B.08.02_Attachment K_Mattituck Final Table_Values.xlsx

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Maintenance Dredging of Mattituck Harbor, New York, Federal Navigation Channel
Solicitation number
W912DS24B0005
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This document appears to be a table containing analytical results for sediment samples collected from the Mattituck Harbor Federal Navigation Channel. The table includes data on various metals, pesticides, PCBs, semi-volatile organics, and volatile organic compounds detected in the sediment samples, as well as applicable regulatory thresholds.

The related federal contract opportunity is a solicitation for the Maintenance Dredging of the Mattituck Harbor, New York Federal Navigation Channel. This is a 100% small business set-aside contract with a project magnitude range between $1,000,000 to $5,000,000. The U.S. Army Corps of Engineers Engineering District New York is the procuring agency, and the contract specialist is Jo Ann McCue.

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Table 1

Mattituck Harbor
NYSDEC Application #1-4738-00995/00005ASI Field ID#20230468A#20230468B#20230469A#20230469B#20230470A#20230470B#20230471A#20230471B
Sample IDMC-6AMC-6BMC-7AMC-7BMC-8AMC-8BMC-9AMC-9B
Unitsmg/kgmg/kgmg/kgmg/kgmg/kgmg/kgmg/kgmg/kg
Parameter Sediment/SoilCAS NumberDMM
Unrestricted Use (ppm)BOH Class B
Threshold1 (mg/kg)BOH
Class C Threshold (mg/kg)ResultQMDLResultQMDLResultQMDLResultQMDLResultQMDLResultQMDLResultQMDLResultQMDL
Metals
Arsenic7440-38-213c14 (8.2)537.10.0767.70.096.10.0845.30.0686.80.118.60.0871.70.0528.60.065
Barium7440-39-3350c410.8390.95330.89300.72431.2470.928.40.55340.69
Beryllium7440-41-77.20.770.0940.850.110.670.10.660.0840.680.140.950.110.180.0650.880.081
Cadmium7440-43-92.5c1.29.50.960.0730.730.0870.820.0810.40.0650.930.111.70.0840.140.050.180.063
Chromium26 (81)110 (370)430.23360.28350.26260.21500.35500.279.40.16290.2
Chromium, hexavalentc18540-29-91b0.92U0.490.92U0.490.94U0.50.8U0.421.2U0.621U0.560.55U0.30.79U0.42
Chromium, trivalentc16065-83-130c430.21360.21350.21260.21500.21500.219.40.21290.21
Copper7440-50-85033207 (270)730.27330.32540.3230.2481F10.41000.3190.19180.23
Total Cyanidee,f270.45U0.340.45U0.340.41U0.310.32U0.250.5U0.380.51U0.390.26U0.20.37U0.28
Lead7439-92-163c33(47)166(218)430.086190.1300.096120.077370.13550.14.70.059100.075
Manganese7439-96-51600c46011003000.563800.672500.622500.53300.843100.65630.393100.49
Mercury0.18c0.171.6 (1.0)0.130.0230.0420.0250.120.0240.03J0.0210.120.0290.190.0270.014J0.0140.033U0.021
Nickel7440-02-03016 (21)50 (52)240.12230.15190.14170.11210.18280.144.90.085190.11
Selenium7782-49-23.9c0.54J0.160.820.190.43J0.180.47J0.140.67J0.240.58J0.180.11J0.110.630.14
Silver7440-22-421.02.2 (3.7)0.480.0370.14J0.0440.340.0410.071J0.0330.370.0540.610.0420.09U0.0250.065J0.032
Zinc7440-66-6109c120 (150)270 (410)160B ^-0.6380B ^-0.75120B ^-0.757B ^-0.56140B ^- F10.94200B ^-0.7321B ^-0.4352B ^-0.54
Pesticides
2,4,5 – TP Acid
(Silvex)f93-72-13.80.046U0.0260.046U0.0260.046U0.0260.04U0.0220.058U0.0320.053U0.0290.028U0.0150.04U0.022
4,4’- DDE72-55-90.0033b0.0013J0.000390.000096U0.000020.000850.000020.000082U0.0000170.0012F10.0000240.00220.0000220.000057U0.0000120.000083U0.000017
