after handling. Emits toxic fumes when heated.

Hazards not otherwise classified

: Prolonged or repeated contact may dry skin and cause irritation.

Section 3. Composition/information on ingredients titanium dioxide ≥5.0 - ≤10 13463-67-7 2,2',2''-nitrilotriethanol ≥1.0 - ≤5.0 102-71-6

Ingredient name CAS number%

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Substance/mixture :

Occupational exposure limits, if available, are listed in Section 8.

Mixture

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

Product name 2550 WB URETHANE GLOSS GRAY - A:

SUB codes represent substances without registered CAS Numbers.

Section 4. First aid measures

Eye contact

Inhalation :

Description of necessary first aid measures

If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of this product, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have Safety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart for at least 10 minutes and seek immediate medical advice.

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

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Section 4. First aid measures Skin contact

Ingestion :

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.

The exposed person may need to be kept under medical surveillance for 48 hours.

Specific treatments : No specific treatment.

Most important symptoms/effects, acute and delayed

Inhalation :

:Ingestion Skin contact :

:Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation No specific data.

No specific data.

Adverse symptoms may include the following:

irritation dryness cracking

Eye contact : No specific data.

Potential acute health effects

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary

Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners.

If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do NOT induce vomiting.

No known significant effects or critical hazards.

No known significant effects or critical hazards.

No known significant effects or critical hazards.

Defatting to the skin. May cause skin dryness and irritation.

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials:

carbon oxides nitrogen oxides metal oxide/oxides

In a fire or if heated, a pressure increase will occur and the container may burst.

Use an extinguishing agent suitable for the surrounding fire.

Extinguishing media

None known.

Suitable extinguishing media

Unsuitable extinguishing media

Special protective actions for fire-fighters

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Section 5. Fire-fighting measures Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

: No action shall be taken involving any personal risk or without suitable training.

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.

Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Large spill :

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Small spill :

Methods and materials for containment and cleaning up

For non-emergency personnel

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".

Section 7. Handling and storage

Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not ingest.

Avoid breathing vapor or mist. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

Precautions for safe handling

Special precautions : If this material is part of a multiple component system, read the Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts.

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Section 7. Handling and storage Advice on general occupational hygiene

Conditions for safe storage, including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Do not store below the following temperature: 5°C (41°F). Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use.

Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

titanium dioxide OSHA PEL (United States, 5/2018).

TWA: 15 mg/m³ 8 hours. Form: Total dust ACGIH TLV (United States, 1/2023).

TWA: 2.5 mg/m³ 8 hours. Form: respirable fraction, finescale particles

2,2',2''-nitrilotriethanol ACGIH TLV (United States, 1/2023).

TWA: 5 mg/m³ 8 hours.

Section 8. Exposure controls/personal protection

Ingredient name Exposure limits

Environmental exposure controls

: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Appropriate engineering controls

: If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.

Control parameters

Individual protection measures

Occupational exposure limits

Recommended monitoring procedures

: Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

Key to abbreviations A Acceptable Maximum Peak=

ACGIH = American Conference of Governmental Industrial Hygienists.

C = Ceiling Limit

Potential skin absorptionS SR = Respiratory sensitization

= Skin sensitizationSS

TD = Total dust

Consult local authorities for acceptable exposure limits.

= Threshold Limit ValueTLV TWA = Time Weighted Average

Fume=F IPEL = Internal Permissible Exposure Limit

= Occupational Safety and Health Administration.OSHA R = Respirable

OSHA 29 CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z

STEL =

Short term Exposure limit values

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Section 8. Exposure controls/personal protection

Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Eye/face protection

Respiratory protection :

Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.

Appropriate techniques should be used to remove potentially contaminated clothing.

Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures :

Skin protection

Other skin protection :

Safety glasses with side shields.

Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary.

The respiratory protection shall be in accordance to 29 CFR 1910.134.

Section 9. Physical and chemical properties

Physical state

Melting point

Vapor pressure

Relative density

Vapor density

Liquid.

Not available.

1.1

Not available.

Not available.

