MSDS - DFM.pdf

(CITY, STATE AND ZIP CODE) COUNTRY

San Antonio, TX 78216-6999 USA

(CITY, STATE AND ZIP CODE) COUNTRY

% SARA RQ

(by volume) PPM MG/M3

PPM MG/M3 TITLE III LBS

Contains or May Contain:

Diesel Fuel #2 68476-34-6 0 - 100 not established

Fuel Oil #2 68476-30-2 0 - 100 not established

Tower Residues, atmospheric 64741-45-3 0 - 100 not established

Residues (petroleum), Vacuum 64741-56-6 0 - 100 not established

Heavy catalytically cracked distillate (e,f,g) 64741-61-3 0 - 100 0.2 0.2

Light thermally cracked distillate (h) 64741-59-9 0 - 100 not established

Catalytically cracked clarified oil (e,g) 64741-62-4 0 - 100 0.2 0.2

Xylene (mixed) (a,b,c) 1330-20-7 0 - 1.1 100 435 100 Yes 1000

Trimethylbenzene 1,2,4 (a) 95-63-6 0 - 1.2 25 125 Yes

Nonane 111-84-2 0 - 1.1 200 1050 200

Sulfur, precipitated 7704-34-9 0 - 5.0 15

Naphthalene (a,b,c,d) 91-20-3 0 - 1 10 50 10 Yes 100

Red Dye not specified Trace

(a,c) See Section 15

May 23, 2002 New

300 Concord Plaza Drive Tesoro Call Center (877) 783-7676

HAZARDOUS COMPONENTS CAS #

OSHA PEL

EMERGENCY TELEPHONE NUMBER

EMERGENCY TELEPHONE NUMBER

(d) Product is listed or defined as a marine pollutant in IMDG Code or 49 CFR 172.101 Appendix B, List of Marine Pollutants and must be classified as an Environmentally Hazardous Substance, Class 9, in addition to any other defined hazards for this product.

Chemtrec (800) 424-9300

ACGIH TWA

ADDRESS (NUMBER, STREET, P.O. BOX)

DATE PREPARED:

(b) Indicates that the Resource Conservation and Recovery Act (RCRA) has determined the waste for this chemical is listed as hazardous and must be handled according to regulations in 40 CFR 260-281.

MANUFACTURER'S NAME

Tesoro Petroleum Companies, Inc.

SECTION 2 - HAZARDOUS INGREDIENTS

TELEPHONE NUMBER FOR INFORMATION

ADDRESS (NUMBER, STREET, P.O. BOX)

DISTRIBUTOR'S NAME

TELEPHONE NUMBER FOR INFORMATION

MATERIAL SAFETY DATA SHEET

SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION

PRODUCT DESCRIPTION: Liquid. Color varies, clear, yellow (pale to straw), red, blue, blue-green color.

Petroleum odor.

GENERAL USE: Fuel

Same

SUPERSEDES:

(e) California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986, chemicals known to the state to cause cancer or reproductive toxicity. A person in the course of doing business must warn others who may consume, come into contact with, or otherwise be exposed to this chemical.

(f) IARC has determined that residual fuels are possibly carcinogenic to humans. Handling procedures and safety precautions in the MSDS should be followed to minimize employee's exposure.

(g) IARC has determined there is sufficient evidence for the carcinogenicity of catalytically cracked oils.

(h) Kidney damage may result following aspiration pneumonitis. The results of animal bioassays on middle distillate fuels show that prolonged dermal contact produces a weak to moderate carcinogenic activity.

PRODUCT NAME: Diesel Fuel; SYNONYMS: Diesel Fuel #1 - LS Dyed; Diesel Fuel #2 – DSL2, Off- Road, On-Road, HS–Dyed, LS–Dyed, LS-Undyed, LS Diesel; Winter Blend; Fuel Oil #2 - Diesel Fuel Oil, No. 2 Diesel Fuel Oil, Non-Hwy Dyed; Diesel Fuel – Premium, Super, Supreme, Powerblend, Non-Taxed LS Dyed; Additized; Russian Summer; Arctic; -10 and –35 F pour point depressed diesel; Lago;Burner Oil; Aleyska Turbine Fuel; Distillate - Mid; No. 2; Marine – Marine Gas Oil, MGO, DFM; Navy Fuel; F76; Marine Diesel Fuel (MDO); Intermediate Marine Fuel IF-30 to IF-460;

IMF; RR Diesel Fuel - No. 40, No. 35, RR Power Fuel HS Off-Road; CARB Diesel Fuel - On-Road, Off-Road, Tax Exempt Blends, TF3, 10%; EPA - LS Diesel Fuel Dyed, Undyed, Off-Road HS Dyed

May 23, 2002

CARCINOGENICITY NTP? No No No

FLASH POINT (METHOD USED) LEL: UEL:

100 - 199° F ( 38 - 93º C) TCC II

This product contains a mixture of petroleum hydrocarbons called middle distillates. Because of this broad description, many products are considered middle distillates yet they are produced by a variety of different petroleum refining processes. Toxicology data developed on some middle distillates found that they caused positive responses in some mutagenicity tests and caused skin cancer when repeatedly applied to mice over their lifetime.

