sds 3.pdf

tuiw Printing date 0 5/2 5 /20 I I

Safe$ Datu Sheet acc. to OSHA HCS

Page 1/8

Reviewed on 05/25/2018

I IdentiJication ' Product identiJier

'Trade name: AUTOWASH EV

'Article number: A364

' Application of the substance / the mixture Roller and Rubber Blanket Cleaner

' Details ofthe supplier ofthe safeE, data sheet ' Manufoctu rer/S upplier :

Printers' Setyice, Inc.

26 Blanchard Street Newark, NJ 07 I 05

USA

' Information department: 1-973-589-7800, Prisco email address - safety@prisco.com ' Emergency telephone number: CHEMTREC (24 hr) l-800-424-9300

2 HaTard(s) identification ' Classification of lhe substance or mixlure

9"^-" Flam. Liq. 2 H225 Highlyflammable liquid and vapor

@u",uoo**o Muta. lB H340 May cause genetic defects.

Carc. IB H350 May cause cancer.

Asp. Tox. 1 H304 May befatal dswallowed and enters airways.

o Skin lrril. 2 H315 Causes skin irritation.

Eye lrrit. 2A H319 Causes serious eye irritation.

STOT SE i H336 May cause drowsiness or dizziness.

' Label elements ' GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).

' Hazard pictograms

90@

GHSO2 GHSOT GHSO8

'Signal word Danger

' Hazsrd-determining components of labeling:

a I ip hat ic p e t ro leum dis til late (C6-9) acetone

' Hszard stotements HighlyJlammable liquid and vapor.

Causes skin irritation.

Causes serious eye irritation, May cause genetic defects.

May cause cancer.

Mav causc drowsiness or dizziness.

May be.fatal if swallowed and enters airways.

' Precautionary slatements Obtain special inslntctiont before u.se.

Do not handle until all sofety precoutions have been read and untlerstood.

Keep awayfrom heathparks/open.fiames/hot surfdces. - No smoking.

Ground/bond contoiner and receiving equipmenl.

U s e exp lo s io n-p r o of el e c tri c al/v entil ati ng/l i ght i ng/e q u ip me n t.

Use only non-sparking tools.

Take precautionary measures against static discharge.

Av o i d b reat hi n g d us t/fum e / gas / mi s t /vap o rs /s p r ay lV'ash thoroughly after handling.

Use only outdoors or in a well-ventilated area.

llear protective gloves/protective clothing/eye protection/face protection.

If swallowed: Immediately call a poison center/doctor.

Specilic tredtment (see on this label).

Do NOT induce vomiting.

If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.

(Contd. on page 2)

Safety Data Sheet acc. to OSHA HCS

Printing date 0 5/2 5/20 I I

Trade name: AUTOTYASH EV

4 First-aid measures ' Description oflirst aid measures ' After inhalation: In case of unconsciousness place patient stably in side position for transportation.

' After skin contact: Immediately yiot1, with water and soap and rinse thoroughly.

'Aflet eye contdct:

Rinse opened eyefor several minules under runningwater. Ifsymptoms persist, consult a doctor.

' After swallowing: If symptoms persist consult doctor.

' Information for doctor:

' Most importanl symploms and effecls, bolh acute antl delayed No further relevant information available.

' Indication of any immediate medical uttention and special treatment needed No further relevant information available.

5 Fire-Jighting measures 'Ertinguishing medio ' Suitable extinguishing agents :

C-O2, extinguishing powder or water spra)). Fight larger fires with water sprdy or alcohol resistant foam.

' Special hazards arising from the subslance or mklure No further relevant information available.

' Advice for tiretighters ' Protective equipment:

Mout h res p i rato ry p rotective devic e.

l4lear self-conlainecl respiratory protective device.

dentsl release measures nal precaulions, protective equipment and emergenqt procedures protective equipment, Keep unprotected persons away.

onuental precautions:

nt seepage into sewage system, workpits and cellars.

Page 2/8

Reviewed on 05/25/2018

IF INHALED: Remove person tofi.esh air and keep comfortablefor breathing.

(contd ofpage l)

Ifin eyes: Rinse cautiously with water for several minutes. Remove contu7t lenses, ifpresent and easy to do.

Continue rinsing.

IF exposed or concerned: Get medical advice/attenlion.

Call a poison center/doctor ifyoufeel unwell.

Take olfcontaminated clothing and wash it before reuse.

Ifskin irritation occurs: Get medical advice/attention.

If eye irritation persists: Get medical advice/attention.

In case offire: Use for extinction: CO2, powder or foam.

