7. Material Safety Data Sheets.pdf

Sodium Hydroxide Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 07/06/1998 Revision date: 02/21/2018 Supersedes: 10/14/2013 Version: 1.1

02/21/2018 EN (English) Page 1

SECTION 1: Identification

1.1. Identification

Product form : Substance Substance name : Sodium Hydroxide CAS-No. : 1310-73-2 Product code : LC23900 Formula : NaOH Synonyms : anhydrous caustic soda / caustic alkali / caustic flake / caustic soda, solid / caustic white / caustic, flaked / hydrate of soda / hydroxide of soda / LEWIS red devil lye / soda lye / sodium hydrate / sodium hydroxide, pellets

1.2. Recommended use and restrictions on use

Use of the substance/mixture : Industrial use Recommended use : Laboratory chemicals Restrictions on use : Not for food, drug or household use

1.3. Supplier

LabChem Inc Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA 16063 - USA T 412-826-5230 - F 724-473-0647 info@labchem.com - www.labchem.com

1.4. Emergency telephone number

Emergency number : CHEMTREC: 1-800-424-9300 or 011-703-527-3887

SECTION 2: Hazard(s) identification

2.1. Classification of the substance or mixture

GHS-US classification Skin corrosion/irritation, Category 1A

H314 Causes severe skin burns and eye damage.

Serious eye damage/eye irritation, Category 1

H318 Causes serious eye damage.

Hazardous to the aquatic environment — Acute Hazard, Category 3

H402 Harmful to aquatic life

Full text of H statements : see section 16

2.2. GHS Label elements, including precautionary statements

GHS-US labelling Hazard pictograms (GHS-US) :

GHS05

Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H314 - Causes severe skin burns and eye damage.

H402 - Harmful to aquatic life Precautionary statements (GHS-US) : P260 - Do not breathe dust, vapours.

P264 - Wash exposed skin thoroughly after handling.

P273 - Avoid release to the environment.

P280 - Wear eye protection, face protection, protective clothing, protective gloves.

P301+P330+P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing.

Rinse skin with water/shower.

P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 - Immediately call a POISON CENTER/doctor mailto:info@labchem.com

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P363 - Wash contaminated clothing before reuse.

P405 - Store locked up.

P501 - Dispose of contents/container to Comply with applicable regulations

2.3. Other hazards which do not result in classification

Other hazards not contributing to the classification

: None under normal conditions.

2.4. Unknown acute toxicity (GHS US)

Not applicable

SECTION 3: Composition/information on ingredients

3.1. Substances

Substance type : Mono-constituent

Name Product identifier % GHS-US classification

(Main constituent)

(CAS-No.) 1310-73-2 100 Skin Corr. 1A, H314 Eye Dam. 1, H318 Aquatic Acute 3, H402

Full text of hazard classes and H-statements : see section 16

3.2. Mixtures

Not applicable

SECTION 4: First-aid measures

4.1. Description of first aid measures

First-aid measures general : Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious with laboured breathing: half-seated. Victim in shock: on his back with legs slightly raised.

Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid physical strain. Depending on the victim's condition: doctor/hospital.

First-aid measures after inhalation : Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service.

First-aid measures after skin contact : Wipe off dry product from skin. Remove clothing before washing. Wash immediately with lots of water (15 minutes)/shower. Do not apply (chemical) neutralizing agents. Do not remove clothing if it sticks to the skin. Cover wounds with sterile bandage. Consult a doctor/medical service. If burned surface > 10%: take victim to hospital.

First-aid measures after eye contact : Rinse immediately with plenty of water for 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Do not apply neutralizing agents. Take victim to an ophthalmologist.

First-aid measures after ingestion : Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do not induce vomiting. Do not give activated charcoal. Do not give chemical antidote. Immediately consult a doctor/medical service. Call Poison Information Centre (www.big.be/antigif.htm). Ingestion of large quantities: immediately to hospital. Take the container/vomit to the doctor/hospital.

4.2. Most important symptoms and effects (acute and delayed)

Symptoms/effects after inhalation : WHEN PROCESSED: Dry/sore throat. Coughing. Irritation of the respiratory tract. Irritation of the nasal mucous membranes. ON CONTINUOUS EXPOSURE/CONTACT: Respiratory difficulties. FOLLOWING SYMPTOMS MAY APPEAR LATER: Possible oedema of the upper respiratory tract. Possible laryngeal spasm/oedema. Risk of lung oedema.

Symptoms/effects after skin contact : Blisters. Caustic burns/corrosion of the skin. Slow-healing wounds.

Symptoms/effects after eye contact : Corrosion of the eye tissue. Permanent eye damage.

Symptoms/effects after ingestion : Dry/sore throat. Nausea. Abdominal pain. Blood in vomit. Difficulty in swallowing. Possible esophageal perforation. Burns to the gastric/intestinal mucosa. Bleeding of the gastrointestinal tract. Shock.

Chronic symptoms : ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Dry skin. Skin rash/inflammation.

Possible inflammation of the respiratory tract. Gastrointestinal complaints.

4.3. Immediate medical attention and special treatment, if necessary Obtain medical assistance.

SECTION 5: Fire-fighting measures

5.1. Suitable (and unsuitable) extinguishing media

Suitable extinguishing media : Adapt extinguishing media to the environment for surrounding fires.

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5.2. Specific hazards arising from the chemical

Fire hazard : DIRECT FIRE HAZARD: Non combustible. INDIRECT FIRE HAZARD: Reactions involving a fire hazard: see "Reactivity Hazard".

Explosion hazard : INDIRECT EXPLOSION HAZARD: Reactions with explosion hazards: see "Reactivity Hazard".

Reactivity : May be corrosive to metals. Absorbs the atmospheric CO2. Violent to explosive reaction with

(some) acids. Reacts violently with many compounds: heat release resulting in increased fire or explosion risk. Violent exothermic reaction with water (moisture): release of corrosive mist.

Reacts exothermically on exposure to water (moisture) with combustible materials: risk of spontaneous ignition.

5.3. Special protective equipment and precautions for fire-fighters Precautionary measures fire : Exposure to fire/heat: keep upwind. Exposure to fire/heat: consider evacuation. Exposure to fire/heat: have neighbourhood close doors and windows.

Firefighting instructions : Cool tanks/drums with water spray/remove them into safety. When cooling/extinguishing: no water in the substance. Take account of toxic fire-fighting water. Use water moderately and if possible collect or contain it.

Protection during firefighting : Heat/fire exposure: compressed air/oxygen apparatus.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures General measures : Absorb spillage to prevent material damage. Dike and contain spill.

6.1.1. For non-emergency personnel

Protective equipment : Gloves. Face-shield. Corrosion-proof suit. Dust cloud production: compressed air/oxygen apparatus. Contact with moisture/water: compressed air/oxygen apparatus. Contact with moisture/water: gas-tight suit.

Emergency procedures : Mark the danger area. Prevent dust cloud formation. Corrosion-proof appliances. Keep containers closed. Avoid ingress of water in the containers. Wash contaminated clothes. On contact with moisture/water: keep upwind. On contact with moisture/water: consider evacuation. In case of hazardous reactions: keep upwind. In case of reactivity hazard: consider evacuation.

Measures in case of dust release : In case of dust production: keep upwind. Dust production: have neighbourhood close doors and windows.

6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection. Do not breathe dust.

Emergency procedures : Stop release.

6.2. Environmental precautions

Prevent soil and water pollution. Prevent spreading in sewers.

6.3. Methods and material for containment and cleaning up

For containment : Contain released product, pump into suitable containers. Plug the leak, cut off the supply. Dam up the solid spill. Hazardous reaction: measure explosive gas-air mixture. Reaction: dilute combustible gas/vapour with water curtain.

Methods for cleaning up : Collect the spill only if it is in a dry state. Wetted substance: cover with powdered limestone or dry sand, earth, vermiculite. Scoop solid spill into closing containers. Under controlled conditions: neutralize leftovers with dilute acid solution. Possible violent reaction if you neutralize. Carefully collect the spill/leftovers. Clean contaminated surfaces with an excess of water. Take collected spill to manufacturer/competent authority. Wash clothing and equipment after handling.

6.4. Reference to other sections

No additional information available

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Avoid raising dust. Avoid contact of substance with water. Measure the concentration in the air regularly. Carry operations in the open/under local exhaust/ventilation or with respiratory protection. Comply with the legal requirements. Remove contaminated clothing immediately.

Clean contaminated clothing. Keep the substance free from contamination. Use corrosionproof equipment. Thoroughly clean/dry the installation before use. Do not discharge the waste into the drain.

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Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Wash contaminated clothing before reuse. Separate working clothes from town clothes. Launder separately.

7.2. Conditions for safe storage, including any incompatibilities Incompatible products : combustible materials. metals. Strong acids. Strong oxidizers. Protect from moisture.

Incompatible materials : incompatible materials. Moisture. Heat sources.

Storage temperature : 20 °C Heat and ignition sources : KEEP SUBSTANCE AWAY FROM: heat sources.

Prohibitions on mixed storage : KEEP SUBSTANCE AWAY FROM: combustible materials. oxidizing agents. (strong) acids.

metals. organic materials. water/moisture.

Storage area : Store in a dry area. Keep container in a well-ventilated place. Keep locked up. Unauthorized persons are not admitted. Store at ambient temperature. Keep only in the original container.

Meet the legal requirements.

Special rules on packaging : SPECIAL REQUIREMENTS: hermetical. watertight. corrosion-proof. dry. clean. correctly labelled. meet the legal requirements. Secure fragile packagings in solid containers.

