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Text version
SDS: 0001758
Date Prepared: 05-Sep-2016
SAFETY DATA SHEET
Safety Data Sheet according to regulation (EC) No 1907/2006 & 1272/2008 and amendments
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND THE
COMPANY/UNDERTAKING
Product Identifier: BR® 127 Corrosion Inhibiting Primer, 10% Solids Product Description: Epoxy/phenolic resins in 2-butanone and tetrahydrofuran
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED AGAINST
Intended/Recommended Use: Corrosion inhibiting primer
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET
Company: Cytec Industries Inc., Five Garret Mountain Plaza, Woodland Park, New Jersey 07424, USA.
For Product and all Non-Emergency Information call 1-800/652-6013. Outside the USA and Canada call +1-973/357- 3193 or your local Cytec contact point. E-mail: custinfo@cytec.com
Local Contact Information: Cytec Industries Inc., Abenbury Way, Wrexham Industrial Estate, Wrexham Clwyd
LL139UZ, GB
Telephone: +44 1-97866-5200
EMERGENCY PHONE (24 hours/day) - For emergency only involving spill, leak, fire, exposure or accident call:
Asia Pacific:
Australia - +61-3-9663-2130 or 1800-033-111 (IXOM) China (PRC) - +86 0532 83889090 (NRCC) New Guinea - +61-3-9663-2130 or 1800-033-111 New Zealand - +61-3-9663-2130 or 0800-734-607 (IXOM) India, Japan, Korea, Malaysia, Thailand - +65 3158 1074 (Carechem24 Singapore) India (Hindi Speaking Only) - +65 3158 1198 or 000800 100 7479 (Carechem24 Singapore) Canada: +1-905-356-8310 (Cytec Welland, Canada plant) Europe/Africa/Middle East (Carechem24 UK):
Europe, Middle East, Africa, Israel - +44 (0) 1235 239 670 (Arabic speaking countries) - +44 (0) 1235 239 671 Latin America:
Brazil - 0800 7077 022 (SUATRANS) Chile - +56-2-2-247-3600 (CITUC QUIMICO) All Others - +52-376-73 74122 (Cytec Atequiza, Mexico plant) USA: +1-703-527-3887 or 1-800-424-9300 (CHEMTREC #CCN6083)
The ® indicates a Registered Trademark in the United States and the ™ indicates a trademark in the United States. The mark may also be registered, subject of an application for registration, or a trademark in other countries.
2. HAZARDS IDENTIFICATION
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE
Classification according to Regulation (EC) No 1272/2008 and amendments kimp SDS Stamp
2. HAZARDS IDENTIFICATION
Flammable Liquid Hazard Category 2 Carcinogenicity Hazard Category 1A Germ Cell Mutagenicity Hazard Category 2 Specific Target Organ Toxicity (STOT) - Single Exposure Hazard Category 3 Serious Eye Damage / Eye Irritation Hazard Category 2 Skin Sensitizer Hazard Category 1 Aquatic Environment Long-term Hazard Category 3
LABEL ELEMENTS
Signal Word Danger
Hazard Statements H225 - Highly flammable liquid and vapour.
H350 - May cause cancer.
H341 - Suspected of causing genetic defects.
H336 - May cause drowsiness or dizziness.
H319 - Causes serious eye irritation.
H317 - May cause an allergic skin reaction.
H412 - Harmful to aquatic life with long lasting effects.
EUH019 - May form explosive peroxides.
EUH066 - Repeated exposure may cause skin dryness or cracking.
Precautionary Statements Precautionary statements on the label will be reduced as indicated in Regulation (EC) No 1272/2008, Article 28.
Print Date: 05-Sep-2016 Page 2 of 20BR® 127 Corrosion Inhibiting Primer, 10% Solids
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P240 - Ground/bond container and receiving equipment.
P241 - Use explosion-proof electrical/ventilating/lighting/equipment.
P242 - Use only non-sparking tools.
P243 - Take precautionary measures against static discharge.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P201 - Obtain special instructions before use.
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
P271 - Use only outdoors or in a well-ventilated area.
P264 - Wash face, hands and any exposed skin thoroughly after handling.
P272 - Contaminated work clothing should not be allowed out of the workplace.
P273 - Avoid release to the environment.
P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P370 + P378 - In case of fire: Use CO2, dry chemical, or foam to extinguish.
P308 + P313 - IF exposed or concerned: Get medical advice/attention.
P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312 - Call a POISON CENTER or doctor/physician if you feel unwell.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 - If eye irritation persists: Get medical advice/attention.
P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention.
P321 - Specific treatment (see supplemental first aid instructions on this label).
P362 + P364 - Take off contaminated clothing and wash it before reuse.
P403 + P235 - Store in a well-ventilated place. Keep cool.
P405 - Store locked up.
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed.
P501 - Dispose of contents/container in accordance with local and national regulations.
OTHER HAZARDS
Polymerisation may occur from excessive heat, contamination or exposure to direct sunlight.
RESULTS OF PBT AND vPvB ASSESSMENT Not determined
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance, Mixture or Article? Mixture
Component / CAS No. % EC-No REACH Registration
Number
Classification according to Regulation (EC) No
1272/2008 (CLP)
M-Factor SVHC
2-Butanone (Methyl ethyl ketone) 78-93-3
45-65 201-159-0 01-2119457290-43 Flam. Liq. 2 (H225)
STOT SE 3 (H336)
Eye Irrit. 2 (H319)
Tetrahydrofuran 109-99-9
10-20 203-726-8 01-2119444314-46 Flam. Liq. 2 (H225) Carc. 2 (H351)
Acute Tox. 4 (H302)
STOT SE 3 (H335)
Eye Irrit. 2 (H319)
Diacetone alcohol 123-42-2
10-20 204-626-7 Not available Eye Irrit. 2 (H319)
Glycidyl Phenol/ Formaldehyde Polymer 28064-14-4
2-8 -- Not available Skin Irrit. 2 (H315) Skin Sens. 1 (H317)
Aquatic Chronic 2 (H411)
SDS: 0001758 Print Date: 05-Sep-2016 Page 3 of 20BR® 127 Corrosion Inhibiting Primer, 10%
Component / CAS No. % EC-No REACH Registration
Number
Classification according to Regulation (EC) No
1272/2008 (CLP)
M-Factor SVHC
Bisphenol A based epoxy resin 25036-25-3
1-5 -- Not available Skin Irrit. 2 (H315) Eye Irrit. 2 (H319)
Skin Sens. 1 (H317) Aquatic Chronic 2 (H411)
Strontium chromate 7789-06-2
1-5 232-142-6 01-2119548391-39 Carc. 1A (H350) Muta. 2 (H341)
Repr. 2 (H361fd) Acute Tox. 4 (H302) Acute Tox. 2 (H330)
STOT SE 3 (H335)
Skin Sens. 1 (H317)
Aquatic Acute 1 (H400) Aquatic Chronic 1 (H410)
1 X
Phenol 108-95-2
0.1-0.25 203-632-7 01-2119471329-32 Muta. 2 (H341) Acute Tox. 3 (H301) Acute Tox. 3 (H311) Acute Tox. 3 (H331)
STOT RE 2 (H373)
Skin Corr. 1B (H314) Aquatic Chronic 2 (H411)
Formaldehyde 50-00-0
0.01-0.06 200-001-8 01-2119488953-20 Carc. 1B (H350) B D Muta. 2 (H341)
Acute Tox. 3 (H301) B D Acute Tox. 3 (H311) B D Acute Tox. 3 (H331) B D Skin Corr. 1B (H314) B D Skin Sens. 1A (H317) B
D Methanol 67-56-1
0.1-1 200-659-6 01-2119433307-44 Flam. Liq. 2 (H225) Acute Tox. 3 (H301) Acute Tox. 3 (H311) Acute Tox. 3 (H331)
STOT SE 1 (H370)
2-Methylimidazole 693-98-1
<0.2 211-765-7 Not available Carc. 2 (H351) Repr. 1B (H360FD) Acute Tox. 4 (H302) Skin Corr. 1B (H314)
See Section 16 for full text of H phrases.
