Attach 7 Appendix D - Coolant Specifications.pdf

Hysol MB 50Product name

Section 1. Identification

Hysol MB 50

Product type

SDS no. 465450

Use of the substance/mixture Metalworking fluid - soluble.

For specific application advice see appropriate Technical Data Sheet or consult our company representative.

Supplier Castrol New Zealand Limited 73 Remuera Road Newmarket Auckland, New Zealand www.castrol.com/nz Technical Helpline 0800 10 40 60

Emergency telephone number 0800 243643 (0800 CHEMHELP) (NZ use only)

SAFETY DATA SHEET

Product code 465450-AU22

0800 764 766 National Poison CentreNew Zealand National Poisons Centre

Liquid.

Section 2. Hazards identification

SKIN IRRITATION - Category 2 SERIOUS EYE DAMAGE - Category 1 SKIN SENSITISATION - Category 1

HSNO Classification

Signal word Danger

Hazard statements Causes skin irritation.

May cause an allergic skin reaction.

Causes serious eye damage.

Symbol

Precautionary statements

Prevention Wear protective gloves. Wear eye or face protection. Avoid breathing vapour.

Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace.

Response Take off contaminated clothing and wash it before reuse. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or physician.

Storage Not applicable.

Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations.

GHS label elements

This material is classified as hazardous according to criteria in the Hazardous Substances (Hazard Classification) Notice 2020.

This material is not classified as DANGEROUS GOODS according to criteria in New Zealand Standard 5433:2012 Transport of Dangerous Goods on Land.

Dermal contact. Eye contact. Inhalation.Routes of entry

Product name

Date of issue3.01

Hysol MB 50

16 August 2023 Format New Zealand

Product code 465450-AU22

Language

Page: 1/9

ENGLISH

( ENGLISH )

Version

Section 2. Hazards identification Other hazards which do not result in classification

Defatting to the skin.

Section 3. Composition/information on ingredients

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Substance/mixture

Occupational exposure limits, if available, are listed in Section 8.

Mixture

Highly refined mineral oil, emulsifiers and additives.

Ingredient name CAS number% (w/w)

Distillates (petroleum), hydrotreated heavy naphthenic ≥30 - ≤60 64742-52-5

Amine neutralised carboxylic acids ≥10 - ≤30 -

Amine neutralised phosphoric acid esters ≤5 -

2-Amino-2-methylpropanol ≤3.4 124-68-5

Amine neutralised carboxylic acids <3 -

2,2',2''-nitrilotriethanol ≤3 102-71-6 boric acid ≤1 10043-35-3

3-Iodo-2-propynyl butylcarbamate ≤0.21 55406-53-6

Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Wash out mouth with water if person is conscious. Get medical attention immediately. Chemical burns must be treated promptly by a physician.

In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing.

Check for and remove any contact lenses. Get medical attention immediately.

Chemical burns must be treated promptly by a physician.

Get medical attention immediately. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognised skin cleanser.

Wash clothing before reuse. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Clean shoes thoroughly before reuse. In the event of any complaints or symptoms, avoid further exposure. Chemical burns must be treated promptly by a physician.

If inhaled, remove to fresh air. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Get medical attention immediately.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

Notes to physician Treatment should in general be symptomatic and directed to relieving any effects.

In case of inhalation of decomposition products in a fire, symptoms may be delayed.

The exposed person may need to be kept under medical surveillance for 48 hours.

Description of necessary first aid measures

Indication of immediate medical attention and special treatment needed, if necessary

Product name

Date of issue3.01

Hysol MB 50

16 August 2023 Format New Zealand

Product code 465450-AU22

Language

Page: 2/9

ENGLISH

Section 5. Firefighting measures

No action shall be taken involving any personal risk or without suitable training.

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire.

Hazardous combustion products

Specific hazards arising from the chemical

Combustion products may include the following:

phosphorus oxides carbon oxides (CO, CO2) (carbon monoxide, carbon dioxide) nitrogen oxides (NO, NO2 etc.)

In a fire or if heated, a pressure increase will occur and the container may burst.

Fire-fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear.

Special protective equipment for fire-fighters

In case of fire, use water fog, alcohol resistant foam, dry chemical or carbon dioxide extinguisher or spray.

Extinguishing media

Do not use water jet.

Suitable

Not suitable

Special precautions for fire-fighters

Hazchem code Not available.

