Appendix_6-Geosyntec_Supplemental_Soil_Sampling_Results_Summary-3-18-2024.pdf

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ARPA Stormwater Starkey Facility M10 Modification (PID 003900A) (Rebid)
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19321 U.S. Highway 19 North, Building C, Suite 200 Clearwater FL 33764

PH 813.792.4820

www.geosyntec.com

Technica l Memorandum Date: 18 March 2024

To: Nancy Lamagna, PE, ENV SP – Pinellas County Public Works Stormwater & Parks Capital Improvements Division

From: Ryan Tuttle, PG and Mark Ellard, PE, CFM, BC.WRE, ENV SP - Geosyntec Consultants

Subject: Supplemental Soil Sampling Results Summary M10 Starkey SMF Retrofit Design Pinellas County, Florida

This memorandum summarizes the result of soil characterization activities pertaining to the M10 Starkey Stormwater Management Facility (SMF) Retrofit. Geosyntec Consultants was tasked by Pinellas County to perform this work. The work was performed under the Pinellas County Stormwater Professional Engineering Services Contract 190-0028-CN.

SOIL CHARACTERIZATION FOR OFFSITE DISPOSAL

Soil borings were performed using direct push technology (DPT) on February 8–9, 2024 from 9 locations. These locations were chosen to collect soils considered representative of the areas that are proposed to be excavated as part of the project. The characterization would allow for evaluation of the potential for soil reuse and/or waste characterization for off-Site disposal.

• Seven locations (6C-1, 6C-2, 6C-3, 6C-4, M10-1, M10-2, M10-3) were sampled in the proposed 6C and M10 pond areas. Composite samples were collected from each location from the land surface to 20 feet (ft) below land surface ([bls]; i.e., two feet below the proposed stormwater pond depth of 18 ft bls). The soils associated with these areas are proposed for offsite reuse where appropriate.

• Two locations (WEIR-1 and WEIR-2) were sampled from the outfall ditch downstream of the wetland mitigation area within the area of the proposed weir structure. Composite samples were collected from each location from land surface to the proposed depth (11 ft bls) of the new weir structure. The soils associated with this area are proposed for offsite landfill disposal.

The approximate soil sampling locations for the ponds are shown on Figure 1 and the weir soil sample locations are shown on Figure 2.

Supplemental Soil Sampling Results Summary

Pinellas County, Florida 18 March 2024

The soil characterization results were screened against the “Dredge Sediment Testing Decision Tree” and “Pinellas County Solid Waste Dredged Material Testing Guidelines” documentation provided to Geosyntec by the County to determine any restrictions on the reuse of these excavated soils on other sites. This guidance documentation reflecting project specific results markups is included as Attachment A.

It is noted that the initial step from the decision tree of screening soils with grain size analysis to determine applicability for analytical evaluation was skipped for these locations because of previous soil results obtained in 2020 which showed some exceedances of various criteria.

Therefore, this current characterization proceeded directly to analytical evaluation.

The following evaluation and analysis were performed on the samples based on the guidance:

• Proposed Weir location samples were evaluated for Toxicity Characteristic Leaching Procedure (TCLP) volatiles, semi-volatiles, and metals (Pinellas County Solid Waste Dredged Material Testing Guidelines). The TCLP results were compared to the TCLP maximum contaminant levels criteria (40 CFR 261.24) and indicated no detections of volatile or semi-volatile constituents. Arsenic, barium, and lead were detected in samples WEIR-1-CS and WEIR-2-CS, but below the referenced maximum contaminant levels. The TCLP sample results demonstrate soils from the weir installation can be disposed at the Pinellas County Solid Waste/Bridgeway Acres Facility as non-hazardous waste. These results are summarized on Table 1.

• Proposed Pond 6C and M10 location samples were evaluated for (non-leaching) semi-volatiles (PAHs), total metals, and total recoverable petroleum hydrocarbons (TRPH) (Dredge Sediment Testing Decision Tree). The results indicated no detections of semi-volatile PAHs and two (2) detections of TRPH, but all were below the Residential Direct Exposure (RDE) and Leachability criteria (Table II, 62-777, FAC) included in the “Dredge Sediment Testing Decision Tree” guidance. Numerous metals were also detected in all the samples including arsenic, barium, copper, lead, nickel, and selenium but all were below groundwater, freshwater, and marine soil leachability criteria. Chromium was found above the freshwater leachability criteria but below the RDE criteria in soil samples from 6C-1 through 6C-4 and M10-1-CS. Speciation of chromium was conducted on 6C-1 through 6C-4 and M10-1-CS samples for further comparison of trivalent and hexavalent chromium concentrations for freshwater leachability criteria. The chromium speciation results for trivalent chromium and hexavalent chromium were compared to the separate freshwater leachability criteria for these chromium species and demonstrated that both chromium

Pinellas County, Florida species were not above freshwater leachability criteria. These results are summarized on Table 2.

• Proposed Pond 6C and M10 location samples were also evaluated for Synthetic Precipitation Leaching Procedure (SPLP) metals (Dredge Sediment Testing Decision Tree). The SPLP testing was conducted on soils below the water table to assess and evaluate leachability of soils left in place following the excavation of the stormwater ponds.

The SPLP results were compared to groundwater and surface water criteria to evaluate the potential impacts from soil leaching (62-777, FAC Soil Cleanup Target Levels [SCTLs] and 62-302.550, FAC Class III criteria). This comparison had several detections of metals cadmium, chromium, copper, lead, nickel, and zinc. Six samples exceeded marine surface water criteria for several metals, and all samples exceeded the freshwater leachability criteria for chromium. These results are summarized on Table 3.

The SPLP method utilizes methods to evaluate leachability that are not typical of site conditions (i.e.; 1) leaching liquid with a pH of 4.2 comprised of nitric and sulfuric acid;

2) grain size reduction by pulverizing for any particles greater than 1 centimeter in diameter; and 3) physical agitation of samples for at least 18 hours at 30 revolutions per minute in an extraction vessel). FDEP and the United States Environmental Protection Agency (EPA) agree that reliance on empirical data is more appropriate for evaluation of leachability rather than leachability testing by the EPA SPLP Method 1312. As stated in the FDEP Technical Report: Development of Cleanup Target Levels for Chapter 62-777, F.A.C.1, “The potential for leaching can be addressed either through comparison with SCTLs or through empirical means, such as leaching tests or evaluation of site history and contamination data for evidence of leaching.” therefore, the SPLP exceedances of chromium above the freshwater surface water cleanup target level are not considered to be representative of potential leaching at the project site. Calcium and magnesium concentrations were used to calculate freshwater surface water cleanup target levels for hardness-based metals (i.e., cadmium, trivalent chromium, copper, lead, nickel, and zinc) using the Florida Department of Environmental Protection Hardness Based Metals Criteria Calculator for Freshwaters. The calculated freshwater surface water cleanup target levels

1 Florida Department of Environmental Protection, 2005. Final Technical Report: Development of Cleanup Target Levels (CTLs) For Chapter 62-777, F.A.C., Page 131, Prepared for the Division of Waste Management Florida Department of Environmental Protection by Center for Environmental & Human Toxicology, University of Florida, Gainesville, Florida. February 2005.

Pinellas County, Florida increased for the SPLP metals and showed that lead did not exceed the freshwater surface water criteria. The calculated hardness based freshwater surface water cleanup target levels are included as Table 4.

SOIL CHARACTERIZATION FOR IN PLACE SOILS LEFT ONSITE

The remaining pond bank soils after proposed pond excavation would be exposed to freshwater surface water. To address concerns whether the remaining soils left in place at the pond locations after excavation may be a concern for leaching, a separate evaluation was undertaken. This included taking additional samples from the approximate water table to the boring termination depth at the aforementioned pond sample locations (6C-1, 6C-2, 6C-3, 6C-4, M10-1, M10-2, and M10-3). Per the decision tree, grain size analysis was performed to determine fines content to then in turn evaluate potential impacts from leaching.

