B08_140P1424Q0056_Attachment_2_Tnemec_Coatings_SDS_and_PDS.pdf
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This document is a Product Data Sheet (PDS) and Safety Data Sheet (SDS) for the Epoxoline Series 21 coating product manufactured by Tnemec Company, Inc. The PDS provides technical details on the coating, including its generic description, common uses, special qualifications, surface preparation requirements, application instructions, and performance properties such as volume solids, dry film thickness, pot life, and volatile organic compound content.
The SDS covers the hazard identification, composition, first aid measures, firefighting, accidental release, handling and storage, exposure controls, physical and chemical properties, stability and reactivity, toxicological information, ecological information, disposal, and regulatory information for the Epoxoline Off White coating. This product is identified as OSHA hazardous and flammable, and contains ingredients that may cause skin/eye irritation, skin sensitization, and carcinogenic effects.
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EPOXOLINE ®
PRODUCT DATA SHEET
SERIES 21
PRODUCT PROFILE
© March 3, 2023 by Tnemec Company, Inc. PDS21
GENERIC DESCRIPTION Phenalkamine Epoxy
COMMON USAGE High solids, immersion-grade coating offering exceptional build per coat for long-term corrosion resistance. For use on the interior and exterior of steel or concrete tanks, reservoirs, pipes, valves, pumps, and equipment, as well as other steel and concrete substrates. Specially formulated to meet the latest requirements for use in potable water applications.
COLORS WH16 Off White, 35GR Black, 33GR Gray, 39BL Delft Blue, 1255 Beige. Note: Epoxies chalk with extended exposure to sunlight. Lack of ventilation, incomplete mixing, miscatalyzation or the use of heaters that emit carbon dioxide and carbon monoxide during application and initial stages of curing may cause yellowing to occur. Important: Due to the product's curing agent chemistry, color variations can be pronounced. However, these changes in color are aesthetic only and will not affect performance or certifications. Contact your Tnemec representative for more information.
SPECIAL QUALIFICATIONS Certified by NSF International in accordance with NSF/ANSI/CAN Std. 61 and the extraction requirements of NSF/ANSI/CAN 600. Series 21 is qualified for interior use on tanks and reservoirs, pipes, fittings, valves, and pumps.
Reference Tnemec’s certified product listing at www.nsf.org for additional details.
Series 21 conforms to AWWA C 210.
Conforms to AWWA D102 Inside Systems No. 1, 2, 5, and 6.
A two-coat and three-coat system of Series 21 meets the requirements of AWWA C550 Protective Interior Coatings for Valves and Hydrants. Contact your Tnemec representative for more information.
Published technical data and instructions are subject to change without notice. The online catalog at www.tnemec.com should be referenced for the most current technical data and instructions or you may contact your Tnemec representative for current technical data and instructions.
COATING SYSTEM
PRIMERS Steel: Self-priming, Series 1, L69, L69F, N69, N69F, 91-H2O, 94-H2O, 98-H2O, L140, L140F, N140, N140F, 394 Concrete: Self-priming, Series L69, L69F, N69, N69F, L140, L140F, N140, N140F, 215, 218 CMU: Self-priming or Series 215 Note: The following maximum recoat times apply; itself, 30 days; Series L69, N69, nine months; Series 1, L140, N140, 12 months.
TOPCOATS Series 21, 22, FC22, 72, 73, 406, 1028, 1029, 1094, 1095, 1096. Note: A 14-day maximum recoat time applies when topcoating with Series 22, FC22. A 30-day maximum recoat time applies when topcoating with itself and Series 72, 73, 406, 1028, 1029. A nine-month maximum recoat time applies when topcoating with Series 1094, 1096. A 12-month maximum recoat time applies when topcoating with Series 1095.
Published technical data and instructions are subject to change without notice. The online catalog at www.tnemec.com should be referenced for the most current technical data and instructions or you may contact your Tnemec representative for current technical data and instructions.
SURFACE PREPARATION
PRIMED STEEL Immersion Service: Scarify the Series L140, L140F, N140, N140F prime coat surface by brush-blasting with fine abrasive before topcoating if it has been exterior exposed for 30 days or longer and 21 is the specified topcoat.
Non-Potable, Immersion Service: Scarify the Series L69, L69F, N69, N69F prime coat surface by brush-blasting with fine abrasive before topcoating if it has been exterior exposed for 30 days or longer and 21 is the specified topcoat.
STEEL Immersion Service: SSPC-SP10/NACE 2 Near-White Blast Cleaning with a minimum angular anchor profile of 2.0 mils.
Non-Immersion Service: SSPC-SP6/NACE 3 Commercial Blast Cleaning with a minimum angular anchor profile of 2.0 mils. Note: Abrasive blast cleaning generally produces the best coating performance. If conditions will not permit this, Series 21 may be applied to SSPC-SP2 or SP3 Hand or Power Tool Cleaned surfaces.
CAST/DUCTILE IRON All external surfaces of ductile iron pipe and fittings shall be delivered to the application facility without asphalt or any other protective lining on the exterior surface. All oils, small deposits of asphalt paint, grease, and soluble deposits should be removed and uniformly abrasive blasted using angular abrasive in accordance with NAPF 500-03-04: External Pipe Surface condition. When viewed without magnification, the exterior surfaces shall be free of all visible dirt, dust, loose annealing oxide, rust, mold coating and other foreign matter. Any area where rust reappears before application shall be reblasted. The surface shall contain a minimum angular anchor profile of 1.5 mils (38.1 microns) (Reference NACE RP0287 or ASTM D 4417, Method C).
