Appendices_Final_2006_NW_IDE_Report-February_2009.pdf

APPENDIX A

CH2M HILL Data Quality Summary for Sulphur Bank Mercury Mine North Wetland Investigation, June 2005

A.1 Introduction The objective of this data quality summary (DQS) is to assess the quality of analytical results for sediment, soil, surface water, and tissue samples collected from June 27–30, 2005, for the Sulphur Bank Mercury Mine (SBMM) North Wetland investigation. Samples were collected and analyzed to establish a baseline of pre-remediation concentrations of constituents of concern in media within North Wetland.

This DQS summarizes the results of the quality assurance/quality control (QA/QC) activities prescribed in the Quality Assurance Project Plan for Sulphur Bank Mercury Mine Superfund Site (QAPP) (CH2M HILL, 2005). The QAPP presents specific policies, organization, functions and QA/QC activities associated with the analytical data generation and assessment that was designed to achieve data quality goals for this project. The QAPP provides comprehensive guidance for obtaining analytical data of known quality.

This report is intended as a general data quality assessment designed to summarize data issues.

A.2 Analytical Data The samples collected include 18 native environmental sediment samples and 2 sediment field duplicates (FD); 18 native environmental soil samples and 2 soil FDs; 18 native environmental surface water samples and 3 surface water FDs; and 11 native environmental tissue samples. The samples were divided into six sample delivery groups (SDG) by the laboratories. A total of 14 methods were used to analyze the environmental samples.

Analyses were performed by the U.S. Environmental Protection Agency (EPA) Region 9 Laboratory located in Richmond, California. Samples were collected and shipped by overnight courier to EPAR9 for analysis. Selected samples were analyzed for one or more of the following analytes and methods:

• Total dissolved solids (TDS) using Method E160.1

• Total suspended solids (TSS) using Method E160.2

• Total and dissolved metals using Method E200.7 and E200.8

• Total and dissolved mercury, using Method E245.1

• Anions using Method E300

• Ammonia using Method E350.1

• Total Kjeldahl nitrogen using Method E351.2

• Total phosphorus using Method E365.4

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CH2M HILL DATA QUALITY SUMMARY FOR SULPHUR BANK MERCURY MINE

NORTH WETLAND INVESTIGATION, JUNE 2005

• Sulfide using Method E376.1

• Total organic carbon (TOC) using Method E415.1

• Alkalinity (carbonate, bicarbonate, hydroxide, and total)using Method SM2320

• Total metals using Method SW6010B

• Total mercury using Method SW7473

CH2M HILL performed a Tier 3 validation review. (The monomethyl mercury data for the North Wetland Investigation was validated by ICF Consulting/Laboratory Data Consultants (see Appendix B.) Analytical performance was initially assessed on an SDG or analytical batch basis. The tables included in this appendix summarize data validation reports by SDG and by analyses method. Several SDGs may be associated with the same laboratory QC samples. The association of laboratory QC samples and normal environ-mental samples from the same analytical batches can be determined by the laboratory lot control number. Each data package was reviewed for the following:

1. Chain-of-custody (CoC) documentation

2. Holding time compliance

3. Required QC samples at the specified frequencies

4. Method blanks

5. Laboratory control samples (LCS)

6. Analytical spike data

7. Matrix spike/matrix spike duplicate (MS/MSD) samples on a site/location basis

8. Initial and continuing calibration information

9. Other method-specific criteria defined in the QAPP

10. Field samples were also reviewed to ascertain field compliance and data quality issues, including equipment blanks and FDs

Data flags were assigned in accordance with the QAPP using the defined QC acceptance limits. Data flags and the reason for each flag are entered into an electronic database and made available to data users. A final flag was applied to the data after evaluating all flags entered into the database and selecting the most conservative of the validation flags, as defined by the QAPP.

The data flags are defined as follows:

• J = Analyte is present but the reported value may not be accurate or precise (estimated).

• R = Data are unusable because of deficiencies in the ability to analyze the sample and meet QC criteria.

• U = Analyte was not detected at the specified detection limit.

• UJ = Analyte was not detected and the specified detection limit may not be accurate or precise (estimated).

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In addition, the following flags, which have no QC implications and are not listed in the QAPP, were used:

• Exclude = Data was not used in site assessment; more appropriate data exists for this analyte.

• None = A flag was not applied. This placeholder is for calculating QC criteria issues without flagging.

An assessment of data quality is summarized below for each analytical method. The overall summaries of the data validation findings are contained in tables (located at the end of this appendix) and summarized in the method sections that follow. Both the method sections and the summary tables contain only the instances where QC criteria exceedances affect data qualification, resulting in a validation flag being added to the data.

The following list provides a summary of the table’s contents:

• Table A-1, Overall Flagging Summary. Presents the number of occurrences for each data validation reason by method.

• Table A-2, Holding Times – Qualified Data. Presents data qualified for instances where the method holding time was exceeded.

• Table A-3, Results between the PQL and the MDL – Qualified Data. Presents results that are estimated because the results are between the practical quantitation limit (PQL) and the method detection limit (MDL).

• Table A-4, MDL Exceeds PQL – Qualified Data. Presents instances where the MDL was greater than the QAPP-specified PQL are presented.

• Table A-5, Calibration Criteria – Qualified Data. Presents data qualified because initial or continuing calibration criteria were exceeded.

• Table A-6, Blank Contamination – Qualified Data. Presents data qualified because of blank contamination.

• Table A-7, Field Duplicate Precision – Qualified Data. Presents data qualified because the FD precision exceeded the sampling and analytical expectation defined in the QAPP.

Analyte reproducibility might be subject to site-specific variability of contaminants.

• Table A-8, Blank Spike – Qualified Data. Presents data qualified because of exceedance of LCS recovery criteria in the QAPP.

• Table A-9, Internal Standards – Qualified Data. Presents data qualified because of an internal standard exceeding QAPP criteria.

• Table A-10, Matrix Spike Precision/Accuracy – Qualified Data. Presents data qualified because MS/MSD criteria have been exceeded.

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• Table A-11, Site Completeness by Analyte – Qualified Data. Presents percent completeness by analyte, matrix, and method.

• Table A-12, Sample Summary by CoC – Data Summary. Presents sample identifiers, sample dates, and SDGs sorted by CoC number.

• Table A-13, Sample Chronology – Data Summary. Presents sample identifiers, methods, sample dates, received dates, extraction dates, and analysis dates sorted by SDG number.

A.3 General Comments A.3.1 Low-level Detects Sample results between the MDL and the PQL have been flagged “J” and are shown in Table A-3. These qualified results represent values determined at levels where the true value of the measured chemical could not be quantified with a high degree of confidence.

The laboratory method detection limit levels support the QAPP-specified PQLs. The data user may consider these qualified results as estimates when making project decisions. Data qualified for this reason are not presented below.

A.3.2 Overall Assessment The number and severity of QC check or field procedure failures was minimal considering the size of the dataset. All QAPP completeness goals were met. Out of approximately 2,400 normal and FD data points, two data points were rejected because of QC exceedances (approximately 0.08 percent); approximately 220 detected results (approximately

9.2 percent) and 12 non-detected results (approximately 0.5 percent) were qualified as estimated due to QC exceedances; and approximately 7 results were affected by laboratory or field blank contamination (approximately 0.29 percent). These numbers and the overall completeness of over 99 percent indicate that the completeness goals for the project were met and that the quality of the analytical program and laboratories was sufficient to meet the project quality objectives (DQO).

A.3.3 Method E160.2 (TSS) Holding Time The holding time for sample NW2CSW-0605 was exceeded by 1 day and the result was flagged “UJ.” This qualified result is shown in Table A-2.

Overall Method Assessment The effect of these QC exceedances is negligible on data usability. Overall, this analysis meets the DQOs of the project.

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A.3.4 Method E200.7 (Total and Dissolved Metals) Matrix Spike/Matrix Spike Duplicate One detected water potassium result associated with an MS recovery that exceeded the upper control limit (UCL) was flagged “J” to indicate this result is an estimated concentration and potentially biased high. The result for the affected sample is presented in Table A-10.

Overall Method Assessment The effect of this QC exceedance on data usability is negligible. Overall, this analysis meets the DQOs of the project.

A.3.5 Method E200.8 (Total and Dissolved Metals) Blanks Aluminum and zinc were detected above the PQL in two equipment blanks. In the associated water samples, the detected concentrations were less than that of the blanks.

These results were flagged “U” and considered non-detected. A summary of the affected samples is presented in Table A-6.

Field Duplicates The dissolved barium and zinc results from one water FD pair exceeded the relative percent difference (RPD) criteria. The associated native and FD results were flagged “J” and considered estimated concentrations. A summary of the affected samples is presented in Table A-7.

