Attachment A - Safety Data Sheet of Contrac All Weather Blox.pdf

Contrac All-Weather Blox Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Issue date: 1/10/2024 Revision date: 1/10/2024 Version: 1.0

1/10/2024 (Revision date) US - en 1/8

SECTION 1: Identification

1.1. Identification

Product form : Mixture

EPA Registration Number : 12455-79

Trade name : Contrac All-Weather Blox

Product code : CB4047, CB4051, CB1616

1.2. Recommended use and restrictions on use

Use of the substance/mixture : Rodenticides

Anti-coagulant

Ready to use product

1.3. Supplier

Bell Laboratories, Inc.

3699 Kinsman Blvd.

Madison, WI, 53704

USA

T 608 241 0202 sds@belllabs.com - www.belllabs.com

1.4. Emergency telephone number

Country Organisation/Company Address Emergency number Comment

USA Medical or Vet Emergency 877-854-2494

952-852-4636

Spill or Transportation

Emergency: 800-424-9300

(CHEMTREC)

SECTION 2: Hazard(s) identification

2.1. Classification of the substance or mixture

GHS US classification

Not classified

2.2. GHS Label elements, including precautionary statements

GHS US labelling

No labelling applicable

2.3. Other hazards which do not result in classification

No additional information available

2.4. Unknown acute toxicity (GHS US)

No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substances

Not applicable mailto:sds@belllabs.com http://www.belllabs.com/

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3.2. Mixtures

Name Product identifier % GHS US classification bromadiolone (ISO); 3- [3-(4′-bromobiphenyl- 4-yl)-3-hydroxy-1-phenylpropyl]-4-hydroxy- 2H-chromen-2-one

CAS-No.: 28772-56-7 0.005 Acute Tox. 1 (Oral), H300

Acute Tox. 1 (Dermal), H310

Acute Tox. 1 (Inhalation), H330

Acute Tox. 2 (Inhalation:dust,mist), H330

Repr. 1B, H360

STOT RE 1, H372

Aquatic Acute 2, H401

Aquatic Chronic 2, H411

Full text of hazard classes and H-statements : see section 16

SECTION 4: First-aid measures

4.1. Description of first aid measures

First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing.

First-aid measures after skin contact : Wash skin with plenty of water.

First-aid measures after eye contact : Rinse eyes with water as a precaution.

First-aid measures after ingestion : Call a poison center or a doctor if you feel unwell.

4.2. Most important symptoms and effects (acute and delayed)

No additional information available

4.3. Immediate medical attention and special treatment, if necessary

Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1. Suitable (and unsuitable) extinguishing media

Suitable extinguishing media : Water spray. Dry powder. Foam.

5.2. Specific hazards arising from the chemical

Hazardous decomposition products in case of fire : Toxic fumes may be released.

5.3. Special protective equipment and precautions for fire-fighters

Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

No additional information available

6.1.2. For emergency responders

Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection".

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6.2. Environmental precautions

Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up : Mechanically recover the product.

Other information : Dispose of materials or solid residues at an authorized site.

6.4. Reference to other sections

For further information refer to section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Wear personal protective equipment. Place inaccessible to children, companion animals and non-target animals. Do not (use/apply) directly on or near food, feed or drinks, or on surfaces or utensils likely to be in direct contact with food, feed, drinks and animals. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Hygiene measures : Do not eat, drink or smoke when using this product. Always wash hands after handling the product.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions : Place inaccessible to children, companion animals and non-target animals. Keep only in the original container in a cool, well ventilated place away from : Other chemicals.

Heat and ignition sources : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

No additional information available

8.2. Appropriate engineering controls

Environmental exposure controls : Avoid release to the environment.

8.3. Individual protection measures/Personal protective equipment

Hand protection:

Protective gloves

Personal protective equipment symbol(s):

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Solid

Appearance : Waxy. Block.

Colour : Blue

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Odour : Fresh Sweet Grains

Odour threshold : No data available pH : No data available

Melting point : No data available

Freezing point : No data available

Boiling point : No data available

Flash point : No data available

Relative evaporation rate (butylacetate=1) : No data available

Flammability (solid, gas) : Non flammable.

Vapour pressure : No data available

Relative vapour density at 20°C : No data available

Relative density : No data available

Solubility : No data available

Partition coefficient n-octanol/water (Log Pow) : No data available

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

Explosive limits : No data available

Explosive properties : No data available

Oxidising properties : No data available

9.2. Other information

No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity

The product is non-reactive under normal conditions of use, storage and transport.

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions

No dangerous reactions known under normal conditions of use.

10.4. Conditions to avoid

None under recommended storage and handling conditions (see section 7).

10.5. Incompatible materials

No additional information available

10.6. Hazardous decomposition products

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity (oral) : Not classified

Acute toxicity (dermal) : Not classified

Acute toxicity (inhalation) : Not classified

1/10/2024 (Revision date) US - en 5/8 bromadiolone (ISO); 3- [3-(4′-bromobiphenyl- 4-yl)-3-hydroxy-1-phenylpropyl]-4-hydroxy- 2H-chromen-2-one (28772-56-7)

LD50 oral rat 1.31 mg/kg bodyweight (OECD 401: Acute Oral Toxicity, Rat, Male / female, Experimental value, Oral, 14 day(s))

LD50 dermal rabbit 2.1 mg/kg (Rabbit, Dermal)

LC50 Inhalation - Rat < 0.2 mg/l (4 h, Rat, Inhalation)

Skin corrosion/irritation : Not classified

Serious eye damage/irritation : Not classified

Respiratory or skin sensitisation : Not classified

Germ cell mutagenicity : Not classified

Carcinogenicity : Not classified

Reproductive toxicity : Not classified

STOT-single exposure : Not classified

STOT-repeated exposure : Not classified bromadiolone (ISO); 3- [3-(4′-bromobiphenyl- 4-yl)-3-hydroxy-1-phenylpropyl]-4-hydroxy- 2H-chromen-2-one (28772-56-7)

STOT-repeated exposure Causes damage to organs through prolonged or repeated exposure.

