Class A Firefighting Foam Safety Data Sheet 1.pdf

SAFETY DATA SHEET (HCS, Annexe D table D.1) Version 4.2 (13/12/2018) - Page 1/7

BIO-EX

ECOPOL F

SAFETY DATA SHEET

SECTION 1 : IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier

Product name : ECOPOL F

1.2. Relevant identified uses of the substance or mixture and uses advised against

Fire fighting foam concentrate

1.3. Details of the supplier of the safety data sheet

Registered company name : BIO-EX.

Address : 5 chemin de Clape-Loup .69280.Sainte-Consorce.FRANCE.

Telephone : +33 (0)4.74.70.23.81. Fax : +33 (0)4.74.70.23.94.

contact@bio-ex.fr

1.4. Emergency telephone number : +33 (0)1 45 42 59 59.

Association/Organisation : INRS / ORFILA http://www.centres-antipoison.net.

SECTION 2 : HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

HCS compliant.

Skin irritation, Category 2 (Skin Irrit. 2).

Serious eye damage, Category 1 (Eye Dam. 1).

This mixture does not present a physical hazard. Refer to the recommendations regarding the other products present on the site.

2.2. Label elements

HCS compliant.

Hazard pictograms :

GHS05

Signal Word :

DANGER

Product identifiers :

PROPRIETARY MIXTURE OF SURFACTANTS

Hazard statements :

H315 Causes skin irritation.

H318 Causes serious eye damage.

Precautionary statements - Prevention :

P280 Wear protective gloves/protective clothing/eye protection/face protection.

Precautionary statements - Response :

P302 + P352 IF ON SKIN: Wash with plenty of water/...

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P362 + P364 Take off contaminated clothing and wash it before reuse.

2.3. Other hazards

No data available.

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SECTION 3 : COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Mixtures

Composition :

Identification HCS Nota %

PROPRIETARY MIXTURE OF

SURFACTANTS

GHS07, GHS05

Dgr

Skin Irrit. 2, H315

Eye Dam. 1, H318

25 <= x % < 50

INDEX: 603-096-00-8

EC: 203-961-6

2-(2-BUTOXYETHOXY)ETHANOL

GHS07

Wng

Eye Irrit. 2, H319

[1] 10 <= x % < 25

(Full text of H-phrases: see section 16)

Information on ingredients :

[1] Substance for which maximum workplace exposure limits are available.

SECTION 4 : FIRST AID MEASURES

As a general rule, in case of doubt or if symptoms persist, always call a doctor.

NEVER induce swallowing by an unconscious person.

4.1. Description of first aid measures

In the event of splashes or contact with eyes :

Wash thoroughly with fresh, clean water for 15 minutes holding the eyelids open.

Regardless of the initial state, refer the patient to an ophthalmologist and show him the label.

In the event of splashes or contact with skin :

Remove contaminated clothing and wash the skin thoroughly with soap and water or a recognised cleaner.

Watch out for any remaining product between skin and clothing, watches, shoes, etc.

If the contaminated area is widespread and/or there is damage to the skin, a doctor must be consulted or the patient transferred to hospital.

In the event of swallowing :

Do not give the patient anything orally.

In the event of swallowing, if the quantity is small (no more than one mouthful), rinse the mouth with water and consult a doctor.

Seek medical attention immediately, showing the label.

4.2. Most important symptoms and effects, both acute and delayed

No data available.

4.3. Indication of any immediate medical attention and special treatment needed

No data available.

SECTION 5 : FIREFIGHTING MEASURES

Non-flammable.

5.1. Extinguishing media

Firefighting foam concentrate not flammable

5.2. Special hazards arising from the substance or mixture

No data available.

5.3. Advice for firefighters

No data available.

SECTION 6 : ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

Consult the safety measures listed under headings 7 and 8.

6.2. Environmental precautions

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Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite, diatomaceous earth in drums for waste disposal.

6.3. Methods and material for containment and cleaning up

If the ground is contaminated, once the product has been recovered by sponging with an inert and non-combustible absorbent material, wash the contaminated area in plenty of water.

6.4. Reference to other sections

No data available.

SECTION 7 : HANDLING AND STORAGE

Requirements relating to storage premises apply to all facilities where the mixture is handled.

7.1. Precautions for safe handling

Always wash hands after handling.

Remove and wash contaminated clothing before re-using.

Emergency showers and eye wash stations will be required in facilities where the mixture is handled constantly.

Recommended equipment and procedures :

For personal protection, see section 8.

Observe precautions stated on label and also industrial safety regulations.

Handle and open the container with care.

Avoid eye contact with this mixture at all times.

Prohibited equipment and procedures :

No smoking, eating or drinking in areas where the mixture is used.

7.2. Conditions for safe storage, including any incompatibilities

No data available.

Packaging

Always keep in packaging made of an identical material to the original.

Recommended types of packaging :

Product in bulk : stainless steel, polyester or mild steel protected with epoxy or polyurethane coating. Tanks in PE, PP

Unsuitable packaging materials :

Mild steel

7.3. Specific end use(s)

No data available.

SECTION 8 : EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Occupational exposure limits :

- European Union (2017/2398, 2017/164, 2009/161, 2006/15/CE, 2000/39/CE, 98/24/CE) :

CAS VME-mg/m3 : VME-ppm : VLE-mg/m3 : VLE-ppm : Notes :

112-34-5 67.5 10 101.2 15 -

- Germany - AGW (BAuA - TRGS 900, 29/01/2018) :

CAS VME : VME : Excess Notes

112-34-5 10 ppm

67 mg/m³

1,5 (I)

- France (INRS - ED984 :2016) :

CAS VME-ppm : VME-mg/m3 : VLE-ppm : VLE-mg/m3 : Notes : TMP No :

112-34-5 10 67.5 15 101.2 - -

- UK / WEL (Workplace exposure limits, EH40/2005, 2011) :

CAS TWA : STEL : Ceiling : Definition : Criteria :

112-34-5 10 ppm

67,5 mg/m³

15 ppm

101,2 mg/m³

8.2. Exposure controls

Personal protection measures, such as personal protective equipment

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Pictogram(s) indicating the obligation of wearing personal protective equipment (PPE) :

Use personal protective equipment that is clean and has been properly maintained.

