HWAD New Bomb Class 2 Q73.pdf

CLASS II OPERATING PERMIT RENEWAL APPLICATION

FOR

HAWTHORNE ARMY DEPOT

NEW BOMB AREA

Prepared by:

18124 Wedge Parkway, #502

Reno, Nevada 89511

(775) 240-0826 www.mm-eem.com

MAY 2016

http://www.mm-eem.com/

THE NEW BOMB AREA, HAWTHORNE ARMY DEPOT

CONTENTS

Section

Introduction

Page

Process Description 6

Tables

1-1 Facility Summary of Potential Emissions

Figures

1-1 Regional Map

1-2 Topography 5

1-3 Aerial Image of the Facility 8

ATTACHMENTS

Operating Permit Application Forms for Class II Operating Permit Renewal

General Facility Information

Appendix 1 - Emission Units Application Forms

Appendix 2 - Insignificant Activity Information Form

Appendix 3 - Facility-Wide Potential to Emit Tables

Appendix 4 - Detailed Emissions Calculations

Appendix 5 - Emissions Cap

Appendix 6 - Process Flow Diagram, Plot Plan, Map, Dust Control Plan

Appendix 7 - Environmental Evaluation and Dispersion Modeling Files

Appendix 8 - Application Certification

1. INTRODUCTION

Hawthorne Army Depot (HWAD) is applying for renewal of its Class II Operating Permit at the

New Bomb Area of HWAD. This document presents the required application forms to renew this permit. The operating permit renewal application will propose identical emission limits and conditions as the existing operating permit (Permit No. AP 9711-1134.01).

The New Bomb Area is associated with and staffed by the personnel from HWAD. The facility is located approximately 22 miles south of HWAD in Mineral County, Nevada and occupies approximately 3,183 acres of Army owned land. The New Bomb facility is located west of state highway 359 in steep terrain accessed by a single dirt road. Public access to the facility is completely restricted. The main area of operation in the facility is around Universal Transverse

Mercator (UTM) coordinates 4,234.057 kilometers (km) north and 356.274 km east (Zone 11, North American Datum [NAD] 83). Figure 1-1 presents the regional map. Figure 1-2 illustrates the topography of the facility. Figure 1-3 provides the aerial image of the facility.

The New Bomb facility is designed to treat waste munitions and is operated as a detonation treatment unit. The facility receives munitions that have been stored in magazines located at the

HWAD Main Base. Personnel at HWAD make the determination that certain munitions have become unserviceable or obsolete and require disposal. Explosive items typically detonated at N e w

Bomb Area consist of cartridges, projectiles, bombs, rockets, artillery, and mortar rounds.

Treatment by detonation takes place in 16 x 6 x 4 foot earthen cells. A total of twenty cell areas are available for detonation with ten cells located at the northern base of a 185- foot high ridge and another ten located at the southern base of the ridge. These cells are repaired after each treatment session for future treatments.

Emission sources are the existing open pit detonation pits (Pit #1- Pit #20). Emissions of all the criteria air pollutants from the New Bomb facility are classified as fugitive emissions, in accordance with the definition of "Fugitive Emissions" in NAC 445B.077. The air pollutants emissions from the detonation operations at the New Bomb facility cannot be reasonably expected to pass through a stack, chimney, vent, or a functionally equivalent opening.

The original calculations which were the basis for the limits in the existing operating permit will remain the same. Table 1-1 summarizes the proposed limits on air emissions of criteria pollutants from the detonation operations at the New Bomb facility.

The proposed caps for the permit renewal are identical with the caps originally proposed for the

New Bomb facility. This facility will continue to demonstrate compliance with all existing monitoring, recordkeeping and reporting requirements of the permit.

The Department of the Army, Hawthorne Army Depot will not discharge or cause the discharge into the atmosphere from the New Bomb facility, the following pollutants in excess of the following limits:

a. The individual discharge of each single hazardous air pollutant (HAP) to the atmosphere will not exceed 9.9 tons per calendar year.

b. The combined discharge of HAPs to the atmosphere will not exceed 24.9 tons per year.

Table 1-1

New Bomb Area’s Potential Fugitive Emissions

Pollutant Potential to Emit

(pounds per day)

Potential to Emit

(tons per year)

Total Particulate Matter (PM) 22,000 1,314

Particulate Matter as PM10

Carbon Monoxide

Sulfur Dioxide

Oxide of Nitrogen

Volatile organic Compounds

22,000 1,314

1,560 117.0

8.8 0.66

148 11.10

64 4.8

FIGURE 1-1

REGIONAL MAP

New Bomb Restricted Area

Figure 1-2 New Bomb Area Topography and Boundary

2. PROCESS DESCRIPTION

The New Bomb facility of HWAD has the responsibility to demilitarize and dispose of unserviceable ammunition and explosives items. Thermal treatment of munitions or military energetic materials by detonation is conducted at the New Bomb facility for demilitarization activities. Detonation is used for treatment of military energetic materials because it is the only safe and effective treatment process currently available for most military energetic material items.

Unserviceable munitions items that are stored in magazines located at the HWAD Main Base are transferred to the New Bomb facility in semi-trailer trucks for treatment by detonation.

Ammunition and projectiles are moved in containers placed on wooden pallets and are delivered to the Materials Staging Area at the New Bomb facility. Explosive items typically treated at the New

Bomb facility consist of cartridges, projectiles, bombs, rockets, small arms, artillery, mortar, and powders.

The detonation process is a batch process. A typical detonation operation takes place in a 20-foot by 6-foot earthen cell dug at least 4 feet deep (Figure 1-4). The cell has sloping sides approximately 10-20 degrees with the vertical. The specific dimensions of each cell will vary depending on the amount and type of munitions to be treated. A total of 20 cell areas are available for detonation with 10 cells located at the northern base of a 185-foot high and 1,300-foot long ridge, and another 10 cells located at the southern base of the ridge. The minimum distance between adjacent cells is 75 feet, to prevent sympathetic detonation. The detonation cells are located in the central section of the New Bomb facility.

The detonation cells or pits are typically dug at the time a detonation operation is planned. But i n the case where an existing pit is used for detonation, inspection for any standing water is conducted. Detonation operations would not take place in any cell in which precipitation has accumulated.

Unusable munitions are placed at the center of the detonation cell. Donor explosive, usually trinitrotoluene (TNT), is placed with the munitions, typically at a 1:1 ratio, to achieve complete reaction. Other than TNT, different types of bulk energetic materials may also be used as donor explosives. HWAD can also use other ordnance items as a source of donor explosives. Donor material punctures shell casings and allows explosives within the shells to be exposed to thermal treatment. After placement of the unserviceable munitions within the cell, one-inch soil cover is provided to avoid sympathetic detonations from adjacent cells during treatment.

The maximum amount of munitions and donor explosive (TNT or any other bulk energetic material or any other ordnance items that contain donor explosives) per cell is 4,000 pounds Net Explosive

Weight (NEW).

Pre-detonation and post-detonation maintenance activities are conducted at the New Bomb facility and include (1) checking all areas for unexploded ammunition and explosives, (2) picking up all metal scrap from road and pit area, (3) removing all unused detonating initiators from the New

Bomb facility and returning them to storage, (4) grooming road network, p i t s , and areas around pits with grader and/or dozer as necessary, (5) performing housekeeping in and around vicinity of buildings located at the New Bomb facility, and (6) clearing immediate a n d surrounding areas of vegetation and other combustible material to ensure minimization of fire hazard.

