Environmental_Site_Assessment_0001.pdf

8744 SW 133RD STREET · MIAMI, FLORIDA 33176 · TEL.: (305) 447-9777 · FAX: (305) 567-2853

January 12, 2016

Mr. Tom Kelly, Chief, Realty Operations National Park Service, Land Acquisition Project Office 2975 Horseshoe Drive, South, Suite 800 Naples, Florida 34104

Re: CRB Project No. NPS 1244-04; Phase II ESA Summary Report, for the Coopertown

Airboat Rides, located at 22700 S.W. 8th Street, Miami, Florida

Dear Mr. Kelly:

CRB Geological & Environmental Services, Inc. (CRB) is pleased to provide you with this Phase II Environmental Site Assessment (Phase II) Summary Report for the above referenced property (Site). This Phase II was implemented to assess potential impacts to the Site associated with the Recognized Environmental Conditions (RECs) identified in the Phase I Environmental Site Assessment prepared by CRB and dated August 25, 2015. These RECs included: 1) Former and Current Maintenance Activities at Maintenance Shop; 2) Chemical Storage Area; 3) Historic Discharges to Septic system; and 4) Former Adjoining Underground Storage Tank Facility (UST). In addition, an asbestos survey and a lead-based paint survey were conducted. Lead was detected in the ceramic tiles in the restrooms only. The asbestos survey was provided under separate cover. Asbestos was detected in the house siding and window caulking. All other assessment activities are included herein. A Site Location Map and Site Map with Sampling Locations are included as Figures 1 and 2, respectively.

Lead was identified in ceramic floor tiles in the restrooms. No other site impacts were identified.

Soil Assessment

On November 23, 2015, CRB personnel were on-site to collect two (2) soil samples from the Site. Soil sample SB-1 was collected from the hydraulic lift area, and soil sample SB-2 was collected from the maintenance area. The locations of the soil samples are shown on Figure 2.

All soil samples were collected using a stainless steel hand auger. Soil sample SB-1 was collected from near the groundwater interface, encountered at approximately two (2) feet below grade, and soil sample SB-2 was collected from approximately one-half (0.5) foot below grade.

All soil sampling was conducted in accordance with DEP SOP-001/01.

The soil samples were preserved on wet ice and transported to Pace Analytical Services, Inc.

(Pace) in Pompano Beach, Florida, using proper chain of custody protocols to control the transfer of samples. Pace analyzed the samples for Volatile Organic Aromatics (VOAs) by EPA Method 8260, Polycyclic Aromatic Hydrocarbons (PAHs) by EPA Method 8270, and Total Recoverable Petroleum Hydrocarbons (TRPH) by Method FL PRO.

NPS 1244-04 2 CRB Geological & Environmental Services, Inc.

All compounds analyzed were reported as Below Detectable Limits (BDL) The exception of Petroleum Rand Organics, which were reported at 474 mg/kg in SB-2. A summary of the soil analytical results is included in Table 1, and the laboratory analytical results and chain of custody record are included in Attachment A.

Groundwater Assessment

On November 23, 2015, CRB personnel were on-site to install monitoring well MW-1 and MW- 2 near the hydraulic lift and maintenance area, respectively. The locations of the monitoring wells are shown on Figure 2. The wells were installed with a truck mounted drill rig equipped with hollow stem augers to a depth of approximately eleven and one-half (11.5) feet below grade. The monitoring well was constructed of 1-inch diameter schedule-40 polyvinyl chloride (PVC) pipe with ten (10) feet of 0.01-inch slotted screen, followed by a solid riser to the surface.

On November 25, 2015, CRB personnel were on-site to collect groundwater samples from the newly installed monitoring wells. Prior to sampling, three (3) well volumes were purged from each monitoring well using a peristaltic pump. Groundwater sampling was conducted in accordance with DEP SOP-001/01. The groundwater sampling log is included in Attachment B.

The groundwater samples were preserved on ice and transported to Pace using proper chain of custody protocols to control the transfer of samples. Pace analyzed the sample for VOAs by EPA Method 8260, PAHs by EPA Method 8270, and TRPH by Method FL PRO.

All compounds analyzed were reported as BDL or below the applicable regulatory standards. A summary of the groundwater results is included in Table 2, and the laboratory analytical reports and chain of custody record are included in Attachment C.

Lead Based Paint Survey

In 1978, the Consumer Product Safety Commission (CPSC) banned the production of virtually all house paints containing lead. Established guidelines for lead in paint include the U.S.

Department of Housing and Urban Development's (HUD's) 1 mg/cm2. This level is only enforceable for HUD properties but is a guideline for other properties at which concentration lead abatement measures or Operations and Maintenance programs should be implemented.

As part of this Phase II, a lead based paint survey was conducted at the Site. This survey included the analysis of suspect materials within the interior and exterior via x-ray fluorescence (XRF). Lead based paint in excess of the HUD guideline, and ranging from 5.40 mg/cm2 to 5.90 mg/cm2, was identified in ceramic floor tiles in both restrooms. All other samples were reported as below the HUD guideline. The lead based paint results are included in Attachment D.

Discussion, Conclusions, & Recommendations

To assess potential impacts associated with the RECs identified in the Phase I ESA, CRB recommended and implemented this Phase II, including the collection and analysis of soil and groundwater samples. In addition, an asbestos survey and a lead based paint survey were requested. The asbestos survey was provided under separate cover. All other results are reported herein.

NPS 1244-04 3 CRB Geological & Environmental Services, Inc.

No compounds were detected above Florida Department of Environmental Protection (DEP) standards in the groundwater samples. In SB-2, Petroleum Range Organics were reported at 474 mg/kg. All other compounds in SB-1 and SB-2 were below FDEP standards. CRB recommends removal of contaminated soil in the area of SB-2. The estimated cost to complete this task is $10,000 to $15,000.

In addition, lead-based paint, in excess of the HUD guidelines, was reported on ceramic tiles in both restrooms. This material may be left in place provided it remains in good condition. In the event removal of the tile is required, all work must be conducted in accordance with the EPA’s Lead Renovation, Repair and Painting (RRP) Program. The cost to remove the tile is estimated at $10,000 to $15,000. This does not include tile replacement.

As stated previously, an asbestos survey was completed and asbestos was detected in the siding and window caulking. The cost to remove the materials is estimated at $18,000 to $29,000.

If you have any questions or require any additional information, please do not hesitate to contact one of us at (305) 447-9777.

Sincerely, CRB Geological & Environmental Services, Inc.

Frederick R. Baddour, P.G. Doug Lowell Senior Project Manager Project Manager

Attachments

FIGURES

TABLES

Table 1 - Summary of Soil Laboratory Analytical Results Coopertown Air Boat Rides Facility

22700 S.W. 8th Street Miami, Florida

Sample ID Date

T R

P H

B en zo (a

)p yr en e

B en zo (k

)f lu or an th en e

F lu or an th en e

P yr en e

T ot al V

O A s

SB-1 11/25/2015 7.9 U 0.032 I 0.027 U 0.053I 0.044 I

SB-2 11/25/2015 474 0.025I 0.030 U 0.034 I 0.031 I

460 0.1 # 3200 2400 *

2700 0.7 # 59000 45000 * 340 8 24 1200 880 *

Notes:

All compounds reported in mg/kg unless otherwise noted.