Matrix Spike/Matrix Spike Duplicate One detected dissolved arsenic result associated with MS/MSD recoveries that exceeded the UCL was flagged “J” to indicate that this result is an estimated concentration and potentially biased high. The result for the affected sample is presented in Table A-10.

Overall Method Assessment The effect of these QC exceedances on data usability is negligible. Overall, this analysis meets the DQOs of the project.

A.3.6 Method E245.1 (Total and Dissolved Mercury) Discrepancy between Total and Dissolved Results The dissolved mercury result was greater than the total mercury result for water sample NW4CSW-0605. Both results were flagged “R” (rejected) for data use (2 of approximately 40;

approximately 5 percent). The result for the affected sample is presented in Table A-10.

Overall Method Assessment The discrepancy between the total and dissolved mercury results has a negligible effect on data completeness and site assessment. Overall, this analysis meets the DQOs of the project.

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A.3.7 Method E415.1 (TOC) Blanks TOC was detected above the PQL in a filter blank associated with four different water samples. In the associated samples, the detected concentrations were less than that of the blanks. These results were flagged “U” and considered non-detected. A summary of the affected samples is presented in Table A-6.

Overall Method Assessment The effect of these QC exceedances is negligible on data usability. Overall, this analysis meets the DQOs of the project.

A.3.8 Method SM2320 (Alkalinity) Holding Time The holding time for water sample NW2CSW-0605 was exceeded by one day and the results were flagged “UJ.” The result for the affected sample is presented in Table A-2.

Overall Method Assessment The effect of this QC exceedance is negligible on data usability. Overall, this analysis meets the DQOs of the project.

A.3.9 Method SW6010B (Total Metals) Matrix Spike/Matrix Spike Duplicate Matrix effects were demonstrated in four soil samples. Multiple analytes were recovered from MS and/or MSDs outside the control limits. Associated detected results were “J” flagged and non-detected results flagged “UJ” to indicate that these results are estimated concentrations and potentially biased. The affected samples are presented in Table A-10.

Overall Method Assessment The effect of these QC exceedances is negligible on data usability. Overall, this analysis meets the DQOs of the project.

A.3.10 Method SW7473 (Total Mercury) Calibration The mercury result for sample NW2CDE-0605 exceeded the linear calibration range and was flagged “J” as an estimated concentration. The affected sample is presented in Table A-5.

Matrix Spike / Matrix Spike Duplicate Matrix effects were demonstrated in three soil samples by MS and/or MSDs recoveries or RPDs outside the control limits. Associated detected results were flagged “J” to indicate that these results are estimated concentrations and potentially biased. The affected samples are presented in Table A-10.

Overall Method Assessment

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The effect of these QC exceedances is negligible on data usability. Overall, this analysis meets the DQOs of the project.

A.3.11 Completeness Table A-11 provides a completeness summary that lists the analytes, the number of samples collected, and completeness calculations for this dataset. Completeness is the number of valid results (not flagged “R”) divided by the number of possible results from all normal and FD samples collected during the sampling event, independent of the reason for rejected data. One hundred percent completeness was attained for this dataset.

The final activity in the data quality evaluation is an assessment of whether the data meet the project DQOs. The goal of this assessment is to demonstrate that a sufficient number of representative samples were collected and the resulting analytical data can be used to support the decision-making process. The precision, accuracy, representativeness, completeness, and comparability (PARCC) are addressed in the QAPP. The following summary highlights the North Wetland data evaluation findings for the previously described events:

1. The completeness objectives were met for all method/analyte combinations.

2. Two data points were rejected for use because of a discrepancy between total and dissolved results.

3. Less than 1 percent of the data is qualified because of low-level blank contamination.

The frequency blank contamination is within reasonable method expectations.

4. The precision and accuracy of the data, as measured by field and laboratory QC indicators, suggest that the QAPP goals have been met.

5. The field crews and laboratories followed guidelines in the QAPP and project documents to assure representativeness and consistency with previous studies.

A.3.12 Quality Assurance Activities Evaluation of 100 percent of the chemical data was performed by using the QAPP as a guide for data quality evaluation. No systematic protocol errors were identified on the basis of the QA program or during the monitoring of the field and laboratory efforts.

A.4 Data Management SBMM sampling activity logs and laboratory analytical data are maintained in a project database and in project files, as appropriate. Data were collected and stored in a manner consistent with the requirements outlined in the QAPP. The data collected include but are not limited to the following:

• Field Data − Daily field progress reports − Field worksheets − Daily field notebooks

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− Sample collection logs − CoC forms

• Laboratory Data − Laboratory data packages grouped by SDG − Internal data evaluation reports for all data

Laboratory data were received in both hardcopy and in electronic, comma-delimited American Standard Code for Information Interchange (ASCII) format. The receipt of both data types was logged into the sample tracking program to determine completeness.

All data validation reports are generated from the electronic database. Final validation flags for global issues, such as matrix interference, are applied after the initial data validation.

These flags are also added to the electronic database and annotated as global flags.

The data management system was designed to maintain the usability and integrity of the data through a series of procedures and QC checks that began at the field site and carried through to generate user data. These data included both the chemical data and field opera-tions information. Chemical data and field information were recorded in a relational database in accordance with the guidelines established in the QAPP and in Environmental Data Management Procedures and Guidelines (CH2M HILL, 1992).

The original, hardcopy laboratory report and electronic data are stored in project files and project local area network server in the CH2M HILL office in Redding, California. The original field data forms are also stored in the CH2M HILL office in Redding, California.

Laboratories are required to archive the analytical data as outlined in the QAPP.

A.5 References CH2M HILL. 2005. Quality Assurance Project Plan for Sulphur Bank Mercury Mine Superfund Site, Clearlake Oaks, California. June.

CH2M HILL. 1992. Environmental Data Management Procedures and Guidelines.

U.S. Environmental Protection Agency (EPA). 2004. Contract Laboratory Program National Functional Guidelines for Inorganic Data Review.

Overall Flagging Summary Table

Data Evaluation Report, 2005 North Wetland Investigation, Sulphur Bank Mercury Mine Superfind Site

A-1

Validation Reason Validation Flag* Flag Type Number of

Affected AnalytesMethod Matrix

E160.2 Water

Holding time exceededHoldingTimeCategory =

UJ Protocol 1 E200.7 Water

Matrix spike recovery greater than upper limitMatrixCategory =

J Other 1 E200.8 Water

Equipment blank concentration greater than the RLBlankCategory =

U Protocol 2 Equipment blank concentration less than the RLBlankCategory =

U Protocol 1 Field duplicate exceeds RPD criteriaFieldDuplicateCategory =

J Other 4 Matrix spike duplicate recovery criteria greater than upper limitMatrixCategory =

J Other 1 Matrix spike recovery greater than upper limitMatrixCategory =

J Other 1 E245.1 Water

Dissolved result greater than total resultMatrixCategory =

R Other 2 E415.1 Water

Laboratory blank contamination greater than the RLBlankCategory =

U Other 4 SM2320 Water

Holding time exceededHoldingTimeCategory =

UJ Protocol 4

March 2006 Page 1 of 21Table epyT galF*galF noitadilaVnosaeR noitadilaV Number of

Affected AnalytesMethod Matrix

SW6010B SOIL

Matrix spike duplicate recovery criteria greater than upper limitMatrixCategory =

J Other 3 Matrix spike duplicate recovery criteria less than lower limitMatrixCategory =

UJ Other 6 J Other 9

Matrix spike recovery greater than upper limitMatrixCategory =

J Other 3 Matrix spike recovery less than lower limitMatrixCategory =

UJ Other 7 J Other 11

SW7473 SOIL

Result greater than linear calibration rangeCalibrationCategory =

J Other 1 Matrix spike duplicate recovery criteria greater than upper limitMatrixCategory =

J Other 1 Matrix spike recovery greater than upper limitMatrixCategory =

J Other 2 Matrix spike recovery less than lower limitMatrixCategory =

J Other 1 Matrix spike RPD criteria exceedanceMatrixCategory =

J Other 1

Qualifier Description:

J = The result is an estimated concentration.

R = The data are unusable.

U = Analyte not detected above quantitation limit.

UJ = Analyte not detected;quantitation limit approx.