Store personal protective equipment in a clean place, away from the work area.

Never eat, drink or smoke during use. Remove and wash contaminated clothing before re-using. Ensure that there is adequate ventilation, especially in confined areas.

- Eye / face protection

Avoid contact with eyes.

Use eye protectors designed to protect against liquid splashes

Before handling, wear safety goggles with protective sides accordance with standard EN166.

Goggles

- Hand protection

Recommended properties :

- Impervious gloves in accordance with standard EN374

- Body protection

Avoid skin contact.

Wear suitable protective clothing.

Work clothing worn by personnel shall be laundered regularly.

After contact with the product, all parts of the body that have been soiled must be washed.

SECTION 9 : PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

General information :

Physical state : Fluid liquid.

Important health, safety and environmental information pH : Not stated.

Neutral.

Boiling point/boiling range : Not specified.

Flash point interval : Not relevant.

Vapour pressure (50°C) : Not relevant.

Density : > 1

Water solubility : Soluble.

Melting point/melting range : Not specified.

Self-ignition temperature : Not specified.

Decomposition point/decomposition range : Not specified.

9.2. Other information

No data available.

SECTION 10 : STABILITY AND REACTIVITY

10.1. Reactivity

No data available.

10.2. Chemical stability

This mixture is stable under the recommended handling and storage conditions in section 7.

10.3. Possibility of hazardous reactions

No data available.

10.4. Conditions to avoid

No data available.

10.5. Incompatible materials

No data available.

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10.6. Hazardous decomposition products

No data available.

SECTION 11 : TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

May cause irreversible damage to the skin; namely inflammation of the skin or the formation of erythema and eschar or oedema following exposure up to four hours.

May have irreversible effects on the eyes, such as tissue damage in the eye, or serious physical decay of sight, which is not fully reversible by the end of observation at 21 days.

Serious eye damage is typified by the destruction of cornea, persistent corneal opacity and iritis.

11.1.1. Substances

No toxicological data available for the substances.

11.1.2. Mixture

No toxicological data available for the mixture.

SECTION 12 : ECOLOGICAL INFORMATION

The product must not be allowed to run into drains or waterways.

12.1. Toxicity

12.1.2. Mixtures

No aquatic toxicity data available for the mixture.

12.2. Persistence and degradability

12.2.2. Mixtures

easily biodegradable

12.3. Bioaccumulative potential

No data available.

12.4. Mobility in soil

No data available.

12.5. Results of PBT and vPvB assessment

No data available.

12.6. Other adverse effects

No data available.

SECTION 13 : DISPOSAL CONSIDERATIONS

The appropriate waste management of the mixture and/or its container must be determined in accordance with local regulations.

13.1. Waste treatment methods

Do not pour into waterways

Waste :

Waste management is carried out without endangering human health, without harming the environment and, in particular without risk to water, air, soil, plants or animals.

Recycle or dispose of waste in compliance with current legislation, preferably via a certified collector or company.

Do not contaminate the ground or water with waste, do not dispose of waste into the environment.

Soiled packaging :

Empty container completely. Keep label(s) on container.

Give to a certified disposal contractor.

SECTION 14 : TRANSPORT INFORMATION

Exempt from transport classification and labelling.

14.1. UN number

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14.2. UN proper shipping name

14.3. Transport hazard class(es)

14.4. Packing group

14.5. Environmental hazards

14.6. Special precautions for user

SECTION 15 : REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

The following regulations have been used:

- OSHA Hazard Communication Standard 29 CFR 1910.1200

- Container information:

No data available.

- Particular provisions :

No data available.

- Standardised American system for the identification of hazards presented by the product in view of emergency procedures (NFPA 704) :

NFPA 704, Labelling: Health=1 Inflammability=0 Instability/Reactivity=0 Specific Risk=none

1 0

- Clean Water Act : Toxic Pollutants (CWA 307A)

Unlisted.

- Clean Water Act : Hazardous Substances (CWA 311)

Unlisted.

- Clean Water Act : Hazardous Substances (CWA 304b)

Unlisted.

- Clean Water Act : Priority Pollutants (CWA Priority)

Unlisted.

- Clean Air Act : Hazardous Air Pollutants (CAA 112(b) HAP (188))

Unlisted.

- Clean Air Act : Organic Hazardous Air Pollutants National Emission Standards (CAA 112(b) HON (387)) CAS Name

112-34-5 2-(2-BUTOXYETHOXY)ETHANOL

- Clean Air Act : Protection of Stratospheric Ozone (CAA 602)

Unlisted.

- SARA 110

Unlisted.

- SARA 302/304

Unlisted.

- SARA 313

Unlisted.

- California proposition 65 : Chemicals known to the state to cause cancer or reproductive toxicity

Unlisted.

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- Massachusetts : Right to Know

Unlisted.

- New Jersey : Right to Know

Unlisted.

- Pennsylvania : Hazardous Substance

Unlisted.

- Rhode Island : Hazardous substance list

Unlisted.

- TSCA (Toxic Substances Control Act) - USA CAS Name

112-34-5 2-(2-BUTOXYETHOXY)ETHANOL

15.2. Chemical safety assessment

No data available.