Packaging materials : SUITABLE MATERIAL: stainless steel. nickel. polyethylene. paper. MATERIAL TO AVOID:

lead. aluminium. copper. tin. zinc. bronze. textile.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Sodium Hydroxide (1310-73-2) ACGIH ACGIH Ceiling (mg/m³) 2 mg/m³

OSHA OSHA PEL (TWA) (mg/m³) 2 mg/m³

IDLH US IDLH (mg/m³) 10 mg/m³

NIOSH NIOSH REL (ceiling) (mg/m³) 2 mg/m³

8.2. Appropriate engineering controls

Appropriate engineering controls : Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Provide adequate general and local exhaust ventilation.

8.3. Individual protection measures/Personal protective equipment

Personal protective equipment:

Safety glasses. Protective clothing. Gloves. Dust/aerosol mask with filter type P3.

Materials for protective clothing:

GIVE GOOD RESISTANCE: natural rubber. neoprene. nitrile rubber. GIVE LESS RESISTANCE: butyl rubber. polyethylene. PVA. GIVE POOR RESISTANCE: natural fibres

Hand protection:

Gloves

Eye protection:

Face shield. In case of dust production: protective goggles

Skin and body protection:

Corrosion-proof clothing. In case of dust production: head/neck protection

Respiratory protection:

Dust production: dust mask with filter type P3.

High dust production: self-contained breathing apparatus

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SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Solid

Appearance : Crystalline solid. Crystalline powder. Little spheres. Lumps. Needles. Scales. Flakes.

Colour : White

Odour : Odourless

Odour threshold : No data available pH : 14 (5 %)

Melting point : 323 °C

Freezing point : No data available

Boiling point : 1388 °C (1013.25 hPa)

Flash point : Not applicable

Relative evaporation rate (butylacetate=1) : No data available

Flammability (solid, gas) : No data available

Vapour pressure : < 0.1 hPa (20 °C)

Relative vapour density at 20 °C : No data available

Relative density : 2.13 (20 °C)

Density : 2130 kg/m³ Molecular mass : 40 g/mol Solubility : Exothermically soluble in water. Soluble in ethanol. Soluble in methanol. Soluble in glycerol.

Water: 100 g/100ml (25 °C) Ethanol: soluble

Log Pow : No data available

Auto-ignition temperature : Not applicable

Decomposition temperature : No data available

Viscosity, kinematic : 0.53 mm²/s (25 °C, 1 mol/l)

Viscosity, dynamic : 0.997 mPa.s (25 °C, Test data)

Explosive limits : No data available

Explosive properties : Not applicable.

Oxidising properties : None.

9.2. Other information

Minimum ignition energy : Not applicable Saturation concentration : 671 g/m³ VOC content : Not applicable (inorganic) Other properties : Translucent. Hygroscopic. Substance has basic reaction.

SECTION 10: Stability and reactivity

10.1. Reactivity

May be corrosive to metals. Absorbs the atmospheric CO2. Violent to explosive reaction with (some) acids. Reacts violently with many compounds: heat release resulting in increased fire or explosion risk. Violent exothermic reaction with water (moisture): release of corrosive mist. Reacts exothermically on exposure to water (moisture) with combustible materials: risk of spontaneous ignition.

10.2. Chemical stability

Hygroscopic. Unstable on exposure to air.

10.3. Possibility of hazardous reactions

Reacts violently with acids. Reacts violently with water.

10.4. Conditions to avoid

Moisture. Incompatible materials.

10.5. Incompatible materials

Water. Strong oxidizers. Strong acids. metals. combustible materials.

10.6. Hazardous decomposition products

Sodium oxide.

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SECTION 11: Toxicological information

11.1. Information on toxicological effects

Likely routes of exposure : Skin and eyes contact

Acute toxicity : Not classified

Skin corrosion/irritation : Causes severe skin burns and eye damage.

pH: 14 (5 %)

Serious eye damage/irritation : Causes serious eye damage.

pH: 14 (5 %)

Respiratory or skin sensitisation : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified

(Based on available data, the classification criteria are not met)

Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified

Specific target organ toxicity (repeated exposure)

: Not classified

Aspiration hazard : Not classified

Potential adverse human health effects and symptoms

: Causes severe skin burns. Causes serious eye damage.

Symptoms/effects after inhalation : WHEN PROCESSED: Dry/sore throat. Coughing. Irritation of the respiratory tract. Irritation of the nasal mucous membranes. ON CONTINUOUS EXPOSURE/CONTACT: Respiratory difficulties. FOLLOWING SYMPTOMS MAY APPEAR LATER: Possible oedema of the upper respiratory tract. Possible laryngeal spasm/oedema. Risk of lung oedema.

Symptoms/effects after skin contact : Blisters. Caustic burns/corrosion of the skin. Slow-healing wounds.

Symptoms/effects after eye contact : Corrosion of the eye tissue. Permanent eye damage.

Symptoms/effects after ingestion : Dry/sore throat. Nausea. Abdominal pain. Blood in vomit. Difficulty in swallowing. Possible esophageal perforation. Burns to the gastric/intestinal mucosa. Bleeding of the gastrointestinal tract. Shock.

