Part 2 Reference Reports Wayne Oakland DCSpec_Rev_02-19.pdf
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- Attached to
- 761/20035. SAR Former Wayne Oakland Oil
- Solicitation number
- RFQ 171 200000000255 5
- Issued by
- Benzie County, Riverview City, Michigan
About this file
This is a soil sample analytical report from the Wayne Oakland Oil Site in Royal Oak, Michigan, documenting volatile organic compound (VOC) results collected between July 2009 and July 2010. The report presents data from twelve soil sample locations (SB-36 through SB-44, with one duplicate sample) at varying depths ranging from 0.5 to 6.0 feet below ground surface. All samples were analyzed using EPA Method 8260 and were collected, extracted/digested, and analyzed between August 2009 and August 2010. The table compares detected analyte concentrations across multiple residential and groundwater protection criteria, including direct contact criteria, drinking water protection criteria, groundwater surface water interface protection criteria, groundwater contact protection criteria, and soil volatilization to indoor air inhalation criteria.
The analytical results identify 34 volatile organic compounds across the sample locations, with concentrations ranging from non-detect (ID) to values exceeding 1.1E+8 micrograms per kilogram. Key compounds detected include common chlorinated solvents such as tetrachloroethylene and trichloroethylene, petroleum hydrocarbons including toluene and xylenes, and oxygenated compounds such as methyl-tert-butyl ether and tetrahydrofuran. Several analytes show concentrations exceeding one or more regulatory criteria, with notations (C), (W), and (X) indicating exceeded criteria categories, critical exceedances, and other significant findings respectively. The data supports environmental assessment and remediation planning for this contaminated site.
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TABLE J1
SOIL SAMPLES -VOC RESULTS - JULY 2009 to JULY 2010
WAYNE OAKLAND OIL SITE
ROYAL OAK, MICHIGAN
Sample ID
Screen Interval (ft bgs)
Date Collected
Date Extracted/Digested
Date Analyzed
EPA Analytical Method
Analyte
1,1,1,2-Tetrachloroethane 1,500 ID 4.4E+5 (C) 6,200 4.4E+5 (C)
Residential
Direct Contact
Criteria
Residential Drinking
Water Protection
Criteria
Groundwater
Surface Water
Interface
Protection Criteria
Groundwater Contact
Protection Criteria
Residential Soil
Volatilization to
Indoor Air
Inhalation
Criteria
Chloromethane (I) 5,200 ID 1.1E+6 (C) 2,300 1.1E+6 (C) cis-1,2-Dichloroethylene 1,400 12,000 6.4E+5 (C) 22,000 6.4E+5 (C) cis-1,3-Dichloropropylene NA NA NA NA NA
Cyclohexane NA NA NA NA NA
Dibromochloromethane 1,600 (W) ID 3.6E+5 3,900 1.1E+5
Dibromomethane 1,600 NA 2.0E+6 (C) ID 2.0E+6 (C)
Dichlorodifluoromethane 95,000 ID 1.0E+6 (C) 9.0E+5 1.0E+6 (C)
Diethyl ether 200 ID 7.4E+6 (C) 7.4E+6 (C) 7.4E+6 (C)
Diisopropyl Ether 600 ID 1,300 (C) 1,300 (C) 1,300 (C)
Ethylbenzene (I) 1,500 360 1.4E+5 (C) 87,000 1.4E+5 (C)
Ethyltertiarybutylbenzene NA ID ID 5.4E+5 ID
Hexachloroethane 430 1,800 (X) 1.1E+5 40,000 2.3E+5
Isopropylbenzene (Cumene) 91,000 3,200 3.9E+5 (C) 3.9E+5 (C) 3.9E+5 (C) m & p-Xylenes (I) 5,600 820 1.5E+5 (C) 1.5E+5 (C) 1.5E+5 (C)
Methyl Iodide NA NA NA NA NA
Methylene chloride 100 30,000 (X) 2.3E+6 (C) 45,000 1.3E+6
Methyl-tert-butyl Ether (MTBE) 800 1.4E+5 (X) 5.9E+6 (C) 5.9E+6 (C) 1.5E+6
Naphthalene 35,000 730 2.1E+6 2.5E+5 1.6E+7 n-Butylbenzene 1,600 ID 1.2E+5 ID 2.5E+6 n-Propylbenzene (I) 1,600 ID 3.0E+5 ID 2.5E+6 o-Xylene (I) 5,600 820 1.5E+5 (C) 1.5E+5 (C) 1.5E+5 (C) p-Isopropyltoluene NA NA NA NA NA sec-Butylbenzene 1,600 ID 88,000 ID 2.5E+6
Styrene 2,700 2,100 (X) 2.7E+5 2.5E+5 4.0E+5 tert-Butylbenzene (I) 1,600 ID 1.8E+5 ID 2.5E+6 tertiary Butyl Alcohol 78,000 NA 1.1E+8 (C) 1.1E+8 (C) 1.1E+8 (C) tertiary Amylmethylether 3,900 NA 4.4E+5 (C) 58,000 4.4E+5 (C)
Tetrachloroethylene 100 1,200 (X) 88,000 (C) 11,000 88,000 (C)
Tetrahydrofuran 1,900 2.2E+5 (X) 3.2E+7 1.3E+6 2.9E+6
Toluene (I) 16,000 5,400 2.5E+5 (C) 2.5E+5 (C) 2.5E+5 (C) trans-1,2-Dichloroethylene 2,000 30,000 (X) 1.4E+6 (C) 23,000 1.4E+6 (C) trans-1,3-Dichloropropene NA NA NA NA NA
SB-36 SB-37 DUP-2 SB-38 SB-39 SB-39 SB-40 SB-41 SB-42 SB-43 SB-43 SB-44
(3.5-5') (2.5-4') SB-37 (2.5-4') (4.5-6.0') (0.5-2.0') (3-5') (4-6') (4.5-6') (3.5-5') (1-3') (3-5') (5-6')
8/6/2009 8/6/2009 8/5/2009 8/18/2009 8/18/2009 8/18/2009 8/18/2009 8/18/2009 8/18/2009 11/10/2009 11/10/2009 7/29/2010
8/12/2009 8/12/2009 8/6/2009 8/25/2009 8/25/2009 8/25/2009 8/25/2009 8/25/2009 8/25/2009 11/13/2009 11/13/2009 8/2/2010
8/12/2009 8/13/2009 8/11/2009 8/26/2009 8/26/2009 8/26/2009 8/26/2009 8/26/2009 8/26/2009 11/17/2009 11/18/2009 8/11/2010
8260 8260 8260 8260 8260 8260 8260 8260 8260 8260 8260 8260
<330 <290 <340 <13,000 <300 <280 <320 <13,000 <330 <310 <5,100 <13000
<65 <59 <68 <2,500 <59 <56 <64 <2,600 <66 <62 <1,000 <2500
<65 <59 <68 <2,500 <59 <56 <64 <2,600 <66 <62 <1,000 <2500
<330 <290 <340 <13,000 <300 <280 <320 <13,000 <330 <310 (7) <5,100 <13000
<65 <59 <68 <2,500 <59 <56 <64 <2,600 <66 <62 <1,000 <2500
<65 <59 <68 <2,500 <59 <56 <64 <2,600 <66 <62 <1,000 <2500
<330 (5) <290 (5) <340 <13,000 (5) <300 (5) <280 (5) <320 (5) <13,000 (5) <330 (5) <310 <5,100 (5) <13000
<260 <230 <270 <10,000 <240 <220 <260 <10,000 <270 <250 <4,100 <10000
<330 <290 <340 <13,000 <300 <280 <320 <13,000 <330 <310 <5,100 <13000
<65 <59 <68 <2,500 <59 <56 <64 <2,600 <66 310 8,700 7,200
<330 <290 <340 <13,000 <300 <280 <320 <13,000 <330 <310 <5,100 <13000
<330 (5,3) <290 (5,3) <340 (5,3) <13,000 (5) <300 (5) <280 (5) <320 (5) <13,000 (5) <330 (5) <310 <5,100 (5) <13000
<65 <59 <68 <2,500 <59 <56 <64 <2,600 <66 <62 1,700 2,600
<130 <120 <140 <5,000 <120 <110 <130 <5,200 <130 970 28,000 6,000
<65 <59 <68 <2,500 <59 <56 <64 <2,600 <66 <62 (5) <1,000 <2500
<130 <120 <140 <5,000 <120 <110 <130 <5,200 <130 <120 <2,000 <5000
<65 <59 <68 <2,500 <59 <56 <64 <2,600 <66 <62 <1,000 <2500
<330 (*) <290 (*) <340 (*) <13,000 (*) <300 (*) <280 (*) <320 (*) <13,000 (*) <330 (*) 2,900 (*) 32,000 (*) 53,000 (*)
<65 <59 <68 <2,500 <59 <56 <64 <2,600 <66 <62 <1,000 <2500
<65 <59 <68 <2,500 <59 <56 <64 <2,600 <66 140 4,100 7,300
<65 <59 <68 <2,500 <59 <56 <64 <2,600 <66 85 <1,000 <2500
<65 <59 <68 <2,500 <59 <56 <64 <2,600 <66 200 3,000 8,100
<65 <59 <68 <2,500 <59 <56 <64 <2,600 <66 83 1,600 4,500
<65 <59 <68 <2,500 <59 <56 <64 <2,600 <66 <62 <1,000 <2500
<65 <59 <68 <2,500 <59 <56 <64 <2,600 <66 <62 <1,000 <2500
<3,300 (5) <2,900 (5) <3,400 (5) <130,000 (5) <3,000 (5) <2,800 (5) <3,200 (5) <130,000 (5) <3,300 (5) <3,100 <51,000 <130000
<330 <290 <340 <13,000 <300 <280 <320 <13,000 <330 <310 <5,100 <13000
<65 <59 <68 <2,500 <59 <56 <64 <2,600 <66 <62 <1,000 <2500
<330 <290 <340 <13,000 <300 <280 <320 <13,000 <330 <310 <5,100 <13000
<65 <59 <68 <2,500 <59 <56 <64 <2,600 <66 89 <1,000 <2500
<65 <59 <68 <2,500 <59 <56 <64 <2,600 <66 <62 <1,000 <2500
<65 <59 <68 <2,500 <59 <56 <64 <2,600 <66 <62 <1,000 <2500
WOO_Soil Analytical_2009-2010_111711 (jch J).xlsx J1_Soil VOC Page 8 of 15
WAYNE OAKLAND OIL SITE
ROYAL OAK, MICHIGAN
Sample ID
Screen Interval (ft bgs)
Date Collected
Date Extracted/Digested
Date Analyzed
EPA Analytical Method
Analyte
1,1,1,2-Tetrachloroethane 1,500 ID 4.4E+5 (C) 6,200 4.4E+5 (C)
Residential
Direct Contact
Criteria
Residential Drinking
Water Protection
Criteria
Groundwater
Surface Water
Interface
Protection Criteria
Groundwater Contact
Protection Criteria
Residential Soil
Volatilization to
Indoor Air
Inhalation
Criteria trans-1,4-Dichloro-2-butene NA NA NA NA NA
Trichloroethylene 100 4,000 (X) 4.4E+5 7,100 5.0E+5 (C,DD)
Trichlorofluoromethane 52,000 NA 5.6E+5 (C) 5.6E+5 (C) 5.6E+5 (C)
Vinyl Chloride 40 260 (X) 20,000 270 3,800
Xylenes, Total (I) 5,600 820 1.5E+5 (C) 1.5E+5 (C) 1.5E+5 (C)
Notes:
Analytical results are presented in µg/Kg.