Odorless.Odor pH

Gray.Color

Evaporation rate Not available.

Auto-ignition temperature

Flash point

Not available.

Closed cup: 121.11°C (250°F) [Product does not sustain combustion.]

Not available.

Not available.Odor threshold

Appearance

Boiling point : >37.78°C (>100°F)

Flammability : Not available.

Lower and upper explosive (flammable) limits

: Not available.

Decomposition temperature : Not available.

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Section 9. Physical and chemical properties

Not applicable.

Viscosity Kinematic (40°C (104°F)): >21 mm2/s (>21 cSt)

Partition coefficient: n-octanol/water

% Solid. (w/w) : 45.922

Density ( lbs / gal ) : 9.18

Volatility : 60% (v/v), 54.078% (w/w)

Solubility(ies) :

Media Result cold water Soluble

Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid

The product is stable.Chemical stability :

Incompatible materials :

Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

When exposed to high temperatures may produce hazardous decomposition products.

Keep away from the following materials to prevent strong exothermic reactions:

oxidizing agents, strong alkalis, strong acids.

Refer to protective measures listed in sections 7 and 8.

Depending on conditions, decomposition products may include the following materials:

carbon oxides nitrogen oxides metal oxide/oxides

Section 11. Toxicological information

Acute toxicity titanium dioxide LC50 Inhalation Dusts and mists Rat >6.82 mg/l 4 hours LD50 Dermal Rabbit >5000 mg/kg - LD50 Oral Rat >5000 mg/kg -

2,2',2''-nitrilotriethanol LD50 Oral Rat 7.39 g/kg -

Product/ingredient name Result Species Dose Exposure

Conclusion/Summary :

Irritation/Corrosion

Conclusion/Summary Skin :

Eyes :

Respiratory :

Sensitization

Conclusion/Summary

Information on toxicological effects

There are no data available on the mixture itself.

There are no data available on the mixture itself.

There are no data available on the mixture itself.

There are no data available on the mixture itself.

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Section 11. Toxicological information

Carcinogenicity

Conclusion/Summary :

Mutagenicity

Conclusion/Summary :

Teratogenicity

Conclusion/Summary :

Reproductive toxicity

Conclusion/Summary :

Skin :

Respiratory :

Specific target organ toxicity (single exposure)

Classification titanium dioxide - 2B - 2,2',2''-nitrilotriethanol - 3 -

Product/ingredient name NTPIARCOSHA

Carcinogen Classification code:

IARC: 1, 2A, 2B, 3, 4

NTP: Known to be a human carcinogen; Reasonably anticipated to be a human carcinogen

OSHA: +

Not listed/not regulated: -

There are no data available on the mixture itself.

There are no data available on the mixture itself.

There are no data available on the mixture itself.

There are no data available on the mixture itself.

There are no data available on the mixture itself.

There are no data available on the mixture itself.

Information on the likely routes of exposure

Specific target organ toxicity (repeated exposure)

Aspiration hazard

Not available.

Potential acute health effects

Inhalation : No known significant effects or critical hazards.

No known significant effects or critical hazards.:Ingestion Skin contact : Defatting to the skin. May cause skin dryness and irritation.

No known significant effects or critical hazards.:Eye contact

Over-exposure signs/symptoms

Inhalation No specific data.:

Eye contact : No specific data.

Target organs : Contains material which may cause damage to the following organs: lungs, liver, upper respiratory tract, skin, eye, lens or cornea.

Name

2,2',2''-nitrilotriethanol Category 3 - Respiratory tract irritation

Category Route of exposure

Target organs

Not available.

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Section 11. Toxicological information

Conclusion/Summary :

General :

Carcinogenicity :

Mutagenicity :

Reproductive toxicity :

Potential chronic health effects

Delayed and immediate effects and also chronic effects from short and long term exposure

Numerical measures of toxicity

Acute toxicity estimates

Potential immediate effects

Short term exposure

Potential delayed effects :

Potential immediate effects

Long term exposure

Potential delayed effects :

Skin contact

Ingestion No specific data.