Following every detonation, HWAD personnel inspect the area for any possible misfires and low order/partial detonation. In case of a misfire, a new firing system is attached and the pile is re-detonated. In case of a low order/partial detonation, the area is posted with an overnight guard to secure the area and to communicate any further hazards.

All scrap metal generated by detonation operations is visually inspected to assure that no explosives are present. After verification and certification that the scrap metal is 100 percent inert, it is transported to HWAD Main Base by semi-trailer trucks, where it is decontaminated at t h e

WADF, and then sold as a scrap metal.

The New Bomb facility is a treatment unit only and does not store any hazardous waste. All materials are treated the day they are transported to the New Bomb facility. Also, certain meteorological conditions must exist before any detonation operation begins. Detonation is not conducted during periods of a greater than 50 percent chance of precipitations and thunder storms.

The detonation operations are limited per the Standard Operating Procedure (SOP) to include daytime operation, winds more than 3 miles per hour and less than 20 miles per hour, no electrical/thunder storms, no periods of reduced visibility less than one mile, and surface winds not blowing to carry smoke and/or byproducts over any populated areas or public road within one mile of the New Bomb facility. There is particulate matter less than or equal 10 micrometers in diameter (PM10) ambient air monitoring program associated with detonation operations. A meteorological station was installed at the New Bomb facility in June 1996 and the meteorological data is currently being accumulated, and is also being used to assure compliance with the SOP.

However, the long-term meteorological forecast data is presently obtained through the Department of Defense Weather Station or the National Weather Station.

In addition to the 20 cell areas, seven small buildings exist within the New Bomb facility for use as shelters and storage sheds. The closest receptor to the New Bomb facility lies nine miles away

(Sweetwater Ranch). State Highway 359 lies approximately 4,000 feet from the detonation unit.

The closest resident population is about 22 miles to the north at the town of Hawthorne.

FIGURE 1-3

Aerial Image of the Facility

Detonation Cells

ATTACHMENTS

Class II Operating Permit

Application Forms

Application for

Class II Air Quality

Operating Permit Renewal

GENERAL COMPANY INFORMATION

All applicants shall complete each item or explain in the space provided why no information is needed. Please specify

"N/A" (Not Applicable) if necessary. The application will be returned to the applicant if it is deemed incomplete.

1. COMPANY NAME AND ADDRESS THAT ARE TO APPEAR ON THE OPERATING PERMIT

[NAC 445B.295.1]:

Department of the Army, Hawthorne Army Depot (Name)

1 South Maine Avenue (Address)

Hawthorne Nevada 89415-5000 (City) (State) (Zip Code)

2. Owner's Name and Address [NAC 445B.295.1]:

Same as above (Name)

(Address)

(City) (State) (Zip Code)

3. Source Name and Mailing Address, if different from #1 [NAC 445B.295.1]:

New Bomb Area (Name)

Same as above (Address)

(City) (State) (Zip Code)

4. Physical Location of Stationary Source [NAC 445B.295.8]: (if no physical address, describe location, e.g., 4 miles south of I-80 at xx Interchange)

Approximately 22 miles south of Hawthorne

Township(s) 5N Range(s) 30E Section(s) 33

5. Plant Manager or Other Appropriate Contact [NAC 445B.295.1]:

George Gram General Manager, SOC (Name) (Title)

2 South Main Avenue (Address)

Hawthorne Nevada 89415 (City) (State)

775-945-7660 775-945-7659

(Zip Code) george.gram@soc-usa.com (Telephone #) (FAX #) (E-mail address) mailto:clifford.cichowalz@dzhc.net

GENERAL COMPANY INFORMATION (CONTINUED)

6. Responsible Official Name, Title and Address [NAC 445B.295.1]:

Charles King Environmental Coordinator

(Name) (Title)

5 south Maine Avenue (Address)

Hawthorne Nevada 89415

(City)

775-945-7317

(State)

775-945-7775

(Zip Code)

(Telephone #) (FAX #) (E-mail address)

7. If records required under the operating permit will be kept at a location other than the source, specify that location [NAC 445B.295.7].

Environmental Offices of SOC

(Name)

2 South Main Street

(Address)

Hawthorne

(City)

Nevada

(State)

89415

(Zip Code)

8. This application is being submitted for the following (please check appropriate box below):

A new Class II Operating Permit

Renewal of a Class II Operating Permit

Revision of a Class II Operating Permit

9. Application Submittal:

Please remove the cover page, Table of Contents and General Information page and all Attachments of the application packet. Submit the remainder of the application packet as your formal application. This should consist of, at a minimum, the Class II Application cover page, the General Company Information and Appendices

1 through 8.

Appendix 1

EMISSION UNITS

APPLICATION FORMS

INDUSTRIAL PROCESS

APPLICATION FORM

CLASS II OPERATING PERMIT

Section 1 - Equipment Description

Check here if this is an alternative operating scenario

a. Type of equipment: Detonation for Treatment of Military Energetic Materials

b. Standard Industrial Classification (SIC) Code 9711

c. Manufacturer of equipment NA

d. Model number NA Serial number NA *Equip. number NA

e. Date equipment manufactured: NA

f. Please check one: Temporary (At the same location for less than 12 months)

Stationary (At the same location for more than 12 months)

g. For crushers: size output setting, check one: Primary (4")

Secondary (< 4" but 1")

Tertiary (< 1")

h. Please check if portable: Portable (transportable or movable within the confines of the stationary source)

i. UTM Coordinates 4,224,470 meters N; 359,210 meters E; Zone 11

j. Basic equipment dimensions (feet): L W H

*The equipment number is the facility's own numbering system for this piece of equipment.

Section 2 - Design Rate/Operating Parameters

*Note: Please complete if other than the maximum design capacity (tons per hour and tons per year) and/or the maximum hours of operation (24 hours per day, 8760 hours per year) are being requested. The permit will be limited to these values.

1Note: Due to the schedule and frequency of detonations, operating rates and design capacities can only be estimated on a daily rate.

Maximum design capacity (tons per day1) 20

Requested operating rate (tons per day1)* 20

Requested operating time: (time of day)* 9:00 am to Dusk Hours per day Days per year Hours per year

Batch load or charge weight (tons) 2.0 per detonation pit

Total hours required to process batch or charge NA

f. Maximum operating rate (tons per year) 3,000

Requested operating rate (tons per year)* 3,000

Type of material processed TNT, Bulk Energetic Material or any other ordinance items

i. Minimum moisture content NA

Section 3 - Fuel Usage

APPLICATION FORM

CONTINUED

(This section only applies to fuel consumed/combusted within the process unit. Fuels consumed/combusted in combustion units are to be listed on the Combustion Equipment Application Form.)

Type of Fuel Amount Used Per

Hour

Heat Content

(specify in Btus)

Ash Content

(% by weight)

Sulfur

Content

( % by weight)

Trace

Elements

(% by weight)

Oil- Specify

Type(s)

None gallons gallons

Gasoline gallons

Propane cubic feet

Natural Gas cubic feet

*Waste Oil gallons

Other

None

Type of

Fuel

Amount

Used

Per

Hour

(tons)

Heat

Content

(specify in Btus)

Ash

Content

(% by weight)

Sulfur

Content

(% by weight)

Trace

Elements

(% by weight)

Percent moisture

Percent volatile matter

Percent fixed carbon

Coal -

Specify

Type(s)

None

If more than one type of fuel is combusted, under this operating scenario please specify primary fuel and percentage on a maximum hourly and annual basis (if fuel blending is the primary fuel, identify percentages of each fuel blended). Attach additional information to this form if necessary.

*Firing of waste oil will require multi metals test to insure fuel is non-hazardous.