Flag Type: Protocol = Flagging due to contractor/laboratory protocol violations Other = Flagging due to sample, matrix, or field issues not related to QAPP or SAP protocol

* The most severe flag for each analyte becomes the final validation flag

March 2006 Page 2 of 21Table

Overall Flagging Summary Table

Data Evaluation Report, 2005 North Wetland Investigation, Sulphur Bank Mercury Mine Superfind Site

A-1

Holding Times - Qualified Data Table

Data Evaluation Report, 2005 North Wetland Investigation, Sulphur Bank Mercury Mine Superfund Site

A-2

Method Matrix Analyte Result Holding Time QualifierSample ID Final Flag*Holding time

E160.2 Water NW2CSW-0605

5 MG/L UJTotal Suspended Solids UJ8 Days

SM2320 Water NW2CSW-0605

10 MG/L UJBicarbonate Alkalinity UJ15 Days 10 MG/L UJCarbonate Alkalinity UJ15 Days 10 MG/L UJHydroxide Alkalinity UJ15 Days 10 MG/L UJTotal Alkalinity UJ15 Days

Qualifier Description:

UJ = Analyte not detected;quantitation limit approx.

* The most severe flag for each analyte becomes the final validation flag

Criteria:

HTa>UCL Holding time exceeded=

March 2006 Page 1 of 12Table

Results between the PQL and MDL - Qualified Data Table A-3

Data Evaluation Report, 2005 North Wetland Investigation, Sulphur Bank Mercury Mine Superfund Site

Method Matrix Analyte Result Low Level Detects Final Qualifier*Sample ID Criteria

E160.2 Water

Total Suspended Solids

5 MG/L JNW3ASW-0605 < RL

E1630 WATER

Hg(Monomethyl)

0.025 NG/L JNW3ASW-0605 T < RL

E200.7 Water

Iron

76 UG/L JNW1ASW-0605RE2 < RL

62 UG/L JNW3CSW-0605RE2 < RL

68 UG/L JNW6ASW-0605RE2 < RL

72 UG/L JNW6CSW-0605RE2 < RL

Iron, dissolved 57 UG/L JNW1ASW-0605 FilteredRE2 < RL 51 UG/L JNW2CSW-0605 FilteredRE2 < RL

E200.8 Water

Aluminum

13 UG/L JNW1BSW-0605 < RL

15 UG/L JNW5ASW-0605RE3 < RL

20 UG/L UNW6ASW-0605RE3 < RL

20 UG/L UNW6CSW-0605 < RL

Arsenic

0.75 UG/L JNW15CSW-0605RE < RL

0.64 UG/L JNW1ASW-0605RE < RL

0.62 UG/L JNW1CSW-0605RE < RL

0.54 UG/L JNW4CSW-0605RE < RL

0.53 UG/L JNW5ASW-0605RE < RL

0.83 UG/L JNW5CSW-0605RE < RL

0.56 UG/L JNW6ASW-0605RE < RL

0.78 UG/L JNW6BSW-0605RE < RL

Arsenic, dissolved

0.6 UG/L JNW15CSW-0605 FiltereRE < RL

0.54 UG/L JNW2CSW-0605 FilteredRE < RL

March 2006 Page 1 of 73Table

*reifilauQ laniF stceteD leveL woLtluseRetylanAxirtaMdohteM Sample ID Criteria

JL/GU 15.0 LR <ERderetliF 5060-WSA3WN JL/GU 75.0 LR <ERderetliF 5060-WSB3WN JL/GU 85.0 LR <ERderetliF 5060-WSC3WN JL/GU 75.0 LR <ERderetliF 5060-WSA5WN JL/GU 65.0 LR <ERderetliF 5060-WSB5WN JL/GU 7.0 LR <ERderetliF 5060-WSC5WN JL/GU 35.0 LR <ERderetliF 5060-WSA6WN JL/GU 68.0 LR <ERderetliF 5060-WSB6WN

Beryllium, dissolved JL/GU 6.3 LR <2LDderetliF 5060-WSA2WN JL/GU 7.3 LR <2LDderetliF 5060-WSB2WN JL/GU 8.3 LR <2LDderetliF 5060-WSC2WN JL/GU 3.3 LR <2LDderetliF 5060-WSA3WN JL/GU 1.3 LR <2LDderetliF 5060-WSB3WN JL/GU 9.2 LR <2LDderetliF 5060-WSC3WN JL/GU 73.0 LR <4ERderetliF 5060-WSC4WN

Cadmium

JL/GU 48.0NW2ASW-0605 < RL

JL/GU 39.0NW2BSW-0605 < RL

JL/GU 99.0NW3ASW-0605 < RL

JL/GU 19.0NW3BSW-0605 < RL

JL/GU 49.0NW3CSW-0605 < RL

JL/GU 6.0NW4BSW-0605 < RL

JL/GU 95.0NW4CSW-0605 < RL

JL/GU 65.0NW6BSW-0605 < RL

Cadmium, dissolved JL/GU 36.0 LR <deretliF 5060-WSA2WN JL/GU 17.0 LR <deretliF 5060-WSB2WN JL/GU 89.0 LR <deretliF 5060-WSC2WN JL/GU 19.0 LR <deretliF 5060-WSA3WN JL/GU 19.0 LR <deretliF 5060-WSB3WN JL/GU 77.0 LR <deretliF 5060-WSC3WN

Chromium

JL/GU 95.0NW2ASW-0605RE2 < RL

Cobalt, dissolved JL/GU 84.0 LR <deretliF 5060-WSA1WN JL/GU 53.0 LR <deretliF 5060-WSC1WN JL/GU 14.0 LR <deretliF 5060-WSB5WN

March 2006 Page 2 of 73Table

Results between the PQL and MDL - Qualified Data

Data Evaluation Report, 2005 North Wetland Investigation, Sulphur Bank Mercury Mine Superfund Site

Copper

JL/GU 1.1 LR <3ER5060-WSA41WN

JL/GU 1.1NW1CSW-0605 < RL

JL/GU 5.1NW2ASW-0605RE3 < RL

JL/GU 8.1NW2BSW-0605RE3 < RL

JL/GU 5.1 LR <3ER5060-WSC2WN

JL/GU 5.1NW3ASW-0605RE3 < RL

JL/GU 3.1NW3BSW-0605RE3 < RL

JL/GU 3.1 LR <3ER5060-WSC3WN

JL/GU 8.1NW4ASW-0605RE3 < RL

JL/GU 1.1NW4BSW-0605RE3 < RL

JL/GU 3.1 LR <3ER5060-WSC4WN

JL/GU 1 LR <3ER5060-WSC6WN

Copper, dissolved JL/GU 3.1 LR <3EReretliF 5060-WSA41WN JL/GU 7.1 LR <3ERderetliF 5060-WSA2WN JL/GU 8.1 LR <3ERderetliF 5060-WSB2WN JL/GU 8.1 LR <3ERderetliF 5060-WSC2WN JL/GU 1 LR <3ERderetliF 5060-WSA3WN JL/GU 1 LR <3ERderetliF 5060-WSB3WN JL/GU 3.1 LR <3ERderetliF 5060-WSC3WN JL/GU 3.1 LR <3ERderetliF 5060-WSB4WN

Molybdenum

JL/GU 62.0NW1ASW-0605 < RL

JL/GU 3.0NW6BSW-0605 < RL

Selenium

JL/GU 88.0NW14ASW-0605 < RL

JL/GU 67.0NW1ASW-0605 < RL

JL/GU 6.0NW1BSW-0605 < RL

JL/GU 85.0NW1CSW-0605 < RL

JL/GU 69.0NW4ASW-0605 < RL

JL/GU 57.0NW4BSW-0605 < RL

JL/GU 67.0NW4CSW-0605 < RL

JL/GU 5.0NW6ASW-0605 < RL

JL/GU 37.0NW6BSW-0605 < RL

JL/GU 86.0NW6CSW-0605 < RL

Zinc

JL/GU 5.2 LR <3ER5060-WSC51WN

March 2006 Page 3 of 73Table

Results between the PQL and MDL - Qualified Data

JL/GU 9.3NW5ASW-0605RE3 < RL

UL/GU 3NW6CSW-0605 < RL

Zinc, dissolved JL/GU 4.3 LR <deretliF 5060-WSA1WN JL/GU 6.2 LR <deretliF 5060-WSB6WN JL/GU 6.2 LR <deretliF 5060-WSC6WN

E245.1 Water

Mercury, dissolved JL/GU 20.0 LR <deretliF 5060-WSA41WN JL/GU 620.0 LR <deretliF 5060-WSA3WN JL/GU 910.0 LR <deretliF 5060-WSB3WN