Chronic symptoms : ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Dry skin. Skin rash/inflammation.

Possible inflammation of the respiratory tract. Gastrointestinal complaints.

SECTION 12: Ecological information

12.1. Toxicity

Ecology - general : Not classified as dangerous for the environment according to the criteria of Regulation (EC) No

1272/2008.

Ecology - air : Not included in the list of fluorinated greenhouse gases (Regulation (EU) No 517/2014). Not classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009).

Ecology - water : Harmful to crustacea. Harmful to fishes. Groundwater pollutant. pH shift.

LC50 fish 1 45.4 mg/l (Other, 96 h, Salmo gairdneri, Static system, Fresh water, Experimental value) EC50 Daphnia 1 40.4 mg/l (Other, 48 h, Ceriodaphnia sp., Experimental value)

12.2. Persistence and degradability

Persistence and degradability Biodegradability: not applicable.

Biochemical oxygen demand (BOD) Not applicable (inorganic) Chemical oxygen demand (COD) Not applicable (inorganic) ThOD Not applicable (inorganic)

12.3. Bioaccumulative potential

Bioaccumulative potential Not bioaccumulative.

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12.4. Mobility in soil

Ecology - soil No (test)data on mobility of the substance available.

12.5. Other adverse effects

SECTION 13: Disposal considerations

13.1. Disposal methods

Waste disposal recommendations : Do not discharge into drains or the environment. Remove waste in accordance with local and/or national regulations. Hazardous waste shall not be mixed together with other waste. Different types of hazardous waste shall not be mixed together if this may entail a risk of pollution or create problems for the further management of the waste. Hazardous waste shall be managed responsibly. All entities that store, transport or handle hazardous waste shall take the necessary measures to prevent risks of pollution or damage to people or animals. Should not be landfilled with household waste. Recycle/reuse. Dilute. Neutralize.

Additional information : Hazardous waste according to Directive 2008/98/EC, as amended by Regulation (EU) No 1357/2014 and Regulation (EU) No 2017/997.

SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Transport document description : UN1823 Sodium hydroxide, solid, 8, II

UN-No.(DOT) : UN1823 Proper Shipping Name (DOT) : Sodium hydroxide, solid Transport hazard class(es) (DOT) : 8 - Class 8 - Corrosive material 49 CFR 173.136 Packing group (DOT) : II - Medium Danger Hazard labels (DOT) : 8 - Corrosive

DOT Packaging Non Bulk (49 CFR 173.xxx) : 212 DOT Packaging Bulk (49 CFR 173.xxx) : 240 DOT Special Provisions (49 CFR 172.102) : IB8 - Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2); Fiberboard (11G); Wooden (11C, 11D and 11F); Flexible (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2).

IP2 - When IBCs other than metal or rigid plastics IBCs are used, they must be offered for transportation in a closed freight container or a closed transport vehicle.

IP4 - Flexible, fiberboard or wooden IBCs must be sift-proof and water-resistant or be fitted with a sift-proof and water-resistant liner.

T3 - 2.65 178.274(d)(2) Normal............. 178.275(d)(2) TP33 - The portable tank instruction assigned for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point which are cooled and transported as a solid mass. Solid substances transported or offered for transport above their melting point are authorized for transportation in portable tanks conforming to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II, unless a tank with more stringent requirements for minimum shell thickness, maximum allowable working pressure, pressure-relief devices or bottom outlets are assigned in which case the more stringent tank instruction and special provisions shall apply. Filling limits must be in accordance with portable tank special provision TP3. Solids meeting the definition of an elevated temperature material must be transported in accordance with the applicable requirements of this subchapter.

DOT Packaging Exceptions (49 CFR 173.xxx) : 154 DOT Quantity Limitations Passenger aircraft/rail

(49 CFR 173.27)

: 15 kg

DOT Quantity Limitations Cargo aircraft only (49

CFR 175.75)

: 50 kg

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DOT Vessel Stowage Location : A - The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a passenger vessel.

DOT Vessel Stowage Other : 52 - Stow ‘‘separated from’’ acids Other information : No supplementary information available.

SECTION 15: Regulatory information

15.1. US Federal regulations

Listed on the United States TSCA (Toxic Substances Control Act) inventory Not subject to reporting requirements of the United States SARA Section 313 RQ (Reportable quantity, section 304 of EPA's List of Lists) 1000 lb SARA Section 311/312 Hazard Classes Immediate (acute) health hazard

All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory

15.2. International regulations

CANADA

Listed on the Canadian DSL (Domestic Substances List)

EU-Regulations

National regulations

15.3. US State regulations

California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm

SECTION 16: Other information

Revision date : 02/21/2018

Full text of H-statements: see section 16:

H314 Causes severe skin burns and eye damage.

H318 Causes serious eye damage.

H402 Harmful to aquatic life

NFPA health hazard : 3 - Materials that, under emergency conditions, can cause serious or permanent injury.

NFPA fire hazard : 0 - Materials that will not burn under typical dire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand.