• Soil hydrometer and grain size analysis was performed on 2-foot intervals below the water table for the pond samples (6C-1 through 6C-4 and M10-1 through M10-3) to assess the gradation of the soils. This resulted in a total of 7 additional samples per location. Per the County guidance, if the soils have less than 10% fines, the soils are suitable for any reuse purpose and no further analysis is necessary.

• Analysis from 14 of the 49 soil samples resulted in fines in excess of 10%, therefore in accordance with the decision tree, additional chemical analysis would be warranted to further characterize the soils to evaluate leachability concerns. The grain size results are included as Table 5. A grain size chart that shows the percentage of fines with depth at each boring location is included as Attachment B.

• The laboratory analysis already performed for the previously summarized Pond 6C and M10 indicated that there were no concerns with constituents exceeding freshwater standards. As such, it was determined that additional analytical characterization was unnecessary and the remaining in place soils in the proposed pond areas were considered not to pose a significant risk to freshwater surface water from leaching.

LABORATORY ANALYSIS

Laboratory chemical and grain size analysis were performed by Eurofins/Test America laboratories (Florida NELAP E87052). The laboratory reports with chain of custody are included as Attachment C.

Pinellas County, Florida

CONCLUSIONS

The proposed weir area soil TCLP sample results indicated no exceedances. As such, the soils from weir construction would meet acceptance criteria at the Pinellas County Solid Waste/Bridgeway Acres Facility or another disposal facility as a non-hazardous waste.

The proposed Pond 6C and M10 area soil sample results for PAHs, TRPH, and total metals indicated no RDE or leachability exceedances. The SPLP sample results indicated metal exceedances of the marine and freshwater surface water cleanup target levels. Although SPLP results showed exceedances of the freshwater criteria for chromium, FDEP and the EPA agree that reliance on empirical data is more appropriate for evaluation of leachability rather than leachability testing by the EPA SPLP Method 1312. Therefore, the SPLP exceedances of chromium above the freshwater surface water cleanup target level are not considered to be representative of potential leaching at the project site.

Based on the multiple SPLP exceedances above marine surface water leachability criteria, a conservative approach is recommended for not using the excavated soils where leachate from the soils can reach marine waters. The excavated soils can be reused where leachate from soils may reach freshwater surface waters.

Based on the evaluation of in-situ soil that would remain after proposed Pond 6C and M10 excavation, no significant concerns were noted with respect to future leaching exposure to freshwater surface water in the proposed ponds.

FIGURES

kj kj kj kj kj kj kj

EN

TE

RP

RI

SE

BL

VD

126TH AVE N

M10-2 M10-1

M10-3

6C-2

6C-4 6C-3

6C-1

0 8040 Feet

Legend kj Sample Locations

Parcel !. Control Structure !. Drainage Structure

Culvert Channels

Soil Sampling Map Pond Locations

Starkey M10 SMF Retrofit

Figure

Starkey M10 Canal

M10 POND

POND 6C

kjkj

126TH AVE N

0 5025 Feet

Legend kj Sample Locations

Parcel !. Drainage Structure

Culvert Channels

Soil Sampling Map Weir Locations

Starkey M10 SMF Retrofit

Wetland Mitigation Area

Figure

Starkey M10 Canal

2 - 60" Culverts

Proposed Weir Location

Sample

WEIR-1

Sample

WEIR-2

TABLES

Volatiles by 8260B TCLP

1,1-Dichloroethene mg/l 0.094 U 0.094 U - -

1,2-Dichloroethane mg/l 0.063 U 0.063 U 0.5

2-Butanone (MEK) mg/l 0.45 U 0.45 U - -

Benzene mg/l 0.071 U 0.13 I 0.5

Carbon tetrachloride mg/l 0.094 U 0.094 U 0.5

Chlorobenzene mg/l 0.072 U 0.072 U 100

Chloroform mg/l 0.080 U 0.080 U 6

Tetrachloroethene mg/l 0.076 U 0.076 U 0.7

Trichloroethene mg/l 0.089 U 0.089 U 0.5

Vinyl chloride mg/l 0.071 U 0.071 U 0.2

Semivolatiles by 8270D TCLP

1,4-Dichlorobenzene mg/l 0.016 U 0.016 U 7.5

2,4,5-Trichlorophenol mg/l 0.017 U 0.017 U 400

2,4,6-Trichlorophenol mg/l 0.017 U 0.017 U 2

2,4-Dinitrotoluene mg/l 0.014 U 0.014 U 0.13

2-Methylphenol mg/l 0.013 U 0.013 U - -

3 & 4 Methylphenol mg/l 0.016 U 0.016 U - -

Hexachlorobenzene mg/l 0.013 U 0.013 U 0.13

Hexachlorobutadiene mg/l 0.016 U 0.016 U 0.5

Hexachloroethane mg/l 0.017 U 0.017 U 3

Nitrobenzene mg/l 0.015 U 0.015 U 2

Pentachlorophenol mg/l 0.019 U 0.019 U 100

Pyridine mg/l 0.015 U 0.015 U 5

GC Semivolatiles by 8081B TCLP

Chlordane (technical) mg/l 0.000097 U 0.000097 U 0.03

Endrin mg/l 0.0000014 U 0.0000014 U 0.02 gamma-BHC (Lindane) mg/l 0.0000014 U 0.0000014 U 0.4

Heptachlor mg/l 0.0000020 U 0.0000020 U 0.008

Methoxychlor mg/l 0.0000067 U 0.0000067 U 10

Toxaphene mg/l 0.000075 U 0.000075 U 0.5

GC Semivolatiles by 8151A TCLP

2,4-D mg/l 0.00048 U 0.00048 U 10

Silvex (2,4,5-TP) mg/l 0.00069 U 0.00069 U - -

Metals by 6010D TCLP

Arsenic mg/l 0.0054 I 0.0070 I 5

Barium mg/l 0.10 0.15 100

Cadmium mg/l 0.0027 U 0.0027 U 1

Chromium mg/l 0.0043 U 0.0043 U 5

Lead mg/l 0.0062 I 0.010 I 5

Selenium mg/l 0.0054 U 0.0054 U 1

Silver mg/l 0.0053 U 0.0053 U 5

Metals by 7470A TCLP

Mercury mg/l 0.0020 U 0.0020 U 0.2 Free Liquids by SW846 9095B (Paint Filter Test) Free Liquids NA CFL CNF NA

Notes:

CFL- Contains free liquid.

CNF- Contains no free liquid.

mg/l - milligrams per liter

I - The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit.

U - Indicates that the compound was analyzed for but not detected.

NA- not available/not applicable.

