NAPA Extended Life 50 50 Prediluted Antifreeze and Coolant.pdf

NAPA Extended Life 50/50 Prediluted Antifreeze & Coolant Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

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SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product form : Mixture

Product name : NAPA Extended Life 50/50 Prediluted Antifreeze & Coolant

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture : Antifreeze & Coolant

1.3. Details of the supplier of the safety data sheet

Old World Industries, LLC 4065 Commercial Ave.

Northbrook, IL 60062 - USA T (847) 559-2000 www.oldworldind.com

1.4. Emergency telephone number

Emergency number : (800) 424-9300; (703) 527 3887 (International) Chemtrec

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

GHS-US classification

Acute Tox. 4 (Oral) H302 Repr. 2 H361

STOT RE 2 H373

Full text of H-phrases: see section 16

2.2. Label elements

GHS-US labelling

Hazard pictograms (GHS-US) :

GHS07

GHS08

Signal word (GHS-US) : Warning

Hazard statements (GHS-US) : H302 - Harmful if swallowed H361 - Suspected of damaging fertility or the unborn child H373 - May cause damage to organs (kidneys) through prolonged or repeated exposure (oral)

Precautionary statements (GHS-US) : P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P260 - Do not breathe mist, spray, vapors P264 - Wash affected areas thoroughly after handling P270 - Do not eat, drink or smoke when using this product P280 - Wear personal protective equipment as required P301+P310 - If swallowed: Immediately call doctor/physician or poison center. Rinse Mouth P301+P330+P331 - If swallowed: rinse mouth. Do NOT induce vomiting P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P308+P313 - If exposed or concerned: Get medical advice/attention P405 - Store locked up P501 - Dispose of contents/container, in a safe manner, to appropriate waste disposal facility, in accordance with local/regional/national/international regulations

2.3. Other hazards

No additional information available

2.4. Unknown acute toxicity (GHS-US)

No data available

NAPA Extended Life 50/50 Prediluted Antifreeze & Coolant

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SECTION 3: Composition/information on ingredients

3.1. Substance

Not applicable

3.2. Mixture

Name Product identifier % by wt GHS-US classification ethylene glycol (CAS No) 107-21-1 <= 50 Acute Tox. 4 (Oral), H302 water (CAS No) 7732-18-5 < 50 Not classified diethylene glycol (CAS No) 111-46-6 < 3 Acute Tox. 4 (Oral), H302

STOT RE 2, H373

potassium 2-ethylhexanoate (CAS No) 3164-85-0 < 2 Repr. 2, H361 denatonium benzoate (CAS No) 3734-33-6 30 - 50 ppm Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Eye Irrit. 2A, H319

STOT SE 3, H335

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible).

First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, give artificial respiration. Allow the victim to rest. If breathing is difficult, give oxygen. Seek immediate medical advice.

First-aid measures after skin contact : Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Rinse immediately with plenty of water (for at least 15 minutes). Get medical advice/attention. Remove contaminated clothing.

First-aid measures after eye contact : Rinse immediately with plenty of water for 15 minutes, lifting lower and upper lids. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Rinse immediately with plenty of water. Get medical advice/attention.

First-aid measures after ingestion : Obtain emergency medical attention. Rinse mouth. Do NOT induce vomiting. Call a POISON CENTER/doctor/physician if you feel unwell. If medical advice is delayed, and if the person has swallowed a moderate volume of material (a few ounces), then give three to four ounces of hard liquor, such as whiskey. For children, give proportionally less liquor, according to weight.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms/injuries : Causes damage to organs (kidneys) Oral. Suspected of damaging fertility or the unborn child.

Symptoms/injuries after skin contact : Causes skin irritation.

Symptoms/injuries after eye contact : Causes serious eye damage.

Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard. The lethal dose in humans is estimated to be 100 mL (3 oz).

4.3. Indication of any immediate medical attention and special treatment needed

A more effective intravenous antidote for physician uses is 4-methylpyrazaole, a potent inhibitor of alcohol dehydrogenases, which effectively blocks the formation of toxic metabolites of ethylene glycol. It has been used to decrease the metabolic consequences of ethylene glycol poisoning before metabolic acidosis coma, seizures, and renal failure have occured.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Fine water spray. Alcohol-resistant foam. Foam. Carbon dioxide. Dry chemical powder. Sand.

