6365 SDS (4in1 CONCENTRATE).pdf

Safety Data Sheet Material Name: ArmaKleen 4 in 1 Cleaner Concentrate SDS ID: 820071

Section 1 - PRODUCT AND COMPANY IDENTIFICATION

Material Name ArmaKleen 4 in 1 Cleaner Concentrate

Product Code 6365, 6466, 6366 Formula Code 42000146 Synonyms Not available.

Product Use

Aqueous, alkaline, concentrated cleaner that is to be diluted with water and used for cleaning aluminum, magnesium, titanium, ferrous and non-ferrous alloys as well as plastic, glass, and composite materials.

Concentrated cleaner must be diluted prior to use to meet local and state VOC emission regulations. If this product is used in combination with other products, refer to the Safety Data Sheet for those products.

Restrictions on Use For professional use only.

MANUFACTURER

Church & Dwight The ArmaKleen™ Company 469 North Harrison Street Princeton, NJ 08543 Phone: (800) 332-5424 www.churchdwight.com

SUPPLIER (in the U.S.A.)

Safety-Kleen Systems, Inc.

42 Longwater Drive Norwell, MA 02061-9149 Phone: 1-800-669-5740 www.safety-kleen.com

SUPPLIER (in Canada) Safety-Kleen Canada Inc.

25 Regan Road Brampton, Ontario, Canada L7A 1B2 Phone: 1-800-669-5740

Emergency Telephone Number Medical: 1-888-234-1828 Chemical: 1-800-424-9300 (CHEMTREC)

Issue Date February 24, 2020 Supersedes Issue Date

March 6, 2017 Original Issue Date

October 22, 2009

Section 2 - HAZARDS IDENTIFICATION

Classification in accordance with Schedule 1 of Canada’s Hazardous Products Regulations (HPR) (SOR/2015-17) and paragraph (d) of 29 CFR 1910.1200 in the United States

Acute Toxicity - Oral - Category 4 Skin Corrosion/Irritation - Category 1 Serious Eye Damage/Eye Irritation - Category 1 Skin Sensitization - Category 1A Specific Target Organ Toxicity - Repeated Exposure - Category 2 Health Hazard Not Otherwise Classified – Category 1

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GHS Label Elements Symbol(s)

Signal Word Danger Hazard Statement(s)

Harmful if swallowed.

Causes severe skin burns and eye damage.

May cause an allergic skin reaction.

May cause damage to organs through prolonged or repeated exposure.

Causes severe damage to the respiratory tract.

Precautionary Statement(s) Prevention

Wear protective gloves/protective clothing/eye protection/face protection. Do not breathe dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Do not eat, drink or smoke when using this product.

Response If exposed or concerned: Call a POISON CENTER or doctor/physician. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER or doctor. IF IN EYES:

Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. Take off contaminated clothing and wash before reuse. If skin irritation or rash occurs: Get medical advice/attention. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor.

Storage Store locked up.

Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.

Statement(s) of Unknown Acute Toxicity Oral 59% of the mixture consists of ingredient(s) of unknown acute toxicity.

Other hazards Repeated exposure may cause skin dryness or cracking.

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

CAS Component Name Percent

7732-18-5 Water 53-60

124-07-2 Octanoic acid 5.0-5.5

68439-46-3 Alcohols, C9-11, ethoxylated 3.8-4.2

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61791-26-2 Amines, tallow alkyl, ethoxylated 2.9-3.2

1310-73-2 Sodium hydroxide 2.5-2.7

497-19-8 Disodium carbonate 1.9-2.1

110-15-6 Succinic acid 1.6-1.8

23783-26-8 Acetic acid, hydroxyphosphono- 2.9-3.2

Section 4 - FIRST AID MEASURES

Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

Immediately call a POISON CENTER or doctor.

Skin IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.

Immediately call a POISON CENTER or doctor. Wash contaminated clothing before reuse.

Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to

do. Continue rinsing. Immediately call a POISON CENTER or doctor.

Ingestion IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor.

Most Important Symptoms/Effects Acute

Harmful if swallowed. Causes skin burns, eye burns, allergic skin reaction. Causes severe damage to the respiratory tract.

Delayed Repeated exposure may cause skin dryness or cracking. May cause damage to organs through prolonged or repeated exposure.

