Attmt 7 - Novec SDS.pdf

Page 1 of 10 Pages 1230 Fire Extinguishant SDS Part Number 26928

Section 1. PRODUCT AND COMPANY IDENTIFICATION

SAFETY DATA SHEET

Product Name:

Other Identifiers:

Product Code(s):

Model Code(s) for Extinguishers:

Recommended Use:

Manufacturer:

Internet Address:

Address:

Company Telephone:

E-mail Address:

Emergency Contacts:

Revised:

3MTM NovecTM 1230 Fire Extinguishant Multi-purpose Liquid Chemical (Pressurized and Non-pressurized) 775/776 Streaming and Flooding Fire suppression, not for human or animal drug use.

AMEREX CORPORATION

www.amerex-fire.com 7595 Gadsden Highway, P.O. Box 81 Trussville, AL 35173-0081

(205) 655-3271 info@amerex-fire.com Chemtrec 1(800) 424-9300 or

(703) 527�3887 May 01, 2024; Revision G

GHS � Classification Hazard Class Category Signal Word

Aerosols Category 3 Warning

Hazardous to the aquatic environment, long-term hazard Category 3 None

GHS � Label Symbol(s):

If Pressurized: Gas Under Pressure

GHS � Signal Word(s): Warning

Other Hazards Not Resulting in Classification: May displace oxygen and cause rapid suffocation (simple asphyxiant).

Section 2. HAZARDS IDENTIFICATION

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Section 3. COMPOSITION/INFORMATION ON INGREDIENTS

Section 4. FIRST AID MEASURES

GHS � Hazard Phrases GHS Hazard GHS Code(s) Code Phrase(s)

Physical H229 *Pressurized container; may burst if heated.

Health None

Environmental H412 Harmful to aquatic life with long lasting effects.

Precautionary:

General P101

If medical advice is needed, have product container or label at hand.

Keep out of reach of children.

Prevention P210

*Keep away from heat, hot surface, sparks, open flames, and other ignition sources. No smoking.

*Do not pierce or burn, even after use.

Avoid release to the environment.

Response None

Storage 410+412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122°F.

Disposal P501 Dispose of contents/container through a licensed disposal company. Contaminated container should be disposed of as unused product.

*- Fire extinguishers are designed to be used to extinguish fires.

Chemical Name EC No. REACH Reg. No. CAS-No. Weight % 1,1,1,2,2,4,5,5,5- Nonafluoro-4-(trifluromethyl)-3-pentanone (Novec 1230)

436-710-6 NA 756-13-8 >99.9

Nitrogen 231-783-9 Annex IV/V 7727-37-9 <1

Note: Pressurized extinguisher uses nitrogen as an expellant

Emergency overview: Clear liquid, low odor.

Eye Exposure: May cause mild irritation. Irrigate eyes with water and repeat until pain free. Seek medical attention if irritation develops, or if vision changes occur.

Skin Exposure: May cause mild skin irritation. In case of contact, wash with plenty of soap and water. Seek medical attention if irritation persists.

Inhalation: No need for first aid is anticipated.

Ingestion: Rinse mouth. Obtain medical attention if ingestion problems continue.

Medical conditions possibly aggravated by exposure: No other medical conditions are anticipated.

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Section 6. ACCIDENTAL RELEASE MEASURES

Flammable Properties: Not flammable Flash Point: None Suitable Extinguishing Media: Non-combustible. Use extinguishing media suitable for surrounding conditions.

Hazardous Combustion Products: Main decomposition product is hydrogen fluoride in fire situations. By products are irritating and potentially toxic. Pressurized container can explode in heat of fire.

Explosion Data:

Sensitivity to Mechanical Impact: Not sensitive Sensitivity to Static Discharge: Not sensitive

Unusual fire/explosion hazards: Pressurized container can explode in heat of fire Protective Equipment and Precautions for Firefighters: As in any fire, wear self-contained breathing apparatus in pressure-demand, NIOSH approved or equivalent and full protective gear.

Personal Precautions: Evacuate area. Ventilate the area with fresh air. Use eye/face protection.

Personal Protective Equipment: Minimum � If a large release occurs in a closed environment, evacuate immediately. Until oxygen concentrations are known, personnel entering the environment should wear self-contained breathing apparatus (positive pressure supplied air respirator).

If ventilation is obviously adequate, wear an air-purifying respirator. If thermal decomposition products are present, wear a full-face air purifying respirator.

Emergency Procedures: NA Methods for Containment: Prevent further leakage or spillage if safe to do so. Contain with sorbent material and booms.

Methods for Clean Up: Contain and collect using sorbent material. Transfer to properly labeled containers for disposal.

Environmental Precautions: Prevent material from entering waterways, drains, and sewer systems.

Other: If product is contaminated, use PPE and containment appropriate to the nature of the most toxic chemical/material in the mixture.