SECTION 16 : OTHER INFORMATION

Since the user's working conditions are not known by us, the information supplied on this safety data sheet is based on our current level of knowledge and on national and community regulations.

The mixture must not be used for other uses than those specified in section 1 without having first obtained written handling instructions.

It is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and local regulations.

The information in this safety data sheet must be regarded as a description of the safety requirements relating to the mixture and not as a guarantee of the properties thereof.

Wording of the phrases mentioned in section 3 :

H315 Causes skin irritation.

H318 Causes serious eye damage.

H319 Causes serious eye irritation.

Abbreviations :

ADR : European agreement concerning the international carriage of dangerous goods by Road.

IMDG : International Maritime Dangerous Goods.

IATA : International Air Transport Association.

ICAO : International Civil Aviation Organisation

RID : Regulations concerning the International carriage of Dangerous goods by rail.

GHS05 : Corrosion

PBT: Persistent, bioaccumulable and toxic.

vPvB : Very persistent, very bioaccumulable.

HCS : Hazard Communication standard (OSHA).

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MATERIAL SAFETY DATA SHEET

IDENTITY- BUCKEYE PLATINUM CLASS A

SECTION I. Chemical Product and Company Identification

Product Name: Buckeye Platinum Class A (BFC-CA.1) Synonym: Class A, Foam fire suppressant Manufacturer: Buckeye Fire Equipment Company 110 Kings Road Kings Mountain, NC 28086 Telephone: 704.739.7415 Emergency: CHEMTREC 1.800.424.9300

Revision Date: 11/20/10

SECTION II. Hazard Identification and Emergency Overview

Emergency Overview: None of the chemicals in this product are under SARA reporting requirements or have SARA Threshold Planning Quantities or CERCLA Reportable Quantities. This product is not defined as a hazardous material under U.S. Department of Transportation 49 CFR 172, or by Transport Canada “Transportation of Dangerous Goods” regulations.

Appearance: Pale yellow water-based liquid solution, mild sweet odor.

Adverse Health Effects and Symptoms: No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet. Symptoms that may arise if the product is mishandled are irritation to the skin, and eyes, coughing or sore throat if ingested. Central nervous system effects may occur if ingested.

Hazard Symbols:

HMIS RATINGS:

Health 1 Flammability 0 Reactivity 0 Personal Protective Equipment: use eye protection, gloves, and appropriate skin protection (See Section 8)

WHMIS (Canadian Workplace Hazardous Materials Identification) D2B- May irritate eyes, mucous membranes, or skin

SECTION III. Composition/Information on Ingredients

Weight %* CAS # Water > 36 7732-18-5 Hexylene Glycol 21 107-41-5 Alpha Olefin Sulfonate 28 68439-57-6 Proprietary mixture of surfactants, foam < 15 N/A stabilizers, and inorganic salts

* % is rounded to the nearest appropriate number. Values are not to be considered product specifications

SECTION IV. First Aid Measures

Eye Exposure- Flush eyes at eye wash station for 15 minutes and repeat until pain-free. If irritation develops or persists or vision changes occur, seek medical attention.

Skin Exposure- Wash with plenty of soap and water. If irritation develops or persists, seek medical attention.

Inhalation- Move victim to fresh air. Trained personnel may provide oxygen if breathing is difficult. If irritation develops or persists, seek medical attention.

Ingestion- If victim is conscious and alert, give 2-3 glasses of water to drink. Do not leave victim unattended. Seek immediate medical attention. On the advice of medical personnel, induce vomiting. If vomiting occurs and the victim is conscious, give additional water to further dilute the chemical. Prevent aspiration of swallowed product by laying victim on side with head lower than their waist.

Medical Conditions Possibly Aggravated by Exposure- Inhalation of the product may aggravate existing chronic respiratory conditions.

SECTION V. Firefighting Measures

Extinguishing Media: N/A. This product is an extinguishing agent. It is nonflammable and noncombustible.

Special Firefighting Procedures: N/A Unusual Fire and Explosion Hazards: This product may decompose in fire and release oxides of sulfur and nitrogen. (Refer to Section X).

Sensitivity to Mechanical Impact or Static Discharge: None

SECTION VI. Accidental Release Measures

Large spills (1 drum or more) should be addressed by hazardous materials technicians following a site-specific emergency response plan and trained in the appropriate use of personal protection equipment.

Clean up released product using absorbent socks for containment followed by absorbent material within the containment. If deemed necessary, wear appropriate APR for amines/glycol ethers (See Section VIII). Bag and drum for disposal. If product is used on a fire and/or contaminated, use personal protection equipment and containment appropriate to the nature of the mixture. Prevent material from entering waterways.

Handle and dispose of as a hazardous waste unless testing indicates otherwise. Decontaminate with detergent and water.

SECTION VII. Handling and Storage

Avoid eye, respiratory, and skin exposure. Use the appropriate personal protective equipment when handling. Wash thoroughly after handling (Refer to Section VIII). Product should be stored in its original container or extinguisher. Use in well-ventilated areas. Do not mix with other extinguishing agents.

SECTION VIII. Exposure Controls and Personal Protection

During the use of this product on fires, exhaust gases and products of incomplete combustion are the main respiratory hazards. In the manufacture of this product, employers and employees must use their collective judgment in determining the on-the-job settings where the use of a respirator is prudent. The need for respiratory protection is not likely for short-term use in well-ventilated areas.

Respiratory Protection: Use air-purifying respirators or powered air-purifying respirators with organic vapor and amine cartridges for short-term exposures, otherwise use positive pressure supplied air respirators or self-contained breathing apparatus.

Eye Protection: Wear chemical goggles.

