Exhibit C - MSDS_JP5-JA1.pdf
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- Solicitation number
- SPE602-25-D-0702
- Issued by
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Defense Logistics Agency Energy
About this file
This Safety Data Sheet (SDS) provides comprehensive safety and hazard information for Aviation Turbine Jet Fuel, specifically Jet A, Jet A-1, Jet A-50, and other variants such as JP-8, JP-5, and F-34. The document, issued by Petro Star Inc. in Anchorage, Alaska, details the product's physical and chemical properties, potential health and environmental hazards, and recommended safety precautions.
Key details include the fuel's classification as a flammable liquid with potential acute and chronic toxicity to aquatic environments. The SDS highlights significant risks such as skin irritation, potential drowsiness or dizziness when exposed, and the possibility of fatal consequences if swallowed and entering airways. Safety recommendations include using protective equipment, avoiding direct contact, ensuring proper ventilation, and taking precautions against static discharge and fire. The document provides emergency contact information (800-633-8253) and specifies proper handling, storage, and disposal procedures to minimize health and environmental risks.
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Aviation Turbine Jet Fuel Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Revision Date: 02/24/2017 Date of Issue: 02/08/2017 Version: 1.0
02/24/2017 EN (English US) 1/7
SECTION 1: IDENTIFICATION
1.1. Product Identifier
Product Form: Mixture Product Name: Aviation Turbine Jet Fuel Synonyms: Jet A, Jet A-1, Jet A-50, Aviation Fuel, Turbine Engine Fuel, JP-8, JP-5 and F-34
1.2. Intended Use of the Product
Use of the Substance/Mixture: Fuel.
1.3. Name, Address, and Telephone of the Responsible Party
Company Petro Star Inc 3900 C Street Suite 4 Anchorage, Alaska 99503-5963 907-339-6600 http://www.petrostar.com/
1.4. Emergency Telephone Number
Emergency Number : 800-633-8253
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the Substance or Mixture
GHS-US Classification Flam. Liq. 3 H226 Skin Irrit. 2 H315
STOT SE 3 H336
Asp. Tox. 1 H304 Aquatic Acute 2 H401 Aquatic Chronic 2 H411 Full text of hazard classes and H-statements : see section 16
2.2. Label Elements
GHS-US Labeling Hazard Pictograms (GHS-US) :
GHS02
GHS07
GHS08
GHS09
Signal Word (GHS-US) : Danger
Hazard Statements (GHS-US) : H226 - Flammable liquid and vapor.
H304 - May be fatal if swallowed and enters airways.
H315 - Causes skin irritation.
H336 - May cause drowsiness or dizziness.
H401 - Toxic to aquatic life.
H411 - Toxic to aquatic life with long lasting effects.
Precautionary Statements (GHS-US) : P210 - Keep away from extremely high or low temperatures, ignition sources, and incompatible materials. - No smoking.
P240 - Ground/Bond container and receiving equipment.
P241 - Use explosion-proof electrical, ventilating, and lighting equipment.
P242 - Use only non-sparking tools.
P243 - Take precautionary measures against static discharge.
P261 - Avoid breathing vapors, mist, or spray.
P264 - Wash hands, forearms, and other exposed areas thoroughly after handling.
P271 - Use only outdoors or in a well-ventilated area.
P273 - Avoid release to the environment.
P280 - Wear protective gloves, protective clothing, and eye protection.
P301+P310 - If swallowed: Immediately call a poison center or doctor.
P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
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P304+P340 - If inhaled: Remove person to fresh air and keep at rest in a position comfortable for breathing.
P312 - Call a poison center or doctor if you feel unwell.
P321 - Specific treatment (see section 4 on this SDS).
P331 - Do NOT induce vomiting.
P332+P313 - If skin irritation occurs: Get medical advice/attention.
P362+P364 - Take off contaminated clothing and wash it before reuse.
P370+P378 - In case of fire: Use appropriate media (see section 5) to extinguish.
P391 - Collect spillage.
P405 - Store locked up.
P501 - Dispose of contents/container in accordance with local, regional, national, and international regulations.
P403+P233+P235 - Store in a well-ventilated place. Keep container tightly closed.
Keep cool.
2.3. Other Hazards
Exposure may aggravate pre-existing eye, skin, or respiratory conditions.
