MSDS - AD2298-FD.pdf

SAFETY DATA SHEET

Issuing Date: 28-Feb-2012 Revision Date: 28-Sep-2016 Revision Number: 2

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Recommended use of the chemical and restrictions on use Industrial paint (Paint or Paint-Related), Restricted to professional users

2. HAZARDS IDENTIFICATION

Classification

OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Serious eye damage/eye irritation Category 2 Skin sensitization Category 1 Specific target organ toxicity (single exposure) Category 3

Label Elements

Emergency Overview

Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Avoid breathing dust/fume/gas/mist/vapors/spray Contaminated work clothing should not be allowed out of the workplace Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. - No smoking Keep container tightly closed Ground/Bond container and receiving equipment Use explosion-proof electrical/ ventilating/ lighting/ equipment Use only non-sparking tools Take precautionary measures against static discharge

Product Code: AD2298-FD Product Name: FAST DRY EPOXY CURING AGENT FOR

MIL-PRF-23377K TYPE I/II CLASS C2

Hentzen Coatings, Inc. Company Phone Number: 1-414-353-4200 6937 West Mill Road, Milwaukee, WI 53218-1225 Emergency telephone number ChemTrec 1-800-424-9300

Flammable Liquids Category 2

DANGER

Hazard Statements Causes serious eye irritation May cause an allergic skin reaction May cause drowsiness or dizziness Highly flammable liquid and vapor

Appearance Opaque Physical state Liquid

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Odor Solvent

AD2298-FD - FAST DRY EPOXY CURING AGENT FOR

MIL-PRF-23377K TYPE I/II CLASS C2

Revision Date: 28-Sep-2016

Wear protective gloves/protective clothing/eye protection/face protection Keep cool

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention If skin irritation or rash occurs: Get medical advice/attention Wash contaminated clothing before reuse IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell In case of fire: Use CO2, dry chemical, or foam for extinction

Precautionary Statements - Storage Store in a well-ventilated place. Keep container tightly closed Store in accordance with local regulations

Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC) Other information

• May be harmful if swallowed

3. COMPOSITION/INFORMATION ON INGREDIENTS

There are no known carcinogenic chemicals in this product

This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of 1990.

Chemical Name CAS No Weight-% ACGIH OSHA

ACETONE 67-64-1 70% - 80% STEL: 500 ppm TWA: 250 ppm

TWA: 1000 ppm TWA: 2400 mg/m3

BENZYL ALCOHOL 100-51-6 1% - 5% N/A N/A

TRIETHYLENETETRAMINE(TETA) 112-24-3 0% - 1% N/A N/A

4. FIRST AID MEASURES

First Aid Measures

General advice Show this safety data sheet to the doctor in attendance. If symptoms persist, call a physician.

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician. Immediately flush eyes with water for at least 15 minutes. Get medical attention. If easy to do, remove contact lenses. Keep eye wide open while rinsing.

Skin Contact Immediate medical attention is not required. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If skin irritation persists, call a physician.

Inhalation Remove to fresh air. If symptoms persist, call a physician. Immediate medical attention is not required. Move to fresh air in case of accidental inhalation of vapors.

Ingestion Immediate medical attention is not required. Rinse mouth. Drink plenty of water. Do NOT induce vomiting. Clean mouth with water and afterwards drink plenty of water. Never give anything by mouth to an unconscious person. Consult a physician if necessary.

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MIL-PRF-23377K TYPE I/II CLASS C2

Revision Date: 28-Sep-2016

Self-protection of the first aider Remove all sources of ignition. Use personal protective equipment as required.

Most important symptoms and effects, both acute and delayed

Most Important Symptoms and Effects

No information available.

Indication of any immediate medical attention and special treatment needed

Notes to physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable Extinguishing Media No information available.

Specific hazards arising from the chemical Extremely flammable.

Explosion Data Sensitivity to Mechanical Impact no data available.

Sensitivity to Static Discharge Yes.

Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal Precautions Remove all sources of ignition. Evacuate personnel to safe areas. Ensure adequate ventilation. Use personal protective equipment as required. Keep people away from and upwind of spill/leak. Avoid breathing vapors or mists. Ventilate the area.

Environmental Precautions

Environmental Precautions Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Do not flush into surface water or sanitary sewer system. Vapors are heavier than air, spread along floors and form explosive mixtures with air.

Methods and materials for containment and cleaning up

Methods for Containment Prevent further leakage or spillage if safe to do so.

Methods for Cleaning Up Pick up and transfer to properly labeled containers. Dam up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Soak up with inert absorbent material.

7. HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Ensure adequate ventilation. Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharges. Use explosion-proof electrical (ventilation and lighting) equipment. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors). Use with local exhaust ventilation. Wear protective gloves/protective clothing/eye protection/face protection. Do not breathe vapor or mist. To dissipate static electricity during transfer, ground drum and

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MIL-PRF-23377K TYPE I/II CLASS C2

Revision Date: 28-Sep-2016 connect to receiving container with bonding strap. Use only non-sparking tools.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep tightly closed in a dry and cool place. Keep in properly labeled containers. Keep containers tightly closed in a cool, well-ventilated place. Keep away from heat, sparks and flame.

Incompatible Products None known based on information supplied.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Guidelines .

Chemical Name ACGIH OSHA NIOSH IDLH

ACETONE

67-64-1 STEL: 500 ppm TWA: 250 ppm

TWA: 1000 ppm TWA: 2400 mg/m3

IDLH: 2500 ppm TWA: 250 ppm

TWA: 590 mg/m3

NIOSH IDLH: Immediately Dangerous to Life or Health

Exposure controls

Engineering Measures Showers Eyewash stations Ventilation systems.

Individual protection measures, such as personal protective equipment

Eye/Face Protection Use personal protective equipment as required.

Skin and Body Protection Chemical resistant apron.

Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.

Hygiene Measures Do not eat, drink or smoke when using this product. Regular cleaning of equipment, work area and clothing is recommended.

9. PHYSICAL AND CHEMICAL PROPERTIES

10. STABILITY AND REACTIVITY

Physical state Liquid Appearance Opaque Odor Solvent. Odor Threshold No data available pH No data available Flash Point -4 °F / -20 °C Decomposition temperature No data available Boiling Point 133 °F / 56 °C Melting Point / Melting Range No data available Freezing Point No data available Vapor Pressure @20°C (kPa) No data available Partition coefficient: No data available Vapor Density No data available Density No data available Bulk density No data available Specific Gravity 0.853874560903113 Evaporation Rate No data available Water solubility No data available Dynamic viscosity No data available Weight per Gallon (lbs/gal): 7.11

Flammability Limits in Air Upper 9.09 % Lower 1.84 %

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MIL-PRF-23377K TYPE I/II CLASS C2

Revision Date: 28-Sep-2016

Reactivity

Chemical stability Stable under recommended storage conditions.

Conditions to Avoid Extremes of temperature and direct sunlight.

Incompatible Materials None known based on information supplied.

Hazardous Decomposition Products None known based on information supplied.

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Product Information The product has not been tested

Inhalation There is no data for this product.

Eye Contact There is no data for this product.

Skin Contact There is no data for this product.

Ingestion There is no data for this product.

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50

ACETONE

67-64-1

5800 mg/kg ( Rat ) N/A 50100 mg/m3 ( Rat ) 8 h

BENZYL ALCOHOL

100-51-6

1230 mg/kg ( Rat ) 2 g/kg ( Rabbit ) 8.8 mg/L ( Rat ) 4 h

TRIETHYLENETETRAMINE(TETA)

112-24-3

2500 mg/kg ( Rat ) 550 mg/kg ( Rabbit ) N/A

Information on toxicological effects

Symptoms No information available.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Sensitization No information available.

MUTAGENIC EFFECTS No information available.

Carcinogenicity No information available.

Legend:

Reproductive Toxicity No information available.

Specific target organ systemic toxicity (single exposure)

No information available.

Specific target organ systemic toxicity (repeated exposure)

No information available.

Chronic Toxicity Avoid repeated exposure.

Target Organ Effects Central nervous system (CNS), Eyes, Respiratory system, Skin.

Aspiration hazard No information available.

Numerical measures of toxicity - Product Information

The following values are calculated based on chapter 3.1 of the GHS document .

ATEmix (oral) 4988 mg/kg ATEmix (dermal) 42561 mg/kg ATEmix (inhalation-dust/mist) 31.9 mg/l

Oral LD50 6506 mg/kg (rat) Estimated Dermal LD50 1310 mg/kg (rat) Estimated

No data available

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MIL-PRF-23377K TYPE I/II CLASS C2

Revision Date: 28-Sep-2016

12. ECOLOGICAL INFORMATION

Ecotoxicity

Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to daphnia and other aquatic invertebrates

ACETONE

67-64-1

N/A 6210 - 8120: 96 h Pimephales promelas mg/L LC50 static 4.74 - 6.33: 96 h Oncorhynchus mykiss mL/L LC50 8300: 96 h Lepomis macrochirus mg/L LC50

10294 - 17704: 48 h Daphnia magna mg/L EC50 Static 12600 - 12700: 48 h Daphnia magna mg/L

EC50

BENZYL ALCOHOL

100-51-6

N/A 10: 96 h Lepomis macrochirus mg/L LC50 static 460: 96 h Pimephales promelas mg/L LC50 static

23: 48 h water flea mg/L EC50

TRIETHYLENETETRAMINE(TETA)

112-24-3

3.7: 96 h Pseudokirchneriella subcapitata mg/L EC50 20: 72 h Pseudokirchneriella subcapitata mg/L EC50 2.5: 72 h Desmodesmus subspicatus mg/L EC50

495: 96 h Pimephales promelas mg/L LC50 570: 96 h Poecilia reticulata mg/L LC50 semi-static

31.1: 48 h Daphnia magna mg/L

EC50

Persistence and degradability No information available.