Skin Protection: Use nitrile, latex, or similar gloves and coveralls. Good personal hygiene practices are essential. After handling the product, avoid food, tobacco products, or other means of transferring the product from hand to mouth until after thoroughly washing.

SECTION IX. Physical and Chemical Properties

Appearance and Odor: Pale yellow liquid solution with a mild, sweet odor.

Specific Gravity: 1.02 Boiling Point: 70º C Flash Point: 88º C Flammability: N/A Solubility: 100%

SECTION X. Stability and Reactivity

Stability: Stable Incompatibles: Strong acids, bases, and oxidizers. Reactive metals. Any material reactive with water Decomposition Products: Not known, but oxides of sulfur and nitrogen may be formed.

Hazardous Reactions: None

SECTION XI. Toxicological Information

Routes of Entry:

Eye Contact: May cause mild transient irritation Skin Contact: May cause mild transient irritation and/or dermatitis Inhalation: Inhalation is not anticipated to be a problem Ingestion: Irritating to mucous membranes. Large oral doses could produce narcosis

Chronic Toxicity: This product’s ingredients are not considered as probable or suspected carcinogens by

OSHA, IARC, or ACGIH.

Reproductive Toxicity: This product is not known to have any reproductive effects.

SECTION XII. Considerations for Disposal

This product is not a RCRA characteristically hazardous or listed hazardous waste. Dispose of according to state or local laws, which may be more restrictive than federal regulations. Be aware that product used on a fire may be altered or contaminated and thereby require different disposal considerations.

SECTION XIII. Transportation Information

This product is not defined as a hazardous material under U.S. Department of Transportation 49 CFR 172, or by Transport Canada “Transportation of Dangerous Goods” regulations.

SECTION XIV. Regulatory Information

International Inventory Status: Some ingredients are on the following inventories

Country Agency

U.S.A. TSCA

Canada DSL Europe EINECS/ELINCS

Australia AICS Japan MITI

South Korea KECL

European Risk and Safety Phrases:

EU Classification- Xi Irritant

R Phrases- 36 Irritating to eyes, respiratory system, and skin.

S Phrases- 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 36 Wear suitable protective clothing

U.S. Federal Regulatory Information:

None of the chemicals in this product are under SARA reporting requirements or have SARA Threshold Planning Quantities or CERCLA Reportable Quantities.

State Regulatory Information:

Chemicals in this product are covered under the specific State regulations noted:

Alaska Designated Toxic and Hazardous Substances- None California Permissible Exposure Limits for Chemical Contaminants- None Florida Substance list- None Illinois Toxic Substance List- None Kansas Section 302/303 List- None Massachusetts Substance list- None Minnesota List of Hazardous Substances- None Missouri Employer Information/Toxic Substance List- None New Jersey Right to Know Hazardous Substance List- None North Dakota List of Hazardous Chemicals, Reportable Quantities- None Pennsylvania Hazardous Substance List- None Rhode Island Hazardous Substance List- None Texas Hazardous Substance List- No West Virginia Hazardous Substance List- None Wisconsin Toxic and Hazardous Substances- None

California Proposition 65- No component is listed on the California Proposition 65 List

SECTION XV. Other Information

This MSDS conforms to the requirements under U.S., U.K., Canadian, Australian, and EU Regulations or Standards. It conforms to the proposed 2003 ANSI Z400.1 format.

The information contained herein is given in good faith as typical values and not as product specifications.

No warranty, either expressed or implied, is hereby made.

PRODUCT NAME: 1% Bushmaster A Class Foam Classified as non hazardous according to criteria of NOHSC

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY

Product Name Bushmaster A Class Foam Product Use Water based foam concentrate Company Name NOWA AUSTRALI A PTY. LTD.

Address 44 Brady Street Virginia South Australia, Australia 5120 Emergency Tel. 61 8 8380 9976 Telephone No/Fax Tel – 61 8 8380 9976 Fax – 61 8 8380 9977

2. COMPOSITION/INFORMATION ON INGREDIENTS

Information on Fire fighting foam based on water-soluble detergents.

Composition Ingredients Name Proportion Nonionic surfactant =12 Anionic detergent blend =24 Glycol ether solvent =14 Corrosion inhibitor =0.30

3. HAZARDS IDENTIFICATION

Classified as non-hazardous according to the criteria of NOHSC and not classified as a dangerous good according to the ADG code.

Risk phrases: R36 Irritating to eyes

Safety phrases: S2 Keep out of reach of children

S25 Avoid contact with eyes and prolonged skin contact.

Hazard Category Nil Symptoms & Effects May dry skin on prolonged contact Other Hazard Info. Nil

44 BRADY STREET

P.O.BOX 52

VIRGINIA

South Australia 5120

PH: (08) 8380 9976

FAX: (08) 83809977

24 HR: 0418 825 300

Material Safety Data Sheet

Issue Date:- 2nd June 2010

Material Safety Data Sheet Issue Date:- 2nd June 2010 Page 2 of 5

4. FIRST AID MEASURES

Inhalation Remove victim to fresh air. Investigate possible misuse of material. Seek medical attention.

Ingestion Rinse mouth thoroughly with water immediately. Give water to drink. DO

NOT induce Vomiting. Seek medical attention. Never give anything by mouth to an unconscious person.

Eyes Remove contact lenses. Immediately irrigate with copious amounts of water for at least 15 minutes. Eyelids to be held open. Seek immediate medical assistance.

Skin Wash affected areas with water.

First Aid Facilities Normal washroom facilities Advice to Doctor Treat symptomatically

5. FIRE FIGHTING MEASURES

Extinguishing Media Use extinguishing media suitable for surrounding fire situation Specific Hazards Nil Precautions in Firefighters should wear Self Contained Breathing Apparatus and full protective clothing (including overalls, neoprene or nitrile gloves, rubber boots, eye goggles and respirator).