CONCRETE Allow new cast-in-place concrete to cure a minimum of 28 days at 75°F (24°C). Verify concrete dryness in accordance with ASTM F 1869 “Standard Test Method for Measuring Moisture Vapor Emission Rate of Concrete Subfloor Using Anhydrous Calcium Chloride” (moisture vapor transmission should not exceed three pounds per 1,000 square feet in a 24 hour period), F 2170 “Standard Test Method for Determining Relative Humidity in Concrete using in situ Probes” (relative humidity should not exceed 80%), or D 4263 “Standard Test Method for Indicating Moisture in Concrete by the Plastic Sheet Method” (no moisture present). Prepare concrete surfaces in accordance with NACE No. 6/SSPC-SP13 Joint Surface Preparation Standards and ICRI Technical Guidelines. Abrasive blast, shot-blast, water jet or mechanically abrade concrete surfaces to remove laitance, curing compounds, hardeners, sealers and other contaminants and to provide a minimum ICRI-CSP 3 surface profile. Large cracks, voids and other surface imperfections should be filled with a recommended filler or surfacer.
ALL SURFACES Must be clean, dry and free of oil, grease, chalk and other contaminants.
Published technical data and instructions are subject to change without notice. The online catalog at www.tnemec.com should be referenced for the most current technical data and instructions or you may contact your Tnemec representative for current technical data and instructions.
TECHNICAL DATA
VOLUME SOLIDS 82% ± 2.0% (mixed) †
RECOMMENDED DFT 4.0 to 20.0 mils (100 to 510 microns). Note: Thickness requirements will vary with the substrate, application method, and exposure. Contact your Tnemec representative.
kgranite Highlight kgranite Highlight kgranite Highlight kgranite Highlight kgranite Highlight kgranite Highlight kgranite Highlight kgranite Highlight kgranite Highlight kgranite Highlight
CURING TIME Temperature To Handle To Topcoat Potable Water Immersion
90°F (32°C) 2 hours 4 hours 7 days
75°F (24°C) 3 hours 5 hours 7 days
65°F (18°C) 5 hours 9 hours 8 days
55°F (13°C) 12 hours 18 hours 10 days
45°F (7°C) 20 hours 24 hours 12 days
40°F (4°C) 22 hours 28 hours 16 days
35°F (2°C) 64 hours 72 hours 18 days
Curing time varies with surface temperature, air movement, humidity, and film thickness. Note: Series 21 will continue to cure below 32°F (0°C), but at a slower speed. Please contact Tnemec Technical Services to discuss project-specific details.
Note: Maximum recoat time with itself is 30 days.
VOLATILE ORGANIC COMPOUNDS Unthinned: 1.20 lbs/gallon (144 grams/litre) Thinned 10% (No. 88 Thinner): 1.69 lbs/gallon (203 grams/litre) †
HAPS Unthinned: 1.14 lbs/gal solids Thinned 10% (No. 88 Thinner): 1.79 lbs/gal solids
THEORETICAL COVERAGE 1,315 mil sq ft/gal (31.5 m²/L at 25 microns). See APPLICATION for coverage rates. †
NUMBER OF COMPONENTS Two: Part A (epoxy) and Part B (amine)
MIXING RATIO By volume: two (Part A) to one (Part B)
PACKAGING Part A Part B When Mixed
Large Kit 2-5 gallon pails 1-5 gallon pail 15 gallons (56.8 L)
Medium Kit 1-6 gallon pail (partially filled)
1-3 gallon pail (partially filled) 5 gallon (18.9 L)
Small Kit 1-1 gallon can (partially filled)
1-1 gallon can (partially filled) 1 gallon (3.79 L)
NET WEIGHT PER GALLON 12.91 ± 0.25 lbs (5.86 ± 0.11 kg) †
STORAGE TEMPERATURE Minimum 20°F (-7°C) Maximum 110°F (43°C) Prior to application, the material temperature should be above 60°F (16°C). It is suggested the material be stored at this temperature at least 48 hours prior to use.
TEMPERATURE RESISTANCE (Dry) Continuous 250°F (121°C) Intermittent 275°F (135°C)
SHELF LIFE 12 months at recommended storage temperature.
FLASH POINT - SETA Part A: 85°F (29°C) Part B: 134°F (57°C)
HEALTH & SAFETY Paint products contain chemical ingredients which are considered hazardous. Read container label warning and Material Safety Data Sheet for important health and safety information prior to the use of this product.
Keep out of the reach of children.
© March 3, 2023 by Tnemec Company, Inc. PDS21
PRODUCT DATA SHEET
EPOXOLINE ® | SERIES 21
APPLICATION
PRODUCT DATA SHEET
EPOXOLINE ® | SERIES 21
PRODUCT DATA SHEET
EPOXOLINE ® | SERIES 21
PRODUCT DATA SHEET
EPOXOLINE ® | SERIES 21
PRODUCT DATA SHEET
EPOXOLINE ® | SERIES 21
PRODUCT DATA SHEET
EPOXOLINE ® | SERIES 21
PRODUCT DATA SHEET
EPOXOLINE ® | SERIES 21
PRODUCT DATA SHEET
EPOXOLINE ® | SERIES 21
PRODUCT DATA SHEET
EPOXOLINE ® | SERIES 21
COVERAGE RATES Dry Mils (Microns) Wet Mils (Microns) Sq Ft/Gal (m²/Gal)
Minimum 4.0 (100) 5.0 (125) 329 (30.5)
Maximum 20.0 (510) 24.0 (610) 66 (6.1)
Note: Maximum of 20.0 mils DFT in one coat. Allow for overspray and surface irregularities. Wet film thickness is rounded to the nearest 0.5 mil or 5 microns. Application of coating below minimum or above maximum recommended dry film thicknesses may adversely affect coating performance.
MIXING Mix the entire contents of Part A and Part B separately. Scrape all of the Part B into the Part A pail by using a flexible spatula. Use a variable speed drill with a PS Jiffy blade and mix the blended components for a minimum of two minutes.
