DREWCLEAN 2000.pdf

SAFETY DATA SHEET Page: 1 Revision Date: 12/20/2009

Print Date: 4/10/2010 MSDS Number: 000000161034

Drewclean® 2000 DEGREASER 721004

Version: 1.0

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

Drew Marine USA, Inc. Regulatory Information Number 1-800-325-3751 One Drew Plaza Telephone 973-263-7600 Boonton, NJ 07005 Emergency telephone 1-800-274-5263

Product name Drewclean® 2000 DEGREASER Product code 721004 Product Use Description No data

2. HAZARDS IDENTIFICATION

Emergency Overview

Appearance: liquid,, green

CAUTION! COMBUSTIBLE LIQUID AND VAPOR. MAY AFFECT THE CENTRAL

NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. MAY BE

HARMFUL IF INHALED. MAY BE HARMFUL IF SWALLOWED. CAUSES

SEVERE EYE BURNS. MAY CAUSE SKIN AND RESPIRATORY TRACT

IRRITATION. PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND

CAUSE DERMATITIS AND BURNS.

Potential Health Effects

Exposure routes Inhalation, Skin absorption, Skin contact, Eye Contact, Ingestion

Eye contact Can cause permanent eye injury. Symptoms include stinging, tearing, redness, and swelling of eyes. Can injure the cornea and cause blindness.

Skin contact Passage of this material into the body through the skin is possible, but it is unlikely that this would result in harmful effects during safe handling and use. Can cause skin irritation. Prolonged or repeated contact may dry the skin. Symptoms may include redness, burning, and drying and cracking of skin, burns and other skin damage.

Additional symptoms of skin contact may include: allergic skin reaction (delayed skin rash which may be followed by blistering, scaling and other skin effects)

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Drewclean® 2000 DEGREASER 721004

Version: 1.0

Ingestion Swallowing small amounts of this material during normal handling is not likely to cause harmful effects. Swallowing large amounts may be harmful. This material can get into the lungs during swallowing or vomiting. This results in lung inflammation and other lung injury.

Inhalation Breathing of vapor or mist is possible. Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing large amounts may be harmful. Symptoms are not expected at air concentrations below the recommended exposure limits, if applicable (see Section 8.).

Aggravated Medical Condition Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material:, Skin, lung (for example, asthma-like conditions)

Symptoms Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include:, stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat, airways), Lung irritation, central nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea, headache, unconsciousness), Lack of coordination, confusion, irregular heartbeat, narcosis (dazed or sluggish feeling), Convulsions, coma

Target Organs Exposure to this material (or a component) has been found to cause kidney damage in male rats. The mechanism by which this toxicity occurs is specific to the male rat and the kidney effects are not expected to occur in humans., Overexposure to this material (or its components) has been suggested as a cause of the following effects in laboratory animals:, mild, reversible liver effects, mild, reversible kidney effects

Carcinogenicity d-Limonene caused kidney cancer in male rats, but not in female rats or in mice of either sex, when given to the animals through a feeding tube. The relevance of this finding to humans is uncertain. This product (or a component) is a petroleum-derived material. Similar materials and certain compounds occurring naturally in petroleum oils have been shown to cause skin cancer in laboratory animals following repeated exposure without washing or removal.

Reproductive hazard

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Print Date: 4/10/2010 MSDS Number: 000000161034

Drewclean® 2000 DEGREASER 721004

Version: 1.0

This material (or a component) has been shown to cause harm to the fetus in laboratory animal studies. Harm to the fetus occurs only at exposure levels that harm the pregnant animal. The relevance of these findings to humans is uncertain.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Components CAS-No. Concentration

ALIPHATIC HYDROCARBON NJTS# 254504001-5164 >=80-<90%

CYCLIC HYDROCARBON NJTS# 254504001-5323 >=5-<10%

TERPINOLENE 586-62-9 >=5-<10%

4. FIRST AID MEASURES

Eyes If symptoms develop, immediately move individual away from exposure and into fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention.

