Purell Advance Hand Sanitizer Gel SDS.pdf

SAFETY DATA SHEET

PURELL® Advanced Hand Sanitizer Gel

Version 1.1 SDS Number: 400000000422 Revision Date: 08/02/2020

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SECTION 1. IDENTIFICATION

Product name : PURELL® Advanced Hand Sanitizer Gel

Manufacturer or supplier's details

Company name of supplier : GOJO Industries, Inc.

Address : One GOJO Plaza, Suite 500

Akron, Ohio 44311 Telephone : 1 (330) 255-6000

Emergency telephone number

: CHEMTREC 1-800-424-9300

CHEMTREC +1-703-527-3887: Outside USA & CANADA

Recommended use of the chemical and restrictions on use

Recommended use : Hand Sanitizer Restrictions on use : This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer.

While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet.

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification

Flammable liquids

: Category 3

Eye irritation

: Category 2A

GHS label elements

Hazard pictograms

Signal word

: Warning

Hazard statements

: H226 Flammable liquid and vapour.

H319 Causes serious eye irritation.

Precautionary statements

: Prevention:

P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

P233 Keep container tightly closed.

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P240 Ground/bond container and receiving equipment.

P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment.

P242 Use only non-sparking tools.

P243 Take precautionary measures against static discharge.

P280 Wear eye protection/ face protection.

Response:

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P337 + P313 If eye irritation persists: Get medical advice/ attention.

P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.

Storage:

P403 + P235 Store in a well-ventilated place. Keep cool.

Disposal:

P501 Dispose of contents/ container to an approved waste disposal plant.

Other hazards

None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous components

Chemical name CAS-No. Concentration (%)

Ethyl Alcohol 64-17-5 >= 60 - < 70

Isopropyl Alcohol 67-63-0 >= 1 - < 5

SECTION 4. FIRST AID MEASURES

General advice : In the case of accident or if you feel unwell, seek medical advice immediately.

When symptoms persist or in all cases of doubt seek medical advice.

If inhaled : If inhaled, remove to fresh air.

If symptoms persist, call a physician.

In case of skin contact : Wash with water and soap as a precaution.

Get medical attention if irritation develops and persists.

In case of eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.

If easy to do, remove contact lens, if worn.

Seek medical advice.

If swallowed : If swallowed, DO NOT induce vomiting.

Rinse mouth with water.

Obtain medical attention.

Most important symptoms and effects, both acute and delayed

: Causes serious eye irritation.

Protection of first-aiders : First Aid responders should pay attention to self-protection and use the recommended protective clothing

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SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Water spray Alcohol-resistant foam Dry chemical Carbon dioxide (CO2)

Unsuitable extinguishing media

: High volume water jet

Specific hazards during firefighting

: Do not use a solid water stream as it may scatter and spread fire.

Cool closed containers exposed to fire with water spray.

Flash back possible over considerable distance.

May form explosive mixtures in air.

Exposure to decomposition products may be a hazard to health.

Carbon oxides

Hazardous combustion products

: Carbon oxides

Specific extinguishing methods

: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Use water spray to cool unopened containers.

Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Special protective equipment for firefighters

: In the event of fire, wear self-contained breathing apparatus.

Use personal protective equipment.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

: Use personal protective equipment.

Ensure adequate ventilation.

Remove all sources of ignition.

Evacuate personnel to safe areas.

Keep people away from and upwind of spill/leak.

Material can create slippery conditions.

Environmental precautions

: Discharge into the environment must be avoided.

Prevent further leakage or spillage if safe to do so.

Retain and dispose of contaminated wash water.

Local authorities should be advised if significant spillages cannot be contained.

Methods and materials for containment and cleaning up

: Non-sparking tools should be used.

Soak up with inert absorbent material.

Suppress (knock down) gases/vapours/mists with a water spray jet.

Keep in suitable, closed containers for disposal.

Clean contaminated floors and objects thoroughly while observing environmental regulations.

SECTION 7. HANDLING AND STORAGE

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Advice on safe handling : For personal protection see section 8.

Keep away from heat.

Use with local exhaust ventilation.

Avoid contact with eyes.

Conditions for safe storage : Take measures to prevent the build up of electrostatic charge.

Keep in properly labelled containers.

Keep container tightly closed in a dry and well-ventilated place.