2.4. Unknown Acute Toxicity (GHS-US)
No data available
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixture
Name Product Identifier % GHS-US classification Kerosine, petroleum, hydrodesulfurized (CAS No) 64742-81-0 0 - 100 Flam. Liq. 3, H226
Skin Irrit. 2, H315
STOT SE 3, H336
Asp. Tox. 1, H304 Aquatic Chronic 2, H411
Kerosine, petroleum (CAS No) 8008-20-6 0 - 100 Flam. Liq. 3, H226 Skin Irrit. 2, H315
STOT SE 3, H336
Asp. Tox. 1, H304 Aquatic Acute 2, H401 Aquatic Chronic 2, H411
Full text of H-phrases: see section 16
SECTION 4: FIRST AID MEASURES
4.1. Description of First-aid Measures
First-aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).
First-aid Measures After Inhalation: When symptoms occur: go into open air and ventilate suspected area. Obtain medical attention if breathing difficulty persists.
First-aid Measures After Skin Contact: Remove contaminated clothing. Drench affected area with water for at least 15 minutes.
Obtain medical attention if irritation develops or persists.
First-aid Measures After Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention.
First-aid Measures After Ingestion: Do NOT induce vomiting. Rinse mouth. Immediately call a POISON CENTER or doctor/physician.
4.2. Most Important Symptoms and Effects Both Acute and Delayed Symptoms/Injuries: Causes skin irritation. May cause drowsiness and dizziness. May be fatal if swallowed and enters airways.
Symptoms/Injuries After Inhalation: High concentrations may cause central nervous system depression such as dizziness, vomiting, numbness, drowsiness, headache, and similar narcotic symptoms.
Symptoms/Injuries After Skin Contact: Redness, pain, swelling, itching, burning, dryness, and dermatitis.
Symptoms/Injuries After Eye Contact: May cause slight irritation to eyes.
Symptoms/Injuries After Ingestion: Aspiration into the lungs can occur during ingestion or vomiting and may cause lung injury.
4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed If exposed or concerned, get medical advice and attention. If medical advice is needed, have product container or label at hand.
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SECTION 5: FIRE-FIGHTING MEASURES
5.1. Extinguishing Media
Suitable Extinguishing Media: Dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). Water may be ineffective but water should be used to keep fire-exposed container cool.
Unsuitable Extinguishing Media: Do not use a heavy water stream. A heavy water stream may spread burning liquid.
5.2. Special Hazards Arising From the Substance or Mixture
Fire Hazard: Flammable liquid and vapor.
Explosion Hazard: May form flammable or explosive vapor-air mixture.
Reactivity: Reacts violently with strong oxidizers. Increased risk of fire or explosion.
5.3. Advice for Firefighters
Precautionary Measures Fire: Exercise caution when fighting any chemical fire.
Firefighting Instructions: Use water spray or fog for cooling exposed containers. In case of major fire and large quantities:
Evacuate area. Fight fire remotely due to the risk of explosion.
Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection.
Hazardous Combustion Products: Carbon dioxide, carbon monoxide, smoke, fumes, unburned hydrocarbons and oxides of sulfur and/or nitrogen. Hydrogen sulfide and other sulfur-containing gases can evolve from this product particularly at elevated temperatures.
Other Information: Do not allow run-off from fire fighting to enter drains or water courses.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Avoid breathing (vapor, mist, spray). Do not get in eyes, on skin, or on clothing. Keep away from heat, hot surfaces, sparks, open flames, and other ignition sources. No smoking. Use special care to avoid static electric charges. Avoid all contact with skin, eyes, or clothing.
6.1.1. For Non-Emergency Personnel
Protective Equipment: Use appropriate personal protective equipment (PPE).
Emergency Procedures: Evacuate unnecessary personnel. Stop leak if safe to do so.
6.1.2. For Emergency Personnel
Protective Equipment: Equip cleanup crew with proper protection.
Emergency Procedures: Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods, protect oneself and the public, secure the area, and call for the assistance of trained personnel as soon as conditions permit.
Ventilate area. Eliminate ignition sources.
6.2. Environmental Precautions
Prevent entry to sewers and public waters. Avoid release to the environment. Collect spillage.
6.3. Methods and Materials for Containment and Cleaning Up
For Containment: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. As an immediate precautionary measure, isolate spill or leak area in all directions.
Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Transfer spilled material to a suitable container for disposal. Contact competent authorities after a spill. Absorb and/or contain spill with inert material. Do not take up in combustible material such as: saw dust or cellulosic material. Use only non-sparking tools.