Section 5. FIRE-FIGHTING MEASURES

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Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Personal Precautions: Use appropriate PPE when handling or maintaining equipment, and wash thoroughly after handling (see Sections 6 and 8). Do not breathe thermal decomposition products. For industrial or professional use only. Do not use in confined area with minimal air exchange. Do not eat, drink, or smoke while using this product. Wash thoroughly after handling. Avoid release to the environment.

Conditions for Safe Storage/Handling: Keep product in original container or extinguisher.

Contents are under pressure � inspect extinguisher for rust periodically to ensure container integrity.

Protect from sunlight. Store in a well-ventilated area.

Store away from strong bases, amines, and alcohols.

Incompatible Products: Incompatible with strong bases.

Chemical Name CAS NO. OSHA PEL 1,1,1,2,2,4,5,5,5- Nonafluoro-4-(trifluoromethyl)-3-pentanone 756-13-8 TWA: 150 ppm (1,940 mg/m3)

Value is an 8 hour time weighted average concentration.

Engineering Controls: Showers Eyewash stations Ventilation systems

Personal Protective Equipment:

Eye/Face Protection: Wear eye protection.

Skin and Body Protection: NA Respiratory Protection: Use a positive supplied-air respirator if there is a potential for over exposure from an uncontrolled release, if exposure levels are not known, or under

Section 7. HANDLING AND STORAGE

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Section 9. PHYSICAL AND CHEMICAL PROPERTIES

Section 10. STABILITY AND REACTIVITY any other circumstances where air-purifying respirators may not provide adequate protection. If thermal degradation products are expected, use a full face supplied air respirator.

Hygiene Measures: Good personal hygiene practices essential, such as avoiding food, tobacco products, or other hand-to-mouth contact when handling. Wash thoroughly after handling.

Appearance: Colorless liquid Molecular Weight: 316.05 Odor: Low odor Odor Threshold: No information available Decomposition Temperature °C: No information available Freezing/Melting Point °C: -108°C Initial Boiling Point °C: 49 °C at 1 atm Physical State: Liquid pH: Not applicable Flash Point °C: None Auto-ignition Temperature °C: Not applicable Flammability: Not Flammable Flammability Limits in Air °C: Upper � Not Flammable; Lower-Not Flammable Explosivity Upper � Not Explosive; Lower-Not Explosive Volatile Organic Compounds 1600 g/l Percent Volatile 100% Evaporation Rate: >1 Vapor Density: 11.6 (AIR=1) Vapor Pressure: 0.404 bar @ 25 °C Specific gravity at 25 °C: 1.6 Solubility: 40.95 mg/L @ 25 °C Partition Coefficient: octanol/air 8.3E-012 Viscosity: 0.6 centipoise @ 25 °C

Stability: Stable under recommended storage and handling conditions.

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Section 11. TOXICOLOGICAL INFORMATION

Reactivity: This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.

Incompatibles: Strong bases, amines, alcohols, water Conditions to Avoid: Storage or handling near incompatibles, heat, sunlight. Pressurized containers may rupture or explode if exposed to heat.

Hazardous Decomposition Products: Heat of fire or elevated temperatures may release hydrogen fluoride and perfluoroisobutylene.

Possibility of Hazardous Reactions: Slight Hazardous Polymerization: Will not occur.

Likely Routes of Exposure: Inhalation, skin, and eye contact.

Symptoms:

Immediate:

Inhalation: No known health effects.

Eyes: Normally does not cause significant irritation.

Skin: Normally does not cause significant irritation.

Delayed: Normally does not have a delayed reaction.

Acute Toxicity: Relatively non-toxic.

Chronic Toxicity:

Short-term Exposure: None known.

Long-term Exposure: None known.

Acute Toxicity Values - Health

Chemical Name LD50 LC50 (Inhalation) Oral Dermal

1,1,1,2,2,4,5,5,5- Nonafluoro-4-(trifluromethyl)-3-pentanone

>2000 mg/kg (rat) >2000 mg/kg (rat) 1,227 mg/m3 (rat)

Reproductive Toxicity: This product�s ingredients are not known to have reproductive or teratogenic effects.

Target Organs and Effects (TOST): This product is not known to have any single exposure target organ toxicities. Some data exists concerning impacts on liver, kidney, bladder, but the data are not sufficient for classification; all other potential organ impacts are not apparent.

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Section 12. ECOLOGICAL INFORMATION

Section 13. DISPOSAL CONSIDERATIONS

Other Toxicity Categories Chemical Name Germ Cell

Mutagenicity Carcinogenicity Reproductive Aspiration

1,1,1,2,2,4,5,5,5- Nonafluoro-4- (trifluromethyl)- 3-pentanone

Not a hazard Not considered carcinogenic

Not considered a hazard

Not a hazard

Note: Nitrogen, the expellant when in a pressurized container, is a simple asphyxiant.

Ecotoxicity: Harmful to aquatic life with long lasting impacts.