Store in accordance with the particular national regulations.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value type (Form of exposure)

Control parameters / Permissible concentration

Basis

Ethyl Alcohol 64-17-5 TWA 1,000 ppm 1,900 mg/m3

NIOSH REL

TWA 1,000 ppm

1,900 mg/m3

OSHA Z-1

STEL 1,000 ppm ACGIH

Isopropyl Alcohol 67-63-0 TWA 200 ppm ACGIH STEL 400 ppm ACGIH TWA 400 ppm

980 mg/m3

ST 500 ppm

1,225 mg/m3

TWA 400 ppm

980 mg/m3

OSHA Z-1

Biological occupational exposure limits

Components CAS-No. Control parameters

Biological specimen

Samplin g time

Permissible concentratio n

Basis

Isopropyl Alcohol 67-63-0 Acetone Urine End of shift at end of workwee k

40 mg/l ACGIH

BEI

Personal protective equipment

Respiratory protection : No personal respiratory protective equipment normally required.

Hand protection Remarks : No special protective equipment required.

Eye protection : Wear face-shield and protective suit for abnormal processing problems.

Skin and body protection : No special measures necessary provided product is used correctly.

Protective measures : Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place.

Ensure that eye flushing systems and safety showers are located close to the working place.

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Hygiene measures : Handle in accordance with good industrial hygiene and safety practice.

Avoid contact with eyes.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid Colour : clear, colourless, light yellow Odour : citrus Odour Threshold : No data available pH : 6.5 - 8.5

Melting point/freezing point : No data available Boiling point/boiling range : 70.00 °C

Flash point : 25.00 °C

Evaporation rate : No data available

Flammability (solid, gas) : Not applicable

Flammability (liquids) :

Upper explosion limit

: No data available

Lower explosion limit

: No data available

Vapour pressure : No data available

Relative vapour density : No data available

Density : 0.8743 g/cm3

Solubility(ies) Water solubility : soluble

Partition coefficient: n-octanol/water

: Not applicable

Auto-ignition temperature : not determined

Thermal decomposition : The substance or mixture is not classified self-reactive.

Viscosity Viscosity, kinematic : 3500 - 23000 mm2/s (20 °C)

Explosive properties : Not explosive

Oxidizing properties : The substance or mixture is not classified as oxidizing.

SECTION 10. STABILITY AND REACTIVITY

Reactivity : Not classified as a reactivity hazard.

Chemical stability : Stable under normal conditions.

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Possibility of hazardous reactions

: Vapours may form explosive mixture with air.

Conditions to avoid : Heat, flames and sparks.

Incompatible materials : Oxidizing agents Hazardous decomposition products

: No hazardous decomposition products are known.

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure Inhalation Skin contact Eye contact

Acute toxicity

Not classified based on available information.

Product:

Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method

Components:

Ethyl Alcohol:

Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg

Acute inhalation toxicity : LC50 (Rat): 124.7 mg/l

Exposure time: 4 h Test atmosphere: vapour

Isopropyl Alcohol:

Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg

Acute inhalation toxicity : LC50 (Rat): 72.6 mg/l

Exposure time: 4 h Test atmosphere: vapour

Acute dermal toxicity : LD50 (Rat): > 5,000 mg/kg

Skin corrosion/irritation

Not classified based on available information.

Components:

Ethyl Alcohol:

Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation

Isopropyl Alcohol:

Species: Rabbit Result: No skin irritation

Serious eye damage/eye irritation

Causes serious eye irritation.

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Ethyl Alcohol:

Species: Rabbit Result: Irritation to eyes, reversing within 21 days Method: OECD Test Guideline 405

Isopropyl Alcohol:

Species: Rabbit Result: Irritation to eyes, reversing within 21 days

Respiratory or skin sensitisation

Skin sensitisation: Not classified based on available information.

Respiratory sensitisation: Not classified based on available information.

Components:

Ethyl Alcohol:

Test Type: Local lymph node assay (LLNA) Exposure routes: Skin contact Species: Mouse Result: negative

Isopropyl Alcohol:

Test Type: Buehler Test Exposure routes: Skin contact Species: Guinea pig Method: OECD Test Guideline 406 Result: negative

Germ cell mutagenicity

Components:

Ethyl Alcohol:

Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test

Genotoxicity in vivo : Test Type: Rodent dominant lethal test (germ cell) (in vivo) Test species: Mouse Application Route: Ingestion

Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES)

Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Test species: Mouse Application Route: Intraperitoneal injection

Carcinogenicity

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Isopropyl Alcohol:

Species: Rat Application Route: inhalation (vapour) Exposure time: 104 weeks Method: OECD Test Guideline 451

IARC

No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

OSHA

equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.