6.4. Reference to Other Sections
See Section 8 for exposure controls and personal protection and Section 13 for disposal considerations.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for Safe Handling
Additional Hazards When Processed: Handle empty containers with care because residual vapors are flammable. Handle in accordance with standard industrial practices, and ensure appropriate ventilation. Avoid all contact with skin, eyes, clothing. Do not release into the environment.
Precautions for Safe Handling: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Avoid breathing vapors, mist, spray. Take precautionary measures against static discharge. Use only non-sparking tools. Avoid contact with eyes, skin and clothing.
Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures.
7.2. Conditions for Safe Storage, Including Any Incompatibilities Technical Measures: Comply with applicable regulations. Take action to prevent static discharges. Ground and bond container and receiving equipment. Use explosion-proof electrical, ventilating, and lighting equipment.
Storage Conditions: Store in a dry, cool place. Keep/Store away from direct sunlight, extremely high or low temperatures and incompatible materials. Store in a well-ventilated place. Keep container tightly closed. Keep in fireproof place.
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Incompatible Products: Strong acids, strong bases, strong oxidizers.
7.3. Specific End Use(s)
Fuel.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control Parameters
For substances listed in section 3 that are not listed here, there are no established exposure limits from the manufacturer, supplier, importer, or the appropriate advisory agency including: ACGIH (TLV), AIHA (WEEL), NIOSH (REL), or OSHA (PEL).
Kerosine, petroleum, hydrodesulfurized (64742-81-0) USA ACGIH ACGIH TWA (mg/m³) 200 mg/m³ (application restricted to conditions in which there are negligible aerosol exposures-total hydrocarbon vapor) USA ACGIH ACGIH chemical category Skin - potential significant contribution to overall exposure by the cutaneous route, Confirmed Animal Carcinogen with Unknown Relevance to Humans
Kerosine, petroleum (8008-20-6) USA ACGIH ACGIH TWA (mg/m³) 200 mg/m³ (application restricted to conditions in which there are negligible aerosol exposures-total hydrocarbon vapor) USA ACGIH ACGIH chemical category Skin - potential significant contribution to overall exposure by the cutaneous route, Confirmed Animal Carcinogen with Unknown Relevance to Humans
USA NIOSH NIOSH REL (TWA) (mg/m³) 100 mg/m³
8.2. Exposure Controls
Appropriate Engineering Controls : Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure adequate ventilation, especially in confined areas. Ensure all national/local regulations are observed. Gas detectors should be used when flammable gases or vapors may be released. Proper grounding procedures to avoid static electricity should be followed. Use explosion-proof equipment.
Personal Protective Equipment : Gloves. Protective clothing. Protective goggles. Insufficient ventilation: wear respiratory protection.
Materials for Protective Clothing : Chemically resistant materials and fabrics. Wear fire/flame resistant/retardant clothing.
Hand Protection : Wear protective gloves.
Eye Protection : Chemical safety goggles.
Skin and Body Protection : Wear suitable protective clothing.
Respiratory Protection : If exposure limits are exceeded or irritation is experienced, approved respiratory protection should be worn. In case of inadequate ventilation, oxygen deficient atmosphere, or where exposure levels are not known wear approved respiratory protection.
Other Information : When using, do not eat, drink or smoke.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on Basic Physical and Chemical Properties
Physical State : Liquid
Appearance : Colorless to Yellowish, Oily
Odor : Diesel
Odor Threshold : No data available pH : Not applicable
Evaporation Rate : 0.04
Melting Point : -80 °F (-62.22 °C)
Freezing Point : No data available
Boiling Point : 347 - 617 °F (175 - 325 °C)
02/24/2017 EN (English US) 5/7
Flash Point : > 100 °F (> 37.78 °C) (ASTM 93)
Auto-ignition Temperature : Not determined
Decomposition Temperature : No data available
Flammability (solid, gas) : No data available
Vapor Pressure : < 5 mm Hg @ 20 °C (68 °F)
Relative Vapor Density at 20°C : 5.8
Specific Gravity : 0.80-0.83 Solubility : Water: Insoluble
Partition Coefficient: N-Octanol/Water : Not determined
Viscosity : No data available
Lower Flammable Limit : 0.7 % Upper Flammable Limit : 5 %
9.2. Other Information
VOC Content : 100 %
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity: Reacts violently with strong oxidizers. Increased risk of fire or explosion.
10.2. Chemical Stability: Flammable liquid and vapor. May form flammable or explosive vapor-air mixture.
10.3. Possibility of Hazardous Reactions: Hazardous polymerization will not occur.
10.4. Conditions to Avoid: Direct sunlight, extremely high or low temperatures, heat, hot surfaces, sparks, open flames, incompatible materials, and other ignition sources.