CONTINUED

Section 4 - Pollution Control Equipment/Exhaust Stack Parameters (this section must be completed) -Complete for emissions exhausting through a stack, chimney or vent: (baghouse, wet scrubber, cyclone, low NOx burner, no control, etc.)

Control #1 Control #2

Type of Control

(See Note 1)

NA

Pollutant(s) Controlled

Manufacturer

Manufacturer's

Guarantee (see Note 2)

Stack height (feet from ground level)

Stack inside diameter

(feet)

Temperature (°F) at design capacity

Stack exit velocity (feet per second)

Gas volume flow rate:

Actual cubic feet per minute

Gas volume flow rate:

Dry standard cubic feet per minute

-Complete for Emissions not exhausting through a stack, chimney or vent: (water sprays, fogging water sprays, pneumatic fogging system, high moisture ore, no control, etc.)

Control #1 Control #2

Type of Control

(See Note 1)

Best Operating Practices

Based on Meteorological Data

Pollutant(s) Controlled Particulate Matter

Manufacturer

Manufacturer's

Guarantee (see Note 1)

Note: Indicate the specific point(s) of emission control application for this emission unit. This must be provided as part of the process flow diagram as required in section 7 of the General Information section of the application form.

Note 1: Specify "uncontrolled" if no pollution control device is installed.

Note 2: Manufacturer's guarantee of control efficiency must be attached to this form if the control efficiency claimed is greater than the control efficiency ratings provided in the Bureau of Air Pollution Control's Emissions Control Technology - Control

Efficiency Ratings provided in Attachment 4.

Section 5 - Requested Emission Limits

APPLICATION FORM

CONTINUED

Pollutant Potential to

Emit

(*pounds/day)

Potential to

Emit

(tons/year)

Calculation (including reference) on Which

Emissions Information is Based (attach supporting information if necessary)

Total Particulate Matter

(PM)

22,000

1,314

Identical to original permit. Operating parameters are based on number of detonations per day.

Therefore potential to emit cannot be based on the hourly rates (pounds/hour).

Particulates as PM10 22,000 1,314 Worst Case: Assume PM2.5 =PM10 Emissions Sulfur Dioxide 8.8 0.66

Carbon Monoxide 1,560 117.0

Oxides of Nitrogen 148 11.10

Volatile Organic

Compounds

64.00 4.80

Lead 5.40

Hydrogen Sulfide NA NA

Hazardous Air Pollutants

(Specify Each Pollutant1)

382.56 24.94

1,3-Butadienea

0.2600 0.0198

4-Nitrophenola

0.0100 0.0005

Acetophenonea

0.0100 0.0005

Benzenea

5.2000 0.3900

Polycyclic Organic Matter 0.0400 0.0031

Benzo(b)fluoranthenea

0.0200 0.0018

Dibenz(a,h)anthracenea

0.0200 0.0013

Dibenzofuransa

0.0100 0.0007

Di-n-butyl Phthalatea

0.3900 0.0294

Dimethyl Phthalatea

0.0100 0.0007

Di(2-ethylhexyl) Phthalatea

0.0800 0.0057

Ethyl Benzenea

0.4000 0.0300

Hexanea

0.3200 0.0240

Cyanide Compounds 92.000 6.9000

Hydrogen Cyanidea

92.000 6.9000

Naphthalenea

0.1200 0.0090

Phenola

0.0700 0.0054

Styrene 209.20 8.9700

Styrene (from casings)b

192.00 7.6800

Styrene (from combustion)a

17.200 1.2900

Toluenea

2.6800 0.2010

Xylenes (Isomers and

Mixtures)a

2.1600 0.1620

Antimony Compounds 8.0000 0.3200

Antimonyb

8.0000 0.3200

Lead Compounds 5.4000

Leadc 5.4000

Manganese Compounds 52.000 2.0800

Manganese (from casings)b

52.000 2.0800

Nickel Compounds 9.6000 0.3840

Nickelb

9.6000 0.3840

*Hourly operating period not applicable to detonation activity; listed proposed limit in pounds/day 1A list of Hazardous Air Pollutants is contained in Attachment 4.

2Other Regulated Pollutants include any Class I or Class II substance subject to a standard adopted pursuant to 42 U.S.C. SS 7671-7671q, inclusive.

aCalculated using the emission factor provided in Table A-27 and multiplying it by a daily limit of 40,000 pounds per day and 6,000,000 pounds per year of NEW.

bCalculated using the emission factor provided in Table A-27 and multiplying it by a daily limit of 40,000 pounds per day and 3,200,000 pounds per year of NEW.

cEmission limit established at 5.4 tons per year to keep the New Bomb facility a synthetic minor source by limiting the total HAP emissions to less than 25 tons per year.

SURFACE AREA DISTURBANCE

CLASS II OPERATING PERMIT

1. Project Name New Bomb Area

2. Surface Area Disturbance Location:

Overall disturbance location description:

Township 5N ; Range 30E ; Section(s) 33 ;

Township ; Range ; Section(s) ;

3. Indicate the total number of acres to be disturbed for the project 743

4. Nevada Administrative Code 445B.22037 requires fugitive dust to be controlled (regardless of the size or amount of acreage disturbed), and requires an ongoing program, using best practical methods, to prevent particulate matter from becoming airborne. All activities which have the potential to adversely affect the local air quality must implement all appropriate measures to limit controllable emissions. Appropriate measures for dust control may consist of a phased approach to acreage disturbance rather than disturbing the entire area all at once; using wet suppression through such application methods as water trucks or water sprays systems to control wind blown dust; the application of soil binding agents or chemical surfactant to roadways and areas of disturbed soil; as well as the use of wind-break or wind-limiting fencing designed to limit wind erosion of soils.

5. Dust Control Plan (please visit http://ndep.nv.gov/bapc/download/class2 for additional information regarding dust control plans).

a. For Pahrump Valley, please include a dust control plan in Appendix 6 if the total number of acres to be disturbed listed in 3 above equals or exceeds 5 acres.

b. Please include a dust control plan in Appendix 6 if the total number of acres to be disturbed in number 3 above equals or exceeds 20 acres.

The dust control measures discussed in 4 above should be considered in the preparation of the required dust control plan. The acceptance of the dust control plan by the Bureau of Air Quality does not limit the permit holder's need to control fugitive dust from the disturbance and its related activities, nor from putting into effect an ongoing program for using the best practical methods of dust control.

Surface Area Disturbance Page 1 of 1 http://ndep.nv.gov/bapc/download/class2

Appendix 2

INSIGNIFICANT

ACTIVITY INFORMATION

FORM

Instructions

Attachment 1 contains the Approved List of Insignificant Activities. Attachment 3 contains the List of Trivial

Activities. Trivial activities are exempted from consideration. PLEASE RESPOND ON THE

INSIGNIFICANT EMISSION UNITS INFORMATION FORM TO SECTIONS 1 THROUGH 4, FOR

EACH INSIGNIFICANT EMISSION UNIT [NAC 445B.295.8].

Section 1. List all insignificant activities that are exempt pursuant to NAC 445B.288.2(a) through (h), and list the appropriate section that provides for the exemption. Provide information sufficient to show that the exemption applies (a copy of NAC 445B.288.2 is provided in Attachment 2).

Section 2. List all insignificant activities that are exempted because they are on the list approved and maintained by the Director pursuant to NAC 445B.288.4. Provide information sufficient to show that the exemption applies.

Section 3. List all proposed insignificant activities that are not already contained in the list in Attachment 1.

Provide sufficient description of activities, and all emission calculations and references. The list of proposed insignificant activities must also be submitted, under separate cover, to the Director for his review and approval.