4,4’ – DDT50-29-30.0033b0.0190.00140.000096U0.0000690.00022p0.0000690.000082U0.0000590.00047F1 p0.0000860.000950.0000790.000057U0.0000410.000076J0.000059
4,4’ - DDD72-54-80.0033b0.00270.00040.000096U0.000020.00028p0.000020.000082U0.0000170.00016F2 F1 p0.0000250.00048p0.0000230.000057U0.0000120.000083U0.000017
Sum of DDT+DDE+DDD0.0030.030.0230.0002880.001350.0002460.001830.003630.0001710.000242
Aldrin309-00-20.005c0.0019U0.00060.000096U0.000030.000097U0.000030.000082U0.0000260.00012U F10.0000370.00011U0.0000340.000057U0.0000180.000083U0.000026
Alpha - BHC319-84-60.020.0019U0.000470.000096U0.0000240.000097U0.0000240.000082U0.000020.00012U F10.0000290.00011U0.0000270.000057U0.0000140.000083U0.00002
Beta – BHC319-85-70.0360.0019U0.000530.000096U0.0000260.000097U0.0000270.000082U0.0000230.00012U F10.0000330.00011U0.000030.000057U0.0000160.000083U0.000023
Delta – BHCg319-86-80.040.0019U0.000610.000096U0.000030.000097U0.0000310.000082U0.0000260.00012U F10.0000380.00011U0.0000350.000057U0.0000180.000083U0.000026
Chlordane (alpha)5103-71-90.0940.0019U0.000480.000096U0.0000240.000097U0.0000240.000082U0.0000210.00012U F10.000030.00011U0.0000280.000057U0.0000140.000083U0.000021
Chlordane0.0030.0360.019U0.00820.00096U0.000410.00097U0.000410.00082U0.000350.0012U0.000510.0011U0.000470.00057U0.000240.00083U0.00036
dibenzofuranf132-64-970.15U0.0560.038U0.0140.076U0.0280.033U0.0120.14U0.0520.043U0.0160.023U0.00830.033U0.012
Dieldrin60-57-10.005c0.110.480.0019U0.000480.000096U0.0000240.000097U0.0000240.000082U0.0000210.00012U F10.000030.00011U0.0000280.000057U0.0000140.000083U0.000021
Endosulfan I d,f959-98-82.40.0019U0.000520.000096U0.0000260.000097U0.0000260.000082U0.0000220.00012U F10.0000330.00011U0.000030.000057U0.0000150.000083U0.000022
Endosulfan II d, f33213-65-92.40.0019U0.000420.000096U0.0000210.000097U0.0000210.000082U0.0000180.00012U F10.0000260.00011U0.0000240.000057U0.0000130.000083U0.000018
Endosulfan sulfated,f1031-07-82.40.0019U0.000880.000096U0.0000440.000097U0.0000440.000082U0.0000380.00012U F10.0000550.00011U0.0000510.000057U0.0000260.000083U0.000038
Endrin72-20-80.0140.0019U0.000360.000096U0.0000180.000097U0.0000180.000082U0.0000150.00028F10.0000220.000320.0000210.000057U0.0000110.000083U0.000016
Heptachlor76-44-80.0420.0019U0.00060.000096U0.000030.000097U0.000030.000082U0.0000260.00012U F10.0000380.00011U0.0000350.000057U0.0000180.000083U0.000026
Lindane58-89-90.10.0019U0.000490.000096U0.0000250.000097U0.0000250.000082U0.0000210.00012U F10.0000310.00011U0.0000280.000057U0.0000150.000083U0.000021
Mirex0.00140.0140.0019U0.000360.000096U0.0000180.000097U0.0000180.000082U0.0000150.00012U0.0000220.00011U0.0000210.000057U0.0000110.000083U0.000016
gamma chlordane**0.0019U0.000450.000096U0.0000220.000097U0.0000230.000082U0.0000190.00012U F10.0000280.000110.0000260.000057U0.0000130.000083U0.000019
PCBs
PCBs (sum of aroclors)1336-36-30.10.110.00870.000340.00220.000350.00730.000340.00084U0.00030.00270.000420.0011U0.000390.00044J0.00020.00083U0.0003
Semi-Volatile Organics
2-chloronaphthalene91-58-70.031U0.0070.0078U0.00180.015U0.00350.0066U0.00150.029U0.00660.0087U0.0020.0046U0.0010.0067U0.0015
2-methylnaphthalene91-57060.031U0.00730.0078U0.00190.015U0.00370.0066U0.00160.029U0.00690.0087U0.00210.0046U0.00110.0067U0.0016
