Water Enhancer 2.pdf

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Attached to
Chemical Testing Federal contract opportunity
Solicitation number
12318723Q0458
Issued by
Department of Agriculture Forest Service

About this file

This material safety data sheet describes the chemical product Blazetamer380. The product is a polyacrylamide copolymer emulsion containing surfactants and performance additives. It is classified as non-hazardous and functions as a Class fire suppression and retarding liquid when diluted with water from 1:150 to 1:1500. The product has a mild odor and is a white milky liquid with a pH of 6.4. It presents minimal risks to human health upon short-term exposure and low risks to the environment when used appropriately for firefighting. The related federal contract opportunity seeks a contractor to perform chemical testing on fire suppression products such as Blazetamer380 for the Department of Agriculture Forest Service. The solicitation number is 12318723Q0458 and the opportunity type is a solicitation.

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Text version

BLAZETAMER380

Version No. 1.5 2011/04/21 Page 1 of 6

Material Safety Data Sheet

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING

Infosafe No. CV44J US/eng/C

Issued Date 2011/04/21

Supplier Telephone Numbers

BIOCENTRAL LABORATORIES LTD

22 Phillips Street Thebarton SA 5031 Australia

Emergency Tel.

+61 415 824 608 or +61 458 047 431

Telephone/Fax Number

Tel: +61 8 8234 8886 Fax: +61 8 8234 8889

Product Use A Class fire suppression and retarding liquid. The use of the product involves significant dilution with water (1:150 to 1:1500).

2. COMPOSITION/INFORMATION ON INGREDIENTS

The product is a polyacrylamide copolymer emulsion, containing surfactants and performance additives.

Name CAS Proportion

Ingredients determined not to be hazardous, including water. 100%

3. HAZARDS IDENTIFICATION

Hazard Classification

This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Chronic Effects Prolonged or repeated exposure to this material may result in irritation to the skin, and aggravate existing respiratory disorders.

Inhalation Inhalation of vapours or mists may cause irritation to the mucous membranes and upper airways.

Ingestion May cause irritation to the mouth, oesophagus and stomach. Symptoms may include nausea and vomiting.

Skin May cause mild irritation in contact with the skin, which can result in redness, itchiness and possible dermatitis.

Eye May cause transient eye irritation resulting in redness, swelling, stinging and lacrimation.

Environmental Hazards Based on component data the product is not expected to be harmful to the environment.

Other Information

MAY CAUSE MILD EYE IRRITATION. MAY CAUSE SLIGHT SKIN IRRITATION.

HMIS rating: Health – 1, Flammability – 0, Reactivity – 0

Version No. 1.5 2011/04/21 Page 2 of 6

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh area. Keep at rest until recovered. If symptoms persist seek medical attention.

Ingestion Do NOT induce vomiting. Wash out mouth and lips thoroughly with water. Seek medical attention.

Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. If symptoms develop seek medical attention.

Eye If in eyes, hold eyelids apart and flush the eyes continuously with running water. Continue flushing for several minutes until all contaminants are washed off completely. Seek medical attention.

First Aid Facilities Normal washroom facilities.

Advice to Doctor Treat symptomatically.

5. FIRE FIGHTING MEASURES

Fire Fighting Measures This product quickly extinguishes the fire. Greatly reduces re-ignition.

Flash Point Not applicable, water-based emulsion.

Flammable Limits UEL Not applicable

Flammable Limits LEL Not applicable

Flammability Non-combustible liquid.

Hazardous Combustion Products Under fire conditions this product may emit toxic and/or irritating fumes including oxides of carbon and oxides of sulphur.

Precautions in connection with Fire Water spray may be used to cool down heat-exposed containers.

Protective Equipment Fire fighters should wear full protective clothing and self-contained breathing apparatus if required.

Other Information NFPA Rating.

6. ACCIDENTAL RELEASE MEASURES

Wear appropriate personal protective equipment and clothing to prevent exposure. If possible contain the spill.

Version No. 1.5 2011/04/21 Page 3 of 6

Place absorbent material onto spillage. Collect the material and place into suitable labelled containers for subsequent recycling or disposal. Dispose of waste according to the applicable local and national regulations. If contamination of sewers or waterways occurs inform the local water authorities and EPA in accordance with local regulations.

Personal Precautions Spills produce extremely slippery surfaces on non porous surfaces only.

7. HANDLING AND STORAGE

Handling Wear appropriate protective equipment to prevent inhalation and eye exposure. Keep containers closed when not in use. Practice good personal hygiene, that is, always wash hands after handling, and before eating, drinking, smoking or using the toilet facilities.

Storage Non combustible liquid. Store in a cool, dry well-ventilated area away from heat and out of direct sunlight. Keep containers closed when not in use and securely sealed and protected against physical damage. Inspect regularly for deficiencies such as damage or leaks.

8. EXPOSURE CONTROLS, PERSONAL PROTECTION

Biological Limit Values No biological limit allocated.

Exposure Limits No exposure standards have been established for this material.

Respiratory Protection In case of insufficient ventilation, suitable respiratory equipment should be worn.

Eye Protection Where eye contamination is likely the use of chemical goggles, safety glasses with side shield protection or face shield as appropriate should be worn.

Hand Protection Suitable impervious gloves, e.g. neoprene, nitrile or laminated film are recommended.

Footwear Safety boots as required.

Body Protection Suitable impervious protective clothing should be worn when handling large quantities.

Eng. Controls Use with good general ventilation.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance White milky liquid.

