Water Enhancer 1.pdf

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Chemical Testing Federal contract opportunity
Solicitation number
12318723Q0458
Issued by
Department of Agriculture Forest Service

About this file

This document file contains multiple material safety data sheets (MSDS) and one federal contract opportunity notice. The MSDS documents provide product information for various fire retardants and surface treatments, including product identifiers, composition, health and safety hazards, handling procedures, and disposal recommendations. The federal contract opportunity is for chemical testing services with the Department of Agriculture Forest Service. It does not specify pricing terms, response dates, or other salient details.

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MATERIAL SAFETY DATA SHEET

IDENTITY (AS USED ON LABEL AND LIST):

BARRICADE II FIRE BLOCKING GEL

SECTION I- MANUFACTURER’S INFORMATION

BARRICADE INTERNATIONAL, INC.

12848 S.E. SUZANNE DRIVE

HOBE SOUND, FLORIDA 33455

EMERGENCY TELEPHONE NUMBER

(800) 201-3927

TELEPHONE NUMBER FOR INFORMATION

(772) 546-5364

DATE PREPARED

JANUARY 7, 2004

SECTION II- HAZARDS IDENTIFICATION

THE PRODUCT RENDERS SURFACES EXTREMELY SLIPPERY, PARTICULARLY WHEN WETTED

SECTION III- PHYSICAL/CHEMICAL CHARACTERISTICS

BOILING POINT: N/A

VAPOR PRESSURE (mm Hg.): N/A VAPOR DENSITY (Air =1): N/A

SOLUBILITY IN WATER: DISPERSABLE

SPECIFIC GRAVITY (H20=1): 1.13

MELTING POINT: NIL

EVAPORATION RATE (BUTYL ACETATE=1): NIL

APPEARANCE AND ODOR: OFF-WHITE DISPERSION WITH A BLAND ODOR

SECTION IV- FIRE AND EXPLOSION HAZARD DATA

NFPA RATINGS- HEALTH-1; FLAMMABILITY-1; REACTIVITY-0

FLASH POINT (METHOD USED)- >500 DEGREES F (COC)

FLAMMABLE LIMITS- N/A

LEL- N/A

UEL- N/A

EXTINGUISHING MEDIA- DRY CHEMICAL, FOAM, WATER OR WATER SPRAY

SPECIAL FIRE FIGHTING PROCEDURES- NONE

UNUSUAL FIRE AND EXPLOSION HAZARDS- NONE

SECTION V- REACTIVITY DATA

STABILITY- N/A

UNSTABLE- N/A

CONDITIONS TO AVOID- N/A

STABLE- YES

INCOMPATIBILITY (MATERIALS TO AVOID)- OXIDIZING AGENTS

HAZARDOUS DECOMPOSITION OR BYPRODUCTS- PRODUCT WILL NOT DECOMPOSE DURING STORAGE.

THERMAL DECOMPOSITION MAY PRODUCE NITROGEN OXIDES (NOx), HYDROCYANIC ACID, CARBON

OXIDES.

SECTION V1- HEALTH HAZARD DATA

HMIS RATINGS- HEALTH-1, FIRE-1, REACTIVITY-0

ROUTE(S) OF ENTRY- INHALATION ?-YES, SKIN ?-YES, INGESTION ?- YES

HEALTH HAZARDS (ACUTE AND CHRONIC)

INGESTION: PRODUCT WILL SWELL

INHALATION: NO SHORT TERM INHALATION LIMITS

SKIN/EYE: FLUSH AND RINSE, PARTICULARLY FOR EYE CONTACT. USE MILD DETERGENT FOR SKIN AND

NON-IRRITATING DETERGENT FOR EYES. NO SIGNIFICANT SKIN REACTION EXPECTED

CARCINOGENICITY: NO

NTP?: NO

IARC MONOGRAPHS?: NO

OSHA REGULATED?: NO

SIGNS AND SYMPTOMS OF EXPOSURE: N/A

MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: N/A

EMERGENCY AND FIRST AID PROCEDURES: EYES- FLUSH WITH WATER FOR AT LEAST FIFTEEN MINUTES

USING A NON-IRRITATING DETERGENT

SECTION VII- PRECAUTIONS FOR SAFE HANDLING AND USE

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED- CONTAIN SPILLS AND PICK UP- USE

SAND OR ABSORBENT MATERIALS; AVOID LOSSES TO WATERWAYS

WASTE DISPOSAL METHOD- REVIEW LOCAL REGULATIONS BEFORE CLEANED UP MATERIALS ARE

INTRODUCED INTO SEWER SYSTEMS OR WASTE TREATMENT SYSTEMS.

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING- AVOID EXCESSIVE HEAT IN STORAGE TO

MAINTAIN PRODUCT QUALITY

OTHER PRECAUTIONS- SOILED RAGS OR ABSORBENT MATERIALS SHOULD NOT BE KEPT UNDER HIGH

TEMPERATURE, CLOSED CONDITIONS IN THE PRESENCE OF OXYGEN

SECTION VIII- CONTROL MEASURES

RESPIRATORY PROTECTION (SPECIFY TYPE)- NONE

VENTILATION- N/A

LOCAL EXHAUST- NOT REQUIRED

SPECIAL- N/A

MECHANICAL (GENERAL)- N/A

OTHER- N/A

PROTECTIVE GLOVES- YES

EYE PROTECTION- WEAR SPLASH GOGGLES WHEN HANDLING THE CONCENTRATE

OTHER PROTECTIVE CLOTHING OR EQUIPMENT- WEAR IMPERVIOUS GLOVES AND LONG SLEEVES WHEN HANDLING CONCENTRATE. WASH THOROUGHLY WITH CLEAN WATER TO REMOVE FROM SKIN. USE A

GOOD QUALITY, WATER RESISTANT HAND CREAM TO PREVENT DRYING OF THE SKIN.

WORK/HYGENIC PRACTICES- USE GOOD CHEMICAL HANDLING PRACTICES

SECTION IX- DISPOSAL CONSIDERATIONS

WASTE FROM RESIDUES / UNUSED PRODUCTS: IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL

REGULATIONS

CONTAMINATED PACKAGING : RINSE EMPTY CONTAINERS WITH WATER .CAN BE LANDFILLED OR

INCINERATED, WHEN IN COMPLIANCE WITH LOCAL REGULATIONS

SECTION X- TRANSPORT INFORMATION

NOT REGULATED BY DOT

SECTION XI- REGULATORY INFORMATION

ALL COMPONENTS OF THIS PRODUCT ARE ON THE TSCA AND DSL INVENTORIES.