Connection with fire clothing to minimize exposure. Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. If safe to do so, remove undamaged containers from fire area.

6. ACCIDENTAL RELEASE MEASURES

Spills & Disposal Contain and collect using absorbent material. Small spills may be flushed to sewer. Dispose off to landfill.

7. HANDLING AND STORAGE

Handling Repeated or prolonged exposure to the concentrate without personal protection should be avoided in order to lessen the possibility of disorders. It is essential that all who come into contact with this material maintain good standards of personal hygiene. i.e. washing hands prior to eating, drinking or going to the toilet. Keep container closed and bung in place.

Storage Keep containers closed when not in use and securely sealed and protected against physical damage. Inspect regularly for deficiencies such as damage or leaks.

Issue Date:- 2nd June 2010 Page 3 of 5

8. EXPOSURE CONTROLS, PERSONAL PROTECTION

Exposure Limits No value assigned for this specific material by the National Occupational Health and Safety Commission (NOHSC). However as with all chemical, exposure to concentrate should be kept to the least possible levels.

Respiratory Protection Approved Respirator recommended. Not necessary for the diluted product or when handling concentrate.

Eye Protection Safety Glasses or Goggles.

Hand Protection Neoprene or rubber gloves recommended. Incidental skin contact is not harmful.

Body Protection Rubber boots and Overalls recommended.

Eng. Controls N/A Other information No Biological Limit Value allocated.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Clear water white to light yellow medium viscosity liquid Odor slight glycol Boiling Point 100°C Solubility in water completely soluble Specific Gravity 1.015@20°C (H O=1) Physical State Liquid pH 7.5@20°C

Flash Point Non flammable Flammability Non flammable Flammable Limits LEL Non flammable Flammable Limits UEL Non flammable

10. STABILITY AND REACTIVITY

Stability Stable under normal conditions of storage and handling Hazardous Will not occur Polymerization Materials to Avoid Strong oxidizing agents Decomposition Products None known Hazardous Reaction Not a fire hazard

Issue Date:- 2nd June 2010 Page 4 of 5

11. TOXICOLOGICAL INFORMATION

Toxicology Information N/A Inhalation Ingredients are considered non-hazardous when used as directed.

Ingestion Not a likely source of exposure, however, moderate quantities of concentrate may cause irritation. Potential symptoms include nausea, diarrhea, abdominal pain and vomiting.

Skin May cause skin irritation if prolonged contact with the concentrate occurs, which can result in redness, itchiness, swelling and possibly lead to dermatitis.

Continual exposure to dilute solutions will cause loss of natural skin oils, and drying of skin.

Eye The concentrate is considered an eye irritant. May cause eye soreness Chronic Effects No known adverse effects

12. ECOLOGICAL INFORMATION

Mobility/ No data is available for this product Persistence No data is available for this product Degradability Fully biodegradable Bioaccumulation No data is available for this product Ecotoxicity No data is available for this product

13. DISPOSAL CONSIDERATIONS

Dispose of waste according to federal, E.P.A., state and local regulations.

Assure conformity with all applicable regulations.

14. TRANSPORT INFORMATION

U.N. Number None allocated Proper Shipping Name None allocated DG Class None allocated Hazchem Code None allocated Packing Group None allocated EPG Number None allocated IERG Number None allocated

15. REGULATORY INFORMATION

Safety Phrase Avoid contact with eyes and prolonged skin contact. Keep out of reach of children. Wear Protective clothing, which should include Overalls, Neoprene or Rubber Gloves, Rubber boots and Safety Glasses or Goggles and respirator is recommended – Consult Material Safety Data Sheet

Poisons Schedule Nil AICS (Australia) All ingredients are listed in the Australian Inventory of Chemical Substances

(AICS)

Issue Date:- 2nd June 2010 Page 5 of 5

16. OTHER INFORMATION

This MSDS summarizes our best knowledge of the health and safety hazard information of the product and how to safely handle and use the product in the workplace. Each user must review this MSDS in the context of how the product will be handled in the workplace and in conjunction with other materials. If clarification or further information is needed to ensure that an appropriate risk assessment can be made, the user should contact this company.

Contact Person Manager – Nowa Australia Pty. Ltd.

Tel – 08 8380 9976 Fax – 08 8380 9977 MSDS History MSDS Creation: 2nd June 2010

Safety Data Sheet

This safety data sheet complies with the requirements of: 2012 OSHA Hazard Communication Standard ( 29CFR 1910.1200)

Product name DIRECTATTACK CLASS A FOAM

1. Identification

Product name DIRECTATTACK CLASS A FOAM

Product code 720000 Synonyms None Chemical Family No information available

Recommended use Fire extinguishing agent Uses advised against Consumer use

Contact point Product Stewardship at 1-715-735-7411 E-mail address psra@tycofp.com

Emergency telephone CHEMTREC 800-424-9300 or 703-527-3887

2. Hazards Identification

OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Serious eye damage/eye irritation - Category 2A

Precautionary Statements

Prevention Wash face, hands and any exposed skin thoroughly after handling. Wear eye/face protection.

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue

1.1. Product Identifier

1.2. Other means of identification

1.3. Recommended use of the chemical and restrictions on use

1.4. Details of the Supplier of the Safety Data Sheet

Company Name Tyco Fire Protection Products

One Stanton Street Marinette, WI 54143-2542 Telephone: 715-735-7411

1.5. Emergency Telephone Number

Classification

2.2. Label Elements

Signal Word

WARNING

hazard statements Causes serious eye irritation

Revision date 22-Feb-2016 Version 1

Product code 720000 / Product name DIRECTATTACK

CLASS A FOAM

/ PAGE 2 / 8

rinsing. If eye irritation persists: Get medical advice/attention.