NFPA reactivity : 1 - Materials that in themselves are normally stable but can become unstable at elevated temperatures and pressures.

Hazard Rating Health : 3 Serious Hazard - Major injury likely unless prompt action is taken and medical treatment is given Flammability : 0 Minimal Hazard - Materials that will not burn Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high temperatures and pressures. Materials may react non-violently with water or undergo hazardous polymerization in the absence of inhibitors.

Personal protection : F F - Safety glasses, Gloves, Synthetic apron, Dust respirator

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SDS US LabChem

Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this SDS. The user must determine suitability of this information for his application.

Aldrich - W268208

The life science business of Merck KGaA, Darmstadt, Germany operates as MilliporeSigma in the US and Canada

SAFETY DATA SHEET

Version 6.6 Revision Date 05/06/2021

Print Date 04/22/2023

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifiers

Product name : Methyl anthranilate

Product Number : W268208

Brand : Aldrich

CAS-No. : 134-20-3

1.2 Relevant identified uses of the substance or mixture and uses advised against

Identified uses : Laboratory chemicals, Synthesis of substances

1.3 Details of the supplier of the safety data sheet

Company : Sigma-Aldrich Inc.

3050 SPRUCE ST

ST. LOUIS MO 63103

UNITED STATES

Telephone : +1 314 771-5765

Fax : +1 800 325-5052

1.4 Emergency telephone

Emergency Phone # : 800-424-9300 CHEMTREC (USA) +1-703-

527-3887 CHEMTREC (International) 24

Hours/day; 7 Days/week

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)

Eye irritation (Category 2A), H319

Short-term (acute) aquatic hazard (Category 2), H401

For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 GHS Label elements, including precautionary statements

Pictogram

Signal word Warning

Hazard statement(s)

H319 Causes serious eye irritation.

H401 Toxic to aquatic life.

Precautionary statement(s)

P264 Wash skin thoroughly after handling.

P273 Avoid release to the environment.

P280 Wear eye protection/ face protection.

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing.

P337 + P313 If eye irritation persists: Get medical advice/ attention.

P501 Dispose of contents/ container to an approved waste disposal plant.

2.3 Hazards not otherwise classified (HNOC) or not covered by GHS - none

3.1 Substances

Synonyms : Methyl 2-aminobenzoate

Methyl anthranilate

Formula : C8H9NO2

Molecular weight : 151.16 g/mol

CAS-No. : 134-20-3

EC-No. : 205-132-4

Component Classification Concentration methyl 2-aminobenzoate

Eye Irrit. 2A; Aquatic

Acute 2; H319, H401

<= 100 %

For the full text of the H-Statements mentioned in this Section, see Section 16.

SECTION 4: First aid measures

4.1 Description of first-aid measures

General advice

Show this material safety data sheet to the doctor in attendance.

If inhaled

After inhalation: fresh air.

In case of skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower.

In case of eye contact

After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

If swallowed

After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.

4.2 Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section

2.2) and/or in section 11

4.3 Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media

Water Foam Carbon dioxide (CO2) Dry powder

Unsuitable extinguishing media

For this substance/mixture no limitations of extinguishing agents are given.

5.2 Special hazards arising from the substance or mixture

Carbon oxides

Nitrogen oxides (NOx)

Combustible.

Vapors are heavier than air and may spread along floors.

Forms explosive mixtures with air on intense heating.

Development of hazardous combustion gases or vapours possible in the event of fire.

5.3 Advice for firefighters

In the event of fire, wear self-contained breathing apparatus.

5.4 Further information

Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.

6.1 Personal precautions, protective equipment and emergency procedures

Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

For personal protection see section 8.

6.2 Environmental precautions

Do not let product enter drains.

6.3 Methods and materials for containment and cleaning up

Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions

(see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb® ).

Dispose of properly. Clean up affected area.

6.4 Reference to other sections

For disposal see section 13.

7.1 Precautions for safe handling

For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions

Tightly closed.

Light sensitive.

Storage class (TRGS 510): 10: Combustible liquids

7.3 Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

8.1 Control parameters

Ingredients with workplace control parameters

Contains no substances with occupational exposure limit values.

8.2 Exposure controls

Appropriate engineering controls

Change contaminated clothing. Wash hands after working with substance.

Personal protective equipment

Eye/face protection

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Skin protection

This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Full contact

Material: butyl-rubber

Minimum layer thickness: 0.7 mm

Break through time: 480 min

Material tested:Butoject® (KCL 898)

This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Splash contact

Material: Chloroprene

Minimum layer thickness: 0.65 mm

Break through time: 30 min

Material tested:KCL 720 Camapren®

Body Protection protective clothing

Respiratory protection required when vapours/aerosols are generated.

Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.

Control of environmental exposure

Do not let product enter drains.