Firefighters must wear full facepiece self - contained breathing apparatus in positive pressure mode. Do not use solid stream of water since stream will scatter and spread fire. Fine water spray can be used to keep fire - exposed containers cool.

POTENTIAL HEALTH EFFECTS

INGESTION: May result in vomiting; aspiration of vomitus into the lungs must be avoided; DO NOT induce vomiting. Minute amounts aspirated into the lungs can produce severe lung injury, chemical pneumonitis, pulmonary edema or death.

IARC MONOGRAPHS? OSHA REGULATED?

AUTOIGNITION TEMPERATURE:

FIRE FIGHTING PROCEDURES

Carbon dioxide, water fog, dry chemical, chemical foam

SECTION 4 - FIRST AID MEASURES

INHALATION: Remove affected person to fresh air; provide oxygen if breathing is difficult; if affected person is not breathing, administer CPR and seek emergency medical attention.

SKIN: Remove contaminated clothing; wash affected area with soap and water; launder contaminated clothing before reuse; if irritation persists, seek medical attention.

EYES: Remove contact lenses. Flush eyes with clear running water for 15 minutes while holding eyelids open; if irritation persists, seek medical attention.

INGESTION: DO NOT induce vomiting; if vomiting occurs spontaneously, keep head below hips to prevent aspiration of liquid into lungs; seek immediate medical attention. Vomiting may be induced only under the supervision of a physician.

FLAMMABLE LIMITS 0.3%

EXTINGUISHING MEDIA

GENERAL HAZARDS: Product is considered combustible. Products of combustion include compounds of carbon, hydrogen and oxygen, including carbon monoxide.

UNUSUAL FIRE AND EXPLOSION HAZARDS

Smoke, fumes, oxides of carbon

SECTION 5 - FIRE FIGHTING MEASURES

10.0%

HAZARDOUS COMBUSTION PRODUCTS

350 - 625°F NFPA CLASS:

EYES: High vapor concentration or contact may cause irritation and discomfort.

Closed containers can explode due to buildup of pressure when exposed to extreme heat. Do not use direct stream of water on pool fires as product may reignite on water surface. Caution - Material is combustible!

Various colored liquid, potentially hazardous vapors. Flammable as defined by DOT and TDG. May be classified by DOT as Combustible.

Classified as Combustible by OSHA. Can cause eye and skin irritation upon contact. Inhalation of vapors can cause anesthetic effect leading to death in poorly ventilated areas. Hazard symbols for this product - F, XI Risk Phrases - R10 20 36 38

INHALATION: High concentrations are irritating to the respiratory tract; may cause headache, dizziness, nausea, vomiting and malaise.

EMERGENCY OVERVIEW

MATERIAL SAFETY DATA SHEET

SECTION 3 - HAZARDS IDENTIFICATION

SKIN: Brief contact may cause slight irritation; prolonged contact may cause moderate irritation or dermatitis.

PRODUCT NAME: Diesel Fuel; SYNONYMS: Diesel Fuel #1 - LS Dyed; Diesel Fuel #2 – DSL2, Off-Road, On-Road, HS–Dyed, LS–Dyed, LS-Undyed, LS Diesel; Winter Blend; Fuel Oil #2 - Diesel Fuel Oil, No. 2 Diesel Fuel Oil, Non-Hwy Dyed;

Diesel Fuel – Premium, Super, Supreme, Powerblend, Non-Taxed LS Dyed; Additized; Russian Summer; Arctic; -10 and –35 F pour point depressed diesel; Lago;Burner Oil; Aleyska Turbine Fuel; Distillate - Mid; No. 2; Marine – Marine Gas Oil, MGO, DFM; Navy Fuel; F76; Marine Diesel Fuel (MDO); Intermediate Marine Fuel IF-30 to IF-460; IMF; RR Diesel Fuel - No. 40, No. 35, RR Power Fuel HS Off-Road; CARB Diesel Fuel - On-Road, Off-Road, Tax Exempt Blends, TF3, 10%; EPA - LS Diesel Fuel Dyed, Undyed, Off-Road HS Dyed

STABILITY UNSTABLE:

STABLE: XXX

HAZARDOUS POLYMERIZATION MAY OCCUR:

WILL NOT OCCUR: XXX

WORK / HYGIENIC PRACTICES: Practice safe workplace habits. Minimize body contact with this, as well as all chemicals in general.

