BAR-RUST 235 MSDS.pdf

MATERIAL SAFETY DATA SHEET

The information contained herein is based on data available at the time of preparation of this data sheet which ICI Paints believes to be reliable. However, no warranty is expressed or implied regarding the accuracy of this data. ICI Paints shall not be responsible for the use of this information, or of any product, method or apparatus mentioned and you must make your own determination of its suitability and completeness for your own use, for the protection of the environment, and the health and safety of your employees and the users of this material.

Complies with OSHA hazard communication standard 29CFR1910.1200.

prepared 08/08/06 B

A R

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ST 235

235K

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I Paints N orth A m erica 15885 Sprague R oad Strongsville, O hio 44136 EM

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TELEPH

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O . (800) 545-2643

HAZARDS IDENTIFICATION (ANSI Section 3) Primary route(s) of exposure : Inhalation, skin contact, eye contact, ingestion.

Effects of overexposure :

Inhalation : Irritation of respiratory tract. Prolonged inhalation may lead to mucous membrane irritation, fatigue, drowsiness, dizziness and/or lightheadedness, headache, uncoordination, nausea, vomiting, diarrhea, abdominal pain, chest pain, blurred vision, coughing, difficulty with speech, apathy, central nervous system depression, intoxication, metallic taste, anesthetic effect or narcosis, difficulty of breathing, allergic response, bronchitis, fever and chills, dehydration, tremors, respiratory tract burns, severe lung irritation or damage, liver damage, kidney damage, pulmonary edema, loss of consciousness, respiratory failure, asphyxiation, death. Possible sensitization to respiratory tract.

Skin contact : Irritation of skin. Prolonged or repeated contact can cause dermatitis, defatting, blistering, allergic response, severe skin irritation, severe skin irritation or burns. Possible sensitization to skin.

Eye contact : Irritation of eyes. Prolonged or repeated contact can cause conjunctivitis, blurred vision, tearing of eyes, redness of eyes, severe eye irritation, severe eye irritation or burns, corneal injury.

Ingestion : Ingestion may cause lung inflammation and damage due to aspiration of material into lungs, mouth and throat irritation, mucous membrane irritation, drowsiness, dizziness and/or lightheadedness, headache, uncoordination, nausea, vomiting, diarrhea, gastro-intestinal disturbances, severe abdominal pain, abdominal pain, visual disturbances, apathy, central nervous system depression, anesthetic effect or narcosis, difficulty of breathing, burns of the mouth, throat, stomach, liver damage, kidney damage, pulmonary edema, convulsions, loss of consciousness, respiratory failure, death.

Medical conditions aggravated by exposure : Eye, skin, respiratory disorders, asthma-like conditions, respiratory disorders.

FIRST-AID MEASURES (ANSI Section 4) Inhalation : Remove to fresh air. Restore and support continued breathing. Get emergency medical attention. Have trained person give oxygen if necessary. Get medical help for any breathing difficulty. Remove to fresh air if inhalation causes eye watering, headaches, dizziness, or other discomfort.

Skin contact : Wash thoroughly with soap and water. If any product remains, gently rub petroleum jelly, vegetable or mineral/baby oil onto skin. Repeated applications may be needed. Remove contaminated clothing. Wash contaminated clothing before re-use. Dispose of contaminated leather items, such as shoes and belts. If irritation occurs, consult a physician.

Eye contact : Flush immediately with large amounts of water, especially under lids for at least 15 minutes. If irritation or other effects persist, obtain medical treatment.

Ingestion : If swallowed, obtain medical treatment immediately.

FIRE-FIGHTING MEASURES (ANSI Section 5) Fire extinguishing media : Dry chemical or foam water fog. Carbon dioxide. Closed containers may explode when exposed to extreme heat or fire. Vapors are heavier than air and may travel long distances to a source of ignition and flash back. Vapors can form explosive mixtures in air at elevated temperatures. Closed containers may burst if exposed to extreme heat or fire. May decompose under fire conditions emitting irritant and/or toxic gases.

Fire fighting procedures : Water may be used to cool and protect exposed containers. Firefighters should use full protective clothing, eye protection, and self-contained breathing apparatus. Self-contained breathing apparatus recommended.

Hazardous decomposition or combustion products : Carbon monoxide, carbon dioxide, oxides of nitrogen, acrid fumes, oxides of sulfur, ammonia, aldehydes, toxic gases, toluene diisocyanate, smoke and soot, unidentified organic compounds. Phenolics

ACCIDENTAL RELEASE MEASURES (ANSI Section 6) Steps to be taken in case material is released or spilled : Comply with all applicable health and environmental regulations. Eliminate all sources of ignition. Ventilate area. Spills may be collected with absorbent materials. Use non-sparking tools. Evacuate all unnecessary personnel. Place collected material in proper container. Wet down spilled material with water. Complete personal protective equipment must be used during cleanup. Large spills - shut off leak if safe to do so. Dike and contain spill. Pump to storage or salvage vessels. Use absorbent to pick up excess residue.

Keep salvageable material and rinse water out of sewers and water courses. Small spills - use absorbent to pick up residue and dispose of properly.

HANDLING AND STORAGE (ANSI Section 7) Handling and storage : Store below 100f (38c). Keep away from heat, sparks and open flame. Keep away from direct sunlight, heat and all sources of ignition. Keep container tightly closed in a well-ventilated area.

Other precautions : Use only with adequate ventilation. Do not take internally. Keep out of reach of children. Avoid contact with skin and eyes, and breathing of vapors. Wash hands thoroughly after handling, especially before eating or smoking. Keep containers tightly closed and upright when not in use. Avoid conditions which result in formation of inhalable particles such as spraying or abrading (sanding) painted surfaces. If such conditions cannot be avoided, use appropriate respiratory protection as directed under exposure controls/personal protection. Empty containers may contain hazardous residues. Ground equipment when transferring to prevent accumulation of static charge.

EXPOSURE CONTROLS/PERSONAL PROTECTION (ANSI Section 8) Respiratory protection : Control environmental concentrations below applicable exposure standards when using this material. When respiratory protection is determined to be necessary, use a NIOSH/MSHA (Canadian z94.4) Approved elastomeric sealing- surface facepiece respirator outfitted with organic vapor cartridges and paint spray (dust/mist) prefilters. Determine the proper level of protection by conducting appropriate air monitoring. Consult 29CFR1910.134 For selection of respirators (Canadian z94.4).

Ventilation : Provide dilution ventilation or local exhaust to prevent build-up of vapors. Use explosion-proof equipment.

Personal protective equipment : Eye wash, safety shower, safety glasses or goggles. Impervious gloves, impervious clothing, face shield, apron.

STABILITY AND REACTIVITY (ANSI Section 10) Under normal conditions : Stable see section 5 fire fighting measures Materials to avoid : Oxidizers, acids, reducing agents, bases, aldehydes, halogens, amines, aluminum, epoxides, nitric acid, combustible materials, magnesium, mineral acids. Nitrates.

Conditions to avoid : Sunlight, elevated temperatures, contact with oxidizing agent, storage near acids, sparks, open flame, ignition sources.

Hazardous polymerization : Will not occur may polymerize in presence of aliphatic amines.

Form: 235K, Page 2 of 4, prepared 08/08/06

TOXICOLOGICAL INFORMATION (ANSI Section 11) Supplemental health information : Contains a chemical that is moderately toxic by ingestion. Contains a chemical that is toxic by ingestion. Contains a chemical that is toxic by inhalation. Contains a chemical that may be absorbed through skin. Excessive inhalation of fumes may lead to metal fume fever characterized by a metallic taste in mouth, excessive thirst, coughing, weakness, fatigue, muscular pain, nausea, chills and fever. Notice - reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Prolonged inhalation of mica may cause pneumoconiosis. Symptoms may include a progressive dry cough, shortness of breath on exertion, decreased chest expansion, weakness and weight loss. Contains iron oxide, repeated or prolonged exposure to iron oxide dust may cause siderosis, a benign pneumoconiosis. Other effects of overexposure may include toxicity to liver, kidney, lungs, central nervous system, blood.

Carcinogenicity : This product contains a polymeric blocked isocyanate based on toluene diisocyanate (tdi).

Free tdi may be released at elevated temperatures during baking. Tdi is highly toxic by inhalation, a severe eye, skin and mucous membrane irritant, and a pulmonary and skin sensitizer. Tdi is classified as a possible human carcinogen by IARC (group 2b) and as a reasonably anticipated carcinogen by NTP.

The OSHA and acgih exposure limit is 0.005 Ppm (twa) and 0.02 Ppm (stel). Inhalation of non-asbestiform cosmetic grade talc for 2 years at 6 and 18 mg/m3 produced clear evidence of carcinogenicity in female rats (lung and adrenal tumors) and some evidence of carcinogenicity in male rats (adrenal tumors). No evidence of carcinogenicity was demonstrated in male and female mice exposed under the same conditions. Microscopic examination of the lungs of rats and mice exposed to talc revealed additional exposure related effects primarily associated with the inflammatory response.

Contains crystalline silica which is considered a hazard by inhalation. IARC has classified crystalline silica as carcinogenic to humans (group 1). Crystalline silica is also a known cause of silicosis, a noncancerous lung disease. The national toxicology program (NTP) has classified crystalline silica as a known human carcinogen. Notice - toluene diisocyanate (tdi) has been reported to be a carcinogen by the national toxicology program (NTP). The international agency for research on cancer (IARC) concluded, based on the NTP study, that there is "sufficient evidence for carcinogenicity of tdi to experimental animals", but "inadequate evidence for carcinogenicity of tdi to humans." The international agency for research on cancer (IARC) has classified carbon black as possibly carcinogenic to humans (group 2b) based on sufficient evidence in animals and inadequate evidence in humans. The international agency for research on cancer (IARC) has evaluated ethylbenzene and classified it as a possible human carcinogen (group 2b) based on sufficient evidence for carcinogenicity in experimental animals, but inadequate evidence for cancer in exposed humans. In a 2 year inhalation study conducted by the national toxicology program (NTP), ethylbenzene vapor at 750 ppm produced kidney and testicular tumors in rats and lung and liver tumors in mice. Genetic toxicity studies showed no genotoxic effects. The relevance of these results to humans is not known. In a lifetime inhalation study, exposure to 250 mg/m3 titanium dioxide resulted in the development of lung tumors in rats. These tumors occurred only at dust levels that overwhelmed the animals' lung clearance mechanisms and were different from common human lung tumors in both type and location. The relevance of these findings to humans is unknown but questionable. The international agency for research on cancer (IARC) has classified titanium dioxide as possibly carcinogenic to humans (group 2b) based on inadequate evidence of carcinogenicity in humans and sufficient evidence of carcinogenicity in experimental animals.

Reproductive effects : High exposures to xylene in some animal studies, often at maternally toxic levels, have affected embryo/fetal development. The significance of this finding to humans is not known.

Mutagenicity : No mutagenic effects are anticipated Teratogenicity : No teratogenic effects are anticipated

ECOLOGICAL INFORMATION (ANSI Section 12) No ecological testing has been done by ICI paints on this product as a whole.

DISPOSAL CONSIDERATIONS (ANSI Section 13) Waste disposal : Dispose in accordance with all applicable regulations. Avoid discharge to natural waters.

REGULATORY INFORMATION (ANSI Section 15) As of the date of this MSDS, all of the components in this product are listed (or are otherwise exempt from listing) on the TSCA inventory. This product contains 10% or greater of a chemical classified by DOT as a marine pollutant (see Chemical Hazard Data table). This product has been classified in accordance with the hazard criteria of the CPR (controlled products regulations) and the MSDS contains all the information required by the CPR.

Physical Data (ANSI Sections 1, 9, and 14)

Product Code Description Wt. / Gal. VOC

gr. / ltr.

% Volatile by Volume

Flash Point

Boiling Range HMIS DOT, proper shipping name

235B1642 bar-rust 235 multi-purpose epoxy coating - buff base 11.79 285.45 33.81 100 f 243-355 *320 paint, combustible liquid, UN 1263, PGIII 235B2531 barrust 235 multi-purpose epoxy coating - im gray base 11.87 289.17 34.22 100 f 243-355 *320 paint, combustible liquid, UN 1263, PGIII 235B2534 bar-rust 235 multi-purpose epoxy coating - medium gray base 11.74 285.09 33.77 100 f 243-355 *320 paint, combustible liquid, UN 1263, PGIII 235B2904 bar-rust 235 multi-purpose epoxy coating - haze gray base 11.67 278.12 32.89 100 f 243-355 *320 paint, combustible liquid, UN 1263, PGIII 235B2973 bar-rust 235 multi-purpose epoxy coating - light gray base 11.74 284.37 33.68 100 f 243-355 *320 paint, combustible liquid, UN 1263, PGIII 235B3501 bar-rust 235 multi-purpose epoxy coating - white base 11.89 287.97 34.10 100 f 243-355 *320 paint, combustible liquid, UN 1263, PGIII 235B7821 bar-rust 235 multi-purpose epoxy coating - oxide red base 11.83 281.98 33.36 100 f 243-355 *320 paint, combustible liquid, UN 1263, PGIII 235B9500 bar-rust 235 multi-purpse epoxy coating whit e tint base 12.09 287.66 34.06 100 f 243-355 *320 paint, combustible liquid, UN 1263, PGIII 235B9501 bar-rust 235 mulri-purpose epoxy coating dee p tint base 11.66 287.97 34.11 100 f 243-355 *320 paint, combustible liquid, UN 1263, PGIII 235B9502 bar-rust 235 multi-purpose epoxy coating neu tral tint base 10.64 296.06 35.06 100 f 243-415 *320 paint, combustible liquid, UN 1263, PGIII 235B9903 bar-rust 235 multi-purpose epoxy coating - black base 11.61 281.14 33.29 100 f 243-355 *320 paint, combustible liquid, UN 1263, PGIII 235C0910 bar-rust 235 multi-purpose epoxy coating - converter for monopak colors 7.98 334.71 36.50 106 f n/d 320 resin solution, combustible liquid, UN1866, PGIII 235C0980 barrust 235 multi-purpose epoxy coating converter 7.90 331.11 38.40 100 f 243-355 320 paint, combustible liquid, UN 1263, PGIII

Form: 235K, Page 3 of 4, prepared 08/08/06

Ingredients Product Codes with % by Weight (ANSI Section 2)

Chemical Name Common Name CAS. No. 235B1642 235B2531 235B2534 235B2904 235B2973 235B3501 235B7821 235B9500 235B9501 235B9502 235B9903 235C0910 235C0980 benzene, ethyl- ethylbenzene 100-41-4 .1-1.0 .1-1.0 .1-1.0 .1-1.0 .1-1.0 .1-1.0 .1-1.0 .1-1.0 .1-1.0 .1-1.0 .1-1.0 1,2-ethanediamine ethylenediamine 107-15-3 1-5 1-5 1,3,5-trimethylbenzene 1,3,5-trimethylbenzene 108-67-8 1-5 1-5 1-5 1-5 1-5 1-5 1-5 1-5 1-5 1-5 1-5 1-5

2-heptanone methyl amyl ketone 110-43-0 1-5 1-5 1-5 1-5 1-5 1-5 1-5 1-5 1-5 1-5 1-5 mica mica 12001-26-2 10-20 10-20 10-20 10-20 10-20 10-20 10-20 10-20 10-20 10-20 10-20 antigorite antigorite 12135-86-3 5-10 1-5 5-10 5-10 5-10 1-5 5-10 1-5 1-5 5-10 5-10 iron oxide ferric oxide 1309-37-1 5-10 benzene, dimethyl- xylene 1330-20-7 1-5 1-5 1-5 1-5 1-5 1-5 1-5 1-5 1-5 1-5 1-5 .1-1.0 carbon black carbon black 1333-86-4 .1-1.0 1-5 titanium oxide titanium dioxide 13463-67-7 5-10 10-20 5-10 1-5 5-10 10-20 10-20 5-10 tremolite, nonasbestiform tremolite 14567-73-8 10-20 5-10 10-20 10-20 10-20 5-10 10-20 5-10 5-10 5-10 10-20 talc talc 14807-96-6 5-10 5-10 5-10 5-10 5-10 5-10 5-10 1-5 5-10 5-10 5-10 quartz quartz 14808-60-7 .1-1.0 .1-1.0 .1-1.0 .1-1.0 anthophyllite, nonasbestiform anthophyllite 17068-78-9 1-5 1-5 1-5 1-5 1-5 1-5 1-5 .1-1.0 1-5 1-5 1-5 oxirane,2,2'-((1-methylethylidene)bis(4,1-phenyleneoxymethylene))bis, homopolymer epoxy resin 25085-99-8 10-20 10-20 10-20 10-20 10-20 10-20 10-20 10-20 10-20 20-30 10-20 c.i. pigment yellow 42 yellow iron oxide 51274-00-1 1-5 solvent naphtha (petroleum), light aromatic light aromatic solvent naphtha

64742-95-6 1-5 1-5 1-5 1-5 1-5 1-5 1-5 1-5 1-5 5-10 1-5 20-30 10-20 distillates (petroleum), steam-cracked, polymers with light steam-cracked petroleum naphtha aromatic hydrocarbon resin

68410-16-2 10-20 10-20 10-20 10-20 10-20 10-20 10-20 10-20 10-20 10-20 10-20 nutshell liquid, polymer with ethylenediamine and formaldehyde alkylated phenolic polyamine

68413-28-5 60-70 60-70

1-butanol n-butanol 71-36-3 5-10 5-10 5-10 5-10 5-10 5-10 5-10 5-10 5-10 5-10 5-10 5-10 5-10 benzene,1,2,4-trimethyl- pseudocumene 95-63-6 1-5 1-5 1-5 1-5 1-5 1-5 1-5 1-5 1-5 5-10 1-5 10-20 alkyl phenol blocked polyisocyanate alkyl phenol blocked polyisocyanate

Sup. Conf. 1-5 1-5 1-5 1-5 1-5 1-5 1-5 1-5 1-5 1-5 1-5 castor oil derivative rheological additive Sup. Conf. 1-5 1-5 1-5 1-5 1-5 1-5 1-5 polyamide rheological additive Sup. Conf. 1-5 1-5 1-5 1-5

Chemical Hazard Data (ANSI Sections 2, 8, 11, and 15)

ACGIH-TLV OSHA-PEL S.R.

