Simplex TC Hydraulic Fluid.pdf

315 Simplex Torque Converter Fluid

Not available.

Liquid.

GHS product identifier

Other means of identification

Product type

Emergency telephone number (with hours of operation)

Section 1. Identification

Supplier's details :

Identified uses

315 Simplex Torque Converter Fluid

SAFETY DATA SHEET

Conforms to HazCom 2012/United States

Multi-functional tractor hydraulic transmission oil.

+1 314 865-4105 (24-hour response number)

Schaeffer Mfg. Company 102 Barton Street Saint Louis, Missouri 63104 Tel: 314-865-4100 Fax: 314-865-4107 Toll Free: 1-800-325-9962 E-Mail: safety@schaefferoil.com Web: http://www.schaefferoil.com

Section 2. Hazards identification

SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2AClassification of the substance or mixture

Signal word : Warning

Hazard statements : Causes serious eye irritation.

Hazard pictograms :

Precautionary statements

Prevention : Wear eye or face protection. Wash hands thoroughly after handling.

Response : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.

Storage : Not applicable.

Disposal : Not applicable.

GHS label elements

General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand.

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200).

Hazards not otherwise classified

: None known.

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Section 3. Composition/information on ingredients

Base Oil(s)(*) 60 - 100 See below.

1-Decene, homopolymer, hydrogenated 10 - 30 68037-01-4 Zinc Alkyldithiophosphate 1 - 5 68649-42-3 Triphenyl phosphite 0.1 - 1 101-02-0

Ingredient name CAS number%

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Substance/mixture :

Occupational exposure limits, if available, are listed in Section 8.

Mixture

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

Base oil(s) contained in this material may be described by one or more of the following CAS Nos.: 8042-47-5, 64742-46-7, 64742-47-8, 64742-53-6, 64742-54-7, 64742-55-8, 64742-56-9, 64742-65-0, 72623-84-8, 72623-85-9, 72623-86-0, 72623-87-1, 178603-64-0, 178603-65-1, 178603-66-2, 445411-73-4.

Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person.

If unconscious, place in recovery position and get medical attention immediately.

Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention.

Flush contaminated skin with plenty of water. Get medical attention if symptoms occur.

Wash clothing before reuse. Clean shoes thoroughly before reuse.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion :

Description of necessary first aid measures

Most important symptoms/effects, acute and delayed

Inhalation : No known significant effects or critical hazards.

Irritating to mouth, throat and stomach.:Ingestion

Skin contact : No known significant effects or critical hazards.

Causes serious eye irritation.:Eye contact

Over-exposure signs/symptoms

Skin contact

Inhalation No known significant effects or critical hazards.

No known significant effects or critical hazards.

Eye contact : Adverse symptoms may include the following:

pain or irritation watering redness

Potential acute health effects

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Section 4. First aid measures

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Specific treatments : No specific treatment.

Ingestion No known significant effects or critical hazards.:

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary

Section 5. Fire-fighting measures

No special measures are required.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

No specific data.

No specific fire or explosion hazard.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

Use an extinguishing agent suitable for the surrounding fire.

Extinguishing media

None known.

Suitable extinguishing media

Unsuitable extinguishing media

Special protective actions for fire-fighters

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

: No action shall be taken involving any personal risk or without suitable training. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. U.S.A. regulations may require reporting spills of this material that could reach any surface waters. Report spills to all applicable Federal, State, Provincial and local authorities and/or the United States National Response Center at (800) 424-8802 as appropriate or required.

Methods and materials for containment and cleaning up

For non-emergency personnel

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".

Small spill Stop leak if without risk. Move containers from spill area. Dispose of via a licensed waste disposal contractor.

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Section 6. Accidental release measures Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas.

Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor.

Contaminated absorbent material may pose the same hazard as the spilled product.

Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

Large spill :

Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage, including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

Protective measures Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous.

Do not reuse container.

Precautions for safe handling

Base Oil(s)(*) NIOSH REL (United States, 10/2013).

TWA: 5 mg/m³ 10 hours. Form: Mist STEL: 10 mg/m³ 15 minutes. Form: Mist ACGIH TLV (United States).

TWA: 5 mg/m³ Form: Oil mist.

