sds 2.pdf

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Product Nemo: DENSE BLACK

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DAT PREPARED : 201519117

SAFETY DATA SHEET

1 PRODUCTAND COMPANY

Product Name Product Use

Manufactured/Di$tributed by

Address Telephone Fax i

I

DENSE BLACK

Sheet-fed offsot printing ink

TOKYO PRINTING INK CORP. USA

2895 Temple Ave., Signal Hill, CA 90755

1562) 424-2226 (562:) 424-2216

2. HAZARDS IDENTIFICA

UN Hazard Classification HAZARD CL,CSS : Not Appticabte UNNA NUMBER. I Not Applicable

GllS Classification* I

Plrysical Flanrmable Liquid -

Health Acute Toxicity (oral)) ^

Acute Toxicity (inhalation) - Eye Corrosion (seilous damage/irritation) -

Skin Corroslon -

Skin Sensitization - Respiratory sensitizer -

Mutagenicity - Aspiration Hazard -

Carcinogenlcity -

Reproductive Toxicity Target Organ Toxicity,(single exposure ) -

Target Organ Toxicity (repeated exposure ) - Envlronmental

Aquatic' Toxicity (acute) - Aquatic Toxicity (chronic) -

Elements azard Code H332 lHarmful if inhaled (mist)

H320 lCauses eye irritation.

H317 lMay cause allerglc skin reaction.

H335 lMey cause respiratory irritation.

Not classified

Not classified Category 4 Category 28 Category 2 Category 1

Not classified Not classified Not elasslfied Not classified Not classified Category 2 Category 2

Not classified Not classified

GHSOT

(h Waming

F1371 lMay cau,qe damage to lungs,.

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Producl Name: DENSE BLACK

PAGE i:,, Page:20f7 DATA PREFARED ; ?.D1St9t1T mmary

Preventjon Code

P201 P202 P260 P264 P270 P27?

P280 PZBl

P302+P352

Avoid breatlring niist *Wear suitable protecflve ctothing and gtoves, After lrandle this product, wash l'rands irnrnediaiely and gargle suffilienfly-rReao weit $afety Data Sheets (SDS) before lrandlhrg rtf you fee-t unweil or aitergy, seek medlcal advice immediately, 308+P31 3

P314

Obtain special instructions before use.

Do not handle until all safety precautions have been read and understood.

Do not breathe d ustlfu m e/gas/mist/vapor$/spray Wash thoroughly after handling.

Do not eat, drink or smoke when using this product.

contaminated work clothing should not be allowed out of the workplace.

Wear protective gioves/protective clothing/eye protectionlface pfotection Use personal protective equipment as required.

lF ON SKIN:Wash with plenty of soap and w6ter.

lF exposed or concerned; Get medical adviceiattention.

Doctor/physiciun.

Get medical advice/attention if you feel r"rnwell.

Specific.treatment (see Prevention on this label), Wash contaminated clothlng before reuse.

Store locl<ed up, Dispose of contents/container in accordance with local, stato and federal regulation.

P321 rJtJS P405 P501

Other Precautionary Statements Keep away from heaVsparkslopen flame. _ No smoking.

Use only in a woll-vontilated area" Store container tighfly closed in cool/\ruell_ventilated plaee.

Sulrstances presenting a lrealth or environmental hazard witlrin the meaning of Regulation (EC) No 127212008 and Directive 67/548/EEC.

EYE CoNTACT : ltr case of eye irritation, flush immediately with clean & large amounts of water for atleast l Sminutqs.' Eyelids, should be held 6way from tlre eye'balt to ensure thor:ough rinsing. cei imnrediate meijical attentiorr.

sKlN C0NTACT : 1155;pn or burning of the skin, lmmedidtely fluslr the skin with plenty of water whileremovirrg contaminated clothing and shoes, Wash skin thoiouglrly *itn ,if O soap Z water, -6et " irnmediate medical attentiorr. wash contaminated clothing tr.f;u'reui..

coMPostTloN

Rosin modified phenolic resin Soybean oil m hydrocarbon Pigment (Black: Carbon black)

70955-45-2 20 - 30 8001.22-7 20 - 30 64742-48-7 15.25 1333-80-4 20 -2s 132+76-1 3 ^ 5

(-) For tull text of Products EU CLp & DSD see section 1b

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PTOduct NEme: DENSE BI.ACK

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I FVL

Page : s ofl DATA PREPARED | 2015ts117

INHALATION : Remove person to fresh air. lf respiratory irritation, dlzziness, nausea , or uncorlsciousness occurs, $6ek immediate medicai assisiance, lf breathing has stoppecl, give arttficlal respiration.

INGESTIoN : Got immediate medical attention. Do not incluce vomiting unless directed by medical personnol.

I s, F|RE-FTGHTTNG MqAS.URES ,. I sultable Extinguish Meclia : Use dry chernical, carbon dioxide, or foam to extinguish fire, Water may be ineffective but should be used spray/fog for cooling and suffocating. Use water tj oitute spills and to flush them away from sources of ignition.