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non-combustible, absorbent material e.g.

sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Contaminated absorbent material may pose the same hazard as the spilt product. Dispose of via a licensed waste disposal contractor.

Entry into a confined space or poorly ventilated area contaminated with vapour, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work. Wear self-contained breathing apparatus. Wear a suitable chemical protective suit. Chemical resistant boots. See also the information in "For non-emergency personnel".

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Large spill

Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Small spill

Methods and material for containment and cleaning up

For non-emergency personnel

For emergency responders Entry into a confined space or poorly ventilated area contaminated with vapour, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work. Wear self-contained breathing apparatus. Wear a suitable chemical protective suit. Chemical resistant boots. See also the information in "For non-emergency personnel".

Section 7. Handling and storage Precautions for safe handling

Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator.

Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Avoid contact of spilt material and runoff with soil and surface waterways. Avoid prolonged or repeated contact with skin. During metal working, solid particles from workpieces or tools will contaminate the fluid and may cause abrasions of the skin. Where such abrasions result in a penetration of the skin, first aid treatment should be applied as soon as reasonably possible. The presence of certain metals in the workpiece or tool, such as chromium, cobalt and nickel, can contaminate the metalworking fluid and as a

Product name

Date of issue3.01

Hysol MB 50

16 August 2023 Format New Zealand

Product code 465450-AU22

Language

Page: 3/9

ENGLISH

Section 7. Handling and storage

Conditions for safe storage, including any incompatibilities result may induce allergic skin reactions. Evaporation of water from soluble cutting fluids during use may lead to an increase in concentration which may result in the development of skin conditions due to irritation and defatting. It is important to monitor fluid strength on a regular basis with a refractometer and maintain it at the recommended concentration. Lubricants from other sources and other contaminants should be minimised. Swarf and other debris should be removed. To maintain optimum performance and minimise bacterial spoilage, machine tool coolant systems should be cleaned on a regular basis.

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Store and use only in equipment/ containers designed for use with this product. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. DO NOT ADD NITRITES TO THIS FLUID.

Distillates (petroleum), hydrotreated heavy naphthenic NZ HSWA 2015 - GRWM 2016 (New Zealand).

WES-TWA: 5 mg/m³ 8 hours. Issued/ Revised: 6/2016 Form: Mist WES-STEL: 10 mg/m³ 15 minutes. Issued/ Revised: 9/2010 Form: Mist

2,2',2''-nitrilotriethanol NZ HSWA 2015 - GRWM 2016 (New Zealand).

WES-TWA: 5 mg/m³ 8 hours. Issued/ Revised: 1/1994

Boric acid ACGIH TLV (United States).

TWA: 2 mg/m³ 8 hours. Issued/Revised:

1/2005 Form: Inhalable fraction STEL: 6 mg/m³ 15 minutes. Issued/Revised:

1/2005 Form: Inhalable fraction

Section 8. Exposure controls/personal protection

Ingredient name Exposure limits

Recommended monitoring procedures

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

Appropriate engineering controls

All activities involving chemicals should be assessed for their risks to health, to ensure exposures are adequately controlled. Personal protective equipment should only be considered after other forms of control measures (e.g. engineering controls) have been suitably evaluated. Personal protective equipment should conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained.

Your supplier of personal protective equipment should be consulted for advice on selection and appropriate standards. For further information contact your national organisation for standards.

Provide exhaust ventilation or other engineering controls to keep the relevant airborne concentrations below their respective occupational exposure limits.

The final choice of protective equipment will depend upon a risk assessment. It is important to ensure that all items of personal protective equipment are compatible.

Control parameters

Occupational exposure limits

Biological exposure indices

No exposure indices known.

Product name

Date of issue3.01

Hysol MB 50

16 August 2023 Format New Zealand

Product code 465450-AU22

Language

Page: 4/9

ENGLISH

Section 8. Exposure controls/personal protection

Hand protection

In case of insufficient ventilation, wear suitable respiratory equipment.

For protection against metal working fluids, respiratory protection that is classified as “resistant to oil” (class R) or oil proof (class P) should be selected where appropriate. Depending on the level of airborne contaminants, an air-purifying, half-mask respirator (with HEPA filter) including disposable (P- or R-series) (for oil mists less than 50mg/m3), or any powered, air-purifying respirator equipped with hood or helmet and HEPA filter (for oil mists less than 125 mg/m3).