STEL: 10 mg/m³ Form: Oil mist.

OSHA PEL (United States).

TWA: 5 mg/m³ Form: Oil mist.

Section 8. Exposure controls/personal protection

Ingredient name Exposure limits

Wear eye protection such as safety glasses, chemical goggles, or face shields if engineering controls or work practices are not adequate to prevent eye contact.

Eye/face protection :

Environmental exposure controls

: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.

Appropriate engineering controls

: Good general ventilation should be sufficient to control worker exposure to airborne contaminants.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.

Appropriate techniques should be used to remove potentially contaminated clothing.

Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures :

Control parameters

Individual protection measures

Occupational exposure limits

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Section 8. Exposure controls/personal protection

Hand protection

If a risk assessment indicates that respiratory protection is required, use a properly fitted, air-purifying or supplied air respirator that complies with an approved standard.

Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Use nitrile or oil resistant gloves.

Respiratory protection :

Body protection Personal protective clothing such as gloves, aprons, boots and complete facial protection should be selected based on the task being performed and the risks involved.

Users should determine acceptable performance characteristics of protective clothing.

Consider physical requirements and other substances present when selecting protective clothing.

Skin protection

Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved.

Section 9. Physical and chemical properties

Physical state

Vapor pressure

Relative density

Vapor density

Solubility

Liquid. [Clear.]

Not available.

0.8519

>1 [Air = 1]

<0.013 kPa (<0.1 mm Hg) [room temperature]

Negligible in water.

Petroleum.Odor pH

Light yellow.Color

Evaporation rate Not available.

Auto-ignition temperature

Flash point

Not available.

Open cup: 229.4°C (444.9°F) [Cleveland.]

Not available.

Not applicable.

Viscosity Kinematic (100°C): 8.5 to 9.7 cSt

Not available.Odor threshold

Partition coefficient: n-octanol/water

Appearance

Boiling point : 315.6°C (600.1°F)

Flammability (solid, gas) : Not available.

Lower and upper explosive (flammable) limits

: Not available.

Decomposition temperature : Not available.

Volatility Not available.:

Melting point/ Dropping Point

VOC content : Not available.

Section 10. Stability and reactivity

The product is stable.Chemical stability :

Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

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Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid No specific data.

Carbon monoxide, carbon dioxide and other organic compounds.

Reactive or incompatible with the following materials: Strong oxidizing agents.

Incompatible materials :

Section 11. Toxicological information

Acute toxicity

Product/ingredient name Result Species Dose Exposure

Carcinogenicity

Irritation/Corrosion

Product/ingredient name Result Score Exposure Observation

Sensitization

Species

Information on the likely routes of exposure

Inhalation : No known significant effects or critical hazards.

Irritating to mouth, throat and stomach.:Ingestion

Skin contact : No known significant effects or critical hazards.

Causes serious eye irritation.:Eye contact

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Inhalation No known significant effects or critical hazards.

No known significant effects or critical hazards.

Eye contact : Adverse symptoms may include the following:

pain or irritation watering redness

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)

Aspiration hazard

Name Result

Information on toxicological effects

: Dermal contact. Eye contact. Inhalation. Ingestion.

Potential acute health effects

Triphenyl phosphite LD50 Oral Rat 444 mg/kg -

Zinc Alkyldithiophosphate Eyes - Irritant Rabbit - - - Triphenyl phosphite Eyes - Mild irritant Rabbit - 24 hours 500 mg -

Skin - Severe irritant Human - 48 hours 125 mg - Skin - Moderate irritant Rabbit - 24 hours 20 mg - Skin - Severe irritant Rabbit - 500 mg -

There is no data available.

There is no data available.

There is no data available.

There is no data available.

1-Decene, homopolymer, hydrogenated ASPIRATION HAZARD - Category 1

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Section 11. Toxicological information

No known significant effects or critical hazards.General :

No known significant effects or critical hazards.Carcinogenicity :

No known significant effects or critical hazards.Mutagenicity :

No known significant effects or critical hazards.Teratogenicity :

Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Ingestion No known significant effects or critical hazards.:

Potential chronic health effects

Delayed and immediate effects and also chronic effects from short and long term exposure

Numerical measures of toxicity

Acute toxicity estimates

Potential immediate effects

: No known significant effects or critical hazards.

