MSDS-LIME-A-WAY_EXTRA-engl..pdf

Identification of product and company

SAFETY DATA SHEET

LIME-A-WAY EXTRA

Conforms to 91/155/EEC - 2001/58/EC - Germany

1.

Identification of the substance or preparation

LIME-A-WAY EXTRAProduct name :

Company/undertaking identification

: Delimer Product is for professional use only

Product use

Supplier : Ecolab Deutschland GmbH Reisholzer Werftstrasse 38-42 Postfach 13 04 06 DE-40554 Düsseldorf Germany Tel +49 (0)211 9893 0 Fax +49 (0)211 9893 384 Notfall-Tel.Nr.: 0211 797 3350

Date of issue :26 July 2005Version :6103223ECode :

anti-poison centre : 030 19240 (Beratungsstelle für Vergiftungserscheinungen - Berlin)

Composition/information on ingredients2.

Substance/preparation Preparation

* Occupational Exposure Limit(s), if available, are listed in Section 8

EINECS % ClassificationIngredient name

See section 16 for the full text of the R Phrases declared above

Phosphoric acid 231-633-2 7664-38-2 30 - 50 C; R34 Alkylethoxy-propoxylates Polymer. 1 - 2 Xi; R38

N; R50

CAS

<5% non-ionic surfactants

Ingredient declaration according to detergent regulation 648/2004/EC:

Hazards identification3.

Classification C; R34:

The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.

:Human health hazards Causes burns.

See section 11 for more detailed information on health effects and symptoms.

Do NOT induce vomiting unless directed to do so by medical personnel. If swallowed, rinse mouth with water (only if the person is conscious).

Skin Contact In case of contact, immediately flush skin copiously with water for at least 15 minutes while removing contaminated clothing and shoes. Obtain medical attention immediately.

4.

First aid measures

If inhaled, remove to fresh air. In all cases of doubt, or when symptoms persist, seek medical attention.

Ingestion

Inhalation :

First aid measures

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LIME-A-WAY EXTRA

In case of contact with eyes, rinse immediately with a copious amount of water. Obtain medical attention immediately

Eye contact :

Specific treatments Not available.:

See section 11 for more detailed information on health effects and symptoms.

Fire-fighting measures5.

Hazardous thermal decomposition products

These products are phosphates.

Fire-fighters should wear proper protective equipment.Special protective equipment for fire-fighters

In case of fire, use water spray (fog), foam, dry chemical, or CO2.Extinguishing media :

Environmental precautions and clean-up methods

Personal Precautions

SMALL SPILL Rinse with plenty of running water. For large spills dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal

6. Accidental release measures

Note: see section 8 for personal protective equipment and section 13 for waste disposal.

: Large spill and leak Immediately contact safety personnel.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Handling

Handling and storage

Storage

7.

Do not get in eyes, on skin or on clothing. Do not breathe vapour or mist.

After handling, always wash hands thoroughly with soap and water. Handle and open container with care.

Packaging materials Use original container.

Keep container tightly closed. Keep away from food, drink and animal feeding stuffs. Keep only in the original container.

Recommended 8B:Storage code

Store between 10 and 30°C

Ingredient name Occupational exposure limits Phosphoric acid TRGS900 MAK (Germany, 9/2003).

Spitzenbegrenzung: 2 mg/m3 15 minute(s). Form: All forms TWA: 1 mg/m3 8 hour(s). Form: All forms

8. Exposure controls/personal protection

Hand protection

(EN 374)

Exposure controls

A respirator is not needed under normal and intended conditions of product use.

1 - 4 hours: butyl rubber, nitrile rubber

Safety glasses.Goggles, face shield, or other full-face protection.Eye protection

(EN 166)

Respiratory protection

(EN 143, 141)

If workers are exposed to concentrations above the exposure limit they must use appropriate, certified respirators.

Occupational exposure controls

Skin protection

(EN 467)

safety apron Suitable protective footwear.:

Physical and chemical properties

Physical state Liquid.

Odourless.Odour Green. (Light.)Colour

9.

General information Appearance

Important health, safety and environmental information

Date of issue : 26 July 2005 Page: 2/4

Not available.

Melting point Boiling point

Vapour pressure Relative density

Vapour density

Solubility

Not available.

1.228 g/cm3 (20 °C)

Not available.

Not applicable.

Easily soluble in cold water, hot water.

pH

Evaporation rate (butyl acetate = 1)

Not applicable.

Flash point > 100°C

Not applicable.

Not applicable.

Not applicable.Flammability (solid, gas)

Not applicable.

1.8 (100%)

Viscosity Not available.

Octanol/water partition coefficient

Explosion Limits Explosive properties

Not available.Oxidising properties :

Hazardous Decomposition Products

Stability and reactivity

These products are phosphates.

Stability

10.

Highly reactive with organic materials, metals, alkalis.

Nonreactive with acids.

Materials to avoid :

Do not mix with other products.

Stable under normal conditions.

Toxicological information11.

No known significant effects or critical hazards.Reproductive toxicity :

Potential acute health effects Inhalation : Corrosive to the respiratory system.

Causes burns.:Ingestion Skin Contact : Corrosive to the skin.

Corrosive to eyes.:Eye contact

Ecological information12.

The surfactants contained in the product are biodegradable according to the requirements of the detergent regulation 648/2004/EC

The product is not subject to ecological classification according to directive 1999/45/EC.

Ecotoxicity

Persistence and degradability

Disposal considerations13.

Not applicable.:Waste classification 200114*European waste catalogue

(EWC)

Waste must be disposed according to applicable regulations. Use as much of the contents as possible, according to instructions. Can be added to general waste collection after completely emptying. Use packages for recycling only when totally empty

:Methods of disposal

Date of issue : 26 July 2005 Page: 3/4

ADR/RID Class

14.

International transport regulations

PHOSPHORIC ACID, LIQUID 8 III

IMDG Class PHOSPHORIC ACID, LIQUID 8 III

Transport information

8PHOSPHORIC ACID, LIQUID IIIUN1805

Regulatory information

UN number Proper shipping name Class Packing group

Label

UN1805

UN1805

ADN Class

Do not ship by air.

Regulatory information15.

Hazard symbol(s) EU Regulations

National regulations 1Hazard class for water

Safety Phrases S2- Keep out of the reach of children.

S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.

S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

R34- Causes burns.Risk Phrases Contains

: Phosphoric acid

UBA : 07791304

Corrosive

Other information16.

R34- Causes burns.

R38- Irritating to skin.

R50- Very toxic to aquatic organisms.

:Full text of R phrases referred to in sections 2 and 3 - Germany

26 July 2005 History Date of printing Date of issue Version Prepared by

26 July 2005

Version

The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE

COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION.

Notice to reader

: Ecolab Regulatory Department Europe

Page: 4/4