4. FIRST AID MEASURES
DESCRIPTION OF FIRST AID MEASURES
Eye Contact:
Rinse immediately with plenty of water for at least 15 minutes. Obtain medical advice if there are persistent symptoms.
Skin Contact:
Wash immediately with plenty of water and soap. Remove contaminated clothing and shoes without delay. Obtain medical attention. Do not reuse contaminated clothing without laundering. Destroy or thoroughly clean shoes before reuse.
Ingestion:
If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person. If vomiting occurs naturally, the victim should lean forward to reduce the risk of aspiration.
SDS: 0001758 Print Date: 05-Sep-2016 Page 4 of 20BR® 127 Corrosion Inhibiting Primer, 10%
Inhalation:
Remove to fresh air. If breathing is difficult, give oxygen. Obtain medical advice if there are persistent symptoms.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED
None known
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDS
Not applicable
5. FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA
Suitable Extinguishing Media:
Use water spray, alcohol foam, carbon dioxide or dry chemical to extinguish fires. Water stream may be ineffective.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE
Keep containers cool by spraying with water if exposed to fire.
ADVICE FOR FIREFIGHTERS
Protective Equipment:
Firefighters, and others exposed, wear self-contained breathing apparatus. Wear full firefighting protective clothing.
See MSDS Section 8 (Exposure Controls/Personal Protection).
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures:
Where exposure level is known, wear approved respirator suitable for level of exposure. Where exposure level is not known, wear approved, positive pressure, self-contained respirator. In addition to the protective clothing/equipment in Section 8 (Exposure Controls/Personal Protection), wear impermeable boots.
Environmental Precautions:
None known
Methods and material for containment and cleaning up:
Remove sources of ignition. Use non-sparking handtools. Cover spills with some inert absorbent material; sweep up and place in a waste disposal container. Flush spill area with water.
References to other sections:
See Sections 8 and 13 for additional information.
7. HANDLING AND STORAGE
PRECAUTIONS FOR SAFE HANDLING
Precautionary Measures: Keep away from heat, sparks and flame. Avoid contact with eyes. Avoid prolonged or repeated contact with skin. Keep container closed. Use with adequate ventilation. Wash thoroughly after handling.
Special Handling Statements: Vapour pressure of organic liquids increases with temperature. Containers must be bonded and grounded when pouring or transferring material. Provide good ventilation of working area (local exhaust ventilation if necessary).
Conditions for safe storage, including any incompatibilities:
Page 5 of 20BR® 127 Corrosion Inhibiting Primer, 10%
SDS: 0001758 Print Date: 05-Sep-2016
Areas containing this material should have fire safe practices and electrical equipment in accordance with applicable regulations and/or guidelines. Standards are primarily based on the material`s flashpoint, but may also take into account properties such as miscibility with water or toxicity. All local and national regulations should be followed.
In the Americas, National Fire Protection Association (NFPA) 30: Flammable and Combustible Liquids Code, is a widely used standard. NFPA 30 establishes storage conditions for the following classes of materials: Class I Flammable Liquids, Flashpoint <37.8 °C. Class II Combustible Liquids, 37.8 °C < Flashpoint <60 °C. Class IIIa Combustible Liquids, 60 °C < Flashpoint < 93 °C. Class IIIb Combustible Liquids, Flashpoint > 93 °C. Containers filled with this product should be kept closed when not in use, as evaporation of water and solvent may cause gelation.
Storage Temperature: Store at <=-17.8 °C Reason: Quality.
Storage Class (TRGS 510): 3
Specific end use(s):
Refer to Section 1 or Exposure Scenario if applicable.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
CONTROL PARAMETERS
109-99-9 Tetrahydrofuran
Print Date: 05-Sep-2016
United Kingdom: WEL (Workplace Exposure Limits) 50 ppm (TWA) 150 mg/m3 (TWA) (skin) 100 ppm (STEL) 300 mg/m3 (STEL)
108-95-2 Phenol
Europe ILV (Indicative Limit Values): Not established Other Value: Not established
United Kingdom: WEL (Workplace Exposure Limits)
123-42-2 Diacetone alcohol
2 ppm (TWA)
7.8 mg/m3 (TWA) (skin) 4 ppm (STEL) 16 mg/m3 (STEL)
United Kingdom: WEL (Workplace Exposure Limits) 50 ppm (TWA) 241 mg/m3 (TWA) 75 ppm (STEL) 362 mg/m3 (STEL)
BR® 127 Corrosion Inhibiting Primer, 10% Solids
Europe ILV (Indicative Limit Values): Not established
Europe ILV (Indicative Limit Values): Not established
Other Value: Not established
50-00-0 Formaldehyde United Kingdom: WEL (Workplace Exposure Limits) 2 ppm (TWA)
2.5 mg/m3 (TWA) 2 ppm (STEL)
2.5 mg/m3 (STEL)
Other Value: Not established
Derived No Effect Level (DNEL):
Use Route DNEL Units Effects Type 2-Butanone (Methyl ethyl ketone) (78-93-3) Worker Dermal 1161 mg/kg/day Long term, systemic Worker Inhalation 600 mg/m3 Long term, systemic Consumer Dermal 412 mg/kg/day Long term, systemic Consumer Inhalation 106 mg/m3 Long term, systemic Consumer Oral 31 mg/kg/day Long term, systemic
Diacetone alcohol (123-42-2) Worker Inhalation 240 mg/m3 Short term, local Worker Inhalation 66.4 mg/m3 Long term, local Worker Dermal 9.4 mg/kg/day Long term, systemic Consumer Inhalation 120 mg/m3 Short term, local Consumer Inhalation 11.8 mg/m3 Long term, local Consumer Inhalation 11.8 mg/m3 Long term, systemic Consumer Oral 3.4 mg/kg/day Long term, systemic Consumer Dermal 3.4 mg/kg/day Long term, systemic Worker Inhalation 66.4 mg/m3 Long term, systemic
Strontium chromate (7789-06-2) Worker Dermal 0.2 µg/cm2 Long term, systemic
Phenol (108-95-2) Worker Inhalation 8 mg/m3 Long term, systemic
200 ppm (TWA) 600 mg/m3 (TWA) (skin) 300 ppm (STEL) 899 mg/m3 (STEL) 70 µmol/L (urine) Butan-2-one (Health Guidance Value)
(EH40)
SDS: 0001758
67-56-1 Methanol
Europe ILV (Indicative Limit Values): Not established Other Value: Not established
United Kingdom: WEL (Workplace Exposure Limits) 200 ppm (TWA) 266 mg/m3 (TWA) (skin) 250 ppm (STEL) 333 mg/m3 (STEL)
Print Date: 05-Sep-2016
Europe ILV (Indicative Limit Values): 200 ppm (TWA) 260 mg/m3 (TWA) (skin)
108-95-2 Phenol
Other Value: Not established
7789-06-2 Strontium chromate
Europe ILV (Indicative Limit Values):
United Kingdom: WEL (Workplace Exposure Limits) 0.05 mg/m3 Cr (TWA)(as Chromium(VI) compounds)
0.15 mg/m3 Cr (STEL)(as Chromium(VI) compounds)
Not established
BR® 127 Corrosion Inhibiting Primer, 10% Solids
Europe ILV (Indicative Limit Values): Not established Other Value: Not established
Other Value: Not established
78-93-3 2-Butanone (Methyl ethyl ketone) United Kingdom: WEL (Workplace Exposure Limits)
Worker Dermal 1.23 mg/kg/day Long term, systemic Worker Inhalation 16 mg/m3 Short term, local General Population Inhalation 1.32 mg/m3 Long term, systemic General Population Dermal 0.4 mg/kg/day Long term, systemic General Population Oral 0.4 mg/kg/day Long term, systemic
Formaldehyde (50-00-0) Worker Inhalation 9 mg/m3 Long term, systemic Worker Inhalation 0.5 mg/m3 Long term, local Worker Inhalation 1 mg/m3 Short term, local Worker Dermal 240 mg/kg/day Long term, systemic Worker Dermal 37 µg/cm2 Long term, local General Population Inhalation 3.2 mg/m3 Long term, systemic General Population Inhalation 0.1 mg/m3 Long term, local General Population Dermal 102 mg/kg/day Long term, systemic General Population Dermal 12 µg/cm2 Long term, local General Population Oral 4.1 mg/kg/day Long term, systemic
Methanol (67-56-1) Worker Inhalation 260 mg/m3 Short term, systemic Worker Inhalation 260 mg/m3 Long term, systemic Worker Inhalation 260 mg/kg/day Short term, local Worker Inhalation 260 mg/m3 Long term, local Worker Dermal 40 mg/kg/day Short term, systemic Worker Dermal 40 mg/kg/day Long term, systemic Consumer Inhalation 50 mg/m3 Short term, systemic Consumer Inhalation 50 mg/m3 Long term, systemic Consumer Dermal 8 mg/kg/day Short term, systemic Consumer Dermal 8 mg/kg/day Long term, systemic Consumer Oral 8 mg/kg/day Short term, systemic Consumer Oral 8 mg/kg/day Long term, systemic Consumer Inhalation 50 mg/m3 Long term, local Consumer Inhalation 50 mg/m3 Short term, local
2-Methylimidazole (693-98-1) Worker Inhalation 0.47 mg/m3 Long term, systemic Worker Dermal 0.33 mg/kg/day Long term, systemic
Predicted No Effect Concentration (PNEC):
Compartment PNEC Units 2-Butanone (Methyl ethyl ketone) (78-93-3) Fresh water 55.8 mg/L Marine water 55.8 mg/L Intermittent water release 55.8 mg/L Sewage treatment plant 709 mg/L Sediment (fresh water) 284.7 mg/kg Soil 22.5 mg/kg Sediment (marine water) 284.7 mg/kg
Diacetone alcohol (123-42-2) Fresh water 2 mg/L Marine water 0.2 mg/L Intermittent water release 1 mg/L Sewage treatment plant 82 mg/L Sediment (fresh water) 9.06 mg/kg Sediment (marine water) 0.91 mg/kg Soil 0.63 mg/kg
SDS: 0001758 Print Date: 05-Sep-2016 Page 8 of 20BR® 127 Corrosion Inhibiting Primer, 10%
Strontium chromate (7789-06-2) Fresh water 0.005 mg/L Marine water 0.005 mg/L Intermittent water release 0.005 mg/L Sewage treatment plant 10 mg/L Sediment (fresh water) 31 mg/kg (dry weight) Sediment (marine water) 31 mg/kg (dry weight) Soil 3.2 mg/kg (dry weight)
Phenol (108-95-2) Fresh water 0.0077 mg/L Marine water 0.00077 mg/L Sediment (fresh water) 0.0915 mg/kg Sediment (marine water) 0.00915 mg/kg Soil 0.136 mg/kg Intermittent water release 0.031 mg/L Sewage treatment plant 2.1 mg/L
Formaldehyde (50-00-0) Fresh water 0.47 mg/L Marine water 0.47 mg/L Sediment (fresh water) 2.44 mg/kg Sediment (marine water) 2.44 mg/kg Soil 0.21 mg/kg Sewage treatment plant 0.19 mg/L Intermittent water release 4.7 mg/L
Methanol (67-56-1) Fresh water 154 mg/L Marine water 15.4 mg/L Intermittent water release 1540 mg/L Sewage treatment plant 100 mg/L Sediment 570.4 mg/kg Soil 23.5 mg/L
2-Methylimidazole (693-98-1) Fresh water 0.19 mg/L Marine water 0.019 mg/L Intermittent water release 19 mg/L Sewage treatment plant 193 mg/L Sediment (fresh water) 17.2 mg/kg (dry weight) Sediment (marine water) 1.72 mg/kg (dry weight) Soil 3.32 mg/kg (dry weight)
EXPOSURE CONTROLS
Engineering Measures:
Where this material is not used in a closed system, good enclosure and local exhaust ventilation should be provided to control exposure when spraying or curing at elevated temperatures.
Respiratory Protection:
Where exposures are below the established exposure limit, no respiratory protection is required.