"ND” indicates analyte concentration was not detected above laboratory detection limit.
Criteria are from Part 201 Generic Cleanup Criteria and Risk-Based Screening Levels (RBSLs), updated March 25, 2011.
Bolded concentrations represent a concentration above detection limits.
Highlighted concentrations indicate concentrations exceeding at least one criteria or screening level.
(3) indicates result(s) and RL(s) are estimated due to low matrix spike recovery.
(5) indicates result(s) and RL are estimated due to low continuing calibration standard criteria failure.
(7) indicates result(s) and RL(s) are estimated due to poor precision.
(+) indicates result and RL are estimated due to initial calibration standard criteria failure.
(*) indicates methods 8260 & 624 are used to analyze volatile organics that have boiling points below 200ºC. 2-Methylnaphthalene & naphthalene have boiling points above 200ºC and are better suited to analysis by methods 8270 or 625 as semivolatile organics.
(Z) indicates result reported below the RL to meet the TDL in RRD Op Memo 2 (10/22/04) multiplied by applicable dilution factor.
See the Analytical Results Notes Page found at the end of the Tables section for footnotes related to Part 201 criteria.
"<" indicates that the parameter was analyzed but not detected above the corresponding laboratory method detection limit.
SB-36 SB-37 DUP-2 SB-38 SB-39 SB-39 SB-40 SB-41 SB-42 SB-43 SB-43 SB-44
(3.5-5') (2.5-4') SB-37 (2.5-4') (4.5-6.0') (0.5-2.0') (3-5') (4-6') (4.5-6') (3.5-5') (1-3') (3-5') (5-6')
8/6/2009 8/6/2009 8/5/2009 8/18/2009 8/18/2009 8/18/2009 8/18/2009 8/18/2009 8/18/2009 11/10/2009 11/10/2009 7/29/2010
8/12/2009 8/12/2009 8/6/2009 8/25/2009 8/25/2009 8/25/2009 8/25/2009 8/25/2009 8/25/2009 11/13/2009 11/13/2009 8/2/2010
8/12/2009 8/13/2009 8/11/2009 8/26/2009 8/26/2009 8/26/2009 8/26/2009 8/26/2009 8/26/2009 11/17/2009 11/18/2009 8/11/2010
8260 8260 8260 8260 8260 8260 8260 8260 8260 8260 8260 8260
<330 (Z) <290 (Z) <340 (Z) <13,000 (Z) <300 (Z) <280 (Z) <320 (Z) <13,000 (Z) <330 (Z) <310 (Z) <5,100 (Z) <13000 (Z)
<65 <59 <68 <2,500 <59 <56 <64 <2,600 <66 <62 <1,000 <2500
<65 <59 <68 <2,500 <59 <56 <64 <2,600 <66 <62 <1,000 <2500
<65 (Z) <59 (Z) <68 (Z) <2,500 (Z) <59 (Z) <56 (Z) <64 (Z) <2,600 (Z) <66 (Z) <62 (Z) <1,000 (Z) <2500 (Z)
<195 <179 <208 <7,500 <179 <166 <194 <7,800 <196 1,055 28,000 6,000
WOO_Soil Analytical_2009-2010_111711 (jch J).xlsx J1_Soil VOC Page 9 of 15
WAYNE OAKLAND OIL SITE
ROYAL OAK, MICHIGAN
Sample ID
Screen Interval (ft bgs)
Date Collected
Date Extracted/Digested
Date Analyzed
EPA Analytical Method
Analyte
1,1,1,2-Tetrachloroethane 1,500 ID 4.4E+5 (C) 6,200 4.4E+5 (C)
1,1,1-Trichloroethane 4,000 1,800 4.6E+5 (C) 2.5E+5 4.6E+5 (C)
1,1,2,2-Tetrachloroethane 170 1,600 (X) 94,000 4,300 53,000
1,1,2-Trichloroethane 100 6,600 (X) 4.2E+5 4,600 1.8E+5
1,1-Dichloroethane 18,000 15,000 8.9E+5 (C) 2.3E+5 8.9E+5 (C)
1,1-Dichloroethylene (I) 140 2,600 2.2E+5 62 2.0E+5
1,2,3-Trichlorobenzene NA NA NA NA NA
1,2,3-Trichloropropane 840 NA 8.3E+5 (C) 4,000 8.3E+5 (C)
1,2,3-Trimethylbenzene NA NA NA NA NA
1,2,4-Trichlorobenzene 4,200 5,900 (X) 1.1E+6 1.1E+6 (C) 9.9E+5 (DD)
1,2,4-Trimethylbenzene (I) 2,100 570 1.1E+5 (C) 1.1E+5 (C) 1.1E+5 (C)
1,2-Dibromo-3-chloropropane NA NA NA NA NA
1,2-Dibromoethane (EDB) 20 (M); 1.0 110 (X) 500 670 92
1,2-Dichlorobenzene 14,000 280 2.1E+5 (C) 2.1E+5 (C) 2.1E+5 (C)
1,2-Dichloroethane (I) 100 7,200 (X) 3.8E+5 2,100 91,000
1,2-Dichloropropane (I) 100 4,600 (X) 3.2E+5 4,000 1.4E+5
1,3,5-Trimethylbenzene (I) 1,800 1,100 94,000 (C) 94,000 (C) 94,000 (C)
1,3-Dichlorobenzene 170 680 51,000 26,000 1.7E+5 (C)
1,4-Dichlorobenzene 1,700 360 1.4E+5 19,000 4.0E+5
2-Butanone (MEK) (I) 2.6E+5 44,000 2.7E+7 (C) 2.7E+7 (C) 2.7E+7 (C,DD)
2-Hexanone 20,000 ID 2.5E+6 (C) 9.9E+5 2.5E+6 (C)
2-Methylnaphthalene 57,000 4,200 5.5E+6 ID 8.1E+6
2-Propanone (acetone) (I) 15,000 34,000 1.1E+8 (C) 1.1E+8 (C) 2.3E+7
4-Methyl-2-Pentanone (MIBK) (I) 36,000 ID 2.7E+6 (C) 2.7E+6 (C) 2.7E+6 (C)
Acrylonitrile (I) 100 (M); 52 100 (M); 40 2.8E+5 6,600 16,000
Benzene (I) 100 4,000 (X) 2.2E+5 1,600 1.8E+5
Bromobenzene (I) 550 NA 3.6E+5 3.1E+5 5.4E+5
Bromochloromethane NA NA NA NA NA
Bromodichloromethane 1,600 (W) ID 2.8E+5 1,200 1.1E+5
Bromoform 1,600 (W) ID 8.7E+5 (C) 1.5E+5 8.2E+5
Bromomethane 200 700 1.4E+6 860 3.2E+5
Carbon disulfide (I,R) 16,000 ID 2.8E+5 (C) 76,000 2.8E+5 (C,DD)
Carbon Tetrachloride 100 900 (X) 92,000 190 96,000
Chlorobenzene (I) 2,000 500 2.6E+5 (C) 1.2E+5 2.6E+5 (C)
Chloroethane 8,600 22,000 (X) 9.5E+5 (C) 9.5E+5 (C) 9.5E+5 (C)
Chloroform 1,600 (W) 7,000 1.5E+6 (C) 7,200 1.2E+6
Residential
Direct Contact
Criteria
Residential Drinking
Water Protection
Criteria
Groundwater
Surface Water
Interface
Protection Criteria
Groundwater Contact
Protection Criteria
Residential Soil
Volatilization to
Indoor Air
Inhalation
Criteria
SB-45 DUP-2 SB-46 SB-47 SB-48 SB-SGW-1 SB-SGW-2 SB-SGW-3 SB-SGW-4 SB-SGW-5 SB-SGW-6
(6.5-7.5')
SB-45 (6.5-
7.5') (4-5') (4-5') (2-4') (2.5-3.5') (2.5-3.5') (4-5') (3.5-4.5') (4-4.5') (3.5-4.5')
7/29/2010 7/29/2010 7/29/2010 7/29/2010 7/29/2010 7/28/2010 7/28/2010 7/28/2010 7/28/2010 7/28/2010 7/28/2010
8/3/2010 8/2/2010 8/3/2010 8/3/2010 8/3/2010 8/2/2010 8/3/2010 8/3/2010 8/3/2010 8/3/2010 8/3/2010
8/3/2010 8/6/2010 8/3/2010 8/5/2010 8/3/2010 8/10/2010 8/3/2010 8/3/2010 8/3/2010 8/3/2010 8/3/2010
8260 8260 8260 8260 8260 8260 8260 8260 8260 8260 8260
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<320 <300 <1300 <2500 <290 <380 <350 <300 <310 <320 <340
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<63 <60 1,100 1,900 <58 <76 <71 <60 <61 <63 <68
<320 <300 <1300 <2500 <290 <380 <350 <300 <310 <320 <340
<63 <60 630 23,000 91 <76 <71 <60 <61 100 <68
<320 <300 <1300 <2500 <290 <380 <350 <300 <310 <320 <340
<63 (Z) <60 (Z) <260 (Z) <490 (Z) <58 (Z) <76 (Z) <71 (Z) <60 (Z) <61 (Z) <63 (Z) <68 (Z)
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<63 <60 <260 490 <58 <76 <71 <60 <61 <63 <68