RCRA STATUS- NOT A HAZARDOUS WASTE

HAZARDOUS WASTE NUMBER- NOT APPLICABLE

REPORTABLE QUANTITY (40 CFR 302)- NOT APPLICABLE

THRESHOLD PLANNING QUANTITY (40 CFR 335)- NOT APPLICABLE

SECTION XII- OTHER INFORMATION

PERSON TO CONTACT: REGULATORY AFFAIRS MANAGER

THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION. THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING, USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE, AND IS NOT TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY PROCESS UNLESS

SPECIFIED IN THE TEXT.

MATERIAL SAFETY DATA SHEET

PRODUCT NAME: THERMO-GEL500P Page 1 of 2

SECTION I Emergency telephone number:

(800) 424-9300

Manufacturer’s Name and Address Telephone Number for Information:

Thermo Technologies, LLC. 701-258-8208 400 East Broadway Ave.

Bismarck, ND 58501 Date Prepared: NA = Not Applicable 5/1/02 NE = Not Established NH = Non-Hazardous

SECTION II – Hazardous Ingrdients/Identity Information Hazardous Components (Specific Chemical Identity: Common Names(s) ) Other Limits %

OSHA PEL ACGTH TLV Recommended (optional)

Sodium Polyacrylate, Crosslinked NE NE 0.05mg/m3 CAS No. 09003-04-7

Thermo Technologies recommended inhalation exposure limit guideline. Small, less than 10 microns respirable polyacrylate. See also Section VI of MSDS

SARA Section 313 Reportable Toxic Chemicals – None %

SECTION III – Physical/Chemical Charcteristics

Boiling Point Solid NE Specific Gravity (H2O=1) Bulk Density 0.4-0.7 Vapor Pressure (mm Hg) Less than 10 Melting Point Greater than 390°F Vapor Density (AIR = 1) Nil NE Evaporation Rate Less than 1 (Butyl Acetate = 1)

Solubility in Water Insoluble Appearance and Odor White granular powder, no odor

SECTION IV – Fire and E xplosion Hazard Data Flash Point (Method Used) None Flammable Limits LEL: NE UEL-- NE

Extinguishing Media Water, CO2 and dry chemical extinguishants

Special Fire Fighting Procedures None

Unusual Fire and Explosion Hazards Extremely slippery conditions are created if spilled product comes in contact with water.

SECTION V - Reactivity Data

Stability Unstable - Conditions to Avoid: None Known

Stable

Incompatibility (Materials to Avoid): None known

Hazardous Decomposition or By-products: None known

Hazardous May Occur Conditions to Avoid: None Known Polymerization X Will Not Occur

PRODUCT NAME: THERMO-GEL® 500P Page 2 of 2

SECTION VI – Health Hazard Data

Route(s) of Entry: Inhalation? Yes Skin? No Ingestion? No

Health Hazards Acute (short term) inhalation of dust may cause mild irritation of upper respiratory tract

(Acute and Chronic) (nose and throat) and lungs.

Chronic (long term) inhalation exposure to rats for a lifetime (two years) using a sodium polyacrylate that had been micronized to a respirable particle size (less than 10 microns) produced non-specific inflammation and chronic lung injury at 0.2mg/m3 and 0.8mg/m3..

At 0.8mg/m3, tumors were seen in some animals. In the absence of chronic inflammation tumors are not expected. There were no adverse effects of any kind at 005mg/m3.

Sodiuum polyacrylate had no effect in mutagenicity tests.

Carcinogenicity: NTP: No IARC: No OSHA: No

Signs and Symptoms of Exposure Possible reddening,drying of skin or eyes with itching, burning or other discomfort;

irritation of nose and throat

Medical Conditions Generally May aggravate existing respiratory conditions; skin conditions (due to drying effect) Aggravated by Exposure

Emergency and First Aid Procedures Flush eyes thoroughly with water. If inhaled, move to source of fresh air. Call a physician regarding any continued discomfort.

SECTION VII - Precautions for Safe Handling and Use

Steps in Case of Release/Spill: Collect material. Avoid contact with water as extremely slippery conditions will result.

Residuals are to be flushed thoroughly with water to the drain for normal wastewater treatment

Waste Disposal Method: Dispose of in accordance with Local, State and Federal regulations. Non-hazardous waste material suitable for approved solid waste landfill.

Precautions to Taken in Handling and Storing: Handle as eye irritant. Do not get into eyes. Avoid prolonged or repeated skin contact.

Do not inhale dust. Do not ingest.

Other Precautions: Dusty conditions may irritate the eyes and respiratory system. Wear goggles and mask with high efficiency filter where dust is created.

SECTION VIII - Control Measures

Respiratory Protection Wear respirator or mask with high efficiency filter for particulate levels above

0.05mg/m3.

Ventilation Local Exhaust Ensure airborne particles are removed. Special: Not required

Mechanical Recommended Other Ventilation: Not required

Protective Gloves Recommended Eye Protection: Safety glasses or goggles

Other Protective handling None Work/Hygienic Wash thoroughly after handling

Clothing or Equipment Practices

M.S.D.S Material Safety Data Sheet

Release Date: August 2007 Revised Date: August 2011

Product Name: FireIce®

Section VI Health Hazard Data

Route(s) of Entry ............................................Inhalation? Yes Skin? Yes Ingestion? Yes

Acute contact with the eyes is minimally irritating as concentrate and non-irritating as a mixed fire chemical. Acute contact with the skin is non-irritating as concentrate and slightly irritating as a mixed fire chemical.

Care must be taken to minimize exposure and prevent workplace inhalation of concentrated respirable dust. Personal Protective Equipment (PPE) is recommended for eye and inhalation exposure when handling this product. (A similar product, ground very finely, produced an inflammatory tissue response in the lungs in a lifetime exposure inhalation in laboratory testing).

According to the United States Forest Service Specification 5100-306A, this product meets the Specification and is considered to be non-toxic to mammals.