Adverse symptoms may include the following:

irritation dryness cracking

Suspected of causing cancer. Risk of cancer depends on duration and level of exposure.

There are no data available on the mixture itself. This product contains TiO2 which has been classified as a GHS Carcinogen Category 2 based on its IARC 2B classification.

For many products, TiO2 is utilized as a raw material in a liquid coating formulation. In this case, the TiO2 particles are bound in a matrix with no meaningful potential for human exposure to unbound particles of TiO2 when the product is applied with a brush or roller. Sanding the coating surface or mist from spray applications may be harmful depending on the duration and level of exposure and require the use of appropriate personal protective equipment and/or engineering controls (see Section 8). If splashed in the eyes, the liquid may cause irritation and reversible damage. Ingestion may cause nausea, diarrhea and vomiting. This takes into account, where known, delayed and immediate effects and also chronic effects of components from short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.

Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.

No known significant effects or critical hazards.

No known significant effects or critical hazards.

There are no data available on the mixture itself.

There are no data available on the mixture itself.

There are no data available on the mixture itself.

There are no data available on the mixture itself.

Product/ingredient name

2,2',2''-nitrilotriethanol 7390 N/A N/A N/A N/A

Oral (mg/ kg)

Dermal (mg/kg)

Inhalation (gases) (ppm)

Inhalation (vapors) (mg/l)

Inhalation (dusts and mists) (mg/ l)

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Section 12. Ecological information

LogPow BCF Potential

Bioaccumulative potential

Product/ingredient name

2,2',2''-nitrilotriethanol -1 3.89 Low

Product/ingredient name Aquatic half-life Photolysis Biodegradability

2,2',2''-nitrilotriethanol - - Readily

Toxicity titanium dioxide Acute LC50 >100 mg/l Fresh water Daphnia - Daphnia magna 48 hours 2,2',2''-nitrilotriethanol Acute LC50 11800 mg/l Fish 96 hours

Product/ingredient name SpeciesResult Exposure

Persistence and degradability

Soil/water partition coefficient (KOC)

: Not available.

Mobility in soil

Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.

Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

:Disposal methods

Disposal should be in accordance with applicable regional, national and local laws and regulations.

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees. Section 6. Accidental release measures

14. Transport information

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14. Transport information

Not regulated.

Not regulated. Not regulated.

DOT IMDG IATA

UN number

UN proper shipping name

Transport hazard class (es)

Packing group

Environmental hazards No. No. No.

Marine pollutant substances

Not applicable.Not applicable.Not applicable.

Special precautions for user Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

Additional information None identified.

None identified.

DOT

IMDG

IATA : None identified.

Transport in bulk according to IMO instruments

: Not applicable.

Section 15. Regulatory information

SARA 302/304

SARA 304 RQ : Not applicable.

Composition/information on ingredients

At least one component is inactive.United States inventory (TSCA 8b) :

United States

No products were found.

SARA 311/312

Classification : CARCINOGENICITY - Category 2 HNOC - Defatting irritant titanium dioxide ≥5.0 - ≤10 CARCINOGENICITY - Category 2 2,2',2''-nitrilotriethanol ≥1.0 - ≤5.0 EYE IRRITATION - Category 2A

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)

(Respiratory tract irritation) - Category 3 HNOC - Defatting irritant

Name % Classification

Composition/information on ingredients

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Section 15. Regulatory information Additional environmental information is contained on the Environmental Data Sheet for this product, which can be obtained from your PPG representative.

Section 16. Other information

Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SGG = Segregation Group UN = United Nations

Hazardous Material Information System (U.S.A.)

National Fire Protection Association (U.S.A.)

Health InstabilityFlammability

Health Flammability Physical hazards

Disclaimer

The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this information is to draw attention to the health and safety aspects concerning the products supplied by PPG, and to recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measures described in this data sheet or for any misuse of the products.

Date of previous issue 3/28/2023:

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on MSDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American Coatings Association, Inc.

The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.

Indicates information that has changed from previously issued version.

Organization that prepared the SDS

: EHS

: : :2 *

( * ) - Chronic effects

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