The use of local exhaust ventilation is recommended to control emissions near the source. Provide mechanical ventilation of confined spaces.

Use explosion-proof ventilation equipment. See Section 2 for Component Exposure Guidelines.

PROTECTIVE GLOVES: Neoprene or rubber gloves with cuffs.

SOLUBILITY IN WATER

SECTION 10 - STABILITY AND REACTIVITY

HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Decomposition will not occur if handled and stored properly. In case of a fire, oxides of carbon, hydrocarbons, fumes, and smoke may be produced.

FREEZING POINT

SPECIFIC GRAVITY @ 60º F (WATER = 1) EVAPORATION RATE (WATER = 1)

0.78 - 0.955 < 1

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: COMBUSTIBLE. Evacuate and ventilate area; confine and absorb into absorbent; place material into approved containers for disposal; for spills in excess of allowable limits (RQ) notify the National Response Center (800) 424 - 8802; refer to CERCLA 40 CFR 302 and SARA Title III, Section 313 40 CFR 372 for detailed instructions concerning reporting requirements. Do not discharge into lakes, ponds, streams or public waters.

SECTION 7 - HANDLING AND STORAGE

PERSONAL PROTECTION:

INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers, strong acids

CONDITIONS TO AVOID: Extreme temperatures, open flames

CONDITIONS TO AVOID: None

Not determined Liquid,.clear, yellow (pale to straw), red, blue, blue-green, petroleum odor.

1.7 - 40.0 cS @ 100°F 6.75 lbs / gallon

Liquid VISCOSITY VOLATILE ORGANIC COMPOUNDS (Total VOC's)

30 - 806° F (1.1 - 430° C)

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: This material is combustible. It should be stored in tightly closed containers in a cool, well ventilated area. Vapor may form explosive mixtures in air. All sources of ignition should be controlled. This material may be classified as COMBUSTIBLE by DOT unless transported by vessel or aircraft. Refer to 49 CFR 173.120. Keep this and other chemicals out of reach of children. Avoid inhaling concentrated fumes or vapors.

EYE PROTECTION: Protective eyeglasses or chemical safety goggles. Refer to 29 CFR 1910.133 or European Standard EN166.

OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Safety eyebath nearby

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

VAPOR PRESSURE (PSIA) VAPOR DENSITY (AIR = 1)

SECTION 6 - ENVIRONMENTAL RELEASE MEASURES

< 0.5 PSIA @ 100º F > 1

BOILING RANGE PHYSICAL STATE

Negligible, below 1.0% - 51º F (- 46º C) pH APPEARANCE AND ODOR

SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

ENGINEERING CONTROLS

RESPIRATORY PROTECTION (SPECIFY TYPE): None required while threshold limits (Section 2) are kept below maximum allowable concentrations; if TWA exceeds limits, NIOSH approved respirator must be worn. Refer to 29 CFR 1910.134 or European Standard EN 149 for complete regulations.

MATERIAL SAFETY DATA SHEET

PRODUCT NAME: Diesel Fuel; SYNONYMS: Diesel Fuel #1 - LS Dyed; Diesel Fuel #2 – DSL2, Off-Road, On-Road, HS–Dyed, LS–Dyed, LS-Undyed, LS Diesel; Winter Blend; Fuel Oil #2 - Diesel Fuel Oil, No. 2 Diesel Fuel Oil, Non-Hwy Dyed;

Diesel Fuel – Premium, Super, Supreme, Powerblend, Non-Taxed LS Dyed; Additized; Russian Summer; Arctic; -10 and –35 F pour point depressed diesel; Lago;Burner Oil; Aleyska Turbine Fuel; Distillate - Mid; No. 2; Marine – Marine Gas Oil, MGO, DFM; Navy Fuel; F76; Marine Diesel Fuel (MDO); Intermediate Marine Fuel IF-30 to IF-460; IMF; RR Diesel Fuel - No. 40, No. 35, RR Power Fuel HS Off-Road; CARB Diesel Fuel - On-Road, Off-Road, Tax Exempt Blends, TF3, 10%; EPA - LS Diesel Fuel Dyed, Undyed, Off-Road HS Dyed

PROPER SHIPPING NAME:

DOT HAZARD CLASS / Pack Group:

REFERENCE:

UN / NA IDENTIFICATION NUMBER:

LABEL:

HAZARD SYMBOLS:

Nonane

Sulfur, precipitated

0 - 1.1 111-84-2 Inhalation - rat

Not applicable

F UN TDG Class / Pack Group:

WASTE DISPOSAL METHOD: Dispose of in accordance with Local, State, and Federal Regulations. This product may produce hazardous vapors or fumes in a closed disposal container creating a dangerous environment. Refer to "40 CFR Protection of Environment Parts 260 - 299" for complete waste disposal regulations. Consult your local, state, or Federal Environmental Protection Agency before disposing of any chemicals. Do not flush to sanitary sewer or waterway.