Water fog.

Unsuitable extinguishing media : Do not use a heavy water stream. May spread fire.

5.2. Special hazards arising from the substance or mixture

Fire hazard : During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Carbon monoxide. Carbon dioxide.

Reactivity : No dangerous reactions known under normal conditions of use.

5.3. Advice for firefighters

Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment.

Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

Special protective equipment for fire fighters : Wear positive pressure self-contained breathing apparatus (SCBA). Protective fire fighting clothing (includes fire-fighting helmet, coat, pants, boots and gloves).

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SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection. Refer to section 8.2.

Emergency procedures : Ventilate area.

6.2. Environmental precautions

Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.

6.4. Reference to other sections

See Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor.

Hygiene measures : Do not eat, drink or smoke when using this product. Wash affected areas thoroughly after handling.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Heat sources.

Keep container closed when not in use. Product may become solid at temperatures below -37 ºC (-34 ºF). Do not store near food, foodstuffs, drugs or potable water supplies. Do not cut, drill, weld, use a blowtorch on, etc. containers even when empty.

Incompatible products : Keep away from strong acids, strong bases and oxidizing agents.

Incompatible materials : Sources of ignition.

7.3. Specific end use(s)

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

ethylene glycol (107-21-1)

USA ACGIH ACGIH Ceiling (mg/m³) 100.00 mg/m³

USA ACGIH Remark (ACGIH) Upper Respiratory Tract (URT) & Eye irritant

8.2. Exposure controls

Personal protective equipment : Avoid all unnecessary exposure. Gloves. Safety glasses.

Hand protection : Wear protective gloves.

Eye protection : Chemical goggles or safety glasses.

Respiratory protection : If exposed to levels above exposure limits wear appropriate respiratory protection.

Other information : Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Liquid

Color : Slightly yellow to green

Odor : Mild

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Odor threshold : No data available pH : 8

Relative evaporation rate (butylacetate=1) : Nil

Freezing point : -37 °C (-34 ºF)

Boiling point : 107 °C (224 ºF)

Flash point : 116 °C (241 ºF) [100% Ethylene Glycol] ASTM D56

Auto-ignition temperature : 400 °C (752 ºF) [100% Ethylene Glycol] Literature

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapor pressure : < 0.1 @ 20 ºC

Relative vapor density at 20 °C : No data available

Specific Gravity : 1.04

Density : 1.04 kg/l (8.7 lbs/gal)

Solubility : Water: Complete

Log Pow : No data available

Log Kow : No data available

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

Explosive properties : Not applicable.

Oxidizing properties : Not applicable.

Explosive limits : Not applicable.

9.2. Other information

VOC content : 0.00 %

SECTION 10: Stability and reactivity

10.1. Reactivity

No dangerous reactions known under normal conditions of use.

10.2. Chemical stability

Stable.

10.3. Possibility of hazardous reactions

Hazardous polymerization will not occur.

10.4. Conditions to avoid

Extremely high or low temperatures. Keep away from any flames or sparking source.

10.5. Incompatible materials

Keep away from strong acids, strong bases and oxidizing agents.

10.6. Hazardous decomposition products

Carbon dioxide. Carbon monoxide. Fume. Aldehydes. Ethers. alcohols.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Oral: Harmful if swallowed.

denatonium benzoate (3734-33-6)

LD50 oral rat 584 mg/kg (Rat)

LD50 dermal rabbit > 2,000 mg/kg (Rabbit)

ATE US (oral) 584 mg/kg bodyweight ethylene glycol (107-21-1)

LD50 oral rat > 5,000 mg/kg (Rat)

ATE US (oral) 500 mg/kg bodyweight diethylene glycol (111-46-6)

LD50 oral rat 12,565 mg/kg (Rat)

LD50 dermal rabbit 11,890 mg/kg (Rabbit)

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ATE US (oral) 500 mg/kg bodyweight

ATE US (dermal) 11,890 mg/kg bodyweight

Skin corrosion/irritation : Not classified pH: 8

Serious eye damage/irritation : Not classified pH: 8

Respiratory or skin sensitisation : Not classified

Germ cell mutagenicity : Not classified

Carcinogenicity : Not classified

Reproductive toxicity : Suspected of damaging fertility or the unborn child.