Acenaphthene83-32-9200.0160.50.031U0.00880.0078U0.00220.015U0.00440.0066U0.00190.029U0.00820.0087U0.00250.0046U0.00130.0067U0.0019
Acenapthylenef208-96-8100a0.0440.640.02J0.00670.0078U0.00170.01J0.00340.0066U0.00140.015J0.00630.0057J0.00190.0046U0.0010.0067U0.0015
Anthracenef120-12-7100a0.0850.110.025J0.00790.0078U0.0020.011J0.0040.0066U0.00170.015J0.00740.0066J0.00230.0046U0.00120.0067U0.0017
Benz(a)anthracenef56-55-31c0.2611.60.0540.0140.0078U0.00350.0330.0070.0066U0.0030.0460.0130.0180.00390.0046U0.00210.0067U0.003
Benzo(a)pyrene50-32-81c0.431.60.0720.0130.0078U0.00330.040.00670.0066U0.00290.0680.0120.0230.00380.0022J0.0020.0067U0.0029
Benzo(b)fluoranthenef205-99-21c0.0950.00750.0038J0.00190.0490.00380.0031J0.00160.0970.0070.0330.00210.0025J0.00110.0067U0.0016
Benzo(g,h,i)perylenef191-24-21000.050.00660.0078U0.00170.0290.00330.0066U0.00140.0540.00620.020.00190.0018J0.000980.0067U0.0014
Benzo(k)fluoroanthenef207-08-90.8c0.0480.00920.0078U0.00230.0260.00460.0066U0.0020.040.00860.0130.00260.0046U0.00140.0067U0.002
Chrysenef218-01-91c0.3842.80.0720.0170.0078U0.00430.0420.00860.0066U0.00370.0720.0160.0260.00480.0046U0.00250.0067U0.0037
Dibenz(a,h)anthracenef53-70-30.33b0.0630.260.031U0.020.0078U0.00490.015U0.00990.0066U0.00420.029U0.0180.0087U0.00560.0046U0.00290.0067U0.0043
Fluoranthenef206-44-0100a0.65.10.130.00810.0062J0.0020.070.00410.0036J0.00170.0870.00750.050.00230.0039J0.00120.0067U0.0018
Fluorene86-73-7300.0190.540.031U0.0060.0078U0.00150.015U0.0030.0066U0.00130.029U0.00560.0087U0.00170.0046U0.000890.0067U0.0013
Indeno(1,2,3-cd)pyrenef193-39-50.5c0.0450.0150.0078U0.00380.0260.00770.0066U0.00330.0450.0140.0160.00430.0046U0.00230.0067U0.0033
m-Cresolf*108-39-40.33b0.15U0.0450.038U0.0110.076U0.0230.033U0.00970.14U0.0420.043U0.0130.023U0.00670.033U0.0098
Naphthalenef91-20-3120.162.10.031U0.0060.0078U0.00150.015U0.0030.0066U0.00130.029U0.00560.0087U0.00170.0046U0.000890.0067U0.0013
o-Cresolf95-48-70.33b0.15U0.0440.038U0.0110.076U0.0220.033U0.00950.14U0.0410.043U0.0120.023U0.00650.033U0.0096
p-Cresolf106-44-50.33b0.15U0.0450.038U0.0110.076U0.0230.033U0.00970.14U0.0420.043U0.0130.023U0.00670.033U0.0098
Pentachlorophenol87-86-50.8b0.78U0.250.2U0.0620.39U0.120.17U0.0530.73U0.230.22U0.070.12U0.0370.17U0.054
Phenanthrenef85-01-81000.241.50.0370.00820.0039J0.00210.020.00410.0018J0.00180.028J0.00770.0130.00230.0018J0.00120.0067U0.0018
Phenol108-95-20.33b0.15U0.0460.038U0.0120.076U0.0230.033U0.010.14U0.0430.043U0.0130.023U0.00690.033U0.01
Pyrenef129-00-01000.6652.60.110.00720.0065J0.00180.0750.00370.0041J0.00160.093F10.00680.0470.00210.0034J0.00110.0067U0.0016
Total PAH20.3340.9440.12960.5210.1050.8340.32350.07080.1206
Volatile Organic Compounds
1,1,1 - trichloroethanef71-55-60.680.013U0.00450.01U0.00350.011U0.00360.0092U0.00310.015U0.0050.013U0.00440.0089U0.0030.0094U0.0031
1,1 - Dichloroethanef75-34-30.270.013U0.00430.01U0.00330.011U0.00350.0092U0.0030.015U0.00480.013U0.00420.0089U0.00280.0094U0.003
1,1 - Dichloroethenef75-35-40.330.013U0.00610.01U0.00470.011U0.00490.0092U0.00420.015U0.00680.013U0.00590.0089U0.0040.0094U0.0043
1,2 - Dichlorobenzenef95-50-11.10.013U0.00450.01U0.00350.011U0.00360.0092U0.00310.015U0.00510.013U0.00440.0089U0.0030.0094U0.0032
1,2 - Dichloroethane107-06-20.02c0.013U0.00390.01U0.0030.011U0.00310.0092U0.00270.015U0.00430.013U0.00380.0089U0.00260.0094U0.0027
cis 1,2 - Dichloroethenef156-59-20.250.013U0.00410.01U0.00320.011U0.00330.0092U0.00280.015U0.00460.013U0.00390.0089U0.00270.0094U0.0028
trans 1,2 - Dichloroethenef156-60-50.190.013U0.00470.01U0.00370.011U0.00380.0092U0.00320.015U0.00530.013U0.00460.0089U0.00310.0094U0.0033
1,3 - Dichlorobenzenef541-73-12.40.013U0.00830.01U0.00640.011U0.00670.0092U0.00570.015U0.00930.013U0.0080.0089U0.00550.0094U0.0058
1,4 - Dichlorobenzene106-46-71.80.013U0.0040.01U0.00310.011U0.00330.0092U0.00280.015U0.00450.013U0.00390.0089U0.00270.0094U0.0028
1,4 – Dioxane123-91-10.1b2.7U0.22.1U0.162.2U0.161.8U0.143U0.232.6U0.21.8U0.131.9U0.14
Acetone67-64-10.050.067U0.0110.052U0.00820.054U0.00850.046U0.00720.075U F20.0120.065U0.010.045U0.00690.047U0.0073
Benzene71-43-20.060.592.160.013U0.00380.01U0.00290.011U0.00310.0092U0.00260.015U0.00430.013U0.00370.0089U0.00250.0094U0.0027
n-Butylbenzenef104-51-8120.013U0.00670.01U0.00520.011U0.00540.0092U0.00460.015U0.00750.013U0.00650.0089U0.00440.0094U0.0047
Carbon tetrachloridef56-23-50.760.013U0.00550.01U0.00420.011U0.00440.0092U0.00380.015U0.00610.013U0.00530.0089U0.00360.0094U0.0038
Chlorobenzene108-90-71.10.013U0.00350.01U0.00270.011U0.00280.0092U0.00240.015U0.00390.013U0.00340.0089U0.00230.0094U0.0024
Chloroform67-66-30.370.013U0.0090.01U0.0070.011U0.00730.0092U0.00620.015U0.010.013U0.00870.0089U0.0060.0094U0.0063
Ethylbenzenef100-41-410.013U0.0050.01U0.00390.011U0.0040.0092U0.00340.015U0.00560.013U0.00480.0089U0.00330.0094U0.0035
Hexachlorobenzenef118-74-10.33b0.031U0.0110.0078U0.00280.015U0.00550.0066U0.00240.029U0.010.0087U0.00310.0046U0.00160.0067U0.0024
Methyl ethyl ketone78-93-30.120.067U0.00690.052U0.00530.054U0.00550.046U0.00470.075U0.00770.065U0.00660.045U0.00450.047U0.0048
Methyl tert-butyl etherf1634-04-40.930.013U0.0040.01U0.00310.011U0.00320.0092U0.00270.015U0.00440.013U0.00380.0089U0.00260.0094U0.0028
Methylene chloride75-09-20.050.013U0.0120.01U0.00940.011U0.00980.0092U0.00830.015U0.0140.013U0.0120.0089U0.0080.0094U0.0085
n-Propylbenzenef103-65-13.90.013U0.00480.01U0.00370.011U0.00390.0092U0.00330.015U0.00540.013U0.00460.0089U0.00320.0094U0.0034
sec-Butylbenzenef135-98-8110.013U0.00660.01U0.00510.011U0.00530.0092U0.00450.015U0.00740.013U0.00640.0089U0.00440.0094U0.0046
tert-Butylbenzenef98-06-65.90.013U0.00570.01U0.00440.011U0.00460.0092U0.00390.015U0.00640.013U0.00550.0089U0.00380.0094U0.004
Tetrachloroethene127-18-41.30.013U0.00540.01U0.00420.011U0.00440.0092U0.00370.015U0.00610.013U0.00520.0089U0.00360.0094U0.0038
Toluene108-88-30.70.013U0.00390.01U0.0030.011U0.00310.0092U0.00270.015U0.00430.013U0.00380.0089U0.00260.0094U0.0027
Trichloroethene79-01-60.470.013U0.00420.01U0.00330.011U0.00340.0092U0.00290.015U0.00470.013U0.00410.0089U0.00280.0094U0.003
1,2,4-Trimethylbenzenef95-63-63.60.013U0.00460.01U0.00360.011U0.00370.0092U0.00320.015U0.00520.013U0.00450.0089U0.00310.0094U0.0032
1,3,5- trimethylbenzenef108-67-88.40.013U0.0050.01U0.00390.011U0.0040.0092U0.00340.015U0.00560.013U0.00490.0089U0.00330.0094U0.0035
Vinyl chloridef75-01-40.020.013U0.00970.01U0.00750.011U0.00780.0092U0.00670.015U0.0110.013U0.00940.0089U0.00640.0094U0.0068
Xylene (mixed)1330-20-70.260.027U0.0190.021U0.0150.022U0.0160.018U0.0130.03U0.0220.026U0.0190.018U0.0130.019U0.014
Total BTEX30.965.90.0530.0410.0440.03640.060.0520.03580.0378