E300 Water

Bromide

JL/GM 70.0NW15CSW-0605 < RL

JL/GM 60.0NW1ASW-0605 < RL

JL/GM 50.0NW1BSW-0605 < RL

JL/GM 70.0NW5ASW-0605 < RL

JL/GM 50.0NW5BSW-0605 < RL

JL/GM 50.0NW5CSW-0605 < RL

JL/GM 70.0NW6ASW-0605 < RL

JL/GM 60.0NW6BSW-0605 < RL

JL/GM 70.0NW6CSW-0605 < RL

SM2320 Water

Bicarbonate Alkalinity

JL/GM 1.6NW14ASW-0605 < RL

JL/GM 1.7NW4ASW-0605 < RL

JL/GM 1.7NW4BSW-0605 < RL

JL/GM 6.7NW4CSW-0605 < RL

Total Alkalinity

JL/GM 1.6NW14ASW-0605 < RL

JL/GM 1.7NW4ASW-0605 < RL

JL/GM 1.7NW4BSW-0605 < RL

JL/GM 6.7NW4CSW-0605 < RL

SW6010B SOIL

Arsenic

JGK/GM 2.2 LR <4ER5060-DSC51WN

JGK/GM 9.4NW2ADE-0605RE4 < RL

March 2006 Page 4 of 73Table

Results between the PQL and MDL - Qualified Data

JGK/GM 6.9NW4CDE-0605RE5 < RL

JGK/GM 21NW5BDE-0605RE < RL

JGK/GM 4.2NW5CDE-0605RE4 < RL

JGK/GM 5.6NW6BDE-0605RE4 < RL

JGK/GM 6.4NW6CSD-0605RE6 < RL

Beryllium

JGK/GM 13.0NW3ASD-0605RE5 < RL

JGK/GM 13.0NW3BSD-0605RE5 < RL

Cobalt

JGK/GM 21 LR <2ER5060-EDA41WN

JGK/GM 7.4NW1ASD-0605RE2 < RL

JGK/GM 2.6NW3ASD-0605RE2 < RL

JGK/GM 8.7NW3BSD-0605RE2 < RL

JGK/GM 31NW4ADE-0605RE2 < RL

JGK/GM 21NW4BDE-0605RE < RL

JGK/GM 32NW4CDE-0605RE < RL

JGK/GM 55NW5BDE-0605DL2 < RL

Copper

JGK/GM 22 LR <2LD5060-DSA41WN

JGK/GM 32 LR <2LD5060-EDC51WN

JGK/GM 12NW1BDE-0605RE < RL

JGK/GM 1.9NW1BSD-0605RE2 < RL

JGK/GM 43NW1CDE-0605RE < RL

JGK/GM 9.7NW1CSD-0605RE2 < RL

JGK/GM 51NW2ASD-0605RE < RL

JGK/GM 61NW2BDE-0605RE < RL

JGK/GM 11NW2BSD-0605RE < RL

JGK/GM 81NW4ASD-0605RE < RL

JGK/GM 4.9NW4BSD-0605RE < RL

JGK/GM 61NW4CSD-0605RE < RL

JGK/GM 05NW6CDE-0605RE < RL

JGK/GM 51NW6CSD-0605RE4 < RL

Lead

JGK/GM 8.4 LR <4ER5060-DSC51WN

JGK/GM 3.6NW1ADE-0605RE6 < RL

JGK/GM 8NW1CDE-0605RE6 < RL

JGK/GM 8.6NW2CDE-0605RE4 < RL

JGK/GM 9.3NW5BSD-0605RE4 < RL

March 2006 Page 5 of 73Table

Results between the PQL and MDL - Qualified Data

JGK/GM 4.4NW5CDE-0605RE4 < RL

JGK/GM 5.4NW5CSD-0605RE4 < RL

JGK/GM 01NW6ADE-0605RE7 < RL

JGK/GM 1.4NW6ASD-0605RE7 < RL

Nickel

JGK/GM 63 LR <2ER5060-EDA41WN

JGK/GM 14NW4ADE-0605RE2 < RL

JGK/GM 13NW4BDE-0605RE < RL

JGK/GM 45NW4CDE-0605RE < RL

Potassium

JGK/GM 0062 LR <2LD5060-DSA41WN

JGK/GM 0042 LR <2LD5060-EDC51WN

JGK/GM 0042NW1BDE-0605RE < RL

JGK/GM 0023NW1CDE-0605RE < RL

JGK/GM 0081NW1CSD-0605RE < RL

JGK/GM 0091NW2ADE-0605RE < RL

JGK/GM 0081NW2ASD-0605RE < RL

JGK/GM 0041NW2BDE-0605RE < RL

JGK/GM 0051NW2BSD-0605RE < RL

JGK/GM 0012NW2CDE-0605RE < RL

JGK/GM 0071NW2CSD-0605RE < RL

JGK/GM 0002NW3ADE-0605RE < RL

JGK/GM 0091NW3BSD-0605RE < RL

JGK/GM 0052NW4ASD-0605RE < RL

Selenium

JGK/GM 6.2NW14ASD-0605RE < RL

JGK/GM 5.4NW1BDE-0605RE6 < RL

JGK/GM 21NW5ADE-0605RE4 < RL

Sodium

JGK/GM 054 LR <2LD5060-EDC51WN

JGK/GM 024NW4ADE-0605RE < RL

JGK/GM 093NW4BDE-0605 < RL

JGK/GM 096NW4CDE-0605 < RL

JGK/GM 013NW6BDE-0605RE < RL

Vanadium

JGK/GM 63NW5BDE-0605DL2 < RL

SW7473 Tissue

Mercury

March 2006 Page 6 of 73Table

Results between the PQL and MDL - Qualified Data

JGK/GM 440.0NW5SN-0605 < RL

Qualifier Description:

J = The result is an estimated concentration.

U = Analyte not detected above quantitation limit.

* The most severe flag for each analyte becomes the final validation flag

March 2006 Page 7 of 73Table

Results between the PQL and MDL - Qualified Data

MDL Exceeds PQL- Qualified Data Table A-4

Data Evaluation Report, 2005 North Wetland Investigation, Sulphur Bank Mercury Mine Superfund Site

Method Matrix Analyte Result QualifierSample ID Criteria

No qualified data

March 2006 Page 1 of 14Table

Calibration Criteria - Qualified Data Table A-5

Data Evaluation Report, 2005 North Wetland Investigation, Sulphur Bank Mercury Mine Superfund Site

Method Matrix Analyte Result Calibration Qualifier*Sample ID Criteria

SW7473 SOIL Mercury

75 MG/KG JNW2CDE-0605 >ICLinearRange

Criteria:

>ICLinearRa Result greater than linear calibration range=

Qualifier Description:

J = The result is an estimated concentration.

March 2006 Page 1 of 15Table

Blank Contamination - Qualified Data Table A-6

Data Evaluation Report, 2005 North Wetland Investigation, Sulphur Bank Mercury Mine Superfund Site

Method Matrix Analyte Result Blank Contamination

Qualifier*Sample ID Criteria Comments

E200.8 Water Aluminum

20 UG/L UNW6ASW-0605 EB>RL blank target = 30UG/L 20 UG/L UNW6CSW-0605 EB>RL blank target = 30UG/L

E200.8 Water Zinc

3 UG/L UNW6CSW-0605 EB<RL blank target = 3.4UG/L E415.1 Water Total Organic Carbon

13 MG/L UNW1BSW-0605 LB>RL

13 MG/L UNW1CSW-0605 LB>RL

4.2 MG/L UNW2ASW-0605 LB>RL

4.6 MG/L UNW2BSW-0605 LB>RL

Criteria:

EB<RL Equipment blank concentration less than the RL= EB>RL Equipment blank concentration greater than the RL= LB>RL Laboratory blank contamination greater than the RL=

Qualifier Description:

U = Analyte not detected above quantitation limit.

March 2006 Page 1 of 16Table

Field Duplicate Precision - Qualified Data Table A-7

Data Evaluation Report, 2005 North Wetland Investigation, Sulphur Bank Mercury Mine Superfund Site

Method Matrix Analyte Result Field Duplicate Qualifier*Sample ID Criteria

E200.8 Water Barium, dissolved

12 UG/L JNW15CSW-0605 FD>RPD

17 UG/L JNW5CSW-0605 FD>RPD

E200.8 Water Zinc

2.5 UG/L JNW15CSW-0605 FD>RPD

17 UG/L JNW5CSW-0605 FD>RPD

Criteria:

FD>RPD Field duplicate exceeds RPD criteria=

Qualifier Description:

J = The result is an estimated concentration.