9.1 Information on basic physical and chemical properties

a) Appearance Form: clear, liquid

Color: colorless, to, light yellowlight yellow

b) Odor sweet

c) Odor Threshold No data available

d) pH No data available

e) Melting point/freezing point

Melting point/range: 24 °C (75 °F) - lit.

f) Initial boiling point and boiling range

256 °C 493 °F - lit.

g) Flash point 128 °C (262 °F) - closed cup - ASTM D 93

h) Evaporation rate No data available

i) Flammability (solid, gas)

No data available

j) Upper/lower flammability or explosive limits

No data available

k) Vapor pressure 1 hPa at 20 °C (68 °F)

l) Vapor density No data available

m) Relative density No data available

n) Water solubility ca.2.79 g/l at 23 °C (73 °F) - OECD Test Guideline 105

o) Partition coefficient:

n-octanol/water log Pow: ca.2.17 at 22 °C (72 °F) - Bioaccumulation is not expected.

p) Autoignition temperature ca.510.6 °C (ca.951.1 °F)

q) Decomposition temperature

No data available

r) Viscosity No data available

s) Explosive properties No data available

t) Oxidizing properties No data available

9.2 Other safety information

Surface tension ca.71.56 mN/m at 19.8 °C (67.6 °F) - OECD Test Guideline 115

10.1 Reactivity

Forms explosive mixtures with air on intense heating.

A range from approx. 15 Kelvin below the flash point is to be rated as critical.

10.2 Chemical stability

The product is chemically stable under standard ambient conditions (room temperature) .

10.3 Possibility of hazardous reactions

Caution! In contact with nitrites, nitrates, nitrous acid possible liberation of nitrosamines!

Violent reactions possible with:

acid halides

Acid anhydrides

Strong oxidizing agents

Bases strong reducing agents acids

10.4 Conditions to avoid

Strong heating.

10.5 Incompatible materials

No data available

10.6 Hazardous decomposition products

In the event of fire: see section 5

11.1 Information on toxicological effects

Acute toxicity

LD50 Oral - Rat - 2,910 mg/kg

Remarks: Behavioral:Somnolence (general depressed activity).

Behavioral:Coma.

Inhalation: No data available

Dermal: No data available

No data available

Skin corrosion/irritation

No data available

Serious eye damage/eye irritation

Eyes - Rabbit

Result: Eye irritation

Remarks: (ECHA)

Respiratory or skin sensitization

No data available

Germ cell mutagenicity

Test Type: Ames test

Test system: S. typhimurium

Metabolic activation: with and without metabolic activation

Method: OECD Test Guideline 471

Result: negative

Carcinogenicity

IARC: No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

NTP: No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.

OSHA: No component of this product present at levels greater than or equal to 0.1% is on OSHA’s list of regulated carcinogens.

Reproductive toxicity

No data available

Specific target organ toxicity - single exposure

No data available

Specific target organ toxicity - repeated exposure

No data available

Aspiration hazard

No data available

11.2 Additional Information

RTECS: CB3325000

To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

Stomach - Irregularities - Based on Human Evidence

Stomach - Irregularities - Based on Human Evidence

12.1 Toxicity

Toxicity to fish static test LC50 - Salmo salar (Atlantic salmon) - 9.12 mg/l - 96 h

Remarks: (ECHA)

12.2 Persistence and degradability

Biodegradability Result: > 70 % - Biodegradable

12.3 Bioaccumulative potential

No data available

12.4 Mobility in soil

No data available

12.5 Results of PBT and vPvB assessment

PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

12.6 Other adverse effects

13.1 Waste treatment methods

Product

Waste material must be disposed of in accordance with the national and local regulations.

Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself. See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

SECTION 14: Transport information

DOT (US)

Not dangerous goods

IMDG

IATA

Further information

Not classified as dangerous in the meaning of transport regulations.

SARA 302 Components

This material does not contain any components with a section 302 EHS TPQ.

SARA 313 Components

This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section

313.

SARA 311/312 Hazards

Acute Health Hazard, Chronic Health Hazard

Massachusetts Right To Know Components

No components are subject to the Massachusetts Right to Know Act.

The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Sigma-Aldrich Corporation and its Affiliates shall not be held liable for any damage resulting from handling or from contact with the above product. See www.sigma-aldrich.com and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.

Copyright 2020 Sigma-Aldrich Co. LLC. License granted to make unlimited paper copies for internal use only.

The branding on the header and/or footer of this document may temporarily not visually match the product purchased as we transition our branding. However, all of the information in the document regarding the product remains unchanged and matches the product ordered. For further information please contact mlsbranding@sial.com.

Version: 6.6 Revision Date: 05/06/2021 Print Date: 04/22/2023

Sigma-Aldrich - 104094

SAFETY DATA SHEET

Version 6.5 Revision Date 03/29/2023

Print Date 04/21/2023

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifiers

Product name : Piperidine

Product Number : 104094

Brand : Sigma-Aldrich

Index-No. : 613-027-00-3

CAS-No. : 110-89-4

1.2 Relevant identified uses of the substance or mixture and uses advised against

Identified uses : Laboratory chemicals, Synthesis of substances

1.3 Details of the supplier of the safety data sheet

Company : Sigma-Aldrich Inc.