Apply the mixed material within pot life limits after agitation. Note: Both components must be above 50°F (10°C) prior to mixing. For optimum application properties, the material temperature should be above 60°F (16°C). For applications to surfaces between 35°F to 50°F (2°C to 10°C) allow mixed material to stand 30 minutes and restir before use. Note: A large volume of material will set up quickly if not applied or lessened in mass. Caution: Do not reseal mixed material.
An explosion hazard may be created.
THINNING Caution: Do not add thinner to Part A prior to mixing with Part B. For air spray, airless spray, brush or roller, thin up to 10% or ¾ pint per gallon with No. 88 Thinner.
POT LIFE 2 hours at 77°F (21°C) 1 hour at 90°F (32°C)
SPRAY LIFE 1 hour at 77°F (21°C) 30 minutes at 90°F (32°C) kgranite Highlight kgranite Highlight kgranite Highlight kgranite Highlight
APPLICATION EQUIPMENT Air Spray
Gun Fluid Tip Air Cap Air Hose ID Mat’l Hose ID Atomizing Pressure Pot Pressure
DeVilbiss JGA E 765 or 704 5/16” or 3/8” (7.9 or 9.5 mm)
3/8” or 1/2” (9.5 or 12.7 mm)
75-100 psi (5.2-6.9 bar)
10-20 psi (0.7-1.4 bar)
Low temperatures or longer hoses require higher pot pressure.
Airless Spray
Tip Orifice Atomizing Pressure Mat’l Hose ID Manifold Filter
0.015”-0.025” (380-635 microns)
3000-4500 psi (207-310 bar)
1/4” or 3/8” (6.4 or 9.5 mm)
60 mesh (250 microns)
Use appropriate tip/atomizing pressure for equipment, applicator technique and weather conditions.
Roller: Roller application optional when environmental restrictions do not allow spraying. Use 3/8” or 1/2” (9.5 mm to
12.7 mm) synthetic woven nap covers.
Brush: Recommended for small areas only. Use high quality natural or synthetic bristle brushes.
SURFACE TEMPERATURE Minimum 35°F (2°C) Maximum 135°F (57°C) The surface should be dry and at least 5°F (3°C) above the dew point. Note: For Series 21 cure capabilities below 35°F (2°C), contact Tnemec Technical Services.
CLEANUP Flush and clean all equipment immediately after use with the recommended thinner or MEK.
† Values may vary with color.
© March 3, 2023 by Tnemec Company, Inc. PDS21
PRODUCT DATA SHEET
EPOXOLINE ® | SERIES 21
WARRANTY & LIMITATION OF SELLER'S LIABILITY: Tnemec Company, Inc. warrants only that its coatings represented herein meet the formulation standards of Tnemec Company, Inc. THE WARRANTY DESCRIBED IN THE ABOVE PARAGRAPH SHALL BE IN LIEU OF ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, INCLUDING BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. THERE ARE NO WARRANTIES THAT EXTEND BEYOND THE DESCRIPTION ON THE FACE HEREOF. The buyer's sole and exclusive remedy against Tnemec Company, Inc. shall be for replacement of the product in the event a defective condition of the product should be found to exist and the exclusive remedy shall not have failed its essential purpose as long as Tnemec is willing to provide comparable replacement product to the buyer. NO OTHER REMEDY (INCLUDING, BUT NOT LIMITED TO, INCIDENTAL OR CONSEQUENTIAL DAMAGES FOR LOST PROFITS, LOST SALES, INJURY TO PERSON OR PROPERTY, ENVIRONMENTAL INJURIES OR ANY OTHER INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL BE AVAILABLE TO THE BUYER. Technical and application information herein is provided for the purpose of establishing a general profile of the coating and proper coating application procedures. Test performance results were obtained in a controlled environment and Tnemec Company makes no claim that these tests or any other tests, accurately represent all environments. As application, environmental and design factors can vary significantly, due care should be exercised in the selection and use of the coating.
Tnemec Company, Inc. 6800 Corporate Drive Kansas City, Missouri 64120-1372 +1 816-483-3400 www.tnemec.com
PDS21© March 3, 2023 by Tnemec Company, Inc. Page 3 of 3
Safety Data Sheet
Issue Date 22-Jun-2023 Revision Date 22-Jun-2023 Revision Number 3
1. IDENTIFICATION
Product identifier Product Code F021-WH16A Product Name EPOXOLINE OFF WHITE
Other means of identification Common Name SERIES 21, PART A UN/ID no. UN1263 Synonyms None
Recommended use of the chemical and restrictions on use Recommended Use industrial paint.
Uses advised against Consumer use, For professional use only. Not for residential use.
Details of the supplier of the safety data sheet
Emergency telephone number Company Phone Number Tnemec Regulatory Dept: 816-474-3400 24 Hour Emergency Phone Number 800-535-5053 (Infotrac)
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Skin sensitization Category 1 Carcinogenicity Category 1A Specific target organ toxicity (single exposure) Category 3 Specific target organ toxicity (repeated exposure) Category 1
Label elements
EMERGENCY OVERVIEW
Manufacturer Address Tnemec Company, Inc. 123 W. 23rd Avenue, North Kansas City, MO 64116-3094 (816) 474-3400
Distributor Tnemec Company, Inc. 86 Boul, des Entreprises, Ste. 203, Boisbriand, Quebec Canada J7G 2T3
Flammable Liquids Category 3
Danger
Page 1 / 10
Hazard statements Causes skin irritation Causes serious eye irritation May cause an allergic skin reaction May cause cancer May cause respiratory irritation. May cause drowsiness or dizziness
F021-WH16A EPOXOLINE OFF WHITE Revision Date 22-Jun-2023
Precautionary Statements Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Contaminated work clothing should not be allowed out of the workplace Wear protective gloves Use only outdoors or in a well-ventilated area Do not breathe dust/fume/gas/mist/vapors/spray Do not eat, drink or smoke when using this product Keep away from heat/sparks/open flames/hot surfaces. — No smoking Keep container tightly closed Ground/bond container and receiving equipment Use only non-sparking tools Take precautionary measures against static discharge Keep cool Use explosion-proof electrical/ventilating/lighting/mixing/equipment
Response IF exposed or concerned: Get medical advice/attention IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention If skin irritation or rash occurs: Get medical advice/attention IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing In case of fire: Use CO2, dry chemical, or foam for extinction
Storage Store locked up Store in a well-ventilated place. Keep container tightly closed Keep away from children
Disposal Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC) Other information Toxic to aquatic life with long lasting effects Cancer hazard. Contains crystalline silica which can cause cancer. (Risk of cancer depends on duration and level of exposure).