Store in a well-ventilated place. Keep container tightly closed.

Store in a well-ventilated place. Keep cool.

Store locked up.

Dispose ofcontenls/container in accordance with local/regional/ndtional/international regtilations.

' Classijication system:

' NFPA ratings (scale 0 - 4)

,6 ' HMlS-ratings (scale 0 - 4)

'Other ha6ards ' Results of PBT and vPvB assessment ' PBT: Not applicable.

.vPvB: Not applicable.

3 Composition/information on ingredients ' Chemical characterization: Mirtures ' Description: Mixture ofthe substances listed below with nonhazardous additions.

' Dangerous comDonents: _ CAS: 64742-89-8 aliphatic petroleum distillate (C6-9) 50_70%

CAS:67-64-| acetone 30-50%

RTECS: AL 3150000

CAS: 34590-94-8 dipropylene glyco! monomethyl ether 10_30%

RTECS: JM 1575000

' Additional information: For the wording of the listed hazard phrases reler to section I 6.

6 Accidentsl rt ' Personal precat

Wear protective ,Environuental Prevent seeoast

S&fety Dstq Slreet acc. to ASHA IflCS

Printiry; da te 0 5/2 5 /20 I 8

D il ute with plen4t of water.

Do not allow lo enler sewers/ surface or grourtd waler.

' Methotls and muterial for contaifinrcnt and cleaning up:

Absorb with liquid-binding nnterial (sand, diatomite, acid binders retnoval conlainers

Reviewed on 05/25/20i8 universal binders, sawdusl) and place inlo

Dispose contaminated mdterial as waste accor.ding to item 13.

Ensure ad equ al e vcn t ilat i on.

' Reference lo other sections

See Section 7.for infurmation on safe handling.

See Section 8 for information on personal prolection equipment.

See Section I 3 for disposal inforntation.

' Prokcrtve Action Criteria for Cheniculs

.PAC-|:

All ingredients are listed

PAC-2:

All ingredients are listed.

,PAC.3:

All ingredients are listed.

7 llandling and storage

'handling:

' Precautionsfor safe handling Store in cool, dty place in tiglxtly closed receptacles.

Ensu'e good ventilation/exhaustion at lhe worlqlace.

' Information about protection against explosions and fires:

Keep ignition sources dway - Do not smoke.

Prolect against electrostatic charges.

' Conditions for safe storage, including any inconrpatibilities 'Storage:

' Requirenenls to be met by storeroons and receptacles: Store in a cool location.

' Information obout storoge in one coilrn on storagefacility: Not required.

' Further informalion about storage conditions:

Keep receptacle tightly sealed.

Store in cool, dry conditions in well sealed receptacles.

'Specific end use(s) Nofurlher relevan! inftrmalion available.

8 Expos ure co ntro Is/pers o nal protectio n 'Additional infornrstion about design oftechnical systents: No.further data; see itent 7.

' Conlrol parameters ' Components with limit valaes tltat require nronitoring at the workplace:

The following constituents are the only constituents of the product which have a PEL, TLV or other recomnrcnded exposure limit, At this time, the remaining cohstituent hds no htown exposure limits.

67-64-1 acetone

PEL Long-term value: 2400 mg/m3, ) 000 ppm

REL Long-termvalue: 590 mg/m3,250 ppm

TLV Short-term value: I 187 mg/mt, 500 ppm Long-term value: 594 ntg/m3, 250 ppnt

BEI

34590-94-8 dipropylene glycol monomethyl ether

PEL Long-term value: 600 mg/m3, I 00 ppm Skin kEL Short-term value: 900 ntg/mt, 150 ppm Long-lerm value: 600 mg/m3, I 00 ppm Skin

TLV Short-term value: 909 mghn3, 150 ppm Lortg-tenn value: 606 mghn3, I 00 ppm

'Skin . Insredients with biolosical lintit values:

67-64-I acetone

BEI 50 mg/L

.' Mediitnt: itrine . Tim.e:'end of shift

Ssktl,Da-ta Sheet tucc. to ASI{A f{CS

FIuid Clear Characteristic Not determined.

Not determined.

Not Applicable 56 "C (t 33 .F)

-20.c (-4 .F)

Not applicable.

270 "C (s I I "F)

Not irtformation available

Product is not selfrgniting.

In use, may form Jlammable/explosive vapour-air mixttu.e

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Trade norne: AUTOWASXI EV

. (Contd. ofpage 3)

; Exposure controls

' General protective and h1'gienic measurcs:

Ke e p aw at, fr o nt fo o ds tuJfs, b ev e r a g es a n d fc e d.