1 Threshold values lower than the Minimum Detection Limit are superseded by the Minimum Detection Limit.

2 Total PAHs – sum the concentrations of the 18 semi-volatile analytes identified as BOH parameters 3 Total BTEX – The sum of benzene, toluene and xylene concentrations a The Soil Cleanup Objectives (SCOs) for unrestricted use were capped at a maximum value of 100 ppm. See Technical Support document, section 9.3 b For constituents where the calculated SCO was lower than the contract required quantitation limit (CRQL), the CRQL is used as the Track 1 SCO value.

c For constituents where the calculated where the calculated SCO was lower than the rural soil background concentration, as determined by the Department and the Department of Health rural soil survey, the rural soil background concentration is used as the track 1 SCO value for this use of the site.

d SCO is the sum of endosulfan I, endosulfan II and endosulfan sulphate.

e The SCO for this specific compound (or family of compounds) is considered to be met if the analysis for the total species of this contaminant is below the specific SCO.

f Protection of ecological resources SCOs were not developed for contaminants identified in Table 375-6.8(b) with “NS”. Where such contaminants appear in Table 375-6.8(a), the applicant may be required by the Department to calculate a protection of ecological resources SCO according to the TSD.

included in total PAH as per NYSDEC
* m-cresol and p-cresol co-elute. Same data reported for each analyte.
** gamma-chlordane added upon request
Reporting Limit included for not-detected analytes in the sums.

Qualifiers

Qualifiers
GC/MS Semi VOA
QualifierQualifier Description
F1MS and/or MSD recovery exceeds control limits
JResult is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
UIndicates the analyte was analyzed for but not detected.
GC Semi VOA
QualifierQualifier Description
F1MS and/or MSD recovery exceeds control limits
F2MS/MSD RPD exceeds control limits
JResult is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
S1-Surrogate recovery exceeds control limits, low biased.
S1+Surrogate recovery exceeds control limits, high biased.
UIndicates the analyte was analyzed for but not detected.
Metals
QualifierQualifier Description
^-Continuing Calibration Verification (CCV) is outside acceptance limits, low biased.
BCompound was found in the blank and sample
F1MS and/or MSD recovery exceeds control limits
JResult is less than the RL but greater than or equal to the MDL and the concentration is an approximate value
UIndicates the analyte was analyzed for but not detected.
VSerial Dilution exceeds the control limits
WPS: Post-digestion exceeds the control limits
General Chemistry
QualifierQualifier Description
UIndicates the analyte was analyzed for but not detected.

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