Not Applicable.

Toxic to aquatic life with long lasting effects.

3. Composition/information on Ingredients

The following component(s) in this product are considered hazardous under applicable OSHA(USA)

Chemical name CAS No weight-% 1-(2-Butoxy-1-methylethoxy)propan-2-ol 29911-28-2 5 - 10

Sodium Alkene sulphonate 68439-57-6 5 - 10 Lauryl Alcohol 112-53-8 1 - 5

4. First aid measures

Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.

Consult a physician.

Skin contact Wash skin with soap and water. Get medical attention if irritation develops and persists.

Inhalation Remove to fresh air. If breathing is difficult, give oxygen. (Get medical attention immediately if symptoms occur.).

Ingestion Rinse mouth. Do not induce vomiting without medical advice. If swallowed, call a poison control center or physician immediately.

Symptoms No information available.

Note to physicians Treat symptomatically.

5. Fire-fighting measures

Hazardous Combustion Products

Carbon oxides, Nitrogen oxides (NOx), Oxides of sulfur

2.3. Hazards Not Otherwise Classified (HNOC)

2.4. OTHER INFORMATION

3.1. Mixture

4.1. Description of first aid measures

4.2. Most Important Symptoms and Effects, Both Acute and Delayed

4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed

5.1. Suitable Extinguishing Media

Product is extinguishing agent. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

5.2. Unsuitable Extinguishing Media

None.

5.3. Specific Hazards Arising from the Chemical

None known.

5.4. Explosion Data

CLASS A FOAM

/ PAGE 3 / 8

Sensitivity to Mechanical Impact None.

Sensitivity to Static Discharge None.

6. Accidental release measures

Personal Precautions Ensure adequate ventilation, especially in confined areas.

For emergency responders Use personal protection recommended in Section 8.

Environmental Precautions Prevent further leakage or spillage if safe to do so. Prevent entry into waterways, sewers, basements or confined areas. See Section 12 for additional Ecological Information.

Methods for Containment Prevent further leakage or spillage if safe to do so.

Methods for Cleaning Up Pick up and transfer to properly labeled containers.

7. Handling and Storage

Advice on safe handling Avoid contact with skin and eyes. Handle in accordance with good industrial hygiene and safety practice.

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.

Incompatible Materials Strong oxidizing agents. Strong acids. Strong bases.

8. Exposure Controls/Personal Protection

Exposure guidelines . This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies.

Engineering controls Showers Eyewash stations Ventilation systems.

Eye/Face Protection Avoid contact with eyes. Tight sealing safety goggles.

Skin and Body Protection Wear protective gloves and protective clothing.

Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be

5.5. Protective Equipment and Precautions for Firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental Precautions

6.3. Methods and material for containment and cleaning up

7.1. Precautions for Safe Handling

7.2. Conditions for safe storage, including any incompatibilities

8.1. Control Parameters

8.2. Appropriate Engineering Controls

8.3. Individual protection measures, such as personal protective equipment

CLASS A FOAM

/ PAGE 4 / 8

provided in accordance with current local regulations.

Ventilation Use local exhaust or general dilution ventilation to control exposure with applicable limits

9. Physical and Chemical Properties

Physical State Liquid

10. Stability and Reactivity

Stable under recommended storage conditions.

None under normal processing.

hazardous polymerization Hazardous polymerization does not occur.

Extremes of temperature and direct sunlight.

Strong oxidizing agents. Strong acids. Strong bases.

8.4. General hygiene considerations

Do not eat, drink or smoke when using this product. Handle in accordance with good industrial hygiene and safety practice.

9.1. Information on basic physical and chemical properties

Odor Characteristic Color No data available odor threshold No data available

Property VALUES Remarks • Method pH 7 Melting point/freezing point No data available Boiling point / boiling range 100 °C / 212 °F Flash Point > 100 °C / > 212 °F Evaporation Rate No data available flammability (solid, gas) No data available Flammability limit in air

Upper flammability limit: No data available Lower flammability limit: No data available

Vapor Pressure No data available Vapor Density No data available Specific gravity No data available Water Solubility No data available Solubility in Other Solvents No data available Partition coefficient No data available Autoignition Temperature No data available Decomposition Temperature No data available Kinematic viscosity No data available

10.1. Chemical Stability

10.2. Reactivity

No data available

10.3. Possibility of hazardous reactions

10.4. Conditions to Avoid

10.5. Incompatible Materials

CLASS A FOAM

/ PAGE 5 / 8

Carbon oxides. Nitrogen oxides (NOx). Oxides of sulfur.

11. Toxicological Information

Product information no data available

INHALATION no data available.

Eye Contact no data available.

Skin contact no data available.

INGESTION no data available.

Acute Toxicity

Chemical name Oral LD50 dermal LD50 Inhalation LC50 1-(2-Butoxy-1-methylethoxy)propan- 2-ol 29911-28-2

= 1620 µL/kg ( Rat ) = 5860 µL/kg ( Rabbit ) = 42.1 ppm ( Rat ) 4 h

Sodium Alkene sulphonate 68439-57-6

= 2310 mg/kg ( Rat ) = 6300 mg/kg ( Rabbit ) -

Lauryl Alcohol 112-53-8

> 5000 mg/kg ( Rat ) - -

Symptoms No information available.

sensitization No information available.

Germ Cell Mutagenicity No information available carcinogenicity No information available.

Reproductive Toxicity No information available.

STOT - Single Exposure No information available.

STOT - Repeated Exposure No information available.