Where organic vapours are a potential hazard during metalworking operations, a combination particulate and organic vapour filter may be necessary.

The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory equipment. Safety procedures should be developed for each intended application.

Respiratory protection equipment should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions.

Wear suitable gloves. Undiluted fluid: Wear chemical resistant gloves.

Recommended: nitrile gloves.

Diluted fluid: Wear protective gloves if prolonged or repeated contact is likely.

Recommended: nitrile gloves. The correct choice of protective gloves depends upon the chemicals being handled, the conditions of work and use, and the condition of the gloves (even the best chemically resistant glove will break down after repeated chemical exposures). Most gloves provide only a short time of protection before they must be discarded and replaced. Because specific work environments and material handling practices vary, safety procedures should be developed for each intended application. Gloves should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions.

Undiluted fluid: Chemical goggles.

Diluted fluid: Safety glasses with side shields.

Eye protection

Respiratory protection

Skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental exposure controls

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.

Appropriate techniques should be used to remove potentially contaminated clothing.

Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures

Individual protection measures

Section 9. Physical and chemical properties

Physical state Liquid.

Not available.

Not available.Odour pH

Yellow. [Light]Colour

Flash point

9.4 to 9.9 [Conc. (% w/w): 5%]

Appearance

Auto-ignition temperature

Drop Point Not available.

Boiling point, initial boiling point, and boiling range

Not available.

Melting point/freezing point

Closed cup: >100°C (>212°F) [Estimated. Water content interferes with flash point determination.]

The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.

Product name

Date of issue3.01

Hysol MB 50

16 August 2023 Format New Zealand

Product code 465450-AU22

Language

Page: 5/9

ENGLISH

Section 9. Physical and chemical properties

Not available.

Density <1000 kg/m³ (<1 g/cm³) at 15°C

Particle characteristics

Median particle size Not applicable.

Ingredient name °C °F Method

2-Amino-2-methylpropanol 438 820.4 ASTM D 2161

2,2',2''-nitrilotriethanol 324 615.2

Vapour pressure

Ingredient name

Vapour Pressure at 20˚C Vapour pressure at 50˚C mm Hg kPa Method mm Hg kPa Method

Distillates (petroleum), hydrotreated heavy naphthenic

<0.08 <0.011 ASTM D 5191

Water 23.8 3.2

2-Amino- 2-methylpropanol

0.34 0.045 ASTM E 1194

2,2',2''-nitrilotriethanol <0.01 <0.0013

Relative vapour density

Solubility(ies) Not available.

Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid Avoid excessive heat.

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.Chemical stability

Incompatible materials

Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Under normal conditions of storage and use, hazardous polymerisation will not occur.

Reactive or incompatible with the following materials: oxidising materials.

Slightly reactive or incompatible with the following materials: acids.

Section 11. Toxicological information Information on likely routes of exposure

Inhalation May give off gas, vapour or dust that is very irritating or corrosive to the respiratory system. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.

May cause burns to mouth, throat and stomach.Ingestion

Skin contact Causes skin irritation. Defatting to the skin. May cause an allergic skin reaction.

Causes serious eye damage.Eye contact

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion

Inhalation No specific data.

Adverse symptoms may include the following:

stomach pains

Adverse symptoms may include the following:

irritation redness dryness cracking

Eye contact Adverse symptoms may include the following:

pain watering redness

Potential chronic health effects

Product name

Date of issue3.01

Hysol MB 50

16 August 2023 Format New Zealand

Product code 465450-AU22

Language

Page: 6/9

ENGLISH

Section 11. Toxicological information No known significant effects or critical hazards.General

No known significant effects or critical hazards.Carcinogenicity

No known significant effects or critical hazards.Mutagenicity

No known significant effects or critical hazards.Teratogenicity

Developmental effects No known significant effects or critical hazards.

Fertility effects No known significant effects or critical hazards.

Inhalation Not applicable.

Not applicable.Ingestion

Skin contact Not applicable.

Not applicable.Eye contact

Section 12. Ecological information

Mobility Liquid. Soluble in water.

LogPow BCF Potential

Bioaccumulative potential

Product/ingredient name

2-Amino-2-methylpropanol -0.63 - low 2,2',2''-nitrilotriethanol -1 - low Boric acid -1.09 - low

Persistence and degradability

Ecotoxicity No known significant effects or critical hazards.