TABLE 1 - SOIL SAMPLE TCLP RESULTS

M10 Starkey SMF Retrofit Design

Pinellas County, Florida

WEIR-2-CS

TCLP MCL (40CFR

261.24) mg/l

WEIR-1-CSParameter Reporting Units

6C-1-CS 6C-2-CS 6C-3-CS 6C-4-CS M10-1-CS M10-2-CS M10-3-CS Residential Commercial / Industrial Groundwater Freshwater Surface Water Marine Surface Water Groundwater of Low

Yield/ Poor Quality

Semivolatiles by 8270E

Acenaphthene mg/kg 0.14 U 0.15 U 0.14 U 0.14 U 0.15 U 0.15 U 0.15 U 2400 20000 2.1 0.3 0.3 21

Acenaphthylene mg/kg 0.14 U 0.15 U 0.15 U 0.14 U 0.15 U 0.16 U 0.15 U 1800 20000 27 NA NA 270

Anthracene mg/kg 0.14 U 0.15 U 0.14 U 0.13 U 0.15 U 0.15 U 0.14 U 21000 300000 2500 0.4 0.4 25000

Benzo[a]anthracene mg/kg 0.14 U 0.15 U 0.15 U 0.14 U 0.15 U 0.16 U 0.15 U # # 0.8 NA NA 8

Benzo[a]pyrene mg/kg 0.089 U 0.096 U 0.093 U 0.089 U 0.096 U 0.10 U 0.095 U 0.1 0.7 8 NA NA 80

Benzo[b]fluoranthene mg/kg 0.12 U 0.13 U 0.12 U 0.12 U 0.13 U 0.13 U 0.13 U # # 2.4 NA NA 24

Benzo[g,h,i]perylene mg/kg 0.14 U 0.15 U 0.14 U 0.14 U 0.15 U 0.15 U 0.15 U 2500 52000 32000 NA NA 320000

Benzo[k]fluoranthene mg/kg 0.14 U 0.15 U 0.15 U 0.14 U 0.15 U 0.16 U 0.15 U # # 24 NA NA 240

Chrysene mg/kg 0.15 U 0.16 U 0.16 U 0.15 U 0.16 U 0.17 U 0.16 U # # 77 NA NA 770

Dibenz(a,h)anthracene mg/kg 0.14 U 0.15 U 0.14 U 0.13 U 0.15 U 0.15 U 0.14 U # # 0.7 NA NA 7

Fluoranthene mg/kg 0.14 U 0.15 U 0.15 U 0.14 U 0.15 U 0.16 U 0.15 U 3200 59000 1200 1.3 1.3 12000

Fluorene mg/kg 0.14 U 0.15 U 0.14 U 0.13 U 0.15 U 0.15 U 0.14 U 2600 33000 160 17 17 1600

Indeno[1,2,3-cd]pyrene mg/kg 0.14 U 0.15 U 0.14 U 0.13 U 0.15 U 0.15 U 0.14 U # # 6.6 NA NA 66

1-Methylnaphthalene mg/kg 0.13 U 0.14 U 0.14 U 0.13 U 0.14 U 0.15 U 0.14 U 200 1800 3.1 10 10 31

2-Methylnaphthalene mg/kg 0.12 U 0.13 U 0.13 U 0.12 U 0.13 U 0.14 U 0.13 U 210 2100 8.5 9.1 9.1 85

Naphthalene mg/kg 0.13 U 0.14 U 0.14 U 0.13 U 0.14 U 0.15 U 0.14 U 55 300 1.2 2.2 2.2 12

Phenanthrene mg/kg 0.14 U 0.15 U 0.14 U 0.14 U 0.15 U 0.16 U 0.15 U 2200 36000 250 NA NA 2500

Pyrene mg/kg 0.14 U 0.16 U 0.15 U 0.14 U 0.16 U 0.16 U 0.15 U 2400 45000 880 1.3 1.3 8800

Caricinogenic PAH TEF mg/kg 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.1 0.7 NA NA NA NA

Metals by 6020B TOTAL

Arsenic mg/kg 0.50 I 1.3 0.67 I 0.64 I 1.9 0.42 I 1.0 I 2.1 12 *** *** *** ***

Barium mg/kg 6.0 7.4 5.1 5.4 7.5 5.6 5.7 120** 130000 1600 NA NA 16000

Cadmium mg/kg 0.63 U 0.68 U 0.68 U 0.65 U 0.72 U 0.72 U 0.67 U 82 1700 7.5 NA 14 75

Total Chromium mg/kg 4.6 6.3 5.4 4.6 11 2.9 3.8 210 470 38 4.2 19 380

Hexavalent Chromium mg/kg 0.66 I J3 0.39 I J3 0.39 I J3 0.36 I J3 0.53 I J3 -- -- 210 470 38 4.2 19 380

Trivalent Chromium mg/kg 3.9 5.9 5.0 4.2 10 -- -- 110000 * NA NA * NA

Copper mg/kg 0.71 I 0.84 I 0.66 I 0.57 I 1.5 0.76 I 0.73 I 150** 89000 *** NA *** ***

Lead mg/kg 1.5 1.4 1.1 I 1.2 1.7 1.7 1.4 400 1400 *** NA *** ***

Nickel mg/kg 0.84 I 1.9 0.95 I 1.1 I 3.6 0.70 I 1.0 I 340** 35000 130 NA 11 1300

Selenium mg/kg 0.42 I 0.43 I 0.36 I 0.22 I 1.1 I 0.29 I 0.40 I 440 11000 5.2 0.5 7.4 52

Silver mg/kg 0.27 U 0.29 U 0.30 U 0.28 U 0.31 U 0.31 U 0.29 U 410 8200 17 0.01 0.06 170

Zinc mg/kg 8.9 U 9.5 U 9.7 U 9.2 U 10 U 10 U 9.5 U 26000 630000 *** NA *** ***

Metals by 7471B TOTAL

Mercury mg/kg 0.024 U 0.026 U 0.023 U 0.023 U 0.026 U 0.027 U 0.025 U 3 17 2.1 0.01 0.03 21

GC Semivolatiles by FL-PRO

Total Petroleum Hydrocarbons (C8-C40) mg/kg 25 U 27 U 26 U 40 I 37 I 28 U 27 U 460 2700 340 340 340 3400

Notes:

not an exceedance based on trivalent and hexavalent chromium speciation results indicating primary form of chromium is trivalent, with hexavalent present below the SCTL.

mg/kg - milligrams per kilogram ug/kg - micrograms per kilogram

-- not analyzed.

PAH- polycyclic aromatic hydrocarbons.

TEF- toxic equivalency factor.

I - The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit.

J3 - Estimated value; value may not be accurate. Spike recovery or relative percent difference outside of criteria.

U - Indicates that the compound was analyzed for but not detected.

Q - Sample held beyond the accepted holding time.

* Contaminant is not a health concern for this exposure scenario

** Direct exposure value based on acute toxicity considerations. This criterion is applicable in scenarios where children might be exposed to soils (e.g. residences, schools, playgrounds)

*** Leachability values may be derived using the SPLP Test to calculate site-specific SCTLs or may be determined using TCLP in the event oily wastes are present.

NA - Not available at time of rule adoption.

# = Site concentrations for carcinogenic polycyclic aromatic hydrocarbons must be converted to Benzo(a)pyrene equivalents before comparison with the appropriate direct exposure SCTL for Benzo(a)pyrene using the approach described in the February 2005 'Final Technical Report: Development of Cleanup Target Levels (CTLs) for Chapter 62-777, F.A.C.

Parameter Reporting Units

Direct Exposure (mg/kg) Leachability (mg/kg)

Soil Cleanup Target Level (SCTLs) per Ch. 62-777, FAC

Soil Sample

TABLE 2 - SOIL SAMPLE TOTAL RESULTS

M10 Starkey SMF Retrofit Design

Pinellas County, Florida

Technical Report: Development of Cleanup Target Levels (CTLs) For Chapter 62-777, F.A.C., FDEP 2005

Groundwater Criteria ug/l

Freshwater Surface Water Criteria ug/l

Marine Surface Water Criteria ug/l

Groundwater of Low Yield / Poor Quality

Criteria ug/l

Predominantly Fresh Waters ug/l

Predominantly Marine Waters ug/l

Metals by 6020B SPLP

Cadmium ug/l 0.39 I 1.0 I 0.35 I 0.35 I 0.46 I 0.27 U 0.27 U 5 (primary) 0.7551 62-302 f,g 9.3 62-302 g 50 0.7551 8.8

Total Chromium ug/l 65 100 61 67 69 36 31 100 (primary) 11 h 50 h 1000 11 50

Copper ug/l 13 13 11 10 15 11 2.5 1000 (secondary) 30.491 62-302 f,g 2.9 62-302 g 10000 30.491 3.7

Lead ug/l 14 18 11 10 11 9.7 5.2 15 (primary) 18.581 62-302 f,g 8.5 62-302 g 150 18.581 8.5

Nickel ug/l 11 25 9.9 11 23 6.7 6.7 100 (primary) 168.541 62-302 f,g 8.3 62-302 g 1000 168.541 8.3

Zinc ug/l 29 33 28 43 21 41 6.1 5000 (secondary) 387.831 62-302 f,g 86 62-302 g 50000 387.831 86

Notes:

mg/l - milligrams per liter ug/l - micrograms per liter Indicates result exceeds Freshwater Surface Water Criteria -- not analyzed. Indicates result exceeds Marine Surface Water Criteria.