TRPH - Total recoverable petroleum hydrocarbons VOA - Volatile organic aromatics

U - The compound was analyzed for but not detected.

* - Regulatory standards provided for individual compounds.

Leachability Commercial SCTL

Residential SCTL

Soil Cleanup Target Levels (SCTLs) and Leachability standards as provided in Rule 62-777, F.A.C.

I - The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit.

NPS 1244-04 CRB Geological & Environmental Services, Inc.

Table 2 - Summary of Groundwater Analytical Results Coopertown Air Boat Rides Facility

22700 S.W. 8th Street Miami, Florida

Sample ID Date

B en ze n e

M T

B E

T R

P H

(m g/

L

T ot al P

A H

MW-1 11/25/2015 0.19I 0.50 U 0.062 U

1 20 5 * 100 200 50 *

Notes:

All compounds are reported in µg/L unless otherwise noted.

MTBE - Methyl-tert-butyl ether TRPH - Total recoverable petroleum hydrocarbons PAH - Polycyclic aromatic hydrocarbons

U - The compound was analyzed for but not detected.

* - Regulatory standards provided for individual compounds.

NADC

GCTL

Groundwater Cleanup Target Levels (GCTLs) and Natural Attenuation Default Concentrations as provided in Rule 62-777, F.A.C.

I - The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit.

NPS 1244-04 CRB Geological & Environmental Services, Inc.

ATTACHMENT A

SOIL LABORATORY ANALYTICAL REPORTS

& CHAIN OF CUSTODY RECORD

#=CL#

December 07, 2015

LIMS USE: FR - DOUG LOWELL

LIMS OBJECT ID: 35218364

35218364 Project:

Pace Project No.:

RE:

Doug Lowell CRB Geological & Environmental Services 8744 S.W. 133rd Street Miami, FL 33176

NPS 1244-04

Dear Doug Lowell:

Enclosed are the analytical results for sample(s) received by the laboratory on November 24, 2015.

The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report.

If you have any questions concerning this report, please feel free to contact me.

Sincerely, Christina Raschke christina.raschke@pacelabs.com Project Manager

Enclosures cc: Brad Compton, CRB Geological & Environmental Services Barbara Livieri, CRB Geological & Environmental Services

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc.

3610 Park Central Blvd N

Pompano Beach, FL 33064 954-582-4300

#=CP#

CERTIFICATIONS

Pace Project No.:

Project:

35218364

NPS 1244-04

Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074

Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc.

3610 Park Central Blvd N

Pompano Beach, FL 33064

#=SS#

SAMPLE SUMMARY

Pace Project No.:

Project:

35218364

NPS 1244-04

Lab ID Sample ID Matrix Date Collected Date Received

35218364001 SB-1 Solid 11/23/15 14:00 11/24/15 13:20

35218364002 SB-2 Solid 11/23/15 14:20 11/24/15 13:20

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc.

3610 Park Central Blvd N

Pompano Beach, FL 33064

#=SA#

SAMPLE ANALYTE COUNT

Pace Project No.:

Project:

35218364

NPS 1244-04

Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts

35218364001 SB-1 FL-PRO 3 PASI-OSMB

EPA 8270 21 PASI-OTWB

EPA 8260 39 PASI-OBCH

ASTM D2974-87 1 PASI-OMLO

35218364002 SB-2 FL-PRO 3 PASI-OSMB

EPA 8270 21 PASI-OTWB

EPA 8260 39 PASI-OBCH

ASTM D2974-87 1 PASI-OMLO

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc.

3610 Park Central Blvd N

Pompano Beach, FL 33064

#=HO#

SUMMARY OF DETECTION

Pace Project No.:

Project:

35218364

NPS 1244-04

Parameters AnalyzedResult Lab Sample ID

Report Limit QualifiersUnitsMethod Client Sample ID

35218364001 SB-1

Benzo(a)anthracene 0.043 I mg/kg 12/07/15 11:360.12EPA 8270 Benzo(a)pyrene 0.032 I mg/kg 12/07/15 11:360.12EPA 8270 Benzo(g,h,i)perylene 0.028 I mg/kg 12/07/15 11:360.12EPA 8270 Chrysene 0.034 I mg/kg 12/07/15 11:360.12EPA 8270 Fluoranthene 0.053 I mg/kg 12/07/15 11:360.12EPA 8270 Indeno(1,2,3-cd)pyrene 0.023 I mg/kg 12/07/15 11:360.12EPA 8270 Pyrene 0.044 I mg/kg 12/07/15 11:360.12EPA 8270 Percent Moisture 20.7 % 12/01/15 13:520.10ASTM D2974-87

35218364002 SB-2

Petroleum Range Organics 474 mg/kg 12/07/15 12:2214.5FL-PRO Benzo(a)anthracene 0.036 I mg/kg 12/07/15 11:580.14EPA 8270 Benzo(a)pyrene 0.025 I mg/kg 12/07/15 11:580.14EPA 8270 Benzo(g,h,i)perylene 0.023 I mg/kg 12/07/15 11:580.14EPA 8270 Chrysene 0.026 I mg/kg 12/07/15 11:580.14EPA 8270 Fluoranthene 0.034 I mg/kg 12/07/15 11:580.14EPA 8270 Pyrene 0.031 I mg/kg 12/07/15 11:580.14EPA 8270 Chloroform 0.0063 I mg/kg 12/03/15 16:000.0099EPA 8260 Percent Moisture 29.6 % 12/01/15 13:530.10ASTM D2974-87

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc.

3610 Park Central Blvd N

Pompano Beach, FL 33064

#=AR#

ANALYTICAL RESULTS

Pace Project No.:

Project:

35218364

NPS 1244-04

Sample: SB-1 Lab ID: 35218364001 Collected: 11/23/15 14:00 Received: 11/24/15 13:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.

Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL

Analytical Method: FL-PRO Preparation Method: EPA 3546FL-PRO Soil Microwave

Petroleum Range Organics 7.9 U mg/kg 12/07/15 12:2212/05/15 15:0012.4 7.9 1 Surrogates o-Terphenyl (S) 69 % 12/07/15 12:22 84-15-112/05/15 15:0062-109 1 N-Pentatriacontane (S) 78 % 12/07/15 12:22 630-07-0912/05/15 15:0042-159 1

Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Short List Microwave

Acenaphthene 0.018 U mg/kg 12/07/15 11:36 83-32-912/05/15 09:000.12 0.018 1 Acenaphthylene 0.013 U mg/kg 12/07/15 11:36 208-96-812/05/15 09:000.12 0.013 1 Anthracene 0.017 U mg/kg 12/07/15 11:36 120-12-712/05/15 09:000.12 0.017 1 Benzo(a)anthracene 0.043 I mg/kg 12/07/15 11:36 56-55-312/05/15 09:000.12 0.015 1 Benzo(a)pyrene 0.032 I mg/kg 12/07/15 11:36 50-32-812/05/15 09:000.12 0.014 1 Benzo(b)fluoranthene 0.093 U mg/kg 12/07/15 11:36 205-99-212/05/15 09:000.12 0.093 1 Benzo(g,h,i)perylene 0.028 I mg/kg 12/07/15 11:36 191-24-212/05/15 09:000.12 0.014 1 Benzo(k)fluoranthene 0.027 U mg/kg 12/07/15 11:36 207-08-912/05/15 09:000.12 0.027 1 Chrysene 0.034 I mg/kg 12/07/15 11:36 218-01-912/05/15 09:000.12 0.015 1 Dibenz(a,h)anthracene 0.019 U mg/kg 12/07/15 11:36 53-70-312/05/15 09:000.12 0.019 1 Fluoranthene 0.053 I mg/kg 12/07/15 11:36 206-44-012/05/15 09:000.12 0.017 1 Fluorene 0.016 U mg/kg 12/07/15 11:36 86-73-712/05/15 09:000.12 0.016 1 Indeno(1,2,3-cd)pyrene 0.023 I mg/kg 12/07/15 11:36 193-39-512/05/15 09:000.12 0.021 1 1-Methylnaphthalene 0.020 U mg/kg 12/07/15 11:36 90-12-012/05/15 09:000.12 0.020 1 2-Methylnaphthalene 0.016 U mg/kg 12/07/15 11:36 91-57-612/05/15 09:000.12 0.016 1 Naphthalene 0.040 U mg/kg 12/07/15 11:36 91-20-312/05/15 09:000.12 0.040 1 Phenanthrene 0.047 U mg/kg 12/07/15 11:36 85-01-812/05/15 09:000.12 0.047 1 Pyrene 0.044 I mg/kg 12/07/15 11:36 129-00-012/05/15 09:000.12 0.013 1 Surrogates Nitrobenzene-d5 (S) 47 % 12/07/15 11:36 4165-60-012/05/15 09:0010-110 1 2-Fluorobiphenyl (S) 53 % 12/07/15 11:36 321-60-812/05/15 09:0018-110 1 Terphenyl-d14 (S) 57 % 12/07/15 11:36 1718-51-012/05/15 09:0010-123 1

Analytical Method: EPA 82608260 MSV 5030 Low Level

1,1,1-Trichloroethane 0.0040 U mg/kg 12/03/15 15:35 71-55-60.0073 0.0040 1 1,1,2,2-Tetrachloroethane 0.0037 U mg/kg 12/03/15 15:35 79-34-50.0073 0.0037 1 1,1,2-Trichloroethane 0.0037 U mg/kg 12/03/15 15:35 79-00-50.0073 0.0037 1 1,1-Dichloroethane 0.0040 U mg/kg 12/03/15 15:35 75-34-30.0073 0.0040 1 1,1-Dichloroethene 0.0037 U mg/kg 12/03/15 15:35 75-35-40.0073 0.0037 1 1,2-Dichlorobenzene 0.0037 U mg/kg 12/03/15 15:35 95-50-10.0073 0.0037 1 1,2-Dichloroethane 0.0037 U mg/kg 12/03/15 15:35 107-06-20.0073 0.0037 1 1,2-Dichloropropane 0.0037 U mg/kg 12/03/15 15:35 78-87-50.0073 0.0037 1 1,3-Dichlorobenzene 0.0037 U mg/kg 12/03/15 15:35 541-73-10.0073 0.0037 1 1,4-Dichlorobenzene 0.0037 U mg/kg 12/03/15 15:35 106-46-70.0073 0.0037 1 Benzene 0.0037 U mg/kg 12/03/15 15:35 71-43-20.0073 0.0037 1 Bromodichloromethane 0.0037 U mg/kg 12/03/15 15:35 75-27-40.0073 0.0037 1 Bromoform 0.0037 U mg/kg 12/03/15 15:35 75-25-20.0073 0.0037 1 Bromomethane 0.0037 U mg/kg 12/03/15 15:35 74-83-90.0073 0.0037 1 Carbon tetrachloride 0.0037 U mg/kg 12/03/15 15:35 56-23-50.0073 0.0037 1

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 06:04 PM

Pace Analytical Services, Inc.

3610 Park Central Blvd N

Pompano Beach, FL 33064

Pace Project No.:

Project:

35218364

NPS 1244-04

Sample: SB-1 Lab ID: 35218364001 Collected: 11/23/15 14:00 Received: 11/24/15 13:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.

Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL

Analytical Method: EPA 82608260 MSV 5030 Low Level

Chlorobenzene 0.0037 U mg/kg 12/03/15 15:35 108-90-70.0073 0.0037 1 Chloroethane 0.0053 U mg/kg 12/03/15 15:35 75-00-30.0073 0.0053 1 Chloroform 0.0043 U mg/kg 12/03/15 15:35 67-66-30.0073 0.0043 1 Chloromethane 0.0041 U mg/kg 12/03/15 15:35 74-87-30.0073 0.0041 1 Dibromochloromethane 0.0037 U mg/kg 12/03/15 15:35 124-48-10.0073 0.0037 1 Dichlorodifluoromethane 0.0039 U mg/kg 12/03/15 15:35 75-71-8 L30.0073 0.0039 1 Ethylbenzene 0.0041 U mg/kg 12/03/15 15:35 100-41-40.0073 0.0041 1 Methyl-tert-butyl ether 0.0037 U mg/kg 12/03/15 15:35 1634-04-40.0073 0.0037 1 Methylene Chloride 0.0037 U mg/kg 12/03/15 15:35 75-09-20.0073 0.0037 1 Tetrachloroethene 0.0037 U mg/kg 12/03/15 15:35 127-18-40.0073 0.0037 1 Toluene 0.0039 U mg/kg 12/03/15 15:35 108-88-30.0073 0.0039 1 Trichloroethene 0.0041 U mg/kg 12/03/15 15:35 79-01-60.0073 0.0041 1 Trichlorofluoromethane 0.0040 U mg/kg 12/03/15 15:35 75-69-40.0073 0.0040 1 Vinyl chloride 0.0039 U mg/kg 12/03/15 15:35 75-01-40.0073 0.0039 1 Xylene (Total) 0.0075 U mg/kg 12/03/15 15:35 1330-20-70.022 0.0075 1 cis-1,2-Dichloroethene 0.0037 U mg/kg 12/03/15 15:35 156-59-20.0073 0.0037 1 cis-1,3-Dichloropropene 0.0037 U mg/kg 12/03/15 15:35 10061-01-50.0073 0.0037 1 m&p-Xylene 0.0075 U mg/kg 12/03/15 15:35 179601-23-10.015 0.0075 1 o-Xylene 0.0038 U mg/kg 12/03/15 15:35 95-47-60.0073 0.0038 1 trans-1,2-Dichloroethene 0.0045 U mg/kg 12/03/15 15:35 156-60-50.0073 0.0045 1 trans-1,3-Dichloropropene 0.0037 U mg/kg 12/03/15 15:35 10061-02-60.0073 0.0037 1 Surrogates 4-Bromofluorobenzene (S) 93 % 12/03/15 15:35 460-00-455-148 1 1,2-Dichloroethane-d4 (S) 104 % 12/03/15 15:35 17060-07-080-131 1 Toluene-d8 (S) 97 % 12/03/15 15:35 2037-26-584-117 1

Analytical Method: ASTM D2974-87Percent Moisture

Percent Moisture 20.7 % 12/01/15 13:520.10 0.10 1

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 06:04 PM

Pace Analytical Services, Inc.

3610 Park Central Blvd N

Pompano Beach, FL 33064

Pace Project No.:

Project:

35218364

NPS 1244-04

Sample: SB-2 Lab ID: 35218364002 Collected: 11/23/15 14:20 Received: 11/24/15 13:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.

Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL

Analytical Method: FL-PRO Preparation Method: EPA 3546FL-PRO Soil Microwave

Petroleum Range Organics 474 mg/kg 12/07/15 12:2212/05/15 15:0014.5 9.2 1 Surrogates o-Terphenyl (S) 65 % 12/07/15 12:22 84-15-112/05/15 15:0062-109 1 N-Pentatriacontane (S) 58 % 12/07/15 12:22 630-07-0912/05/15 15:0042-159 1

Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Short List Microwave

Acenaphthene 0.020 U mg/kg 12/07/15 11:58 83-32-912/05/15 09:000.14 0.020 1 Acenaphthylene 0.015 U mg/kg 12/07/15 11:58 208-96-812/05/15 09:000.14 0.015 1 Anthracene 0.019 U mg/kg 12/07/15 11:58 120-12-712/05/15 09:000.14 0.019 1 Benzo(a)anthracene 0.036 I mg/kg 12/07/15 11:58 56-55-312/05/15 09:000.14 0.017 1 Benzo(a)pyrene 0.025 I mg/kg 12/07/15 11:58 50-32-812/05/15 09:000.14 0.016 1 Benzo(b)fluoranthene 0.10 U mg/kg 12/07/15 11:58 205-99-212/05/15 09:000.14 0.10 1 Benzo(g,h,i)perylene 0.023 I mg/kg 12/07/15 11:58 191-24-212/05/15 09:000.14 0.016 1 Benzo(k)fluoranthene 0.030 U mg/kg 12/07/15 11:58 207-08-912/05/15 09:000.14 0.030 1 Chrysene 0.026 I mg/kg 12/07/15 11:58 218-01-912/05/15 09:000.14 0.017 1 Dibenz(a,h)anthracene 0.021 U mg/kg 12/07/15 11:58 53-70-312/05/15 09:000.14 0.021 1 Fluoranthene 0.034 I mg/kg 12/07/15 11:58 206-44-012/05/15 09:000.14 0.019 1 Fluorene 0.018 U mg/kg 12/07/15 11:58 86-73-712/05/15 09:000.14 0.018 1 Indeno(1,2,3-cd)pyrene 0.024 U mg/kg 12/07/15 11:58 193-39-512/05/15 09:000.14 0.024 1 1-Methylnaphthalene 0.023 U mg/kg 12/07/15 11:58 90-12-012/05/15 09:000.14 0.023 1 2-Methylnaphthalene 0.018 U mg/kg 12/07/15 11:58 91-57-612/05/15 09:000.14 0.018 1 Naphthalene 0.045 U mg/kg 12/07/15 11:58 91-20-312/05/15 09:000.14 0.045 1 Phenanthrene 0.052 U mg/kg 12/07/15 11:58 85-01-812/05/15 09:000.14 0.052 1 Pyrene 0.031 I mg/kg 12/07/15 11:58 129-00-012/05/15 09:000.14 0.015 1 Surrogates Nitrobenzene-d5 (S) 60 % 12/07/15 11:58 4165-60-012/05/15 09:0010-110 1 2-Fluorobiphenyl (S) 63 % 12/07/15 11:58 321-60-812/05/15 09:0018-110 1 Terphenyl-d14 (S) 74 % 12/07/15 11:58 1718-51-012/05/15 09:0010-123 1

Analytical Method: EPA 82608260 MSV 5030 Low Level

1,1,1-Trichloroethane 0.0054 U mg/kg 12/03/15 16:00 71-55-60.0099 0.0054 1 1,1,2,2-Tetrachloroethane 0.0050 U mg/kg 12/03/15 16:00 79-34-50.0099 0.0050 1 1,1,2-Trichloroethane 0.0050 U mg/kg 12/03/15 16:00 79-00-50.0099 0.0050 1 1,1-Dichloroethane 0.0054 U mg/kg 12/03/15 16:00 75-34-30.0099 0.0054 1 1,1-Dichloroethene 0.0050 U mg/kg 12/03/15 16:00 75-35-40.0099 0.0050 1 1,2-Dichlorobenzene 0.0050 U mg/kg 12/03/15 16:00 95-50-10.0099 0.0050 1 1,2-Dichloroethane 0.0050 U mg/kg 12/03/15 16:00 107-06-20.0099 0.0050 1 1,2-Dichloropropane 0.0050 U mg/kg 12/03/15 16:00 78-87-50.0099 0.0050 1 1,3-Dichlorobenzene 0.0050 U mg/kg 12/03/15 16:00 541-73-10.0099 0.0050 1 1,4-Dichlorobenzene 0.0050 U mg/kg 12/03/15 16:00 106-46-70.0099 0.0050 1 Benzene 0.0051 U mg/kg 12/03/15 16:00 71-43-20.0099 0.0051 1 Bromodichloromethane 0.0050 U mg/kg 12/03/15 16:00 75-27-40.0099 0.0050 1 Bromoform 0.0050 U mg/kg 12/03/15 16:00 75-25-20.0099 0.0050 1 Bromomethane 0.0050 U mg/kg 12/03/15 16:00 74-83-90.0099 0.0050 1 Carbon tetrachloride 0.0050 U mg/kg 12/03/15 16:00 56-23-50.0099 0.0050 1

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 06:04 PM

Pace Analytical Services, Inc.

3610 Park Central Blvd N

Pompano Beach, FL 33064

Pace Project No.:

Project:

35218364

NPS 1244-04

Sample: SB-2 Lab ID: 35218364002 Collected: 11/23/15 14:20 Received: 11/24/15 13:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.

Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL

Analytical Method: EPA 82608260 MSV 5030 Low Level

Chlorobenzene 0.0050 U mg/kg 12/03/15 16:00 108-90-70.0099 0.0050 1 Chloroethane 0.0071 U mg/kg 12/03/15 16:00 75-00-30.0099 0.0071 1 Chloroform 0.0063 I mg/kg 12/03/15 16:00 67-66-30.0099 0.0059 1 Chloromethane 0.0056 U mg/kg 12/03/15 16:00 74-87-30.0099 0.0056 1 Dibromochloromethane 0.0050 U mg/kg 12/03/15 16:00 124-48-10.0099 0.0050 1 Dichlorodifluoromethane 0.0053 U mg/kg 12/03/15 16:00 75-71-8 L30.0099 0.0053 1 Ethylbenzene 0.0056 U mg/kg 12/03/15 16:00 100-41-40.0099 0.0056 1 Methyl-tert-butyl ether 0.0050 U mg/kg 12/03/15 16:00 1634-04-40.0099 0.0050 1 Methylene Chloride 0.0050 U mg/kg 12/03/15 16:00 75-09-20.0099 0.0050 1 Tetrachloroethene 0.0050 U mg/kg 12/03/15 16:00 127-18-40.0099 0.0050 1 Toluene 0.0054 U mg/kg 12/03/15 16:00 108-88-30.0099 0.0054 1 Trichloroethene 0.0056 U mg/kg 12/03/15 16:00 79-01-60.0099 0.0056 1 Trichlorofluoromethane 0.0054 U mg/kg 12/03/15 16:00 75-69-40.0099 0.0054 1 Vinyl chloride 0.0053 U mg/kg 12/03/15 16:00 75-01-40.0099 0.0053 1 Xylene (Total) 0.010 U mg/kg 12/03/15 16:00 1330-20-70.030 0.010 1 cis-1,2-Dichloroethene 0.0050 U mg/kg 12/03/15 16:00 156-59-20.0099 0.0050 1 cis-1,3-Dichloropropene 0.0050 U mg/kg 12/03/15 16:00 10061-01-50.0099 0.0050 1 m&p-Xylene 0.010 U mg/kg 12/03/15 16:00 179601-23-10.020 0.010 1 o-Xylene 0.0051 U mg/kg 12/03/15 16:00 95-47-60.0099 0.0051 1 trans-1,2-Dichloroethene 0.0061 U mg/kg 12/03/15 16:00 156-60-50.0099 0.0061 1 trans-1,3-Dichloropropene 0.0050 U mg/kg 12/03/15 16:00 10061-02-60.0099 0.0050 1 Surrogates 4-Bromofluorobenzene (S) 73 % 12/03/15 16:00 460-00-455-148 1 1,2-Dichloroethane-d4 (S) 108 % 12/03/15 16:00 17060-07-080-131 1 Toluene-d8 (S) 89 % 12/03/15 16:00 2037-26-584-117 1