Mobility in soil

Soil/water partition coefficient (KOC)

Not available.

Not available.

Expected to be biodegradable.

Section 13. Disposal considerations The generation of waste should be avoided or minimised wherever possible.

Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled.

Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Diluted Fluid The spent diluted fluid comprises a relatively stable emulsion. Dispose of via an authorised person/ licensed waste disposal contractor or by other suitable waste treatment techniques (e.g. emulsion splitting, coagulation and filtration) approved by the local authority. Spent fluid should never be disposed of down the drain. The aqueous phase should not be discharged into sewage systems unless provided for by local regulations; the non-aqueous phase should be disposed of as undiluted fluid. Note that separated aqueous solutions or effluents may contain metal salts as well as traces of oil and must be checked for conformity in these respects against consents given by the authorities before disposal. Further treatment may be required.

Disposal methods

Product name

Date of issue3.01

Hysol MB 50

16 August 2023 Format New Zealand

Product code 465450-AU22

Language

Page: 7/9

ENGLISH

Section 14. Transport information

UN number Proper shipping name

ClassesRegulatory information

PG* Label Additional information

IATA Class

IMDG Class

Not regulated.

Not regulated.

PG* : Packing group

ADG Class

New Zealand Class

Not regulated.

Not regulated.

Section 15. Regulatory information

HSNO Approval Number HSR002606

HSNO Group Standard Lubricants, Lubricant Additives, Coolants and Anti-freeze Agents (Subsidiary Hazard) Group Standard 2020

HSNO Classification SKIN IRRITATION - Category 2 SERIOUS EYE DAMAGE - Category 1 SKIN SENSITISATION - Category 1

For the REACH status of this product please consult your company contact, as identified in Section 1.

Not determined.

All components are listed or exempted.

Not determined.

Not determined.

At least one component is not listed.

Not determined.

At least one component is not listed.

REACH Status

United States inventory (TSCA 8b)

Philippines inventory

(PICCS)

China inventory (IECSC)

Canada inventory status

Australia inventory (AIIC)

Korea inventory (KECI)

Japan inventory (CSCL)

Regulation according to other foreign laws

New Zealand Regulatory Information

Taiwan Chemical Substances Inventory (TCSI)

Not determined.

Section 16. Other information History

Not available.

Date of issue/Date of revision

Version

Prepared by

Notice to reader

Date of previous issue

Indicates information that has changed from previously issued version.

Key to abbreviations Varies = may contain one or more of the following 64741-88-4, 64741-89-5, 64741-95-3, 64741-96-4, 64742-01-4, 64742-44-5, 64742-45-6, 64742-52-5, 64742-53-6, 64742-54-7, 64742-55-8, 64742-56-9, 64742-57-0, 64742-58-1, 64742-62-7, 64742-63-8, 64742-65-0, 64742-70-7, 72623-85-9, 72623-86-0, 72623-87-1

16 August 2023

29 July 2022.

3.01

Product name

Date of issue3.01

Hysol MB 50

16 August 2023 Format New Zealand

Product code 465450-AU22

Language

Page: 8/9

ENGLISH

Section 16. Other information All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy or completeness of the data and information in this data sheet.

The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other than for the stated application or applications without seeking advice from BP Group.

It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions that should be taken. You can contact the BP Group to ensure that this document is the most current available. Alteration of this document is strictly prohibited.

Product name

Date of issue3.01

Hysol MB 50

16 August 2023 Format New Zealand

Product code 465450-AU22

Language

Page: 9/9

ENGLISH

Hysol castrol.com/industrial-us

888-CASTROL

Your answer to the challenges of modern manufacturing

Castrol® Hysol®

MB 50

Multi-applications, multiple metals and harsh operating conditions make it difficult to keep metal-working fluids stable. Tramp oil, swarf and waste can leach into the system and promote bacterial growth, reduce the life of the fluid, compromise performance, and ultimately cause the system to fail. Combating this requires constant maintenance intervention that add complexity and cost to your operations. Castrol® Hysol® MB 50 makes a difference in the way you work, saving you time and money.