I - The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit.

U - Indicates that the compound was analyzed for but not detected.

f = Hardness-dependent per Chapter 62-302, F.A.C.

h = In the absence of concentration data specific for the III and VI valence states of chromium, total chromium concentrations in surface water should be compared to the criteria for Chromium (hexavalent).

NA = Not available at time of Rule adoption.

1= Calculated using Florida Department of Environmental Protection Hardness Based Metals Criteria Calculator for Freshwaters (see Table 4).

TABLE 3 - SOIL SAMPLE SPLP RESULTS

M10 Starkey SMF Retrofit Design

Pinellas County, Florida

* = There are no surface water standards for these individual polycyclic aromatic hydrocarbons. Per Chapter 62-302, F.A.C., the surface water criterion for Polycyclic Aromatic Hydrocarbons (PAHs) shall apply to the total concentration of Acenaphthylene, Benzo(a)anthracene, Benzo(a)pyrene, Benzo(fluoranthene, Benzo(g,i,h)perylene, Benzo(k)fluoranthene, Chrysene, Dibenzo(a,h,)anthracene, Indeno(1,2,3-cd)pyrene, and Phenanthrene.

g = Criteria for these metals are measured as total recoverable metal. However, they may be applied as dissolved metals when, as part of a permit application, a dissolved metals translator has been established according to the procedures described in the document, “Guidance for Establishing a Metals Translator”, Florida Department of Environmental Protection, December 17, 2001.

Soil Leaching Results Compared to Class III and Class III-Limited Criteria Annotated Rule 62-302.530, FAC (proposed revised 4/19)

Soil Leaching Results Compared to Groundwater and Surface Water Cleanup Levels (GSWCTLs)

62-777, FAC

6C-1-CS 6C-2-CS 6C-3-CSParameter Reporting Units 6C-4-CS M10-1-CS M10-2-CS M10-3-CS

Cadmium µg/L

Chromium III µg/L

Copper µg/L

Lead µg/L

Nickel µg/L

Zinc µg/L

6C-1 (6-8) 230 160 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-1 (8-10) 210 140 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-1 (10-12) 250 130 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-1 (12-14) 260 190 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-1 (14-16) 190 140 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-1 (16-18) 270 190 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-1 (18-20) 1600 540 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-2 (6-8) 280 220 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-2 (8-10) 270 170 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-2 (10-12) 200 150 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-2 (12-14) 180 130 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-2 (14-16) 300 190 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-2 (16-18) 1400 280 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-2 (18-20) 47000 610 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-3 (6-8) 44000 140 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-3 (8-10) 710 210 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-3 (10-12) 33000 100 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-3 (12-14) 32000 150 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-3 (14-16) 27000 290 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-3 (16-18) 610 220 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-3 (18-20) 700 340 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-4 (6-8) 44000 200 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-4 (8-10) 20000 260 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-4 (10-12) 37000 160 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-4 (12-14) 2600 340 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-4 (14-16) 35000 580 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-4 (16-18) 9800 540 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 6C-4 (18-20) 21000 490 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 M10-1 (6-8) 570 200 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 M10-1 (8-10) 480 220 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 M10-1 (10-12) 340 190 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 M10-1 (12-14) 310 150 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 M10-1 (14-16) 940 270 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 M10-1 (16-18) 8200 670 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 M10-1 (18-20) 120000 830 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 M10-2 (6-8) 430 180 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 M10-2 (8-10) 500 200 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 M10-2 (10-12) 370 150 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 M10-2 (12-14) 540 150 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 M10-2 (14-16) 780 240 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 M10-2 (16-18) 1000 250 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 M10-2 (18-20) 1900 670 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 M10-3 (6-8) 300 150 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 M10-3 (8-10) 430 220 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 M10-3 (10-12) 330 160 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 M10-3 (12-14) 450 190 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 M10-3 (14-16) 1000 280 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 M10-3 (16-18) 14000 810 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303 M10-3 (18-20) 41000 1100 400.00 0.7558 268.2205 30.4994 18.5809 168.5410 387.8303

Notes:

mg/L- milligrams per liter.

µg/L- micrograms per liter.

FAC- Florida Administrative Code.

TABLE 4 - HARDNESS BASED METALS CRITERIA CALCULATOR FOR FRESHWATERS

M10 Starkey SMF Retrofit Design

Pinellas County, Florida

FAC 62-302(530) Criteria for Class I, Class III and Class III-Limited Freshwaters

Sample ID Calcium mg/L

Magnesium mg/L

Final Total Hardness mg/L

6C-1 (6-8) 6C-1 (8-10) 6C-1 (10-12) 6C-1 (12-14) 6C-1 (14-16) 6C-1 (16-18) 6C-1 (18-20) 6C-2 (6-8) 6C-2 (8-10) 6C-2 (10-12) 6C-2 (12-14) 2/9/24 2/9/24 2/9/24 2/9/24 2/9/24 2/9/24 2/9/24 2/8/24 2/8/24 2/8/24 2/8/24

6-8 8-10 10-12 12-14 14-16 16-18 18-20 6-8 8-10 10-12 12-14

Geotechnical by D422 Clay % 4.7 5 4.4 4.6 4.6 8.5 9.6 4.9 4.3 3.8 3.4

Coarse Sand % 0 0 0 0 0 0 0 0 0 0 0 Fine Sand % 93 94 93 93 94 88 85 93 93 94 95 Gravel % 0 0 0 0 0 0 0 0 0 0 0 Hydrometer Reading 1 - Percent Finer % passing 5.2 5 5.4 4.6 5.1 9 10 4.9 4.8 4.3 3.4 Hydrometer Reading 2 - Percent Finer % passing 5.2 5 4.9 4.6 5.1 9 10 4.9 4.8 4.3 3.4 Hydrometer Reading 3 - Percent Finer % passing 5.2 5 4.9 4.6 5.1 9 10 4.9 4.8 4.3 3.4 Hydrometer Reading 4 - Percent Finer % passing 5.2 5 4.4 4.6 4.6 8.5 9.6 4.9 4.8 4.3 3.4 Hydrometer Reading 5 - Percent Finer % passing 4.7 5 4.4 4.6 4.6 8.5 9.6 4.9 4.3 3.8 3.4 Hydrometer Reading 6 - Percent Finer % passing 4.5 4.8 4.2 4.4 3.9 6.3 8.3 4.7 4.3 3.8 3.4 Hydrometer Reading 7 - Percent Finer % passing 4.6 4.9 3.8 4.5 3.5 5.4 7.3 4.2 3.8 3.8 3.4 Medium Sand % 1.7 1.1 1.5 1.2 1.5 3.7 3.3 1.8 1.7 1.3 1 Sand % 95 95 95 95 95 91 89 94 95 95 96