Analytical Method: ASTM D2974-87Percent Moisture

Percent Moisture 29.6 % 12/01/15 13:530.10 0.10 1

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 06:04 PM

Pace Analytical Services, Inc.

3610 Park Central Blvd N

Pompano Beach, FL 33064

#=QC#

QUALITY CONTROL DATA

Pace Project No.:

Project:

35218364

NPS 1244-04

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

MSV/16838

EPA 8260

EPA 8260

8260 MSV 5030 Low

Associated Lab Samples: 35218364001, 35218364002

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: 1408972

Associated Lab Samples: 35218364001, 35218364002

Matrix: Solid

AnalyzedMDL

1,1,1-Trichloroethane mg/kg 0.0027 U 0.0050 12/03/15 11:090.0027 1,1,2,2-Tetrachloroethane mg/kg 0.0025 U 0.0050 12/03/15 11:090.0025 1,1,2-Trichloroethane mg/kg 0.0025 U 0.0050 12/03/15 11:090.0025 1,1-Dichloroethane mg/kg 0.0027 U 0.0050 12/03/15 11:090.0027 1,1-Dichloroethene mg/kg 0.0025 U 0.0050 12/03/15 11:090.0025 1,2-Dichlorobenzene mg/kg 0.0025 U 0.0050 12/03/15 11:090.0025 1,2-Dichloroethane mg/kg 0.0025 U 0.0050 12/03/15 11:090.0025 1,2-Dichloropropane mg/kg 0.0025 U 0.0050 12/03/15 11:090.0025 1,3-Dichlorobenzene mg/kg 0.0025 U 0.0050 12/03/15 11:090.0025 1,4-Dichlorobenzene mg/kg 0.0025 U 0.0050 12/03/15 11:090.0025 Benzene mg/kg 0.0025 U 0.0050 12/03/15 11:090.0025 Bromodichloromethane mg/kg 0.0025 U 0.0050 12/03/15 11:090.0025 Bromoform mg/kg 0.0025 U 0.0050 12/03/15 11:090.0025 Bromomethane mg/kg 0.0025 U 0.0050 12/03/15 11:090.0025 Carbon tetrachloride mg/kg 0.0025 U 0.0050 12/03/15 11:090.0025 Chlorobenzene mg/kg 0.0025 U 0.0050 12/03/15 11:090.0025 Chloroethane mg/kg 0.0036 U 0.0050 12/03/15 11:090.0036 Chloroform mg/kg 0.0029 U 0.0050 12/03/15 11:090.0029 Chloromethane mg/kg 0.0028 U 0.0050 12/03/15 11:090.0028 cis-1,2-Dichloroethene mg/kg 0.0025 U 0.0050 12/03/15 11:090.0025 cis-1,3-Dichloropropene mg/kg 0.0025 U 0.0050 12/03/15 11:090.0025 Dibromochloromethane mg/kg 0.0025 U 0.0050 12/03/15 11:090.0025 Dichlorodifluoromethane mg/kg 0.0026 U 0.0050 12/03/15 11:090.0026 Ethylbenzene mg/kg 0.0028 U 0.0050 12/03/15 11:090.0028 m&p-Xylene mg/kg 0.0051 U 0.0099 12/03/15 11:090.0051 Methyl-tert-butyl ether mg/kg 0.0025 U 0.0050 12/03/15 11:090.0025 Methylene Chloride mg/kg 0.0025 U 0.0050 12/03/15 11:090.0025 o-Xylene mg/kg 0.0026 U 0.0050 12/03/15 11:090.0026 Tetrachloroethene mg/kg 0.0025 U 0.0050 12/03/15 11:090.0025 Toluene mg/kg 0.0027 U 0.0050 12/03/15 11:090.0027 trans-1,2-Dichloroethene mg/kg 0.0030 U 0.0050 12/03/15 11:090.0030 trans-1,3-Dichloropropene mg/kg 0.0025 U 0.0050 12/03/15 11:090.0025 Trichloroethene mg/kg 0.0028 U 0.0050 12/03/15 11:090.0028 Trichlorofluoromethane mg/kg 0.0027 U 0.0050 12/03/15 11:090.0027 Vinyl chloride mg/kg 0.0027 U 0.0050 12/03/15 11:090.0027 Xylene (Total) mg/kg 0.0051 U 0.015 12/03/15 11:090.0051 1,2-Dichloroethane-d4 (S) % 100 80-131 12/03/15 11:09 4-Bromofluorobenzene (S) % 97 55-148 12/03/15 11:09 Toluene-d8 (S) % 99 84-117 12/03/15 11:09

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 06:04 PM

Pace Analytical Services, Inc.

3610 Park Central Blvd N

Pompano Beach, FL 33064

Pace Project No.:

Project:

35218364

NPS 1244-04

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

1408973LABORATORY CONTROL SAMPLE:

LCSSpike

1,1,1-Trichloroethane mg/kg 0.021.02 104 68-130 1,1,2,2-Tetrachloroethane mg/kg 0.020.02 101 70-130 1,1,2-Trichloroethane mg/kg 0.020.02 102 70-130 1,1-Dichloroethane mg/kg 0.019.02 98 69-130 1,1-Dichloroethene mg/kg 0.019.02 97 67-130 1,2-Dichlorobenzene mg/kg 0.021.02 103 70-130 1,2-Dichloroethane mg/kg 0.020.02 101 70-130 1,2-Dichloropropane mg/kg 0.020.02 103 70-130 1,3-Dichlorobenzene mg/kg 0.021.02 105 70-130 1,4-Dichlorobenzene mg/kg 0.021.02 104 70-130 Benzene mg/kg 0.021.02 104 70-130 Bromodichloromethane mg/kg 0.020.02 100 70-130 Bromoform mg/kg 0.019.02 96 70-130 Bromomethane mg/kg 0.024.02 119 42-156 Carbon tetrachloride mg/kg 0.021.02 106 65-132 Chlorobenzene mg/kg 0.020.02 102 70-130 Chloroethane mg/kg 0.026.02 133 56-146 Chloroform mg/kg 0.021.02 104 69-130 Chloromethane mg/kg 0.024.02 122 50-145 cis-1,2-Dichloroethene mg/kg 0.021.02 104 70-130 cis-1,3-Dichloropropene mg/kg 0.021.02 104 70-130 Dibromochloromethane mg/kg 0.020.02 102 70-130 Dichlorodifluoromethane mg/kg 0.028 J(L0).02 140 58-138 Ethylbenzene mg/kg 0.020.02 103 70-130 m&p-Xylene mg/kg 0.042.04 105 70-130 Methyl-tert-butyl ether mg/kg 0.017.02 83 70-130 Methylene Chloride mg/kg 0.016.02 80 40-159 o-Xylene mg/kg 0.021.02 105 70-130 Tetrachloroethene mg/kg 0.020.02 99 63-130 Toluene mg/kg 0.020.02 103 70-130 trans-1,2-Dichloroethene mg/kg 0.018.02 92 70-130 trans-1,3-Dichloropropene mg/kg 0.021.02 105 70-130 Trichloroethene mg/kg 0.021.02 105 69-130 Trichlorofluoromethane mg/kg 0.025.02 124 67-130 Vinyl chloride mg/kg 0.024.02 122 67-130 Xylene (Total) mg/kg 0.063.06 105 70-130 1,2-Dichloroethane-d4 (S) % 98 80-131 4-Bromofluorobenzene (S) % 98 55-148 Toluene-d8 (S) % 100 84-117