Castrol® Hysol® MB 50 is formulated to help you:

• Extend fluid life through a robust pH buffer package

• Reduce maintenance burden and machine downtime

• Minimize metalworking fluid usage, limit waste and reduce overall chemical spend

• Increase tramp oil rejection for easier removal, cleaner running systems and increased part cleanliness

Applicable sectors Aerospace, Automotive, Agriculture, Construction, Engine Manufacturing, Heavy Industry, Job Shops, Machine Manufacturing, Medical, Primary and Secondary Metals, Precision Machining

Multi-purpose product capabilities When your business performs a variety of operations over a range of different metals, using a single coolant often seems unachievable and with compromises between quality, practicality and the demand of your operations.

Developed to solve multiple challenges, Hysol® MB 50 can take you from a position of compromise to one of strength. It gives you the advantages of a single multi-metal, multi-purpose metalworking fluid with all of the expertise of Castrol® engineering behind it.

Typical characteristics Concentrate Mineral Oil High Ester Yes Boron Yes Amine Yes Chlorides No Biocide No

Emulsion Properties Refractometer Factor 1.1 Concentration (%) 5 - 10 Appearance Translucent Milky pH – 5% in DI Water 9.3 - 9.8 Cast Iron Chip Break Point 3% Water Tolerance, gpg 5-35

Hysol castrol.com/industrial-us

888-CASTROL

Castrol® Hysol®

MB 50

Address your machining challenges with

Increase productivity:

• Deliver consistently high quality surface finishes balanced with efficient production

• Eliminate risk of errors during top-ups with different coolants in the shop

Lower costs:

• Less downtime and manpower for coolant changeout

• Lowers inventory complexity by reducing the amount of metal-working fluids that are needed

Safer working environment:

• Reduce use of additives such as biocides and pH boosters

Increase productivity:

• Reduce downtime for cleaning, coolant refresh and filter changes

• Reduce stoppages due to foam

Lower costs:

• Extend tool life, reduce need for maintenance and spares

• Reduce water treatment management

Safer working environment:

• Cleaner workplace and less chemical handling

Challenge:

Coolant life

Challenge:

Multiple coolants, multi-metal machining

Challenge:

Water hardness tolerance

Castrol® Hysol® MB 50 is formulated with a resilient additive technology that resists the negative effects of bacterial growth and contamination. Your metalworking systems maintain performance, so you can rely on them to work harder for longer.

Castrol® Hysol® MB 50 delivers consistent performance across multiple machining processes and metals. You can run your shop on a single coolant, simplify operations and make it easier to meet business demands.

Castrol® Hysol® MB 50 is designed to operate across a range of water hardness (100 – 600 ppm CaCO3). It resists foaming and provides superior emulsion stability, reducing maintenance needs and simplifying operations.

Increase productivity:

• Less downtime for cleaning

• Reduce frequency of coolant top-ups

Lower costs:

• Reduce maintenance for cleaning contaminated systems

• Coolant lasts longer with lower waste disposal

Safer working environment:

• Bacteria-resistant technology reduces the need for tank side biocides

HOCUT™ 795-H

Not available.

CHEMTREC US/Canada:1-800-424-9300 or 1-703-527-3887 (24 hours)

SAFETY DATA SHEET

Product name

Other means of identification

Emergency telephone number (with hours of operation)

Section 1. Identification

Supplier : Quaker Houghton PA, Inc.

901 E. Hector Street Conshohocken, PA 19428 USA T: 610-832-4000

Wallover Oil Company 21845 Drake Road Strongsville, OH 44149 USA www.wallover.com T: (440) 238-9250

ProductStewardship@quakerhoughton.com www.quakerhoughton.com

HOCUT™ 795-H

Relevant identified uses of the substance or mixture and uses advised against

Relevant uses

Uses advised against

Product code : 202374-01

SDS according to the U.S. OSHA Hazard Communication Standard (29 CFR 1910.1200), Revison 2012

Metalworking fluid

Any other purpose.

Section 2. Hazards identification

SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A SKIN SENSITIZATION - Category 1

Classification of the substance or mixture

Signal word : Warning

Hazard statements : Causes skin irritation.

May cause an allergic skin reaction.

Causes serious eye irritation.

Hazard pictograms :

GHS label elements

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200).

Date of issue/Date of revision : 24 January 2021 Version : 1 1/10

HOCUT™ 795-H 202374-01

Section 2. Hazards identification Precautionary statements

Prevention : Wear eye or face protection. Avoid breathing vapor. Wash thoroughly after handling.