Sieve Size #10 - Percent Finer % passing 100 100 100 100 100 100 100 100 100 100 100

Sieve Size #100 - Percent Finer % passing 59 71 63 75 71 61 61 61 58 67 75

Sieve Size #20 - Percent Finer % passing 100 100 100 100 100 100 100 100 100 100 100

Sieve Size #200 - Percent Finer % passing 5.4 5.3 5.1 5.4 4.7 8.6 11 5.5 5 4.5 3.8

Sieve Size #4 - Percent Finer % passing 100 100 100 100 100 100 100 100 100 100 100

Sieve Size #40 - Percent Finer % passing 98 99 99 99 99 96 97 98 98 99 99

Sieve Size #60 - Percent Finer % passing 90 95 92 95 93 86 87 91 90 93 94

Sieve Size #80 - Percent Finer % passing 77 86 80 88 84 74 74 80 76 83 87

Sieve Size 0.375 inch - Percent Finer % passing 100 100 100 100 100 100 100 100 100 100 100

Sieve Size 0.75 inch - Percent Finer % passing 100 100 100 100 100 100 100 100 100 100 100

Sieve Size 1 inch - Percent Finer % passing 100 100 100 100 100 100 100 100 100 100 100

Sieve Size 1.5 inch - Percent Finer % passing 100 100 100 100 100 100 100 100 100 100 100

Sieve Size 2 inch - Percent Finer % passing 100 100 100 100 100 100 100 100 100 100 100

Sieve Size 3 inch - Percent Finer % passing 100 100 100 100 100 100 100 100 100 100 100

Silt % 0.73 0.37 0.7 0.82 0.16 0.12 1.9 0.66 0.68 0.74 0.38

Notes:

indicates greater than 10% fines.

% - percentage.

% passing - percent passing.

ft bls- feet below land surface.

TABLE 5 - GRAIN SIZE RESULTS

M10 Starkey SMF Retrofit Design

Pinellas County, Florida

Sample ID Sample Collection Date Sample Interval (ft bls)

Parameter Reporting Units

Geotechnical by D422 Clay %

Coarse Sand % Fine Sand % Gravel % Hydrometer Reading 1 - Percent Finer % passing Hydrometer Reading 2 - Percent Finer % passing Hydrometer Reading 3 - Percent Finer % passing Hydrometer Reading 4 - Percent Finer % passing Hydrometer Reading 5 - Percent Finer % passing Hydrometer Reading 6 - Percent Finer % passing Hydrometer Reading 7 - Percent Finer % passing Medium Sand % Sand %

Sieve Size #10 - Percent Finer % passing

Sieve Size #100 - Percent Finer % passing

Sieve Size #20 - Percent Finer % passing

Sieve Size #200 - Percent Finer % passing

Sieve Size #4 - Percent Finer % passing

Sieve Size #40 - Percent Finer % passing

Sieve Size #60 - Percent Finer % passing

Sieve Size #80 - Percent Finer % passing

Sieve Size 0.375 inch - Percent Finer % passing

Sieve Size 0.75 inch - Percent Finer % passing

Sieve Size 1 inch - Percent Finer % passing

Sieve Size 1.5 inch - Percent Finer % passing

Sieve Size 2 inch - Percent Finer % passing

Sieve Size 3 inch - Percent Finer % passing

Silt %

Notes:

indicates greater than 10% fines.

% - percentage.

% passing - percent passing.

ft bls- feet below land surface.

Sample ID Sample Collection Date Sample Interval (ft bls)

Parameter Reporting Units

6C-2 (14-16) 6C-2 (16-18) 6C-2 (18-20) 6C-3 (6-8) 6C-3 (8-10) 6C-3 (10-12) 6C-3 (12-14) 6C-3 (14-16) 6C-3 (16-18) 6C-3 (18-20) 6C-4 (6-8) 2/8/24 2/8/24 2/8/24 2/9/24 2/9/24 2/9/24 2/9/24 2/9/24 2/9/24 2/9/24 2/9/24 14-16 16-18 18-20 6-8 8-10 10-12 12-14 14-16 16-18 18-20 6-8

7.5 6.4 7.2 4.2 4.3 3.5 4 4.6 5 4.9 3.9 0 0 0 3.3 0.5 6.1 1.9 2.2 0.5 0 8.2

89 91 90 87 94 80 91 89 93 93 66 0 0 0 1.4 0.3 5.4 0.8 1.3 0 0 11

8.1 6.9 7.8 4.2 4.9 3.5 4 5.5 5.5 4.9 3.9

8.1 6.9 7.2 4.2 4.9 3.5 4 5.1 5.5 4.9 3.9

8.1 6.9 7.2 4.2 4.9 3.5 4 5.1 5 4.9 3.9

7.5 6.4 7.2 4.2 4.4 3.5 4 5.1 5 4.9 3.9

7.5 6.4 7.2 4.2 4.4 3.5 4 4.6 5 4.9 3.9

6.4 5.3 6.7 5.2 3.8 3.1 4 4.6 4.5 4.4 3.4

5.3 5.3 6.2 4.8 3.9 2.7 3.5 4.2 4 3.9 3.4 3 2.4 2.8 3.6 1.1 4.4 2.3 2.7 0.7 1.8 5.7

92 93 92 94 95 91 95 94 94 95 80 100 100 100 95 99 89 97 97 100 100 80

55 63 62 60 75 49 62 60 77 72 44

100 100 100 93 99 86 96 95 99 100 77

7.9 6.5 7.5 4.7 4.3 3.7 4.1 5.1 5.6 5.3 8.4

100 100 100 99 100 95 99 99 100 100 89

97 98 97 92 98 84 95 94 99 98 75

88 89 88 86 95 76 89 87 96 92 69

75 77 75 75 88 64 79 75 90 84 59

100 100 100 100 100 100 100 100 100 100 96

100 100 100 100 100 100 100 100 100 100 100

100 100 100 100 100 100 100 100 100 100 100

100 100 100 100 100 100 100 100 100 100 100

100 100 100 100 100 100 100 100 100 100 100

100 100 100 100 100 100 100 100 100 100 100

0.41 0.17 0.32 0.46 -0.01 0.14 0.1 0.5 0.63 0.4 4.5

TABLE 5 - GRAIN SIZE RESULTS

Coarse Sand % Fine Sand % Gravel % Hydrometer Reading 1 - Percent Finer % passing Hydrometer Reading 2 - Percent Finer % passing Hydrometer Reading 3 - Percent Finer % passing Hydrometer Reading 4 - Percent Finer % passing Hydrometer Reading 5 - Percent Finer % passing Hydrometer Reading 6 - Percent Finer % passing Hydrometer Reading 7 - Percent Finer % passing Medium Sand % Sand %

Sieve Size #10 - Percent Finer % passing

Sieve Size #100 - Percent Finer % passing

Sieve Size #20 - Percent Finer % passing

Sieve Size #200 - Percent Finer % passing

Sieve Size #4 - Percent Finer % passing

Sieve Size #40 - Percent Finer % passing

Sieve Size #60 - Percent Finer % passing

Sieve Size #80 - Percent Finer % passing

Sieve Size 0.375 inch - Percent Finer % passing

Sieve Size 0.75 inch - Percent Finer % passing

Sieve Size 1 inch - Percent Finer % passing

Sieve Size 1.5 inch - Percent Finer % passing

Sieve Size 2 inch - Percent Finer % passing

Sieve Size 3 inch - Percent Finer % passing

Silt %

Notes:

indicates greater than 10% fines.

% - percentage.