Iruntediately remove all soiled and contaminated clothing.

Wash hands beft;re breaks and at the ettd ofwork.

Store protective clothing separately.

Avoid contact with the eyes and skin.

'Bteathing equipment:

In cas_e of intensive or longer exposure Ltse respit"atorv protective device lhal is independent of cit culating air.

Suitable respiratot? protective device recommended, btfi not necessat-v ifroont is will-ventilited.

' Prolection of hands:

'The glove m-aterial has to be impermeable and resistant to lhe product/ the substantce/ the preparariott.

' fi{aterial ofgloves " To find the recommended glove material to use when handing Prisco@ pressrdom chemisttl, we advise to visit tlwv'.prisco.conr. Choose location & preferred language and go to the "SLt1:port" drop-dou'n box v,l.tere ),otr select: "SafetvGloveRecomntendation".Nov'clickonthePDF-ht,perlinktoobtainthedicuntentinrhelangtiage ofyour preference.

The selection ofthe suitable gloves does not ortllt depend on lhe.material, buf also on.further nru.rks o.[qualih, and variesfrom ntarutfacturer to tflanufaclurer. As the prodtLct is o preparation ofseveral strbstances, tie resiirance ofthe glove material cannot be calculated in advance and ltas therefore to be checlced prior to the application.

' Penetration time olglove material The exact breakthrough tinre has to befound out by the.nnntrfacturer ofthe protective gloves a.nd ltas to be observed.

' EJ)e protection:

Tigiztiy seaieci goggies

9 Physical and chemical properties ' Information on basic physical and chemical properties ' General Informatiort 'Appearance:

Form:

Color:

'Odor:

' Odor threshold:

'pW-value:

' Change in conditiott Melti n g po i nt/M elti n g ra ng e :

B o ilin g p o int/B o ilin g ra n g e :

' Flash point:

' Flanutability (solid, gaseous):

. Ignition lempersturc:

' D e co mp o s iti o n tenrp erdture :

'Auto igniting:

' Danger of explosion:

' Explosion linits:

Lower:

Upper:

' Vapor pressure at 2A "C g8 oF):

' Densiq, at 20 oC (68 "F):

' Relative dens.itS, ' Vopbr density ' Evaporation rate

Solubility in / Miscibility with

0.9 Yol %

l4 Yol%

2ii hPa (174.8 mm Hg)

0.78 g/cntr (6.51 lbs/gol) Not delermined.

Not deternined.

No/ deterntined.

SoIuble.

Noi determined o

P artitioyt co eff cient Qt-octat oU*,ater) :

"""."."..-.-..,..'i".".-...,!.],.|lunlLc;.,.l\olaLl€rbi'|c(.,."."......:".....i-.wl ." .1,., ..-.Dt,rtrittti

Pri nting date 0 5/2 5 /20 I I

Ssfety Ds.ta Slteet acc. to OSHA ItrCS

. Page 5/B

Reviewed on 05/25/2018

Trade name: ,AUTOWASI{ EV

' Other information No fur th er r el et,an I info rnt a tio n aiail a b le.

(Contd. ofpage 4)

10 Stabili4t and reactivity . Reactivity Avoi.d stt"ong oxidizing agents, strong bases ;txcl strong ocids.

' Chcmical stability Stable uuder normal conditiorrs 'Thermal deconrposition / conilitions to be avoitled: No decomposition ifused according to specifrcations.

' Possibility of lmzardous reactiotts No dangerous reactions known.

' Conditions to avoid No further relevant information available.

' Incompatible materials: No.further relevant informatiotl availa ble.

' Hazardous decomposition products: Carbon motoxide and carbon dioxide

I I Toxicological informati.on ' Itforma$on on toxicological effects ,Acute toxicity:

' Primary irritant effect:

' on the skin: lrritant lo skin and mucous membranes.

' on the q)e: h'ritating effect.

' Sensitization: No sensitizing effects. lotown.

' A dditi on al toxic o logica I i nfonn uti o n :

The product shows thefollowing dangers according to internally approved calculation methods for preparatiohs:

Product nny cause in'itation.

The product can cause inheritable datnage.

' Carcinogenic categories ' IARC (International Agency for'Research on Cancer)

None ofthe ingredients is listed.

' NTP (Ngtional Toxicologv Program) None ofthe ingredients is listed.

' OSHA-Ca (Occupational Safety & Health Adnrinistrationt Noneof theingredientsislistei.