Response : Take off contaminated clothing and wash it before reuse. Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.

Continue rinsing. If eye irritation persists: Get medical advice or attention.

Storage : Not applicable.

Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations.

Hazards not otherwise classified

: None known.

Section 3. Composition/information on ingredients

Mineral oil ≥50 - ≤75 ** 1-aminopropan-2-ol ≤10 78-96-6 Amine neutralized carboxylic Acid ≤5 - Amine neutralized carboxylic Acid ≤5 - Amine neutralized dicarboxylic Acid ≤3 - Alcohols, C12-15, ethoxylated ≤3 68131-39-5 Amine neutralized carboxylic Acid ≤3 - Amine neutralized carboxylic Acid ≤2.3 - 1,2-benzisothiazol-3(2H)-one ≤0.1 2634-33-5

Ingredient name CAS number%

Substance/mixture : Mixture

The exact percentage (concentration) of composition has been withheld as a trade secret

64742-52-5,64742-53-6:** May contain

The mineral oils in the product contain < 3% DMSO extract (IP 346).

Ingestion may cause gastrointestinal irritation and diarrhea. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person.

Flush with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Remove contact lenses, if present and easy to do. Get medical attention if symptoms occur.

Wash with plenty of soap and water. Remove contaminated clothing and wash it before reuse. Get medical attention if symptoms occur.

Move affected person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Get medical attention.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion :

Description of necessary first aid measures

Most important symptoms and effects, both acute and delayed

Inhalation : Not expected under normal use.

Not expected under normal use.:Ingestion

Skin contact : pain or irritation,redness,skin rash or hives pain or irritation,redness,watering:Eye contact

General advice : Get medical attention. If medical advice is needed, have product container or label at hand. Use personal protective equipment as required. Remove contaminated clothing and wash it before reuse. Wash skin surfaces thoroughly after contact.

Date of issue/Date of revision : 24 January 2021 Version : 1 2/10

Section 4. First aid measures

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Use personal protective equipment as required.

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.

The exposed person may need to be kept under medical surveillance for 48 hours.

Specific treatments : No specific treatment.

Indication of immediate medical attention and special treatment needed, if necessary

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

In a fire, hazardous decomposition products may be produced. carbon oxides (CO, CO₂) nitrogen oxides

In a fire or if heated, a pressure increase will occur and the container may burst.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

Use an extinguishing agent suitable for the surrounding fire. Use dry chemical, CO₂, water spray (fog) or foam.

Extinguishing media

Do not use water jet.

Suitable extinguishing media

Unsuitable extinguishing media

Special protective actions for fire-fighters

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Stop leak if without risk. Move containers from spill area. For large spills, dike spilled material or otherwise contain it to ensure runoff does not reach a waterway. Absorb with an inert material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

: No action shall be taken involving any personal risk or without suitable training. Put on appropriate personal protective equipment (see Section 8). Keep unnecessary personnel away. Avoid breathing vapor or mist. Provide adequate ventilation.

Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Do not allow any potentially contaminated water, including rain water, runoff from fire fighting or spills, to enter any waterway, sewer or drain.

Large spill :

Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Absorb with an inert material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Small spill :

Methods and materials for containment and cleaning up

For non-emergency personnel

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". Evacuate area.

Date of issue/Date of revision : 24 January 2021 Version : 1 3/10

Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage, including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

Protective measures Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest.

Precautions for safe handling

Storage temperature : Store between the following temperatures: -5 to 50°C (23 to 122°F).

Mineral oil NIOSH REL (United States, 10/2016).

TWA: 5 mg/m³ 10 hours. Form: Mist STEL: 10 mg/m³ 15 minutes. Form: Mist ACGIH TLV (United States).

TWA: 5 mg/m³ 8 hours.

STEL: 10 mg/m³ 15 minutes.

1-aminopropan-2-ol None.

Amine neutralized carboxylic Acid None.

Amine neutralized carboxylic Acid None.

Amine neutralized dicarboxylic Acid None.

Alcohols, C12-15, ethoxylated None.

Amine neutralized carboxylic Acid None.

Amine neutralized carboxylic Acid None.

1,2-benzisothiazol-3(2H)-one None.

Section 8. Exposure controls/personal protection

Ingredient name Exposure limits

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.