Where exposures exceed the established exposure limit, use respiratory protection recommended for the material and level of exposure.
A full facepiece respirator also provides eye and face protection.
Cutting, grinding or sanding of parts fabricated after curing may create respirable dust particles. Respiratory protection appropriate for this dust may be required. Refer to components listed above for potential hazardous components in the dust.
Page 9 of 20BR® 127 Corrosion Inhibiting Primer, 10%
SDS: 0001758 Print Date: 05-Sep-2016
Eye protection:
Wear eye/face protection such as chemical splash proof goggles or face shield.
Eyewash equipment and safety shower should be provided in areas of potential exposure.
Skin Protection:
Avoid skin contact.
Wear impermeable gloves and suitable protective clothing.
Barrier creams may be used in conjunction with the gloves to provide additional skin protection.
Since this product is absorbed through the skin, care must be taken to prevent skin contact and contamination of clothing.
Hand protection:
Nitrile or fluorinated rubber gloves. Consider the porosity and elasticity data of the glove manufacturer and the specific conditons in the work place. Barrier creams may help to protect the exposed areas of the skin, they should however not be applied once exposure has occurred. Replace gloves immediately when torn or any change in appearance (dimension, colour, flexibility etc) is noticed.
The chemical resistance depends on the type of product and amount of product on the glove. Therefore gloves need to be changed when in contact with chemicals.
Due to many conditions (e.g. temperature, abrasion) the practical usage of a chemical protective glove in practice may be much shorter than the permeation time determined through testing.
Additional Advice:
Food, beverages, and tobacco products should not be carried, stored, or consumed where this material is in use.
Before eating, drinking, or smoking, wash face and hands thoroughly with soap and water.
It is recommended that a shower be taken after completion of workshift especially if significant contact has occurred. Work clothing should then be laundered prior to reuse. Street clothing should be stored separately from work clothing and protective equipment. Work clothing and shoes should not be taken home.
9. PHYSICAL AND CHEMICAL PROPERTIES
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES
Colour: colorless to light-yellow or blue-green Appearance: suspension Odor: strong sweet Odor Threshold: See Section 8 for exposure limits.
pH: Not available Melting Point: Not applicable Boiling Point: 80 °C (value for methyl ethyl ketone) Flash point: -6.1 °C Tag closed cupValue for MEK Evaporation Rate: 3.3 - 6.6(n-Butyl acetate = 1)(value for methyl ethyl ketone) Flammability (solid, gas): Not available Flammable Limits (% By Vol): Lower: 1.4 Upper: 11.4(values for methyl ethyl ketone) Vapor Pressure: 82 - 83 mm Hg @ 23.9 °C (value for methyl ethyl ketone) Vapour density: 2.5 (air = 1)(value for methyl ethyl ketone) Specific Gravity/Density: 0.88 Solubility In Water: Not available Partition coefficient (n-octanol/water):
Not available
Autoignition (Self) Temperature: 321.1 °C Decomposition Temperature: Not available Viscosity (Kinematic): Not available Viscosity (Dynamic): Not available
OTHER INFORMATION
Fat Solubility (Solvent-Oil): Not available
BR® 127 Corrosion Inhibiting Primer, 10%
SDS: 0001758 Print Date: 05-Sep-2016 Page 10 of 20
Percent Volatile (% by wt.): ~90 Solids Content: Not available Saturation In Air (% By Vol.): Not available Acid Number (mg KOH/g): Not available Hydroxyl Value (mg KOH/g): Not available Volatile Organic Content
(1999/13/EC):
780 - 800gm/L
Dissociation Constant: Not available Explosion Properties: Not available Oxidizing Properties: Not available Granulometry (Particle Size): Not available
DUST HAZARD INFORMATION
Particle Size (microns): Not applicable Kst (bar-m/sec): Not applicable Maximum Explosion Pressure (Pmax): Not applicable Dust Class: Not applicable Minimum Ignition Energy (MIE) (mJ): Not applicable Minimum Ignition Temperature (MIT) (°C): Not applicable Minimum Explosive Concentration (MEC) (g/m3): Not applicable Limiting Oxygen Concentration (LOC) (%): Not applicable
10. STABILITY AND REACTIVITY
Reactivity: No information available
CHEMICAL STABILITY
Stability: Stable
Conditions To Avoid: None known
POSSIBILITY OF HAZARDOUS REACTIONS
Polymerization: May occur
Conditions To Avoid: Polymerisation may occur slowly at room temperature. Store at or below -18 C (0 F) to prolong shelf life.
Incompatible materials: Strong oxidizing agents and strong bases., Strong mineral acids.
Hazardous Decomposition Products:
Carbon dioxide Carbon monoxide (CO) chromium oxides Oxides of nitrogen
11. TOXICOLOGICAL INFORMATION
INFORMATION ON TOXICOLOGICAL EFFECTS
Likely Routes of Exposure: Skin, Eyes, Oral.
Acute toxicity - oral: Not classified - Based on available data and/or professional judgment, the classification criteria are not met.
Acute toxicity - dermal: Not Classified - Based on available data and/or professional judgment, the classification criteria are not met.
Acute toxicity - inhalation: Not Classified - Based on available data and/or professional judgment, the classification criteria are not met.
SDS: 0001758 Print Date: 05-Sep-2016 Page 11 of 20BR® 127 Corrosion Inhibiting Primer, 10%
Skin corrosion / irritation: Not Classified - Based on available data and/or professional judgment, the classification criteria are not met.
Serious eye damage / eye irritation: Causes serious eye irritation.
Respiratory sensitization: Not Classified - Based on available data and/or professional judgment, the classification criteria are not met.
Skin sensitization: May cause an allergic skin reaction.
Carcinogenicity: May cause cancer.
Germ cell mutagenicity: Suspected of causing genetic defects.
Reproductive toxicity: Not Classified. - Based on available data and/or professional judgment, the classification criteria are not met.
Specific target organ toxicity (STOT) - single exposure: May cause drowsiness or dizziness.
Specific target organ toxicity (STOT) - repeated exposure: Not Classified - Based on available data and/or professional judgment, the classification criteria are not met.
Aspiration hazard: Not Classified - Based on available data and/or professional judgment, the classification criteria are not met.
PRODUCT TOXICITY INFORMATION
ACUTE TOXICITY DATA
LOCAL EFFECTS ON SKIN AND EYE
ALLERGIC SENSITIZATION
GENOTOXICITY
Assays for Gene Mutations
OTHER INFORMATION
The product toxicity information above has been estimated.