Sample Interval (ft bls)

Parameter Reporting Units

6C-4 (8-10) 6C-4 (10-12) 6C-4 (12-14) 6C-4 (14-16) 6C-4 (16-18) 6C-4 (18-20) M10-1-CS (6-8) M10-1-CS (8-10) M10-1-CS (10-12) M10-1-CS (12-14) M10-1-CS (14-16) 2/9/24 2/9/24 2/9/24 2/9/24 2/9/24 2/9/24 2/8/24 2/8/24 2/8/24 2/8/24 2/8/24 8-10 10-12 12-14 14-16 16-18 18-20 6-8 8-10 10-12 12-14 14-16

6.3 4 6.2 6.5 5.8 7.8 11 5.2 6.9 6.9 5.3

2.5 7.5 2.2 0.4 2 6.3 0 0 0 0 0 84 70 84 88 87 73 83 85 92 89 85 2 9.5 2.8 0 1.1 2.8 0 0 0 0 0

6.8 4 7.6 7 7.4 8.4 12 6.6 7.5 6.9 6.2

6.3 4 7.6 7 7.4 8.4 12 5.6 7.5 6.9 5.8

6.3 4 6.7 7 7.4 8.4 12 5.6 7.5 6.9 5.8

6.3 4 6.7 7 6.3 8.4 12 5.6 7.5 6.9 5.8

6.3 4 6.2 6.5 5.8 7.9 11 5.2 6.9 6.9 5.3

5.8 4 6.2 6 5.8 6.8 11 5.2 6.4 6.4 5.2

5.3 3.5 5.7 6 5.8 6.3 11 5.2 5.8 5.4 4.7

2.7 6.4 1.8 1 3 5.5 1.7 0.7 1.1 1.9 1.5 89 84 88 89 92 85 85 86 93 91 86 96 83 95 100 97 91 100 100 100 100 100

62 44 67 61 69 55 59 79 70 69 82

94 79 94 99 96 89 100 100 100 99 100

9.1 6.6 9.4 11 7 12 15 14 6.9 9 14

98 91 97 100 99 97 100 100 100 100 100

93 77 93 99 94 85 98 99 99 98 99

88 69 90 94 87 76 90 96 93 93 93

78 59 80 86 79 66 77 90 84 84 93

100 96 98 100 100 100 100 100 100 100 100

100 100 100 100 100 100 100 100 100 100 100

100 100 100 100 100 100 100 100 100 100 100

100 100 100 100 100 100 100 100 100 100 100

100 100 100 100 100 100 100 100 100 100 100

100 100 100 100 100 100 100 100 100 100 100

2.8 2.6 3.2 4.2 1.2 4.6 4 9 -0.03 2.1 8.3

TABLE 5 - GRAIN SIZE RESULTS

Coarse Sand % Fine Sand % Gravel % Hydrometer Reading 1 - Percent Finer % passing Hydrometer Reading 2 - Percent Finer % passing Hydrometer Reading 3 - Percent Finer % passing Hydrometer Reading 4 - Percent Finer % passing Hydrometer Reading 5 - Percent Finer % passing Hydrometer Reading 6 - Percent Finer % passing Hydrometer Reading 7 - Percent Finer % passing Medium Sand % Sand %

Sieve Size #10 - Percent Finer % passing

Sieve Size #100 - Percent Finer % passing

Sieve Size #20 - Percent Finer % passing

Sieve Size #200 - Percent Finer % passing

Sieve Size #4 - Percent Finer % passing

Sieve Size #40 - Percent Finer % passing

Sieve Size #60 - Percent Finer % passing

Sieve Size #80 - Percent Finer % passing

Sieve Size 0.375 inch - Percent Finer % passing

Sieve Size 0.75 inch - Percent Finer % passing

Sieve Size 1 inch - Percent Finer % passing

Sieve Size 1.5 inch - Percent Finer % passing

Sieve Size 2 inch - Percent Finer % passing

Sieve Size 3 inch - Percent Finer % passing

Silt %

Notes:

indicates greater than 10% fines.

% - percentage.

Sample Interval (ft bls)

Parameter Reporting Units

M10-1-CS (16-18) M10-1-CS (18-20) M10-2-CS (6-8) M10-2-CS (8-10) M10-2-CS (10-12) M10-2-CS (12-14) M10-2-CS (14-16) 2/8/24 2/8/24 2/8/24 2/8/24 2/8/24 2/8/24 2/8/24 16-18 18-20 6-8 8-10 10-12 12-14 14-16

7.6 10 5.3 6 5.4 5.4 5.3 0 4.5 0 0 0 0 0

88 68 93 89 93 94 91 0 4.3 0 0 0 0 0

8.1 12 5.3 6 6 5.4 5.3

8.1 12 5.3 6 5.4 5.4 5.3

8.1 11 5.3 6 5.4 5.4 5.3

8.1 11 5.3 6 5.4 5.4 5.3

7.6 10 5.3 6 5.4 5.4 5.3

7.5 9.9 4.7 5.9 4.7 4.7 4.8 7 9.2 4.7 5.4 4.7 4.2 4.8

3.7 4.6 1.7 0.7 0.7 0.3 1.6 92 77 95 90 94 94 93 100 91 100 100 100 100 100

58 57 58 75 77 77 70

100 89 100 100 100 100 100

8.1 19 5.4 10 5.9 5.8 7

100 96 100 100 100 100 100

96 87 98 99 99 100 98

86 80 90 95 97 96 92

73 69 77 88 91 89 83

100 100 100 100 100 100 100

100 100 100 100 100 100 100

100 100 100 100 100 100 100

100 100 100 100 100 100 100

100 100 100 100 100 100 100

100 100 100 100 100 100 100

0.45 8.5 0.12 4.2 0.54 0.41 1.7

TABLE 5 - GRAIN SIZE RESULTS

Coarse Sand % Fine Sand % Gravel % Hydrometer Reading 1 - Percent Finer % passing Hydrometer Reading 2 - Percent Finer % passing Hydrometer Reading 3 - Percent Finer % passing Hydrometer Reading 4 - Percent Finer % passing Hydrometer Reading 5 - Percent Finer % passing Hydrometer Reading 6 - Percent Finer % passing Hydrometer Reading 7 - Percent Finer % passing Medium Sand % Sand %

Sieve Size #10 - Percent Finer % passing

Sieve Size #100 - Percent Finer % passing

Sieve Size #20 - Percent Finer % passing

Sieve Size #200 - Percent Finer % passing

Sieve Size #4 - Percent Finer % passing

Sieve Size #40 - Percent Finer % passing

Sieve Size #60 - Percent Finer % passing

Sieve Size #80 - Percent Finer % passing

Sieve Size 0.375 inch - Percent Finer % passing

Sieve Size 0.75 inch - Percent Finer % passing

Sieve Size 1 inch - Percent Finer % passing

Sieve Size 1.5 inch - Percent Finer % passing

Sieve Size 2 inch - Percent Finer % passing

Sieve Size 3 inch - Percent Finer % passing

Silt %

Notes:

indicates greater than 10% fines.

% - percentage.