Indication of any immediate medical attention and special treatment needed Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES

Extinguishing Media Suitable Extinguishing Media

Use extinguishing agents appropriate for surrounding fire.

Unsuitable Extinguishing Media

Do not use high-pressure water streams. Avoid using a direct stream of water.

Special Hazards Arising from the Chemical

Negligible fire hazard.

Hazardous Combustion Products

Burning may produce carbon monoxide, nitrogen oxide.

Advice for firefighters

Containers may rupture or explode if exposed to heat.

Fire Fighting Measures

Move container from fire area if it can be done without risk. Keep storage containers cool with water spray.

Heated containers may rupture. "Empty" containers may retain residue and can be dangerous. Product is not sensitive to mechanical impact or static discharge.

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Special Protective Equipment and Precautions for Firefighters A positive-pressure, self-contained breathing apparatus (SCBA) and full-body protective equipment are required for fire emergencies.

Section 6 - ACCIDENTAL RELEASE MEASURES

Personal Precautions, Protective Equipment and Emergency Procedures Wear personal protective clothing and equipment, see Section 8.

Methods and Materials for Containment and Cleaning Up Spilled product is slippery. Remove all ignition sources. Do not touch or walk through spilled product. Keep unnecessary and unprotected personnel from entering. Ventilate area and avoid breathing vapor or mist.

Contain spill as a liquid for possible recovery, or sorb with compatible sorbent material and shovel with a clean, spark proof tool into a sealable container for disposal. Additionally, for large spills: Dike far ahead of liquid spill for collection and later disposal.

Environmental Precautions Prevent material from entering drains or sewers.

Section 7 - HANDLING AND STORAGE

Precautions for Safe Handling Keep away from sparks or flame. Do not breathe dust or vapors. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection.

Wash thoroughly after handling.

Conditions for Safe Storage, Including any Incompatibilities Do not store below 40°F. Store locked up. Keep container tightly closed when not in use and during transport. Store containers in a cool, dry place. Do not pressurize, cut, weld, braze, solder, drill, or grind containers. Keep containers away from flame, sparks, static electricity, or other sources of ignition. Empty product containers may retain product residue and can be dangerous. May be corrosive to metals.

Incompatible Materials Strong acids, metals, reducing agents, oxidizers.

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

Component Exposure Limits

Sodium hydroxide 1310-73-2

Alberta , British Columbia, Manitoba, New Brunswick, Quebec, Northwest Territories, Nova Scotia, Nunavut, Ontario, Prince Edward Island, Yukon

2 mg/m3 Ceiling

ACGIH: 2 mg/m3 Ceiling

ACGIH - Threshold Limit Values - Biological Exposure Indices (BEI) There are no biological limit values for any of this product's components.

Engineering Controls Provide general ventilation needed to maintain concentration of vapor or mist below applicable exposure limits. Where adequate general ventilation is unavailable, use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below applicable exposure limits.

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Individual Protection Measures, such as Personal Protective Equipment Eye/face protection

Wear safety glasses. Additional protection like goggles, face shields, or respirators may be needed dependent upon anticipated use and concentrations of mists or vapors. Eye wash fountain and emergency showers are recommended. Contact lens use is not recommended.

Respiratory Protection A respiratory protection program which meets USA's OSHA General Industry Standard 29 CFR 1910.134 or Canada's CSA Standard Z94.4 requirements must be followed whenever workplace conditions warrant use of a respirator. Consult a qualified Industrial Hygienist or Safety Professional for respirator selection guidance.

Skin Protection/Glove Recommendations Where skin contact is likely, wear gloves impervious to product; use of natural rubber (latex) or equivalent gloves is not recommended. To avoid prolonged or repeated contact where spills and splashes are likely, wear appropriate chemical-resistant face shield, boots, apron, whole body suits or other protective clothing.

When product is heated and skin contact is likely, wear heat-resistant gloves, boots, and other protective clothing.