Parameter Units

MS

Result % Rec Limits Qualifiers% RecConc.

1410415MATRIX SPIKE SAMPLE:

MSSpike

Result 35218422015

1,1,1-Trichloroethane mg/kg 0.020.04 50 42-1310.0032 U 1,1,2,2-Tetrachloroethane mg/kg 0.035.04 89 50-1300.0029 U

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 06:04 PM

Pace Analytical Services, Inc.

3610 Park Central Blvd N

Pompano Beach, FL 33064

Pace Project No.:

Project:

35218364

NPS 1244-04

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

Parameter Units

MS

Result % Rec Limits Qualifiers% RecConc.

1410415MATRIX SPIKE SAMPLE:

MSSpike

Result 35218422015

1,1,2-Trichloroethane mg/kg 0.035.04 88 59-1300.0029 U 1,1-Dichloroethane mg/kg 0.031.04 78 50-1300.0032 U 1,1-Dichloroethene mg/kg 0.023.04 59 51-1300.0029 U 1,2-Dichlorobenzene mg/kg 0.023.04 59 20-1340.0029 U 1,2-Dichloroethane mg/kg 0.028.04 69 57-1300.0029 U 1,2-Dichloropropane mg/kg 0.028.04 69 52-1300.0029 U 1,3-Dichlorobenzene mg/kg 0.024.04 61 20-1330.0029 U 1,4-Dichlorobenzene mg/kg 0.024.04 59 20-1340.0029 U Benzene mg/kg 0.023.04 57 24-1410.0030 U Bromodichloromethane mg/kg 0.021.04 52 20-1550.0029 U Bromoform mg/kg 0.022.04 56 30-1300.0029 U Bromomethane mg/kg 0.022.04 54 22-1520.0029 U Carbon tetrachloride mg/kg 0.015.04 39 23-1410.0029 U Chlorobenzene mg/kg 0.023.04 57 34-1300.0029 U Chloroethane mg/kg 0.023.04 59 43-1460.0042 U Chloroform mg/kg 0.024.04 59 42-1320.0034 U Chloromethane mg/kg 0.032.04 81 31-1440.0033 U cis-1,2-Dichloroethene mg/kg 0.024.04 60 45-1310.0029 U cis-1,3-Dichloropropene mg/kg 0.023.04 58 33-1320.0029 U Dibromochloromethane mg/kg 0.024.04 60 20-1510.0029 U Dichlorodifluoromethane mg/kg 0.026.04 64 39-1300.0031 U Ethylbenzene mg/kg 0.023.04 57 30-1300.0033 U m&p-Xylene mg/kg 0.045.079 56 27-1500.0060 U Methyl-tert-butyl ether mg/kg 0.037.04 94 31-1560.0029 U Methylene Chloride mg/kg 0.031.04 79 20-1500.0029 U o-Xylene mg/kg 0.024.04 59 27-1500.0030 U Tetrachloroethene mg/kg 0.030.04 76 23-1440.0029 U Toluene mg/kg 0.023.04 55 24-1370.0031 U trans-1,2-Dichloroethene mg/kg 0.021.04 54 50-1300.0036 U trans-1,3-Dichloropropene mg/kg 0.028.04 71 33-1300.0029 U Trichloroethene mg/kg 0.021.04 54 42-1300.0033 U Trichlorofluoromethane mg/kg 0.026.04 65 40-1300.0032 U Vinyl chloride mg/kg 0.030.04 75 47-1300.0031 U Xylene (Total) mg/kg 0.068.12 57 26-1300.0060 U 1,2-Dichloroethane-d4 (S) % 95 80-131 4-Bromofluorobenzene (S) % 86 55-148 Toluene-d8 (S) % 94 84-117

Parameter Units Dup

Result Max RPD QualifiersRPDResult

35218422016

1410416SAMPLE DUPLICATE:

1,1,1-Trichloroethane mg/kg 0.0030 U 400.0028 U 1,1,2,2-Tetrachloroethane mg/kg 0.0028 U 400.0026 U 1,1,2-Trichloroethane mg/kg 0.0028 U 400.0026 U 1,1-Dichloroethane mg/kg 0.0030 U 400.0028 U

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 06:04 PM

Pace Analytical Services, Inc.

3610 Park Central Blvd N

Pompano Beach, FL 33064

Pace Project No.:

Project:

35218364

NPS 1244-04

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

Parameter Units Dup

Result Max RPD QualifiersRPDResult

35218422016

1410416SAMPLE DUPLICATE:

1,1-Dichloroethene mg/kg 0.0028 U 400.0026 U 1,2-Dichlorobenzene mg/kg 0.0028 U 400.0026 U 1,2-Dichloroethane mg/kg 0.0028 U 400.0026 U 1,2-Dichloropropane mg/kg 0.0028 U 400.0026 U 1,3-Dichlorobenzene mg/kg 0.0028 U 400.0026 U 1,4-Dichlorobenzene mg/kg 0.0028 U 400.0026 U Benzene mg/kg 0.0028 U 400.0026 U Bromodichloromethane mg/kg 0.0028 U 400.0026 U Bromoform mg/kg 0.0028 U 400.0026 U Bromomethane mg/kg 0.0028 U 400.0026 U Carbon tetrachloride mg/kg 0.0028 U 400.0026 U Chlorobenzene mg/kg 0.0028 U 400.0026 U Chloroethane mg/kg 0.0040 U 400.0037 U Chloroform mg/kg 0.0033 U 400.0031 U Chloromethane mg/kg 0.0031 U 400.0029 U cis-1,2-Dichloroethene mg/kg 0.0028 U 400.0026 U cis-1,3-Dichloropropene mg/kg 0.0028 U 400.0026 U Dibromochloromethane mg/kg 0.0028 U 400.0026 U Dichlorodifluoromethane mg/kg 0.0030 U 400.0028 U Ethylbenzene mg/kg 0.0031 U 400.0029 U m&p-Xylene mg/kg 0.0057 U 400.0053 U Methyl-tert-butyl ether mg/kg 0.0028 U 400.0026 U Methylene Chloride mg/kg 0.0028 U 400.0026 U o-Xylene mg/kg 0.0029 U 400.0027 U Tetrachloroethene mg/kg 0.0028 U 400.0026 U Toluene mg/kg 0.0030 U 400.0028 U trans-1,2-Dichloroethene mg/kg 0.0034 U 400.0032 U trans-1,3-Dichloropropene mg/kg 0.0028 U 400.0026 U Trichloroethene mg/kg 0.0031 U 400.0029 U Trichlorofluoromethane mg/kg 0.0030 U 400.0028 U Vinyl chloride mg/kg 0.0030 U 400.0028 U Xylene (Total) mg/kg 0.0057 U 400.0053 U 1,2-Dichloroethane-d4 (S) % 89 5 40100 4-Bromofluorobenzene (S) % 93 9 4091 Toluene-d8 (S) % 94 6 4094

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 06:04 PM

Pace Analytical Services, Inc.