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<320 <300 <1300 2500 <290 <380 <350 <300 <310 <320 <340
<320 <300 <1300 <2500 <290 <380 <350 <300 <310 <320 <340
<320 (*) <300 (*) 5,400 (*) 31,000 (*) <290 (*) <380 (*) <350 (*) <300 (*) <310 (*) <320 (*) <340 (*)
<1300 <1200 <5100 <9900 <1200 <1500 <1400 <1200 <1200 <1300 <1400
<320 <300 <1300 <2500 <290 <380 <350 <300 <310 <320 <340
<320 (Z) <300 (Z) <1300 (Z) <2500 (Z) <290 (Z) <380 (Z) <350 (Z) <300 (Z) <310 (Z) <320 (Z) <340 (Z)
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<250 <240 <1000 <2000 <230 <300 <280 <240 <240 <250 <270
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<63 <60 <260 <490 <58 ,76 <71 <60 <61 <63 <68
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<320 <300 <1300 (7) <2500 (7) <290 <380 <350 <300 <310 <320 <340
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
WOO_Soil Analytical_2009-2010_111711 (jch J).xlsx J1_Soil VOC Page 10 of 15
WAYNE OAKLAND OIL SITE
ROYAL OAK, MICHIGAN
Sample ID
Screen Interval (ft bgs)
Date Collected
Date Extracted/Digested
Date Analyzed
EPA Analytical Method
Analyte
1,1,1,2-Tetrachloroethane 1,500 ID 4.4E+5 (C) 6,200 4.4E+5 (C)
Residential
Direct Contact
Criteria
Residential Drinking
Water Protection
Criteria
Groundwater
Surface Water
Interface
Protection Criteria
Groundwater Contact
Protection Criteria
Residential Soil
Volatilization to
Indoor Air
Inhalation
Criteria
Chloromethane (I) 5,200 ID 1.1E+6 (C) 2,300 1.1E+6 (C) cis-1,2-Dichloroethylene 1,400 12,000 6.4E+5 (C) 22,000 6.4E+5 (C) cis-1,3-Dichloropropylene NA NA NA NA NA
Cyclohexane NA NA NA NA NA
Dibromochloromethane 1,600 (W) ID 3.6E+5 3,900 1.1E+5
Dibromomethane 1,600 NA 2.0E+6 (C) ID 2.0E+6 (C)
Dichlorodifluoromethane 95,000 ID 1.0E+6 (C) 9.0E+5 1.0E+6 (C)
Diethyl ether 200 ID 7.4E+6 (C) 7.4E+6 (C) 7.4E+6 (C)
Diisopropyl Ether 600 ID 1,300 (C) 1,300 (C) 1,300 (C)
Ethylbenzene (I) 1,500 360 1.4E+5 (C) 87,000 1.4E+5 (C)
Ethyltertiarybutylbenzene NA ID ID 5.4E+5 ID
Hexachloroethane 430 1,800 (X) 1.1E+5 40,000 2.3E+5
Isopropylbenzene (Cumene) 91,000 3,200 3.9E+5 (C) 3.9E+5 (C) 3.9E+5 (C) m & p-Xylenes (I) 5,600 820 1.5E+5 (C) 1.5E+5 (C) 1.5E+5 (C)
Methyl Iodide NA NA NA NA NA
Methylene chloride 100 30,000 (X) 2.3E+6 (C) 45,000 1.3E+6
Methyl-tert-butyl Ether (MTBE) 800 1.4E+5 (X) 5.9E+6 (C) 5.9E+6 (C) 1.5E+6
Naphthalene 35,000 730 2.1E+6 2.5E+5 1.6E+7 n-Butylbenzene 1,600 ID 1.2E+5 ID 2.5E+6 n-Propylbenzene (I) 1,600 ID 3.0E+5 ID 2.5E+6 o-Xylene (I) 5,600 820 1.5E+5 (C) 1.5E+5 (C) 1.5E+5 (C) p-Isopropyltoluene NA NA NA NA NA sec-Butylbenzene 1,600 ID 88,000 ID 2.5E+6
Styrene 2,700 2,100 (X) 2.7E+5 2.5E+5 4.0E+5 tert-Butylbenzene (I) 1,600 ID 1.8E+5 ID 2.5E+6 tertiary Butyl Alcohol 78,000 NA 1.1E+8 (C) 1.1E+8 (C) 1.1E+8 (C) tertiary Amylmethylether 3,900 NA 4.4E+5 (C) 58,000 4.4E+5 (C)
Tetrachloroethylene 100 1,200 (X) 88,000 (C) 11,000 88,000 (C)
Tetrahydrofuran 1,900 2.2E+5 (X) 3.2E+7 1.3E+6 2.9E+6
Toluene (I) 16,000 5,400 2.5E+5 (C) 2.5E+5 (C) 2.5E+5 (C) trans-1,2-Dichloroethylene 2,000 30,000 (X) 1.4E+6 (C) 23,000 1.4E+6 (C) trans-1,3-Dichloropropene NA NA NA NA NA
SB-45 DUP-2 SB-46 SB-47 SB-48 SB-SGW-1 SB-SGW-2 SB-SGW-3 SB-SGW-4 SB-SGW-5 SB-SGW-6
(6.5-7.5')
SB-45 (6.5-
7.5') (4-5') (4-5') (2-4') (2.5-3.5') (2.5-3.5') (4-5') (3.5-4.5') (4-4.5') (3.5-4.5')
7/29/2010 7/29/2010 7/29/2010 7/29/2010 7/29/2010 7/28/2010 7/28/2010 7/28/2010 7/28/2010 7/28/2010 7/28/2010
8/3/2010 8/2/2010 8/3/2010 8/3/2010 8/3/2010 8/2/2010 8/3/2010 8/3/2010 8/3/2010 8/3/2010 8/3/2010
8/3/2010 8/6/2010 8/3/2010 8/5/2010 8/3/2010 8/10/2010 8/3/2010 8/3/2010 8/3/2010 8/3/2010 8/3/2010
8260 8260 8260 8260 8260 8260 8260 8260 8260 8260 8260
<320 <300 <1300 <2500 <290 <380 <350 <300 <310 <320 <340
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<320 <300 <1300 <2500 <290 <380 <350 <300 <310 <320 <340
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<320 <300 <1300 <2500 <290 <380 <350 <300 <310 <320 <340
<250 <240 <1000 <2000 <230 <300 <280 <240 <240 <250 <270
<320 <300 <1300 <2500 <290 <380 <350 <300 <310 <320 <340
<63 <60 440 1,600 <58 <76 <71 <60 <61 <63 <68
<320 <300 <1300 <2500 <290 <380 <350 <300 <310 <320 <340
<320 <300 <1300 <2500 <290 <380 <350 <300 <310 <320 <340
<63 <60 <260 660 <58 <76 <71 <60 <61 <63 <68
<130 <120 <510 <1500 <120 <150 <140 <120 <120 220 <140
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<130 <120 <510 <990 <120 <150 <140 <120 <120 <130 <140
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<320 (*) <300 (*) <1300 (*) 12,000 (*) <290 (*) <380 (*) <350 (*) <300 (*) <310 (*) <320 (*) <340 (*)
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<63 <60 270 1,700 <58 <76 <71 <60 <61 <63 <68
<63 <60 <260 <490 <58 <76 <71 <60 <61 130 <68
<63 <60 430 3,000 <58 <76 <71 <60 <61 <63 <68
<63 <60 <260 1,800 <58 <76 <71 <60 <61 <63 <68
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<3200 <3000 <13000 <25000 <2900 <3800 <3500 <3000 <3100 <3200 <3400
<320 <300 <1300 <2500 <290 <380 <350 <300 <310 <320 <340
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<320 <300 <1300 <2500 <290 <380 <350 <300 <310 <320 <340
<63 <60 <260 <490 <58 <76 <71 <60 <61 230 <68
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
WOO_Soil Analytical_2009-2010_111711 (jch J).xlsx J1_Soil VOC Page 11 of 15
WAYNE OAKLAND OIL SITE
ROYAL OAK, MICHIGAN
Sample ID
Screen Interval (ft bgs)
Date Collected
Date Extracted/Digested
Date Analyzed
EPA Analytical Method
Analyte
1,1,1,2-Tetrachloroethane 1,500 ID 4.4E+5 (C) 6,200 4.4E+5 (C)
Residential
Direct Contact
Criteria
Residential Drinking
Water Protection
Criteria
Groundwater
Surface Water
Interface
Protection Criteria
Groundwater Contact
Protection Criteria
Residential Soil
Volatilization to
Indoor Air
Inhalation
Criteria trans-1,4-Dichloro-2-butene NA NA NA NA NA
Trichloroethylene 100 4,000 (X) 4.4E+5 7,100 5.0E+5 (C,DD)
Trichlorofluoromethane 52,000 NA 5.6E+5 (C) 5.6E+5 (C) 5.6E+5 (C)
Vinyl Chloride 40 260 (X) 20,000 270 3,800
Xylenes, Total (I) 5,600 820 1.5E+5 (C) 1.5E+5 (C) 1.5E+5 (C)
Notes:
Analytical results are presented in µg/Kg.
"ND” indicates analyte concentration was not detected above laboratory detection limit.
Criteria are from Part 201 Generic Cleanup Criteria and Risk-Based Screening Levels (RBSLs), updated March 25, 2011.
Bolded concentrations represent a concentration above detection limits.
Highlighted concentrations indicate concentrations exceeding at least one criteria or screening level.
(3) indicates result(s) and RL(s) are estimated due to low matrix spike recovery.
(5) indicates result(s) and RL are estimated due to low continuing calibration standard criteria failure.
(7) indicates result(s) and RL(s) are estimated due to poor precision.
(+) indicates result and RL are estimated due to initial calibration standard criteria failure.
(*) indicates methods 8260 & 624 are used to analyze volatile organics that have boiling points below 200ºC. 2-Methylnaphthalene & naphthalene have boiling points above 200ºC and are better suited to analysis by methods 8270 or 625 as semivolatile organics.
(Z) indicates result reported below the RL to meet the TDL in RRD Op Memo 2 (10/22/04) multiplied by applicable dilution factor.
See the Analytical Results Notes Page found at the end of the Tables section for footnotes related to Part 201 criteria.
"<" indicates that the parameter was analyzed but not detected above the corresponding laboratory method detection limit.
SB-45 DUP-2 SB-46 SB-47 SB-48 SB-SGW-1 SB-SGW-2 SB-SGW-3 SB-SGW-4 SB-SGW-5 SB-SGW-6
(6.5-7.5')
SB-45 (6.5-
7.5') (4-5') (4-5') (2-4') (2.5-3.5') (2.5-3.5') (4-5') (3.5-4.5') (4-4.5') (3.5-4.5')
7/29/2010 7/29/2010 7/29/2010 7/29/2010 7/29/2010 7/28/2010 7/28/2010 7/28/2010 7/28/2010 7/28/2010 7/28/2010
8/3/2010 8/2/2010 8/3/2010 8/3/2010 8/3/2010 8/2/2010 8/3/2010 8/3/2010 8/3/2010 8/3/2010 8/3/2010
8/3/2010 8/6/2010 8/3/2010 8/5/2010 8/3/2010 8/10/2010 8/3/2010 8/3/2010 8/3/2010 8/3/2010 8/3/2010
8260 8260 8260 8260 8260 8260 8260 8260 8260 8260 8260
<320 (*) <300 (Z) <1300 (Z) <2500 (Z) <290 (Z) <380 (Z) <350 (Z) <300 (Z) <310 (Z) <320 (Z) <340 (Z)
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<63 <60 <260 <490 <58 <76 <71 <60 <61 <63 <68
<63 (Z) <60 (Z) <260 (Z) <490 (Z) <58 (Z) <76 (Z) <71 (Z) <60 (Z) <61 (Z) <63 (Z) <68 (Z)
<196 <180 <770 1,500 <178 <226 <221 <180 <181 350 208
WOO_Soil Analytical_2009-2010_111711 (jch J).xlsx J1_Soil VOC Page 12 of 15
WAYNE OAKLAND OIL SITE
ROYAL OAK, MICHIGAN
Sample ID
Screen Interval (ft bgs)
Date Collected
Date Extracted/Digested
Date Analyzed
EPA Analytical Method
Analyte
1,1,1,2-Tetrachloroethane 1,500 ID 4.4E+5 (C) 6,200 4.4E+5 (C)
1,1,1-Trichloroethane 4,000 1,800 4.6E+5 (C) 2.5E+5 4.6E+5 (C)
1,1,2,2-Tetrachloroethane 170 1,600 (X) 94,000 4,300 53,000
1,1,2-Trichloroethane 100 6,600 (X) 4.2E+5 4,600 1.8E+5
1,1-Dichloroethane 18,000 15,000 8.9E+5 (C) 2.3E+5 8.9E+5 (C)
1,1-Dichloroethylene (I) 140 2,600 2.2E+5 62 2.0E+5
1,2,3-Trichlorobenzene NA NA NA NA NA
1,2,3-Trichloropropane 840 NA 8.3E+5 (C) 4,000 8.3E+5 (C)
1,2,3-Trimethylbenzene NA NA NA NA NA
1,2,4-Trichlorobenzene 4,200 5,900 (X) 1.1E+6 1.1E+6 (C) 9.9E+5 (DD)
1,2,4-Trimethylbenzene (I) 2,100 570 1.1E+5 (C) 1.1E+5 (C) 1.1E+5 (C)
1,2-Dibromo-3-chloropropane NA NA NA NA NA
1,2-Dibromoethane (EDB) 20 (M); 1.0 110 (X) 500 670 92
1,2-Dichlorobenzene 14,000 280 2.1E+5 (C) 2.1E+5 (C) 2.1E+5 (C)
1,2-Dichloroethane (I) 100 7,200 (X) 3.8E+5 2,100 91,000
1,2-Dichloropropane (I) 100 4,600 (X) 3.2E+5 4,000 1.4E+5
1,3,5-Trimethylbenzene (I) 1,800 1,100 94,000 (C) 94,000 (C) 94,000 (C)
1,3-Dichlorobenzene 170 680 51,000 26,000 1.7E+5 (C)
1,4-Dichlorobenzene 1,700 360 1.4E+5 19,000 4.0E+5
2-Butanone (MEK) (I) 2.6E+5 44,000 2.7E+7 (C) 2.7E+7 (C) 2.7E+7 (C,DD)
2-Hexanone 20,000 ID 2.5E+6 (C) 9.9E+5 2.5E+6 (C)
2-Methylnaphthalene 57,000 4,200 5.5E+6 ID 8.1E+6
2-Propanone (acetone) (I) 15,000 34,000 1.1E+8 (C) 1.1E+8 (C) 2.3E+7
4-Methyl-2-Pentanone (MIBK) (I) 36,000 ID 2.7E+6 (C) 2.7E+6 (C) 2.7E+6 (C)
Acrylonitrile (I) 100 (M); 52 100 (M); 40 2.8E+5 6,600 16,000
Benzene (I) 100 4,000 (X) 2.2E+5 1,600 1.8E+5
Bromobenzene (I) 550 NA 3.6E+5 3.1E+5 5.4E+5
Bromochloromethane NA NA NA NA NA
Bromodichloromethane 1,600 (W) ID 2.8E+5 1,200 1.1E+5
Bromoform 1,600 (W) ID 8.7E+5 (C) 1.5E+5 8.2E+5
Bromomethane 200 700 1.4E+6 860 3.2E+5
Carbon disulfide (I,R) 16,000 ID 2.8E+5 (C) 76,000 2.8E+5 (C,DD)
Carbon Tetrachloride 100 900 (X) 92,000 190 96,000
Chlorobenzene (I) 2,000 500 2.6E+5 (C) 1.2E+5 2.6E+5 (C)
Chloroethane 8,600 22,000 (X) 9.5E+5 (C) 9.5E+5 (C) 9.5E+5 (C)
Chloroform 1,600 (W) 7,000 1.5E+6 (C) 7,200 1.2E+6
Residential
Direct Contact
Criteria
Residential Drinking
Water Protection
Criteria
Groundwater
Surface Water
Interface
Protection Criteria
Groundwater Contact
Protection Criteria
Residential Soil
Volatilization to
Indoor Air
Inhalation
Criteria
SB-SGW-7 DUP-1
(3.5-4.5')
SB-SGW-7
(3.5-4.5') 7/28/2010 7/28/2010
8/3/2010 8/3/2010
8/3/2010 8/3/2010
8260 8260
<68 <70
<68 <70
<68 <70
<68 <70
<68 <70
<68 <70
<340 <350
<68 <70
<68 <70
<340 <350
97 <70
<340 <350
<68 (Z) <70 (Z)
<68 <70
<68 <70
<68 <70
<68 <70
<68 <70
<68 <70
<340 <350
<340 <350
<340 (*) <350 (*)
<1400 <1400
<340 <350
<340 (Z) <350 (Z)
<68 <70
<68 <70
<68 <70
<68 <70
<68 <70
<270 <280
<68 <70
<68 <70
<68 <70
<340 <350
<68 <70
WOO_Soil Analytical_2009-2010_111711 (jch J).xlsx J1_Soil VOC Page 13 of 15
WAYNE OAKLAND OIL SITE
ROYAL OAK, MICHIGAN
Sample ID
Screen Interval (ft bgs)
Date Collected
Date Extracted/Digested
Date Analyzed
EPA Analytical Method
Analyte
1,1,1,2-Tetrachloroethane 1,500 ID 4.4E+5 (C) 6,200 4.4E+5 (C)
Residential
Direct Contact
Criteria
Residential Drinking
Water Protection
Criteria
Groundwater
Surface Water
Interface
Protection Criteria
Groundwater Contact
Protection Criteria
Residential Soil
Volatilization to
Indoor Air
Inhalation
Criteria
Chloromethane (I) 5,200 ID 1.1E+6 (C) 2,300 1.1E+6 (C) cis-1,2-Dichloroethylene 1,400 12,000 6.4E+5 (C) 22,000 6.4E+5 (C) cis-1,3-Dichloropropylene NA NA NA NA NA
Cyclohexane NA NA NA NA NA
Dibromochloromethane 1,600 (W) ID 3.6E+5 3,900 1.1E+5
Dibromomethane 1,600 NA 2.0E+6 (C) ID 2.0E+6 (C)
Dichlorodifluoromethane 95,000 ID 1.0E+6 (C) 9.0E+5 1.0E+6 (C)
Diethyl ether 200 ID 7.4E+6 (C) 7.4E+6 (C) 7.4E+6 (C)
Diisopropyl Ether 600 ID 1,300 (C) 1,300 (C) 1,300 (C)
Ethylbenzene (I) 1,500 360 1.4E+5 (C) 87,000 1.4E+5 (C)
Ethyltertiarybutylbenzene NA ID ID 5.4E+5 ID
Hexachloroethane 430 1,800 (X) 1.1E+5 40,000 2.3E+5
Isopropylbenzene (Cumene) 91,000 3,200 3.9E+5 (C) 3.9E+5 (C) 3.9E+5 (C) m & p-Xylenes (I) 5,600 820 1.5E+5 (C) 1.5E+5 (C) 1.5E+5 (C)
Methyl Iodide NA NA NA NA NA
Methylene chloride 100 30,000 (X) 2.3E+6 (C) 45,000 1.3E+6
Methyl-tert-butyl Ether (MTBE) 800 1.4E+5 (X) 5.9E+6 (C) 5.9E+6 (C) 1.5E+6
Naphthalene 35,000 730 2.1E+6 2.5E+5 1.6E+7 n-Butylbenzene 1,600 ID 1.2E+5 ID 2.5E+6 n-Propylbenzene (I) 1,600 ID 3.0E+5 ID 2.5E+6 o-Xylene (I) 5,600 820 1.5E+5 (C) 1.5E+5 (C) 1.5E+5 (C) p-Isopropyltoluene NA NA NA NA NA sec-Butylbenzene 1,600 ID 88,000 ID 2.5E+6
Styrene 2,700 2,100 (X) 2.7E+5 2.5E+5 4.0E+5 tert-Butylbenzene (I) 1,600 ID 1.8E+5 ID 2.5E+6 tertiary Butyl Alcohol 78,000 NA 1.1E+8 (C) 1.1E+8 (C) 1.1E+8 (C) tertiary Amylmethylether 3,900 NA 4.4E+5 (C) 58,000 4.4E+5 (C)
Tetrachloroethylene 100 1,200 (X) 88,000 (C) 11,000 88,000 (C)
Tetrahydrofuran 1,900 2.2E+5 (X) 3.2E+7 1.3E+6 2.9E+6
Toluene (I) 16,000 5,400 2.5E+5 (C) 2.5E+5 (C) 2.5E+5 (C) trans-1,2-Dichloroethylene 2,000 30,000 (X) 1.4E+6 (C) 23,000 1.4E+6 (C) trans-1,3-Dichloropropene NA NA NA NA NA
SB-SGW-7 DUP-1
(3.5-4.5')
SB-SGW-7
(3.5-4.5') 7/28/2010 7/28/2010
8/3/2010 8/3/2010
8/3/2010 8/3/2010
8260 8260
<340 <350
<68 <70
<68 <70
<340 <350
<68 <70
<68 <70
<340 <350
<270 <280
<340 <350
<68 <70
<340 <350
<340 <350
<68 <70
150 <140
<68 <70
<140 <140
<68 <70
340 (*) <350 (*)
<68 <70
<68 <70
120 <70
<68 <70
<68 <70
<68 <70
<68 <70
<3400 <3500
<340 <350
<68 <70
<340 <350
110 <70
<68 <70
<68 <70
WOO_Soil Analytical_2009-2010_111711 (jch J).xlsx J1_Soil VOC Page 14 of 15
WAYNE OAKLAND OIL SITE
ROYAL OAK, MICHIGAN
Sample ID
Screen Interval (ft bgs)
Date Collected
Date Extracted/Digested
Date Analyzed
EPA Analytical Method
Analyte
1,1,1,2-Tetrachloroethane 1,500 ID 4.4E+5 (C) 6,200 4.4E+5 (C)
Residential
Direct Contact
Criteria
Residential Drinking
Water Protection
Criteria
Groundwater
Surface Water
Interface
Protection Criteria
Groundwater Contact
Protection Criteria
Residential Soil
Volatilization to
Indoor Air
Inhalation
Criteria trans-1,4-Dichloro-2-butene NA NA NA NA NA
Trichloroethylene 100 4,000 (X) 4.4E+5 7,100 5.0E+5 (C,DD)
Trichlorofluoromethane 52,000 NA 5.6E+5 (C) 5.6E+5 (C) 5.6E+5 (C)
Vinyl Chloride 40 260 (X) 20,000 270 3,800
Xylenes, Total (I) 5,600 820 1.5E+5 (C) 1.5E+5 (C) 1.5E+5 (C)
Notes:
Analytical results are presented in µg/Kg.
"ND” indicates analyte concentration was not detected above laboratory detection limit.
Criteria are from Part 201 Generic Cleanup Criteria and Risk-Based Screening Levels (RBSLs), updated March 25, 2011.
Bolded concentrations represent a concentration above detection limits.
Highlighted concentrations indicate concentrations exceeding at least one criteria or screening level.
(3) indicates result(s) and RL(s) are estimated due to low matrix spike recovery.
(5) indicates result(s) and RL are estimated due to low continuing calibration standard criteria failure.
(7) indicates result(s) and RL(s) are estimated due to poor precision.
(+) indicates result and RL are estimated due to initial calibration standard criteria failure.
(*) indicates methods 8260 & 624 are used to analyze volatile organics that have boiling points below 200ºC. 2-Methylnaphthalene & naphthalene have boiling points above 200ºC and are better suited to analysis by methods 8270 or 625 as semivolatile organics.
(Z) indicates result reported below the RL to meet the TDL in RRD Op Memo 2 (10/22/04) multiplied by applicable dilution factor.
See the Analytical Results Notes Page found at the end of the Tables section for footnotes related to Part 201 criteria.
"<" indicates that the parameter was analyzed but not detected above the corresponding laboratory method detection limit.