Aspiration Hazard No information available.

The following values are calculated based on chapter 3.1 of the GHS document mg/kg

12. Ecological Information

Toxic to aquatic life with long lasting effects

0% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical name Algae/aquatic plants Fish Crustacea

1-(2-Butoxy-1-methylethoxy)propan- 2-ol

29911-28-2

- LC50 96 h = 841 mg/L Poecilia reticulata static

Sodium Alkene sulphonate 68439-57-6

- LC50 96 h = 12.2 mg/L Brachydanio rerio semi-static LC50 96 h 1.0 -

10.0 mg/L Brachydanio rerio static

1,2-Propanediol 57-55-6

EC50 96 h = 19000 mg/L Pseudokirchneriella subcapitata

LC50 96 h = 51600 mg/L Oncorhynchus mykiss static LC50

EC50 48 h > 1000 mg/L Daphnia magna Static EC50 24 h > 10000

10.6. Hazardous decomposition products

11.1. Information on Likely Routes of Exposure

11.2. Information on Toxicological Effects

11.3. Delayed and immediate effects as well as chronic effects from short and long-term exposure

11.4. Numerical Measures of Toxicity - Product information

12.1. ecotoxicity

CLASS A FOAM

/ PAGE 6 / 8

96 h 41 - 47 mL/L Oncorhynchus mykiss static LC50 96 h = 51400 mg/L Pimephales promelas static

LC50 96 h = 710 mg/L Pimephales promelas mg/L Daphnia magna

Lauryl Alcohol 112-53-8

EC50 96 h = 0.62 mg/L Desmodesmus subspicatus

LC50 96 h = 1.01 mg/L Pimephales promelas flow-through LC50 96 h =

0.1855 mg/L Pimephales promelas

EC50 48 h = 320 mg/L Daphnia magna

No information available.

No information available.

Chemical name Partition coefficient Lauryl Alcohol

112-53-8 5.36

No information available

13. Disposal Considerations

Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations.

Contaminated Packaging Do not reuse container.

14. Transport Information

DOT NOT REGULATED

TDG NOT REGULATED

MEX NOT REGULATED

ICAO (air) NOT REGULATED

IATA NOT REGULATED

IMDG NOT REGULATED

15. Regulatory Information

TSCA Complies DSL/NDSL Does not comply ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies

12.2. Persistence and Degradability

12.3. Bioaccumulation

12.4. Other Adverse Effects

13.1. Waste Treatment Methods

15.1. International Inventories

CLASS A FOAM

/ PAGE 7 / 8

Legend:

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances

SARA 313

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

SARA 311/312 Hazard Categories Acute Health Hazard No Chronic health hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No

CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40

CFR 122.42)

CERCLA

This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material

California Proposition 65 This product does not contain any Proposition 65 chemicals

U.S. State Right-to-Know Regulations

Chemical name New Jersey Massachusetts Pennsylvania 1,2-Propanediol

57-55-6 X - X

16. Other information, including date of preparation of the last revision

Revision date 22-Feb-2016 Revision note No information available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

15.2. US Federal Regulations

15.3. US State Regulations

NFPA Health Hazards 1 flammability 1 Instability 0 Physical and chemical properties -

HMIS Health Hazards 1 flammability 1 Physical Hazards 0 Personal Protection X

CLASS A FOAM

/ PAGE 8 / 8

End of Safety Data Sheet

SOLBERG FIRE-BRAKE 3150A CLASS A FIRE FIGHTING FOAM Page 1 of 8

CONCENTRATE

SOLBERG ASIA PACIFIC PTY LIMITED

3 Charles Street

St. Marys NSW 2760, AUSTRALIA .

Phone: 02-9673-5300 (in Australia) or 61-2-9673-5300 (International)

FAX: 02-9673-5303 (in Australia) or 61-2-9673-5303 (International)

24HR EMERGENCY: 0413-803-892 (in Australia) or 61-413-803-892 (International).

Document ID : 3150A-AU-V01.0 Issue date : 07/12/2010

Version : 1.0 Supersedes date : 04/10/2007

Document status : Issued

This MSDS has been prepared by Solberg Asia Pacific Pty Ltd.

1 PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME:

SOLBERG FIRE-BRAKE(TM) 3150A CLASS A FIRE FIGHTING FOAM CONCENTRATE

SOLBERG PRODUCT ID: Fire-Brake 3150A 20L, Fire-Brake 3150A 200L, Fire-Brake 3150A 1000L, Fire-Brake 3150A Bulk

RECOMMENDED USE: To extinguish bushfires/wildfire, paper, wood and structural fires.

2 HAZARDS IDENTIFICATION

NOTE: NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.

POISONS SCHEDULE NONE ALLOCATED

Risk Codes and Phrases

Not applicable

Safety Codes and Phrases

S24/25 Avoid contact with the skin and eyes.

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S28A After contact with skin, wash immediately with plenty of soap

SOLBERG FIRE-BRAKE 3150A CLASS A FIRE FIGHTING FOAM Page 2 of 8 and water.

3 COMPOSITION

Ingredient Name CAS number Percentage

WATER 7732-18-5 81.0 - 85.0

DIETHYLENE GLYCOL BUTYL ETHER 112-34-5 8.0 - 9.0

ALKYL SULFATE AMINE SALT +(6076P) --- 3.0 - 4.0

SODIUM ALKYL SULFATE +(6079P) --- 1.0 - 2.0

SURFACTANTS +(6082P, 6058P) --- 3.0 - 4.0

TOLYL TRIAZOLE 29385-43-1 < 0.5

4 FIRST AID MEASURES

EYE CONTACT

Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention.