Section 4. This section must be completed if the potential to emit for all other emitting activities associated with the stationary source exceeds 60 tons per year for any individual regulated air pollutant. If the potential to emit is below the 60 ton per year threshold, only sections 1 through 3 of this form must be completed (-lease attach additional sheets as necessary). If the potential to emit exceeds the 60 tons per year threshold, emissions calculations to determine maximum uncontrolled emissions for each insignificant activity must be provided and included in Appendix 4. Calculate the maximum uncontrolled emissions for insignificant activities listed under Sections 1 through

3, if the . Emissions calculations must be based on the maximum design throughput, maximum design production rate, maximum design heat input rate value, no controls, and 8760 hours per year of operation, unless otherwise indicated in NAC 445B.288.2 or on the list of approved insignificant activities provided in Attachment 1.

Section 1 - List All Emission Units that are Insignificant Activities Pursuant to NAC 445B.288.2(a) through

(h) (see Attachment 2 for regulation).

Emission Unit Exemption Regulation

(Example - NAC 445B.288.2(b)) Reason Exemption Applies

Section 2 - List All Emission Units Proposed as Insignificant Activities Pursuant to List Approved by the

Director (see Attachment 1 - List of Approved Insignificant Activities)

Emission Unit Reason Exemption Applies

Section 3 - List All Emission Units Proposed as Insignificant Activities and Not Otherwise Listed in Section 1 or

Section 2 (NAC 445B.288.4). Proposed insignificant activities from this Section must be submitted, under separate cover, to the Director for his approval. The submittal must include a sufficient description of the emission unit(s), all emissions calculations, and references.

Emission Unit

Section 4 -Emissions Calculations - Insignificant Emission Units/Activities Calculate the maximum uncontrolled emissions for insignificant activities listed under Sections 1 through 3.

Emissions calculations must be based on the maximum design throughput, maximum design production rate, maximum design heat input rate value, no controls, and 8760 hours per year of operation, unless otherwise indicated in NAC 445B.288.2 or on the list of approved insignificant activities provided in Attachment 1. No consideration for emissions reduction from pollution controls or limits on the hours of operation or other operational constraints may be allowed unless otherwise approved by the Director or as indicated in NAC

445B.288.3 or on the list provided in Attachment 1.

Appendix 3

FACILITY-WIDE

POTENTIAL TO EMIT

TABLES

TABLE 1

FACILITY-WIDE (STATIONARY SOURCE)

POUNDS/HOUR AND TONS/YEAR

Pollutant Potential to Emit

(*pounds/day)

(tons/year)

Total Particulate Matter (PM) 22,000 1,314 Particulates as PM10 22,000 1,314 Sulfur Dioxide 8.8 0.66 Carbon Monoxide 1,560 117 Oxides of Nitrogen 148 11.1 Volatile Organic Compounds 64 4.8 Lead 5.4 Hazardous Air Pollutants

(Specify Each Pollutant1) 24.94

1,3-Butadienea

0.2600 0.0198

4-Nitrophenola

0.0100 0.0005

Acetophenonea

0.0100 0.0005

Benzenea

5.2000 0.3900

Polycyclic Organic Matter 0.0400 0.0031 Benzo(b)fluoranthenea

0.0200 0.0018

Dibenz(a,h)anthracenea

0.0200 0.0013

Dibenzofuransa

0.0100 0.0007

Di-n-butyl Phthalatea

0.3900 0.0294

Dimethyl Phthalatea

0.0100 0.0007

Di(2-ethylhexyl) Phthalatea

0.0800 0.0057

Ethyl Benzenea

0.4000 0.0300

Hexanea

0.3200 0.0240

Cyanide Compounds 92.000 6.9000 Hydrogen Cyanide 92.000 6.9000

Naphthalenea

0.1200 0.0090

Phenola

0.0700 0.0054

Styrene 209.20 8.9700 Styrene (from casings)b

192.00 7.6800 Styrene (from combustion)a

17.200 1.2900

Toluenea

2.6800 0.2010

Xylenes (Isomers and Mixtures)a

2.1600 0.1620

Antimony Compounds 8.0000 0.3200 Antimonyb

8.0000 0.3200

Lead Compounds

Leadc

5.4000

Manganese Compounds

Manganese (from casings)b

52.000 2.0800

Nickel Compounds

Nickelb

9.6000 0.3840

*Hourly operating period not applicable to detonation activity; listed proposed limit in pounds/day 1A list of Hazardous Air Pollutants is contained in Attachment 4.

2Other Regulated Pollutants include any Class I or Class II substance subject to a standard adopted pursuant to 42 U.S.C. SS 7671-7671q, inclusive.

aCalculated using the emission factor provided in Table A-27 and multiplying it by a daily limit of 40,000 pounds per day and

6,000,000 pounds per year of NEW.

bCalculated using the emission factor provided in Table A-27 and multiplying it by a daily limit of 40,000 pounds per day and

3,200,000 pounds per year of NEW.

cEmission limit established at 5.4 tons per year to keep the New Bomb facility a synthetic minor source by limiting the total

HAP emissions to less than 25 tons per year.

TABLE 2

INSIGNIFICANT ACTIVITIES

POUNDS/HOUR AND TONS/YEAR

Insignificant Activity Pollutant Potential to Emit

(pounds/hour)

(tons/year)

Appendix 4

DETAILED EMISSIONS

CALCULATIONS

AIR EMISSIONS CALCULATIONS

This operating permit renewal application is proposing identical emission limits and conditions as the existing operating permit (AP9711-1134.01). This section contains the original calculations that were the basis of the proposed limits for the original permit and the existing permit. Please note that the original calculations estimated emissions from underground detonation operations. The facility is presently performing only open detonation, in accordance with the Air Quality Operating Permit No. AP9711-1134.01. Therefore, the actual particulate matter emission rates are less than the particulate matter emission rates presented in the original application. Hawthorne Army Depot is proposing identical pollutant emission rates as the exiting permit. Any references to underground detonation operations throughout this application would also be applicable to open detonation operations. However, the facility is no longer performing underground detonation.

This section contains the following information:

(1) Type of wastes that are treated by detonation at the New Bomb facility,

(2) The various types of air pollutants (including criteria pollutants and HAPs) generated from detonation operations at the New Bomb facility.

(3) Results of the air dispersion modeling analysis originally carried out based on POLU-11 emission factors to determine the effect of emissions of various air pollutants on the ambient environment.

Appendix 7 will present results of additional air dispersion modeling results performed with the latest version of Open Burning Open Detonation Model (OBODM).

(4) Summary of the results of various open burning/open detonation emission tests conducted by the United

States Army and Air Force.

(5) Determination of air emission factors from open burning/open detonation based on methodology provided in the guidance document prepared by Halliburton NUS Corporation for the United States

Army.

(6) Results of the air dispersion modeling analysis carried out based on air emission factors provided in the guidance document prepared by the Halliburton NUS Corporation for the United States Army. Also, please refer to Appendix 7 and the enclosed Compact Disk (CD) for the results of air dispersion modeling that has been performed based on the most recent version of OBODM.

(7) Emission factors used to calculate the amount of air emissions of various criteria pollutants and HAPs generated from underground detonation operations at the New Bomb facility.

(8) The methodology for calculating the maximum design production capacity air emissions, the proposed production limit air emissions, and the actual annual air emissions of various criteria pollutants and

HAPs generated from detonation operations at the New Bomb facility.

(9) Emissions calculations for maximum design production capacity air emissions and proposed limits on air emissions for various criteria pollutants and HAPs generated from underground detonation operations at the New Bomb facility.