10.5. Incompatible Materials: Strong acids, strong bases, strong oxidizers.
10.6. Hazardous Decomposition Products: None expected under normal conditions of use.
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on Toxicological Effects
Acute Toxicity: Not classified
LD50 Oral Rat > 5000 mg/kg LD50 Dermal Rabbit > 2000 mg/kg LC50 Inhalation Rat > 5.2 mg/l/4h
LD50 Oral Rat > 5000 mg/kg LD50 Dermal Rabbit > 2000 mg/kg LC50 Inhalation Rat > 5.28 mg/l/4h
Skin Corrosion/Irritation: Causes skin irritation.
pH: Not applicable
Serious Eye Damage/Irritation: Not classified pH: Not applicable
Respiratory or Skin Sensitization: Not classified Germ Cell Mutagenicity: Not classified Carcinogenicity: Not classified
Reproductive Toxicity: Not classified Specific Target Organ Toxicity (Single Exposure): May cause drowsiness or dizziness.
Specific Target Organ Toxicity (Repeated Exposure): Not classified
Aspiration Hazard: May be fatal if swallowed and enters airways.
Symptoms/Injuries After Inhalation: High concentrations may cause central nervous system depression such as dizziness, vomiting, numbness, drowsiness, headache, and similar narcotic symptoms.
Symptoms/Injuries After Skin Contact: Redness, pain, swelling, itching, burning, dryness, and dermatitis.
Symptoms/Injuries After Eye Contact: May cause slight irritation to eyes.
Symptoms/Injuries After Ingestion: Aspiration into the lungs can occur during ingestion or vomiting and may cause lung injury.
SECTION 12: ECOLOGICAL INFORMATION
12.1. Toxicity
Ecology - General : Toxic to aquatic life. Toxic to aquatic life with long lasting effects.
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LC50 Fish 1 45 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) EC50 Daphnia 1 4720 mg/l (Exposure time: 48 h - Species: Den-dronereides heteropoda) LC50 Fish 2 1740 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static])
LC50 Fish 1 2 (2 - 5) mg/kg (Exposure time: 96 h - Species: Oncorhynchus mykiss [semi-static]) NOEC Chronic Fish 0.098 mg/l (PETROTOX, Klimmish score: 2)
12.2. Persistence and Degradability
Persistence and Degradability May cause long-term adverse effects in the environment.
12.3. Bioaccumulative Potential
Bioaccumulative Potential Not established.
BCF Fish 1 61 - 159
12.4. Mobility in Soil
No additional information available
12.5. Other Adverse Effects
Other Information : Avoid release to the environment.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste Treatment Methods
Waste Disposal Recommendations: Dispose of contents/container in accordance with local, regional, national, and international regulations.
Additional Information: Handle empty containers with care because residual vapors are flammable.
Ecology - Waste Materials: Avoid release to the environment. This material is hazardous to the aquatic environment. Keep out of sewers and waterways.
SECTION 14: TRANSPORT INFORMATION
The shipping description(s) stated herein were prepared in accordance with certain assumptions at the time the SDS was authored, and can vary based on a number of variables that may or may not have been known at the time the SDS was issued.
14.1. In Accordance with DOT
See the 49 CFR Section 100-185 for specific shipping information.
SECTION 15: REGULATORY INFORMATION
15.1. US Federal Regulations
Aviation Turbine Jet Fuel SARA Section 311/312 Hazard Classes Fire hazard
Immediate (acute) health hazard
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. US State Regulations
U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION
Revision Date : 02/24/2017 Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200
GHS Full Text Phrases:
------ Aquatic Acute 2 Hazardous to the aquatic environment - Acute Hazard Category 2 ------ Aquatic Chronic 2 Hazardous to the aquatic environment - Chronic Hazard Category 2
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------ Asp. Tox. 1 Aspiration hazard Category 1 ------ Flam. Liq. 3 Flammable liquids Category 3 ------ Skin Irrit. 2 Skin corrosion/irritation Category 2 ------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3 ------ H226 Flammable liquid and vapor ------ H304 May be fatal if swallowed and enters airways ------ H315 Causes skin irritation ------ H336 May cause drowsiness or dizziness ------ H401 Toxic to aquatic life ------ H411 Toxic to aquatic life with long lasting effects
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.
SDS US (GHS HazCom)
File details come from the government source that posted it. Updated .