HAZARDOUS INGREDIENT TOXICITY DATA
Acute Irritation rat
Skin No data
Acute LD50
Acute Irritation
BR® 127 Corrosion Inhibiting Primer, 10% Solids eye
.>2000 mg/kg
Irritating dermal
Sensitization Skin Sensitizing rabbit
SDS: 0001758
Sensitization
Acute LD50 respiratory No data
.>2000 mg/kg inhalation
Ames Salmonella Assay
Print Date: 05-Sep-2016
No data rat Acute LC50 4 hr .>20 mg/l (Vapors) oral
Tetrahydrofuran (THF) has acute oral (rat) and dermal (rabbit) LD50 values of 1650 mg/kg and 2000-3160 mg/kg, respectively. The 3-hour inhalation LC50 (rat) value is 21000 ppm (52.7 mg/L/4hr). Tetrahydrofuran in concentrations greater than 20% are moderately irritating to the eyes, nose and respiratory tract. Tetrahydrofuran also causes moderate skin irritation, without sensitization. Based on acute inhalation studies in rats, tetrahydrofuran is not acutely neurotoxic. Acute inhalation exposure to tetrahydrofuran caused sedation in rats (central nervous system depression) at doses of 5000 ppm and 2500 ppm. All rats recovered fully after removal from exposure and no other clinical signs were observed. Subchronic inhalation exposure to high levels (5000 ppm) of THF produced liver effects and gastrointestinal irritation in laboratory animals. In a developmental toxicity test, inhalation of THF caused fetotoxic effects in laboratory animals. In a two year cancer study with rats and mice exposed by inhalation, THF produced kidney tumors in the male rats and liver tumors in the female mice.
Print Date: 05-Sep-2016
Diacetone alcohol has acute oral (rat) and dermal (rabbit) LD50 values of 3002 mg/kg and 13,500 mg/kg, respectively. The 8-hour inhalation LC50 (rat) value is >1000 ppm (9.48 mg/L/4hr). Acute overexposure to diacetone alcohol vapor may cause severe eye and respiratory irritation. Direct contact with liquid diacetone alcohol may cause mild skin irritation.
Glycidyl Phenol/Formaldehyde Polymer has acute oral (rat) and dermal (rabbit) LD50 values of >5000 mg/kg and 4000 mg/kg, respectively. Direct contact may cause mild eye irritation. Prolonged or repeated dermal exposure may cause irritation. This material may cause allergic skin reactions in rare instances. This polymer has been reported to have tested positive for mutagenicity in the standard Ames screening test as well as in a mouse lymphoma cell point mutation assay.
2-Butanone (MEK) has acute oral (rat) and dermal (rabbit) LD50 values of 2700 mg/kg and 6500 mg/kg, respectively. The acute inhalation (rat) LC50 following a 2-hour exposure is 4000 ppm (8.3 mg/L/4hr). Acute exposure to 2-Butanone (MEK) vapor may cause eye and respiratory tract irritation, central nervous system depression, headache, nausea, dizziness and staggered gait. 2-Butanone (MEK) causes moderate to severe eye and mild to moderate skin irritation upon contact. Chronic exposure to 2-Butanone (MEK) vapor may cause central nervous system depression and sleepiness. In a teratogenicity study, pregnant rats inhaled 0, 400, 1000, or 3000 ppm 2-Butanone for 7 hr/day on days 6 through 15 of gestation. Exposure at these levels did not cause any serious birth defects. A few minor malformations were observed at 3000 ppm. At this level, maternal toxicity, evidenced by decreased weight gain and water intake, was observed. In another teratogenicity study, minor malformations were also observered, however, no signs of maternal toxicity were noted. MEK is reported to have shown positive results in a screening test for mutagenicity using the S. cerevisiae strain of yeast. Absorption of a high dose of MEK caused death in laboratory animals. Human ingestion of MEK has caused central nervous system effects and aspiration has caused sudden death in laboratory animal tests.
BR® 127 Corrosion Inhibiting Primer, 10% Solids
BBisphenol A based epoxy resin has acute oral (rat) and dermal (rabbit) LD50 values of 30 g/kg and >2000 mg/kg.
A 4-hour inhalation LC50 (rat) value of >700 mg/m3 has been reported. Prolonged or repeated exposure may cause primary skin irritation and allergic skin reactions in some instances. Mechanical action of this resin may cause eye irritation upon contact. This resin has Bisphenol A based epoxy resin has acute oral (rat) and dermal (rabbit) LD50 values of 30 g/kg and >2000 mg/kg. A 4-hour inhalation LC50 (rat) value of >700 mg/m3 has been reported.
Prolonged or repeated exposure may cause primary skin irritation and allergic skin reactions in some instances.
Mechanical action of this resin may cause eye irritation upon contact. This resin has produced moderate eye irritation in laboratory animals. This resin has been reported to have tested positive for mutagenicity in the standard Ames screening test as well as in a mouse lymphoma cell point mutation assay. The literature reports several cases of asthmatic symptoms developing in workers due to occupational exposure to this resin. Large oral doses of Bisphenol A based epoxy resin have produced central nervous system effects in laboratory animals.
Strontium chromate has estimated acute oral (rat) and estimated acute dermal (rabbit) and LD50 values of >300- 2000 mg/kg and >2000 mg/kg, respectively. The acute (aerosol) 4-hr inhalation (rat) LC50 ranges from 0.27-0.51 mg/L. Direct contact with this material is not expected to produce skin irritation but may produce mild eye irritation.
Inhalation exposure to dust/mist may cause respiratory tract irritation. Prolonged or repeated contact may cause dermal sensitization. Based on in vitro and in vivo testing with hexavalent chromium, strontium chromate may be expected mutagenic, genotoxic or clastogenic. Testing with structurally similar substances, (soluble chromates) have shown the ability to potentially damage fertility or the unborn offspring. Hexavalent chromium has been associated with malignancies of the lung in rats and humans following inhalation exposure and is classified as a known human carcinogen via the inhalation route. Carcinomas and sarcomas have also been found in mouse skin.
Strontium chromate is classified as Carcinogenic to Humans by IARC (Group1).
BR® 127 Corrosion Inhibiting Primer, 10% Solids
SDS: 0001758
Phenol has acute oral (rat) and acute dermal (rabbit) LD50 values of >50-300 mg/kg and 630-660 mg/kg, respectively. The acute inhalation (aerosol) LC50 (rat/4 hour) value is estimated to be >0.5 - 1.0 mg/L. Direct contact with this material is expected to cause severe skin burns and eye damage. Exposure by any route (oral, dermal, inhalation) can cause effects on the heart and nervous system including changes in heart rate, blood pressure, respiration, as well as tremors and lung disorders, possibly resulting in death. Ingestion of phenol may also cause damage to the liver and muscle fibers and gastrointestinal, circulatory and urinary systems. Chronic dermal exposure can cause digestive disturbances, liver and kidney damage. Chronic ingestion caused a decrease in red blood cell numbers and a decrease in immune response. Chronic inhalation in laboratory animals caused liver and kidney damage. Based on battery of reported in vitro and in vivo studies, this substance is suspected of causing genetic defects. Phenol was not carcinogenic in mice or rats.
Print Date: 05-Sep-2016
Formaldehyde is considered toxic if swallowed, in contact with skin and if inhaled. With acute oral (rat), acute dermal (rabbit) and acute (inhalation) 4-hr (rat-gas) LD/LC50 values of >50 </= 300 mg/kg, >500 </= 1000 mg/kg and >500 </= 2500 ppm, respectively. When formaldehyde is present in the air at levels exceeding 0.1 ppm, some individuals may experience adverse effects such as watery eyes; burning sensations in the eyes, nose, and throat;
coughing; wheezing; nausea; and skin irritation. Some people are very sensitive to formaldehyde, whereas others have no reaction to the same level of exposure. Normal breathing may be seriously impaired at levels above 10 ppm and serious lung damage can occur at levels exceeding 50 ppm. Formaldehyde has been reported to cause pulmonary hypersensitivity in some individuals who were exposed to concentrations known to cause irritation;
however, no pulmonary sensitization has been demonstrated in laboratory animal studies. Direct contact with formaldehyde solutions can cause severe eye irritation and corrosion to the skin. Repeated or prolonged exposure to this substance may cause dermal sensitization. Formaldehyde was found to be mutagenic in a number of in vitro genotoxicity tests and positive in certain in vivo screening tests for mutagenicity. Formaldehyde did not cause birth defects in rats inhaling concentrations up to 10 ppm. In an oral gavage study 29 -76 pregnant mice per dose group were exposed to 0, 74, 148, 185 mg/kg bw/day formaldehyde (concentration of applied solution: 0, 0.7, 1.5, 1.8%) once daily at gestation day 6-15 (termination at gestation day 19). Maternal toxicity was obvious at 74 mg/kg bw/day (decreased body weight gain); data on local effects in the gastro-intestinal tract are not available, however, these effects were expected even at the low dose level. No embryo- or fetotoxic effects and no teratogenic effects were reported at any dose level, although 185 mg/kg bw/day resulted in a high mortality rate in pregnant mice.
There is no existing data (by any route) that conclusively show adverse reproductive or developmental effects in animals exposed to formaldehyde. The International Agency for Research on Cancer (IARC) has classified formaldehyde as a Group 1 (known) human carcinogen based on epidemiological evidence linking formaldehyde exposure to the occurrence of nasopharyngeal cancer, a rare type of cancer. IARC also found limited evidence of cancer of the nasal cavity and paranasal sinuses and sufficient evidence for an association between formaldehyde and leukemia.
12. ECOLOGICAL INFORMATION
TOXICITY, PERSISTENCE AND DEGRADABILITY, BIOACCUMULATIVE POTENTIAL, MOBILITY IN SOIL, OTHER
ADVERSE EFFECTS
Aquatic Chronic Toxicity: Harmful to aquatic life with long lasting effects
The ecological assessment for this material is based on an evaluation of its components.
MOBILITY IN SOIL
Not available
RESULTS OF PBT AND vPvB ASSESSMENT Not determined
HAZARDOUS INGREDIENT TOXICITY DATA
Methanol has acute oral (rat) and dermal (rabbit) LD50 values of >5600 mg/kg and 15800 mg/kg, respectively. The 4-hour inhalation exposure LC50 (rat) for methanol vapor is 64,000 ppm (83.78 mg/L). Acute exposure to methanol vapor may cause headache and gastrointestinal irritation. Chronic or extreme inhalation exposure to vapors can cause blurred vision, serious eye damage, central nervous depression and death. Ingestion and inhalation of methanol has caused blindness in humans. Ingestion can also cause harmful effects on the central nervous system and gastrointestinal systems and can lead to death in extreme cases. Absorption of methanol can cause systemic toxicity. It has been reported that chronic skin absorption of methanol has caused ocular disturbances and blindness. Methanol has produced fetotoxicity in rats and teratogenicity in mice exposed by inhalation to high concentrations that did not produce significant maternal toxicity. Methanol is not considered to be a reproductive toxin. Literature also reports an oral (rat) LD50 value of 13.0 ml/kg (10g/kg).
BR® 127 Corrosion Inhibiting Primer, 10% Solids
SDS: 0001758
2-Methylimidazole has acute oral (rat) and acute dermal (rat) LD50 values of 1500 mg/kg and >2000 mg/kg, respectively. Direct contact with this material causes severe skin burns and eye damage. This material did not produce dermal sensitization in the Local Lymph Node Assay. 2-Methylimidazole was not mutagenic in the Ames Assay but was shown to have both positive and negative results in the in vivo Rat/Mouse Micronucleus Assays. A reproduction/developmental toxicity screening test was conducted in male and female rats (10/sex/group). The animals were dosed by oral gavage at dose levels of 50, 150 and 500 mg/kg bw/day. Mortality (shortly after parturition) and slightly reduced body weight and food consumption was seen in females at 500 mg/kg bw/day.
Males showed no adverse effect up to 500 mg/kg bw/day. Increased gestation length and reduced live birth index was noted in females at 500 mg/kg bw/day. No adverse effect on reproduction parameters were noted in the males. The presence of dissecting aneurysms in the great vessels of the heart was noted at the lowest dose tested (50 mg/kg bw/day). Groups of 25 pregnant female rats received the 2-Methylimidazole by oral gavage at dose levels of 0, 2, 10 or 50 mg/kg/day from gestation day 6 through day 3 of lactation. No signs of maternal toxicity were observed up to 50 mg/kg bw/day. The presence of dissecting aneurysms in the great vessels of the heart was noted in the pups from dams dosed at 10 mg/kg bw/day and above. The No-Observed-Adverse-Effect Level (NOAEL) for maternal toxicity was established at 50 mg/kg/day and the NOAEL for fetal development was considered to be 2 mg/kg bw/day. In a Combined Chronic Toxicity/ Carcinogenicity Study rats fed, daily for two years showed increased an incidence of hepatocellular adenoma or carcinoma. This substance is listed as an IARC Group 2B - Possibly carcinogenic to humans.
Print Date: 05-Sep-2016
Component / CAS No. Toxicity to Algae Toxicity to Fish Toxicity to Water Flea 2-Butanone (Methyl ethyl ketone) 78-93-3
Not available LC50 3130 - 3320 mg/L - Pimephales promelas (96h) flow-through
EC50 > 520 mg/L - Daphnia magna (48h)
EC50 = 5091 mg/L - Daphnia magna (48h)
EC50 4025 - 6440 mg/L - Daphnia magna (48h) Static
Tetrahydrofuran 109-99-9
Not available LC50 1970 - 2360 mg/L - Pimephales promelas (96h) flow-through LC50 2700 - 3600 mg/L -
Pimephales promelas (96h) static
Not available
Diacetone alcohol 123-42-2
Not available LC50 = 420 mg/L - Lepomis macrochirus (96h) static
LC50 = 420 mg/L - Lepomis macrochirus (96h)
Not available
Glycidyl Phenol/ Formaldehyde Polymer 28064-14-4
Not available Not available Not available
Bisphenol A based epoxy resin 25036-25-3
Not available Not available Not available
Strontium chromate 7789-06-2
LC/EC50 <1 mg/L (estimated) - Algae (72h)
LC/EC50 <1 mg/L (estimated) - Fish (96h)
LC/EC50 <1 mg/L (estimated) - Algae (48h)
Phenol 108-95-2
EbC50 = 61.1 mg/L (nominal) - Green Algae (96h)
LC50 = 24.9-67.5 mg/L (measured) - Fathead Minnows
(96h) flow-through LC50 = 8.9 mg/L (measured) -
Rainbow Trout (96h) flow-through
EC50 = 3.1 mg/L (measured) - Ceriodaphnia dubia (48h) semi-static
Formaldehyde 50-00-0
EC50 estimated 10-100 mg/L LC50 estimated 10-100 mg/L EC50 estimated 10-100 mg/L
Methanol 67-56-1
Not available LC50 13500 - 17600 mg/L - Lepomis macrochirus (96h) flow-through LC50 > 100 mg/L - Pimephales promelas (96h) static LC50 18 - 20 mL/L -
Oncorhynchus mykiss (96h) static
LC50 19500 - 20700 mg/L - Oncorhynchus mykiss (96h) flow-through LC50 = 28200 mg/L -
Pimephales promelas (96h) flow-through
Not available
2-Methylimidazole 693-98-1
Not available Not available Not available
13. DISPOSAL CONSIDERATIONS
Waste Treatment Methods The Company encourages the recycle, recovery and reuse of materials, where permitted. If disposal is necessary, The Company recommends that organic materials, especially when classified as hazardous waste, be disposed of by thermal treatment or incineration at approved facilities. All local and national regulations should be followed.
14. TRANSPORT INFORMATION
SDS: 0001758 Print Date: 05-Sep-2016 Page 16 of 20BR® 127 Corrosion Inhibiting Primer, 10%
14. TRANSPORT INFORMATION
This section provides basic shipping classification information. Refer to appropriate transportation regulations for specific requirements.
ADR/RID/ADN
Dangerous Goods? X Proper Shipping Name: Flammable liquid, n.o.s.
Class: 3 UN Number: UN1993 Packing Group: II Transport Label Required: Flammable liquid Technical Name (N.O.S.): tetrahydrofuran, 2-Butanone Tunnel restriction code: D/E Comments: Not intended for shipment by inland waterways in tank vessels.
IMO
Dangerous Goods? X Proper Shipping Name: Flammable liquid, n.o.s.
Hazard Class: 3 UN Number: UN1993 Packing Group: II Transport Label Required: Flammable liquid Technical Name (N.O.S.): tetrahydrofuran, 2-Butanone
ICAO / IATA
Dangerous Goods? X Proper Shipping Name: Flammable liquid, n.o.s.
Hazard Class: 3 Packing Group: II UN Number: UN1993 Transport Label Required: Flammable liquid Technical Name (N.O.S.): tetrahydrofuran, 2-Butanone
15. REGULATORY INFORMATION
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS / LEGISLATION SPECIFIC FOR THE SUBSTANCE OR
MIXTURE
Ozone Depleting Substances (Regulation (EC) No 1005/2009): Not applicable Persistent Organic Pollutants (Regulation (EC) No 850/2004): Not applicable Prior Informed Consent (Regulation (EC) No 689/2008): Not applicable Substances subject to Authorization (Annex XIV of Regulation (EC) No 1907/2006): Yes
Substances subject to Restrictions for certain applications(Annex XVII of Regulation(EC)No 1907/2006):
Yes Refer to Annex XVII of REACH for details of the restricted applications.
2-Butanone (Methyl ethyl ketone) (45-65 %)
BR® 127 Corrosion Inhibiting Primer, 10% Solids
This substance is a flammable restricted for aerosols under item 40.
Tetrahydrofuran (10-20 %)
SDS: 0001758
This substance is a flammable restricted for aerosols under item 40.
Print Date: 05-Sep-2016
Arsenic (0 %)
Strontium chromate (1-5 %)
This substance is restricted under item 19.
Strontium chromate (1-5 %)
This is a carcinogen substance restricted under item 28.
Water Endangering Class (Germany): 2 according to VwVwS, 17.05.1999
Inventory Information
European Economic Area (including EU): Cytec has appointed an Only Representative to relieve our customers from their registration requirements under the REACH Regulation (EC) No. 1907/2006. Please contact us if you wish to benefit from the OR arrangement.
United States (USA):
All components of this product are included on the TSCA Chemical Inventory or are not required to be listed on the TSCA Chemical Inventory.
Canada:
All components of this product are included on the Domestic Substances List (DSL) or are not required to be listed on the DSL.
Australia: All components of this product are included in the Australian Inventory of Chemical Substances (AICS) or are not required to be listed on AICS.
China: All components of this product are included on the Chinese inventory or are not required to be listed on the Chinese inventory.
Japan: All components of this product are included on the Japanese (ENCS) inventory or are not required to be listed on the Japanese inventory.
Korea: All components of this product are included on the Korean (ECL) inventory or are not required to be listed on the Korean inventory.
Philippines: One or more components of this product are NOT included on the Philippine (PICCS) inventory.
Switzerland: All components of this product are exempt from the new substance notification requirements for Switzerland (SR 813.11 art. 16-17).
Taiwan: All components of this product are included on the Taiwan Chemical Substance Inventory (TCSI) or are not required to be listed on the Taiwan inventory.
CHEMICAL SAFETY ASSESSMENT
No Chemical Safety Assessment has been carried out.
16. OTHER INFORMATION
Reasons for Issue: Revised Section 3
Revised Section 11 Revised Section 16
Date Prepared: 05-Sep-2016 Date of last significant revision: 05-Sep-2016
Classification methods include one or more of the following: use of specific product data, read-across data, modeling, professional judgment or a component based evaluation.
Component Hazard Phrases
SDS: 0001758
2-Butanone (Methyl ethyl ketone)
Print Date: 05-Sep-2016
H225 - Highly flammable liquid and vapour.
H319 - Causes serious eye irritation.
H336 - May cause drowsiness or dizziness.
Strontium chromate (1-5 %)
Tetrahydrofuran
Page 18 of 20BR® 127 Corrosion Inhibiting Primer, 10%
Prepared By: Legal & Compliance Services; E-mail: custinfo@cytec.com
Diacetone alcohol
H350 - May cause cancer.
H341 - Suspected of causing genetic defects.
H361fd - Suspected of damaging fertility. Suspected of damaging the unborn child.
H302 - Harmful if swallowed.
H330 - Fatal if inhaled.
H335 - May cause respiratory irritation.
H317 - May cause an allergic skin reaction.
H400 - Very toxic to aquatic life.
H410 - Very toxic to aquatic life with long lasting effects.
BR® 127 Corrosion Inhibiting Primer, 10% Solids
Phenol H301 - Toxic if swallowed.
H311 - Toxic in contact with skin.
H314 - Causes severe skin burns and eye damage.
H331 - Toxic if inhaled.
H341 - Suspected of causing genetic defects.
H373 - May cause damage to organs through prolonged or repeated exposure.
H411 - Toxic to aquatic life with long lasting effects.
H319 - Causes serious eye irritation.
Formaldehyde
SDS: 0001758
H301 - Toxic if swallowed.
H311 - Toxic in contact with skin.
H314 - Causes severe skin burns and eye damage.
H317 - May cause an allergic skin reaction.
H331 - Toxic if inhaled.
H341 - Suspected of causing genetic defects.
H350 - May cause cancer.
Glycidyl Phenol/ Formaldehyde Polymer
Methanol H225 - Highly flammable liquid and vapour.
H301 - Toxic if swallowed.
H311 - Toxic in contact with skin.
H331 - Toxic if inhaled.
H370 - Causes damage to organs.
H315 - Causes skin irritation.
H317 - May cause an allergic skin reaction.
H411 - Toxic to aquatic life with long lasting effects.
2-Methylimidazole
Print Date: 05-Sep-2016
H302 - Harmful if swallowed.
H314 - Causes severe skin burns and eye damage.
H351 - Suspected of causing cancer.
H360FD - May damage fertility. May damage the unborn child.
Bisphenol A based epoxy resin
H225 - Highly flammable liquid and vapour.
H351 - Suspected of causing cancer.
H302 - Harmful if swallowed.
H335 - May cause respiratory irritation.
H319 - Causes serious eye irritation.
H315 - Causes skin irritation.
H317 - May cause an allergic skin reaction.
H319 - Causes serious eye irritation.
H411 - Toxic to aquatic life with long lasting effects.
Strontium chromate
This information is given without any warranty or representation. We do not assume any legal responsibility for same, nor do we give permission, inducement, or recommendation to practice any patented invention without a license. It is offered solely for your consideration, investigation, and verification. Before using any product, read its label.
Print Date: 05-Sep-2016 Page 20 of 20BR® 127 Corrosion Inhibiting Primer, 10%
BR
127 CORROSION INHIBITING PRIMER
TE CH N ICA L DA T A SHE E T
A E A D - 0 00 2 2 R E V : 0 1 0 A U G U S T 2 01 0
DESCRIPTION
BR® 127 corrosion inhibiting primer is a modified epoxy primer. It is the industry standard for high-performance corrosion inhibiting primers and has been used in virtually every commercial aircraft built since its introduction.
BR 127 primer can be used with essentially all 250°F (121°C) film adhesives and has been designed to provide optimal structural performance at temperatures ranging from -67°F to 300°F (-55°C to 149°C).
BR 127 primer is formulated to provide maximum environmental resistance and durability within the bond line, as well as prevent corrosive undercutting. It can also be used effectively as a protective coating outside bonded areas.
BR 127 corrosion inhibiting primer can be cured prior to bonding. Recommended cure cycles range from 4 hours at 180°F (82°C) to 30 minutes at 250°F (121°C).
Articles primed with BR 127 primer and then cured have an indefinite shelf life. Primed details should be wrapped in Kraft paper (as protection from dust and dirt) and stored prior to adhesive bonding.
Maintaining controlled conditions of 85°F (29°C) maximum temperature and 65% maximum humidity is recommended for extended storage life.
Cure cycles for adhesive films primed with BR 127 primer may vary from 200°F to 350°F (93°C to 177°C) with minimum pressures to assure proper mating of bonded details.
FEATURES & BENEFITS
Industry-wide standard for corrosion resistant primers
Prevents hydrolysis of oxide layers
Structural performance from -67F to 300F (-55C to 149C)
Compatible with a wide variety of adhesive systems
Improves hydrolytic stability at the adhesive-to-metal interface
Protects prepared surfaces from further oxidation
127 CORROSION INHIBITING PRIMER
TE CH N ICA L DA T A SHE E T
A E A D - 0 00 2 2 R E V : 0 www.cytec.com
CHARACTERISTICS
Table 1 | Product Description
Color Yellow
Solids 10% ± 1% sprayable
Density 7.3 lb/gal (875 g/liter)
Volatile organic content 6.6 lb/gal (792 g/liter)
Out-gassing properties
0.48% TML, 0.03% CVCM
Shop life at 75F (24C) 10 days
Shop life at 90F (32C) 5 days
Shelf life at recommended storage 12 months
Recommended storage Store at or below 0F (-18C)
NASA reference publication 1124, GSC 10164-reference number)
Complimentary Products
The following products are recommended for use with BR 127 corrosion inhibiting primer:
FM® 73 film adhesive
FM® 87 film adhesive
FM® 94 film adhesive
BR® 95 past adhesive
FM® 123-2 film adhesive
FM® 123-5 film adhesive
FM® 300 film adhesive
FM® 300-1 film adhesive
FM® 300-2 film adhesive
127 CORROSION INHIBITING PRIMER
TE CH N ICA L DA T A SHE E T
A E A D - 0 00 2 2 R E V : 0
PROPERTIES
Table 2 | Physical Properties of Structural Adhesives Cured with BR 127
Property Condition
FM 73
adhesive
FM 87-1 K
Tensile shear, psi (MPa)
(Federal standard MMM-A-132A)
-67F (-55C) 6650 (45.9) 5500 (38.0)
75F (24C) 6500 (44.9) 6700 (46.2)
180F (82C) 4340 (29.9) 4120 (28.4)
250F (120C) 1040 (7.2) 3250 (22.4)
Wide area lap shear, psi (MPa)
(Federal standard MMM-A-132A)
-67F (-55C) 5460 (37.6) 5490 (37.9)
75F (24C) 5100 (35.2) 5200 (35.9)
180F (82C) 4080 (28.2) 4200 (29.0)
250F (120C) 1410 (9.7) 2710 (18.7)
Metal-to-metal climbing drum peel, in-lb/in (Nm/m)
(ASTM-D-1781-76)
-67F (-55C) 73 (325) 63 (280)
75F (24C) 95 (423) 73 (325)
180F (82C) 130 (578) 75 (334)
250F (120C) 68 (302) 57 (254)
Floa…
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