Eye/face protection :

Environmental exposure controls

: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Appropriate engineering controls

: If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Keep equipment clean.

Hygiene measures :

Control parameters

Individual protection measures

Occupational exposure limits

Date of issue/Date of revision : 24 January 2021 Version : 1 4/10

Section 8. Exposure controls/personal protection Hand protection

Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers.

Respiratory protection :

Other skin protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Thermal hazards : Not expected under normal use. Not relevant/applicable due to nature of the product.

Section 9. Physical and chemical properties

Physical state

Melting point

Vapor pressure

Relative density

Vapor density

Solubility

Liquid.

Not available.

0.942

Not available.

Not available.

Characteristic.Odor pH

HazyColor

Evaporation rate Not available.

Auto-ignition temperature

Flash point

Not available.

Not available.

Not available.

10.2 [Conc. (% w/w): 5%]

Viscosity Kinematic (40°C (104°F)): >0.206 cm2/s (>20.6 cSt)

Not available.Odor threshold

Partition coefficient: n-octanol/water

Appearance

Boiling point : Not available.

Flammability (solid, gas) : Not available.

Lower and upper explosive (flammable) limits

: Not available.

Decomposition temperature : Not available.

Solubility in water : Not available.

Emulsifies.

VOC content

142 g/l:Product ASTM E1868-10

Date of issue/Date of revision : 24 January 2021 Version : 1 5/10

Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid No specific measures identified.

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.Chemical stability

Strong oxidizing materials. strong acids. strong alkalis

Incompatible materials :

Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Section 11. Toxicological information

Numerical measures of toxicity

1-aminopropan-2-ol LD50 Dermal Rabbit 1851 mg/kg - LD50 Oral Rat 1715 mg/kg -

Alcohols, C12-15, ethoxylated LD50 Oral Rat 2 g/kg - 1,2-benzisothiazol-3(2H)-one LC50 Inhalation Dusts and mists Rat 0.0501 mg/l 4 hours

LD50 Dermal Rat 4115 mg/kg - LD50 Oral Rat 1020 mg/kg -

Product/ingredient name Result Species Dose Exposure

Carcinogenicity

Mutagenicity

Reproductive toxicity

Irritation/Corrosion

1-aminopropan-2-ol Eyes - Severe irritant Rabbit - 24 hours 250 ug

Eyes - Severe irritant Rabbit - 970 ug - Skin - Mild irritant Rabbit - 24 hours 500 mg

Skin - Moderate irritant Rabbit - 485 mg - 1,2-benzisothiazol-3(2H)-one Skin - Mild irritant Human - 48 hours 5 % -

Product/ingredient name Result Score Exposure Observation

: Causes severe eye irritation. Causes skin irritation.

Sensitization

Species

Information on the likely routes of exposure

Other information : None identified.

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)

Acute toxicity estimates

Aspiration hazard

Information on toxicological effects

Route

Oral 4816.6 mg/kg Dermal 10785.65 mg/kg

ATE value

Acute toxicity : Based on available data, the classification criteria are not met.

: May cause sensitization by skin contact.

Based on available data, the classification criteria are not met.

Based on available data, the classification criteria are not met.

: Based on available data, the classification criteria are not met.

Based on available data, the classification criteria are not met.

Based on available data, the classification criteria are not met.

: Based on available data, the classification criteria are not met.

Date of issue/Date of revision : 24 January 2021 Version : 1 6/10

Section 11. Toxicological information Inhalation : No known significant effects or critical hazards.

:Ingestion

Skin contact : Causes skin irritation. May cause sensitization by skin contact.

Causes serious eye irritation.:Eye contact

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion

Inhalation Not expected under normal use.

Not expected under normal use.

pain or irritation,redness,skin rash or hives

Eye contact : pain or irritation,redness,watering

No known significant effects or critical hazards.

Delayed and immediate effects and also chronic effects from short and long term exposure

None identified.

Section 12. Ecological information

LogPow BCF Potential

Bioaccumulative potential

Other adverse effects : No known significant effects or critical hazards.