Skin Remove contaminated clothing. Flush exposed area with large amounts of water.

If skin is damaged, seek immediate medical attention. If skin is not damaged and symptoms persist, seek medical attention. Launder clothing before reuse. Remove contaminated clothing. Wash exposed area with soap and water. If symptoms persist, seek medical attention. Launder clothing before reuse.

Ingestion Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended.

Inhalation If symptoms develop, immediately move individual away from exposure and into fresh air. Seek immediate medical attention; keep person warm and quiet. If person is not breathing, begin artificial respiration. If breathing is difficult, administer oxygen.

Notes to physician

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Drewclean® 2000 DEGREASER 721004

Version: 1.0

Hazards: This material is an aspiration hazard. Potential danger from aspiration must be weighed against possible oral toxicity (See Section 2 - Swallowing) when deciding whether to induce vomiting.

Treatment: No information available.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media Carbon dioxide (CO2), Water spray, Foam, Dry chemical

Hazardous combustion products carbon dioxide and carbon monoxide, Hydrocarbons

Precautions for fire-fighting If product is heated above its flash point it will produce vapors sufficient to support combustion. Vapors are heavier than air and may travel along the ground and be ignited by heat, pilot lights, other flames and ignition sources at locations near the point of release. Never use welding or cutting torch on or near drum (even empty) because product (even just residue) can ignite explosively.Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA).

Flammability Class for Flammable Liquids Combustible Liquid Class IIIA

6. ACCIDENTAL RELEASE MEASURES

Personal precautions For personal protection see section 8. Eliminate all ignition sources (flares, flames including pilot lights, electrical sparks). Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Stop spill at source. Prevent from entering drains, sewers, streams or other bodies of water. Prevent from spreading. If runoff occurs, notify authorities as required. Pump or vacuum transfer spilled product to clean containers for recovery. Absorb unrecoverable product.

Transfer contaminated absorbent, soil and other materials to containers for disposal.

Environmental precautions Prevent run-off to sewers, streams or other bodies of water. If run-off occurs, notify proper authorities as required, that a spill has occurred.

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Drewclean® 2000 DEGREASER 721004

Version: 1.0

Methods for cleaning up Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Stop spill at source, dike area of spill to prevent spreading, pump liquid to salvage tank. Remaining liquid may be taken up on sand, clay, earth, floor absorbent, or other absorbent material and shoveled into containers.

7. HANDLING AND STORAGE

Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. Static ignition hazard can result from handling and use. Electrically bond and ground all containers, personnel and equipment before transfer or use of material. Special precautions may be necessary to dissipate static electricity for non-conductive containers. Use proper bonding and grounding during product transfer as described in National Fire Protection Association document NFPA 77.

Storage Store in a cool, dry, ventilated area, away from incompatible substances.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines

ALIPHATIC HYDROCARBON NJTS# 254504001-5164

ACGIH time weighted average 200 mg/m3 Non-aerosol NIOSH Recommended exposure limit

(REL):

100 mg/m3

ACGIH time weighted average 200 mg/m3 Non-aerosol

General advice These recommendations provide general guidance for handling this product.

Personal protective equipment should be selected for individual applications and should consider factors which affect exposure potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local authorities.

Exposure controls Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below TLV(s).

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Drewclean® 2000 DEGREASER 721004

Version: 1.0

Eye protection Chemical splash goggles in compliance with OSHA regulations are advised;

however, OSHA regulations also permit other type safety glasses. Consult your safety representative.

Skin and body protection

To prevent repeated or prolonged skin contact, wear impervious clothing and boots.

Wear resistant gloves such as:

Neoprene

Respiratory protection If workplace exposure limit(s) of product or any component is exceeded (see exposure guidelines), a NIOSH-approved air supplied respirator is advised in absence of proper environmental control. OSHA regulations also permit other NIOSH respirators (negative pressure type) under specified conditions (see your industrial hygienist).