Aspiration hazard : Not classified

Viscosity, kinematic : No data available

SECTION 12: Ecological information

12.1. Toxicity

Ecology - general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment.

bromadiolone (ISO); 3- [3-(4′-bromobiphenyl- 4-yl)-3-hydroxy-1-phenylpropyl]-4-hydroxy- 2H-chromen-2-one (28772-56-7)

LC50 - Fish [1] 2.86 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Oncorhynchus mykiss, Semi-static system, Experimental value)

EC50 - Crustacea [1] 5.79 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static system, Experimental value)

EC50 72h - Algae [1] < 1 mg/l Source: NCIS

EC50 96h - Algae [1] 0.17 mg/l (OECD 201: Alga, Growth Inhibition Test, Scenedesmus subspicatus, Static system, Experimental value, Biomass)

ErC50 algae 1.14 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata, Static system, Experimental value)

12.2. Persistence and degradability

bromadiolone (ISO); 3- [3-(4′-bromobiphenyl- 4-yl)-3-hydroxy-1-phenylpropyl]-4-hydroxy- 2H-chromen-2-one (28772-56-7)

Persistence and degradability Not readily biodegradable in water.

12.3. Bioaccumulative potential

bromadiolone (ISO); 3- [3-(4′-bromobiphenyl- 4-yl)-3-hydroxy-1-phenylpropyl]-4-hydroxy- 2H-chromen-2-one (28772-56-7)

Partition coefficient n-octanol/water (Log Pow) 4.3 (23 °C)

Bioaccumulative potential Potential for bioaccumulation (4 ≤ Log Kow ≤ 5).

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12.4. Mobility in soil

bromadiolone (ISO); 3- [3-(4′-bromobiphenyl- 4-yl)-3-hydroxy-1-phenylpropyl]-4-hydroxy- 2H-chromen-2-one (28772-56-7)

Surface tension 71.2 – 72.1 mN/m (20 - 21 °C, 1.47 - 17.4 mg/l)

Ecology - soil Low potential for mobility in soil.

12.5. Other adverse effects

No additional information available

SECTION 13: Disposal considerations

13.1. Disposal methods

Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions.

SECTION 14: Transport information

In accordance with DOT / TDG / IMDG / IATA

14.1. UN number

DOT NA No : Not regulated

UN-No. (TDG) : Not applicable

UN-No. (IMDG) : Not regulated

UN-No. (IATA) : Not regulated

14.2. UN proper shipping name

Proper Shipping Name (DOT) : Not regulated

Proper Shipping Name (TDG) : Not applicable

Proper Shipping Name (IMDG) : Not regulated

Proper Shipping Name (IATA) : Not regulated

14.3. Transport hazard class(es)

DOT

Transport hazard class(es) (DOT) : Not regulated

TDG

Transport hazard class(es) (TDG) : Not applicable

IMDG

Transport hazard class(es) (IMDG) : Not regulated

IATA

Transport hazard class(es) (IATA) : Not regulated

14.4. Packing group

Packing group (DOT) : Not regulated

Packing group (TDG) : Not applicable

Packing group (IMDG) : Not regulated

Packing group (IATA) : Not regulated

14.5. Environmental hazards

Other information : No supplementary information available.

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14.6. Special precautions for user

DOT

Not regulated

TDG

Not applicable

IMDG

IATA

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Not applicable

SECTION 15: Regulatory information

15.1. US Federal regulations

All components of this product are present and listed as Active on the United States Environmental Protection Agency Toxic Substances Control Act

(TSCA) inventory

This product or mixture is not known to contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40

CFR §372.38(a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40

CFR Part 372.

bromadiolone (ISO); 3- [3-(4′-bromobiphenyl- 4-yl)-3-hydroxy-1-phenylpropyl]-4-hydroxy- 2H-chromen-2-one (28772-56-7)

RQ (Reportable quantity, section 304 of EPA's List of

Lists)

100 lb

SARA Section 302 Threshold Planning Quantity

(TPQ)

10000 lb 100lb if the substance is solid in powder form with particle size less than 100 microns, or is in solution or molten form

FIFRA Labelling

EPA Registration Number 12455-79

This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label.

15.2. International regulations

No additional information available

15.3. US State regulations

California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm

SECTION 16: Other information

Revision date : 1/10/2024

1/10/2024 (Revision date) US - en 8/8

Full text of H-statements

H300 Fatal if swallowed.

H310 Fatal in contact with skin.

H330 Fatal if inhaled.

H360 May damage fertility or the unborn child.

H372 Causes damage to organs through prolonged or repeated exposure.

H401 Toxic to aquatic life

H411 Toxic to aquatic life with long lasting effects.

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.