SB-SGW-7 DUP-1
(3.5-4.5')
SB-SGW-7
(3.5-4.5') 7/28/2010 7/28/2010
8/3/2010 8/3/2010
8/3/2010 8/3/2010
8260 8260
<340 (Z) <350 (Z)
<68 <70
<68 <70
<68 (Z) <70 (Z)
270 <210
WOO_Soil Analytical_2009-2010_111711 (jch J).xlsx J1_Soil VOC Page 15 of 15
TABLE K
GROUNDWATER SAMPLES -VOC RESULTS - JULY 2009 to JULY 2010
WAYNE OAKLAND OIL SITE
ROYAL OAK, MICHIGAN
Sample ID SB-13 SB-15 SB-16 SB-17 SB-18 SB-19 DUP-1 SB-20 SB-21 SB-22 SB-23
Screen Interval (ft bgs) (5-10') (4-9') (4-9') (5-10') (5-10') (4.5-9.5')
SB-19 (4.5-
9.5') (5-10') (5-10') (5-10') (5-10')
Date Collected 7/29/2009 7/30/2009 7/30/2009 7/30/2009 7/30/2009 7/30/2009 7/30/2009 7/31/2009 7/31/2009 7/31/2009 7/31/2009
Date Analyzed 8/11/2009 8/10/2009 8/10/2009 8/10/2009 8/11/2009 8/11/2009 8/11/2009 8/11/2009 8/11/2009 8/11/2009 8/11/2009
EPA Analytical Method 8260 8260 8260 8260 8260 8260 8260 8260 8260 8260 8260
Analyte
1,1,1,2-Tetrachloroethane 77 ID 15,000 30,000 ID ID ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
1,1,1-Trichloroethane 200 (A) 89 6.6E+05 1.3E+6 (S) ID 1.3E+6 (S) ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
1,1,2,2-Tetrachloroethane 8.5 78 (X) 12,000 4,700 ID ID ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
1,1,2-Trichloroethane 5.0 (A) 330 (X) 17,000 21,000 NA ID ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
1,1-Dichloroethane 880 740 1.0E+06 2.4E+6 3.80E+05 ID ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
1,1-Dichloroethylene (I) 7.0 (A) 130 200 11,000 97,000 1.40E+05 ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
1,2,3-Trichlorobenzene NA NA NA NA NA NA ND <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
1,2,3-Trichloropropane 42 NA 8,300 84,000 NA ID ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
1,2,3-Trimethylbenzene NA NA NA NA NA NA 140 <1 <1 1.8 <1 55 <1 <1 <1 <1 <1 <1
1,2,4-Trichlorobenzene 70 (A) 99 (X) 3.0E+5 (S) 19,000 NA 3.0E+5 (S) ND <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
1,2,4-Trimethylbenzene (I) 63 (E) 17 56,000 (S) 56,000 (S) 56,000 (S) ID 240 <1 <1 2.9 1.4 190 <1 <1 <1 <1 <1 <1
1,2-Dibromo-3-chloropropane 0.2 (A) ID 1,200 (S) 390 NA ID ND <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
1,2-Dibromoethane (EDB) 0.05 (A) 5.7 (X) 2,400 25 ID ID ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
1,2-Dichlorobenzene 600 (A) 13 1.6E+5 (S) 1.6E+5 (S) NA 1.6E+5 (S) ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
1,2-Dichloroethane (I) 5.0 (A) 360 (X) 9,600 19,000 2.50E+06 ID ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
1,2-Dichloropropane (I) 5.0 (A) 230 (X) 16,000 16,000 5.50E+05 2.8E+6 (S) ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
1,3,5-Trimethylbenzene (I) 72 (E) 45 61,000 (S) 61,000 (S) ID ID 36 <1 <1 <1 7.9 36 <1 <1 <1 <1 <1 <1
1,3-Dichlorobenzene 6.6 28 18,000 2,000 ID ID ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
1,4-Dichlorobenzene 75 (A) 17 16,000 6,400 NA ID ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
2-Butanone (MEK) (I) 13,000 2,200 2.4E+8 (S) 2.4E+8 (S) ID 2.4E+8 (S) ND <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
2-Hexanone 1,000 ID 4.2E+06 5.2E+6 NA ID ND <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
2-Methylnaphthalene 260 19 25,000 (S) 25,000 (S) ID ID 290 (*) 5.4 <5 (*) <5 (*) <5 (*) 140 <5 (*) <5 (*) <5 (*) <5 (*) <5 (*) <5 (*)
2-Propanone (acetone) (I) 730 1,700 1.0E+9 (D,S) 3.1E+7 1.50E+07 1.0E+9 (D) ND <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20
4-Methyl-2-Pentanone (MIBK) (I) 1,800 ID 2.0E+7 (S) 1.3E+7 ID 2.0E+7 (S) ND <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
Acrylonitrile (I) 2.6 2.0 (M); 1.2 34,000 14,000 6.40E+06 ID ND <5 <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z)
Benzene (I) 5.0 (A) 200 (X) 5,600 11,000 68,000 67,000 300 <1 <1 7.4 7.5 6.8 <1 <1 <1 <1 <1 <1
Bromobenzene (I) 18 NA 1.8E+05 12,000 ID ID ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Bromochloromethane NA NA NA NA NA NA
Bromodichloromethane 80 (A,W) ID 4,800 14,000 ID ID ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Bromoform 80 (A,W) ID 4.7E+05 1.4E+5 ID ID ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Bromomethane 10 35 4,000 70,000 ID ID ND <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
Carbon disulfide (I,R) 800 ID 2.5E+05 1.2E+6 (S) 13,000 ID 1.3 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Carbon Tetrachloride 5.0 (A) 45 (X) 370 4,600 ID 96,000 ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Chlorobenzene (I) 100 (A) 25 2.1E+05 86,000 1.60E+05 ID ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Chloroethane 430 1,100 (X) 5.7E+6 (S) 4.4E+5 1.10E+05 ID ND <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
Chloroform 80 (A,W) 350 28,000 1.5E+5 ID ID ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Chloromethane (I) 260 ID 8,600 4.9E+5 36,000 2.10E+05 ND <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 cis-1,2-Dichloroethylene 70 (A) 620 93,000 2.0E+5 5.30E+05 ID ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 cis-1,3-Dichloropropylene NA NA NA NA NA NA ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Cyclohexane NA NA NA NA NA NA 24 <5 <5 <5 14 13 <5 <5 <5 <5 <5 <5
Dibromochloromethane 80 (A,W) ID 14,000 18,000 ID ID ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Dibromomethane 80 NA ID 5.3E+5 ID ID ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Dichlorodifluoromethane 1,700 ID 2.2E+05 3.0E+5 (S) ID ID ND <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
Diethyl ether 10 (E) ID 6.1E+7 (S) 3.5E+7 6.50E+05 6.1E+7 (S) ND <5 <5 <5 <5 <5 <5 <5 <5 (5) <5 (5) <5 (5) <5 (5)
Diisopropyl Ether 30 ID 8,000 (S) NA 8,000 (S) ID ND <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
Ethylbenzene (I) 74 (E) 18 1.1E+05 1.7E+5 (S) 43,000 1.7E+5 (S) 210 1.0 <1 3.5 <1 120 <1 <1 <1 <1 <1 <1
Ethyltertiarybutylbenzene NA NA NA NA NA NA ND <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
Hexachloroethane 7.3 6.7 (X) 27,000 1,900 ID ID ND <5 <5 <5 <5 <5 <5 <5 <5 (+) <5 (+) <5 (+) <5 (+)
Isopropylbenzene (Cumene) 800 28 56,000 (S) 56,000 (S) 29,000 ID 28 <1 <1 1.8 9.6 17 3.2 3 <1 <1 <1 <1
Maximum
Detected
Concentration
Flammability &
Explosivity
Screening
Levels
Residential Drinking
Water Criteria
Groundwater
Surface Water
Interface Criteria
Residential
Groundwater
Volatilization to Indoor
Air Inhalation Criteria
Groundwater
Contact Criteria
Acute
Inhalation
Screening
Level
WOO_GW_Analytical_2009-2010 092111 (jch KL).xlsx K_Water VOC Page 1 of 8
WAYNE OAKLAND OIL SITE
ROYAL OAK, MICHIGAN
Sample ID SB-13 SB-15 SB-16 SB-17 SB-18 SB-19 DUP-1 SB-20 SB-21 SB-22 SB-23
Screen Interval (ft bgs) (5-10') (4-9') (4-9') (5-10') (5-10') (4.5-9.5')
SB-19 (4.5-
9.5') (5-10') (5-10') (5-10') (5-10')
Date Collected 7/29/2009 7/30/2009 7/30/2009 7/30/2009 7/30/2009 7/30/2009 7/30/2009 7/31/2009 7/31/2009 7/31/2009 7/31/2009
Date Analyzed 8/11/2009 8/10/2009 8/10/2009 8/10/2009 8/11/2009 8/11/2009 8/11/2009 8/11/2009 8/11/2009 8/11/2009 8/11/2009
EPA Analytical Method 8260 8260 8260 8260 8260 8260 8260 8260 8260 8260 8260
Analyte
Maximum
Detected
Concentration
Flammability &
Explosivity
Screening
Levels
Residential Drinking
Water Criteria
Groundwater
Surface Water
Interface Criteria
Residential
Groundwater
Volatilization to Indoor
Air Inhalation Criteria
Groundwater
Contact Criteria
Acute
Inhalation
Screening
Level m & p-Xylenes (I) 280 (E) 41 1.9E+5 (S) 1.9E+5 (S) 70,000 1.9E+5 (S) 190 <2 <2 2.4 <2 59 <2 <2 <2 <2 <2 <2
Methyl Iodide NA NA NA NA NA NA ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Methylene chloride 5.0 (A) 1,500 (X) 2.2E+05 2.2E+5 ID ID ND <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
Methyl-tert-butyl Ether (MTBE) 40 (E) 7,100 (X) 4.7E+7 (S) 6.10E+5 ID ID 1.1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Naphthalene 520 11 31,000 (S) 31,000 (S) NA 31,000 (S) 350 (*) <5 (*) <5 (*) <5 (*) <5 (*) 170 <5 (*) <5 (*) <5 (*) <5 (*) <5 (*) <5 (*) n-Butylbenzene 80 ID ID 5,900 ID ID 9.0 1.1 <1 <1 4.5 <1 2.8 2.4 <1 <1 <1 <1 n-Propylbenzene (I) 80 ID ID 15,000 ID ID 39 1.4 <1 1.1 18 28 6.5 5.8 <1 <1 <1 <1 o-Xylene (I) 280 (E) 41 1.9E+5 (S) 1.9E+5 (S) 70,000 1.9E+5 (S) 13 <1 <1 1 <1 4.8 <1 <1 <1 <1 <1 <1 p-Isopropyltoluene NA NA NA NA NA NA 9.5 <1 <1 <1 2.9 6.2 <1 <1 <1 <1 <1 <1 sec-Butylbenzene 80 ID ID 4,400 ID ID 10 <1 <1 <1 3.6 5.7 1.8 1.6 <1 <1 <1 <1
Styrene 100 (A) 80 (X) 1.7E+05 9,700 1.40E+05 3.1E+5 (S) ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 tert-Butylbenzene (I) 80 ID ID 8,900 ID ID ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 tertiary Butyl Alcohol 3,900 NA 1.0E+9 (D,S) 7.9E+7 6.10E+07 ID ND <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 tertiary Amylmethylether 190 (E) NA 2.6E+05 2.6E+6 (S) NA NA ND <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
Tetrachloroethylene 5.0 (A) 60 (X) 25,000 12,000 ID 2.0E+5 (S) ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Tetrahydrofuran 95 11,000 (X) 6.9E+06 1.6E+6 60,000 3.60E+06 ND <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
Toluene (I) 790 (E) 270 5.3E+5 (S) 5.3E+5 (S) 61,000 ID 10 <1 <1 <1 <1 1.9 <1 <1 <1 <1 <1 <1 trans-1,2-Dichloroethylene 100 (A) 1,500 (X) 85,000 2.2E+5 2.30E+05 ID ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 trans-1,3-Dichloropropene NA NA NA NA NA NA ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 trans-1,4-Dichloro-2-butene NA NA NA NA NA NA ND <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z)
Trichloroethylene 5.0 (A) 200 (X) 15,000 22,000 ID 1.1E+6 (S) ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Trichlorofluoromethane 2,600 NA 1.1E+6 (S) 1.1E+6 (S) ID 1.1E+6 (S) 1.6 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Vinyl Chloride 2.0 (A) 13 (X) 1,100 1,000 33,000 ID ND <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
Xylenes, Total (I) 280 (E) 41 1.9E+5 (S) 1.9E+5 (S) 70,000 1.9E+5 (S) 203 <3 <3 3.4 <3 63.8 <3 <3 <3 <3 <3 <3
Notes:
Analytical results are presented in µg/l.
"ND” indicates analyte concentration was not detected above laboratory detection limit.
"<" indicates that the parameter was analyzed but not detected above the corresponding laboratory method detection limit.
Criteria are from Part 201 Cleanup Criteria and Part 213 Risk-Based Screening Levels (RBSLs), updated March 25, 2011.
Bolded concentrations represent a concentration above detection limits.
Highlighted concentrations indicate concentrations exceeding at least one criteria or screening level.
(5) indicates result and RL are estimated due to low continuing calibration standard criteria failure.
(7) indicates results(s) and RL(s) are estimated due to poor precision.
(+) indicates result and RL are estimated due to initial calibration standard criteria failure.
(*) indicates methods 8260 & 624 are used to analyze volatile organics that have boiling points below 200ºC. 2-Metylnaphthalene & naphthalene have boiling points above 200ºC and are better suited to analysis by methods 8270 or 625 as semivolatile organics.
(Z) indicates result reported below the RL to meet the TDL in RRD Op Memo 2 (10/22/04) multiplied by applicable dilution factor.
See the Analytical Results Notes Page found at the end of the Tables section for footnotes related to Part 201 criteria.
WOO_GW_Analytical_2009-2010 092111 (jch KL).xlsx K_Water VOC Page 2 of 8
WAYNE OAKLAND OIL SITE
ROYAL OAK, MICHIGAN
Sample ID
Screen Interval (ft bgs)
Date Collected
Date Analyzed
EPA Analytical Method
Analyte
1,1,1,2-Tetrachloroethane 77 ID 15,000 30,000 ID
1,1,1-Trichloroethane 200 (A) 89 6.6E+05 1.3E+6 (S) ID
1,1,2,2-Tetrachloroethane 8.5 78 (X) 12,000 4,700 ID
1,1,2-Trichloroethane 5.0 (A) 330 (X) 17,000 21,000 NA
1,1-Dichloroethane 880 740 1.0E+06 2.4E+6 3.80E+05
1,1-Dichloroethylene (I) 7.0 (A) 130 200 11,000 97,000
1,2,3-Trichlorobenzene NA NA NA NA NA
1,2,3-Trichloropropane 42 NA 8,300 84,000 NA
1,2,3-Trimethylbenzene NA NA NA NA NA
1,2,4-Trichlorobenzene 70 (A) 99 (X) 3.0E+5 (S) 19,000 NA
1,2,4-Trimethylbenzene (I) 63 (E) 17 56,000 (S) 56,000 (S) 56,000 (S)
1,2-Dibromo-3-chloropropane 0.2 (A) ID 1,200 (S) 390 NA
1,2-Dibromoethane (EDB) 0.05 (A) 5.7 (X) 2,400 25 ID
1,2-Dichlorobenzene 600 (A) 13 1.6E+5 (S) 1.6E+5 (S) NA
1,2-Dichloroethane (I) 5.0 (A) 360 (X) 9,600 19,000 2.50E+06
1,2-Dichloropropane (I) 5.0 (A) 230 (X) 16,000 16,000 5.50E+05
1,3,5-Trimethylbenzene (I) 72 (E) 45 61,000 (S) 61,000 (S) ID
1,3-Dichlorobenzene 6.6 28 18,000 2,000 ID
1,4-Dichlorobenzene 75 (A) 17 16,000 6,400 NA
2-Butanone (MEK) (I) 13,000 2,200 2.4E+8 (S) 2.4E+8 (S) ID
2-Hexanone 1,000 ID 4.2E+06 5.2E+6 NA
2-Methylnaphthalene 260 19 25,000 (S) 25,000 (S) ID
2-Propanone (acetone) (I) 730 1,700 1.0E+9 (D,S) 3.1E+7 1.50E+07
4-Methyl-2-Pentanone (MIBK) (I) 1,800 ID 2.0E+7 (S) 1.3E+7 ID
Acrylonitrile (I) 2.6 2.0 (M); 1.2 34,000 14,000 6.40E+06
Benzene (I) 5.0 (A) 200 (X) 5,600 11,000 68,000
Bromobenzene (I) 18 NA 1.8E+05 12,000 ID
Bromochloromethane NA NA NA NA NA
Bromodichloromethane 80 (A,W) ID 4,800 14,000 ID
Bromoform 80 (A,W) ID 4.7E+05 1.4E+5 ID
Bromomethane 10 35 4,000 70,000 ID
Carbon disulfide (I,R) 800 ID 2.5E+05 1.2E+6 (S) 13,000
Carbon Tetrachloride 5.0 (A) 45 (X) 370 4,600 ID
Chlorobenzene (I) 100 (A) 25 2.1E+05 86,000 1.60E+05
Chloroethane 430 1,100 (X) 5.7E+6 (S) 4.4E+5 1.10E+05
Chloroform 80 (A,W) 350 28,000 1.5E+5 ID
Chloromethane (I) 260 ID 8,600 4.9E+5 36,000 cis-1,2-Dichloroethylene 70 (A) 620 93,000 2.0E+5 5.30E+05 cis-1,3-Dichloropropylene NA NA NA NA NA
Cyclohexane NA NA NA NA NA
Dibromochloromethane 80 (A,W) ID 14,000 18,000 ID
Dibromomethane 80 NA ID 5.3E+5 ID
Dichlorodifluoromethane 1,700 ID 2.2E+05 3.0E+5 (S) ID
Diethyl ether 10 (E) ID 6.1E+7 (S) 3.5E+7 6.50E+05
Diisopropyl Ether 30 ID 8,000 (S) NA 8,000 (S)
Ethylbenzene (I) 74 (E) 18 1.1E+05 1.7E+5 (S) 43,000
Ethyltertiarybutylbenzene NA NA NA NA NA
Hexachloroethane 7.3 6.7 (X) 27,000 1,900 ID
Isopropylbenzene (Cumene) 800 28 56,000 (S) 56,000 (S) 29,000
Flammability &
Explosivity
Screening
Levels
Residential Drinking
Water Criteria
Groundwater
Surface Water
Interface Criteria
Residential
Groundwater
Volatilization to Indoor
Air Inhalation Criteria
Groundwater
Contact Criteria
SB-24 SB-25 SB-26 SB-27 SB-28 SB-29 SB-30 SB-31 SB-32 SB-33 DUP-2 SB-34 SB-35
(4.5-9.5') (5-10') (5-10') (5-10') (5-10') (5-10') (5-10') (5-10') (5-10') (6-11')
SB-33 (6-
11') (4-9') (5-10')
8/3/2009 8/3/2009 8/3/2009 8/3/2009 8/3/2009 8/4/2009 8/4/2009 8/4/2009 8/4/2009 8/5/2009 8/5/2009 8/6/2009 8/6/2009
8/12/2009 8/12/2009 8/12/2009 8/12/2009 8/12/2009 8/12/2009 8/13/2009 8/12/2009 8/13/2009 8/12/2009 8/12/2009 8/12/2009 8/12/2009
8260 8260 8260 8260 8260 8260 8260 8260 8260 8260 8260 8260 8260
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
11 <1 <1 <1 <1 <1 1.1 8.4 71 43 42 <1 <1
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
67 <1 <1 <1 <1 <1 1.4 31 170 88 90 <1 <1
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
9.3 <1 <1 <1 <1 <1 <1 3.5 26 9.7 9.6 <1 <1
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 (5) <5 (5)
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 (5) <5 (5)
31 (*) <5 (*) <5 (*) <5 (*) <5 (*) <5 (*) <5 (*) 17 (*) 200 (*) 44 (*) 48 (*) <5 (*) <5 (*)
<20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
<5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z)
<1 <1 <1 <1 49 <1 <1 8.2 27 260 300 <1 <1
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
7.8 <5 <5 <5 <5 <5 <5 (7) <5 7.7 (7) 12 12 <5 <5
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 (5) <5 (5)
<5 (5) <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
<1 <1 <1 <1 <1 <1 <1 <1 13 27 26 <1 <1
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 (+) <5 (+)
12 <1 4.8 3.9 2 <1 2.9 9.1 28 21 21 <1 <1
WOO_GW_Analytical_2009-2010 092111 (jch KL).xlsx K_Water VOC Page 3 of 8
WAYNE OAKLAND OIL SITE
ROYAL OAK, MICHIGAN
Sample ID
Screen Interval (ft bgs)
Date Collected
Date Analyzed
EPA Analytical Method
Analyte
1,1,1,2-Tetrachloroethane 77 ID 15,000 30,000 ID
Flammability &
Explosivity
Screening
Levels
Residential Drinking
Water Criteria
Groundwater
Surface Water
Interface Criteria
Residential
Groundwater
Volatilization to Indoor
Air Inhalation Criteria
Groundwater
Contact Criteria m & p-Xylenes (I) 280 (E) 41 1.9E+5 (S) 1.9E+5 (S) 70,000
Methyl Iodide NA NA NA NA NA
Methylene chloride 5.0 (A) 1,500 (X) 2.2E+05 2.2E+5 ID
Methyl-tert-butyl Ether (MTBE) 40 (E) 7,100 (X) 4.7E+7 (S) 6.10E+5 ID
Naphthalene 520 11 31,000 (S) 31,000 (S) NA n-Butylbenzene 80 ID ID 5,900 ID n-Propylbenzene (I) 80 ID ID 15,000 ID o-Xylene (I) 280 (E) 41 1.9E+5 (S) 1.9E+5 (S) 70,000 p-Isopropyltoluene NA NA NA NA NA sec-Butylbenzene 80 ID ID 4,400 ID
Styrene 100 (A) 80 (X) 1.7E+05 9,700 1.40E+05 tert-Butylbenzene (I) 80 ID ID 8,900 ID tertiary Butyl Alcohol 3,900 NA 1.0E+9 (D,S) 7.9E+7 6.10E+07 tertiary Amylmethylether 190 (E) NA 2.6E+05 2.6E+6 (S) NA
Tetrachloroethylene 5.0 (A) 60 (X) 25,000 12,000 ID
Tetrahydrofuran 95 11,000 (X) 6.9E+06 1.6E+6 60,000
Toluene (I) 790 (E) 270 5.3E+5 (S) 5.3E+5 (S) 61,000 trans-1,2-Dichloroethylene 100 (A) 1,500 (X) 85,000 2.2E+5 2.30E+05 trans-1,3-Dichloropropene NA NA NA NA NA trans-1,4-Dichloro-2-butene NA NA NA NA NA
Trichloroethylene 5.0 (A) 200 (X) 15,000 22,000 ID
Trichlorofluoromethane 2,600 NA 1.1E+6 (S) 1.1E+6 (S) ID
Vinyl Chloride 2.0 (A) 13 (X) 1,100 1,000 33,000
Xylenes, Total (I) 280 (E) 41 1.9E+5 (S) 1.9E+5 (S) 70,000
Notes:
Analytical results are presented in µg/l.
"ND” indicates analyte concentration was not detected above laboratory detection limit.
"<" indicates that the parameter was analyzed but not detected above the corresponding laboratory method detection limit.
Criteria are from Part 201 Cleanup Criteria and Part 213 Risk-Based Screening Levels (RBSLs), updated March 25, 2011.
Bolded concentrations represent a concentration above detection limits.
Highlighted concentrations indicate concentrations exceeding at least one criteria or screening level.
(5) indicates result and RL are estimated due to low continuing calibration standard criteria failure.
(7) indicates results(s) and RL(s) are estimated due to poor precision.
(+) indicates result and RL are estimated due to initial calibration standard criteria failure.
(*) indicates methods 8260 & 624 are used to analyze volatile organics that have boiling points below 200ºC. 2-Metylnaphthalene & naphthalene have boiling points above 200ºC and are better suited to analysis by methods 8270 or 625 as semivolatile organics.
(Z) indicates result reported below the RL to meet the TDL in RRD Op Memo 2 (10/22/04) multiplied by applicable dilution factor.
See the Analytical Results Notes Page found at the end of the Tables section for footnotes related to Part 201 criteria.
SB-24 SB-25 SB-26 SB-27 SB-28 SB-29 SB-30 SB-31 SB-32 SB-33 DUP-2 SB-34 SB-35
(4.5-9.5') (5-10') (5-10') (5-10') (5-10') (5-10') (5-10') (5-10') (5-10') (6-11')
SB-33 (6-
11') (4-9') (5-10')
8/3/2009 8/3/2009 8/3/2009 8/3/2009 8/3/2009 8/4/2009 8/4/2009 8/4/2009 8/4/2009 8/5/2009 8/5/2009 8/6/2009 8/6/2009
8/12/2009 8/12/2009 8/12/2009 8/12/2009 8/12/2009 8/12/2009 8/13/2009 8/12/2009 8/13/2009 8/12/2009 8/12/2009 8/12/2009 8/12/2009
8260 8260 8260 8260 8260 8260 8260 8260 8260 8260 8260 8260 8260
16 <2 <2 <2 <2 <2 <2 14 57 68 67 <2 <2
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<5 (*) <5 (*) <5 (*) <5 (*) <5 (*) <5 (*) <5 (*) 27 (*) 220 (*) 58 (*) 58 (*) <5 (*) <5 (*)
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
17 <1 2.5 1.7 <1 <1 3.8 9.6 35 25 26 <1 <1
1.2 <1 <1 <1 <1 <1 <1 1.2 3.3 5.3 5.2 <1 <1
3.1 <1 <1 <1 <1 <1 <1 1.5 9.5 3.7 3.9 <1 <1
4.4 <1 3.1 3.2 <1 <1 2.9 3.8 10 4.8 4.8 <1 <1
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<50 (5) <50 (5) <50 (5) <50 (5) <50 (5) <50 (5) <50 (5) <50 (5) <50 (5) <50 (5) <50 (5) <50 (5) <50 (5)
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 (5) <5 (5)
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5
<1 <1 <1 <1 <1 <1 <1 <1 <1 4.8 4.7 <1 <1
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z) <5 (Z)
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 1.6
<1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1
<3 <3 <3 <3 <3 <3 <3 15.2 60.3 73.3 72.2 <3 <3
WOO_GW_Analytical_2009-2010 092111 (jch KL).xlsx K_Water VOC Page 4 of 8
WAYNE OAKLAND OIL SITE
ROYAL OAK, MICHIGAN
Sample ID
Screen Interval (ft bgs)
Date Collected
Date Analyzed
EPA Analytical Method
Analyte
1,1,1,2-Tetrachloroethane 77 ID 15,000 30,000 ID
1,1,1-Trichloroethane 200 (A) 89 6.6E+05 1.3E+6 (S) ID
1,1,2,2-Tetrachloroethane 8.5 78 (X) 12,000 4,700 ID
1,1,2-Trichloroethane 5.0 (A) 330 (X) 17,000 21,000 NA
1,1-Dichloroethane 880 740 1.0E+06 2.4E+6 3.80E+05
1,1-Dichloroethylene (I) 7.0 (A) 130 200 11,000 97,000
1,2,3-Trichlorobenzene NA NA NA NA NA
1,2,3-Trichloropropane 42 NA 8,300 84,000 NA
1,2,3-Trimethylbenzene NA NA NA NA NA
1,2,4-Trichlorobenzene 70 (A) 99 (X) 3.0E+5 (S) 19,000 NA
1,2,4-Trimethylbenzene (I) 63 (E) 17 56,000 (S) 56,000 (S) 56,000 (S)
1,2-Dibromo-3-chloropropane 0.2 (A) ID 1,200 (S) 390 NA
1,2-Dibromoethane (EDB) 0.05 (A) 5.7 (X) 2,400 25 ID
1,2-Dichlorobenzene 600 (A) 13 1.6E+5 (S) 1.6E+5 (S) NA
1,2-Dichloroethane (I) 5.0 (A) 360 (X) 9,600 19,000 2.50E+06
1,2-Dichloropropane (I) 5.0 (A) 230 (X) 16,000 16,000 5.50E+05
1,3,5-Trimethylbenzene (I) 72 (E) 45 61,000 (S) 61,000 (S) ID
1,3-Dichlorobenzene 6.6 28 18,000 2,000 ID
1,4-Dichlorobenzene 75 (A) 17 16,000 6,400 NA
2-Butanone (MEK) (I) 13,000 2,200 2.4E+8 (S) 2.4E+8 (S) ID
2-Hexanone 1,000 ID 4.2E+06 5.2E+6 NA
2-Methylnaphthalene 260 19 25,000 (S) 25,000 (S) ID
2-Propanone (acetone) (I) 730 1,700 1.0E+9 (D,S) 3.1E+7 1.50E+07
4-Methyl-2-Pentanone (MIBK) (I) 1,800 ID 2.0E+7 (S) 1.3E+7 ID
Acrylonitrile (I) 2.6 2.0 (M); 1.2 34,000 14,000 6.40E+06
Benzene (I) 5.0 (A) 200 (X) 5,600 11,000 68,000
Bromobenzene (I) 18 NA 1.8E+05 12,000 ID
Bromochloromethane NA NA NA NA NA
Bromodichloromethane 80 (A,W) ID 4,800 14,000 ID
Bromoform 80 (A,W) ID 4.7E+05 1.4E+5 ID
Bromomethane 10 35 4,000 70,000 ID
Carbon disulfide (I,R) 800 ID 2.5E+05 1.2E+6 (S) 13,000
Carbon Tetrachloride 5.0 (A) 45 (X) 370 4,600 ID
Chlorobenzene (I) 100 (A) 25 2.1E+05 86,000 1.60E+05
Chloroethane 430…
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