3610 Park Central Blvd N

Pompano Beach, FL 33064

Pace Project No.:

Project:

35218364

NPS 1244-04

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

OEXT/25587

EPA 3546

EPA 8270

8270 Solid MSSV Microwave Short Spike

Associated Lab Samples: 35218364001, 35218364002

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: 1411160

Associated Lab Samples: 35218364001, 35218364002

Matrix: Solid

AnalyzedMDL

1-Methylnaphthalene mg/kg 0.0055 U 0.033 12/07/15 10:280.0055 2-Methylnaphthalene mg/kg 0.0044 U 0.033 12/07/15 10:280.0044 Acenaphthene mg/kg 0.0049 U 0.033 12/07/15 10:280.0049 Acenaphthylene mg/kg 0.0035 U 0.033 12/07/15 10:280.0035 Anthracene mg/kg 0.0045 U 0.033 12/07/15 10:280.0045 Benzo(a)anthracene mg/kg 0.0040 U 0.033 12/07/15 10:280.0040 Benzo(a)pyrene mg/kg 0.0039 U 0.033 12/07/15 10:280.0039 Benzo(b)fluoranthene mg/kg 0.025 U 0.033 12/07/15 10:280.025 Benzo(g,h,i)perylene mg/kg 0.0038 U 0.033 12/07/15 10:280.0038 Benzo(k)fluoranthene mg/kg 0.0072 U 0.033 12/07/15 10:280.0072 Chrysene mg/kg 0.0040 U 0.033 12/07/15 10:280.0040 Dibenz(a,h)anthracene mg/kg 0.0051 U 0.033 12/07/15 10:280.0051 Fluoranthene mg/kg 0.0045 U 0.033 12/07/15 10:280.0045 Fluorene mg/kg 0.0043 U 0.033 12/07/15 10:280.0043 Indeno(1,2,3-cd)pyrene mg/kg 0.0058 U 0.033 12/07/15 10:280.0058 Naphthalene mg/kg 0.011 U 0.033 12/07/15 10:280.011 Phenanthrene mg/kg 0.012 U 0.033 12/07/15 10:280.012 Pyrene mg/kg 0.0035 U 0.033 12/07/15 10:280.0035 2-Fluorobiphenyl (S) % 75 18-110 12/07/15 10:28 Nitrobenzene-d5 (S) % 83 10-110 12/07/15 10:28 Terphenyl-d14 (S) % 90 10-123 12/07/15 10:28

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

1411161LABORATORY CONTROL SAMPLE:

LCSSpike

1-Methylnaphthalene mg/kg 1.41.7 81 49-130 2-Methylnaphthalene mg/kg 1.21.7 75 48-130 Acenaphthene mg/kg 1.11.7 68 47-145 Acenaphthylene mg/kg 1.21.7 73 33-145 Anthracene mg/kg 1.31.7 75 27-133 Benzo(a)anthracene mg/kg 1.31.7 77 33-143 Benzo(a)pyrene mg/kg 1.31.7 78 17-163 Benzo(b)fluoranthene mg/kg 1.21.7 74 24-159 Benzo(g,h,i)perylene mg/kg 1.11.7 65 10-219 Benzo(k)fluoranthene mg/kg 1.61.7 94 11-162 Chrysene mg/kg 1.31.7 79 17-168 Dibenz(a,h)anthracene mg/kg 1.21.7 72 10-227 Fluoranthene mg/kg 1.31.7 80 26-137 Fluorene mg/kg 1.31.7 76 59-121 Indeno(1,2,3-cd)pyrene mg/kg 1.21.7 71 10-171

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 06:04 PM

Pace Analytical Services, Inc.

3610 Park Central Blvd N

Pompano Beach, FL 33064

Pace Project No.:

Project:

35218364

NPS 1244-04

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

1411161LABORATORY CONTROL SAMPLE:

LCSSpike

Naphthalene mg/kg 1.21.7 72 21-133 Phenanthrene mg/kg 1.31.7 76 54-120 Pyrene mg/kg 1.31.7 76 56-130 2-Fluorobiphenyl (S) % 78 18-110 Nitrobenzene-d5 (S) % 81 10-110 Terphenyl-d14 (S) % 82 10-123

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 06:04 PM

Pace Analytical Services, Inc.

3610 Park Central Blvd N

Pompano Beach, FL 33064

Pace Project No.:

Project:

35218364

NPS 1244-04

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

OEXT/25589

EPA 3546

FL-PRO

FL-PRO Soil

Associated Lab Samples: 35218364001, 35218364002

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: 1411188

Associated Lab Samples: 35218364001, 35218364002

Matrix: Solid

AnalyzedMDL

Petroleum Range Organics mg/kg 2.5 U 4.0 12/07/15 11:512.5 N-Pentatriacontane (S) % 73 42-159 12/07/15 11:51 o-Terphenyl (S) % 63 62-109 12/07/15 11:51

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

1411189LABORATORY CONTROL SAMPLE:

LCSSpike

Petroleum Range Organics mg/kg 163198 82 63-153 N-Pentatriacontane (S) % 92 42-159 o-Terphenyl (S) % 92 62-109

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 06:04 PM

Pace Analytical Services, Inc.

3610 Park Central Blvd N

Pompano Beach, FL 33064

Pace Project No.:

Project:

35218364

NPS 1244-04

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

PMST/4106

ASTM D2974-87

ASTM D2974-87

Dry Weight/Percent Moisture

Associated Lab Samples: 35218364001, 35218364002

Parameter Units Dup

Result Max RPD QualifiersRPDResult

35218063001

1406543SAMPLE DUPLICATE:

Percent Moisture % 9.2 9 108.4

Parameter Units Dup

Result Max RPD QualifiersRPDResult

35218068007

1406544SAMPLE DUPLICATE:

Percent Moisture % 8.0 J(D6)13 107.0

Parameter Units Dup

Result Max RPD QualifiersRPDResult

35218355001

1406545SAMPLE DUPLICATE:

Percent Moisture % 3.4 7 103.2

Parameter Units Dup

Result Max RPD QualifiersRPDResult

35218355010

1406546SAMPLE DUPLICATE:

Percent Moisture % 22.1 3 1021.5

Parameter Units Dup

Result Max RPD QualifiersRPDResult

35218422001

1406547SAMPLE DUPLICATE:

Percent Moisture % 17.4 J(D6)15 1020.3

Parameter Units Dup

Result Max RPD QualifiersRPDResult

35218422013

1406548SAMPLE DUPLICATE:

Percent Moisture % 8.5 3 108.8

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 06:04 PM

Pace Analytical Services, Inc.

3610 Park Central Blvd N

Pompano Beach, FL 33064

#=QL#

QUALIFIERS

Pace Project No.:

Project:

35218364

NPS 1244-04

DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.