Respirable crystalline silica (quartz) can cause silicosis, a fibrosis (scarring) of the lungs
SEE SAFETY DATA SHEET
Acute Toxicity 20.64858 % of the mixture consists of ingredient(s) of unknown toxicity.
Causes damage to organs through prolonged or repeated exposure Flammable liquid and vapor
Appearance viscous liquid Physical state liquid
Page 2 / 10
Odor No information available
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical name CAS No. Weight-%
EPOXY RESIN (LER) 25085-99-8 10 - <30%
MAGNESIUM SILICATE 14807-96-6 10 - <30%
CRYSTALLINE SILICA (QUARTZ) 14808-60-7 10 - <30%
TITANIUM DIOXIDE (TOTAL DUST) 13463-67-7 10 - <30%
METHYL ISOBUTYL KETONE 108-10-1 1 - <10%
CRYSTALLINE SILICA (QUARTZ) 14808-60-7 1 - <10%
PROPYLENE GLYCOL MONOMETHYL ETHER
(SKIN)
107-98-2 0.1 - <1%
*The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
Description of first aid measures
General advice If symptoms persist, call a physician.
Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If symptoms persist, call a physician.
Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
Ingestion If swallowed, do not induce vomiting. Get medical attention immediately.
Self-protection of the first aider Use personal protective equipment. Avoid contact with eyes, skin and clothing.
Most important symptoms and effects, both acute and delayed
Notes to physician Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media Carbon dioxide. Foam. Dry chemical.
Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire.
Specific hazards arising from the chemical Thermal decomposition can lead to release of irritating gases and vapours In the event of fire and/or explosion do not breathe fumes
Hazardous combustion products Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Carbon oxides. Aldehydes. Phenolics.
Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
Page 3 / 10
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions Use personal protective equipment. Avoid contact with eyes, skin and clothing. Ensure adequate ventilation. Remove all sources of ignition.
Environmental Precautions
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system.
Methods and material for containment and cleaning up
Methods for containment Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non-sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal.
Methods for cleaning up Pick up and transfer to properly labelled containers.
7. HANDLING AND STORAGE
Precautions for safe handling
Handling Handle in accordance with good industrial hygiene and safety practice. Wear personal protective equipment. Avoid contact with eyes, skin and clothing. Remove and wash contaminated clothing before re-use. Keep away from open flames, hot surfaces and sources of ignition. Do not breathe vapours or spray mist. Ensure adequate ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Do not ingest. Do not eat, drink or smoke when using this product. Wash thoroughly after handling.
Conditions for safe storage, including any incompatibilities
Storage Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children. Store locked up.
Incompatible products Incompatible with oxidizing agents. Acids. Bases. Halogenated compounds. Peroxides.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure guidelines .
Chemical name ACGIH TLV OSHA PEL NIOSH IDLH
MAGNESIUM SILICATE
14807-96-6
TWA: 2 mg/m3 particulate matter containing no asbestos and <1% crystalline silica, respirable particulate matter
- 1000 mg/m3
CRYSTALLINE SILICA (QUARTZ)
14808-60-7
TWA: 0.025 mg/m3 respirable particulate matter
TWA: 50 µg/m3 50 mg/m3 respirable dust
TITANIUM DIOXIDE (TOTAL DUST)
13463-67-7
TWA: 0.2 mg/m3 nanoscale respirable particulate matter
TWA: 2.5 mg/m3 finescale respirable particulate matter
TWA: 15 mg/m3 total dust 5000 mg/m3
METHYL ISOBUTYL KETONE
108-10-1
TWA: 20 ppm STEL: 75 ppm
TWA: 100 ppm TWA: 410 mg/m3
500 ppm
CRYSTALLINE SILICA (QUARTZ)
14808-60-7
TWA: 0.025 mg/m3 respirable particulate matter
TWA: 50 µg/m3 50 mg/m3 respirable dust
PROPYLENE GLYCOL
MONOMETHYL ETHER (SKIN)
107-98-2
TWA: 50 ppm STEL: 100 ppm
Page 4 / 10
Appropriate engineering controls
Engineering measures Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH''s Threshold Limit Values (TLV).
Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product.
Individual protection measures, such as personal protective equipment
Eye/face protection Use chemical resistant splash type goggles.
Skin and body protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Respiratory protection Use only with adequate ventilation. Do not breathe vapors, spray mist, or dust. Ensure fresh air entry during application and drying. If you experience eye watering, headache or dizziness or if air monitoring demonstrates vapor/mist or dust levels are above applicable limits, wear an appropriate, properly fitted respirator (NIOSH/MSHA approved) during and after application. Follow respirator manufacturer's directions for respirator use.
General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.
Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state liquid
Other Information
Molecular weight No information available Density 14.25938 lbs/gal Volatile organic compounds (VOC) content
1.35464 lbs/gal
Total volatiles weight percent 9.5 %
Appearance viscous liquid Odor No information available Color No information available Odor threshold No information available
Property Values Remarks pH No data available Melting point / freezing point No data available Boiling point / boiling range No information available Flash point 29 °C / 85 °F Pensky Martens - Closed Cup Evaporation rate No data available Flammability (solid, gas) No data available Flammability Limit in Air No data available
Upper flammability limit NA Lower flammability limit NA
Vapor pressure No data available Vapor density No data available Specific gravity 1.70976 g/cm3 Water solubility Insoluble in cold water Solubility in other solvents No data available Partition coefficient: n-octanol/water No data available Autoignition temperature No data available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity 6200 centipoises approx
Page 5 / 10
Total volatiles volume percent 20.29 % Bulk density No information available
10. STABILITY AND REACTIVITY
Reactivity
Chemical stability Stable under recommended storage conditions.
Possibility of hazardous reactions Polymerization can occur.
Conditions to avoid Heat, flames and sparks.
Incompatible materials Incompatible with oxidizing agents, Acids, Bases, Halogenated compounds, Peroxides
Hazardous decomposition products Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke).
Carbon monoxide. Unidentified organic and inorganic compounds. Carbon oxides. Aldehydes. Phenolics.
11. TOXICOLOGICAL INFORMATION
Information on Likely Routes of Exposure
Inhalation May cause central nervous system depression with nausea, headache, dizziness, vomiting, and incoordination. May cause irritation.
Eye contact Causes serious eye irritation.
Skin contact Irritating to skin. May cause sensitization by skin contact.
Ingestion Harmful if swallowed.
Chemical name LD50 Oral LD50 Dermal LC50 Inhalation
TITANIUM DIOXIDE (TOTAL DUST)
13463-67-7
> 10000 mg/kg ( Rat ) - = 5.09 mg/L ( Rat ) 4 h
METHYL ISOBUTYL KETONE
108-10-1
= 2080 mg/kg ( Rat ) = 3000 mg/kg ( Rabbit ) 2000 - 4000 ppm ( Rat ) 4 h
PROPYLENE GLYCOL
MONOMETHYL ETHER (SKIN)
107-98-2
= 5000 mg/kg ( Rat ) = 13 g/kg ( Rabbit ) > 7559 ppm ( Rat ) 6 h
Information on toxicological effects
Symptoms Symptoms of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing. May cause allergic skin reaction. May cause skin and eye irritation.
May cause respiratory irritation.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Chronic Toxicity Avoid repeated exposure. Prolonged exposure may cause chronic effects. Contains a known or suspected carcinogen. Skin sensitizer. Causes damage to organs through prolonged or repeated exposure.
Sensitization Product is or contains a sensitizer.
Mutagenicity No information available.
No data available
Page 6 / 10
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Chemical name ACGIH IARC NTP OSHA
MAGNESIUM SILICATE
14807-96-6
Group 3 -
CRYSTALLINE SILICA
(QUARTZ)
14808-60-7
A2 Group 1 Known X
TITANIUM DIOXIDE (TOTAL
DUST)
13463-67-7
A3 Group 2B - X
METHYL ISOBUTYL
KETONE
108-10-1
A3 Group 2B - X
CRYSTALLINE SILICA
(QUARTZ)
14808-60-7
A2 Group 1 Known X
Reproductive effects No information available.
STOT - single exposure Causes damage to organs STOT - repeated exposure Causes damage to organs through prolonged or repeated exposure Aspiration hazard No information available.
Acute Toxicity 20.64858 % of the mixture consists of ingredient(s) of unknown toxicity.
12. ECOLOGICAL INFORMATION
Ecotoxicity
Toxic to aquatic life with long lasting effects
25.37163 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical name Toxicity to algae Toxicity to fish Toxicity to daphnia
EPOXY RESIN (LER)
25085-99-8
11 mg/L 72 hr 2 mg/L 96 hr Oncorhynchus mykiss 1.8 mg/L 48h
MAGNESIUM SILICATE
14807-96-6
- 100: 96 h Brachydanio rerio g/L LC50 semi-static
METHYL ISOBUTYL KETONE
108-10-1
400: 96 h Pseudokirchneriella subcapitata mg/L EC50
496 - 514: 96 h Pimephales promelas mg/L LC50 flow-through
170: 48 h Daphnia magna mg/L
EC50
PROPYLENE GLYCOL
MONOMETHYL ETHER (SKIN)
107-98-2
- 20.8: 96 h Pimephales promelas g/L LC50 static
23300: 48 h Daphnia magna mg/L
EC50
Persistence and degradability No information available.
Bioaccumulation No information available.
Mobility in Environmental Media Chemical name log Pow
EPOXY RESIN (LER)
25085-99-8
METHYL ISOBUTYL KETONE
108-10-1
1.19
PROPYLENE GLYCOL MONOMETHYL ETHER (SKIN)
107-98-2
-0.437
Other Adverse Effects No information available
13. DISPOSAL CONSIDERATIONS
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Waste treatment methods
Disposal Methods It must undergo special treatment, e.g. at suitable disposal site, to comply with local regulations.
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
US EPA Waste Number
Chemical name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes
METHYL ISOBUTYL
KETONE
108-10-1
Included in waste stream:
F039
U161
BENZENE
71-43-2
U019 Included in waste streams:
F005, F024, F025, F037, F038, F039, K085, K104, K105, K141, K142, K143, K144, K145, K147, K151, K159, K169, K171, K172
0.5 mg/L regulatory level U019
CUMENE (SKIN)
98-82-8
U055
14. TRANSPORT INFORMATION
DOT
UN/ID no. UN1263 Proper Shipping Name PAINT Hazard Class 3 Packing Group III Emergency Response Guide Number
IATA
UN/ID no. UN1263 Proper Shipping Name PAINT Hazard Class 3 Packing Group III ERG Code 128
IMDG/IMO
UN/ID no. UN1263 Proper Shipping Name PAINT, (Epoxy Resin) Hazard Class 3 Packing Group III EmS No. F-E,S-E Marine Pollutant Yes
Additional Information Call TNEMEC Traffic Department - 816-474-3400 for additional information or other modes of Transportation.
15. REGULATORY INFORMATION
International Inventories TSCA Complies DSL/NDSL Does Not Comply EINECS/ELINCS Does Not Comply ENCS Does Not Comply IECSC Does Not Comply
KECL
Page 8 / 10
Does Not Comply
PICCS Does Not Comply AICS Does Not Comply
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):
Chemical name HAPS Data
METHYL ISOBUTYL KETONE
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and and Title 40n of the Code of Federal Regulations, Part 372:
Chemical name SARA 313 - Threshold Values
METHYL ISOBUTYL KETONE - 108-10-1 0.1
SARA 311/312 Hazardous Categorization
Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard Yes Sudden Release of Pressure Hazard No Reactive Hazard Yes
CERCLA
Chemical name Hazardous Substances RQs CERCLA EHS RQs RQ
METHYL ISOBUTYL KETONE
108-10-1 5000 lb RQ 5000 lb final RQ
RQ 2270 kg final RQ
California Prop. 65
WARNING: This product can expose you to the following chemicals which are known to the State of California to cause cancer and birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov.
Chemical name California Prop. 65 CRYSTALLINE SILICA (QUARTZ) - 14808-60-7 Carcinogen
TITANIUM DIOXIDE (TOTAL DUST) - 13463-67-7 Carcinogen METHYL ISOBUTYL KETONE - 108-10-1 Carcinogen
Developmental CRYSTALLINE SILICA (QUARTZ) - 14808-60-7 Carcinogen
AMORPHOUS SILICA - 7631-86-9 Carcinogen BENZENE - 71-43-2 Carcinogen
Developmental Male Reproductive
CUMENE (SKIN) - 98-82-8 Carcinogen
California SCAQMD Rule 443 Contains Photochemically Reactive Solvent
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State Right-to-Know
Chemical name New Jersey Massachusetts Pennsylvania
MAGNESIUM SILICATE
14807-96-6 X X X
CRYSTALLINE SILICA (QUARTZ)
14808-60-7
X X X
TITANIUM DIOXIDE (TOTAL DUST)
13463-67-7
X X X
METHYL ISOBUTYL KETONE
108-10-1
X X X
CRYSTALLINE SILICA (QUARTZ)
14808-60-7
X X X
PROPYLENE GLYCOL
MONOMETHYL ETHER (SKIN)
107-98-2
X X X
16. OTHER INFORMATION
Prepared By Tnemec Regulatory Dept: 816-474-3400 Revision Date 22-Jun-2023 Revision Summary 1 9 5 10 6 7 8 11 13 15 14 Disclaimer For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910.
To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist.
End of SDS
NFPA Health 2 Flammability 3 Instability 1 Physical hazard - HMIS (Hazardous Material Information System)
Health 2* Flammability 3 Reactivity 1
Page 10 / 10
Issue Date 22-Jun-2023 Revision Date 22-Jun-2023 Revision Number 5
1. IDENTIFICATION
Product identifier Product Code F021-0021B Product Name EPOXOLINE AMINE
Other means of identification Common Name SERIES 21, PART B UN/ID no. UN3469 Synonyms None
Recommended use of the chemical and restrictions on use Recommended Use industrial paint.
Uses advised against Consumer use, For professional use only. Not for residential use.
Details of the supplier of the safety data sheet
Emergency telephone number Company Phone Number Tnemec Regulatory Dept: 816-474-3400 24 Hour Emergency Phone Number 800-535-5053 (Infotrac)
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Acute toxicity - Oral Category 4 Acute toxicity - Dermal Category 4 Acute toxicity - Inhalation (Vapors) Category 4 Acute toxicity - Inhalation (Dusts/Mists) Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Respiratory sensitization Category 1 Skin sensitization Category 1 Germ cell mutagenicity Category 1B Carcinogenicity Category 1A Reproductive Toxicity Category 1B Specific target organ toxicity (single exposure) Category 1 Specific target organ toxicity (repeated exposure) Category 1
Label elements
EMERGENCY OVERVIEW
Manufacturer Address Tnemec Company, Inc. 123 W. 23rd Avenue, North Kansas City, MO 64116-3094 (816) 474-3400
Distributor Tnemec Company, Inc. 86 Boul, des Entreprises, Ste. 203, Boisbriand, Quebec Canada J7G 2T3
Flammable Liquids Category 3
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F021-0021B EPOXOLINE AMINE Revision Date 22-Jun-2023
Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Use only outdoors or in a well-ventilated area In case of inadequate ventilation wear respiratory protection Contaminated work clothing should not be allowed out of the workplace Wear protective gloves Do not breathe dust/fume/gas/mist/vapors/spray Keep away from heat/sparks/open flames/hot surfaces. — No smoking Keep container tightly closed Ground/bond container and receiving equipment Use only non-sparking tools Take precautionary measures against static discharge Use explosion-proof electrical/ventilating/lighting/mixing/equipment
Response IF exposed: Call a POISON CENTER or doctor/physician IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician Call a POISON CENTER or doctor/physician if you feel unwell If skin irritation or rash occurs: Get medical advice/attention IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth In case of fire: Use CO2, dry chemical, or foam for extinction
Storage
Danger
Hazard statements Causes skin irritation Causes serious eye damage May cause allergy or asthma symptoms or breathing difficulties if inhaled May cause an allergic skin reaction May cause genetic defects May cause cancer May damage fertility or the unborn child Causes damage to organs Causes damage to organs through prolonged or repeated exposure Flammable liquid and vapor
Appearance opaque Physical state liquid
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Odor amine
Store locked up Store in a well-ventilated place. Keep cool Keep away from children
Disposal Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC) Other information Harmful to aquatic life with long lasting effects Cancer hazard. Contains crystalline silica which can cause cancer. (Risk of cancer depends on duration and level of exposure).
Respirable crystalline silica (quartz) can cause silicosis, a fibrosis (scarring) of the lungs
SEE SAFETY DATA SHEET
Acute Toxicity 73.07911 % of the mixture consists of ingredient(s) of unknown toxicity.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical name CAS No. Weight-%
ALKYLATED PHENOLIC POLYAMINE 68413-28-5 30 - <60%
CRYSTALLINE SILICA (QUARTZ) 14808-60-7 10 - <30%
BENZYL ALCOHOL 100-51-6 10 - <30%
N-BUTANOL (SKIN) 71-36-3 1 - <10%
M-XYLENEDIAMINE 1477-55-0 1 - <10%
PHENOL (SKIN) 108-95-2 1 - <10%
ETHYLENEDIAMINE 107-15-3 1 - <10%
P-P'-ISOPROPYLIDENEDIPHENOL 80-05-7 0.1 - <1%
PETROLEUM SOLVENT (NAPTHA) 64742-95-6 0.1 - <1%
*The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
Description of first aid measures
General advice If symptoms persist, call a physician.
Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Immediate medical attention is required.
Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If symptoms persist, call a physician.
Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
Ingestion If swallowed, do not induce vomiting. Get medical attention immediately.
Self-protection of the first aider Use personal protective equipment. Avoid contact with eyes, skin and clothing.
Most important symptoms and effects, both acute and delayed
Notes to physician Treat symptomatically.
5. FIRE-FIGHTING MEASURES
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Suitable extinguishing media Carbon dioxide. Foam. Dry chemical.
Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire.
Specific hazards arising from the chemical Thermal decomposition can lead to release of irritating gases and vapours In the event of fire and/or explosion do not breathe fumes
Hazardous combustion products Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Carbon oxides. Oxides of nitrogen. Ammonia. Aldehydes.
Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions Use personal protective equipment. Avoid contact with eyes, skin and clothing. Ensure adequate ventilation. Remove all sources of ignition. Do not touch or walk through spilled material. Stop leak if you can do it without risk.
Environmental Precautions
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system.
Methods and material for containment and cleaning up
Methods for containment Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non-sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal.
Methods for cleaning up Pick up and transfer to properly labelled containers.
7. HANDLING AND STORAGE
Precautions for safe handling
Handling Handle in accordance with good industrial hygiene and safety practice. Wear personal protective equipment. Remove and wash contaminated clothing before re-use. Avoid contact with eyes, skin and clothing. Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharges. Do not breathe vapours or spray mist. Ensure adequate ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Do not ingest. Do not eat, drink or smoke when using this product. Wash thoroughly after handling.
Conditions for safe storage, including any incompatibilities
Storage Keep container tightly closed in a dry and well-ventilated place. Store locked up. Keep out of the reach of children.
Incompatible products sodium hypochlorite. Organic Acids. Oxidizing materials. Halogenated compounds.
Reducing agents. Zinc. calcium. Peroxides.
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure guidelines .
Chemical name ACGIH TLV OSHA PEL NIOSH IDLH
CRYSTALLINE SILICA (QUARTZ)
14808-60-7
TWA: 0.025 mg/m3 respirable particulate matter
TWA: 50 µg/m3 50 mg/m3 respirable dust
N-BUTANOL (SKIN)
71-36-3
TWA: 20 ppm TWA: 100 ppm TWA: 300 mg/m3
1400 ppm
M-XYLENEDIAMINE
1477-55-0
Skin Ceiling: 0.018 ppm
PHENOL (SKIN)
108-95-2
TWA: 5 ppm Skin
TWA: 5 ppm TWA: 19 mg/m3
Skin
250 ppm
ETHYLENEDIAMINE
107-15-3
TWA: 10 ppm Skin
TWA: 10 ppm TWA: 25 mg/m3
1000 ppm
Appropriate engineering controls
Engineering measures Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH''s Threshold Limit Values (TLV).
Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product.
Individual protection measures, such as personal protective equipment
Eye/face protection Use chemical resistant splash type goggles. If splashes are likely to occur, wear face-shield.
Skin and body protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Respiratory protection Use only with adequate ventilation. Do not breathe vapors, spray mist, or dust. Ensure fresh air entry during application and drying. If you experience eye watering, headache or dizziness or if air monitoring demonstrates vapor/mist or dust levels are above applicable limits, wear an appropriate, properly fitted respirator (NIOSH/MSHA approved) during and after application. Follow respirator manufacturer's directions for respirator use.
General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.
Avoid breathing dust created by cutting, sanding, or grinding.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state liquid Appearance opaque Odor amine Color No information available Odor threshold No information available
Property Values Remarks pH No data available Melting point / freezing point No data available Boiling point / boiling range No information available Flash point 57 °C / 134 °F Pensky Martens - Closed Cup Evaporation rate No data available Flammability (solid, gas) No data available Flammability Limit in Air No data available
Upper flammability limit N/A Lower flammability limit N/A
Vapor pressure No data available Vapor density
Page 5 / 12
Other Information
Molecular weight No information available Density 10.19994 lbs/gal Volatile organic compounds (VOC) content
0.88739 lbs/gal
Total volatiles weight percent 8.7 % Total volatiles volume percent 12.72 % Bulk density No information available
10. STABILITY AND REACTIVITY
Reactivity
Chemical stability Stable under recommended storage conditions.
Possibility of hazardous reactions None under normal processing.
Conditions to avoid Heat, flames and sparks.
Incompatible materials sodium hypochlorite, Organic Acids, Oxidizing materials, Halogenated compounds, Reducing agents, Zinc, calcium, Peroxides
Hazardous decomposition products Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke).
Carbon monoxide. Unidentified organic and inorganic compounds. Oxides of nitrogen. Ammonia. Aldehydes. Carbon oxides.
11. TOXICOLOGICAL INFORMATION
Information on Likely Routes of Exposure
Inhalation Harmful if inhaled. May cause sensitization by inhalation. May cause central nervous system depression with nausea, headache, dizziness, vomiting, and incoordination.
Eye contact Causes serious eye damage.
Skin contact Irritating to skin. May cause sensitization by skin contact.
Ingestion Harmful if swallowed.
Chemical name LD50 Oral LD50 Dermal LC50 Inhalation
BENZYL ALCOHOL
100-51-6
= 1230 mg/kg ( Rat ) = 2 g/kg ( Rabbit ) > 4178 mg/m3 ( Rat ) 4 h
N-BUTANOL (SKIN)
71-36-3
= 700 mg/kg ( Rat ) = 3402 mg/kg ( Rabbit ) > 8000 ppm ( Rat ) 4 h
M-XYLENEDIAMINE = 660 mg/kg ( Rat ) = 2 g/kg ( Rabbit ) = 1.16 mg/L ( Rat ) 4 h = 1.38 mg/L
Specific gravity 1.22301 g/cm3 Water solubility Insoluble in cold water Solubility in other solvents No data available Partition coefficient: n-octanol/water No data available Autoignition temperature No data available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity 3300 centipoises approx
Page 6 / 12
1477-55-0 ( Rat ) 4 h
PHENOL (SKIN)
108-95-2
= 340 mg/kg ( Rat ) = 630 mg/kg ( Rabbit ) -
ETHYLENEDIAMINE
107-15-3
= 637 mg/kg ( Rat ) = 560 mg/kg ( Rabbit ) = 14.7 mg/L ( Rat ) 4 h
P-P'-ISOPROPYLIDENEDIPHENOL
80-05-7
= 3300 mg/kg ( Rat ) = 3000 mg/kg ( Rabbit ) > 170 mg/m3 ( Rat ) 6 h
PETROLEUM SOLVENT (NAPTHA)
64742-95-6
= 8400 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) = 3400 ppm ( Rat ) 4 h
Information on toxicological effects
Symptoms Symptoms of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing. Skin disorders. Respiratory disorders. Eye Damage. Irritating to eyes and skin.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Chronic Toxicity Avoid repeated exposure. Prolonged exposure may cause chronic effects. Substances known to be mutagenic to man. Substances known to be carcinogenic to man. Substances known to impair fertility. May cause sensitization by inhalation and skin contact. Causes damage to organs through prolonged or repeated exposure. Eye Damage.
Sensitization May cause sensitization of susceptible persons.
Mutagenicity Substances known to be mutagenic to man.
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Chemical name ACGIH IARC NTP OSHA
CRYSTALLINE SILICA
(QUARTZ)
14808-60-7
A2 Group 1 Known X
PHENOL (SKIN)
108-95-2
Group 3 -
Reproductive effects Product is or contains a chemical which is a known or suspected reproductive hazard.
STOT - single exposure Causes damage to organs STOT - repeated exposure Causes damage to organs through prolonged or repeated exposure
Target organ effects Central nervous system, Eyes, kidney, liver, respiratory system, Skin, Reproductive System.
Aspiration hazard No information available.
Acute Toxicity 73.07911 % of the mixture consists of ingredient(s) of unknown toxicity.
12. ECOLOGICAL INFORMATION
Ecotoxicity
Harmful to aquatic life with long lasting effects
73.38499 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical name Toxicity to algae Toxicity to fish Toxicity to daphnia
BENZYL ALCOHOL
100-51-6
- 10: 96 h Lepomis macrochirus mg/L LC50 static 460: 96 h Pimephales promelas mg/L LC50 static
23: 48 h water flea mg/L EC50
N-BUTANOL (SKIN)
71-36-3
500: 72 h Desmodesmus subspicatus mg/L EC50 500: 96 h Desmodesmus subspicatus mg/L
EC50
100000 - 500000: 96 h Lepomis macrochirus µg/L LC50 static 1730 -
1910: 96 h Pimephales promelas mg/L LC50 static 1740: 96 h
Pimephales promelas mg/L LC50 flow-through 1910000: 96 h
Pimephales promelas µg/L LC50 static
1897 - 2072: 48 h Daphnia magna mg/L EC50 Static 1983: 48 h Daphnia magna mg/L EC50
M-XYLENEDIAMINE
1477-55-0
- 87.6: 96 h Oryzias latipes mg/L LC50 semi-static
PHENOL (SKIN)
108-95-2
0.0188 - 0.1044: 96 h Pseudokirchneriella subcapitata
11.9 - 25.3: 96 h Lepomis macrochirus mg/L LC50 flow-through
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10.2 - 15.5: 48 h Daphnia magna mg/L EC50 4.24 - 10.7: 48 h mg/L EC50 static 187 - 279: 72 h Desmodesmus subspicatus mg/L
EC50 static 46.42: 96 h Pseudokirchneriella subcapitata mg/L EC50
11.9 - 50.5: 96 h Pimephales promelas mg/L LC50 flow-through
20.5 - 25.6: 96 h Pimephales promelas mg/L LC50 static 23.4 - 36.6: 96 h Oryzias latipes mg/L
LC50 static 33.9 - 43.3: 96 h Oryzias latipes mg/L LC50 flow-through
34.09 - 47.64: 96 h Poecilia reticulata mg/L LC50 static 4.23 - 7.49: 96 h Oncorhynchus mykiss mg/L LC50 semi-static 5.0 - 12.0: 96 h Oncorhynchus mykiss mg/L LC50
5.449 - 6.789: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 7.5 - 14: 96 h Oncorhynchus mykiss mg/L LC50 static 0.00175:…
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