Odour Mild odour.

Melting Point 32°F approx.

Boiling Point >212°F

Solubility in Water Miscible with water.

Specific Gravity (H2O=1) 0.998 pH Value 6.4 (as supplied)

Vapour Pressure Not available

Vapour Density (Air=1) Not available

Flash Point Not applicable, water-based emulsion.

Flammability Non-combustible liquid.

Version No. 1.5 2011/04/21 Page 4 of 6

Flammable Limits - Lower Not applicable

Flammable Limits - Upper Not applicable

10. STABILITY AND REACTIVITY

Hazardous Polymerization Will not occur.

Hazardous Decomposition Products Decomposition may lead to the release of toxic and/or irritating fumes including carbon monoxide and sodium oxide and oxides of sulphur.

11. TOXICOLOGICAL INFORMATION

Toxicology Information Acute Oral Toxicity:

LD50 >5050 mg/kg

Acute Dermal Toxicity:

LD50 >2020 mg/kg

Primary Eye Irritation - Nonwashed Eyes:

For the Concentrate: Mildly irritating. Toxicity category IV. Irritation score: 5.3 For the Mixed Fire Chemical: Practically non-irritating. Toxicity category IV. Irritation score: 0.7

Primary Eye Irritation - Washed Eyes:

For the Concentrate: Minimally irritating. Toxicity category IV. Irritation score: 5.3 For the Mixed Fire Chemical: Practically non-irritating. Toxicity category IV. Irritation score: 1.3

Primary Dermal Irritation:

For the Concentrate: Slight irritant. Toxicity category III For the Mixed Fire Chemical: Slight irritant. Toxicity category IV

Inhalation Inhalation of vapours or mists may cause irritation to the mucous membranes and upper airways.

Ingestion May cause irritation to the mouth, oesophagus and stomach. Symptoms may include nausea and vomiting.

Skin May cause mild irritation in contact with the skin, which can result in redness, itchiness and possible dermatitis.

Eye May cause transient eye irritation resulting in redness, swelling, stinging and lacrimation.

Chronic Effects Prolonged or repeated exposure to this material may result in irritation to the skin, and aggravate existing respiratory disorders.

12. ECOLOGICAL INFORMATION

Environ. Protection This product is an A Class fire suppression and retarding liquid. The use of the product involves significant dilution with water (1:150 to 1:1500).

This product represents a low risk to the environment if it is used appropriately in a fire fighting scenario.

Mobility Not available

Persistence / Degradability Non-degraded anionic polyacrylamide has been shown to be recalcitrant to microbial degradation. This is

Version No. 1.5 2011/04/21 Page 5 of 6 probably related to the extremely high molecular weight which renders microbial attack very difficult. However, once the polymer has been degraded through photolysis (i.e., the action of UV light), and the macromolecule broken down into oligomers, it becomes bioavailable and is biomineralized.

Bioaccumulation Anionic polyacrylamide has no potential to bioaccumulate, being completely soluble in water (only limited by viscosity) and insoluble in octanol.

Acute Toxicity - Fish LC50 (Bracbydanio rerio) 96 hours: 178 - 357 mg/L Test F242:OECD 203/GLP/report 21/12/1995

Acute Toxicity - Daphnia EC50 (Daphnia magna) 48hr: 212 mg/L Test F243:OECD 202/GLP/report 21/12/1995

Acute Toxicity - Algae EC50A (I)/Chlorella vulgaris/ 96 hours: > 1,000 mg/L EC50µ (I)/Chlorella vulgaris/ 96 hours: > 1,000 mg/L No Observed Effect Concentration (NOEC): 708 mg/L Test F244:OECD 201/GLP/report 21/12/1995

Acute Toxicity - Bacteria EC10/Pseudomonas putida/18 hours: 127 mg/L EC50/Pseudomonas putida/18 hours: 892 mg/L Test F245:OECD 301F,DIN 38412-27,ISO 7027/GLP/report 21/12/1995

Ecotoxicity Anionic polyacrylamide has no systemic toxicity to aquatic organisms or micro-organisms.

13. DISPOSAL CONSIDERATIONS

Dispose of waste, according to federal, EPA and state regulations. Assure conformity with all applicable regulations.

14. TRANSPORT INFORMATION

Not dangerous for transport under DOT, IMO, and IATA/ICAO codes.

DOT Packing Group None allocated

IMDG Hazard Class None Allocated

DOT Class None allocated

IMDG Pack. Group None Allocated

IATA Hazard Class None Allocated

IATA Packing Group None Allocated

DOT

This product is not regulated for transportation.

DOT Packing Group None Allocated

Version No. 1.5 2011/04/21 Page 6 of 6

15. REGULATORY INFORMATION

TSCA (USA) Not established.

16. OTHER INFORMATION

SDS History SDS amendment: August 2013

1. Identification of the substance/mixture and of the company/undertaking

2. Composition/information on ingredients

3. Hazards identification

6. Accidental release measures

9. Physical and chemical properties

11. Toxicological Information

12. Ecological information

16. Other information

SDS amendment: January 2013

12. Ecological information

MSDS Reviewed: April 2011 Supersedes: December 2008

Technical Contact Point BioCentral Laboratories Limited 22 Phillips Street, Thebarton, South Australia, 5031.

Phone Business Hours: +61 8 8234 8886 Facsimile: +61 8 8234 8889 Emergency Phone all Hours 24/7: +61 415 824 608 or +61 458 047 431

... End Of MSDS ...

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