Std. S2 S3 CCCommon Name CAS. No. 8-Hour TWA STEL C S 8-Hour TWA STEL C S H M N I O ethylbenzene 100-41-4 100 ppm 125 ppm not est. not est. 100 ppm not est. not est. not est. not est. n y y y n n y n ethylenediamine 107-15-3 10 ppm not est. not est. y 10 ppm not est. not est. not est. not est. y n y n n n n n 1,3,5-trimethylbenzene 108-67-8 25 ppm 35 ppm not est. not est. not est. not est. not est. not est. not est. n n n n n n n n methyl amyl ketone 110-43-0 50 ppm not est. not est. not est. 100 ppm not est. not est. not est. not est. n n n n n n n n mica 12001-26-2 3 mg/m3 not est. not est. not est. 3 mg/m3 not est. not est. not est. not est. n n n n n n n n antigorite 12135-86-3 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n n ferric oxide 1309-37-1 5 mg/m3 not est. not est. not est. 5 mg/m3 not est. not est. not est. not est. n n n n n n n n xylene 1330-20-7 100 ppm 150 ppm not est. not est. 100 ppm not est. not est. not est. not est. n y y y n n n n carbon black 1333-86-4 3.5 mg/m3 not est. not est. not est. 3.5 mg/m3 not est. not est. not est. not est. n n n n n n y n titanium dioxide 13463-67-7 10 mg/m3 not est. not est. not est. 10 mg/m3 not est. not est. not est. not est. n n n n n y y n tremolite 14567-73-8 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n n talc 14807-96-6 2 mg/m3 not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n n quartz 14808-60-7 .025 mg/m3 not est. not est. not est. 0.1 mg/m3 not est. not est. not est. not est. n n n n n y y n anthophyllite 17068-78-9 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n n

Footnotes: H=Hazardous Air Pollutant, M=Marine Pollutant C=Ceiling - Concentration that S=Skin - Additional exposure, n/a=not applicable ppm=parts per million S2=Sara Section 302 EHS P=Pollutant, S=Severe Pollutant should not be exceeded, over and above airborn exposure, not est=not established mg/m3=milligrams per cubic meter S3=Sara Section 313 Chemical Carcinogenicity Listed By:

even instantaneously. may result from skin absorption. CC=CERCLA Chemical Sup Conf=Supplier Confidential S.R.Std.=Supplier Recommended Standard N=NTP, I=IARC, O=OSHA, y=yes, n=no

Form: 235K, Page 4 of 4, prepared 08/08/06 epoxy resin 25085-99-8 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n n yellow iron oxide 51274-00-1 5 mg/m3 not est. not est. not est. 10 mg/m3 not est. not est. not est. not est. n n n n n n n n light aromatic solvent naphtha 64742-95-6 not est. not est. not est. not est. 500x ppm not est. not est. not est. not est. n n n n n n n n aromatic hydrocarbon resin 68410-16-2 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n n alkylated phenolic polyamine 68413-28-5 not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n n n-butanol 71-36-3 20 ppm not est. not est. not est. 100 ppm not est. not est. not est. not est. n y y n n n n n pseudocumene 95-63-6 25 ppm not est. not est. not est. not est. not est. not est. not est. not est. n y n n n n n n alkyl phenol blocked polyisocyanate Sup. Conf. not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n n rheological additive Sup. Conf. not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n n rheological additive Sup. Conf. not est. not est. not est. not est. not est. not est. not est. not est. not est. n n n n n n n n

Chemical Hazard Data (Continued) (ANSI Sections 2, 8, 11, and 15)

ACGIH-TLV OSHA-PEL S.R.

Std. S2 S3 CCCommon Name CAS. No. 8-Hour TWA STEL C S 8-Hour TWA STEL C S H M N I O

Footnotes: H=Hazardous Air Pollutant, M=Marine Pollutant C=Ceiling - Concentration that S=Skin - Additional exposure, n/a=not applicable ppm=parts per million S2=Sara Section 302 EHS P=Pollutant, S=Severe Pollutant should not be exceeded, over and above airborn exposure, not est=not established mg/m3=milligrams per cubic meter S3=Sara Section 313 Chemical Carcinogenicity Listed By:

even instantaneously. may result from skin absorption. CC=CERCLA Chemical Sup Conf=Supplier Confidential S.R.Std.=Supplier Recommended Standard N=NTP, I=IARC, O=OSHA, y=yes, n=no