Acute Oral Toxicity: LD50 >505 mg/Kg (Concentrate), LD50>5050 mg/Kg (Mixed Fire Chemical)

Acute Dermal Toxicity: LD50 > 2020 mg/Kg (Concentrate), LD50>2020 mg/Kg (Mixed Fire Chemical)

Primary Dermal Irritation: Concentrate is non-irritating (Score: 0.0, Toxicity Category IV), Mixed Fire Chemical is slightly irritating (Score: 0.3, Toxicity Category IV)

Primary Eye Irritation: Concentrate is minimally irritating (Score: 2.0, Toxicity Category IV), Mixed Fire Chemical is non-irritating (Score: 0.0, Toxicity Category IV)

Above testing results as reported by the United States Forest Service and is a summary of Mammalian Toxicity Testing of FireIce® Water Enhancer. FireIce® is compliant with the United States Forest Service Specification 5100-306A and all results are acceptable to the USFS.

Fish Toxicity test results in accordance with USDA Forest Service Specification 5100-306A are as follows and all results are acceptable to the USFS: OPPTS 850.1075 on rainbow trout (approximately 60-days post hatch) in ASTM soft water.

Requirement 96-hr LC50 must be ≥10 mg/L.

Result: FireIce® Fire Chemical is LC50 = 348 mg/L

1460 Park Lane South, Suite 1 Jupiter, Florida 33458

561.427.6144 | Fax: 561.427.6182

Product Name: FireIce®

Section VII Precautions For Safe Handling And Use

Steps to be taken in case material is released or spilled: Vacuum (using HEPA filter equipped system) if possible to avoid generating airborne dust. Avoid adding water, the product will become slippery when wet.

Waste Disposal Method: Dispose of in accordance with federal, state and local regulations.

Precautions to be taken in Handling and Storing: Store in a cool, dry place. Avoid breathing powder. Avoid skin and eye contact.

Other Precautions: Slippery when wet.

Section VIII Control Measures

Respiratory Protection (specific type) ............Use NIOSH/MSHA approved or equivalent with high efficiency filter for particulate levels above 0.05mg/m³

Ventilation ......................................................Local Exhaust ....................As appropriate to control airborne dust levels below the applicable exposure limits

Mechanical (general)..........As appropriate Other ................................None

Protective Gloves............................................Impervious/rubber (only necessary during mixing process) Eye Protection ................................................Safety goggles (only necessary during mixing process) Other Protective Clothing ..............................None Work/Hygienic Practices ................................Use good housekeeping practices

The information has been compiled from sources believed to be reliable and is accurate to the best of our knowledge.

However, GelTech Solutions® cannot give guarantees regarding information from other sources, and expressly do not make any warranties, nor assume any liability for its use.

1460 Park Lane South, Suite 1 Jupiter, Florida 33458

561.427.6144 | Fax: 561.427.6182

Page 1/6

Safety Data Sheet acc. to US OSHA GHS

Printing date 04/13/2015 Reviewed on 04/13/2015

40.1.3

1 Identification . Product identifier

. Trade name: Phos-Chek Insul-8 Article number: AST10196

. Article number: AST10196

. Relevant identified uses of the substance or mixtur e and uses advised against No further relevant information available.

. Application of the substance / the mixture Fire retarding agent Surface active agent Wetting & dispersing agents

. Manufacturer/Supplier:

ICL PERFORMANCE PRODUCTS LP

622 Emerson Road - Suite 500 St. Louis, Missouri 63141

. Information department: General information: 1 800 244 6169 (Worldwide)

. Emergency telephone number:

In USA call CHEMTREC: 1 800 424 9300 Outside the USA, including ships at sea, call CHEMTREC’s international and maritime telephone number (collect calls accepted):

+1 (703) 527-3887 In Canada call CANUTEC: 1 613 996 6666

* 2 Hazard(s) identification . Classification of the substance or mixture STOT SE 3 H336 May cause drowsiness or dizziness.

. GHS label elements The product is classified and labelled according to the US Globally Harmonized System (GHS).

. Hazard pictograms

GHS07

. Signal word Warning

. Hazard-determining components of labeling:

Distillates (petroleum), hydrotreated light

. Hazard statements H336 May cause drowsiness or dizziness.

. Precautionary statements P261 Avoid breathing mist/vapours/spray.

P271 Use only outdoors or in a well-ventilated area.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P312 Call a poison center/doctor if you feel unwell.

P405 Store locked up.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P501 Dispose of contents/container in accordance with local/regional/national/international regulations.

(Contd. on page 2)

USA

Page 2/6 acc. to US OSHA GHS

Printing date 04/13/2015 Reviewed on 04/13/2015

Trade name: Phos-Chek Insul-8 Article number: AST10196

(Contd. of page 1)

40.1.3

. Classification system:

. NFPA ratings (scale 0 - 4)

Health = 0 Fire = 0 Reactivity = 0

. HMIS-ratings (scale 0 - 4)

HEALTH

FIRE

REACTIVITY

Health = 0 Fire = 0 Reactivity = 0

3 Composition/information on ingredients . Chemical characterization: Mixtures . Description: Mixture of the substances listed below with nonhazardous additions.

. Dangerous components:

64742-47-8 Distillates (petroleum), hydrotreated light 25 - <50%

4 First-aid measures . Description of first aid measures . General information: Immediately remove any clothing soiled by the product.

. After inhalation: Supply fresh air; consult doctor in case of complaints.

. After skin contact:

Wash with water and acidic soap.

If skin irritation continues, consult a doctor.

. After eye contact:

Rinse opened eye for 15 minutes under running water. Then consult a doctor.

Seek immediate medical advice.

. After swallowing: If symptoms persist consult doctor.

. Most important symptoms and effects, both acute and delayed No further relevant information available.

. Indication of any immediate medical attention and s pecial treatment needed No further relevant information available.

5 Fire-fighting measures . Extinguishing media . Suitable extinguishing agents:

CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

. Special hazards arising from the substance or mixtu re In case of fire, the following can be released:

Carbon monoxide (CO)

. Advice for firefighters

. Protective equipment: Wear self-contained respiratory protective device.

6 Accidental release measures . Personal precautions, protective equipment and emer gency procedures Wear protective clothing.

Use respiratory protective device against the effects of fumes/dust/aerosol.

(Contd. on page 3)

Page 3/6 acc. to US OSHA GHS

Printing date 04/13/2015 Reviewed on 04/13/2015

Trade name: Phos-Chek Insul-8 Article number: AST10196

(Contd. of page 2)

40.1.3

. Environmental precautions: Do not allow to enter sewers/ surface or ground water.