NTP

equal to 0.1% is identified as a known or anticipated carcinogen by NTP.

Reproductive toxicity

Components:

Ethyl Alcohol:

Effects on fertility : Test Type: Two-generation reproduction toxicity study

Species: Mouse Application Route: Ingestion Method: OECD Test Guideline 416

Effects on fertility : Test Type: Two-generation reproduction toxicity study

Species: Rat

Effects on foetal development

: Test Type: Embryo-foetal development Species: Rat

STOT - single exposure

Components:

Assessment: May cause drowsiness or dizziness.

STOT - repeated exposure

Repeated dose toxicity

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Ethyl Alcohol:

Species: Rat NOAEL: 2,400 mg/kg Application Route: Ingestion Exposure time: 2 y

Isopropyl Alcohol:

Species: Rat NOAEL: 5000 ppm Application Route: inhalation (vapour) Exposure time: 104 w Method: OECD Test Guideline 413

Aspiration toxicity

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Components:

Ethyl Alcohol:

Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): > 1,000 mg/l

Exposure time: 96 h

Toxicity to daphnia and other aquatic invertebrates

: EC50 (Daphnia magna (Water flea)): > 1,000 mg/l Exposure time: 48 h

Toxicity to algae : EC50 (Chlorella vulgaris (Fresh water algae)): 275 mg/l Exposure time: 72 h Method: OECD Test Guideline 201

(Chronic toxicity)

: NOEC (Daphnia magna (Water flea)): 9.6 mg/l Exposure time: 9 d

Toxicity to bacteria : EC50 (Photobacterium phosphoreum): 32.1 mg/l Exposure time: 0.25 h

Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 10,000 mg/l

Exposure time: 96 h

: EC50 (Daphnia magna (Water flea)): > 10,000 mg/l Exposure time: 24 h

Toxicity to bacteria : EC50 (Pseudomonas putida): > 1,050 mg/l Exposure time: 16 h

Persistence and degradability

Ethyl Alcohol:

Biodegradability : Result: Readily biodegradable.

Biodegradation: 84 %

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Exposure time: 20 d

Biodegradability : Result: rapidly degradable

Bioaccumulative potential

Ethyl Alcohol:

Partition coefficient: n-

: log Pow: -0.35

Partition coefficient: n-

: log Pow: 0.05

Mobility in soil

No data available

Other adverse effects

No data available

Product:

Regulation 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances

Remarks This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods

Waste from residues : Dispose of in accordance with local regulations.

Contaminated packaging : Dispose of as unused product.

Empty containers should be taken to an approved waste handling site for recycling or disposal.

SECTION 14. TRANSPORT INFORMATION

International Regulation

IATA-DGR

UN/ID No. : UN 1987

Proper shipping name : Alcohols, n.o.s.

(Ethanol, Propan-2-ol)

Class : 3

Packing group : III

Packing instruction (cargo aircraft)

: 366

Packing instruction (passenger aircraft)

: 355

IMDG-Code

UN number : UN 1987

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Proper shipping name : ALCOHOLS, N.O.S.

(Ethanol, Propan-2-ol)

Class : 3 Packing group : III Labels : 3 EmS Code : F-E, S-D Marine pollutant : no National Regulations

49 CFR

UN/ID/NA number : UN 1987

Proper shipping name : Alcohols, n.o.s.

Class : 3

Packing group : III

ERG Code : 127

Marine pollutant : no

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know Act

SARA 311/312 Hazards

: Fire Hazard Acute Health Hazard

SARA 302

: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313

: The following components are subject to reporting levels established by SARA Title III, Section 313:

Isopropyl Alcohol

67-63-0 3.4086 %

Clean Air Act

This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61).

This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F).

The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489):

Ethyl Alcohol 64-17-5 65.2821 % Isopropyl Alcohol 67-63-0 3.4086 % This product does not contain any VOC exemptions listed under the U.S. Clean Air Act Section 450.

California Prop 65 This product does not require a warning label under California

Proposition 65.

The components of this product are reported in the following inventories:

TSCA

: On TSCA Inventory

CH INV

: On the inventory, or in compliance with the inventory

AICS : On the inventory, or in compliance with the inventory

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DSL

ENCS

ISHL

KECI

PICCS

IECSC

NZIoC

Inventories

AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA)

SECTION 16. OTHER INFORMATION

Further information

NFPA: HMIS III:

Revision Date : 08/02/2020 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Flammability

H e a lt h

In s ta b ility

FLAMMABILITY

PHYSICAL HAZARD

HEALTH

Special hazard.

0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic