sds 1.pdf

tuiw Printing date 05/2 5/20 I 8

SsfeA Datu Sheet acc, to OSHA HCS

Page l/8

Reviewed on 05/25/2018

I ldentification . Product identifier

'Trade name: AUTOWASH EV

'Article number: 4364

' Application of the substance / the mixture Roller and Rubber Blanket Cleaner

'Details ofthe supplier ofthe safety data sheet ' M a n ufac t u r e r/S upp I ie r :

Printers' Service, Inc.

26 Blanchqrd Street Newark, NJ 07105

USA

' Information department: I -97 3-5 89-7800, Prisco email address - safety@prisco.com ' Emergency telephone number: CHEMTREC (24 hr) l-800-424-9300

2 Hazard(s) identitication

W:,;"d"the substance or mixture

Flam. Liq. 2 H225 Highlyflammable liquid and vapor.

@r",n hhazard

Muta. IB H340 May cause genetic defects.

Carc. lB H350 May cawe cancer.

Asp. Tox. I H304 May be J'atal d swallowed and enters ait.ways.

e Skin lrril. 2 H3 I 5 Causes skin irritation.

Eye lrrit. 2A H3l9 Causes serious eye iffitation.

STOT SE i Hjj6 May cause drowsiness or dizziness.

' Label elements ' GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).

' Hazard pictograms

00@

GHSO2 GHSOT CHSOS

'Signal word Danger

' Hazard-determining componenLs of labeling:

aliphatic petroleum distillate (C6-9) acetone

' Hazard statements Highlyflammable liquid and vapor.

Causes skin irritation.

Causes serious eye ilrilation.

May cause genetic defects.

May cause cancer.

Mav cause drowsiness or dizziness.

May be.fatal if swallowed and enters airwa))s.

' Precaationary statements Obtain special instructions before use.

Do not handle until all sufety precautions have been read and under.ttood.

Keep awayfrom heat/sparks/open.flames/hot surfaces. - No smoking.

Ground/bond container and receiving equipment.

Us e exp lo s i o n- p r o of e I e c tr ic al/vent il ating/li ghtin g/ e q uipm ent.

Use only non-sparking tools.

Take precautionary measures against static discharge.

Av o id b r e at hing d u s t/fu me/gas /mis t /vap o rs h p ray llash thoroughly after handling.

Use only outdoors or in a well-ventilated area.

Wear protective gloves/protective clothing/eye protectiott/face protection.

If swallowed: Immediately call a poison center/doctor.

SpeciJic tredtment (see on this label).

Do NOT induce vomiting.

If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with t ater/shower.

(Contd. on page 2)

Safety Data Sheet acc. to OSHA HCS

Printing date 0 5/2 5/20 I I

Trsde nome: AUTOWASH EV

4 First-aid measures ' Description offirst aid measures 'Alter inhalation: In case ofunconsciousness place patient stably in side positionfor transportation, ' After skin conlact: Immediateb, wash with water and soap and rinse thoroughly.

'Afler eye coiltoct:

Rinse opened eye for several minutes under running water. If symptoms persist, consuil a doctor.

' After swallowing: If symptoms persist consult doctor.

' Information for doclor:

' Most imporlant symptoms an.l effecls, both acute anil ilelayed No.further relevant information available ' Indication of any immediate medical attention and special treatment needed No furlher r e levant inform at ion availabl e.

5 Fire-Jighting messures 'Extinguishing media ' Suilable extinguishing agents:

CO2, extinguishing powder or water spra)). Fight larger Jires teith wdter spray or alcohol resistant foam.

' Special hazards arising front the substance or mkture No further relevant information available.

' Advice for Jirefighters ' Prolective equipment:

Mouth respiratory protective device.

Ilear self-containe.l respirqtory protective device, Page 2/8

Reviewed on 05/25/2018

IF INHALED: Remove person tofi.esh air and keep comfortablefor breathing.

(contd' ofpage l)

Ifin eyes: Rinse cautiously with waterfor several minutes. Remove contact lenses, ifpresenl and easy to do.

Conlinue rinsing.

IF exposed or concerned: Gel medical advice/attentiotl.

Call a poison center/doctor ifyoufeel unwell.

Take offcontaminated clothing and wash it before reuse.

Ifskin irritation occurs: Get medical advice/attention.

If eye irritation persists : Get medical advice/attention.

In case ofJire: Usefor extinction: CO2, powder orfoam.

Store in a well-ventilated place. Keep container tightly closed.

Store in a well-ventilated place. Keep cool.

Store locked up.

Dispose ofconlents/container in accordance with local/regional/national/inlernational regulations.