Sample Interval (ft bls)

Parameter Reporting Units

M10-2-CS (16-18) M10-2-CS (18-20) M10-3-CS (6-8) M10-3-CS (8-10) M10-3-CS (10-12) M10-3-CS (12-14) M10-3-CS (14-16) M10-3-CS (16-18) M10-3-CS (18-20) 2/8/24 2/8/24 2/8/24 2/8/24 2/8/24 2/8/24 2/8/24 2/8/24 2/8/24 16-18 18-20 6-8 8-10 10-12 12-14 14-16 16-18 18-20

6.8 8.6 5.1 5.3 6 6 6.2 8 9.1 0 0 0 0 0 0 0 0.4 2.9

84 83 93 87 85 83 90 85 78 0 0 0 0 0 0 0 0.2 1.9

7.4 8.6 5.1 6.4 6 6 6.2 8 9.6

6.8 8.6 5.1 6.4 6 6 6.2 8 9.6

6.8 8.6 5.1 6.4 6 6 6.2 8 9.6

6.8 8.6 5.1 6.4 6 6 6.2 8 9.6

6.8 8.6 5.1 5.3 6 6 6.2 8 9.1

6.3 8 4.6 5.3 6 5.5 5.7 6.8 7.9

5.2 7.5 4.1 5.3 5 5 5.1 6.2 6.7

2.5 2.7 1.7 1 1.2 0.6 1.5 2.8 4.3 86 85 94 88 87 84 91 88 85 100 100 100 100 100 100 100 99 95

63 64 50 68 67 81 70 64 59

100 100 100 100 100 100 100 99 94

14 15 5.7 12 14 16 9 12 13

100 100 100 100 100 100 100 100 98

98 97 98 99 99 99 99 97 91

88 88 90 94 93 96 93 88 82

76 76 76 83 84 91 85 76 71

100 100 100 100 100 100 100 100 100

100 100 100 100 100 100 100 100 100

100 100 100 100 100 100 100 100 100

100 100 100 100 100 100 100 100 100

100 100 100 100 100 100 100 100 100

100 100 100 100 100 100 100 100 100

6.9 6.2 0.54 6.7 7.5 10 2.8 4.1 4

M10 Starkey SMF Retrofit Design

TABLE 5 - GRAIN SIZE RESULTS

ATTACHMENT A

Dredge Sediment Testing Decision Tree

Request sediment cores be taken to 2 feet below proposed dredge depth at worst case and representative locations.

Request sediment grain size analysis be done at 6 inch intervals (or 1 foot if no stratification) along the cores.

Evaluate results of grain size analysis for each sample interval: Does sample contain less than 10% fines?

Yes, the sample contains less than 10% fines. No, the sample contains more than 10% fines.

No further analysis is required.

These sediments may be used for any authorized fill project.

Further analysis is needed.

Go to Page 2.

Dredge Sediment Testing Decision Tree

Sediment Sampling and Appropriate Disposal – Decision Trees

Continue to Page 3

Sediments with more than 10% fines require further analysis. Testing guidance documents can be found at: http://www.dep.state.fl.us/labs/library

Always request:

• RCRA metals (Arsenic, Barium, Cadmium, Chromium, Lead, Mercury, Selenium, Silver)

• Zinc, Copper, Nickel

• Polycyclic Aromatic Hydrocarbons (PAH’s)

• Total Recoverable Petroleum Hydrocarbons (TRPH’s)

Note: NEVER substitute oil & grease analysis for PAH analysis.

In freshwater sediments, or if sediments are to be stored next to a freshwater body, also request:

• Surface water hardness in mg/L (Calcium Carbonate hardness equivalent)

• Synthetic Precipitate Leaching Procedure (SPLP) for Cadmium, Chromium, Copper, Lead, Nickel, and Zinc http://www.dep.state.fl.us/labs/library

Check results against the Soil Cleanup Target Level (SCTL) table (excerpt from Table II, 62- 777, F.A.C. – attached). Note any exceedances for Residential Direct Exposure (RDE) Criteria, Commercial Direct Exposure (CDE) Criteria, leachability to groundwater, leachability to freshwater surface water, and leachability to marine surface water.

If one or more of the carcinogenic PAH’s is detected in the sample at a concentration equal to or higher than the Method Detection Limit (MDL), use the Benzo(a)pyrene BaP) Toxicity Equivalence Conversion spreadsheet to determine if there are any exceedances of the BAP Equivalent SCTL.

Are the sediments from a freshwater body or will dredged sediments be stored adjacent to a freshwater body?

Yes No

Run hardness based calculations using the excel spreadsheet. Check hardness based freshwater standard results against the values provided by the SPLP results.

Note any exceedances.

Proceed to Page 4 for disposal options.

Does any result exceed Residential Direct Exposure (RDE) limits or default leachability criteria listed in Table II of 62-777, F.A.C.?

Yes No

The dredged and dewatered sediments may be used for any authorized fill project or sold as fill if appropriate (muck or mucky sediment is generally not an appropriate fill material) or may be stored in uplands.

Only leachability exceedances.

There are RDE limit exceedances.

What are the exceedances? (RDE or Leachability) PAH’s must be added together and compared to 62-302.530(56)(a), F.A.C.

Sediments must be disposed of at an appropriate disposal facility (Class I, lined landfill).

Applicant should call disposal facilities to determine what their maximum contaminant levels are. Facility usually requires copies of lab results.

Groundwater, marine surface water, or fresh surface water leachability exceedances?

(Could exceed more than one)

Groundwater Marine surface water Fresh surface water

May not be permanently placed where leachate would affect groundwater. May require Class I Disposal.

May not be permanently placed where runoff can reach marine waters (i.e., uplands adjacent to marine surface waters)

May not be permanently placed where runoff can reach fresh waters (i.e., uplands adjacent to fresh surface waters)

Excerpt from Table II, 62-377, F.A.C.

Residential

Commercial/ Industrial

(mg/kg) (mg/kg) (mg/kg) (mg/kg) (mg/kg) (mg/kg) Arsenic NOCAS 2.1 12 *** *** *** *** -Carcinogen -Cardiovascular -Skin Barium (soluble salts) (b)

7440-39-3

120** 130000 1600 NA NA 16000

-Cardiovascular

Cadmium (b,c,h)

7440-43-9

82 1700 7.5 NA 14 75

-Carcinogen -Kidney

Chromium (total) (b,g)

NOCAS

210 470 38 4.2 19 380

-Carcinogen

Copper 7440-50-8 150** 89000 *** NA *** *** -Gastrointestinal Lead (d)

7439-92-1

400 1400 *** NA *** ***

-Neurological

Mercury (c)

7439-97-6 3 17 2.1 0.01 0.03 21

-Neurological

Nickel (b,c)

7440-02-0 340** 35000 130 NA 11 1300 -Body Weight

Selenium (b,c)

7782-49-2 440 11000 5.2 0.5 7.4 52

-Hair Loss -Neurological -Skin

Silver (b)

7440-22-4 410 8200 17 0.01 0.06 170

-Skin

TRPH NOCAS 460 2700 340 340 340 3400 -Multiple Endpoints Mixed Contaminants Zinc (b,c)

7440-66-6

26000 630000 *** NA *** ***

-Blood

Leachability Based on

Groundwater of Low Yield/ Poor Quality

Target Organs/Systems or Effects†

Contaminants CAS#s

Direct Exposure Leachability Based on

Groundwater Criteria

Leachability Based on

Freshwater Surface Water

Criteria

Leachability Based on Marine Surface Water

Criteria

** Direct exposure value based on acute toxicity considerations.

*** Leachability values may be derived using the SPLP Test to calculate site-specific SCTLs or may be determined using TCLP in the event oily wastes are present.

(b) = Leachability values derived from USEPA Soil Screening Guidance (1996). These values were derived assuming soil pH 6.8.

These leachability values are dependent upon both the metal concentration in soil and soil characteristics. Thus, if site-specific soil characteristics are different than the defaults, these leachability values may not apply. If this is the case, site-specific leachability values should be derived using methods such as TCLP or SPLP.

(c) = Phytotoxicity must be considered.

(d) = Residential direct exposure value from USEPA Revised Interm Soil Guidance for CERCLA Sites and RCRA Corrective Action Facilities. OSWER Directive 9355.4-12 (1994). The industrial direct exposure value was derived using methodologies outlined in USEPA 'Recommendations of the Technical Review Workgroup for Lead for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil', December 1996; and in 'Blood Lead Concentrations of U.S. Adult Females: Summary Statistics from Phases 1 and 2 of the NHANES III', March 2002.