I 2 E c o I o gic a I inform atio n 'Toxici$ ' A q u atic to xic ity : N o fu r th e r r elev a nt i nfo r mat i o n av a il ab le.

' Persistence and degradability No further relevant information available.

. Behavior in environmental systems:

' Bioaccunulative potential No furlier relevant infornation available.

' Mobilily in soil No.further relet ant information available.

' . Additional ecological information:

' General notes:

lVater hazard class ) (Self-assessntent): slightly hazardous for utater Do nol allow undihrted product or large qudntities of it to reach ground water, water course or sewage system.

. Results of PBT and vPvB dssessment ' PBT: Not applicable.

' r,PvB: Not applicable.

' Other adverse effects No,/iulher relevant idornution available.

I 3 Disposal considerotion s ' Wasle treatfienl nelhods ' Recommendation:

Product must not be disposed oftogelher with household refuse. Do not allow product to reach sewage systen.

' Uncleaned packagings:

' Recommendation: Disposal must be made according to fficial regulations.

' Recommended cleansing agenl: l|/ater, iJ'neces,saryt with cleansitlg dgents.

uNt993

. Flammable liquids, n.o'.s. (Acetone, aliphatic petroleum distiilate, (c6-e)

Printing date 0 5/2 5/24 I B

Ss"fe'qt Data Sheet qcc.,rc ASI{A IICS

Page 6,8

Ret,iewed on 05/2 5/20 I I

Trade nanie: AUTOW'ASH El/

(Contd. ofpage 5)

'Class 'Label 'Class 'Label ' Packing group

.DOT, ADR

. Environmentsl hczards:

' Special precautions for user j Flammable liquids

3 Flammable liquids il Not applicable.

lYarning: Flammable liquids

' Tlansport haiard class(es)

.DOT

"^@#bv

' Transport in bulk according to Annex II of MARPOLT|/78 and the IBC Code Not applicable.

DOT

.Quantity linitations

' Excepted quantities (EQ)

' Limited quantities (LQ) ' Excepted quantities (EQ)

' UN "Model R.egulatiott":

"On passenger aircrafth"ail: 5 L

On cargo aircraft only: 60 L Code: E2 Maximum net quantity per inner paclcaging: 30 nl Maximum net quantiy'per outer packaging: 500 ml

IL

. Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml

UN 1993 FLAMMABLE LIQUIDS, N.O.S. (ACETONE, ALIPHATIC

PETROLEUM DISTILLATE (C6-9)

), 3, II

o

I 5 Re g ulato ry info rm atio n ' Safety' health and environmental regulations/legislation specilic for the substance or mixture 'Sara ' Section 3 5 5 (extremely hazardoas substanceil :

None ofthe ingredient is listed.

'Section 313 (Specific toxic chemical listings):

None ofthe ingreCients is listed.

' TSC4 (Toxic Substances Contol Act): _ All ingredients are listed.

,THE SECTION BELAW IS APPLICABLE ONLY TO TI{E END.USERS LOCATED IN CALIFORNIA

'Catifurnia Propo llarning: This product contains a chenrical known to the State of Califurnia to cause bit.th defects or other reproductive harm.

lllarning: Tltis product contains a chemical l*town to the Stale of Catifornia to cause cdncer.

' California Proposition 65 chemicals known to cause cancer:

100-41-4 etl4tlfissur"

7 I -4i-2 benzene

91-20-3 naphthalene California Proposition 65 chenicals knov,n to cause reproductitte toxicituJor Jqlrrlgll None Califomia Proposition 65 chenicals knoh'n to cause reprod.uctive toxicii,- for males:

7 I -43-2 benzene California Proposition 65 chenicols krtou'n to cause dcvelopmcfltal toxicitl:

I 0B-88-3 toluene

7 I-43-2 benzene

Can cerogenity catego ries EPA (EnvironMentsl Protection Agenc.

None ofthe ingredients is listed.

TLV (Threshold Lirnit l/alue cstablished by .ACGIH)

None ofthe ingredients is listed.

lttIOSH-Ca (National In stitute.for O ccuitoti b n al.S afefi. an d H e alth )

Ncne ofthe ifigredienrs is'listed , GHS label elenrents Tlrc proCuct is classillieci ard"i.abaied :iceoiding to tk Clobcli; Harntoni:ci S)'stLlrl: (CHS!: . i

{Contd. on nase'lf ',(F:J ---_=---:--;-=-:-- i :i.

o ia

Printing date 05/2 5/2 0 I 8

Sefet), Data Skeet acc. to OSIIA I{CS

Page 7/B ll

Reviewed on 05/25/2018

Trade nante: AUTOWASII EY l6 Other information This infornntion is based on our pr\sent knowledge. However, this shall nol conslitute a guarantee for any specifc product featt)res and shall not establish a legally valid conlractual relationship.

o

GHSOS

(Contd. ofpage 6)

' Hax,ard pictogranrs ss

GHSO2. GHSOT

'Signal word Danger

. H azard-det er m in i n g co mp o ne nt s of label i n g :

aliphatic petroleum distillate (C6-9) acetone

' Hazard stotements Highty /tammabte liquid and vapoi.