Flammable

Hazardous Ingredients (All products may not be listed if information is not available)

MATERIAL SAFETY DATA SHEET

Oral - mouse

IATA HAZARD CLASS / Pack Group:

RID/ADR Dangerous Goods Code:

IMDG HAZARD CLASS:

0 - 5.0

Not applicable

Note: Transportation information provided is for reference only. Client is urged to consult CFR 49 parts 100 - 177, IMDG, IATA, EC, United Nations TDG, and WHMIS (Canada) TDG information manuals for detailed regulations and exceptions covering specific container sizes, packaging materials and methods of shipping.

Trimethylbenzene 1,2,4 (a)

LC50 of Ingredient (Species)

Trace not specified Not determined

SECTION 11 - TOXICOLOGICAL INFORMATION

5 gm / kg

Not available

NA 1993

49 CFR 173.150, .203, .242

Not applicable3 / III

Diesel Fuel

Not applicable

18 gm / m3 / 4H

7704-34-9

SECTION 12 - ECOLOGICAL INFORMATION

SECTION 14 - TRANSPORT INFORMATION

Not established Oral - rat

SECTION 13 - DISPOSAL CONSIDERATIONS

No data are available on the adverse effects of this material on the environment. Neither COD nor BOD data are available. Release of this product should be prevented from contaminating soil and water and from entering drainage and sewer systems. U.S.A. regulations require reporting spills of this material that could reach any surface waters. The toll free number for the U.S. Coast Guard National Response Center is

(800) 424-8802. Naphthalene (91-20-3) one of the ingredients in this mixture is classified as a Marine Pollutant.

218 mg / kg Oral - mouse

0 - 1.2 95-63-6 Inhalation - rat 3200 ppm / 4H

Contains or May Contain:

Not available

Red Dye

1780 mg / kg

Not determined

Naphthalene (a,b,c,d) 0 - 1 91-20-3

% CAS #

LD50 of Ingredient

(Species and Route)

Heavy catalytically cracked distillate (e,f,g) 0 - 100 64741-61-3 Not established

Fuel Oil #2 0 - 100 68476-30-2

Not established

Tower Residues, atmospheric 0 - 100 64741-45-3 Not established Not established

Light thermally cracked distillate (h) 0 - 100 64741-59-9

Catalytically cracked clarified oil (e,g) 0 - 100 64741-62-4 Not established

Not established Not established

Not established

Not established

Not established

Not determined Not determined

Diesel Fuel #2 0 - 100 68476-34-6 Not established

Oral - rat Inhalation - rat Xylene (mixed) (a,b,c) 0 - 1.1 1330-20-7

4300 mg / kg

PRODUCT NAME: Diesel Fuel; SYNONYMS: Diesel Fuel #1 - LS Dyed; Diesel Fuel #2 – DSL2, Off-Road, On-Road, HS–Dyed, LS–Dyed, LS-Undyed, LS Diesel; Winter Blend; Fuel Oil #2 - Diesel Fuel Oil, No. 2 Diesel Fuel Oil, Non-Hwy Dyed;

Diesel Fuel – Premium, Super, Supreme, Powerblend, Non-Taxed LS Dyed; Additized; Russian Summer; Arctic; -10 and –35 F pour point depressed diesel; Lago;Burner Oil; Aleyska Turbine Fuel; Distillate - Mid; No. 2; Marine – Marine Gas Oil, MGO, DFM; Navy Fuel; F76; Marine Diesel Fuel (MDO); Intermediate Marine Fuel IF-30 to IF-460; IMF; RR Diesel Fuel - No. 40, No. 35, RR Power Fuel HS Off-Road; CARB Diesel Fuel - On-Road, Off-Road, Tax Exempt Blends, TF3, 10%; EPA - LS Diesel Fuel Dyed, Undyed, Off-Road HS Dyed

Residues (petroleum), Vacuum 0 - 100 64741-56-6 Not established

5000 ppm / 4H

HMIS HAZARD RATINGS 1

B

REVISION SUMMARY:

MSDS Prepared by:

(800) 255-3924 Outside USA (813) 248-0573

Components of this product identified by CAS number are listed on the DSL or NDSL and may or may not be listed in Section 2 of this document. Only ingredients classified as "hazardous" are listed in Section 2 unless otherwise indicated.