(g) = Unless concentrations for both chromium III and VI are known, total chromium concentrations should by compared with direct exposure SCTLs for chromium VI.

(h) = Residential chronic SCTL for cadmium should be used as a not-to-exceed value because the residential chronic SCTL for cadmium is indistinguishable from the SCTL based on acute toxicity.

62-302.530(56)(a), F.A.C.

Parameter Units Class I Class II Class III:

Fresh

Class III:

Marine

Class IV Class V

(56) (a) Polycyclic Aro-matic Hydrocar-bons (PAHs).

Total of: Ace-naphthylene;

Ben-zo(a)anthracene;

Benzo(a)pyrene;

Benzo(b)fluoran-thene; Benzo- (ghi)perylene;

Benzo(k)fluorant hene; Chrysene;

Dibenzo- (a,h)anthracene;

Indeno(1,2,3-cd)pyrene; and Phenanthrene

Micrograms/L < 0.0028 annual avg.

< 0.031 annual avg.

< 0.031annual avg.

< 0.031 annual avg.

ATTACHMENT B

Grain Size Chart

8 10 12 14 16 18 20

Fi ne s P as si ng

Si ev e

Depth (feet below land surface)

ATTACHMENT B

Fine Percentages Profile with Depth (All Borings)

M10-3 M10-2 M10-1 6C-1 6C-2 6C-3 6C-4 > 10% Fines

ATTACHMENT C

Laboratory Reports

ANALYTICAL REPORT

PREPARED FOR

Attn: Ryan Tuttle

Geosyntec Consultants Inc 19321 U.S. Highway 19 North

Building C, Suite 200 Clearwater, Florida 33764

Generated 2/27/2024 10:14:07 AM Revision 2

JOB DESCRIPTION

M10 Starkey, Pinellas County

JOB NUMBER

670-34556-1

See page two for job notes and contact information.

Altamonte Springs FL 32701 481 Newburyport Avenue Eurofins Orlando https://eol.et.eurofinsus.com/myEOL/

Eurofins Orlando

Eurofins Orlando is a laboratory within Eurofins Environment Testing Southeast, LLC, a company within Eurofins Environment Testing Group of Companies

Job Notes This report may not be reproduced except in full, and with written approval from the laboratory. The results relate only to the samples tested. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page.

The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written approval of the laboratory. All questions should be directed to the Eurofins Environment Testing Southeast, LLC Project Manager.

Authorization

Generated

2/27/2024 10:14:07 AM

Revision 2

Authorized for release by Jess Hornsby, Client Services Manager Jess.Hornsby@et.eurofinsus.com (321)280-2054

Page 2 of 345 2/27/2024 (Rev. 2)

Table of Contents

Client: Geosyntec Consultants Inc Project/Site: M10 Starkey, Pinellas County

Laboratory Job ID: 670-34556-1

Eurofins Orlando

2/27/2024 (Rev. 2)

Cover Page

Table of Contents

Sample Summary

Detection Summary

Case Narrative

Definitions/Glossary

Client Sample Results

QC Sample Results

QC Association Summary

Lab Chronicle

Method Summary

Certification Summary

Chain of Custody

Receipt Checklists

Sample Summary Client: Geosyntec Consultants Inc Job ID: 670-34556-1 Project/Site: M10 Starkey, Pinellas County

Lab Sample ID Client Sample ID Matrix Collected Received

670-34556-1 6C-1-CS Solid 02/09/24 13:15 02/10/24 07:00

670-34556-2 6C-2-CS Solid 02/08/24 17:30 02/10/24 07:00

670-34556-3 6C-3-CS Solid 02/09/24 11:45 02/10/24 07:00

670-34556-4 6C-4-CS Solid 02/09/24 10:00 02/10/24 07:00

670-34556-5 M10-1-CS Solid 02/08/24 13:00 02/10/24 07:00

670-34556-6 M10-2-CS Solid 02/08/24 11:00 02/10/24 07:00

670-34556-7 M10-3-CS Solid 02/08/24 15:05 02/10/24 07:00

670-34556-9 6C-1 (6-8) Solid 02/09/24 12:30 02/10/24 07:00

670-34556-10 6C-1 (8-10) Solid 02/09/24 12:35 02/10/24 07:00

670-34556-11 6C-1 (10-12) Solid 02/09/24 12:40 02/10/24 07:00

670-34556-12 6C-1 (12-14) Solid 02/09/24 12:45 02/10/24 07:00

670-34556-13 6C-1 (14-16) Solid 02/09/24 12:50 02/10/24 07:00

670-34556-14 6C-1 (16-18) Solid 02/09/24 12:55 02/10/24 07:00

670-34556-15 6C-1 (18-20) Solid 02/09/24 13:00 02/10/24 07:00

670-34556-17 6C-2 (6-8) Solid 02/08/24 16:15 02/10/24 07:00

670-34556-18 6C-2 (8-10) Solid 02/08/24 16:20 02/10/24 07:00

670-34556-19 6C-2 (10-12) Solid 02/08/24 16:25 02/10/24 07:00

670-34556-20 6C-2 (12-14) Solid 02/08/24 16:30 02/10/24 07:00

670-34556-21 6C-2 (14-16) Solid 02/08/24 16:35 02/10/24 07:00

670-34556-22 6C-2 (16-18) Solid 02/08/24 16:40 02/10/24 07:00

670-34556-23 6C-2 (18-20) Solid 02/08/24 16:45 02/10/24 07:00

670-34556-25 6C-3 (6-8) Solid 02/09/24 10:40 02/10/24 07:00

670-34556-26 6C-3 (8-10) Solid 02/09/24 10:45 02/10/24 07:00

670-34556-27 6C-3 (10-12) Solid 02/09/24 10:50 02/10/24 07:00

670-34556-28 6C-3 (12-14) Solid 02/09/24 10:55 02/10/24 07:00

670-34556-29 6C-3 (14-16) Solid 02/09/24 11:00 02/10/24 07:00

670-34556-30 6C-3 (16-18) Solid 02/09/24 11:05 02/10/24 07:00

670-34556-31 6C-3 (18-20) Solid 02/09/24 11:10 02/10/24 07:00

670-34556-33 6C-4 (6-8) Solid 02/09/24 08:45 02/10/24 07:00

670-34556-34 6C-4 (8-10) Solid 02/09/24 08:50 02/10/24 07:00

670-34556-35 6C-4 (10-12) Solid 02/09/24 08:55 02/10/24 07:00

670-34556-36 6C-4 (12-14) Solid 02/09/24 09:00 02/10/24 07:00

670-34556-37 6C-4 (14-16) Solid 02/09/24 09:05 02/10/24 07:00

670-34556-38 6C-4 (16-18) Solid 02/09/24 09:10 02/10/24 07:00

670-34556-39 6C-4 (18-20) Solid 02/09/24 09:15 02/10/24 07:00

670-34556-41 M10-1-CS (6-8) Solid 02/08/24 12:00 02/10/24 07:00

670-34556-42 M10-1-CS (8-10) Solid 02/08/24 12:05 02/10/24 07:00

670-34556-43 M10-1-CS (10-12) Solid 02/08/24 12:10 02/10/24 07:00

670-34556-44 M10-1-CS (12-14) Solid 02/08/24 12:15 02/10/24 07:00

670-34556-45 M10-1-CS (14-16) Solid 02/08/24 12:20 02/10/24 07:00

670-34556-46 M10-1-CS (16-18) Solid 02/08/24 12:25 02/10/24 07:00

670-34556-47 M10-1-CS (18-20) Solid 02/08/24 12:30…

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File details come from the government source that posted it. Updated .