Special Fire Fighting Procedures : Exposed flreflghters must wear proper protective equipment and positive pressure self'contained breathing apparatus with full face mask, Do not inhale combustion gases.

HAZARDOUS DECONPOSITION PRODUCTS ; products of combustion are hazardous includlng carbon monoxide and Carbon dioxide.

GENERAL : 'Consult atr expert on the disposal of recovered material. Ensure disposal in compliance wlth government requirements and ensure conformity to local dispo$al regulations.

'Notify the appropriate authorities immediately. Take all additional actlon nece-qsary to prevent and remedy the adverse effects of the spill.

LAND SPILL ; Vapor protective clothing should be worn for and leaks. Shut off ignition sollrces; no flares, smol<ing or flames in hazard area. Keep putrlic away. Take up with sand oiother noncombustible absorbent materlal and place into containers for later disposal. Prevent additional discharge of product if possible to do so without hazard

WATER SPTLL : Remove frorn surface by skirnming or with suitable absorbents. Do not flush to sewer or wateMays. Prevent release to the environment if fiossible, Handling Avoid contact with eyes. Av.oid prolonged repeated s[<in contact and breathing mists/vapors, Use only with adequate ventilation. Use good hygiene practices. Wash hands betore eiting, drlnking, smotdng, Renrove contarninated cloflring and clean befgle. re-usg: Keep away from heat and flame.

-*eep opeiating temperatures below ignition temperatures at ell times. Use non.spaiking tools.

Storage STOMGE TEMPERATURE (min, /max, ) ; 59"F (1S'C) / B6"F (g0'C) AVERAGE SHELF LIFE : z years at ss"F (,1S")

SPECIAL SENSITTVITY r Heat. Air (Oxigen)

Risk of rapid polymeriza{ion ,/ possibly rupturing cgntainer by fire, high heat sources, ralsing temperature, Siore ln tightly closed containers in cool, dry, well-ventilated area away from heat, sources of ignltion and incompatlbles' Ground lines_and equipment used during transfer to reduce the possibiliiy of static spark-initiated fire or explosion, Store in ambient or lowerJemperature. Store out of direct suntigf,t.

Protect against physical darrage, S3/52/2017 03:59 4105251322 PAGE :

Product Name; DEN.SE BLACK PeE€:40(7 DATA PREPARED : 2015t9117

Exposure Llmits n/e - none established

OSHA Hazardous by definition of Hazard Communicatjon Standard (29 CFR 19'10,1200) :

Carbon black is considered hazarclot-ts ingredient (List on "Table 21" )

ACGIH : Petroleum hydrocarbon (as oil mist) TLV; $prg/p'13 as TWA IACGIH2004], Carbon black TLV ;

3.5m9/rn3 as TWA & 44 (not classifiable as a human carcinogen)[AcclH2004j.

Engineering Cohtrols \/ENTILATION : Local exhaust ventilation mey be necessary to control alr contaminants to their Exposure llmits. The use of local ventilation is recommended to control emissions neer the source.

Provide mechanical ventilation for conflned spaces, Use explosiorr-proof ventilation equipment.

PERSONAL PROTECTIVE EOUIPMENT (PPE)

Wear chemical safety spla$h-proof goggles for eye protection and face shield, Avoid skin contact.

Wear impervious gloves for skin protection, Use NIOSH approved respirators wlren nece.t$ary, PROPERTIES

APPEARANCE : Mscous Paste VAPOR PRESSURE : No Data Available

Color ;Various Colors VAPOR OENSITY (AlR=t; : No Data Available ODOR :Mild MOLECULAR FORMULA:Mixture FLASH POINT: > 132'C /270'F MOLECULAR \ EIHGT:Mixture BOILING POINT : 270-320"C (Mineral oll) SPECIFIC GRAVITY : 0.9-1.2 at25"C / 77'F MELTING POINT : Not Applicable SoLUBILITY lN WATER : lnsolubte p H i No Daia Available

Condition to avoid : Avoid open flames, welding arcs, or other high tomperature sources whlch lnclude tlrejrmal decomposition.

lncompatibles : Oxidizing agents

Hazardous Reactions/Decomposition Products : Reacts with strong oxidizing agents, Thermal decomposition products may include oxldes of carbon and nitrogen,

1. INFORMATI

Conosive and lrritant Properties pe*oreumhvdrocarbon

3:?L:113,[lli,;;rr#ilfJ-, lnhalation LD50(rat) = 2,'1.8mgil

Cobalt compound Oral LD50 (rai) = 3900mgn(g

Petroleum Hydrocarbon

Acute Toxicity (inhalation)- Category 4 Skin Corrosion/irritation- Category 3

Eye Corrosion/irritation- Category 2B Aspiration lrazard - Category 1

Target Organ Toxtcity (following single exposr_tre ) - Category 2

Substance CAS# OSHA. ACGIH

TWA STEL TWA STEL

Petroleum hydrocarbon Carbon black

64742^46-7 1 333-86-4 nle ? 6ma/mn n/e n/e 5mg/m5, 3-5mo/mi n/e

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Product Nanret DENBE BLACK Pagc:5of7 DATA PREPARED i 2a1519117

Target Organ Toxicity (following repeated exposure )^ Category 1

Carbon Black -GHS lnfornlation

Carcinogeniclty - Category 2-' '* Classified on the basjs of evaluation as. Group 2B (Possibly carcinogenic to humans) according to IARC, printing inks are nol classifiable as to thelr carcinogenicity to humans (Group 3).

Target Organ Toxicity (following repeated exposure) - Catagory 1

Cause_s damage to lungs, Cobatt compound

$kin Sensitization - Category 1

Carcinogenicity - Category 2-' * rARC : Cob"]!-uld.:?l"po,unds are possibry carcinogenic to humans (Group 2B). But rhematerlal concerned was not classifled so th6t therE raEs the descrlptiori otirnJfu'ir inadequate evidFtLgcfor thecarcinogenicity of cobalt-,., ano cobait[g1 acetaie in experimentai animals." (4.5 Evaluation of IARC Monographs/monoSZ-iO,t1/tOtOSl other evaluations of carcinogeniclty are not applicable by EpA, EU,and NTp.

No Inforrnation available

GHS lnformation - Not classifled

Dlspose of in accordance with Federal, State and local regulations.

Empty containers must be handled with care due to product residue.

U.S. Department of Transportation (DOT) Proper SHIPPING NAME : Not applicable HAZARD CLASS : Not appticabte UNINA NO : Not applicabte Packing Group ; Not applicable Labels Required : Not applicable

The following description is transport in accordance with ADR for road, RID for rail, IMDG for sea and ICAO for alr transport.

ADR/RID/IMDG/ICAQ/IATA Class : Not applicable UN Number : Not appllcable Label : Not applicable Packing group: Not applicable Proper SHIPPING NAME ; Not appticable

(1). U,S, Federal Regulations Toxic Substances Control Act (TSCA) information Allconrponents of these products are included on the g (b) TSCA lnventory list.

super-fund Amendments and Reauthorization Act (SARA) TifleIII lnformation Tlrese products contains none of the substances subject to reporting requlrements of SARA section 313

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Safety ($) Plrrases :

Producl Neme: DENSE BLACK

(40 cFR 372)

National Fire Protection Association (NFpA) Ratings individuats trained in the NFpA system-

Code letter and hazard designation of product: No symbol Risk (R) Plirases: none

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DATA FREPARE) I 2O15I\I17

: This information is ihtended sololy for the use of

Health : 1

Flammability: 1

Reactivity : 0

(2). EU Regr-rlations

Eut!qg-"! lnventory of Existing chemicals (ElNECs) : All of the components of this product are includedon EINECS.

The followihg information is l:asecl on current EU (djrectives 67ll4BtEEC - 28th update [2001/59/EC],19ss/4slEc, 2001/58/EC and clp Hazard crassification tneguhtro;(E61 ruo razzlzoooll.

EU CLP & DSD,Classification :

Designatlon aecording to EC guidelines in label ;

CLP

DSD

By the component of under cobart dryer 1o/o, not crassifled Risk phrase R4zr43, 57 Keep container tighfly closed 524125 Avoid'co,rtact Wth eyes and st<ln s20 ln case of contact with eyes, rrnse immediatery with prenty of water and seekmedicaladvice.

sza After contact with skin, wash immediatery with prenty of water and seekmedical advice-

536/37 Wear suitable protective clothing and gloves, .*f:^luo'o rerease to the environment. Refer to speciar instructions/safety data

Components Hazard lnformation :

Petroleum hydrocarborr Cas No.64742-46'7is classified into R45 (May cause cancer) for DSD, or into Carc,1B, GHSo8,Dgr and H350 Tor CLP, but this product is refined highly, and tlii* *rtpri"t ,emoru* a cqncer-causinq materi_al. IARQ classified Group 3, Cobalt compoLrnd (Co CAS No. 7440-49-4 \.CLP Resp, Sens, 1 GHSOB H334

Skin Sens. 1

Aquatic Chronic 4DSD Xn Harmful R4Zl43 May cause sensitizaUon by inhalation and skin contact, R68 Possible risk irreversible effocts.

"Colralt in the material concerned is not classified. in flre CLp and DSD Regulationsfor the content ,qf unde-r 0.ll o/o

Follow all regulations in your country.

Dgr H317 Itt4att+tJ

CLP Hazardous substance; none CLP Classification : No classifieation standards appticable

Contains [Cobatt driersJ. May produce allergic st<in r.*.iion. S:

7 -24 t25-26-28-36/37.6 1

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Product Namei DENSE BLACK Pace;70f7 OATA PREPARED : 201519t17

16. OTHER INFORMATION

Disllaimer The information provided in this Material Safety Data Sheet is conect to the best.of our knowledge, information and bellef at the date of its publicaiion, The information given is designed only as a guidance for safe handling, use, processing, storege, transpoftation, disposal and release and is niltto be considered a warranty 0r quallty speciflcation. The inforrnation relates only to the specific material designated and may not be valid for such material used in combination wlth any other materlals or in any proceis, unless specified in the text.