Bioaccumulation No information available.

Chemical Name Partition coefficient

ACETONE

67-64-1 -0.24

BENZYL ALCOHOL

100-51-6

1.1

TRIETHYLENETETRAMINE(TETA)

112-24-3

-1.4

Other adverse effects No information available

13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Waste treatment methods This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261).

US EPA Waste Number D001

Chemical Name RCRA - Basis for Listing RCRA - D Series Wastes

ACETONE

67-64-1 Included in waste stream: F039 N/A

This product contains one or more substances that are listed with the State of California as a hazardous waste.

Chemical Name California Hazardous Waste Status

ACETONE

67-64-1 Ignitable

14. TRANSPORT INFORMATION

DOT

UN-No UN1263 Proper shipping name Paint

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MIL-PRF-23377K TYPE I/II CLASS C2

Revision Date: 28-Sep-2016

Hazard class 3 Packing Group II Special Provisions 149, B52, IB2, T4, TP1, TP8, TP28 Description UN1263, Paint, Marine Pollutant, 3, II, RQ Emergency Response Guide Number

TDG

UN-No UN1263 Proper shipping name Paint Hazard class 3 Packing Group II Description UN1263, Paint, Marine Pollutant, 3, II

MEX

UN-No UN1263 Proper shipping name Paint Hazard class 3 Packing Group II Description UN1263, Paint, 3, II

ICAO

UN-No UN1263 Proper shipping name Paint Hazard class 3 Packing Group II Special Provisions A3, A72 Description UN1263, Paint, 3, II

IATA

UN-No UN1263 Hazard class 3 Packing Group II ERG Code 3L Special Provisions A3, A72, A192

IMDG/IMO

UN-No UN1263 Hazard class 3 Packing Group II EmS-No F-E, S-E Special Provisions 163, 367

RID

UN-No UN1263 Proper shipping name Paint Hazard class 3 Packing Group II Classification Code F1 Description UN1263, Paint, Environmentally Hazardous, 3, II

ADR/RID

UN-No UN1263 Proper shipping name Paint Hazard class 3 Packing Group II Classification Code F1 Tunnel restriction code (D/E) Special Provisions 163, 640C, 650, 367 Description UN1263, Paint, Environmentally Hazardous, 3, II, (D/E) ADR/RID-Labels 3

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ADN

Proper shipping name Paint Hazard class 3 Packing Group II Classification Code F1 Special Provisions 163, 640C, 650 Description UN1263, Paint, Environmentally Hazardous, 3, II Hazard Labels 3 Limited Quantity (LQ) 5 L Ventilation VE01

15. REGULATORY INFORMATION

International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances

US Federal Regulations

SARA 313

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard Yes Sudden Release of Pressure Hazard No Reactive Hazard No

CAA (Clean Air Act) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of 1990.

Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40

CFR 122.42)

CERCLA

This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)

Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQ (reportable quantity)

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MIL-PRF-23377K TYPE I/II CLASS C2

Revision Date: 28-Sep-2016

RQs ACETONE 5000 lb N/A RQ 5000 lb final RQ

RQ 2270 kg final RQ

State Regulations

California Proposition 65 This product does not contain any Proposition 65 chemicals

U.S. State Right-to-Know Regulations

Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode Island

ACETONE X X X N/A X

TRIETHYLENETETRAMINE

(TETA)

X X X N/A N/A

International Regulations

Mexico - Grade Serious risk, Grade 3

Chemical Name Carcinogenic Status Exposure Limits ACETONE N/A Mexico: TWA 1000 ppm

Mexico: TWA 2400 mg/m3

Mexico: STEL 1260 ppm Mexico: STEL 3000 mg/m3

16. OTHER INFORMATION

NFPA Rating

Chronic Hazard Star Legend * Chronic Health Hazard

Issuing Date: 28-Feb-2012 Revision Date: 28-Sep-2016 Revision Note No information available

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. AD2298-FD

NFPA Health Hazard 1 Flammability 3 Instability 0 Physical and Chemical Hazards -

HMIS Health Hazard 2 * Flammability 3 Physical Hazard 0 Personal protection X

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