' Classitication system:

' NFPA ratings (scale 0 - 4)

Ao HMlS-ratings (scale 0 - 4)

' Other hazards ' Results of PBT and vPvB assessment 'PBT: Not applicable.

' vPvB: Not applicable.

3 C omp os itio n/information on in gr e d i e nts ' Chemical characterization : Mixtures ' Description: Mixture of the substances listed belov, with nonhazardous additions.

' D a n g e r o u s_q 9 mp pg e nts :

CAS: 64742-89-8 aliphatic pe*oleum distillate (C6-9) 50-70%

CAS:67-64-| acetone 30-50%

RTECS: AL 3150000

CAS: 34590-94-8 dipropylene glycol monomethyl ether 10-30%

RTECS: JM 1575000

' Additional information: For the wording of the listed hazard phrases refer to section I 6.

6 Accidental release measures ' Personal prectutions, protective equipmenl and emergenqt procedures llear protective equipment. Keep unprotected persons away.

' Environmental precaulions:

Prevent seepage into sewage system, workpits and cellars.

(Contd. on page 3)

Snfety Dsta Slaeet acc. to OSIIA IICS t.

' Page j/B

Ret,iewed on C5/25/20 i IPrintiqr; dc te .0 5/2 5 /20 I B

Dilute with plenry of wctter.

Do not albw lo enter sewers/ surface or ground waler.

Methorls and materialfor containmenl and cleaning up:

Absorb with liquid-binding nnterial (sand, diatomite, acid binders, removal containers Dispose contdminaled moleriaL as waste accor.ding lo ilem 13.

E nsure ad cqu o t e vcnl ilat ion.

' Reference lo other sections

See Section 7.[or infurmation on safe handling.

See Sectiot't 8 for information on personal prolection equipment See Section I 3 for disposal ittfornution.

' Protective Action Criteriafor Chemicals

.PAC.I:

universal binders, sawdust) and place into

All ingredients are lisled

PAC-2:

Ail ingredients are lisled

PAC.3:

All ingredients are listed

7 Handling and stordge

'Handting:

' Precautions for sdfe hdndling Store in cool, dry place in tightly closed receptacles.

Ensure good ventilation/exhaustion at the worlqlae.

' Information dbout protection against explosions and fires:

Keep ignition sources areay - Do nol smoke.

Protect against electrostatic charges.

' Conditions for safe storage, including any incontpatibilities 'Storage:

' Requirenents to be met by storeroons and receptacles: Slore in a cool localiort ' Informatiorr about storage in one cornn oil storagefacility: Not requir"ed.

' Further information about storage conditions:

Keep receptacle tightly sealed.

Store in cool, dry conditions in well sealed receptacles.

'SpeciJic end use(s) Nofurther relevant i,tformation avttilable.

8 Expo s ure co ntro ls/pers o nal protectio n 'Additional iltformation about design oftechnical systenrs: No.further data; see item 7.

' Control parameters 'Components with litttit values tlrut require monitoring at the workplace:

Thefollowing conslituents are the only constituents ofthe productwhich have a PEL, TLV or otlzer reconntended exposure lintit.

At this time, the remaining constiluent has no lonwn exposure limits.

67-64-l acelone

PEL Long-terntvalue: 2400 mg/ntr, 1000 ppm

REL Longtermvalue: 590 mghn3, 250 ppm

TLV Shortterm value: I 187 mg/mt, 500 ppm Long-term value: 594 mg/m3, 250 ppnt

BEI

34590-94-8 dipropylene glycol monomethyl ether

PEL Long-term value: 600 mghn3, 100 pprn Skin

REL Short-term value: 900 Long-term value: 600 Skin

TLV Short-term value: 909 tnghn3, I 50 ppm Long-termvalue: 606 mght3, 100 ppm

'Skin

I 5A ppm 100 ppm

67-64-l acetoile

BEI 50 ng/L MedLullt: Lll u1e

Tinry:.end o/shift

Page 4/B

SakE, D,ata Strteet acc. ta ASI{A f{CS

Print in g do te 0 5/2 5 /2 0 I 8

9 Physical and chemical properties ' Information on basic physical and chemical propefiies ' Generol Information ' ,Appearance:

Form:

Color:

'Ador:

' Odor threshold:

'pH-value:

' Change in condition

Fluid Clear Characteristic Not deternrined.

Not determined.

Not Applicable s6'c (1 33 .F)

-20 "c (-4 "F)

Not applicable.

270 "C (s 1 I "F)

Not irrformation available

Product is not selfigniting.

In use, mayform fammable/explosive vapour-air mixture

0.9 Vol %

14 Yol%

233 hPa (174.8 nm Hg)

0.78 g/cm3 (6.51 lbs/gal) Not detetlnined.

Not deternined.

Not determined.

Soluble.

o

Me ltin g p o int/M elti n g ra n g e :

B o i li ng po irt/B o ilin g ra n g e :

' Flash point:

' Flammahility (solitl, gaseous):

' Ignitio n tempe,.ulute:

' D eco np o s i ti o n tentp eyature :

'Auto igniting:

' Danger ofexplosion:

' Explosion linits:

' Vapor p.ressure at 20 oC (68 oF):

' Densitl' at 20 oC (68 oF):

' Relative dens.itS, Vapbr density

'Evaporotion rate . Solubility in / Miscibility with ll'ater:

P a r t i t i ott c.o efJi c i e n t (n - o c t aq o yH' at e r) : N o t d e t e rn i n e d.

o

Ket'rcu ed on U ) // )/_, U I t;

(Contd. of page 3)

; Exposure controls

' General protective and hygienic measures:

Ke e p aw a v fr o nt fo o ds tuJfs, b ev e r a g e s a n d fe e d.

Imntediately rcmove all soiled and conlaminated clothing.

lilash hands before breal<s and at the end ofwork, Store protective clothing separately.

Avoid contact with the eyes and skin.

' Breathing equipment:

In cas,e,of intensive or longer exposure use respiralorv prorective device lhat is independenl of circulating ait..

Suitable respiratoty protective device recommended, btfi not necessarlt if room is will_ventilited.

' Prolection ofhands:

'The glove material has lo be impermeaitle anc! resistant to thc product/ th" substancet the preparatiol.

' Material of gloues " Tortnd lhe recontntended glove material to use when handing Prisco@ pressrr)om chemistrlt we advise to visil r|wv'.prisco.cont. Choose localion & preferred language and go to the "Sltpport" drop-diu,n box v,here ',ouselect: "Safetv Glove Recontntendation". Nou,click on the PDF-htperlinli b ;b'tuin the document in the langtiage ofyour preference.

The selection ofthe suitahle gloves does nol ortll'depend on the.material, but also on.furtlter ntarks ofqualin, and variesft'ont ntaru,tfacturer to manufaclurer. As the prodtrct is a preparation o{several substances, the'resi;tunce ofthe glot'e material cannot be calatlated in advance and has tierifore to be checked pr-ior to the application.

' Pcnetration time of glove materisl The exac.t breakthrough tine has to be found our by the .nnnufacttter of the protective gloves ond has to be obsen ed.

' Eye protection:

righttyseated goggtes

Printing date 05/25/201 8

Trade none: AUTOWASI{ EV

(Contd. of page 4)

Ssfeq) Dats. Sheet ace. n ASMA IICS

. Page 5/8

Ret,iewed on 05/2 5/20 I I

10 Stability and reactivity ' Reactivity Avoid sn.ong oxidizing agents, strong bases incl strong acid.s.

. Chemical stability Stable uuder normal condltions ' Tltermal decontposition / conditions lo be avoitled: No decontposition ifused according to specifications ' Possibili4t of luzardous reactions No dangerous reactions known.

' Conditions to avoid Nofurther relevant information available.

' I n co mp at ib le mdt erials : No.furthe r re I eva nt info rm a t io t1 at,a il a b I e.

' Hazardous decompositiott products: Carbon monoxide and carbon dioxide

1 1 Toxi co lo gic al i nfo rmatio n . htformatjon on toxicological effects 'Acute toxicity:

' Prinary irritont effect:

, on the skitl: Irritant to skin and mucous membranes.

' on lhe e),e: Irritating ffict.

' S e n s it i zati o n : No s en s itizin g ef.fe c ts knov,n.

' A d diti on at toxic o logi ca I i nfonn uti'o n :

The product shows thefollowing dangers according to internally approved calculation merhods for preparations:

Product may cause irritatiort.

The product cdn cause inheritable darnage.

' Carcinogenic categories ' IARC (International Agency.for'Research on Cancer) None ofthe ingredients is listed.

' NTP (National ToxicoloKt Progran) None ofthe ingredients is listed.

OSHA-Ca (Occupational Safety & Health Adninistrotion) None of the ingredients is listed.

1 2 E co lo gica I info r m ati o n 'Toxicity ' Aquatic toxicity: No further relevant information available.

. Persistence and degradability No further relevant information available.

' Behavior in environmental syslems:

' Bioaccumulative polential No ftu.ther relevant infornation available.

' Mobility in soil No.further relevant information available.