1. CHARACTERIZATION OF THE WASTES TREATED BY DETONATION OPERATIONS

The wastes to be treated by detonation at the New Bomb facility will consist primarily of military energetic materials or ordnance items that have exceeded their shelf life, off-specification versions of these same materials and those that cannot be treated at Hawthorne’s Western Area Demilitarization Facility (WADF) or by open burning at the Old Bomb facility located on the Main Base. The off- specification items generally are composed of the same raw materials as the usable items, but for one or more reasons they do not meet some performance specification(s).

The ordnance items that must be demilitarized because their shelf lives have been exceeded or because deterioration of the energetic compound(s) or container (casing) has occurred, have some changes in chemical and physical characteristics of the energetic constituents. However, the overall chemical composition and resulting combustion products will not be affected, because the energetic materials are composed chiefly of carbon, hydrogen, and nitrogen. Concentrations of inorganic compounds such as metallic compounds also will not change, nor will the likely combustion products.

Table A-1 shows the general chemical composition of the military energetic materials or ordnance items. A complete list of the ordnance items treated by detonation at the New Bomb facility is shown in Table A-2. The ordnance items are identified by their Department of Defense Access Number (DODAC). The specific chemical composition of representative energetic materials contained in ordnance items to be treated by underground detonation at the New Bomb facility is provided in Table A-3.

Additional ordnance items that are not included in Table A-2 may be treated by detonation at the New Bomb facility after they are completely characterized. Characterization of such ordnance items is completed as part of the Munitions Items Disposition Action System (MIDAS) database program. The MIDAS database program, designed by Argonne National Laboratory and centrally located at the U.S. Army Defense Ammunition Center and School, provides a systematic approach for disposing unwanted munitions items and identifies alternatives to open burning, open detonation, or underground detonation. The program supports demilitarization (demil) execution, resource recovery and recycling, research and development technology applications, and environmental permitting. Approximately 11,000 ordnance items have been characterized under the MIDAS database program.

TABLE A-1

GENERAL CHEMICAL COMPOSITION OF MILITARY ENERGETIC

MATERIALS THERMALLY TREATED BY DETONATION

AT THE NEW BOMB FACILITY

PROPELLANTS

Name Chemical Formula

Nitrocellulose C12H16(ONO2)4O6

Nitroglycerine C3H5N3O9

Nitroguanidine CH4N4O2

The above three primary constituents can be used singly or in various combinations along with metals, metallic salts, and organic polymer binders.

PRIMARY EXPLOSIVES

Lead Azide H6Pb (71 percent Pb)

Mercury Fulminate C2HgN2O2 (70.5 percent Hg)

Diazodinitrophenol (DDNP) C6H2N4O5

Lead Styphnate C6HN3O8Pb (44.2 percent Pb)

Tetracene C2H8N10O

Potassium Dinitrobenzofuroxane (KDNBF) C6H2N4O6K

Lead Mononitroresorcinate (LMNR) C6H5NO4XPb (57.5 percent Pb)

Ingredients to Rocket Propellant:

Copper Monobasic Salicylate

Lead Salicylate

C14H12Cu2O8

C14H10O6Pb

Fuels:

Lead Thiocyanate

Antinomy Sulfide

Calcium Silicide

Pb(SCN)2 (64 percent Pb)

S5Sb2

C14H10O6Pb

Oxidizers:

Potassium Chlorate

Ammonium Perchlorate

Barium Nitrate Calcium

Resinate

Strontium Peroxide

Barium Peroxide

Strontium Nitrate

Potassium Perchlorate

KClO3

NH4ClO4

N2O6Ba

Ca(C44H62O4)2

SrO2

BaO2

Sr(NO3)2

KClO4

Primary Compositions include a mixture of primary explosive (as shown above), fuels, oxidizers, and binders (e.g., paraffin wax).

AT THE NEW BOMB FACILITY (continued)

BOOSTER AND SECONDARY EXPLOSIVES

(High Explosives)

Aliphatic Nitrate Esters:

1,2,4-butanetriol Trinitrate (BTN)

Diethyleneglycol Dinitrate (DEGN)

Nitroglycerine (NG)

Nitrostarch (NS)

Pentaerythritol Tetranitrate (PETN)

Triethylene Glycol Dinitrate (TEGDN)

1,1,1-Trimethylethane Trinitrate (TMETN)

Nitrocellulose (NC)

C4H7N3O9

C4H8N2O7

C3H5N3O9

C6H7(OH)x(ONO2)Y WHERE X - Y = 3

C5H8N4O12

C6H12N2O8

C5H9N3O9

C12H16(ONO2)4O6

Nitramines:

C4H8N8O8 Cyclotetramethylene Tetranitramine (HMX)

Cyclotrimethylene Trinitramine (RDX) C3H6N6O6

Ethylenediamine Dinitrate (EDDN, Haleite) C2H6N4O4

Nitroguanidine (NQ) CH4N4O2

2,4,6-Trinitrophenylmethylnitramine (Tetryl) C7H5N5O8

Nitroaromatics:

Ammonium Picrate (Explosive D)

1,3-Diamino-2,4,6-Trinitrobenzene (DATB)

2,2'4,4'6,6'-Hexanitroazobenzene (HNAB)

Hexanitrostilbene (HNS)

1,3,5-Triamino-2,4,6-Trinitrobenzene (TATB)

2,4,6-Trinitrotoluene (TNT)

Ammonium Nitrate

C6H3N3O7H3N

C6H4N5O6

C12H4N8O12

C14H2N6O12

C14H2N6O12

C6H6N6O6

C7H5N3O6

HNO3H3N

AT THE NEW BOMB FACILITY (continued)

COMPOSITIONS

Binary Mixtures:

Amotols (Ammonium Nitrate + TNT)

Composition A (RDX + Desensitizer)

Composition B (RDX + TNT)

Composition C (RDX + Plasticizer)

Ednatols (Haleite + TNT)

LX-14 [HMX (95.5 percent) + Estane 5702-F1]

Octols (HMX + TNT)

Pentolite (PETN + TNT)

Picratol [Ammonium Picrate (52 percent) + TNT (48 percent)]

Tetrytols (TNT + Tetryl)

Tritonal [TNT (80 percent) + Flaked Aluminum (Al) (20 percent)]

Ternary Mixtures:

Amatex 20 [RDX (40 percent) + Ammonium Nitrate (20 percent)]

Ammonals (Ammonium Nitrate + Al and TNT, DNT, or RDX)

HBX - High Blast Explosives (TNT + RDX + AlD2 Wax + Calcium Chloride)

HTA-3 (HMX + TNT + Al Mixture 3)

Minol-2 (TNT + Ammonium Nitrate + Al)

Torpex [RDX (41.6 percent), TNT (39.7 percent, Al (18.0 percent), Wax (0.7 percent)]

Quaternary Mixtures:

DBX [TNT (40 percent), RDX (21 percent), Ammonium Nitrate (21 percent), Al (18 percent)]

Plastic Bonded Explosives (PBX):

Basic Explosive [RDX, HMX, HNS, or PETN + Polymeric Binder (Polyester, Polyurethane, Nylon, Polystyrene, Rubbers, Nitrocellulose, Teflon)]

Pyrotechnics

Combination of:

Oxidizer - Oxygen or Fluorine

Fuel - Powdered Aluminum or Magnesium

Binding Agents - Resins, Waxes, Plastics, Oils, Retardants

Waterproofing, Color Intensifier

Source: Military Explosives, Department of the Army, Technical Manual, TM9-1300-214, September 1984

TABLE A-2

LIST OF ORDNANCE ITEMS (BY DODAC NUMBER)

TREATED BY DETONATION AT THE NEW BOMB FACILITY

DODAC Number Type of Munition1 Description2

1305-A974 CTG 25MM APDS-T M791 LNKD

1305-A975 CTG 25MM HEI-T M792 LNKD

1305-A976 CTG 25MM TP-T M793 LNKD

1305-A978 CTG 25MM TP PGU-23/U SNGL RD

1305-B112 CTG 30MM HEI MK3Z LNKD LHF

1305-B113 CTG 30MM TP MK4Z LNKD LHF

1305-B114 CTG 30MM HEI M3Z-1 LNKD RHF

1305-B115 CTG 30MM TP MK4Z LNKD RHF

1305-B124 CTG 30MM HEI M799 LNKD LHF

1305-B125 CTG 30MM HEI M799 LNKD RHF

1310-B470 CTG 40MM HE M384 SERIES LNKD

1310-B480 CTG 40MM TP M385 SERIES LNKD F/HELI LAUNCHER

1310-B534 CTG 40MM MP M576

1310-B542 CTG 40MM HEDP M430 LNKD

1310-B545 CTG 40MM BLANK SALUTING

1310-B549 CTG 40MM HEI-P M162

1310-B551 CTG 40MM AP M81A1 CLIPPED

1310-B552 CTG 40MM AP-T M81 SERIES CTN PACK

1310-B553 CTG 40MM HEP MK2

1310-B554 CTG 40MM HE-SD

1310-B555 CTG 40MM HEI-P MK2

1310-B556 CTG 40MM HEI-P-NP

1310-B557 CTG 40MM HEI-SD 4/CLIP

1310-B558 CTG 40MM HEI-T-NSD 4/CLIP

1310-B559 CTG 40MM HEI-T-SD 4/CLIP

1310-B560 CTG 40MM HRI-T-DI-SD

1310-B561 CTG 40MM HE-P

1310-B562 CTG 40MM HE-T SD MK2

1310-B563 CTG 40MM BL-P

1310-B564 CTG 40MM BL-T 4/CLIP

TREATED BY DETONATION AT THE NEW BOMB FACILITY (continued)

1310-B568 CTG 40MM HE M406

1310-B569 CTG 40MM HE M406

1310-B572 CTG 40MM HE M384 SERIES LNKD

1310-B576 CTG 40MM TP M385 LNKD

1310-B577 CTG 40MM TP M407A1

1310-B666 CTG 3 POUNDER BLNK MK1-1

1315-C025 CTG 75MM BLANK M337A2

1315-C139 CTG 3 IN 50 CAL BLANK

1315-C162 CTG 3 IN 50 CAL VT NON-FRAG MK33

1315-C164 CTG 3 IN 50 CAL VT NON-FRAG MK33

1315-C183 CTG 3 IN 50 CAL BLANK

1315-C262 CTG 90MM CANISTER APER M336

1315-C275 CTG 90MM APER-T M580 SERIES

1315-C319 CTG 3 IN 50 CAL VT NON-FRAG MK31

1315-C320 CTG 3 IN 50 CAL VT NON-FRAG MK31

1315-C373 CTG 3 IN 50 CAL VT NON-FRAG MK36 NFL

1315-C375 CTG 3 IN 50 CAL VT NON-FRAG MK36 NFL

1315-C513 CTG 105 MM APERS-T M546

1315-C519 CTG 105MM APERS-T M494 SERIES

1315-C697 CTG 4.2 IN HE M329A2 W/O FUZE

1315-CX30 BAG LOADING ASSY F/4.2 MORTAR

1320-D229 CTG 5 IN 38 CAL BLNK SALUTING MK5 MOD 0

1320-D249 PROJ 5 IN 38 CAL VT NOT-FRAG MK 35/31

1320-D260 PROJ 5 IN 38 CAL HE CVT RCKT ASST MK57 MOD 0

1320-D261 PROJ 5 IN 38 CAL HE CVT RCKT ASST MK57 MOD 1

1320-D262 PROJ 5 IN 38 CAL HE CVT RCKT ASST MK57 MOD 2

1320-D307 PROJ 5 IN 54 CAL BLACK SALUTING MK6

1320-D325 PROJ 5 IN 54 CAL HE-CVT RCKT ASST MK58

1320-D361 CHG PROP 175MM WB M86A2/T58E10

1320-D561 PROJ 155MM HE APER H449/449E1

1320-D579 PROJ 15MM HE RAP M549 SERIES (COMP B)

1325-E173 DSP&BOMB CBU MK20 MOD 2

1325-E174 DSP&BOMB ACFT CBU-49

1325-E184 DSP&BOMB ACFT CBU-24

1325-E463 BOMB GP 250 LB MK81 MOD 1 H-6/TRITONAL

1325-E464 BOMB GP 250 LB MK81 MOD 0 TRITONAL

1325-E465 BOMB GP 250 LB MK81 MOD 1 H-6/TRITONAL

1325-E485 BOMB GP 500 LB MK82 MOD 1 TRITONAL

1325-E506 BOMB GP 1000 LB MK83 MOD 4

1325-E820 DSP&BOMB ACFT CBU 59/B

1325-F372 ADAPTER BOOSTER T45E7

1325-F387 ADAPTER BOOSTER BOMB M147

1325-F390 ADAPTER BOOSTER BOMB TAIL M150

1325-F392 ADAPTER BOOSTER BOMB NOSE M148E1

1325-F525 BURSTER BOMB MK4 MOD 0 F/FIREBOMB

1325-F679 FUZE BOMB TAIL M990E1

1325-F681 FUZE BOMB NOE M904E3

1325-F720 FUZE BOMB TAIL AN MK230 MOD 4A

1325-F724 FUZE BOMB TAIL M990E4

1325-F837 FUZE BOMB TAIL MK344 MOD 0

1325-G104 FUZE BOMB TAIL MK 376 MOD 0

1325-G109 FUZE BOMB TAIL MK346

1330-G881 GRENADE HAND FRAG M67

1330-G890 GRENADE HAND FRAG MK2/M25 SERIES

1330-G892 GRENADE HAND FRAG MK2A1

1330-G910 GRENADE HAND OFFENSIVE MK3 SERIES

1330-G9111 GRENADE HAND OFF MK3A2

1330-G970 GRENADE RIFLE HEAT M28/M31

1336-VX75 ERD ACCUMULATOR (HAWK)

1340-H305 RCKT MTR M3 OR M3A2

1340-H342 RCKT MTR JATO MK25 MOD 1

1340-H343 RCKT MTR JATO MK7 MOD 2 W/O IGNITER

1340-H345 RCKT MTR JATO MK7 MOD 1 W/O IGNITER

1340-H557 RCKT 60MM HEAT M72A2

1340-H923 WHD HE MK29 MOD 0 W/BD FUZE F/5 IN RCKT

1340-HX04 RCKT 83MM ASSAULT PRAC MK4 MOD 0 (SMAW)