SKIN CONTACT

Flush skin with large amounts of water. If irritation persists, contact a doctor.

INHALATION

If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, seek medical attention.

IF SWALLOWED

If swallowed, give two glasses of water and contact a doctor or Poisons Information Centre.

Do NOT induce vomiting.

5 FIRE FIGHTING MEASURES

SUITABLE EXTINGUISHING MEDIA

Product is a fire-extinguishing agent.

FIRE FIGHTING PROCEDURES

Wear full protective clothing, including helmet, self-contained, positive pressure or positive pressure demand self-contained breathing apparatus, tunic and pants, bands around arms, waist and legs, full face-piece, and protective covering for exposed areas of the head.

SOLBERG FIRE-BRAKE 3150A CLASS A FIRE FIGHTING FOAM Page 3 of 8

COMBUSTION PRODUCTS FROM FIRE

Combustion Products from Fire are listed in Section 10, STABILITY AND REACTIVITY.

6 ACCIDENTAL RELEASE MEASURES (SPILL)

Personal Precautions

Observe precautions from other sections of this Material Safety Data

Sheet.

Spill Response

Ventilate area with fresh air. Cover with absorbent material. Collect as much of the spilled material as possible. Clean up residue with water. Place in an approved metal container. Seal the container.

7 HANDLING AND STORAGE

Precautions for Safe Handling

Keep container tightly closed when not in use. No smoking: Smoking while using this product can result in contamination of the tobacco and/or smoke and lead to the formation of the hazardous decomposition products mentioned in Section 10 of this MSDS.

Conditions for Safe Storage

Do not store containers on their sides. Store at room temperature.

Keep container closed when not in use.

Incompatibility - Materials to Avoid

None known.

EXPLOSION AVOIDANCE

Non flammable: ordinary combustible material.

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Special Information, Exposure/Protection

The extent to which the following recommendations for exposure control and protection are observed should depend on the risk assessment undertaken for the specific conditions under which this product is used, including occupational hygiene measurements.

SOLBERG FIRE-BRAKE 3150A CLASS A FIRE FIGHTING FOAM Page 4 of 8

Recommended Ventilation

Provide sufficient ventilation to maintain emissions well below exposure standards. If exhaust ventilation is not available, use appropriate respiratory protection.

Eye Protection

Avoid eye contact with vapour, spray, or mist. During operations in which eye exposure is likely, the following should be worn alone, or in combination, as appropriate: Vented goggles. Full-face shield. Eye protection should comply with AS/NZS1337.

Hand Protection

During operations in which hand exposure is likely, wear appropriate gloves. Gloves made from one of the following material(s) are recommended: Butyl rubber.

Skin Protection

Avoid skin contact.

Respiratory Protection

Avoid breathing vapours, mists or spray.

Prevention of Accidental Ingestion

As a precaution against accidental ingestion, wash hands after handling and before eating. Do not ingest.

SOLBERG FIRE-BRAKE 3150A CLASS A FIRE FIGHTING FOAM Page 5 of 8

9 PHYSICAL/CHEMICAL PROPERTIES

Appearance and Odour Clear, light yellow liquid pH 7 -9

Vapour pressure 118 mmHg @ 55C

Vapour density 1 (Air=1)

Boiling point 100 C (Typical)

Melting point Not applicable

Water Solubility Complete

Specific gravity Approx.1 (Water=1)

Flash point None

Flammable Limits - LEL Not applicable

Flammable Limits - UEL Not applicable

Autoignition temperature Not applicable

Volatile organic compounds (VOC) 95 g/L (g/L of material) content

Evaporation rate Not determined

Viscosity Not determined

10 STABILITY AND REACTIVITY

Stability

Stable. Hazardous polymerisation will not occur.

Materials to Avoid

Not applicable

SOLBERG FIRE-BRAKE 3150A CLASS A FIRE FIGHTING FOAM Page 6 of 8

Hazardous Decomposition Products

Carbon Monoxide, Carbon Dioxide. Oxides of Sulfur. Hydrogen Chloride.

Amine Compounds.

11 TOXICOLOGICAL INFORMATION

Effects from Eye Contact

Moderate Eye irritation: Signs/symptoms can include redness, swelling, pain, tearing and blurred or hazy vision.

Effects from Skin Contact

May cause mild skin irritation (more likely after prolonged or repeated contact). Signs/symptoms can include redness, swelling and itching. May be absorbed through the skin and produce effects similiar to those caused by inhalation and/or ingestion.

Effects from Inhalation

Inhalation may cause: Upper Respiratory Tract Irritation:

Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.

Effects from Ingestion

Ingestion is unlikely to be a route of exposure. Ingestion may cause:

Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting.

Other Toxicological Information

A Solberg Product Toxicity Summary Sheet is available.

12 ECOLOGICAL INFORMATION

Environmental Data

Not determined

13 DISPOSAL CONSIDERATIONS

Disposal methods

Slowly discharge spent solutions and small quantities (less than 20L) to a wastewater treatment system. Reduce discharge rate if foaming occurs. Large quantities can be treated by a waste water treatment system if added slowly over several days (or longer). Alternatively, incinerate large quantities in an industrial or commercial incinerator.

SOLBERG FIRE-BRAKE 3150A CLASS A FIRE FIGHTING FOAM Page 7 of 8

14 TRANSPORT INFORMATION

ADG (Road/Rail)

UN NUMBER NONE ALLOCATED

PROPER SHIPPING NAME NONE ALLOCATED

DANGEROUS GOODS CLASS NONE ALLOCATED

SUBSIDIARY RISK NONE ALLOCATED

PACKING GROUP NONE ALLOCATED

IATA (Airfreight)

IMO (Seafreight)

SOLBERG FIRE-BRAKE…