..Persistence/Degradability: Insoluble in water; Photolytic half-life 3-5 days.

Probability of rapid biodegradation: Est: -1.325 (Slow) Anaerobic biodegradation probability: Est: 0.2243 (Slow) Bioaccummulation potential: 63.04 L/Kg (Low) Bioconcentration factor: 63.02 L/Kg (wet-wt) (Low BFC) Mobility in soil: Highly insoluble in water Log Koc (Kow Method): Est: 2.66 Log Koa: Est: 1.529 Log Kow: Est 2.79

Ecotoxicological Information - 1,1,1,2,2,4,5,5,5- Nonafluoro-4-(trifluromethyl-3-pentanone

Test Organism Acute (LC50) EC50 Green algae, Selenastrum capricornutum N/A 7.7 mg/l (72 hours) Zebra Fish, Brachydanio rerio >1200 mg/l (96 hours) NA Water flea, Daphnia magna NA >1200 mg/l (48 hours) Green algae, Selenastrum capricornutum NA 1.2 mg/l (72 hours, No obs EC)

Safe Handling Use appropriate PPE when handling and wash thoroughly after handling (see Section 8).

Waste Disposal Considerations Dispose in accordance with federal, state, and local regulations.

Contaminated Packaging Dispose in accordance with federal, state, and local regulations. Use a leak-proof container

Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Combustion products will include halogen acid (HCl/HF/HBr). Facility must be capable of handling halogenated materials. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations

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Section 14. TRANSPORT INFORMATION

Section 15. REGULATORY INFORMATION classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.

NOTES:

This product is not a RCRA characteristically hazardous or listed hazardous waste.

Marine Pollutant: NO

See current applicable transport regulations (DOT - Ground, IATA � Air, IMDG � Maritime) prior to shipping.

NOTES:

This product is not defined as a hazardous material under U.S. Department of Transportation (DOT) 49 CFR 172, or by Transport Canada �Transportation of Dangerous Goods� regulations. This transportation information covers the Novec 1230 (CAS 756-13-8) fire extinguisher agent as shipped in bulk containers and not when contained in fire extinguishers or fire extinguisher systems.

Special Precautions for Shipping:

If shipped in a stored pressure-type fire extinguisher, and pressurized with a non-flammable, non-toxic inert expellant gas, the fire extinguisher is considered a hazardous material by the US Department of Transportation and Transport Canada. The proper shipping name shall be FIRE EXTINGUISHER and the UN designation is UN 1044. The DOT hazard class/division is LIMITED QUANTITY when pressurized to less than 241 psig and when shipped via highway or rail. UN Class

2.2. Non-Flammable Gas, when shipping via air. Packing Group � N/A

International Inventory Status: All ingredients are on the following inventories:

Country(ies) Agency Status United States of America TSCA Yes Canada DSL Yes Europe EINECS/ELINCS Yes Australia AICS Yes Japan MITI Yes South Korea KECL Does not comply

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U.S. Federal Regulatory Information:

SARA Title III Sect 311/312 Categorization: Pressurized Pressure Hazard

SARA Title III Sect 311/312 Categorization: Non-pressurized None

SARA Title III Sect 313 This product does not contain any chemicals that are listed in Section 313 at or above de minimis concentrations.

Clean Water/Clean Air Acts:

This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) or Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) and Section 112 of the Clean Air Act Amendments of 1990.

CERCLA

This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfunds Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, state, or provincial level.

U.S. State Regulatory Information:

Chemicals in this product are covered under specific State regulations, as denoted below:

Alaska - Designated Toxic and Hazardous Substances: None California � Permissible Exposure Limits for Chemical Contaminants: None Florida � Substance List: None Illinois � Toxic Substance List: None Kansas � Section 302/303 List: None Massachusetts � Substance List: None Minnesota � List of Hazardous Substances: None Missouri � Employer Information/Toxic Substance List: None New Jersey � Right to Know Hazardous Substance List: None North Dakota � List of Hazardous Chemicals, Reportable Quantities: None Pennsylvania � Hazardous Substance List: None Rhode Island � Hazardous Substance List: None Texas � Hazardous Substance List: None West Virginia � Hazardous Substance List: None Wisconsin � Toxic and Hazardous Substances: None California Proposition 65: No component is listed on the California Proposition 65 list.

U.S. State Right-to-Know Regulations

This product does not contain any substances regulated by state right-to-know regulations.

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This SDS conforms to requirements under U.S., U.K., Canadian, Australian, and EU regulations or standards, and conforms to the 2003 ANSI Z400.1 format. No modifications of this SDS are authorized by AMEREX Corporation. Questions or comments should be directed to AMEREX Corporation (See Section 1).

Issuing Date Revision Date Revision Notes

13-March-2018 01-May-2024; Revision G None

The information herein is given in good faith but no warranty, expressed or implied, is made.

This document is controlled by Amerex Compliance Department.

Section 16. OTHER INFORMATION