', Additional ecological information:

. General notes:

Water hazard class I (Self-assessment): stightly hazardotts.for utater Do nol allow undifuted product or large quantilies of it to reach ground water, wd.ter course or sewage svstem.. Results of PBT and vPvB dssessment

. PBT: Not applicable.

.vPvB: Not applicable.

'Other adverse effects Nofurther relevant inforntation available.

1 3 Disposal considerution s ' Wa.sle treatnrcnt nrcthotls ' Recoumendation:

Product must not be disposed of together with household refuse. Do not allow product to reach sewage systent.

' Uncleaned packagings:

' Recommendation: Disposal must be made according to fficial regulations.

' Recommended cleansing agent: ll/dter, ifne1essa4t with cleansing agents.

I 4 Tr an sp o rt info rm otio n

,DOT

' UN proper shipping nanre

,DOT

.ADR

uN199i

. Flammable liquids, n.o'.s. (Acetone, aliphatic petroleurn distiilate (c6-e)

,,1 lp9 j Flamntabte liquids, n.o..t. (Acetone, aliphatic petroleLrnt drstcts.te (lo-y)

Printing date A5/25/24 I B

SafeEr Data Skeet acc. rc ASI'{A I{CS

Page 6,8

Revietved on 05/25/20 I B o ' Tlansport haxard class(es)

.DAT

' Class 'Label 'Class 'Label ' Packing group

'DOT, ADR

' Environmental hazards:

' Special precautions for user

' Quantity lint itatio ns

' Excepted quantities (EQ)

' Limited quantities (LQ) ' Excepted quantities (EQ)

' UN "Model Regulation":

I 5 Regulatory informatio n

II

Not Wa;

' Transport in bulk according to Annex II of MARPOLT3/78 and the IBC Code Not

DOT

OrL Onr Cod' Max Max

IL

Cod Max Max

UN

PET

), 3, (Contd. ofpage 5)

3 Flammable liquids

3 Flammable liquids il Not applicable.

Warning. Flammo ble I iqu id s

Not applicable.

On passenger airuafth'ail: 5 L On cargo aircraft only: 60 L Code: E2 Maximum net quantity per inner packaging: j0 ntl Maximum net qudntiy'per outer packaging: 500 ml

IL

Code: E2 Maxinrum net quantity per inner packaging: 30 ml Maximunt net quantity per outer packaging: 500 nrl

UN 1993 FLAMMABLE LIQUIDS, N.O,S. (ACETONE, ALIPHATIC

P ETRO LEUM D I STI LLATE (C 6-9 )

), 3, II

' Safety, health and environmental regulali 'Sara 'Section 355 (extremely hazardoas substan

None ofthe ingredient is listed.

h and environmental regulalions/legislation specific for the substance or mixture

(exlre me ly h azar do as substances) :

TSCA (Toxic Substances Control Act):

ONLY TO TI{E END-ASERS LOCATED IN CALIFORNIA

Warn.ing: This product contains a chentical known lo tlrc State of California to cduse birth defects or other reproductive harm.

ll/arning: Tlis product contains a chenrical lorown to the Stale ofCaldornia lo cause cancer.

Cslifornia Proposition 65 chemicsls known to cause cancer:

100-41-4 ethylfisnz.r.

7l-43-2 benzene

9 1-20-3 naplrthalene California Proposition 65 chemicals knoh,n to cause reproductiye toxicitv for feruales:

Qalifunia Proposition 65 chenicals known to cause reproductivs toxicity for males:

California Proposition 65 chenicals known to cause dcvelopmcntal toxicity:

108-88-3 toluene

'Section 313 toxic chcmical

None ofthe ingreCients is listed, ' TSC4 (Toxic Substances Contt

All ingredients are listed.

.THE SECTION BELOWIS APPLICABLE O,

' California Proposition 65 Stqtements

Warning: This product contains a chentical ] reproductive harm.

ll/arning: Tlis product contains a chenrical kno csls known to

100-41-4 ethylfisnz.r.

7l-43-2 benzene

9 1-20-3 naplrthalene California Propt

None California Propt

7l-43-2 benzene

65 chenicals knou,n to

65 chenicals known to

65 chenticals knnwn to

108-88-3 toluene

7 I-43-2 benzene

' Cancerogenity catego ries ' EPA (Environmental Protectio

None ofthe ingredients is listed TLV Limit l/alue established bt'4C None ofthe ingredients is listed

' l\tIOSH-Ca (Nilional [nstitutc . None tf ihe iigredients is'listed. . :

, QIIS label elenrcnts The proCuct is classifci at o aa

Printing date 0 5/2 5/20 I I

S&fety Data Sfteet acc. to OSIIA IICS

Page 7/8 la

Reviewed on 05/25/2018

Trade nanrc: AUTOWASII El/

. Hazartl pictograms (Contd olpage 6)

@>d.>&\7\/.V

GHSO2. GHSOT GHSOS

'Signal word Danger

' Hazard-determining components of labeling:

aliphatic petroleum-distillate (C6-9) acelone

' Hazard statements Highly Jtammable liquid and vapoi.