March 2006 Page 1 of 17Table

Blank Spike - Qualified Data Table A-8

Data Evaluation Report, 2005 North Wetland Investigation, Sulphur Bank Mercury Mine Superfund Site

Method Matrix Analyte Result Qualifier*Sample ID / QC Type CriteriaLCS Recovery

No data qualified

Sample ID / Type = Field Sample Identifier and QAQC Type

March 2006 Page 1 of 18Table

Internal Standards - Qualified Data Table A-9

Data Evaluation Report, 2005 North Wetland Investigation, Sulphur Bank Mercury Mine Superfund Site

Method Matrix Analyte Result Internal Standard Qualifier*Sample ID Criteria

No data qualified

March 2006 Page 1 of 19Table

Matrix Spike Precision/Accuracy - Qualified Data Table A-10

Data Evaluation Report, 2005 North Wetland Investigation, Sulphur Bank Mercury Mine Superfund Site

Method Matrix Analyte Result MS/MSD Qualifier*Sample ID Criteria

E200.7 Water Potassium

8200 UG/L JNW6ASW-0605 MS>UCL

E200.8 Water Arsenic, dissolved

0.7 UG/L JNW5CSW-0605 MS>UCL

0.7 UG/L JNW5CSW-0605 SD>UCL

E245.1 Water Mercury

0.015 UG/L RNW4CSW-0605 Diss>Total

E245.1 Water Mercury, dissolved

0.17 UG/L RNW4CSW-0605 Diss>Total

SW6010B SOIL Aluminum

36000 MG/KG JNW5CDE-0605 MS<LCL

SW6010B SOIL Antimony

28 MG/KG UJNW3ADE-0605 MS<LCL

28 MG/KG UJNW3ADE-0605 SD<LCL

23 MG/KG UJNW5CDE-0605 MS<LCL

23 MG/KG UJNW5CDE-0605 SD<LCL

16 MG/KG UJNW5CSD-0605 MS<LCL

16 MG/KG UJNW5CSD-0605 SD<LCL

97 MG/KG UJNW6CDE-0605 MS<LCL

97 MG/KG UJNW6CDE-0605 SD<LCL

SW6010B SOIL Barium

540 MG/KG JNW5CDE-0605 MS<LCL

530 MG/KG JNW5CSD-0605 SD<LCL

680 MG/KG JNW6CDE-0605 MS<LCL

680 MG/KG JNW6CDE-0605 SD<LCL

SW6010B SOIL Beryllium

12 MG/KG JNW6CDE-0605 MS<LCL

SW6010B SOIL Boron

660 MG/KG JNW6CDE-0605 MS>UCL

660 MG/KG JNW6CDE-0605 SD>UCL

March 2006 Page 1 of 310Table

*reifilauQ DSM/SMtluseRetylanAxirtaMdohteM Sample ID Criteria

SW6010B SOIL Chromium

JGK/GM 56NW5CDE-0605 MS<LCL

JGK/GM 38NW6CDE-0605 MS>UCL

JGK/GM 38NW6CDE-0605 SD>UCL

SW6010B SOIL Cobalt

JGK/GM 19NW3ADE-0605 SD<LCL

SW6010B SOIL Copper

JGK/GM 13NW3ADE-0605 MS<LCL

JGK/GM 13NW3ADE-0605 SD<LCL

JGK/GM 05NW6CDE-0605 MS>UCL

JGK/GM 05NW6CDE-0605 SD>UCL

SW6010B SOIL Lead

JUGK/GM 51NW6CDE-0605 MS<LCL

JUGK/GM 51NW6CDE-0605 SD<LCL

SW6010B SOIL Magnesium

JGK/GM 00031NW3ADE-0605 SD<LCL

JGK/GM 00041NW5CDE-0605 MS<LCL

SW6010B SOIL Manganese

JGK/GM 0061NW5CDE-0605 MS<LCL

SW6010B SOIL Nickel

JGK/GM 041NW3ADE-0605 SD<LCL

SW6010B SOIL Potassium

JGK/GM 0002NW3ADE-0605 SD<LCL

JGK/GM 0092NW5CDE-0605 MS<LCL

SW6010B SOIL Selenium

JGK/GM 72NW6CDE-0605 MS<LCL

JGK/GM 72NW6CDE-0605 SD<LCL

SW6010B SOIL Silver

JUGK/GM 7.9NW6CDE-0605 MS<LCL

SW6010B SOIL Thallium

JUGK/GM 41NW3ADE-0605 MS<LCL

JUGK/GM 41NW3ADE-0605 SD<LCL

SW6010B SOIL Zinc

JGK/GM 062NW3ADE-0605 MS<LCL

March 2006 Page 2 of 310Table

Matrix Spike Precision/Accuracy - Qualified Data

*reifilauQ DSM/SMtluseRetylanAxirtaMdohteM Sample ID Criteria

JGK/GM 062NW3ADE-0605 SD<LCL

SW7473 SOIL Mercury

JGK/GM 22NW3ADE-0605 MS<LCL

JGK/GM 22NW3ADE-0605 MSRPD

JGK/GM 4NW5CDE-0605 MS>UCL

JGK/GM 2.3NW5CSD-0605 MS>UCL

JGK/GM 2.3NW5CSD-0605 SD>UCL

Criteria:

Diss>Total Dissolved result greater than total result= MS<LCL Matrix spike recovery less than lower limit= MS>UCL Matrix spike recovery greater than upper limit= MSRPD Matrix spike RPD criteria exceedance= SD<LCL Matrix spike duplicate recovery criteria less than lower limit= SD>UCL Matrix spike duplicate recovery criteria greater than upper limit=

Qualifier Description:

J = The result is an estimated concentration.

R = The data are unusable.

UJ = Analyte not detected;quantitation limit approx.

* The most severe flag for each analyte becomes the final validation flag

March 2006 Page 3 of 310Table

Matrix Spike Precision/Accuracy - Qualified Data

Sample Summary by COC - Data Summary Table A-12

Data Evaluation Report, 2005 North Wetland Investigation, Sulphur Bank Mercury Mine Superfund Site