Product/ingredient name

1-aminopropan-2-ol -0.96 0.11 low Alcohols, C12-15, ethoxylated 2.03 to 6.24 - high

Toxicity

1-aminopropan-2-ol Acute EC50 32.7 mg/l Algae - Scenedesmus subspicatus

72 hours

Acute EC50 108.82 mg/l Daphnia - Daphnia magna 48 hours Acute LC50 210 mg/l Fresh water Fish - Carassius auratus 96 hours

Alcohols, C12-15, ethoxylated Acute EC50 0.7 mg/l Fresh water Algae - Pseudokirchneriella subcapitata

96 hours

Acute EC50 0.39 mg/l Fresh water Crustaceans - Ceriodaphnia dubia - Neonate

48 hours

Acute EC50 302 µg/l Fresh water Daphnia - Daphnia magna - Neonate

48 hours

Acute LC50 1400 µg/l Fresh water Fish - Pimephales promelas 96 hours Chronic NOEC 1 mg/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours

Chronic NOEC 83 µg/l Fresh water Daphnia - Daphnia magna - Neonate

21 days

1,2-benzisothiazol-3(2H)-one Acute EC50 0.11 mg/l Algae - Selenastrum capricornutum

72 hours

Acute EC50 97 ppb Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 10 to 20 mg/l Fresh water Crustaceans - Ceriodaphnia dubia 48 hours

Acute LC50 167 ppb Fresh water Fish - Oncorhynchus mykiss 96 hours

Product/ingredient name SpeciesResult Exposure

Persistence and degradability

Soil/water partition coefficient (KOC)

: Not available.

Mobility in soil

This material is toxic to aquatic life. This material is harmful to aquatic life with long lasting effects.

Date of issue/Date of revision : 24 January 2021 Version : 1 7/10

Section 12. Ecological information

Section 13. Disposal considerations Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Empty containers or liners may retain some product residues. Empty containers retain product residue and can be hazardous.

Care should be taken when handling emptied containers that have not been cleaned or rinsed out.

:Disposal methods

Section 14. Transport information

Not regulated.

Not regulated. Not regulated.

DOT Classification

UN number

UN proper shipping name

Transport hazard class(es)

Packing group

Additional information

Environmental hazards

Special precautions for user

No. No. No.

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IMDG IATA

Transport in bulk according to IMO instruments

: Not available.

Section 15. Regulatory information U.S. Federal regulations

Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs)

SARA 302/304

None of the components are listed.

Clean Water Act (CWA) 311

None of the components are listed.

None of the components are listed.

Clean Water Act (CWA) 307

CERCLA: Hazardous substances.

Reportable quantity 1,4-dioxane: 100 lbs. (45.4 kg); ethylene oxide: 10 lbs. (4.54 kg); 2,2'-iminodiethanol:

100 lbs. (45.4 kg); sodium hydroxide: 1000 lbs. (454 kg); acetaldehyde: 1000 lbs. (454 kg);

This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).

Date of issue/Date of revision : 24 January 2021 Version : 1 8/10

Section 15. Regulatory information

The following components are listed: 1-AMINO-2-PROPANOLMassachusetts :

SARA 313

Diethanolamine Trace Cancer Ethylene oxide Trace Cancer, Developmental, Reproductive female, Reproductive male Acetaldehyde Trace Cancer 1,4-Dioxane Trace Cancer

Ingredient name Concentration

California Prop. 65

New York : None of the components are listed.

New Jersey : The following components are listed: 2-PROPANOL, 1-AMINO-

Pennsylvania : The following components are listed: 2-PROPANOL, 1-AMINO-

State regulations

None of the components are listed.

SARA 311/312

Classification : See GHS Classification in section 2 for hazard class information

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.

California

SCAQMD Rule 1144

142 g/l ASTM E1868-10Product as-supplied :

International regulations

Montreal Protocol

Not listed.

Stockholm Convention on Persistent Organic Pollutants

Not listed.

Rotterdam Convention on Prior Informed Consent (PIC)

UNECE Aarhus Protocol on POPs and Heavy Metals

Not listed.

Inventory list

United States : All components are active or exempted.

Not listed.

Canada : All components are listed or exempted.

The sale or distribution in the SCAQM District of California for metal working fluids or direct-contact lubricants is allowed if EITHER the VOC of the product itself OR the VOC of the diluted product at the point of use is less than the following limits: (1) 75 g VOC/L for metal forming, metal removal, metal treating; (2) 50 g VOC/L for metal protection, direct-contact lubricant. The VOC of this product as sold is:

Date of issue/Date of revision : 24 January 2021 Version : 1 9/10

Section 16. Other information

Version

This…