3050 SPRUCE ST

ST. LOUIS MO 63103

UNITED STATES

Telephone : +1 314 771-5765

Fax : +1 800 325-5052

1.4 Emergency telephone

Emergency Phone # : 800-424-9300 CHEMTREC (USA) +1-703-

527-3887 CHEMTREC (International) 24

Hours/day; 7 Days/week

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)

Flammable liquids (Category 2), H225

Acute toxicity, Oral (Category 4), H302

Acute toxicity, Inhalation (Category 3), H331

Acute toxicity, Dermal (Category 3), H311

Skin corrosion (Category 1B), H314

Serious eye damage (Category 1), H318

Short-term (acute) aquatic hazard (Category 3), H402

2.2 GHS Label elements, including precautionary statements

Pictogram

Signal Word Danger

Hazard statement(s)

H225 Highly flammable liquid and vapor.

H302 Harmful if swallowed.

H311 + H331 Toxic in contact with skin or if inhaled.

H314 Causes severe skin burns and eye damage.

H402 Harmful to aquatic life.

Precautionary statement(s)

P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking.

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment.

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.

P261 Avoid breathing mist or vapors.

P264 Wash skin thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P273 Avoid release to the environment.

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.

P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth.

P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.

P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.

P305 + P351 + P338 +

P310

IF IN EYES: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor.

P362 Take off contaminated clothing and wash before reuse.

P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.

P403 + P233 Store in a well-ventilated place. Keep container tightly closed.

P403 + P235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

P501 Dispose of contents/ container to an approved waste disposal plant.

2.3 Hazards not otherwise classified (HNOC) or not covered by GHS - none

3.1 Substances

Synonyms : Hexahydropyridine

Formula : C5H11N

Molecular weight : 85.15 g/mol

CAS-No. : 110-89-4

EC-No. : 203-813-0

Index-No. : 613-027-00-3

Component Classification Concentration

Piperidine

Flam. Liq. 2; Acute Tox. 4;

Acute Tox. 3; Skin Corr.

1B; Eye Dam. 1; Aquatic

Acute 3; H225, H302, H331, H311, H314, H318, H402

<= 100 %

SECTION 4: First aid measures

4.1 Description of first-aid measures

General advice

First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance.

If inhaled

After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.

In case of skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

In case of eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist.

Remove contact lenses.

If swallowed

After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Pulmonary failure possible after aspiration of vomit. Call a physician immediately. Do not attempt to neutralise.

4.2 Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section

2.2) and/or in section 11

4.3 Indication of any immediate medical attention and special treatment needed

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media

Carbon dioxide (CO2) Foam Dry powder

Unsuitable extinguishing media

For this substance/mixture no limitations of extinguishing agents are given.

5.2 Special hazards arising from the substance or mixture

Carbon oxides

Nitrogen oxides (NOx)

Combustible.

Pay attention to flashback.

Vapors are heavier than air and may spread along floors.

Development of hazardous combustion gases or vapours possible in the event of fire.

Forms explosive mixtures with air at ambient temperatures.

5.3 Advice for firefighters

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

5.4 Further information

Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.

6.1 Personal precautions, protective equipment and emergency procedures

Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition.

Evacuate the danger area, observe emergency procedures, consult an expert.

For personal protection see section 8.

6.2 Environmental precautions

Do not let product enter drains. Risk of explosion.

6.3 Methods and materials for containment and cleaning up

Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions

(see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g.

Chemizorb®). Dispose of properly. Clean up affected area.

6.4 Reference to other sections

For disposal see section 13.

7.1 Precautions for safe handling

Advice on safe handling

Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.

Advice on protection against fire and explosion

Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge.

Hygiene measures

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions

Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Keep locked up or in an area accessible only to qualified or authorized persons.

Storage class

Storage class (TRGS 510): 3: Flammable liquids

7.3 Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

8.1 Control parameters

Ingredients with workplace control parameters

Component CAS-No. Value Control parameters

Basis

Piperidine

110-89-4

TWA 1 ppm

USA. Workplace Environmental

Exposure Levels (WEEL)

Remarks Skin

8.2 Exposure controls

Appropriate engineering controls

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

Personal protective equipment

Eye/face protection

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Skin protection

This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Full contact

Material: butyl-rubber

Minimum layer thickness: 0.7 mm

Break through time: 480 min

Material tested:Butoject® (KCL 898)

This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Splash contact

Material: Nitrile rubber

Minimum layer thickness: 0.4 mm

Break through time: 120 min

Material tested:Camatril® (KCL 730 / Aldrich Z677442, Size M)

Body Protection

Flame retardant antistatic protective clothing.

Respiratory protection required when vapours/aerosols are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.

Control of environmental exposure

Do not let product enter drains. Risk of explosion.