. Methods and material for containment and cleaning u p:

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).

Send for recovery or disposal in suitable receptacles.

. Reference to other sections See Section 7 for information on safe handling.

See Section 8 for information on personal protection equipment.

7 Handling and storage

. Handling:

. Precautions for safe handling No special precautions are necessary if used correctly.

Keep receptacles tightly sealed.

Store in cool, dry place in tightly closed receptacles.

Prevent formation of aerosols.

Use only in well ventilated areas.

. Information about protection against explosions and fires: No special measures required.

. Conditions for safe storage, including any incompat ibilities

. Storage:

. Further information about storage conditions: Keep receptacle tightly sealed.

. Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection

. Control parameters

. Components with limit values that require monitorin g at the workplace:

. Additional information: The lists that were valid during the creation were used as basis.

. Exposure controls

. Appropriate engineering controls Not determined

. Personal protective equipment:

. General protective and hygienic measures:

The usual precautionary measures for handling chemicals should be followed.

Wash hands before breaks and at the end of work.

Avoid contact with the eyes and skin.

Do not inhale gases / fumes / aerosols.

. Respiratory Protection:

Not necessary if room is well-ventilated.

Use suitable respiratory protective device only when aerosol or mist is formed.

In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air.

Short term filter device:

Filter A/P2

. Protection of hands: Protective gloves

. Material of gloves Butyl rubber, BR Fluorocarbon rubber (Viton) Nitrile rubber, NBR Natural rubber, NR Chloroprene rubber, CR Neoprene gloves

(Contd. on page 4)

Page 4/6 acc. to US OSHA GHS

Printing date 04/13/2015 Reviewed on 04/13/2015

Trade name: Phos-Chek Insul-8 Article number: AST10196

(Contd. of page 3)

40.1.3

. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.

. Not suitable are gloves made of the following mater ials: Leather gloves

. Eye protection: Safety glasses

* 9 Physical and chemical properties . Information on basic physical and chemical properti es . General Information . Appearance:

Form: Fluid Color: Yellow-brown

. Odor: Aromatic

. Odour threshold: Not determined

. pH-value: Not determined

. Change in condition Melting point/Melting range: Not determined Boiling point/Boiling range: Not determined

. Flash point: > 177 ° F (COC)

. Flammability (solid, gaseous): Not determined

. Auto-ignition temperature: Not determined

. Decomposition temperature: Not determined

. Danger of explosion: Not determined

. Explosion limits:

Lower: Not determined

. Oxidizing properties Not determined

. Vapor pressure: Not determined

. Density at 40 °C (104 °F): 0.988 g/cm³ (8.245 lbs/gal)

. Evaporation rate Not determined

. Solubility in / Miscibility with Water: Insoluble.

. Partition coefficient (n-octanol/water): Not determined

. Viscosity:

Dynamic at 40 °C (104 °F): 950 cps Kinematic at 40 °C (104 °F): 961 mm2/s

. Other information No further relevant information available.

10 Stability and reactivity . Reactivity No hazardous reactions when stored and handled according to instructions.

. Chemical stability . Thermal decomposition / conditions to be avoided: No decomposition if used and stored according to specifications.

. Possibility of hazardous reactions No dangerous reactions known.

. Conditions to avoid No further relevant information available.

. Incompatible materials: No further relevant information available.

(Contd. on page 5)

Page 5/6 acc. to US OSHA GHS

Printing date 04/13/2015 Reviewed on 04/13/2015

Trade name: Phos-Chek Insul-8 Article number: AST10196

(Contd. of page 4)

40.1.3

. Hazardous decomposition products: Carbon monoxide and carbon dioxide

11 Toxicological information . Information on toxicological effects . Acute toxicity:

. LD/LC50 values that are relevant for classification :

Oral LD50 > 5050 mg/kg (rat) Dermal LD50 > 2020 mg/kg (rabbit)

. Primary irritant effect:

. on the skin: Moderate irritation

. on the eye: Moderate irritation

. Additional toxicological information:

. Carcinogenic categories . IARC (International Agency for Research on Cancer) None of the ingredients is listed.

. NTP (National Toxicology Program) None of the ingredients is listed.

. OSHA-Ca (Occupational Safety & Health Administratio n) None of the ingredients is listed.

12 Ecological information . Toxicity

. Aquatic toxicity:

LC50 (96 h) 1051 mg/L (rainbow trout)

. Persistence and degradability Not easily biodegradable

. Other information: modified Sturm test (OECD 301B, 42 d): 56%

. Behavior in environmental systems:

. Bioaccumulative potential No further relevant information available.

. Mobility in soil No further relevant information available.

. Other adverse effects No further relevant information available.

13 Disposal considerations . Waste treatment methods . Recommendation:

Must not be disposed of together with household garbage. Do not allow product to reach sewage system.

Must be specially treated adhering to official regulations.

. Uncleaned packagings:

. Recommendation:

Empty contaminated packagings thoroughly. They can be recycled after thorough and proper cleaning.

Packagings that cannot be cleansed are to be disposed of in the same manner as the product.

Dispose of packaging according to regulations on the disposal of packagings.

. Recommended cleansing agent: Water, if necessary with cleansing agents.

* 14 Transport information . UN-Number . DOT, ADN, IMDG, IATA Void

(Contd. on page 6)

Page 6/6 acc. to US OSHA GHS

Printing date 04/13/2015 Reviewed on 04/13/2015

Trade name: Phos-Chek Insul-8 Article number: AST10196

(Contd. of page 5)

40.1.3

. UN proper shipping name

. DOT, ADR, ADN, IMDG, IATA Void

. Transport hazard class(es)

. DOT, ADR, ADN, IMDG, IATA

. Class Void

. Packing group

. DOT, ADR, IMDG, IATA Void

. Environmental hazards: Not applicable.

. Special precautions for user Not applicable.

. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable.

. Transport/Additional information: Not dangerous according to the above specifications.

. UN "Model Regulation": -

15 Regulatory information . Safety, health and environmental regulations/legisl ation specific for the substance or mixture . Sara . Section 355 (extremely hazardous substances): Not applicable . Section 313 (Specific toxic chemical listings): Not applicable . TSCA (Toxic Substances Control Act): All ingredients are listed.

. Proposition 65 . Chemicals known to cause cancer:

This product contains a component (< 1.0 %) that may contain residual (<100 ppm) concentrations of propylene oxide

(CAS 75-56-9).