Protective Materials Personal protective equipment should be selected based upon the conditions under which this material is used. A hazard assessment of the work area for PPE requirements should be conducted by a qualified professional pursuant to regulatory requirements. The following PPE should be considered the minimum required: Safety glasses, Gloves, Lab coat or apron.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Appearance Amber clear liquid Physical State Liquid

Odor Mild Color Clear, amber

Odor Threshold Not available pH 11.9 (aqueous solution)

Melting Point 0°C Boiling Point 212°F (100°C)

Boiling Point Range Not available Freezing point Not available

Evaporation Rate Not available Flammability (solid, gas) Not available

Autoignition Temperature Not available Flash Point >212°F (100°C)

Lower Explosive Limit Not available Decomposition temperature Not available

Upper Explosive Limit Not available Vapor Pressure Not available

Vapor Density (air=1) Not available Specific Gravity (water=1) 1.055

Water Solubility (complete) Partition coefficient: n-octanol/water

Not available

Viscosity Not available Kinematic viscosity Not available

Solubility (Other) Not available Density Not available

Molecular Weight Not available

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Volatile Organic Compounds (As regulated)

2.5% Solution 0.51 WT%; 0.044 LB/US gal; 5.25 g/L; As per 40 CFR Part 51.100(s) Product Vapor Pressure @20°C = 17.5 mmHg 5.0% Solution 1.02 WT%; 0.088 LB/US gal; 10.5 g/L; As per 40 CFR Part 51.100(s) Product Vapor Pressure @20°C = 17.5 mmHg VOC Vapor Pressure @38°C = 0.644 mmHg 10% Solution 2.04 WT%; 0.175 LB/US gal; 21g/L; As per 40 CFR Part 51.100(s) Product Vapor Pressure @20°C = 17.5 mmHg VOC Vapor Pressure @38°C = 0.734 mmHg 100% Concentrate 21.1 WT%; 1.76 LB/US gal; 210.92 g/L; As per 40 CFR Part 51.100(s) Product Vapor Pressure @20°C = 17.5 mmHg This product does not contain an ingredient that meets the definition of a ‘Photochemically Reactive Solvent’ as found in California’s South Coast Air Quality Management District Rule 102 – Definition of Terms. Consult your state or local air district regulations for location specific definitions.

Section 10 - STABILITY AND REACTIVITY

Reactivity May react on contact with strong acids.

Chemical Stability Stable under normal temperatures and pressures.

Possibility of Hazardous Reactions Polymerization is not known to occur under normal temperature and pressures. Not reactive with water.

Conditions to Avoid Avoid sparks or flame.

Incompatible Materials Strong acids, reducing agents, oxidizers.

Hazardous decomposition products Oxides of carbon, nitrogen oxides. See also SECTION 5: HAZARDOUS COMBUSTION PRODUCTS.

Thermal decomposition products Carbon monoxide, nitrogen oxides (NOx).

Section 11 - TOXICOLOGICAL INFORMATION

Information on Likely Routes of Exposure Inhalation

Causes severe damage to the respiratory tract.

Skin Contact

Causes burns. May cause allergic skin reaction.

Eye Contact

Causes eye burns.

Ingestion

Harmful if swallowed. May cause irritation.

Acute and Chronic Toxicity Component Analysis - LD50/LC50

The components of this material have been reviewed in various sources and the following selected endpoints are published:

Octanoic acid (124-07-2) Oral LD50 Rat 10080 mg/kg; Dermal LD50 Rabbit >5 g/kg (no deaths occurred ) Alcohols, C9-11, ethoxylated (68439-46-3) Oral LD50 Rat 1400 mg/kg Amines, tallow alkyl, ethoxylated (61791-26-2)

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Oral LD50 Rat 500 mg/kg Sodium hydroxide (1310-73-2) Oral LD50 Rat 325 mg/kg; Dermal LD50 Rabbit 1350 mg/kg Disodium carbonate (497-19-8) Oral LD50 Rat 4090 mg/kg Succinic acid (110-15-6) Oral LD50 Rat 2260 mg/kg

Product Toxicity Data Acute Toxicity Estimate

Dermal > 2000 mg/kg

Oral 1001.0732 mg/kg

Immediate Effects Harmful if swallowed. Causes burns, eye burns, skin burns. May cause allergic skin reaction. Causes severe damage to the respiratory tract.

Delayed Effects Repeated exposure may cause skin dryness or cracking. May cause damage to organs through prolonged or repeated exposure.

Irritation/Corrosivity Data Causes burns. Causes severe damage to the respiratory tract.

Respiratory Sensitization Based on best current information, there is no known human sensitization associated with this product.

Dermal Sensitization May cause allergic skin reaction.

Component Carcinogenicity None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA.

Germ Cell Mutagenicity Based on best current information, there is no known teratogenicity associated with this product.