9.1 Information on basic physical and chemical properties

a) Appearance Form: clear, liquid

Color: colorless

b) Odor amine-like

c) Odor Threshold Do not attempt to smell the product as it is hazardous.

d) pH 12.6 at 100 g/l at 20 °C (68 °F)

e) Melting point/freezing point

Melting point/range: -13 °C (9 °F) - lit.

f) Initial boiling point and boiling range

106 °C 223 °F - lit.

g) Flash point 16 °C (61 °F) - closed cup

h) Evaporation rate No data available

i) Flammability (solid, gas)

No data available

j) Upper/lower flammability or explosive limits

Upper explosion limit: 10.3 %(V)

Lower explosion limit: 1.5 %(V)

k) Vapor pressure 19.58 hPa at 20 °C (68 °F) - OECD Test Guideline 104

l) Vapor density 2.94 - (Air = 1.0)

m) Density 0.862 g/cm3 at 20 °C (68 °F) - lit.

Relative density No data available

n) Water solubility miscible

o) Partition coefficient:

n-octanol/water log Pow: 0.64 - 0.7 at 20 °C (68 °F) - - Bioaccumulation is not expected.

p) Autoignition temperature

No data available

q) Decomposition temperature

> 100 °C (> 212 °F) -

r) Viscosity 1.77 mm2/s at 20 °C (68 °F) - OECD Test Guideline 114 - 1.23 mm2/s at 40 °C (104 °F) - OECD Test Guideline 114 -

s) Explosive properties No data available

t) Oxidizing properties none

9.2 Other safety information

Relative vapor density

2.94 - (Air = 1.0)

10.1 Reactivity

Vapors may form explosive mixture with air.

10.2 Chemical stability

The product is chemically stable under standard ambient conditions (room temperature) .

10.3 Possibility of hazardous reactions

Caution! In contact with nitrites, nitrates, nitrous acid possible liberation of nitrosamines!

Risk of explosion with:

dicyanofurazan

N-nitrosoacetanilide

N-perchlorylpiperidine

Exothermic reaction with:

Strong oxidizing agents fire-promoting substances

10.4 Conditions to avoid

Warming.

10.5 Incompatible materials

Strong oxidizing agents

10.6 Hazardous decomposition products

In the event of fire: see section 5

11.1 Information on toxicological effects

Acute toxicity

LD50 Oral - Rat - male and female - 740 mg/kg

(US-EPA)

LC50 Inhalation - Rat - male and female - 4 h - 4.8 mg/l - vapor

(OECD Test Guideline 403)

LD50 Dermal - Rabbit - male - 275 mg/kg

Remarks: (ECHA)

No data available

Skin corrosion/irritation

Skin - Rabbit

Result: Corrosive - 4 h

(OECD Test Guideline 404)

Remarks: (Regulation (EC) No 1272/2008, Annex VI)

Serious eye damage/eye irritation

Eyes - Rabbit

Result: Irreversible effects on the eye

(OECD Test Guideline 405)

Remarks: Causes serious eye damage.

Respiratory or skin sensitization

Buehler Test - Guinea pig

Result: negative

(US-EPA)

Germ cell mutagenicity

Test Type: In vitro mammalian cell gene mutation test

Test system: Chinese hamster lung cells

Metabolic activation: with and without metabolic activation

Method: OECD Test Guideline 476

Result: negative

Test Type: Micronucleus test

Species: Mouse

Cell type: Bone marrow

Application Route: Oral

Method: OECD Test Guideline 474

Result: negative

Carcinogenicity

IARC: No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

NTP: No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.

OSHA: No component of this product present at levels greater than or equal to 0.1% is on OSHA’s list of regulated carcinogens.

Reproductive toxicity

No data available

Specific target organ toxicity - single exposure

No data available

Specific target organ toxicity - repeated exposure

No data available

Aspiration hazard

No data available

11.2 Additional Information

RTECS: TM3500000

Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., Cough, Shortness of breath, Headache, Nausea

To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

12.1 Toxicity

Toxicity to fish static test LC50 - Leuciscus idus (Golden orfe) - 68.12 mg/l - 96 h

(DIN 38412)

Toxicity to daphnia and other aquatic invertebrates static test EC50 - Daphnia magna (Water flea) - 19 mg/l - 48 h

(OECD Test Guideline 202)

Toxicity to algae static test ErC50 - Desmodesmus subspicatus (green algae) - 106 mg/l - 72 h

(Regulation (EC) No. 440/2008, Annex, C.3)

Toxicity to bacteria static test EC50 - activated sludge - > 1,000 mg/l - 0.5 h

(OECD Test Guideline 209)

Toxicity to daphnia and other aquatic invertebrates(Chronic toxicity) semi-static test NOEC - Daphnia magna (Water flea) - 3.8 mg/l - 21 d

(OECD Test Guideline 211)

12.2 Persistence and degradability

Biodegradability aerobic - Exposure time 14 d

Result: 100 % - Readily biodegradable.

(OECD Test Guideline 301C)

12.3 Bioaccumulative potential