COC Number Matrix SampleID (Type)Sample Date SDG Lab

EPA9-060501 29-Jun-05

WATER

NW-AB060501 ( AB) 05BR0969 BRL

NW-TB060501 ( TB) 05BR0969 BRL

EPA9-060502 27-Jun-05

WATER

B5G0062-MS1 ( MS) 05179A EPAR9

B5G0062-MS2 ( MS) 05179A EPAR9

B5G0062-MS3 ( MS) 05179A EPAR9

B5G0062-MS4 ( MS) 05179A EPAR9

B5G0062-MSD1 ( SD) 05179A EPAR9

B5G0062-MSD2 ( SD) 05179A EPAR9

B5G0062-MSD3 ( SD) 05179A EPAR9

B5G0062-MSD4 ( SD) 05179A EPAR9

B5G0065-MS1 ( MS) 05179A EPAR9

B5G0065-MS2 ( MS) 05179A EPAR9

B5G0065-MSD1 ( SD) 05179A EPAR9

B5G0065-MSD2 ( SD) 05179A EPAR9

NW14ASW-0605 ( FD) 05179A EPAR9

NW15ASW-0605 ( FD) 05BR0969 BRL

NW15CSW-0605 ( FD) 05179A EPAR9

NW1ASW-0605 ( FD) 05179A EPAR9

NW1ASW-0605 ( N) 05179A EPAR9

NW1ASW-0605 ( N) 05BR0969 BRL

NW1BSW-0605 ( MS) 05179A EPAR9

NW1BSW-0605 ( N) 05179A EPAR9

NW1BSW-0605 ( SD) 05179A EPAR9

NW1CSW-0605 ( MS) 05179A EPAR9

NW1CSW-0605 ( N) 05179A EPAR9

NW1CSW-0605 ( SD) 05179A EPAR9

NW1CSW-0605MS ( MS) 05179A EPAR9

March 2006 Page 1 of 512Table

)epyT( DIelpmaSxirtaMrebmuN COC baLGDSetaD elpmaS

EPA9-060502 27-Jun-05

WATER

NW1CSW-0605SD ( SD) 05179A EPAR9

NW2ASW-0605 ( MS) 05179A EPAR9

NW2ASW-0605 ( N) 05179A EPAR9

NW2ASW-0605 ( N) 05BR0969 BRL

NW2ASW-0605 ( SD) 05179A EPAR9

NW2BSW-0605 ( N) 05179A EPAR9

NW2CSW-0605 ( N) 05179A EPAR9

NW3ASW-0605 ( N) 05179A EPAR9

NW3ASW-0605 ( N) 05BR0969 BRL

NW3BSW-0605 ( N) 05179A EPAR9

NW3CSW-0605 ( N) 05179A EPAR9

NW4ASW-0605 ( MS) 05179A EPAR9

NW4ASW-0605 ( N) 05179A EPAR9

NW4ASW-0605 ( SD) 05179A EPAR9

NW4BSW-0605 ( N) 05179A EPAR9

NW4CSW-0605 ( N) 05179A EPAR9

NW4CSW-0605 ( N) 05BR0969 BRL

NW5ASW-0605 ( N) 05179A EPAR9

NW5ASW-0605 ( N) 05BR0969 BRL

NW5BSW-0605 ( N) 05179A EPAR9

NW5CSW-0605 ( MS) 05179A EPAR9

NW5CSW-0605 ( N) 05179A EPAR9

NW5CSW-0605 ( SD) 05179A EPAR9

NW5CSW-0605MS ( MS) 05179A EPAR9

NW5CSW-0605SD ( SD) 05179A EPAR9

NW6ASW-0605 ( N) 05179A EPAR9

NW6ASW-0605 ( N) 05BR0969 BRL

NW6ASW-0605MS ( MS) 05179A EPAR9

NW6ASW-0605SD ( SD) 05179A EPAR9

NW6BSW-0605 ( MS) 05179A EPAR9

NW6BSW-0605 ( N) 05179A EPAR9

NW6BSW-0605 ( SD) 05179A EPAR9

NW6CSW-0605 ( N) 05179A EPAR9

NW6CSW-0605MS ( MS) 05179A EPAR9

NW6CSW-0605SD ( SD) 05179A EPAR9

March 2006 Page 2 of 512Table

Sample Summary by COC - Data Summary

EPA9-060502 27-Jun-05

WATER

NW-AB060502 ( AB) 05BR0969 BRL

NW-TB060502 ( TB) 05BR0969 BRL

EPA9-060503 30-Jun-05

SOIL

B5G0086-MS1 ( MS) 05188A EPAR9

B5G0086-MSD1 ( SD) 05188A EPAR9

NW14ADE-0605 ( FD) 05182A EPAR9

NW14ASD-0605 ( FD) 05182A EPAR9

NW15CDE-0605 ( FD) 05182B EPAR9

NW15CSD-0605 ( FD) 05182B EPAR9

NW15DE-0605 ( FD) 05BR0969 BRL

NW15SD-0605 ( FD) 05BR0969 BRL

NW1ADE-0605 ( N) 05182B EPAR9

NW1ASD-0605 ( N) 05182B EPAR9

NW1BDE-0605 ( N) 05182B EPAR9

NW1BSD-0605 ( N) 05182B EPAR9

NW1CDE-0605 ( N) 05182B EPAR9

NW1CSD-0605 ( N) 05182B EPAR9

NW1DE-0605 ( N) 05BR0969 BRL

NW1SD-0605 ( N) 05BR0969 BRL

NW2ADE-0605 ( N) 05182B EPAR9

NW2ASD-0605 ( N) 05182B EPAR9

NW2BDE-0605 ( N) 05182B EPAR9

NW2BSD-0605 ( N) 05182B EPAR9

NW2CDE-0605 ( N) 05182B EPAR9

NW2CSD-0605 ( N) 05182B EPAR9

NW2DE-0605 ( N) 05BR0969 BRL

NW2SD-0605 ( N) 05BR0969 BRL

NW3ADE-0605 ( N) 05182A EPAR9

NW3ADE-0605MS ( MS) 05182A EPAR9

NW3ADE-0605SD ( SD) 05182A EPAR9

NW3ASD-0605 ( N) 05182A EPAR9

NW3BDE-0605 ( N) 05182A EPAR9

NW3BSD-0605 ( N) 05182A EPAR9

March 2006 Page 3 of 512Table

Sample Summary by COC - Data Summary

EPA9-060503 30-Jun-05

SOIL

NW3CDE-0605 ( N) 05182A EPAR9

NW3CSD-0605 ( N) 05182A EPAR9

NW3DE-0605 ( N) 05BR0969 BRL

NW3SD-0605 ( N) 05BR0969 BRL

NW4ADE-0605 ( N) 05182A EPAR9

NW4ASD-0605 ( N) 05182A EPAR9

NW4BDE-0605 ( N) 05182A EPAR9

NW4BSD-0605 ( N) 05182A EPAR9

NW4CDE-0605 ( N) 05182A EPAR9

NW4CSD-0605 ( N) 05182A EPAR9

NW4DE-0605 ( N) 05BR0969 BRL

NW4SD-0605 ( N) 05BR0969 BRL

NW5ADE-0605 ( N) 05182B EPAR9

NW5ASD-0605 ( N) 05182B EPAR9

NW5BDE-0605 ( N) 05182B EPAR9

NW5BSD-0605 ( N) 05182B EPAR9

NW5CDE-0605 ( MS) 05182B EPAR9

NW5CDE-0605 ( N) 05182B EPAR9

NW5CDE-0605 ( SD) 05182B EPAR9

NW5CSD-0605 ( MS) 05182B EPAR9

NW5CSD-0605 ( N) 05182B EPAR9

NW5CSD-0605 ( SD) 05182B EPAR9

NW5DE-0605 ( N) 05BR0969 BRL

NW5DE-MS0605 ( MS) 05BR0969 BRL

NW5DE-SD0605 ( SD) 05BR0969 BRL

NW5SD-0605 ( N) 05BR0969 BRL

NW5SD-MS0605 ( MS) 05BR0969 BRL

NW5SD-SD0605 ( SD) 05BR0969 BRL

NW6ADE-0605 ( N) 05188A EPAR9

NW6ASD-0605 ( N) 05188A EPAR9

NW6BDE-0605 ( N) 05188A EPAR9

NW6BSD-0605 ( N) 05188A EPAR9

NW6CDE-0605 ( N) 05188A EPAR9

NW6CDE-0605MS ( MS) 05188A EPAR9

NW6CDE-0605SD ( SD) 05188A EPAR9

March 2006 Page 4 of 512Table

Sample Summary by COC - Data Summary

EPA9-060503 30-Jun-05

SOIL

NW6CSD-0605 ( N) 05188A EPAR9

NW6DE-0605 ( N) 05BR0969 BRL

NW6SD-0605 ( N) 05BR0969 BRL

TISSUE

NW1BB-0605 ( N) 05BR0969 BRL

NW1BG-0605 ( N) 05188B EPAR9

NW1BG-0605 ( N) 05BR0969 BRL

NW1BT-0605 ( N) 05188B EPAR9

NW1BT-0605 ( N) 05BR0969 BRL

NW1SN-0605 ( N) 05188B EPAR9

NW1SN-0605 ( N) 05BR0969 BRL

NW2MI-0605 ( N) 05188B EPAR9

NW2MI-0605 ( N) 05BR0969 BRL

NW3MI-0605 ( N) 05BR0969 BRL

NW4BM-0605 ( N) 05188B EPAR9

NW4MI-0605 ( N) 05BR0969 BRL

NW5BM-0605 ( N) 05188B EPAR9

NW5BT-0605 ( N) 05188B EPAR9

NW5BT-0605 ( N) 05BR0969 BRL

NW5SN-0605 ( N) 05188B EPAR9

NW5SN-0605 ( N) 05BR0969 BRL

NW6BM-0605 ( N) 05188B EPAR9

NW6BT-0605 ( N) 05188B EPAR9

NW6BT-0605 ( N) 05BR0969 BRL

NW6MI-0605 ( N) 05188B EPAR9

NW6MI-0605 ( N) 05BR0969 BRL

NW6SN-0605 ( N) 05BR0969 BRL

WATER

Filter Blank 6/29 ( EB) 05BR0969 BRL Filter Blank 6/30 ( EB) 05BR0969 BRL

NW-EB060501 ( EB) 05179A EPAR9

NW-EB060501 ( EB) 05BR0969 BRL

NW-TB060503 ( TB) 05BR0969 BRL

March 2006 Page 5 of 512Table

Sample Summary by COC - Data Summary

Sample Chronology - Data Summary Table A-13

Data Evaluation Report, 2005 North Wetland Investigation, Sulphur Bank Mercury Mine Superfund Site

Lab Name/ Package Number SampleID Method Sample Date ReceiveDate ExtractDate AnalysisDate