Causes slti.n irritation.

Causes serious qte irritation.

May cause genetic defects.

May cause cancer.

May cause drowsiness or dizziness.

May befotal if swallowed and enters ait\)ovs.

' P r ecauti on ary itateh t e nts Obtain special instructions before use.

Do not handle wxil all safely precdulions have been read and understood.

Keep away{ront heat/sparl<s/openflames/hot surfaces. - No smoking.

Grourrd/bond container and recefuing equipment.

U s e exp lo s io tt- p r o of e I ec u" i c a I /v enti I atin g,4 i ghtin g/e q ui pm en t.

Use only non-sparking tools.

Take precautionar), measures against slatic discharge.

Avo id b r eathing dus t/fume/gas /mis tA,ap ors /spr ay Wash tlnroughly aJter hondling.

Use only outdoors or in a well-ventilated area.

lI/ear protebtive gloves/protective clothing/eye protection/face protection.

If swallowed: Immediately call a poison center/doclor.

SpeciJic trehtntent (see on this label).

with water/shoier.

lenses, ifpresent and easy to do.

Continue rinsing.

IF exposed or ioncerned: Get ntedical advice/attention.

Call a poison center/doctor if you feel uwell.

Take off contantinated clothing and wash it before reuse.

If skin irritation occurs: Gel medicaL advice/attention.

If elte irritation persists : Get medical advice/attenlion.

In case offire: Use.[or extinction: CO2, powder orfoam.

Store in a well-ventilated place. Keep container tightly closed.

Store in a well-ventilated place. Keep cool.

Store locked up.

Dispose of contents/container in accordance with local/regional/national/international regulations.

' N ation a I regulations :

' Additionol classiJication according to Decree on Hazardous Materials:

Carcinogenic hazardous material group III (dangerous).

' Information about limitation of use:

l{orkers are not allowed to be exposed to the hazardous carcinogenic materials conlained in this preparation Exceptions can be made by lhe authorities in certdin cases.

. Vl/ater hazard class: lI/ater ltazard class I (Self-assessment): slightly ltazardous for water.

. Chemical safety assessmZnt: A Chemical Safety Assessnrcnt hai not been carriid out.

Do NOT induce vomiting.

If on skin (or hair): Take of.f immediately all contaminated clothing. Rinse skin IF INHALED: Rentove person to fresh air and keep comfortable for breatlzing.

If in eyes: Rinse cautiously with water for several minules. Remove contact

Printing dote 0 5/2 5/20 I 8

I/OC. Volatile Organic Conpounds (USA, EU) PBT: Persisteht, Bioaccumulatiye and Toxic

CAS: Chcmical Abstrdcts Scrvice (d.ivision of thc Arncrican Chcnicql Socictt) NFP/: National Fit.e Protection Associotion (USI) HMIST Hazonlous Muterials ldehti/icotiott g,ten (USA)

Safe1'Data Skeet icc. * ASI-[A. I-XCS

Page 8/B

(Contd. ofpage 7)

|PtB : veD' Persistent otd tery Bioaccunulutive NICSH. Nationol lt6titfie for Occufotional Salety OSHA. Occupational Safetl' & Health TLY: Thrcshold Liuil l/qlue PEL: Pemissible Exposure Limil REL: Recommended Etposure Limit BEI: Biological Exposurc Limit Flan. Liq. 2: Flamnable liquids - Coregorl,2 Skin lrrit. 2: Skh corrosion/irritation - Category 2 Eye lrrit. 2A: Seriotrs cye danagc/eye irritatio, - Catego\v 2A Muta. lB: Gem cell nutogeniciq,- Category lB Carc. lB: Carcinogeilcity - Category lB

.STOT SE 3: Specifc target organ toxicitt'(single exposwe) - CdtegoD,3 Asp. Tox. l: Aspiration hazard - Categon, I

. * Data corrrpared to the Wevious version sltered..

Ret,iey,ed on 05i2 5/2() I 8