Causes ski.n irritation.

Causes serious eye irrilation.

May cause genetic defects.

May cause cancer.

May cause drowsiness or dizzittess.

May befatal dswallowed and enters ainuays.

' P r ecauti on ary it atenre n ts Obtain special instructions before use.

Do not handle util all safety pt'ecautions have been read and understood.

Keep aw ay fr o nt h eat/sp a r ks /op en Jl ant es,hto t s u rfaces. - N o s mo king.

Ground/bond container and receiving equipnenl.

U s e exp I o s i o n -p r o of e I e c u' ic o l/v e nti ldtih g/l i g hti n g/ e q uipm en t.

Use only non-sparking tools.

Take precautionat)' measures againsl static discharge.

Avoid b r e athing dus t/fume/gas /mis t/t, ap ors /spray Ilash tlrcroughly after hondling.

Use only outdoors or in a well-ventilated area.

lilear protebtive gloves/protective clothing/eye protection/face protection.

If swallowed: Intmediately call a poison center/doctor.

Specific *eafinent (see on this label).

Do NOT induce vomiting.

If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.

IF INHALED: Rentot,e person tofresh air and keep comfortablefor breathing.

Ifin eyes: Rinse cautiously with water/or seteral minutes. Remove contact lenses, ifpresent and easy lo do.

Continue rinsing.

IF exposed or ioncerned: Get ntedical advice/attention.

Call a poison center/doctor ifyou feel unwell.

Take off contaminated clothing and wash it before reuse. ' Ifskin irritation occurs: Gel medical advice/attention.

If elte irritation persists: Get medical odvice/attention.

In case offire: Usefor extinction: CO2, powder orfoam.

Store in a well-ventilated place. Keep container tightly closed.

Store itt a well-ventilated place. Keep cool.

Store locked up.

Dispose of conlents/container in accordance with local/regional/natio,tal/internetional regulations"

' National regulations:

' Additional classification according to Decree on Hazardous Materials:

Carcinogenic hazardous material group III (dangerous).

' Information about limitation of use:

Workers are not allowed lo be exposed to the ha:ardous carcinogenic materials contained in this preparation.

Exceptions can be made by the authorities in certain cases.

' llater hazard class: Water lmzard class I (Self-assessment): slightly lruzardous for water.

' Chemical safety assessmZnt: A Chentical Safety Assessntent has not been carried out.

l6 Other informatiort This infornntion is based on our prasent knowledge. However, tltis shall nol constitute a guarantee for any

Ah hrevintio ns ui d acro n rm s''-""'- 1""" 1 ADR. Accord europk!\sut tn ,rnur)oy, ics'ntarcha'ndisis dange"reusis par Riute (Europeai tlgreententx'onceritinglLaJnterhatio)ai , Printing date A5/25/201 I

Sakty D,nta Sheet ttcc. to ASI.IA HCS

Page 8/B

Ret,iey,ed on 05/25/2() I 8

Trade name: AUTOWASI{ EV

(Contd. ofpage 7) CAS: Chcnical Abstrqcts Scn'icc (clivision ol thc Atncrican Chcnicol Socicl) NFPI: National Fit e Prctectioh lssociqtian (IJS+) HMISr Hozanlous Mutcriuls Identification $sten (IJSA) l/OC: Volatile Organic Conpounds (USA, EU) PBT; Persistent, Bioaccumulatit,c ond Toxic yPvB : ven' Persistent ahd let, Bioil.,cuntuldtive NICSH; National lnstit!ile Ior Occtfatiotnl Safety OSHA: Occupational Safetv & HeaIth TLV. Threshold Linil l,alue PEL: Pemissible Exposure Linit REL: Recommerrded Exposure Limit BEI: Biological Exposurc Limit Flan. Liq. 2: Flamuable liquitls - Category, ) Skin lrrit.2: Skin corrosion/irritation - Category 2 Eye lrrit. 2A: Seiotrs cye danagc/eye irritatiou - Cqtegor.v 2A Muta. I B: Oem cell mutagenici\' - Category t B Carc. lB: Carcinogenicity - Category lB

,STOT SE 3: Specific target organ toxicir' (single exposure) - Category j Asp. Tox. L Aspiration hazard - Categorv I

* Datc compared to the previous version alrcred.

". .. ,"..1, "...