. National regulations:

. Information about limitation of use: Employment restrictions concerning young persons must be observed.

16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.

. Department issuing SDS: ESH & S

. Contact: SDS@ICL-PPLP.com

. Date of preparation / last revision 04/13/2015 / 1

. Abbreviations and acronyms:

ICAO: International Civil Aviation Organisation ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3

. Sources source ECHA: European Chemicals Agency, http://echa.europa.eu/

. * Data compared to the previous version altered.

Thermo Technologies, L.L.C. U.S. Department of Labor Material Safety Data Sheet Occupational Safety and Health Administration May be used to comply with OSHA’s Hazard (Non-Mandatory Form) Communication Standard, 29 CFR 1910.1200. Form Approved Standards must be consulted for specific requirements. OMB No. 1218-0072

Identity (As used on Label and List) Note: Blank Spaces are not permitted. If any item is not Thermo-Gel® 200L (red pail/red label) applicable, or no information is available, the space must be marked to indicate that.

Emergency Telephone Number:

Section I (800) 424-9300 Distributor’s Name and Address Telephone Number for Information:

(701) 258-8208 Thermo Technologies, L.L.C. Date prepared: NA = Not Applicable 400 East Broadway Suite 50 05/09/07 NE = Not Established Bismarck, ND 58501 Signature of Preparer (optional) NH = Non-Hazardous

Section II – Hazardous Ingredients/Identity Information Serial Number 0485-1 Hazardous Components (Specific Other Limits Chemical Identity; Common Name (s)) OSHA PEL ACGHI TLV Recommended % (Optional) NE NE Irritant (eye) Polyacrylate Polymer Proprietary Blend

Petroleum hydrocarbon 5 mg/m3* 5 mg/m3* *(Oil mist in air) Proprietary Blend

Surfactant NE NE Irritant (eye, skin) Proprietary Blend

The final components of this product are listed in the US TSCA Chemical Substance Inventory. This product is not transport regulated.

SARA Section 313 Reportable Toxic Chemicals – NONE%

Section III – Physical/Chemical Characteristic

Boiling Point Initial 96°C Specific gravity (H2O=1) Approx. 1.05 Vapor Pressure (mm Hg.) Not established NE Melting Point Not established NE Vapor Density (Air=1) Not established NE Evaporation Rate Not established NE (Butyl Acetate =1)

Solubility in Water Emulsifies in water with some soluble components present.

Appearance and Odor White opaque liquid with mild odor of hydrocarbon.

Section IV – Fire and Explosion Hazard Data

Flash Point (Method Used) Greater than 100°C (components summary) Flammable Limit LEL NE UEL NE

Extinguishing Media Water fog, CO2, dry chemical extinguishments.

Special Fire Fighting Procedures Use water fog. Avoid water jet/stream. Use self-contained breathing apparatus and protective gear for any hostile fire. Spilled product creates slippery conditions.

Unusual Fire and Explosion Hazards Petroleum hydrocarbon component, although formulated to prevent separation, if separated can burn. Its flash point is in the range of 265°F (method: Cleveland Open Cup).

Reproduced Locally Page 1 SZMR1094

Thermo-Gel® 200L (red pail/red label) 05/09/07 Serial No. 0485-1

Section V – Reactivity Data

Stability Unstable Conditions to Avoid None known.

X Stable

Incompatibility (Material to Avoid) Strong oxidizers, strong acids.

Hazardous Decomposition or Byproducts On thermal decomposition, oxides of carbon and nitrogen.

Hazardous May Occur Conditions to Avoid None known.

Polymerization X Will not Occur

Section VI – Health Hazard Data

Routes of Entry Inhalation: Yes Skin: Yes Ingestion: No

Health Hazards Components may cause skin and eye irritation. Irritation of the mucous membranes (Acute and Chronic) may result from inhalation of vapors/mist forms. Proper handling procedures, including skin and eye protection are advised.

Carcinogenicity NTP: No IARC: No OSHA: No

Signs and Symptoms of Exposure Reddening, swelling of the affected area with burning, itching or other discomfort.

Medical Conditions Generally Not confirmed. Existing cuts, rashes, allergies and other sensitive areas.

Aggravated by Exposure Respiratory disorder may be aggravated.

Emergency and First Aid Procedures Eyes: flush thoroughly with water. Skin: wash with soap and water.

Inhalation: move to fresh air. Ingestion: If ill effects occur, get medical attention.

For any continued discomfort/discoloration get professional medical attention.

Section VII – Precautions for Safe Handling and Use

Steps in Case of Contain. Wear protective gear. Collect, using suitable absorbent if needed. Flush residuals to the drain Released/Spill for normal biological wastewater treatment. Put collected material into suitable containers for proper disposal. Exercise caution in spill area as spilled material creates very slippery conditions.

Waste Disposal Incinerate according to applicable regulations. Diluted liquid form may be flushed with water to Method normal wastewater treatment in accordance with Local, State/Provincial and Federal regulations.

Precautions to be Components may cause skin and eye irritation. Proper handling procedures, including Taken in Handling/ skin and eye protection are advised. Avoid inhalation of vapors/mist forms. Do not ingest.

Storage

Other Precautions Exercise caution with spilled product as very slippery conditions, especially in contact with water, are created. Prevent release of concentrate to waterways.

Section VIII – Control Measures

Respiratory Protection Not required for normal product end use. Observe any Section II MSDS exposure limits.

Ventilation Local Exhaust Ensure vapors/mist forms are removed. Special Not required.

Mechanical Recommended Other Ventilation Not required.

Protective Gloves Impervious neoprene or rubber. Eye Protection Safety goggles.

Other Protective Apron, shoes, or other to prevent Work/Hygienic Wash thoroughly after handling.

Clothing or Equipment skin contact. Practices

SAFETY DATA SHEET

Class-A Fire Suppressant & Water Enhancer Concentrate SDS DATE: January 30, 2018 Version; 4.0

TetraKO™ XL-P Class-A Fire Suppressant & Water Enhancer

Version #: 4.0 Revision date: January 30, 2018

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

1.1 Product Identifiers

-Product Name: TetraKO™ XL-P Concentrate for Class-A Fire Suppressant & Water Enhancer for Wildland Fire Management

-Includes: TetraKO XL-P 2.5; TetraKO XL-P 5; TetraKO XL-P 100; TetraKO XL-P 250;

TetraKO XL-P 500; TetraKO XL-P 3.5k, TetraKO XL-P 17k

-CAS No.: Mixture -EC No.:

-REACH Reg No.:

1.2 Relevant identified uses of the substance or mixture and uses advised against -Relevant identified uses: Concentrate for Class-A Fire Suppressant & Water Enhance for Wildland Fire Management.

-Uses advised against:

1.3 Details of the supplier of the Safety Data Sheet

-Company: EarthClean LLC -Address: 2829 Univesity Ave SE, Suite 650 Minneapolis MN, 55414 -Telephone: 844-838-7256 -Fax 651-600-3592 -E-mail address: CustomerService@EarthClean.com

1.4 Emergency telephone number

-Emergency telephone number: 1-800-535-5053

SECTION 2: HAZARDS IDENTIFICATION

2.1. GHS Classification - No OSHA GHS Classification required under US 29CFR1910.1200 is required.

2.1.1. European regulation (EC) 1272/2008, as amended

Not Classified as Hazardous according to the European regulation (EC) 1272/2008, as amended

2.2. EC Label - According to Regulation (EC) 1272/2008, as amended

2.2.1 Name(s) on Label: None

Hazardous components: None

2.2.2. Signal word: None

2.2.3. Hazard symbols: None

2.2.4. Hazard statements: None

2.2.5. Precautionary statements

Prevention: None Response: None

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.1. Substances: Mixture

3.2. Mixtures

Description: Mixture of dry water-thickening agents

Chemical Name CAS No. Wgt% LD50 of Component No Hazardous Materials per OSHA 29CFR1910.1200

SECTION 4: FIRST AID MEASURES

4.1. Description of first-aid measures

4.1.1. If inhaled

- Inhalation is not expected due to the particle size.

- In the unusual event of inhalation, move the person to fresh air and treat as a dust exposure.

4.1.2. In case of eye contact

- Direct exposure to undiluted concentrate is minimally irritating. Wash eyes with plain water if irritation occurs.

4.1.3. In case of skin contact

- Skin contact with concentrate and mixed solutions with water are non-toxic.

- TetraKO concentrate and mixed solutions with water can be rinsed off the skin and clothing with plain water

4.1.4. If swallowed

- TetraKO concentrate and mixed solutions with water are non-toxic and will pass through the digestive tract.

- Do not induce vomiting.

4.2. Most important symptoms/effects, acute and delayed

- None expected.

4.2.1. Inhalation

- Symptoms: In the event of inhalation, coughing as with dust exposure may occurr.

4.2.2. Skin contact

- Symptoms: Repeated or prolonged exposure to the concentrate and mixtures with water could cause dry skin.

SDS DATE: January 30, 2018

4.2.3. Eye contact

- Symptoms: Minimally irritating.

4.2.4. Ingestion

- Symptoms: None expected.

SECTION 5: FIRE-FIGHTING MEASURES

5.1. Extinguishing media

5.1.1. Suitable extinguishing media

- Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

5.1.2. Unsuitable extinguishing media

- None

5.2. Specific hazards arising from the chemical

- Not flammable.

- Not combustible.

5.3. Special protective actions for fire-fighters

- Typical firefighting protective equipment associated with Class A fires

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. Advice for non-emergency personnel

- Prevent accidental releases, if safe to do so.

6.1.2. Advice for emergency responders

- Wear suitable protective clothing. Cleans up with plain water.

6.2. Environmental precautions

- Concentrate and water mixtures are non-toxic and biodegradable. Practice good stewarship to prevent accidental releases into the environment.

- In the event of accidental releases inform respective authorities.

6.3. Methods and materials for containment and cleaning up

- Sweep up and shovel into suitable containers for disposal.

- Keep in properly labeled containers.

- Keep in suitable, closed containers for disposal. See SECTION 7: HANDLING AND STORAGE

- Treat recovered material as described in the section "Disposal considerations".

6.4. Reference to other sections

- Refer to protective measures listed in sections 7 and 8.

SECTION 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

- Use only equipment and materials which are compatible with the product.

- Follow general hygiene considerations recognized as common good workplace practices.

7.2. Conditions for storage, including incompatibilities

7.2.1. Storage

- Store in original container.

- Keep in a dry place.

- Keep in properly labeled containers. Keep container closed when not in use.

7.2.2. Packaging material

7.2.2.1. Suitable material

- Plastics

- Polyethylene, Polyvinyl Chloride (PVC), Resin-Treated Fiberglass, High-Density Polyethylene (HDPE), Low-Density Polyethylene (LDPE), Flexible Polyolefin

- Metals

- Paper

7.2.2.2. Unsuitable material

- None identified.

7.3. Specific use(s)

- Please contact the supplier.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

8.1.1. Exposure Limit Values

Nuisance Dust

- UK. EH40 Workplace Exposure Limits (WELs) 2007 10mg/m3 (total inhalable) 4mg/m3 (respirable)

- US. ACGIH Threshold Limit Values 2009 10mg/m3 (total particles) 3mg/m3 (respirable particles)

SDS DATE: January 30, 2018

8.1.2. Other information on limit values

8.1.2.1. Derived No Effect Level / Derived minimal effect level

- None available

8.2. Exposure controls.

8.2.1. Appropriate engineering controls

- Ensure adequate ventilation.

- Apply technical measures to comply with the occupational exposure limits.

8.2.2. Individual protection measures

8.2.2.1. Respiratory protection

- In the case of dust formation use respirator with an approved filter.

- Recommended Filter type: Dust elimination type

8.2.2.2. Hand protection

- Follow general hygiene considerations recognized as common good workplace practices and wash hands with water.

- Unsuitable material: Leather

8.2.2.3. Eye protection

- Goggles may be worn to prevent entry into the eyes in the event of dust formation.

8.2.2.4. Skin and body protection

- Follow general hygiene considerations recognized as good workplace practices.

8.2.2.5. Hygiene measures

- Eye wash bottles or eye wash stations in compliance with applicable standards.

- Wash contaminated clothing before reuse.

- Handle in accordance with good industrial hygiene and safety practice.

8.2.3. Environmental exposure controls

- Dispose of rinse water in accordance with local and national regulations.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Physical and chemical properties

9.1.1. General Information

- Appearance: Powder/Solid

- Color White

- Odor Odorless

- Molecular Weight Mixture

9.1.2. Important health safety and environmental information

- pH(1% sol) 6.5-7.5

- pKa No data

- Melting point/freezing point Decomposes

- Boiling point/boiling range Decomposes

- Flash point Not flammable

- Evaporation rate 0 mg/m2/hr - Solid

- Flammability Not flammable

- Explosive properties Not explosive, See section 10.

- Vapor pressure None – Solid

- Vapor density None – Solid

- Relative density 0.62 g/cc, at 20 °C

- Bulk density 0.62 g/cc, at 20 °C

- Solubility Soluable in water

- Solubility/qualitative No Data

- Partition coefficient No Data

- n-octanol/water No Data

- Auto ignition temperature No Data

- Decomposition temperature Estimated to be 400°C / 752°F

- Viscosity Not applicable, solid

- Explosive Properties No Data

- Oxidizing properties Non-oxidizer

9.2. Other information

- Granulometry Up to 1,000 micron, mean diameter

SECTION 10: STABILITY AND REACTIVITY

10.1. Reactivity

-None known.

10.2. Chemical Stability

-Stable at normal conditions.

10.3. Possibility of hazardous reactions

- None identified.

10.4. Conditions to avoid

- None identified.

10.5. Materials to avoid

- None identified.

SDS DATE: January 30, 2018

10.6. Hazardous decomposition products

-None identified.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1. Acute toxicity

11.1.1. Acute oral toxicity

- Oral Rat LD50 >5050 mg/kg (liquid) ((OCSPP 870.1100)

- Oral Rat LD50 >1200 mg/kg (solid; solubility limit; no mortality) (OCSPP 870.1100)

11.1.2. Acute inhalation toxicity

- No data available

11.1.3. Acute dermal toxicity

- (Greater than) >2020-mg/Kg (rabbit) )(OCSPP 870.1200)

11.2. Skin corrosion/irritation

- Non-irritating (rabbit)(OCSPP 870.2500)

11.3. Serious eye damage/eye irritation

- Minimally irritating (rabbit)(irritation score 7.3-12.0)(OCSPP 870.2400)

11.4. Respiratory or skin sensitization

- No data available.

11.5. Mutagenicity

- None identified.

11.6. Carcinogenicity

- None identified.

11.7. Toxicity for reproduction

- None identified.

11.8. Specific target organ toxicity - single exposure

- Inhalation: None identified.

- Oral: None identified.

- Dermal: None identified.

11.9. Specific target organ toxicity - repeated exposure

- None identified.

SECTION 12: ECOLOGICAL INFORMATION

12.1. Toxicity

- Toxicity to Fish - Rainbow Trout LC50 = 123 mg/L of concentrate. As typically used in gel form, it is non-toxic

- Toxicity to daphnia and - No data available aquatic invertebrates

- Toxicity to algae - No data available

12.2. Persistence and degradability -No data available

12.2.1. Abiotic degradation

- Air: No data available

- Water: No data available

- Soil: No data available

12.3 Bio-accumulative potential

- Given the biodegradability of the component substances, bioaccumulative potential is not anticipated

12.4. Mobility

- No data available

12.5. PBT and vPvB assessment

- Not considered a PBT based on low toxicity and biodegradability of the component substances

12.6. Other adverse effects

- No data available

SECTION 13: DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

- Dilute with water.

- Dispose of in accordance with local and national regulations. US users must receive local sewage treatment plant permission for discharge prior to release.

13.2. Contaminated packaging

- Where possible recycling is preferred to disposal or incineration.

- Clean container with water and mild detergent or normal saline (< 1 %) to thin the gel in water.

- Dispose of in accordance with local and national regulations.

SECTION 14: TRANSPORT INFORMATION

14.1. International transport regulations

-UN Number - Not regulated for transport -IATA DGR - Not regulated for transport -IMDG - Not regulated for transport

SDS DATE: January 30, 2018

-ADR - Not regulated for transport -RID - Not regulated for transport -AND - Not regulated for transport

14.2 UN proper shipping name: Not Applicable

14.3 Transport hazard class(es): Not Applicable

14.4 Packing group: Not Applicable

14.5 Environmental hazards: Not Applicable

14.6 Special precautions for user: Not Applicable

14.7 Transport in bulk accordance with Annex II of MARPOL 73/78 and the IBC Code: Not regulated for transport

SECTION 15: REGULATORY INFORMATION

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) of Canada and the MSDS contains all of the information required by the CPR.

--Global Chemical Inventories—

USA All components of this material are on the US TSCA Inventory or are exempt.

Other TSCA Reg. None known.

EU All components are in compliance with the EC Seventh Amendment Directive 92/33EEC or are exempt.

Japan All components are in compliance with the Chemical Substances Control Law of Japan.

Australia All components are in compliance with the chemical notification requirements in Australia.

Canada All components are in compliance with the Canadian Environmental Protection Act and are present on the Domestic Substances

List(s).

Korea All components are in compliance in Korea

--Other U.S. Fedral Regulations—

SARA Ext. Haz. Subst. This product does not contain greater than 1.0% of any chemical substance on the SARA Extremely Hazardous Substances List.

SARA Section 313 This product does not contain greater than 1.0% (greater than 0.1% for carcinogenic substances) of any chemical substance listed under SARA 313 SARA Classifications

Acute Hazard No Chronic Hazard No Fire Hazard No Reactivity Hazard No

CERCLA Hazardous None.

Substances FDA Approval Not Applicable.

California Prop. 65 No Proposition 65 statement is required for this product.

SECTION 16: OTHER INFORMATION

OTHER INFORMATION:

HMIS INFORMATION

A = Safety Glasses.

PREPARATION INFORMATION:

Version 1.0 (August 2012) Created SDS Version 2.0 (October 2012) Data added Version 3.0 (November 2016) Updated toxicity data.

Version 4.0 (January 2018) Updated Name and Address

Prepared by:

DISCLAIMER:

EarthClean LLC urges each customer or recipient of this SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate. However, no warranty, express or implied, is given, including any warranty of merchantability or fitness for a particular purpose. Regulatory requirements are subject to change and may differ between various locations. The information presented here pertains only to the product as shipped. Since conditions for use of the product are not under control of the manufacturer, it is the buyer’s/user’s duty to determine the conditions necessary for the safe use of this product.

HEALTH 0

FLAMMABILITY 0

PHYSICAL HAZARD 0

PERSONAL

PROTECTION

A

MSDS ID: CR-156

Page 1 of 5 Issue Date: 01/01/06 Rev: 1.0000 Print Date: 4/28/2006

* * * Section 1 - Chemical Product and Company Identification * * *

PRODUCT NAME: Thermo-Gel® 300L

Chemical Name: Anionic Emulsion Copolymer of acrylamide

Manufacturer Information

Thermo Technologies, LLC. Phone: (701) 258-8202 400 East Broadway Suite 50 Fax: (701) 258-7259 Bismarck, ND 58501 Emergency: (800) 538-8122

General Comments

Emergency telephone numbers are to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving the product.

* * * Section 2 - Hazards Identification * * *

Emergency Overview

Concentrate contains surfactants that may cause eye irritation on contact.

Potential Health Effects: Eyes

Concentrate may cause burning, itching and other discomfort, resulting in reddening of the eyes.

Potential Health Effects: Skin

Concentrate may cause skin irritation.

Potential Health Effects: Ingestion

As in any instance of non-food consumption, seek medical attention in the event of any adverse symptoms.

Potential Health Effects: Inhalation

Irritation of the mucous membranes may result from inhalation of vapors or mists.

HMIS Ratings: Health: 1 Fire: 0 Reactivity: 0

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard

* * * Section 3 - Composition / Information on Ingredients * * *

Component Percent Propenoic acid, sodium salt, polymer 20-30 Fatty acids, methyl esters 20-25 Surfactants 1-5

Component Information/Information on Non-Hazardous Components

This product is not considered hazardous under 29 CFR 1910.1200 (Hazard Communication). Product contains surfactants that may cause eye irritation on contact (See sections 3 & 4).

cjohnson12 Text Box

MSDS-0666

Thermo-Gel® 300L MSDS ID: CR-156

Page 2 of 5 Issue Date: 01/01/06 Rev: 1.0000 Print Date: 4/28/2006

* * * Section 4 - First Aid Measures * * *

First Aid: Eyes

Immediately flush eyes with plenty of water for at least 15 minutes.

First Aid: Skin

Wash with soap and water. Remove contaminated clothing.

First Aid: Ingestion

If swallowed, seek medical attention.

First Aid: Inhalation

If inhaled, move to source of fresh air. Seek medical attention if symptoms persist.

* * * Section 5 - Fire Fighting Measures * * *

General Fire Hazards

Thermal decomposition of this product may be hazardous as noted in Sections 2 & 3. Firefighters should wear full protective clothing.

Upper Flammable Limit (UFL): Not Established Lower Flammable Limit (LFL): Not Established Method Used: Component Flash Point: >212oF Flammability Classification: None Auto Ignition: Not Established

Hazardous Combustion Products On thermal decomposition, oxides of carbon and nitrogen.

Extinguishing Media Dry chemical, foam, carbon dioxide, water fog. Very slippery conditions are created if spilled product comes in contact with water.

Fire Fighting Equipment/Instructions Firefighters should wear full protective clothing.

NFPA Ratings: Health: 1 Fire: 0 Reactivity: 0 Other: B

Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe

* * * Section 6 - Accidental Release Measures * * *

Containment Procedures

Dike the spilled material, where this is possible. Contain and absorb spill with inert material. Prevent discharge of concentrate into waterways. Keep on-lookers away.

Clean-Up Procedures Use caution after contact of product with water as very slippery conditions will result. Residuals may be flushed with water into the drain for normal wastewater treatment.

Evacuation Procedures None required.

Page 3 of 5 Issue Date: 01/01/06 Rev: 1.0000 Print Date: 4/28/2006

* * * Section 7 - Handling and Storage * * *

Handling Procedures

Handle as an eye and respiratory tract irritant. Use chemical/splash goggles when handling concentrate.

Storage Procedures

Store in cool, dry and well ventilated areas. Keep containers tightly closed. Keep away from oxidizing agents, excessive heat, and ignition sources.

* * * Section 8 - Exposure Controls / Personal Protection * * *

Exposure Guidelines A: General Product Information

Attempts should be made to eliminate all contact with eyes and to limit inhalation exposure.

B: Component Exposure Limits

No information is available.

Engineering Controls

Provide local and general exhaust ventilation to effectively remove and prevent buildup of any vapors or mists generated from the handling of this product.

PERSONAL PROTECTIVE EQUIPMENT

Personal Protective Equipment: Eyes/Face

Wear safety glasses with side shields when using end product.

Personal Protective Equipment: Skin

Use impervious gloves when handling the concentrate in the manufacturing environment.

Personal Protective Equipment: Respiratory

Personal Protective Equipment: General

Obey reasonable safety precautions and practice good housekeeping. Wash thoroughly after handling.

* * * Section 9 - Physical & Chemical Properties * * *

Appearance: Opaque Odor: characteristic Physical State: Liquid pH: 7.0 @27.5g/l (20oC)

Vapor Pressure: Not Established Vapor Density: Not Established Boiling Point: ~96oC Melting Point: Not Established

Solubility (H2O): Disperses in water, large rise in viscosity.

Specific Gravity: 1.05 g/cm3 @ 20oC

Flash Point: >212oF

Page 4 of 5 Issue Date: 01/01/06 Rev: 1.0000 Print Date: 4/28/2006

* * * Section 10 - Chemical Stability & Reactivity Information * * *

Chemical Stability

The product is stable.

Chemical Stability: Conditions to Avoid

Avoid elevated temperatures.

Incompatibility

Strong oxidizers and strong acids.

Hazardous Decomposition

Will not decompose on storage. Combustion produces carbon monoxide, carbon dioxide along with thick smoke.

Hazardous Polymerization Will not occur.

* * * Section 11 - Toxicological Information * * *

Acute and Chronic Toxicity

No information

Carcinogenicity A: General Product Information

None B: Component Carcinogenicity

No information is available.

Chronic Toxicity

No chronic health effects have been observed.

Component Carcinogenicity No information is available.

* * * Section 12 - Ecological Information * * *

Ecotoxicity

Component Analysis

Environmental Fate

No Information Known,.

* * * Section 13 - Disposal Considerations * * *

US EPA Waste Number & Descriptions

Component Waste Numbers

No EPA Waste Numbers are applicable for this product's components.

Disposal Instructions

Page 5 of 5 Issue Date: 01/01/06 Rev: 1.0000 Print Date: 4/28/2006

* * * Section 14 - Transportation Information * * *

This product is not regulated by DOT (Department of Transportation) as a…

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