Tumorigenic Data No data available

Reproductive Toxicity Based on best current information, there is no known reproductive toxicity associated with this product.

Specific Target Organ Toxicity - Single Exposure No target organs identified.

Specific Target Organ Toxicity - Repeated Exposure May cause damage to organs through prolonged or repeated exposure.

Aspiration hazard Based on available data, the classification criteria are not met.

Medical Conditions Aggravated by Exposure Individuals with pre-existing respiratory tract (nose, throat, and lungs), eye, and/or skin disorders may have increased susceptibility to the effects of exposure.

Section 12 - ECOLOGICAL INFORMATION

Component Analysis - Aquatic Toxicity

Octanoic acid 124-07-2

Fish:

LC50 96 h Oryzias latipes 310 mg/L [semi-static ]; LC50 96 h Brachydanio rerio 110 mg/L [semi-static ]

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Sodium hydroxide

1310-73-2

Fish: LC50 96 h Oncorhynchus mykiss 45.4 mg/L [static ]

Disodium carbonate

497-19-8

Fish:

LC50 96 h Lepomis macrochirus 300 mg/L [static ]; LC50 96 h Pimephales promelas 310 - 1220 mg/L [static ]

Invertebrate: EC50 48 h Daphnia magna 265 mg/L IUCLID

Succinic acid 110-15-6

Fish: LC50 96 h Danio rerio >100 mg/L [semi-static ]

Invertebrate Toxicity No additional information is available.

Persistence and Degradability No information available for the product.

Bioaccumulative Potential No information available for the product.

Mobility No information available for the product.

Section 13 - DISPOSAL CONSIDERATIONS

Disposal Methods Dispose in accordance with federal, state, provincial, and local regulations. Regulations may also apply to empty containers. The responsibility for proper waste disposal lies with the owner of the waste. Contact ArmaKleen regarding proper recycling or disposal.

Section 14 - TRANSPORT INFORMATION

US DOT Information: Not regulated for transport.

IATA Information: Not regulated for transport.

TDG Information: Not regulated for transport.

International Bulk Chemical Code

This material contains one or more of the following chemicals required by the IBC Code to be identified as dangerous chemicals in bulk.

Octanoic acid 124-07-2

IBC Code: Category Y (all isomers )

Alcohols, C9-11, ethoxylated 68439-46-3

IBC Code: Category Y

Amines, tallow alkyl, ethoxylated 61791-26-2

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IBC Code: Category X (>95% )

Sodium hydroxide 1310-73-2

IBC Code: Category Y (solution )

Section 15 - REGULATORY INFORMATION

Canada Regulations CEPA - Priority Substances List

None of this product's components are on the list.

Ozone Depleting Substances

None of this product's components are on the list.

Council of Ministers of the Environment - Soil Quality Guidelines

None of this product's components are on the list.

Council of Ministers of the Environment - Water Quality Guidelines

None of this product's components are on the list.

U.S. Federal Regulations

This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), and/or require an OSHA process safety plan.

Sodium hydroxide 1310-73-2

CERCLA: 1000 lb final RQ ; 454 kg final RQ

California Not listed under California Proposition 65.

Component Analysis - Inventory

Octanoic acid (124-07-2)

US CA AU CN EU

JP -

ENCS

JP - ISHL

KR KECI -

Annex 1

KR KECI -

Annex 2

Yes DSL Yes Yes EIN Yes Yes Yes No

KR - REACH CCA MX NZ PH

TH-

TECI

TW VN (Draft)

No Yes Yes Yes Yes Yes Yes

Alcohols, C9-11, ethoxylated (68439-46-3)

US CA AU CN EU

JP -

ENCS

JP - ISHL

KR KECI -

Annex 1

KR KECI -

Annex 2

Yes DSL Yes Yes No No No Yes No

KR - REACH CCA MX NZ PH

TH-

TECI

TW VN (Draft)

No Yes Yes Yes Yes Yes Yes

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Amines, tallow alkyl, ethoxylated (61791-26-2)

US CA AU CN EU

JP -

ENCS

JP - ISHL

KR KECI -

Annex 1

KR KECI -

Annex 2

Yes DSL Yes Yes No No No Yes No

KR - REACH CCA MX NZ PH

TH-

TECI

TW VN (Draft)

No Yes Yes Yes No Yes Yes

Sodium hydroxide (1310-73-2)

