FIO-Appendices_Sampling_Analysis_Report_SanLuisReyRiver_Sept2016.pdf

Appendix A Core Photographs

Appendix B Field Data Logs

Appendix C Analytical Laboratory Reports

WORK ORDER NUMBER: 16-07-0102

Analytical Report For Client: Kinnetic Laboratories, Inc.

Client Project Name: San Luis Rey River Attention: Danielle Gonsman

2750 East Spring Street Suite 190 Long Beach, CA 90806-2249

Approved for release on by:

Carla Hollowell Project Manager

AIR SOIL WATER MARINE CHEMISTRY

Eurofins Calscience, Inc. (Calscience) certifies that the test results provided in this report meet all NELAC requirements for parameters for which accreditation is required or available. Any exceptions to NELAC requirements are noted in the case narrative. The original report of subcontracted analyses, if any, is attached to this report. The results in this report are limited to the sample(s) tested and any reproduction thereof must be made in its entirety. The client or recipient of this report is specifically prohibited from making material changes to said report and, to the extent that such changes are made, Calscience is not responsible, legally or otherwise. The client or recipient agrees to indemnify Calscience for any defense to any litigation which may arise.

07/29/2016

Supplemental Report 2 mailto:CarlaHollowell@eurofinsUS.com https://www.calscience.com/clientwebaccess/login.aspx

Contents

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Client Project Name: San Luis Rey River

Work Order Number: 16-07-0102

1 Work Order Narrative

2 Sample Summary

3 Client Sample Data

3.1 EPA 300.0 Anions (Solid)

3.2 EPA 314.0 (M) Perchlorate (Solid)

3.3 CA Fish and Game 96-Hour Acute Aquatic Bioassay (Solid)

3.4 EPA 160.4 (M) Volatile Solids (Solid)

3.5 EPA 1664A (M) HEM: Oil and Grease (Solid)

3.6 EPA 1664A (M) HEM-SGT: Oil and Grease (Solid)

3.7 EPA 7196A/3060A Chromium VI (Solid)

3.8 EPA 9060A Total Organic Carbon (Solid)

3.9 SM 2540 B (M) Total Solids (Solid)

3.10 SM 2540 C (M) Total Dissolved Solids (Solid)

3.11 SM 4500-NH3 B/C (M) Ammonia (Solid)

3.12 EPA 8015B (M) TPH Motor Oil (Solid)

3.13 EPA 8015B (M) TPH Diesel (Solid)

3.14 EPA 8015B (M) C4-C12 (Solid)

3.15 Pyrethroids by EPA 8270D (M)/TQ/EI (Solid)

3.16 Chromium III (Solid)

3.17 DHS LUFT Organic Lead (Solid)

3.18 EPA 6020 ICP/MS Metals (Solid)

3.19 EPA 7471A Mercury (Solid)

3.20 EPA 8081A Organochlorine Pesticides (Solid)

3.21 EPA 8151A Chlorinated Herbicides (Solid)

3.22 EPA 8270C Semi-Volatile Organics Appendix IX (Solid)

3.23 1,4-Dioxane by EPA 8270C (M) Isotope Dilution Soil (Solid)

3.24 EPA 8270C Bisphenol (Solid)

3.25 EPA 8270C SIM OC Pesticides (Solid)

3.26 EPA 8270C SIM (Solid)

3.27 EPA 8270C SIM PCB Congeners (Solid)

3.28 Krone et al. Organotins (Solid)

3.29 EPA 8260B Volatile Organics (Solid)

4 Quality Control Sample Data

Contents

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

4.1 MS/MSD

4.2 PDS/PDSD

4.3 Sample Duplicate

4.4 LCS/LCSD

5 Glossary of Terms and Qualifiers

6 Chain-of-Custody/Sample Receipt Form

7 Subcontract Narrative

8 Subcontract Report - Asbestos - 16-07-0102

9 Subcontract Report - TCDD - 16-07-0102

Condition Upon Receipt:

Samples were received under Chain-of-Custody (COC) on 07/01/16. They were assigned to Work Order 16-07-0102.

Unless otherwise noted on the Sample Receiving forms all samples were received in good condition and within the recommended EPA temperature criteria for the methods noted on the COC. The COC and Sample Receiving Documents are integral elements of the analytical report and are presented at the back of the report.

Holding Times:

All samples were analyzed within prescribed holding times (HT) and/or in accordance with the Calscience Sample Acceptance

Policy unless otherwise noted in the analytical report and/or comprehensive case narrative, if required.

Any parameter identified in 40CFR Part 136.3 Table II that is designated as "analyze immediately" with a holding time of <= 15 minutes (40CFR-136.3 Table II, footnote 4), is considered a "field" test and the reported results will be qualified as being received outside of the stated holding time unless received at the laboratory within 15 minutes of the collection time.

Quality Control:

All quality control parameters (QC) were within established control limits except where noted in the QC summary forms or described further within this report.

Subcontractor Information:

Unless otherwise noted below (or on the subcontract form), no samples were subcontracted.

Additional Comments:

Air - Sorbent-extracted air methods (EPA TO-4A, EPA TO-10, EPA TO-13A, EPA TO-17): Analytical results are converted from mass/sample basis to mass/volume basis using client-supplied air volumes.

Solid - Unless otherwise indicated, solid sample data is reported on a wet weight basis, not corrected for % moisture. All QC results are always reported on a wet weight basis.

Work Order Narrative

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Work Order: 16-07-0102 Page 1 of 1

R et ur n to C on te nt s

Sample Identification Lab Number Collection Date and Time Number of Containers

Matrix

SLRRHA16-A Comp 16-07-0102-1 07/01/16 10:02 5 Sediment

SLRRHA16-B Comp 16-07-0102-2 06/30/16 14:55 5 Sediment

SLRRHA16-C Comp 16-07-0102-3 06/30/16 16:36 5 Sediment

SLRRHA16-D Comp 16-07-0102-4 07/01/16 09:57 5 Sediment

SPAHA16-Comp 16-07-0102-5 07/01/16 11:40 5 Sediment

Sample Summary

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Client: Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Work Order: 16-07-0102

Project Name: San Luis Rey River

PO Number:

Date/Time Received:

07/01/16 18:35

Number of Containers:

Attn: Danielle Gonsman

R et ur n to C on te nt

Client Sample Number Lab Sample Number

Date/Time Collected

Matrix Instrument Date Prepared

Date/Time Analyzed

QC Batch ID

SLRRHA16-A Comp 16-07-0102-1-B 07/01/16 10:02

Sediment IC 10 07/12/16 07/12/16 23:12

160712L01P

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Fluoride 0.48 1.1 0.33 1.00 J

SLRRHA16-B Comp 16-07-0102-2-B 06/30/16 14:55

Sediment IC 10 07/12/16 07/12/16 23:31

160712L01P

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Fluoride 0.51 1.0 0.32 1.00 J

SLRRHA16-C Comp 16-07-0102-3-B 06/30/16 16:36

Sediment IC 10 07/12/16 07/12/16 23:50

160712L01P

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Fluoride 0.35 1.0 0.32 1.00 J

SLRRHA16-D Comp 16-07-0102-4-B 07/01/16 09:57

Sediment IC 10 07/12/16 07/13/16 00:09

160712L01P

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Fluoride 0.85 1.1 0.33 1.00 J

SPAHA16-Comp 16-07-0102-5-A 07/01/16 11:40

Sediment IC 10 07/12/16 07/13/16 00:28

160712L01P

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Fluoride 0.37 1.1 0.33 1.00 J

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: N/A

Method: EPA 300.0

Units: mg/kg

Project: San Luis Rey River Page 1 of 2

RL: Reporting Limit. DF: Dilution Factor. MDL: Method Detection Limit.

R et ur n to C on te nt

Date/Time Collected

Matrix Instrument Date Prepared

Date/Time Analyzed

QC Batch ID

Method Blank 099-12-922-743 N/A Solid IC 10 07/12/16 07/12/16 22:34

160712L01P

Comment(s): - Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Fluoride ND 1.0 0.31 1.00

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: N/A

Method: EPA 300.0

Units: mg/kg

Project: San Luis Rey River Page 2 of 2

RL: Reporting Limit. DF: Dilution Factor. MDL: Method Detection Limit.

R et ur n to C on te nt

Date/Time Collected

Matrix Instrument Date Prepared

Date/Time Analyzed

QC Batch ID

SLRRHA16-A Comp 16-07-0102-1-AA 07/01/16 10:02

Sediment IC 13 07/11/16 07/11/16 19:02

160711L01P

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Perchlorate ND 0.021 0.0072 1.00

SLRRHA16-B Comp 16-07-0102-2-AA 06/30/16 14:55

Sediment IC 13 07/11/16 07/11/16 19:17

160711L01P

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Perchlorate ND 0.021 0.0071 1.00

SLRRHA16-C Comp 16-07-0102-3-AA 06/30/16 16:36

Sediment IC 13 07/11/16 07/11/16 19:31

160711L01P

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Perchlorate ND 0.020 0.0070 1.00

SLRRHA16-D Comp 16-07-0102-4-AA 07/01/16 09:57

Sediment IC 13 07/11/16 07/11/16 19:46

160711L01P

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Perchlorate ND 0.021 0.0072 1.00

SPAHA16-Comp 16-07-0102-5-AA 07/01/16 11:40

Sediment IC 13 07/11/16 07/11/16 20:00

160711L01P

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Perchlorate 0.017 0.021 0.0073 1.00 J

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: N/A

Method: EPA 314.0 (M)

Units: mg/kg

Project: San Luis Rey River Page 1 of 2

RL: Reporting Limit. DF: Dilution Factor. MDL: Method Detection Limit.

R et ur n to C on te nt

Date/Time Collected

Matrix Instrument Date Prepared

Date/Time Analyzed

QC Batch ID

Method Blank 099-05-205-1132 N/A Solid IC 13 07/11/16 07/11/16 17:36

160711L01P

Comment(s): - Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Perchlorate ND 0.020 0.0068 1.00

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: N/A

Method: EPA 314.0 (M)

Units: mg/kg

Project: San Luis Rey River Page 2 of 2

RL: Reporting Limit. DF: Dilution Factor. MDL: Method Detection Limit.

R et ur n to C on te nt

Initial Water Quality Parameters

Sample Preparation

The sample was adjusted to test temperature.

Sample Adjustment During Analysis

No Supplemental aeration needed.

If needed, supplemental aeration to maintain required Dissolved Oxygen level is supplied via a low pressure oil-free pump connected to individual lines for each tank/chamber from a common manifold. Individual valves at each tank/chamber control the flow rate as required.

Laboratory Notes

Sample was received within recommended holding time.

All testing was within method protocol.

LC 50 Results

Test Species: Fathead Minnow (Pimephales Promelas) Mean Length: 44 mm Mean Weight: 0.48 g

Sample Collected: 07/01/16 10:02:00 Sample Received: 07/01/16 18:35:00

Test Start: 07/07/16 14:00:00 Test End: 07/11/16 14:00:00

Residual Chlorine: < 0.01 mg/L Temperature: 19.9 °C pH: 7.77 units Conductivity: 910 umhos/cm

Dissolved Oxygen (D.O.): 7.17 mg/L Alkanlinity: 194 mg/L

Hardness: 42 mg/L Ammonia: N/A

Client Sample Number Lab Sample Number Date Collected Matrix Date Prepared Date/Time Analyzed

QC Batch ID

SLRRHA16-A Comp 16-07-0102-1-A 07/01/16 Sediment 07/07/16 07/11/16 14:00:00

Parameter Result Units

Bioassay 750 mg/L (% Mortality) 0 %

Bioassay 250 mg/L (% Mortality) 0 %

SRT sample (mg/L): 25.10

Upper 95% confidence limit: 26.60

Lower 95% confidence limit: 23.60

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: N/A

Method: CA Fish and Game

Project: San Luis Rey River Page 1 of 5

SRT: Standard Reference Toxicant.

R et ur n to C on te nt

The sample was adjusted to test temperature.

If needed, supplemental aeration to maintain required Dissolved Oxygen level is supplied via a low pressure oil-free pump connected to individual lines for each tank/chamber from a common manifold. Individual valves at each tank/chamber control the flow rate as required.

Test Species: Fathead Minnow (Pimephales Promelas) Mean Length: 44 mm Mean Weight: 0.48 g

Sample Collected: 06/30/16 14:55:00 Sample Received: 07/01/16 18:35:00

Test Start: 07/07/16 14:00:00 Test End: 07/11/16 14:00:00

Residual Chlorine: < 0.01 mg/L Temperature: 19.9 °C pH: 7.78 units Conductivity: 910 umhos/cm

Dissolved Oxygen (D.O.): 7.14 mg/L Alkanlinity: 194 mg/L

Hardness: 42 mg/L Ammonia: N/A

Client Sample Number Lab Sample Number Date Collected Matrix Date Prepared Date/Time Analyzed

QC Batch ID

SLRRHA16-B Comp 16-07-0102-2-A 06/30/16 Sediment 07/07/16 07/11/16 14:00:00

Parameter Result Units

Bioassay 750 mg/L (% Mortality) 0 %

Bioassay 250 mg/L (% Mortality) 0 %

SRT sample (mg/L): 25.10

Upper 95% confidence limit: 26.60

Lower 95% confidence limit: 23.60

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: N/A

Method: CA Fish and Game

Project: San Luis Rey River Page 2 of 5

SRT: Standard Reference Toxicant.

R et ur n to C on te nt

The sample was adjusted to test temperature.

If needed, supplemental aeration to maintain required Dissolved Oxygen level is supplied via a low pressure oil-free pump connected to individual lines for each tank/chamber from a common manifold. Individual valves at each tank/chamber control the flow rate as required.

Test Species: Fathead Minnow (Pimephales Promelas) Mean Length: 44 mm Mean Weight: 0.48 g

Sample Collected: 06/30/16 16:36:00 Sample Received: 07/01/16 18:35:00

Test Start: 07/07/16 14:00:00 Test End: 07/11/16 14:00:00

Residual Chlorine: < 0.01 mg/L Temperature: 19.9 °C pH: 7.79 units Conductivity: 910 umhos/cm

Dissolved Oxygen (D.O.): 7.12 mg/L Alkanlinity: 194 mg/L

Hardness: 42 mg/L Ammonia: N/A

Client Sample Number Lab Sample Number Date Collected Matrix Date Prepared Date/Time Analyzed

QC Batch ID

SLRRHA16-C Comp 16-07-0102-3-A 06/30/16 Sediment 07/07/16 07/11/16 14:00:00

Parameter Result Units

Bioassay 750 mg/L (% Mortality) 0 %

Bioassay 250 mg/L (% Mortality) 0 %

SRT sample (mg/L): 25.10

Upper 95% confidence limit: 26.60

Lower 95% confidence limit: 23.60

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: N/A

Method: CA Fish and Game

Project: San Luis Rey River Page 3 of 5

SRT: Standard Reference Toxicant.

R et ur n to C on te nt

The sample was adjusted to test temperature.

If needed, supplemental aeration to maintain required Dissolved Oxygen level is supplied via a low pressure oil-free pump connected to individual lines for each tank/chamber from a common manifold. Individual valves at each tank/chamber control the flow rate as required.

Test Species: Fathead Minnow (Pimephales Promelas) Mean Length: 44 mm Mean Weight: 0.48 g

Sample Collected: 07/01/16 09:57:00 Sample Received: 07/01/16 18:35:00

Test Start: 07/07/16 14:00:00 Test End: 07/11/16 14:00:00

Residual Chlorine: < 0.01 mg/L Temperature: 19.9 °C pH: 7.76 units Conductivity: 910 umhos/cm

Dissolved Oxygen (D.O.): 7.18 mg/L Alkanlinity: 194 mg/L

Hardness: 42 mg/L Ammonia: N/A

Client Sample Number Lab Sample Number Date Collected Matrix Date Prepared Date/Time Analyzed

QC Batch ID

SLRRHA16-D Comp 16-07-0102-4-A 07/01/16 Sediment 07/07/16 07/11/16 14:00:00

Parameter Result Units

Bioassay 750 mg/L (% Mortality) 0 %

Bioassay 250 mg/L (% Mortality) 0 %

SRT sample (mg/L): 25.10

Upper 95% confidence limit: 26.60

Lower 95% confidence limit: 23.60

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: N/A

Method: CA Fish and Game

Project: San Luis Rey River Page 4 of 5

SRT: Standard Reference Toxicant.

R et ur n to C on te nt

The sample was adjusted to test temperature.

If needed, supplemental aeration to maintain required Dissolved Oxygen level is supplied via a low pressure oil-free pump connected to individual lines for each tank/chamber from a common manifold. Individual valves at each tank/chamber control the flow rate as required.

Test Species: Fathead Minnow (Pimephales Promelas) Mean Length: 44 mm Mean Weight: 0.48 g

Sample Collected: 07/01/16 11:40:00 Sample Received: 07/01/16 18:35:00

Test Start: 07/07/16 14:00:00 Test End: 07/11/16 14:00:00

Residual Chlorine: < 0.01 mg/L Temperature: 19.9 °C pH: 7.78 units Conductivity: 910 umhos/cm

Dissolved Oxygen (D.O.): 7.17 mg/L Alkanlinity: 194 mg/L

Hardness: 42 mg/L Ammonia: N/A

Client Sample Number Lab Sample Number Date Collected Matrix Date Prepared Date/Time Analyzed

QC Batch ID

SPAHA16-Comp 16-07-0102-5-A 07/01/16 Sediment 07/07/16 07/11/16 14:00:00

Parameter Result Units

Bioassay 750 mg/L (% Mortality) 0 %

Bioassay 250 mg/L (% Mortality) 0 %

SRT sample (mg/L): 25.10

Upper 95% confidence limit: 26.60

Lower 95% confidence limit: 23.60

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: N/A

Method: CA Fish and Game

Project: San Luis Rey River Page 5 of 5

SRT: Standard Reference Toxicant.

R et ur n to C on te nt

Date/Time Collected

Matrix Instrument Date Prepared

Date/Time Analyzed

QC Batch ID

SLRRHA16-A Comp 16-07-0102-1-A 07/01/16 10:02

Sediment N/A 07/07/16 07/07/16 20:00

G0707VSB1

Comment(s): - Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Solids, Volatile 1.3 0.10 0.10 1.00

SLRRHA16-B Comp 16-07-0102-2-A 06/30/16 14:55

Sediment N/A 07/07/16 07/07/16 20:00

G0707VSB1

Comment(s): - Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Solids, Volatile 1.0 0.10 0.10 1.00

SLRRHA16-C Comp 16-07-0102-3-A 06/30/16 16:36

Sediment N/A 07/07/16 07/07/16 20:00

G0707VSB1

Comment(s): - Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Solids, Volatile 0.70 0.10 0.10 1.00

SLRRHA16-D Comp 16-07-0102-4-A 07/01/16 09:57

Sediment N/A 07/07/16 07/07/16 20:00

G0707VSB1

Comment(s): - Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Solids, Volatile 1.4 0.10 0.10 1.00

SPAHA16-Comp 16-07-0102-5-A 07/01/16 11:40

Sediment N/A 07/07/16 07/07/16 20:00

G0707VSB1

Comment(s): - Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Solids, Volatile 2.3 0.10 0.10 1.00

Method Blank 099-05-020-1073 N/A Solid N/A 07/07/16 07/07/16 20:00

G0707VSB1

Comment(s): - Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Solids, Volatile ND 0.10 0.10 1.00

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: N/A

Method: EPA 160.4 (M)

Units: %

Project: San Luis Rey River Page 1 of 1

RL: Reporting Limit. DF: Dilution Factor. MDL: Method Detection Limit.

R et ur n to C on te nt

Date/Time Collected

Matrix Instrument Date Prepared

Date/Time Analyzed

QC Batch ID

SLRRHA16-A Comp 16-07-0102-1-AA 07/01/16 10:02

Sediment N/A 07/13/16 07/13/16 15:45

G0713HEML3

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

HEM: Oil and Grease ND 11 8.3 1.00

SLRRHA16-B Comp 16-07-0102-2-AA 06/30/16 14:55

Sediment N/A 07/13/16 07/13/16 15:45

G0713HEML3

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

HEM: Oil and Grease ND 10 8.2 1.00

SLRRHA16-C Comp 16-07-0102-3-AA 06/30/16 16:36

Sediment N/A 07/13/16 07/13/16 15:45

G0713HEML3

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

HEM: Oil and Grease 10 10 8.0 1.00

SLRRHA16-D Comp 16-07-0102-4-AA 07/01/16 09:57

Sediment N/A 07/13/16 07/13/16 15:45

G0713HEML3

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

HEM: Oil and Grease ND 11 8.3 1.00

SPAHA16-Comp 16-07-0102-5-AA 07/01/16 11:40

Sediment N/A 07/13/16 07/13/16 15:45

G0713HEML3

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

HEM: Oil and Grease 25 11 8.4 1.00

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: N/A

Method: EPA 1664A (M)

Units: mg/kg

Project: San Luis Rey River Page 1 of 2

RL: Reporting Limit. DF: Dilution Factor. MDL: Method Detection Limit.

R et ur n to C on te nt

Date/Time Collected

Matrix Instrument Date Prepared

Date/Time Analyzed

QC Batch ID

Method Blank 099-12-040-621 N/A Solid N/A 07/13/16 07/13/16 15:45

G0713HEML3

Comment(s): - Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

HEM: Oil and Grease ND 10 7.9 1.00

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: N/A

Method: EPA 1664A (M)

Units: mg/kg

Project: San Luis Rey River Page 2 of 2

RL: Reporting Limit. DF: Dilution Factor. MDL: Method Detection Limit.

R et ur n to C on te nt

Date/Time Collected

Matrix Instrument Date Prepared

Date/Time Analyzed

QC Batch ID

SLRRHA16-A Comp 16-07-0102-1-AA 07/01/16 10:02

Sediment N/A 07/13/16 07/13/16 18:45

G0713HEML4

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

HEM - SGT: Oil and Grease ND 11 8.5 1.00

SLRRHA16-B Comp 16-07-0102-2-AA 06/30/16 14:55

Sediment N/A 07/13/16 07/13/16 18:45

G0713HEML4

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

HEM - SGT: Oil and Grease ND 10 8.4 1.00

SLRRHA16-C Comp 16-07-0102-3-AA 06/30/16 16:36

Sediment N/A 07/13/16 07/13/16 18:45

G0713HEML4

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

HEM - SGT: Oil and Grease ND 10 8.2 1.00

SLRRHA16-D Comp 16-07-0102-4-AA 07/01/16 09:57

Sediment N/A 07/13/16 07/13/16 18:45

G0713HEML4

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

HEM - SGT: Oil and Grease ND 11 8.5 1.00

SPAHA16-Comp 16-07-0102-5-AA 07/01/16 11:40

Sediment N/A 07/13/16 07/13/16 18:45

G0713HEML4

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

HEM - SGT: Oil and Grease 21 11 8.6 1.00

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: N/A

Method: EPA 1664A (M)

Units: mg/kg

Project: San Luis Rey River Page 1 of 2

RL: Reporting Limit. DF: Dilution Factor. MDL: Method Detection Limit.

R et ur n to C on te nt

Date/Time Collected

Matrix Instrument Date Prepared

Date/Time Analyzed

QC Batch ID

Method Blank 099-12-207-142 N/A Solid N/A 07/13/16 07/13/16 18:45

G0713HEML4

Comment(s): - Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

HEM - SGT: Oil and Grease ND 10 8.1 1.00

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: N/A

Method: EPA 1664A (M)

Units: mg/kg

Project: San Luis Rey River Page 2 of 2

RL: Reporting Limit. DF: Dilution Factor. MDL: Method Detection Limit.

R et ur n to C on te nt

Date/Time Collected

Matrix Instrument Date Prepared

Date/Time Analyzed

QC Batch ID

SLRRHA16-A Comp 16-07-0102-1-AA 07/01/16 10:02

Sediment UV 8 07/11/16 07/11/16 17:13

G0711CRL1

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Chromium, Hexavalent ND 0.84 0.23 1.00

SLRRHA16-B Comp 16-07-0102-2-BB 06/30/16 14:55

Sediment UV 8 07/11/16 07/11/16 17:13

G0711CRL1

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Chromium, Hexavalent ND 0.83 0.22 1.00

SLRRHA16-C Comp 16-07-0102-3-BB 06/30/16 16:36

Sediment UV 8 07/11/16 07/11/16 17:13

G0711CRL1

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Chromium, Hexavalent ND 0.81 0.22 1.00

SLRRHA16-D Comp 16-07-0102-4-BB 07/01/16 09:57

Sediment UV 8 07/11/16 07/11/16 17:13

G0711CRL1

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Chromium, Hexavalent ND 0.84 0.23 1.00

SPAHA16-Comp 16-07-0102-5-AA 07/01/16 11:40

Sediment UV 8 07/11/16 07/11/16 17:13

G0711CRL1

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Chromium, Hexavalent ND 0.85 0.23 1.00

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: N/A

Method: EPA 7196A

Units: mg/kg

Project: San Luis Rey River Page 1 of 2

RL: Reporting Limit. DF: Dilution Factor. MDL: Method Detection Limit.

R et ur n to C on te nt

Date/Time Collected

Matrix Instrument Date Prepared

Date/Time Analyzed

QC Batch ID

Method Blank 099-05-001-5784 N/A Solid UV 8 07/11/16 07/11/16 17:13

G0711CRL1

Comment(s): - Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Chromium, Hexavalent ND 0.80 0.22 1.00

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: N/A

Method: EPA 7196A

Units: mg/kg

Project: San Luis Rey River Page 2 of 2

RL: Reporting Limit. DF: Dilution Factor. MDL: Method Detection Limit.

R et ur n to C on te nt

Date/Time Collected

Matrix Instrument Date Prepared

Date/Time Analyzed

QC Batch ID

SLRRHA16-A Comp 16-07-0102-1-B 07/01/16 10:02

Sediment TOC 10 07/14/16 07/14/16 16:50

G0714TOCL1

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Carbon, Total Organic 0.10 0.053 0.018 1.00

SLRRHA16-B Comp 16-07-0102-2-B 06/30/16 14:55

Sediment TOC 10 07/14/16 07/14/16 16:50

G0714TOCL1

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Carbon, Total Organic 0.46 0.052 0.018 1.00

SLRRHA16-C Comp 16-07-0102-3-B 06/30/16 16:36

Sediment TOC 10 07/14/16 07/14/16 16:50

G0714TOCL1

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Carbon, Total Organic ND 0.051 0.018 1.00

SLRRHA16-D Comp 16-07-0102-4-B 07/01/16 09:57

Sediment TOC 10 07/14/16 07/14/16 16:50

G0714TOCL1

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Carbon, Total Organic 0.086 0.053 0.018 1.00

SPAHA16-Comp 16-07-0102-5-A 07/01/16 11:40

Sediment TOC 10 07/14/16 07/14/16 16:50

G0714TOCL1

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Carbon, Total Organic 1.1 0.053 0.018 1.00

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: N/A

Method: EPA 9060A

Units: %

Project: San Luis Rey River Page 1 of 2

RL: Reporting Limit. DF: Dilution Factor. MDL: Method Detection Limit.

R et ur n to C on te nt

Date/Time Collected

Matrix Instrument Date Prepared

Date/Time Analyzed

QC Batch ID

Method Blank 099-06-013-1575 N/A Solid TOC 10 07/14/16 07/14/16 16:50

G0714TOCL1

Comment(s): - Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Carbon, Total Organic ND 0.050 0.017 1.00

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: N/A

Method: EPA 9060A

Units: %

Project: San Luis Rey River Page 2 of 2

RL: Reporting Limit. DF: Dilution Factor. MDL: Method Detection Limit.

R et ur n to C on te nt

Date/Time Collected

Matrix Instrument Date Prepared

Date/Time Analyzed

QC Batch ID

SLRRHA16-A Comp 16-07-0102-1-A 07/01/16 10:02

Sediment N/A 07/06/16 07/06/16 21:00

G0706TSB2

Comment(s): - Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Solids, Total 95.1 0.100 0.100 1.00

SLRRHA16-B Comp 16-07-0102-2-A 06/30/16 14:55

Sediment N/A 07/06/16 07/06/16 21:00

G0706TSB2

Comment(s): - Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Solids, Total 96.0 0.100 0.100 1.00

SLRRHA16-C Comp 16-07-0102-3-A 06/30/16 16:36

Sediment N/A 07/06/16 07/06/16 21:00

G0706TSB2

Comment(s): - Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Solids, Total 98.4 0.100 0.100 1.00

SLRRHA16-D Comp 16-07-0102-4-A 07/01/16 09:57

Sediment N/A 07/06/16 07/06/16 21:00

G0706TSB2

Comment(s): - Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Solids, Total 95.1 0.100 0.100 1.00

SPAHA16-Comp 16-07-0102-5-A 07/01/16 11:40

Sediment N/A 07/06/16 07/06/16 21:00

G0706TSB2

Comment(s): - Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Solids, Total 94.2 0.100 0.100 1.00

Method Blank 099-05-019-3335 N/A Solid N/A 07/06/16 07/06/16 21:00

G0706TSB2

Comment(s): - Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Solids, Total ND 0.100 0.100 1.00

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: N/A

Method: SM 2540 B (M)

Units: %

Project: San Luis Rey River Page 1 of 1

RL: Reporting Limit. DF: Dilution Factor. MDL: Method Detection Limit.

R et ur n to C on te nt

Date/Time Collected

Matrix Instrument Date Prepared

Date/Time Analyzed

QC Batch ID

SLRRHA16-A Comp 16-07-0102-1-AA 07/01/16 10:02

Sediment N/A 07/09/16 07/09/16 19:00

G0709TDSB6

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Solids, Total Dissolved 0.71 0.0011 0.00011 1.00

SLRRHA16-B Comp 16-07-0102-2-AA 06/30/16 14:55

Sediment N/A 07/09/16 07/09/16 19:00

G0709TDSB6

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Solids, Total Dissolved 0.68 0.0010 0.00010 1.00

SLRRHA16-C Comp 16-07-0102-3-AA 06/30/16 16:36

Sediment N/A 07/09/16 07/09/16 19:00

G0709TDSB6

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Solids, Total Dissolved 0.20 0.0010 0.00010 1.00

SLRRHA16-D Comp 16-07-0102-4-AA 07/01/16 09:57

Sediment N/A 07/09/16 07/09/16 19:00

G0709TDSB6

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Solids, Total Dissolved 0.50 0.0011 0.00011 1.00

SPAHA16-Comp 16-07-0102-5-AA 07/01/16 11:40

Sediment N/A 07/09/16 07/09/16 19:00

G0709TDSB6

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Solids, Total Dissolved 1.2 0.011 0.00011 1.00

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: N/A

Method: SM 2540 C (M)

Units: %

Project: San Luis Rey River Page 1 of 2

RL: Reporting Limit. DF: Dilution Factor. MDL: Method Detection Limit.

R et ur n to C on te nt

Date/Time Collected

Matrix Instrument Date Prepared

Date/Time Analyzed

QC Batch ID

Method Blank 099-12-182-421 N/A Solid N/A 07/09/16 07/09/16 19:00

G0709TDSB6

Comment(s): - Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Solids, Total Dissolved ND 0.00010 0.00010 1.00

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: N/A

Method: SM 2540 C (M)

Units: %

Project: San Luis Rey River Page 2 of 2

RL: Reporting Limit. DF: Dilution Factor. MDL: Method Detection Limit.

R et ur n to C on te nt

Date/Time Collected

Matrix Instrument Date Prepared

Date/Time Analyzed

QC Batch ID

SLRRHA16-A Comp 16-07-0102-1-AA 07/01/16 10:02

Sediment BUR05 07/18/16 07/08/16 18:07

G0718NH3L1

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Ammonia (as N) 29 11 7.0 2.00

SLRRHA16-B Comp 16-07-0102-2-AA 06/30/16 14:55

Sediment BUR05 07/18/16 07/08/16 18:07

G0718NH3L1

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Ammonia (as N) 73 10 6.9 2.00

SLRRHA16-C Comp 16-07-0102-3-AA 06/30/16 16:36

Sediment BUR05 07/18/16 07/08/16 18:07

G0718NH3L1

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Ammonia (as N) 57 10 6.8 2.00

SLRRHA16-D Comp 16-07-0102-4-AA 07/01/16 09:57

Sediment BUR05 07/18/16 07/08/16 18:07

G0718NH3L1

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Ammonia (as N) 27 11 7.0 2.00

SPAHA16-Comp 16-07-0102-5-AA 07/01/16 11:40

Sediment BUR05 07/18/16 07/08/16 18:07

G0718NH3L1

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Ammonia (as N) 120 11 7.1 2.00

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: N/A

Method: SM 4500-NH3 B/C (M)

Units: mg/kg

Project: San Luis Rey River Page 1 of 2

RL: Reporting Limit. DF: Dilution Factor. MDL: Method Detection Limit.

R et ur n to C on te nt

Date/Time Collected

Matrix Instrument Date Prepared

Date/Time Analyzed

QC Batch ID

Method Blank 099-12-812-938 N/A Solid BUR05 07/18/16 07/08/16 18:07

G0718NH3L1

Comment(s): - Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

Ammonia (as N) ND 5.0 3.3 1.00

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: N/A

Method: SM 4500-NH3 B/C (M)

Units: mg/kg

Project: San Luis Rey River Page 2 of 2

RL: Reporting Limit. DF: Dilution Factor. MDL: Method Detection Limit.

R et ur n to C on te nt

Date/Time Collected

Matrix Instrument Date Prepared

Date/Time Analyzed

QC Batch ID

SLRRHA16-A Comp 16-07-0102-1-AA 07/01/16 10:02

Sediment GC 49 07/12/16 07/13/16 21:41

160712B05

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

TPH as Motor Oil Range 2.0 5.2 0.95 1.00 HD,J

Surrogate Rec. (%) Control Limits Qualifiers n-Octacosane 82 61-145

SLRRHA16-B Comp 16-07-0102-2-AA 06/30/16 14:55

Sediment GC 49 07/12/16 07/13/16 21:59

160712B05

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

TPH as Motor Oil Range 4.2 5.3 0.97 1.00 HD,J

Surrogate Rec. (%) Control Limits Qualifiers n-Octacosane 89 61-145

SLRRHA16-C Comp 16-07-0102-3-AA 06/30/16 16:36

Sediment GC 49 07/12/16 07/13/16 22:16

160712B05

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

TPH as Motor Oil Range 2.6 5.0 0.93 1.00 HD,J

Surrogate Rec. (%) Control Limits Qualifiers n-Octacosane 86 61-145

SLRRHA16-D Comp 16-07-0102-4-AA 07/01/16 09:57

Sediment GC 49 07/12/16 07/13/16 22:34

160712B05

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

TPH as Motor Oil Range 4.4 5.2 0.95 1.00 HD,J

Surrogate Rec. (%) Control Limits Qualifiers n-Octacosane 91 61-145

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: EPA 3550B

Method: EPA 8015B (M)

Units: mg/kg

Project: San Luis Rey River Page 1 of 2

RL: Reporting Limit. DF: Dilution Factor. MDL: Method Detection Limit.

R et ur n to C on te nt

Date/Time Collected

Matrix Instrument Date Prepared

Date/Time Analyzed

QC Batch ID

SPAHA16-Comp 16-07-0102-5-AA 07/01/16 11:40

Sediment GC 49 07/12/16 07/13/16 22:51

160712B05

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

TPH as Motor Oil Range 29 5.3 0.99 1.00 HD

Surrogate Rec. (%) Control Limits Qualifiers n-Octacosane 78 61-145

Method Blank 099-12-838-140 N/A Solid GC 49 07/12/16 07/13/16 20:32

160712B05

Comment(s): - Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

TPH as Motor Oil Range ND 5.0 0.93 1.00

Surrogate Rec. (%) Control Limits Qualifiers n-Octacosane 92 61-145

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: EPA 3550B

Method: EPA 8015B (M)

Units: mg/kg

Project: San Luis Rey River Page 2 of 2

RL: Reporting Limit. DF: Dilution Factor. MDL: Method Detection Limit.

R et ur n to C on te nt

Date/Time Collected

Matrix Instrument Date Prepared

Date/Time Analyzed

QC Batch ID

SLRRHA16-A Comp 16-07-0102-1-AA 07/01/16 10:02

Sediment GC 47 07/12/16 07/12/16 15:56

160712B04

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

TPH as Diesel 2.9 5.2 1.3 1.00 HD,J

Surrogate Rec. (%) Control Limits Qualifiers n-Octacosane 89 61-145

SLRRHA16-B Comp 16-07-0102-2-AA 06/30/16 14:55

Sediment GC 47 07/12/16 07/12/16 16:13

160712B04

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

TPH as Diesel 4.3 5.1 1.3 1.00 HD,J

Surrogate Rec. (%) Control Limits Qualifiers n-Octacosane 65 61-145

SLRRHA16-C Comp 16-07-0102-3-AA 06/30/16 16:36

Sediment GC 47 07/12/16 07/12/16 16:29

160712B04

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

TPH as Diesel 2.6 5.1 1.3 1.00 HD,J

Surrogate Rec. (%) Control Limits Qualifiers n-Octacosane 123 61-145

SLRRHA16-D Comp 16-07-0102-4-AA 07/01/16 09:57

Sediment GC 47 07/12/16 07/12/16 16:46

160712B04

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

TPH as Diesel 2.9 5.3 1.3 1.00 HD,J

Surrogate Rec. (%) Control Limits Qualifiers n-Octacosane 73 61-145

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: EPA 3550B

Method: EPA 8015B (M)

Units: mg/kg

Project: San Luis Rey River Page 1 of 2

RL: Reporting Limit. DF: Dilution Factor. MDL: Method Detection Limit.

R et ur n to C on te nt

Date/Time Collected

Matrix Instrument Date Prepared

Date/Time Analyzed

QC Batch ID

SPAHA16-Comp 16-07-0102-5-AA 07/01/16 11:40

Sediment GC 47 07/12/16 07/12/16 17:03

160712B04

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

TPH as Diesel 19 5.2 1.3 1.00 HD

Surrogate Rec. (%) Control Limits Qualifiers n-Octacosane 75 61-145

Method Blank 099-15-422-2541 N/A Solid GC 47 07/12/16 07/12/16 14:49

160712B04

Comment(s): - Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

TPH as Diesel ND 5.0 1.3 1.00

Surrogate Rec. (%) Control Limits Qualifiers n-Octacosane 88 61-145

Analytical Report

7440 Lincoln Way, Garden Grove, CA 92841-1427 • TEL: (714) 895-5494 • FAX: (714) 894-7501

Kinnetic Laboratories, Inc.

2750 East Spring Street, Suite 190

Long Beach, CA 90806-2249

Date Received: 07/01/16

Work Order: 16-07-0102

Preparation: EPA 3550B

Method: EPA 8015B (M)

Units: mg/kg

Project: San Luis Rey River Page 2 of 2

RL: Reporting Limit. DF: Dilution Factor. MDL: Method Detection Limit.

R et ur n to C on te nt

Date/Time Collected

Matrix Instrument Date Prepared

Date/Time Analyzed

QC Batch ID

SLRRHA16-A Comp 16-07-0102-1-C 07/01/16 10:02

Sediment GC 4 07/07/16 07/10/16 05:06

160709L016

Comment(s): - Results are reported on a dry weight basis.

- Results were evaluated to the MDL (DL), concentrations >= to the MDL (DL) but < RL (LOQ), if found, are qualified with a "J" flag.

Parameter Result RL MDL DF Qualifiers

C4-C5 ND 0.54 0.12 1.00

C6 ND 0.54 0.15 1.00

C7 ND 0.54 0.16 1.00

C8 ND 0.54 0.16 1.00

C9-C10 ND 0.54 0.16 1.00

C11-C12 ND 0.54 0.25 1.00

GRO (C4-C12) Total ND 0.54 0.25 1.00

Surrogate Rec. (%) Control Limits Qualifiers

1,4-Bromofluorobenzene - FID 89 42-126

SLRRHA16-B Comp 16-07-0102-2-C 06/30/16 14:55

Sediment GC 4 07/07/16 07/10/16 06:49

160709L016

Comment(s): - Results are reported on a dry…