ND - Not Detected at or above adjusted reporting limit.

MDL - Adjusted Method Detection Limit.

PQL - Practical Quantitation Limit.

RL - Reporting Limit.

S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration.

Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.

LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable.

SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected.

N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration.

Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.

TNI - The NELAC Institute.

LABORATORIES

Pace Analytical Services - Ormond BeachPASI-O

ANALYTE QUALIFIERS

The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. I Compound was analyzed for but not detected. U Estimated Value. The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.

J(D6)

Estimated Value. Analyte recovery in the laboratory control sample (LCS) was outside QC limits.J(L0) Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in associated samples. Results unaffected by high bias.

L3

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 06:04 PM

Pace Analytical Services, Inc.

3610 Park Central Blvd N

Pompano Beach, FL 33064

#=CR#

QUALITY CONTROL DATA CROSS REFERENCE TABLE

Pace Project No.:

Project:

35218364

NPS 1244-04

Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch

35218364001 OEXT/25589 GCSV/16642SB-1 EPA 3546 FL-PRO

35218364002 OEXT/25589 GCSV/16642SB-2 EPA 3546 FL-PRO

35218364001 OEXT/25587 MSSV/8917SB-1 EPA 3546 EPA 8270

35218364002 OEXT/25587 MSSV/8917SB-2 EPA 3546 EPA 8270

35218364001 MSV/16838SB-1 EPA 8260

35218364002 MSV/16838SB-2 EPA 8260

35218364001 PMST/4106SB-1 ASTM D2974-87

35218364002 PMST/4106SB-2 ASTM D2974-87

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 12/07/2015 06:04 PM

Pace Analytical Services, Inc.

3610 Park Central Blvd N

Pompano Beach, FL 33064

P age 20 of 21

ATTACHMENT B

GROUNDWATER SAMPLING LOGS

DEP Form FD 9000-24: GROUNDWATER SAMPLING LOG

SITE

NAME: Coopertown; NPS 1244-04

SITE

LOCATION: 22700 SW 8TH STREET MIAMI, FL

WELL NO: MW-A SAMPLE ID: MW-A DATE: 11/25/15

PURGING DATA

WELL

DIAMETER (inches): 2

TUBING

DIAMETER (inches): 0.25

WELL SCREEN INTERVAL

DEPTH: 13.06 feet to 3.06 feet

STATIC DEPTH

TO WATER (feet): 4.39

PURGE PUMP TYPE

OR BAILER: Peristaltic

WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH – STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable)

= ( 13.06 feet – 4.39 feet) X 0.16 gallons/foot = 1.4 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable)

= gallons + ( gallons/foot X feet) + gallons = gallons

INITIAL PUMP OR TUBING

DEPTH IN WELL (feet): 5.0

FINAL PUMP OR TUBING

DEPTH IN WELL (feet): 5.0

PURGING

INITIATED AT: 901

PURGING

ENDED AT: 906

TOTAL VOLUME

PURGED (gallons): 1.4

TIME

VOLUME

PURGED

(gallons)

CUMUL.

VOLUME

PURGED

(gallons)

PURGE

RATE

(gpm)

DEPTH

TO

WATER

(feet) pH (standard units)

TEMP.

(OC)

COND.

(S/cm)

DISSOLVED

OXYGEN

(% saturation)

TURBIDITY

(NTUs)

COLOR

(describe)

ODOR

(describe)

906 1.4 1.4 0.28 4.39 7.92 25.2 1201 28.8 139.9 Cloudy None

WELL CAPACITY (Gallons Per Foot): 0.75” = 0.02; 1” = 0.04; 1.25” = 0.06; 2” = 0.16; 3” = 0.37; 4” = 0.65; 5” = 1.02; 6” = 1.47; 12” = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify)

SAMPLING DATA

SAMPLED BY (PRINT) / AFFILIATION:

David Bobbitt/CRB Geological

SAMPLER(S) SIGNATURE(S): SAMPLING

INITIATED AT: 911

SAMPLING

ENDED AT: 916

PUMP OR TUBING

DEPTH IN WELL (feet): 5.0

TUBING

MATERIAL CODE: S, HDPE

FIELD-FILTERED: Y N FILTER SIZE: 0.45 m Filtration Equipment Type:

FIELD DECONTAMINATION: PUMP Y N TUBING Y N (replaced) DUPLICATE: Y N SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION (including wet ice) INTENDED

ANALYSIS AND/OR

METHOD

SAMPLING

EQUIPMENT

CODE

SAMPLE PUMP

FLOW RATE

(mL per minute)SAMPLE

ID CODE

CONTAINERS

MATERIAL

CODE VOLUME PRESERVATIVE

USED

TOTAL VOL

ADDED IN FIELD (mL)

FINAL

pH

MW-A 1 AG 1 L H2SO4 N/A <2 TRPH APP 1060

MW-A 1 PE 250 mL HNO3 N/A <2 As APP 1060 MW-A 3 CG 40 mL HCL N/A <2 VOA/VOH RFPP 100

REMARKS: Slow recharge rate. AFTER FIRST VOLUME WELL BECAME DRY. 5 MINUTES LATER SAMPLES COLECTED. INLINE FIELD FILTER USED FOR VOA/VOH.

~3’ RISER

MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene;

S = Silicone; T = Teflon; O = Other (Specify)

SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump;

RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Specify)

NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C.

2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 oC Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2);

optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater)

62-160.800 F.A.C. Revision Date: March 1, 2014

DEP Form FD 9000-24: GROUNDWATER SAMPLING LOG

SITE

NAME: Coopertown; NPS 1244-04

SITE

LOCATION: 22700 SW 8TH STREET MIAMI, FL

WELL NO: MW-B SAMPLE ID: MW-B DATE: 11/25/15

PURGING DATA

WELL

DIAMETER (inches): 1

TUBING

DIAMETER (inches): 0.25

WELL SCREEN INTERVAL

DEPTH: 0.00 feet to 9.31 feet

STATIC DEPTH

TO WATER (feet): 0.95

PURGE PUMP TYPE

OR BAILER: Peristaltic

WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH – STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable)

= ( 9.31 feet – 0.95 feet) X 0.04 gallons/foot = 0.3 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable)

= gallons + ( gallons/foot X feet) + gallons = gallons

INITIAL PUMP OR TUBING

DEPTH IN WELL (feet): 2.0

FINAL PUMP OR TUBING

DEPTH IN WELL (feet): 2.0

PURGING

INITIATED AT: 950

PURGING

ENDED AT: 955

TOTAL VOLUME

PURGED (gallons): 1.5

TIME

VOLUME

PURGED

(gallons)

CUMUL.

VOLUME

PURGED

(gallons)

PURGE

RATE

(gpm)

DEPTH

TO

WATER

(feet) pH (standard units)

TEMP.

(OC)

COND.

(S/cm)

DISSOLVED

OXYGEN

(% saturation)

TURBIDITY

(NTUs)

COLOR

(describe)

ODOR

(describe)

951 0.3 0.3 0.30 0.95 6.21 27.1 790 10.3 94.94 Dark None 952 0.3 0.6 0.30 0.95 6.21 27.1 792 6.4 47.33 Dark None 953 0.3 0.9 0.30 0.95 6.20 27.1 795 5.9 27.78 Dark None 954 0.3 1.2 0.30 0.95…