B5G0062-MS1 E245.1 7/14/2005 7/14/2005 7/14/2005 7/15/200505179AEPAR9

B5G0062-MS2 E245.1 7/14/2005 7/14/2005 7/14/2005 7/15/2005

B5G0062-MS3 E245.1 7/14/2005 7/14/2005 7/14/2005 7/15/2005

B5G0062-MS4 E245.1 7/14/2005 7/14/2005 7/14/2005 7/15/2005

B5G0062-MSD1 E245.1 7/14/2005 7/14/2005 7/14/2005 7/15/2005

B5G0062-MSD2 E245.1 7/14/2005 7/14/2005 7/14/2005 7/15/2005

B5G0062-MSD3 E245.1 7/14/2005 7/14/2005 7/14/2005 7/15/2005

B5G0062-MSD4 E245.1 7/14/2005 7/14/2005 7/14/2005 7/15/2005

B5G0065-MS1 E245.1 7/14/2005 7/14/2005 7/14/2005 7/15/2005

B5G0065-MS2 E245.1 7/14/2005 7/14/2005 7/14/2005 7/15/2005

B5G0065-MSD1 E245.1 7/14/2005 7/14/2005 7/14/2005 7/15/2005

B5G0065-MSD2 E245.1 7/14/2005 7/14/2005 7/14/2005 7/15/2005

NW14ASW-0605 E160.1 6/28/2005 6/29/2005 6/30/2005 6/30/2005

NW14ASW-0605 E160.2 6/28/2005 6/29/2005 7/5/2005 7/5/2005

NW14ASW-0605 E200.7 6/28/2005 6/29/2005 7/5/2005 8/25/2005

NW14ASW-0605 E200.7 6/28/2005 6/29/2005 7/5/2005 8/26/2005

NW14ASW-0605 E200.7 6/28/2005 6/29/2005 7/5/2005 8/27/2005

NW14ASW-0605 E200.7 6/28/2005 6/29/2005 7/5/2005 8/29/2005

NW14ASW-0605 E200.8 6/28/2005 6/29/2005 7/5/2005 7/18/2005

NW14ASW-0605 E200.8 6/28/2005 6/29/2005 7/5/2005 7/25/2005

NW14ASW-0605 E200.8 6/28/2005 6/29/2005 7/5/2005 8/1/2005

NW14ASW-0605 E200.8 6/28/2005 6/29/2005 7/5/2005 8/2/2005

NW14ASW-0605 E200.8 6/28/2005 6/29/2005 7/5/2005 8/3/2005

NW14ASW-0605 E200.8 6/28/2005 6/29/2005 7/5/2005 8/4/2005

NW14ASW-0605 E200.8 6/28/2005 6/29/2005 7/5/2005 8/5/2005

NW14ASW-0605 E200.8 6/28/2005 6/29/2005 7/5/2005 8/10/2005

NW14ASW-0605 E200.8 6/28/2005 6/29/2005 7/5/2005 8/11/2005

NW14ASW-0605 E200.8 6/28/2005 6/29/2005 7/5/2005 8/19/2005

NW14ASW-0605 E245.1 6/28/2005 6/29/2005 7/14/2005 7/15/2005

NW14ASW-0605 E300 6/28/2005 6/29/2005 6/29/2005 6/29/2005

NW14ASW-0605 E300 6/28/2005 6/29/2005 7/1/2005 7/1/2005

NW14ASW-0605 E350.1 6/28/2005 6/29/2005 7/25/2005 7/25/2005

March 2006 Page 1 of 2313Table

Lab Name/ Package Number etaDsisylanAetaDtcartxEetaDevieceRetaD elpmaSdohteMDIelpmaS

5002/03/65002/92/65002/92/65002/82/62.153E5060-WSA41WN05179AEPAR9

5002/03/65002/92/65002/92/65002/82/64.563E5060-WSA41WN

5002/1/75002/1/75002/92/65002/82/61.673E5060-WSA41WN

5002/22/75002/12/75002/92/65002/82/61.514E5060-WSA41WN

5002/21/75002/11/75002/92/65002/82/60232MS5060-WSA41WN

5002/5/75002/5/75002/03/65002/92/61.061E5060-WSC51WN

5002/5/75002/5/75002/03/65002/92/62.061E5060-WSC51WN

5002/52/85002/5/75002/03/65002/92/67.002E5060-WSC51WN

5002/62/85002/5/75002/03/65002/92/67.002E5060-WSC51WN

5002/72/85002/5/75002/03/65002/92/67.002E5060-WSC51WN

5002/92/85002/5/75002/03/65002/92/67.002E5060-WSC51WN

5002/81/75002/5/75002/03/65002/92/68.002E5060-WSC51WN

5002/52/75002/5/75002/03/65002/92/68.002E5060-WSC51WN

5002/1/85002/5/75002/03/65002/92/68.002E5060-WSC51WN

5002/2/85002/5/75002/03/65002/92/68.002E5060-WSC51WN

5002/3/85002/5/75002/03/65002/92/68.002E5060-WSC51WN

5002/4/85002/5/75002/03/65002/92/68.002E5060-WSC51WN

5002/01/85002/5/75002/03/65002/92/68.002E5060-WSC51WN

5002/11/85002/5/75002/03/65002/92/68.002E5060-WSC51WN

5002/21/85002/5/75002/03/65002/92/68.002E5060-WSC51WN

5002/51/75002/41/75002/03/65002/92/61.542E5060-WSC51WN

5002/03/65002/03/65002/03/65002/92/6003E5060-WSC51WN

5002/52/75002/52/75002/03/65002/92/61.053E5060-WSC51WN

5002/72/75002/72/75002/03/65002/92/62.153E5060-WSC51WN

5002/72/75002/72/75002/03/65002/92/64.563E5060-WSC51WN

5002/1/75002/1/75002/03/65002/92/61.673E5060-WSC51WN

5002/22/75002/12/75002/03/65002/92/61.514E5060-WSC51WN

5002/21/75002/21/75002/03/65002/92/60232MS5060-WSC51WN

5002/03/65002/03/65002/82/65002/72/61.061E5060-WSA1WN

5002/03/65002/03/65002/82/65002/72/62.061E5060-WSA1WN

5002/52/85002/5/75002/82/65002/72/67.002E5060-WSA1WN

5002/62/85002/5/75002/82/65002/72/67.002E5060-WSA1WN

5002/72/85002/5/75002/82/65002/72/67.002E5060-WSA1WN

5002/92/85002/5/75002/82/65002/72/67.002E5060-WSA1WN

5002/81/75002/5/75002/82/65002/72/68.002E5060-WSA1WN

5002/52/75002/5/75002/82/65002/72/68.002E5060-WSA1WN

5002/1/85002/5/75002/82/65002/72/68.002E5060-WSA1WN

March 2006 Page 2 of 2313Table

Sample Chronology - Data Summary

5002/3/85002/5/75002/82/65002/72/68.002E5060-WSA1WN05179AEPAR9

5002/4/85002/5/75002/82/65002/72/68.002E5060-WSA1WN

5002/01/85002/5/75002/82/65002/72/68.002E5060-WSA1WN

5002/11/85002/5/75002/82/65002/72/68.002E5060-WSA1WN

5002/51/75002/41/75002/82/65002/72/61.542E5060-WSA1WN

5002/82/65002/82/65002/82/65002/72/6003E5060-WSA1WN

5002/52/75002/52/75002/82/65002/72/61.053E5060-WSA1WN

5002/03/65002/92/65002/82/65002/72/62.153E5060-WSA1WN

5002/03/65002/92/65002/82/65002/72/64.563E5060-WSA1WN

5002/1/75002/1/75002/82/65002/72/61.673E5060-WSA1WN

5002/22/75002/12/75002/82/65002/72/61.514E5060-WSA1WN

5002/7/75002/7/75002/82/65002/72/60232MS5060-WSA1WN

5002/7/75002/7/75002/82/65002/72/60232MS5060-WSA1WN

5002/03/65002/03/65002/82/65002/72/61.061E5060-WSB1WN

5002/03/65002/03/65002/82/65002/72/62.061E5060-WSB1WN

5002/52/85002/5/75002/82/65002/72/67.002E5060-WSB1WN

5002/62/85002/5/75002/82/65002/72/67.002E5060-WSB1WN

5002/72/85002/5/75002/82/65002/72/67.002E5060-WSB1WN

5002/92/85002/5/75002/82/65002/72/67.002E5060-WSB1WN

5002/81/75002/5/75002/82/65002/72/68.002E5060-WSB1WN

5002/52/75002/5/75002/82/65002/72/68.002E5060-WSB1WN

5002/1/85002/5/75002/82/65002/72/68.002E5060-WSB1WN

5002/2/85002/5/75002/82/65002/72/68.002E5060-WSB1WN

5002/3/85002/5/75002/82/65002/72/68.002E5060-WSB1WN

5002/4/85002/5/75002/82/65002/72/68.002E5060-WSB1WN

5002/01/85002/5/75002/82/65002/72/68.002E5060-WSB1WN

5002/11/85002/5/75002/82/65002/72/68.002E5060-WSB1WN

5002/21/85002/5/75002/82/65002/72/68.002E5060-WSB1WN

5002/91/85002/5/75002/82/65002/72/68.002E5060-WSB1WN

5002/51/75002/41/75002/82/65002/72/61.542E5060-WSB1WN

5002/82/65002/82/65002/82/65002/72/6003E5060-WSB1WN

5002/82/65002/82/65002/82/65002/82/6003E5060-WSB1WN

5002/82/65002/82/65002/82/65002/82/6003E5060-WSB1WN

5002/52/75002/52/75002/82/65002/72/61.053E5060-WSB1WN

5002/03/65002/92/65002/82/65002/72/62.153E5060-WSB1WN

5002/03/65002/92/65002/82/65002/72/64.563E5060-WSB1WN

5002/1/75002/1/75002/82/65002/72/61.673E5060-WSB1WN

March 2006 Page 3 of 2313Table

Sample Chronology - Data Summary

5002/22/75002/12/75002/82/65002/72/61.514E5060-WSB1WN05179AEPAR9

5002/7/75002/7/75002/82/65002/72/60232MS5060-WSB1WN

5002/03/65002/03/65002/82/65002/72/61.061E5060-WSC1WN

5002/03/65002/03/65002/82/65002/72/62.061E5060-WSC1WN

5002/52/85002/5/75002/82/65002/72/67.002E5060-WSC1WN

5002/62/85002/5/75002/82/65002/72/67.002E5060-WSC1WN

5002/72/85002/5/75002/82/65002/72/67.002E5060-WSC1WN

5002/81/75002/5/75002/82/65002/72/68.002E5060-WSC1WN

5002/52/75002/5/75002/82/65002/72/68.002E5060-WSC1WN

5002/1/85002/5/75002/82/65002/72/68.002E5060-WSC1WN

5002/3/85002/5/75002/82/65002/72/68.002E5060-WSC1WN

5002/4/85002/5/75002/82/65002/72/68.002E5060-WSC1WN

5002/01/85002/5/75002/82/65002/72/68.002E5060-WSC1WN

5002/11/85002/5/75002/82/65002/72/68.002E5060-WSC1WN

5002/51/75002/41/75002/82/65002/72/61.542E5060-WSC1WN

5002/82/65002/82/65002/82/65002/72/6003E5060-WSC1WN

5002/52/75002/52/75002/82/65002/72/61.053E5060-WSC1WN

5002/03/65002/92/65002/82/65002/72/62.153E5060-WSC1WN

5002/03/65002/92/65002/92/65002/72/62.153E5060-WSC1WN

5002/03/65002/92/65002/92/65002/72/62.153E5060-WSC1WN

5002/03/65002/92/65002/82/65002/72/64.563E5060-WSC1WN

5002/03/65002/92/65002/92/65002/72/64.563E5060-WSC1WN

5002/03/65002/92/65002/92/65002/72/64.563E5060-WSC1WN

5002/1/75002/1/75002/82/65002/72/61.673E5060-WSC1WN

5002/22/75002/12/75002/82/65002/72/61.514E5060-WSC1WN

5002/7/75002/7/75002/82/65002/72/60232MS5060-WSC1WN

5002/52/85002/5/75002/5/75002/5/77.002ESM5060-WSC1WN

5002/72/85002/5/75002/5/75002/5/77.002ESM5060-WSC1WN

5002/81/75002/5/75002/5/75002/5/78.002ESM5060-WSC1WN

5002/1/85002/5/75002/5/75002/5/78.002ESM5060-WSC1WN

5002/3/85002/5/75002/5/75002/5/78.002ESM5060-WSC1WN

5002/4/85002/5/75002/5/75002/5/78.002ESM5060-WSC1WN

5002/52/85002/5/75002/5/75002/5/77.002EDS5060-WSC1WN

5002/72/85002/5/75002/5/75002/5/77.002EDS5060-WSC1WN

5002/81/75002/5/75002/5/75002/5/78.002EDS5060-WSC1WN

5002/1/85002/5/75002/5/75002/5/78.002EDS5060-WSC1WN

5002/3/85002/5/75002/5/75002/5/78.002EDS5060-WSC1WN

March 2006 Page 4 of 2313Table

Sample Chronology - Data Summary

5002/4/85002/5/75002/5/75002/5/78.002EDS5060-WSC1WN05179AEPAR9

5002/03/65002/03/65002/82/65002/72/61.061E5060-WSA2WN

5002/03/65002/03/65002/82/65002/72/62.061E5060-WSA2WN

5002/52/85002/5/75002/82/65002/72/67.002E5060-WSA2WN

5002/62/85002/5/75002/82/65002/72/67.002E5060-WSA2WN

5002/72/85002/5/75002/82/65002/72/67.002E5060-WSA2WN

5002/92/85002/5/75002/82/65002/72/67.002E5060-WSA2WN

5002/81/75002/5/75002/82/65002/72/68.002E5060-WSA2WN

5002/52/75002/5/75002/82/65002/72/68.002E5060-WSA2WN

5002/1/85002/5/75002/82/65002/72/68.002E5060-WSA2WN

5002/2/85002/5/75002/82/65002/72/68.002E5060-WSA2WN

5002/3/85002/5/75002/82/65002/72/68.002E5060-WSA2WN

5002/4/85002/5/75002/82/65002/72/68.002E5060-WSA2WN

5002/5/85002/5/75002/82/65002/72/68.002E5060-WSA2WN

5002/01/85002/5/75002/82/65002/72/68.002E5060-WSA2WN

5002/11/85002/5/75002/82/65002/72/68.002E5060-WSA2WN

5002/91/85002/5/75002/82/65002/72/68.002E5060-WSA2WN

5002/51/75002/41/75002/82/65002/72/61.542E5060-WSA2WN

5002/82/65002/82/65002/82/65002/72/6003E5060-WSA2WN

5002/52/75002/52/75002/82/65002/72/61.053E5060-WSA2WN

5002/03/65002/92/65002/82/65002/72/62.153E5060-WSA2WN

5002/03/65002/92/65002/82/65002/72/64.563E5060-WSA2WN

5002/1/75002/1/75002/82/65002/72/61.673E5060-WSA2WN

5002/22/75002/12/75002/82/65002/72/61.514E5060-WSA2WN

5002/22/75002/12/75002/12/75002/12/71.514E5060-WSA2WN

5002/22/75002/12/75002/12/75002/12/71.514E5060-WSA2WN

5002/7/75002/7/75002/82/65002/72/60232MS5060-WSA2WN

5002/03/65002/03/65002/82/65002/72/61.061E5060-WSB2WN

5002/03/65002/03/65002/82/65002/72/62.061E5060-WSB2WN

5002/52/85002/5/75002/82/65002/72/67.002E5060-WSB2WN

5002/62/85002/5/75002/82/65002/72/67.002E5060-WSB2WN

5002/72/85002/5/75002/82/65002/72/67.002E5060-WSB2WN

5002/92/85002/5/75002/82/65002/72/67.002E5060-WSB2WN

5002/81/75002/5/75002/82/65002/72/68.002E5060-WSB2WN

5002/52/75002/5/75002/82/65002/72/68.002E5060-WSB2WN

5002/1/85002/5/75002/82/65002/72/68.002E5060-WSB2WN

5002/2/85002/5/75002/82/65002/72/68.002E5060-WSB2WN

March 2006 Page 5 of 2313Table

Sample Chronology - Data Summary

5002/3/85002/5/75002/82/65002/72/68.002E5060-WSB2WN05179AEPAR9

5002/4/85002/5/75002/82/65002/72/68.002E5060-WSB2WN

5002/5/85002/5/75002/82/65002/72/68.002E5060-WSB2WN

5002/01/85002/5/75002/82/65002/72/68.002E5060-WSB2WN

5002/11/85002/5/75002/82/65002/72/68.002E5060-WSB2WN

5002/91/85002/5/75002/82/65002/72/68.002E5060-WSB2WN

5002/51/75002/41/75002/82/65002/72/61.542E5060-WSB2WN

5002/82/65002/82/65002/82/65002/72/6003E5060-WSB2WN

5002/52/75002/52/75002/82/65002/72/61.053E5060-WSB2WN

5002/03/65002/92/65002/82/65002/72/62.153E5060-WSB2WN

5002/03/65002/92/65002/82/65002/72/64.563E5060-WSB2WN

5002/1/75002/1/75002/82/65002/72/61.673E5060-WSB2WN

5002/22/75002/12/75002/82/65002/72/61.514E5060-WSB2WN

5002/7/75002/7/75002/82/65002/72/60232MS5060-WSB2WN

5002/03/65002/03/65002/92/65002/72/61.061E5060-WSC2WN

5002/5/75002/5/75002/92/65002/72/62.061E5060-WSC2WN

5002/52/85002/5/75002/92/6…