Engineering or administrative controls should be implemented to reduce exposure.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state liquid Form No data Colour green Odour pleasant Boiling point/boiling range 175.50 °C / 347.9 °F@ 1,017.23 hPa Melting point/range -75 °F / -59 °C pH No data Flash point (>)142.00 °F / 61.11 °C, Pensky Martens closed cup Evaporation rate > 1 (Ethyl Ether) Explosion limits 0.6 %(V) 7 %(V) Vapour pressure 26.66 hPa @ 68 °F / 20 °C Vapour density (>) 1 (AIR=1) Density 0.790 g/cm3 @ 77 °F / 25 °C

Solubility No data Partition coefficient: n-octanol/water

No data log Pow no data available Autoignition temperature No data

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Drewclean® 2000 DEGREASER 721004

Version: 1.0

10. STABILITY AND REACTIVITY

Stability Stable.

Conditions to avoid

Incompatible products Strong oxidizing agents

Hazardous decomposition products carbon dioxide and carbon monoxide, Hydrocarbons

Hazardous reactions Product will not undergo hazardous polymerization.

Thermal decomposition No data

11. TOXICOLOGICAL INFORMATION

Acute oral toxicity ALIPHATIC HYDROCARBON LD 50 Rat: > 8,000 mg/kg CYCLIC HYDROCARBON LD 50 Rat: > 5 g/kg TERPINOLENE LD 50 Rat: 4,390 mg/kg

Acute inhalation toxicity ALIPHATIC HYDROCARBON LD 50 Rat: > 2500 ppm, 4 h

CYCLIC HYDROCARBON no data available TERPINOLENE no data available

Acute dermal toxicity ALIPHATIC HYDROCARBON LD 50 Rabbit: > 4,000 mg/kg

CYCLIC HYDROCARBON LD 50 Rabbit: > 5 g/kg

TERPINOLENE no data available

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Print Date: 4/10/2010 MSDS Number: 000000161034

Drewclean® 2000 DEGREASER 721004

Version: 1.0

12. ECOLOGICAL INFORMATION

Aquatic toxicity

Acute and Prolonged Toxicity to Fish No data Acute Toxicity to Aquatic Invertebrates No data

Environmental fate and pathways

BOD5: 160,000 mg/l

COD: 454,000 mg/l

13. DISPOSAL CONSIDERATIONS

Waste disposal methods No data

14. TRANSPORT INFORMATION

IMDG:

UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

(TERPENES, ) 9, III

IATA_P:

UN3082, Environmentally hazardous substance, liquid, n.o.s. (TERPENES, ) 9, III

IATA_C:

UN3082, Environmentally hazardous substance, liquid, n.o.s. (TERPENES, ) 9, III

CFR_ROAD:

UN3082, Environmentally hazardous substances, liquid, n.o.s. (TERPENES, ) 9, III

CFR_RAIL:

UN3082, Environmentally hazardous substances, liquid, n.o.s. (TERPENES, ) 9, III

CFR_INWTR:

UN3082, Environmentally hazardous substances, liquid, n.o.s. (TERPENES, ) 9, III

IMDG_ROAD:

UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

(TERPENES, ) 9, III

IMDG_RAIL:

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SAFETY DATA SHEET Page: 9

Print Date: 4/10/2010 MSDS Number: 000000161034

Drewclean® 2000 DEGREASER 721004

Version: 1.0

UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

(TERPENES, ) 9, III

Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment.

15. REGULATORY INFORMATION

California Prop. 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects.

SARA Hazard Classification Fire Hazard

Acute Health Hazard

SARA 313 Component(s)

Reportable quantity - Components ALIPHATIC HYDROCARBON NJTS# 254504001-5164 none CYCLIC HYDROCARBON NJTS# 254504001-5323 none TERPINOLENE 586-62-9 none

Health Flammability Reactivity Other

HMIS 3 2 1

NFPA 3 2 1

16. OTHER INFORMATION

The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by Ashland's Environmental Health and Safety Department (1-800-325-3751).

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