S28 After contact with skin, wash immediately with plenty of soap and water.

MATERIAL SAFETY DATA SHEET

R20 Harmful by inhalation

S62 If swallowed, do not induce vomiting; seek medical advice immediately and show this label.

R36 Irritating to eyes

EINECS (European Inventory of Existing Commercial Chemical Substances)

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.

(a) A "Yes" in the SARA TITLE III column in Section 2 indicates a toxic chemical subject to annual reporting requirements of Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372.

Components of this product identified by CAS numbers are on the European Inventory of Existing Commercial Chemical Substances.

S29 Do not empty into drains

R10 Flammable S23 Do not breathe vapor

CPR (Canadian Controlled Products Regulations)

IDL (Canadian Ingredient Disclosure List) Components of this product identified by CAS number are listed on the Canadian Ingredient Disclosure List are shown in Section 2.

R38 Irritating to skin.

SECTION 16 - OTHER INFORMATION

S25 Avoid contact with eyes

1 = SLIGHT 4 = EXTREME

No revisions available

DSL / NDSL (Canadian Domestic Substances List / Non-Domestic Substances List)

Acute health, flammable

1305 N. Florida Ave.

313 Reportable Ingredients:

CERCLA (Comprehensive Response Compensation and Liability Act)

Chem-Tel, Inc.

S16 Keep away from sources of ignition

Values do not reflect absolute minimums and maximums; these values are typical which may vary from time to time.

DISCLAIMER: The information supplied in this data sheet is obtained from currently available sources, which are believed to be reliable. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OF THE INFORMATION OR THE RESULTS TO BE

OBTAINED FROM ITS USE.

Handling, storage, use or disposal of the above-referenced product is beyond our control and may occur under conditions with which we are unfamiliar. FOR THESE AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM ANY LIABILITY FOR DAMAGE, INJURY AND COST ARISING FROM OR

RELATED TO THE USE OF THE PRODUCT.

HEALTH

(c) The Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) has notification requirements for releases or spills to the environment of the Reportable Quantity (RQ for this mixture > 24,000 lbs) or greater amounts, according to 40 CFR 302.

R51 Toxic to aquatic organisms.

EC Risk Phrases

Tampa, Florida USA 33602

TSCA (Toxic substance Control Act) Components of this product are listed on the TSCA Inventory.

SARA TITLE III (Superfund Amendments and Reauthorization Act)

SECTION 15 - REGULATORY INFORMATION

311/312 Hazard Categories

PRODUCT NAME: Diesel Fuel; SYNONYMS: Diesel Fuel #1 - LS Dyed; Diesel Fuel #2 – DSL2, Off-Road, On-Road, HS–Dyed, LS–Dyed, LS-Undyed, LS Diesel; Winter Blend; Fuel Oil #2 - Diesel Fuel Oil, No. 2 Diesel Fuel Oil, Non-Hwy Dyed; Diesel Fuel – Premium, Super, Supreme, Powerblend, Non-Taxed LS Dyed; Additized; Russian Summer; Arctic; -10 and –35 F pour point depressed diesel; Lago;Burner Oil;

Aleyska Turbine Fuel; Distillate - Mid; No. 2; Marine – Marine Gas Oil, MGO, DFM; Navy Fuel; F76; Marine Diesel Fuel (MDO); Intermediate Marine Fuel IF-30 to IF-460; IMF; RR Diesel Fuel - No. 40, No. 35, RR Power Fuel HS Off-Road; CARB Diesel Fuel - On-Road, Off-Road, Tax Exempt Blends, TF3, 10%; EPA - LS Diesel Fuel Dyed, Undyed, Off-Road HS Dyed

0 = INSIGNIFICANT

FLAMMABILITY

PERSONAL PROTECTIVE EQUIPMENT

REACTIVITY 2 = MODERATE

3 = HIGH

Safety Glasses, Gloves

EC Safety Phrases

R65 Damaging to lungs when swallowed

This MSDS has been revised in the following sections:

PRODUCT NUMBER (s): BHPP-1052, BHPP-1054, MSDS-1054, 2, 3, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 39, 46, 75, 88, 89, 90, 94, 97, 98, 99, 100, 101, 102, 103, 104, 105, 106, 108, 109, 111, 116, 117, 118, 282, 290, 291, 294, 304, 319, 351, 352, 1000, 1001, 1071,1076