Short term exposure

Potential delayed effects : No known significant effects or critical hazards.

Potential immediate effects

: No known significant effects or critical hazards.

Long term exposure

Potential delayed effects : No known significant effects or critical hazards.

There is no data available.

Section 12. Ecological information

LogPow BCF Potential

Bioaccumulative potential

Other adverse effects : No known significant effects or critical hazards.

Product/ingredient name

Toxicity

Product/ingredient name SpeciesResult Exposure

Persistence and degradability

Soil/water partition coefficient (KOC)

: Not available.

Mobility in soil

Zinc Alkyldithiophosphate Acute EC50 1 to 5 mg/L Algae 96 hours Acute EC50 1 to 1.5 mg/L Crustaceans 48 hours Chronic LC50 1 to 5 mg/L Fish 96 hours

There is no data available.

1-Decene, homopolymer, hydrogenated

>6.5 - high

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Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

:Disposal methods

Section 14. Transport information

Not regulated.

Not regulated. Not regulated.

DOT Classification IMDG IATA

UN number

UN proper shipping name

Transport hazard class(es)

Packing group

Additional information

Environmental hazards

No. No. No.

AERG : Not applicable

Special precautions for user

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

: Not available.

Section 15. Regulatory information U.S. Federal regulations

Clean Water Act (CWA) 307: Zinc Alkyldithiophosphate; Toluene

Clean Water Act (CWA) 311: Toluene

Clean Air Act Section 112

(b) Hazardous Air Pollutants (HAPs)

: Not listed

Clean Air Act Section 602 Class I Substances

: Not listed

TSCA 8(a) PAIR: Zinc Alkyldithiophosphate; Siloxanes and Silicones, di-Me

TSCA 8(a) CDR Exempt/Partial exemption: Not determined

United States inventory (TSCA 8b): All components are listed or exempted.

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Section 15. Regulatory information

None of the components are listed.

WARNING: This product contains less than 1% of a chemical known to the State of California to cause birth defects or other reproductive harm.

Massachusetts :

SARA 313

Product name CAS number %

SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.

Toluene No. Yes. No. 7000 µg/day (ingestion) 13000 µg/day (inhalation)

Ingredient name Cancer Reproductive No significant risk level

Maximum acceptable dosage level

Zinc Alkyldithiophosphate 68649-42-3 1 - 5

Zinc Alkyldithiophosphate 68649-42-3 1 - 5

Form R - Reporting requirements

Supplier notification

California Prop. 65

Clean Air Act Section 602 Class II Substances

: Not listed

DEA List I Chemicals (Precursor Chemicals)

: Not listed

DEA List II Chemicals (Essential Chemicals)

: Not listed

New York : None of the components are listed.

New Jersey : The following components are listed: Distillates (petroleum), solvent-dewaxed heavy paraffinic; Zinc Alkyldithiophosphate

Pennsylvania : The following components are listed: Zinc Alkyldithiophosphate

State regulations

SARA 302/304

SARA 304 RQ : Not applicable.

Composition/information on ingredients

SARA 311/312

Classification : Immediate (acute) health hazard

Name % Fire hazard

Sudden release of pressure

Reactive Immediate (acute) health hazard

Delayed (chronic) health hazard

Composition/information on ingredients

No products were found.

Zinc Alkyldithiophosphate 1 - 5 No. No. No. Yes. No.

Triphenyl phosphite 0.1 - 1 No. No. No. Yes. No.

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Section 16. Other information

History

Prepared by :

Hazardous Material Information System (U.S.A.)

National Fire Protection Association (U.S.A.)

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA).

HMIS® materials may be purchased exclusively from J. J. Keller.

The customer is responsible for determining the PPE code for this material.

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.

Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.

Date of issue mm/dd/yyyy

Version :

01/15/2015

KMK Regulatory Services Inc.

Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.

Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

Health : 1Flammability :1 Physical hazards : 0

Health : 011 Instability :Flammability :

Revised Section(s) : Not applicable.

US Tariff Heading Number

Schedule B Code

: 2710.19.3080

2710.19.3080

Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com 10/10

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