1345-K090 MINE AP M2 SERIES

1345-K092 MINE APER M16 SERIES BOUNDING

1345-K121 MINE APERS M14

1345-K143 MINE APERS M18A1 W/M57 FIRING DEVICE

1345-K146 MINE APERS M26 BOUNDING

1345-K181 MINE AT HEAVY M21

1345-K250 MINE AT HEAVY M19 NON-METALLIC

1370-L377 SIM DETONATION EXPL MK2 MOD 0

1370-L594 SIM PROJ GRND BURST M115A1

1370-L596 SIM FLASH ARTY M110

1370-L598 SIM EXPL BOOBY TRAP FLASH M117

1370-L599 SIM EXPL BOOBY TRAP ILLUM M118

1370-L600 SIM BOOBY TRAP WHISTLING M119

1370-L621 STARTER FIRE M2 NP-3

1375-M023 CHG DEMO BLOCK M112 1 1/4 LB COMP C-4

1375-M026 DEMO KIT BANGALORE TORP M1A1

1375-M029 CHG DEMO SHAPED FLEX LINEAR

1375-M031 CHG DEMO BLOCK TNT 1/2 LB

1375-M032 CHG DEMO BLOCK TNT 1 LB

1375-M034 CHG DEMO BLOCK TNT 8 LB

1375-M035 CHG DEMO CHAIN M1 8 X 2 1/2 LB

1375-M040 CHG DEMO MK2 & MODS 55 LB CRATERING

1375-M420 CHG DEMO SHAPED M2 SERIES 15 LB

1375-M421 CHG DEMO SHAPED M3 SERIES 40 LB

1375-M445 DEMO KIT PROJ CHG AP M1/M1A1

1375-M456 CORD DET PETN TYP 1 CL E (NEW-1000 FT)

1375-M485 CUTTER HE MK3-1

1375-M591 DYNA DYNAMITE MILITARY M1

1375-M757 CHG ASSY DEMO M183 COMP C-4 8 X 2 1/2 LB

1375-M791 CHG ASSY DEMO MK133 MODS 0/1/2

1375-M792 CHG ASSY DEMO MK135/137/138

1375-M976 CHG DEMO BLOCK MK36 MOD 1

1375-M981 CHG DEMO SHEET ROLL 25 FT

1375-M995 CHG DEMO RIGID LINEAR MK86 MOD 0

1375-M996 CHG DEMO RIGID LINEAR MK87 MOD 0

1375-M997 CHG DEMO RIGID LINEAR MK88 MOD 0

1375-M998 CHG DEMO RIGID LINEAR MK89 MOD 0

1377-M182 CTG ACFT FIRE EXTINGUISHER

1377-M314 CATAPULT ACFT EJECT SEAT MK8 MOD 0

1377-M316 CATAPULT ACFT EJECT SEAT MK7 MOD 1

1377-M349 CATAPULT ACFT EJECT SEAT

1377-M392 CTG IMPULSE SDCP NO 3

1377-M499 CUTTER CTG ACTUATED MK4 MOD 0

1377-M500 CUTTER CTG ACT M21 F/REEFING LINE

1377-M504 CUTTER CTC ACT M22 F/REEFING LINE

1377-M506 CTG IMPULSE MK73 MOD 0

1377-M507 CTG IMPULSE MK85 MOD 0

1377-M509 CTG IMPULSE MK9 MOD 0

1377-M514 CTG IMPULSE MK44 MOD 0

1377-M519 CTG IMPULSE MK51 MODS 0/1

1377-M523 CTG IMPULSE MK105 MOD 0

1377-M571 CTG IMPULSE GAS GENERATOR

1377-M928 RCKT MTR MK82 MOD 0

1390-N538 PRIMER ELEC MK49 MOD 4

1390-N634 BOOSTER FUZE M125A1

DODAC Department of Defense Access

1 Abbreviations for "Type of Munition"

ACTVR Activator FLARE Flare PROJ Projectile

CAN Canister FUZE or FUSE Fuse RCA Riot Control

CAP Blasting Cap GM Guided Missile RCKT Rocket

CHG Charge GRENADE Grenade RCKT MTR Rocket Motor

CORD Detonation Cord IGNITER Igniter REDUCER Reducer

CTG Cartridge LCR&CTG Launcher and SIGNAL Signal

DEMO KIT Demolitions Kit Cartridge SIM Simulator

DYNA Dynamite MINE Mine SMK POT Smoke pot

FD Firing Device PRIMER Primer

2 Abbreviations for "Description"

ACFT

AP

APER

Aircraft

Armor Piercing

Anti-Personnel

HE

HEAT

HEDP

High Explosive High

Explosive Antitank

High Explosive Dual

SEC

SIM

SMK

Second

Simulator

Smoke

Purpose

API Armor Piercing

Incendiary

HEI High Explosive Incendiary SNGL Single

API-T Armor Piercing

Incendiary - Tracer

HEI-T High Explosive Incendiary -

Tracer

STD Standard

ARTY Artillery HEP High Explosive Plastic SUB-CAL Sub-Caliber

ASSY Assembly ILLUM Illuminating SURF Surface

AT Antitank IN Inch TORP Torpedo

BL-P Blind Loaded and

Plugged

INCD Incendiary TOW Tube Launched, Optically Sighted, Wire

Guided

BL-T Blind Loaded Tracer LHF Left Hand Feed TP Target Practice

CAL Caliber LNCHR Launcher TP-T Target Practice - Tracer

CHEM Chemical LNKD Linked TPDS Target Practice

Discarding Sabot

CHG Charge MG Minigun TR Tracer

CNTR Container MICLIC Mine Clearing Line Charge TRNR Trainer

COMP Composition MM Millimeter VIO Violet

CTN Carton MOD Model W/O Without

DEMO Demolition MTL Metal W/ With

ELEC Electric MTSQ Mechanical Time, Super

Quick

WB White Bag

EXPL Explosive PARA Parachute WDN Wooden

EXT Extended PD Point Detonating WP White Phosphorus

F/ For PERC Percussion WPNS Weapons

FRAG Fragmentation PKG Package WRBND Wire Bound

GAGE Guage PRAC Practice YLW Yellow

GB Green Bag PROP Propellant

GREN Grenade PROX Proximity

GRN Green RD Round

GRND Ground RHF Right Hand Feed

HC Hexachloroethane-Zinc RP Red Phosphorus

TABLE A-3

CHEMICAL COMPOSITION OF ENERGETICS IN ORDNANCE ITEMS TREATED

BY DETONATION AT THE NEW BOMB FACILITY

DODAC

Number

Item

Energetic Constituent

Weight

(pounds)

Weight

Percent

Hazardous

Waste Code

1305-A974 Cartridge, 25-mm APDS-T Nitrocellulose 2.02E-1 91.4 D003, D030

Lnkd, M791 Dinitrotoluene 1.54E-2 7.0

Potassium Sulfate 1.32E-3 0.6

Diphenylamine 1.98E-3 0.9

Graphite 4.41E-4 0.2

1305-A975 Cartridge, 25-mm HEI-T HMX 5.20E-2 19.79 D003, D030

Lnkd, M792 Nylon 2.74E-3 1.04

Nitrocellulose 1.90E-1 72.30

Dinitrotoluene 1.45E-2 5.52

Potassium Sulfate 1.25E-3 0.48

Diphenylamine 1.87E-3 0.71

Graphite 4.16E-4 0.16

1305-A976 Cartridge, 25-mm TP-T Lnkd, Nitrocellulose 2.02E-1 91.4 D003, D030

M793 Dinitrotoluene 1.54E-2 7.0

Potassium Sulfate 1.32E-3 0.6

Diphenylamine 1.98E-3 0.9

Graphite 4.41E-4 0.2

1305-A978 Cartridge, 25-mm TP Sngl Nitrocellulose 1.91E-1 91.4 D003, D030

Rd, PGU-23/U Dinitrotoluene 1.47E-2 7.0

Potassium Sulfate 1.26E-3 0.6

Diphenylamine 1.89E-3 0.9

Graphite 4.19E-4 0.2

1305-B112 Cartridge, 30-mm HEI Lnkd PETN 1.10E-1 50 D003, D030

LHF, MK3Z TNT 1.10E-1 50

1305-B113 Cartridge, 30-mm TP Lnkd Nitrocellulose 9.25E-2 91.4 D003, D030

LHF, MK4Z Dinitrotoluene 7.10E-3 7.0

Potassium Sulfate 6.00E-4 0.6

Diphenylamine 9.00E-4 0.9

Graphite 2.00E-4 0.2

1305-B114 Cartridge, 30-mm HEI Lnkd PETN 1.40E-1 50 D003, D030

RHF, M3Z-1 TNT 1.40E-1 50

1305-B115 Cartridge, 30-mm TP Lnkd Nitrocellulose 9.25E-2 91.4 D003, D030

RHF, MK4Z Dinitrotoluene 7.10E-3 7.0

Potassium Sulfate 6.08E-4 0.6

Diphenylamine 9.12E-4 0.9

Graphite 2.03E-4 0.2

1305-B124 Cartridge, 30-mm HEI Lnkd PETN 1.00E-1 50 D003, D030

LHF, M799 TNT 1.00E-1 50

1305-B125 Cartridge, 30-mm HEI Lnkd PETN 1.00E-1 50 D003, D030

RHF, M799 TNT 1.00E-1 50

BY DETONATION AT THE NEW BOMB FACILITY (continued)

(pounds)

Weight

Percent

Hazardous

Waste Code

1310-B470 Cartridge, 40-mm HE Lnkd, RDX 1.18E-1 90.63 D003, D005, M384 Series Wax 1.80E-3 1.38 D008

Nitrocellulose 7.92E-3 6.08

Nitroglycerin 1.99E-3 1.53

Potassium Nitrate 8.10E-5 0.06

Lead Compounds 1.49E-4 0.11

Antimony Sulfide 1.30E-5 0.01

Barium Nitrate 1.50E-4 0.12

Ethyl Centralite 6.10E-5 0.05

Potassium Chlorate 2.70E-5 0.02

1310-B480 Cartridge, 40-mm TP Lnkd Nitrocellulose 7.60E-3 77.27 D003, D005, F/Heli Launcher, M385 Nitroglycerin 1.91E-3 19.46 D008

Potassium Nitrate 7.43E-5 0.76

Antimony Sulfide 8.57E-6 Trace

Barium Nitrate 1.37E-4 1.39

Ethyl Centralite 5.86E-5 0.60

Lead Azide 2.86E-6 0.03

Potassium Chlorate 2.71E-5 0.28

Lead Thiocyanate 1.29E-5 0.13

1310-B534 Cartridge, 40-mm MP, M576 Metal Pellets 5.28E-2 99.12 D003, D005, Antimony Sulfide 8.57E-6 0.02 D008

Barium Nitrate 5.71E-6 0.01

Nitrocellulose 3.21E-4 0.60

Nitroglycerin 8.14E-5 0.15

Potassium Nitrate 2.86E-6 5.37E-3

Lead Azide 2.86E-6 5.37E-3

Graphite 1.43E-6 2.69E-3

Ethyl Centralite 2.86E-6 5.37E-3

Potassium Chlorate 2.71E-6 0.05

Lead Thiocyanate 1.29E-5 0.02

1310-B542 Cartridge 40-mm HEDP, Lead Azide 2.68E-4 0.28 D003, D005, M430 Antimony Sulfide 1.29E-5 0.01 D008

Barium Nitrate 1.50E-4 0.16

Tetracene 1.43E-6 0.01

Nitrocellulose 7.92E-3 8.29

Nitroglycerin 1.99E-3 2.09

Potassium Nitrate 8.14E-5 0.08

RDX 8.24E-2 86.34

Tetryl 1.23E-3 1.30

Desensitizer 1.25E-3 1.31

Ethyl Centralite 6.14E-5 0.06

Potassium Chlorate 2.71E-5 0.03

(pounds)

Weight

Percent

Hazardous

Waste Code

1310-B545 Cartridge, 40-mm Blank Sodium Nitrate 5.78E-1 75 D003

Saluting Charcoal 1.16E-1 15

Sulfur 7.71E-2 10

1310-B551 Cartridge, 40-mm AP Potassium:

6.85E-3

0.99

D003, D005, Clipped, M81A1 Nitrate + Chlorate D008, D030

Lead Thiocyanate 3.57E-5 Trace

Antimony Sulfide 2.43E-5 Trace

Nitrocellulose 5.52E-1 80.23

Dinitrotoluene 6.49E-2 9.44

Dibutylphthalate 3.25E-2 4.72

Diphenylamine 6.49E-3 0.94

Strontium Nitrate 1.12E-2 1.62

Magnesium 7.50E-3 1.09

Aluminum 3.80E-4 0.05

Polyvinyl Chloride 1.40E-3 0.20

Barium Peroxide 2.30E-3 0.33

1310-B553 Cartridge, 40-mm HEP MK2 Nitrocellulose 6.11E-1 69.77 D003, D008, TNT 1.40E-1 15.99 D030

Dinitrotoluene 7.19E-2 8.21

Dibutylphthalate 3.60E-2 4.11

Diphenylamine 7.19E-3 0.82

Potassium Nitrate + Chlorate 6.86E-3 0.78

Charcoal 1.43E-3 0.16

Sulfur 9.51E-4 0.11

Lead Azide + Thiocyanate 2.91E-4 0.03

Antimony Sulfide 4.57E-5 0.01

1310-B555 Cartridge, 40-mm HEI-P Nitrocellulose 6.11E-1 69.77 D003, D008, MK2 TNT 1.40E-1 15.99 D030

Dinitrotoluene 7.19E-2 8.21

Dibutylphthalate 3.60E-2 4.11

Diphenylamine 7.19E-3 0.82

Potassium Nitrate + Chlorate 6.86E-3 0.78

Charcoal 1.43E-3 0.16

Sulfur 9.51E-4 0.11

Lead Azide + Thiocyanate 2.91E-4 0.03

Antimony Sulfide 4.57E-5 0.01

1310-B556 Cartridge, 40-mm HEI-P-NP TNT 2.03E-1 100 D003, D030

1310-B557 Cartridge, 40-mm HEI-SD

4/Clip

TNT 2.03E-1 100 D003, D030

(pounds)

Weight

Percent

Hazardous

Waste Code

1310-B558 Cartridge, 40-mm HEI-T-NSD

4/Clip

TNT 2.03E-1 100 D003, D030

1310-B559 Cartridge, 40-mm HE-T-SD Nitrocellulose 6.12E-1 70.38 D003, D008, 4/Clip Dinitrotoluene 7.20E-2 8.38 D030

Diphenylamine 7.20E-3 0.83

Dibutylphthalate 2.88E-2 3.31

Potassium Chlorate 9.95E-5 0.01

Antimony Sulfide 4.81E-5 5.53E-3

Potassium Nitrate 6.86E-3 0.79

Charcoal 1.37E-3 0.16

Sulfur 9.14E-4 0.11

Lead 2.63E-4 0.03

TNT 1.40E-1 16.10

Carborundum 3.57E-6 4.11E-4

Lead Sulfocyanate 3.57E-5 4.11E-3

1310-B560 Cartridge, 40-mm

HEI-T-DI-SD

TNT 2.03E-1 100 D003, D030

1310-B561 Cartridge, 40-mm HEP TNT 2.03E-1 100 D003, D030

1310-B562 Cartridge, 40-mm HE-T-SD, MK2

TNT 2.03E-1 100 D003, D030

1310-B563 Cartridge, 40-mm BL-P Nitrocellulose 6.04E-1 91.4…