US CA AU CN EU

JP -

ENCS

JP - ISHL

KR KECI -

Annex 1

KR KECI -

Annex 2

Yes DSL Yes Yes EIN Yes Yes Yes No

KR - REACH CCA MX NZ PH

TH-

TECI

TW VN (Draft)

Yes Yes Yes Yes Yes Yes Yes

Disodium carbonate (497-19-8)

US CA AU CN EU

JP -

ENCS

JP - ISHL

KR KECI -

Annex 1

KR KECI -

Annex 2

Yes DSL Yes Yes EIN Yes Yes Yes No

KR - REACH CCA MX NZ PH

TH-

TECI

TW VN (Draft)

No Yes Yes Yes Yes Yes Yes

Succinic acid (110-15-6)

US CA AU CN EU

JP -

ENCS

JP - ISHL

KR KECI -

Annex 1

KR KECI -

Annex 2

Yes DSL Yes Yes EIN Yes Yes Yes No

KR - REACH CCA MX NZ PH

TH-

TECI

TW VN (Draft)

No Yes Yes Yes Yes Yes Yes

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Acetic acid, hydroxyphosphono- (23783-26-8)

US CA AU CN EU

JP -

ENCS

JP - ISHL

KR KECI -

Annex 1

KR KECI -

Annex 2

Yes DSL Yes Yes ELN No Yes Yes No

KR - REACH CCA MX NZ PH

TH-

TECI

TW VN (Draft)

No No Yes Yes Yes Yes Yes

Section 16 - OTHER INFORMATION

NFPA Ratings Health: 1 Fire: 0 Reactivity: 0 Hazard Scale: 0 = Minimal; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe Summary of Changes

Regulatory review and update.

Key / Legend

ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport;

AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CA/MA/MN/NJ/PA - California/Massachusetts/Minnesota/New Jersey/Pennsylvania*; CAS - Chemical Abstracts Service;

CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CFR - Code of Federal Regulations (US); CLP - Classification, Labelling, and Packaging; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSD

- Dangerous Substance Directive; DSL - Domestic Substances List; EC – European Commission; EEC - European Economic Community; EIN - European Inventory of (Existing Commercial Chemical Substances);

EINECS - European Inventory of Existing Commercial Chemical Substances; ENCS - Japan Existing and New Chemical Substance Inventory; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; F - Background (for Venezuela Biological Exposure Indices); IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; ISHL - Japan Industrial Safety and Health Law; IUCLID - International Uniform Chemical Information Database; JP - Japan; Kow - Octanol/water partition coefficient; KR KECI Annex 1 - Korea Existing Chemicals Inventory (KECI) / Korea Existing Chemicals List (KECL); KR KECI Annex 2 - Korea Existing Chemicals Inventory (KECI) / Korea Existing Chemicals List (KECL) , KR - Korea; LD50/LC50 - Lethal Dose/ Lethal Concentration; LEL - Lower Explosive Limit;

LLV - Level Limit Value; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; MX – Mexico; Ne- Non-specific; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; Nq - Non-quantitative; NSL – Non-Domestic Substance List (Canada); NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PEL- Permissible Exposure Limit; PH - Philippines; RCRA - Resource Conservation and Recovery Act; REACH- Registration, Evaluation, Authorisation, and restriction of Chemicals; RID - European Rail Transport; SARA - Superfund Amendments and Reauthorization Act; Sc - Semi-quantitative; STEL - Short-term Exposure Limit; TCCA – Korea Toxic Chemicals Control Act; TDG - Transportation of Dangerous Goods; TLV - Threshold Limit Value; TSCA - Toxic Substances Control Act;

TW – Taiwan; TWA - Time Weighted Average; UEL - Upper Explosive Limit; UN/NA - United Nations /North American; US - United States; VLE - Exposure Limit Value (Mexico); VN (Draft) - Vietnam (Draft);

WHMIS - Workplace Hazardous Materials Information System (Canada).

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Other Information Disclaimer:

User assumes all risks incident to the use of this product. To the best of our knowledge, the information contained herein is accurate. However, ArmaKleen assumes no liability whatsoever for the accuracy or completeness of the information contained herein. No representations or warranties, either expressed or implied, of merchantability, fitness for a particular purpose or of any other nature are made hereunder with respect to the information or the product to which the information refers. The data contained on this sheet apply to the product as supplied to the user.