Specific target organ toxicity (single exposure) : Not classified

Specific target organ toxicity (repeated exposure)

: May cause damage to organs (kidneys) through prolonged or repeated exposure (oral).

Aspiration hazard : Not classified

Potential adverse human health effects and symptoms

: Based on available data, the classification criteria are not met. Harmful if swallowed.

Symptoms/injuries after skin contact : Causes skin irritation.

Symptoms/injuries after eye contact : Causes serious eye damage.

Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard. The lethal dose in humans is estimated to be 100 mL (3 oz).

SECTION 12: Ecological information

12.1. Toxicity

LC50 fish 1 > 1,000 mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss)

EC50 Daphnia 1 13 mg/l (48 h; Daphnia magna) ethylene glycol (107-21-1)

LC50 fish 1 53,000 mg/l (96 h; Pimephales promelas; Static system)

EC50 Daphnia 1 > 10,000 mg/l (24 h; Daphnia magna)

LC50 fish 2 40,761 mg/l (96 h; Salmo gairdneri (Oncorhynchus mykiss); Static system)

Threshold limit algae 1 > 10,000 mg/l (168 h; Scenedesmus quadricauda)

Threshold limit algae 2 2,000 mg/l (192 h; Microcystis aeruginosa) diethylene glycol (111-46-6)

LC50 fish 1 > 5,000 ppm (24 h; Carassius auratus)

LC50 other aquatic organisms 1 1,174 mg/l (Xenopus laevis)

EC50 Daphnia 1 > 10,000 mg/l (24 h; Daphnia magna)

LC50 fish 2 61,072 ppm (168 h; Poecilia reticulata)

TLM fish 1 > 32,000 mg/l (96 h; Gambusia affinis)

TLM other aquatic organisms 1 > 1,000 ppm (96 h)

Threshold limit other aquatic organisms 1 1,174 mg/l (72 h; Xenopus laevis; Toxicity test)

Threshold limit other aquatic organisms 2 10,745 mg/l (16 h; Protozoa; Toxicity test)

Threshold limit algae 1 2,700 mg/l (168 h; Scenedesmus quadricauda)

Threshold limit algae 2 100 mg/l (Selenastrum capricornutum)

12.2. Persistence and degradability

Persistence and degradability Biodegradability in water: no data available. No (test) data on mobility of the substance available.

ethylene glycol (107-21-1)

Persistence and degradability Readily biodegradable in water. Biodegradable in the soil.

Biochemical oxygen demand (BOD) 0.47 g O2/g substance

Chemical oxygen demand (COD) 1.24 g O2/g substance

ThOD 1.29 g O2/g substance

BOD (% of ThOD) 0.36 % ThOD

04/14/2015 EN (English) 6/9 diethylene glycol (111-46-6)

Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Photolysis in the air.

Biochemical oxygen demand (BOD) 0.02 g O2/g substance

Chemical oxygen demand (COD) 1.51 g O2/g substance

ThOD 1.51 g O2/g substance

BOD (% of ThOD) 0.015 % ThOD

12.3. Bioaccumulative potential

Log Pow 1.78 (Estimated value)

Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).

ethylene glycol (107-21-1)

BCF fish 1 10 (72 h; Leuciscus idus)

BCF other aquatic organisms 1 0.21 - 0.6 (Procambarus sp.; Chronic)

BCF other aquatic organisms 2 190 (24 h; Algae)

Log Pow -1.34 (Experimental value)

Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).

diethylene glycol (111-46-6)

Log Pow -1.98

Bioaccumulative potential Bioaccumulation: not applicable.

12.4. Mobility in soil

Surface tension 0.048 N/m (20 ºC / 68 ºF)

Surface tension 0.0485 N/m

12.5. Other adverse effects

Effect on ozone layer : No known effect on the ozone layer

Effect on global warming : No known ecological damage caused by this product.

Effect on global warming : No additional information available

Other information : Avoid release to the environment.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste disposal recommendations : Dispose of contents/container, in a safe manner, to appropriate waste disposal facility, in accordance with local/regional/national/international regulations.

Ecology - waste materials : Avoid release to the environment.

SECTION 14: Transport information

In accordance with DOT

Transport document description : UN3082 Environmentally hazardous substances, liquid, n.o.s., 9, III

UN-No.(DOT) : 3082

DOT NA no. : UN3082

Proper Shipping Name (DOT) : Environmentally hazardous substances, liquid, n.o.s.

Department of Transportation (DOT) Hazard Classes

: 9 - Class 9 - Miscellaneous hazardous material 49 CFR 173.140

Hazard labels (DOT) : 9 - Class 9 (Miscellaneous dangerous materials)

DOT Symbols : G - Identifies PSN requiring a technical name

Packing group (DOT) : III - Minor Danger

DOT Packaging Exceptions (49 CFR 173.xxx) : 155

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DOT Packaging Non Bulk (49 CFR 173.xxx) : 203

DOT Packaging Bulk (49 CFR 173.xxx) : 241

DOT Quantity Limitations Passenger aircraft/rail

(49 CFR 173.27)

: No limit

DOT Quantity Limitations Cargo aircraft only (49

CFR 175.75)

: No limit

DOT Vessel Stowage Location : A - The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a passenger vessel.

Other information : Non Bulk: Not regulated by the US D.O.T. (in quantities under 5,000 lbs in any one inner package).

ADR

Transport by sea

Proper Shipping Name (IMDG) : Not regulated by IMDG (in quantities under 5,000 lbs in any one inner package)

Air transport

Proper Shipping Name (IATA) : Not regulated by IATA (in quantities under 5,000 lbs in any one inner package)

SECTION 15: Regulatory information

15.1. US Federal regulations

EPA TSCA Regulatory Flag Toxic Substances Control Act (TSCA): The intentional ingredients of this product are listed

Listed on the United States TSCA (Toxic Substances Control Act) inventory

Listed on United States SARA Section 313

RQ (Reportable quantity, section 304 of EPA's List of Lists)

5000 lb(s)

SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Delayed (chronic) health hazard Ethylene glycol is subject to Tier I and/or Tier II annual inventory reporting.

SARA Section 313 - Emission Reporting Ethylene glycol is subject to Form R Reporting requirements.

potassium 2-ethylhexanoate (3164-85-0)

15.2. International regulations

CANADA

NAPA Extended Life 50/50 Prediluted Antifreeze & Coolant

WHMIS Classification Class D Division 2 Subdivision A - Very toxic material causing other toxic effects

WHMIS Classification

Class D Division 2 Subdivision A - Very toxic material causing other toxic effects

EU-Regulations

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Classification according to Regulation (EC) No. 1272/2008 [CLP]

Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]

Not classified

15.2.2. National regulations

NAPA Extended Life 50/50 Prediluted Antifreeze & Coolant

DSL (Canada): The intentional ingredients of this product are listed ECL (South Korea): The intentional ingredients of this product are listed.

EINECS (Europe): The intentional ingredients of this product are listed ENCS (Japan): The intentional ingredients of this product are listed

15.3. US State regulations

U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List

U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List

SECTION 16: Other information

Full text of H-phrases:

------ Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4

------ Eye Irrit. 2A Serious eye damage/eye irritation, Category 2A

------ Repr. 2 Reproductive toxicity, Category 2

------ Skin Irrit. 2 Skin corrosion/irritation, Category 2

------ STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2

------ STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation

------ H302 Harmful if swallowed

------ H315 Causes skin irritation

------ H319 Causes serious eye irritation

------ H335 May cause respiratory irritation

------ H361 Suspected of damaging fertility or the unborn child

------ H373 May cause damage to organs through prolonged or repeated exposure

NFPA health hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given.

NFPA fire hazard : 1 - Must be preheated before ignition can occur.

NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water.

HMIS III Rating

Health : 2 Moderate Hazard - Temporary or minor injury may occur

Flammability : 1 Slight Hazard

Physical : 0 Minimal Hazard

Personal Protection : B

SDS GHS US (GHS HazCom 2012) OWI

Old World Industries, LLC makes no warranty, representation or guarantee as to the accuracy, sufficiency or completeness of the material set forth herein. It is the user's responsibility to determine the safety, toxicity and suitability of his own use, handling and disposal of this product. Since actual use by others is beyond our control, no warranty, expressed or implied, is made by Old World Industries, LLC as to the effects of such use, the results to be obtained or the safety and toxicity of this product, nor does Old World Industries, LLC assume liability arising out of the use by others of this product referred to herein. The data in this SDS relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process.

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