Amend2 CLAW TSpecsPgs.pdf
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Lock Approach Wall Beams Chickamauga Lock Replacement W912P5-10-B-0006 Amendment No. 0002 Hamilton County, Tennessee
PROJECT TABLE OF CONTENTS
DIVISION 01 - GENERAL REQUIREMENTS
01 00 00 GENERAL REQUIREMENTS
01 00 50 FORMS AND ATTACHMENTS
01 22 00 MEASUREMENT AND PAYMENT
01 32 17 NETWORK ANALYSIS SCHEDULES (NAS)
01 33 00 SUBMITTAL PROCEDURES
01 35 26 GOVERNMENTAL SAFETY REQUIREMENTS
01 42 00 SOURCES FOR REFERENCE PUBLICATIONS
01 45 01 USACE QUALITY CONTROL
01 45 02 USACE QUALITY CONTROL SYSTEM (QCS)
01 57 20 ENVIRONMENTAL PROTECTION
01 57 23 STORM WATER
01 78 02 AS-BUILT DRAWINGS
DIVISION 03 - CONCRETE
03 20 02 STEEL BARS AND WELDED WIRE FABRIC FOR CONCRETE
REINFORCEMENT FOR CIVIL WORKS
03 23 01 POST-TENSIONING
03 41 34 PRECAST CONCRETE BEAMS FOR APPROACH WALLS
03 41 35 LONG-TERM STORAGE OF PRECAST CONCRETE BEAMS
DIVISION 05 - METALS
05 50 14 STRUCTURAL METAL FABRICATIONS
05 50 15 CIVIL WORKS FABRICATIONS
DIVISION 09 - FINISHES
09 97 02 PAINTING: HYDRAULIC STRUCTURES
-- End of Project Table of Contents --
PROJECT TABLE OF CONTENTS Page 1
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SECTION TABLE OF CONTENTS
DIVISION 09 - FINISHES
SECTION 09 97 02
PAINTING: HYDRAULIC STRUCTURES
PART 1 GENERAL
1.1 REFERENCES
1.2 SYSTEM DESCRIPTION
1.2.1 Surface Preparation Procedures
1.2.1.1 Hoses And Nozzles
1.2.1.2 Workers Other Than Blasters
1.2.2 Paint Application
1.2.2.1 Explosion Proof Equipment
1.2.2.2 Further Precautions
1.2.2.3 Ignition Sources
1.2.3 Cleaning
1.2.4 Environmental Protection
1.2.5 Waste Classification, Handling, and Disposal
1.2.6 Visible Emissions Monitoring
1.2.7 Air Quality Monitoring
1.2.7.1 PM-10 Monitoring
1.3 SUBMITTALS
1.4 QUALITY ASSURANCE
1.4.1 Certified Professional
1.4.2 Qualified Painting Contractor
1.4.3 Coating Thickness Gage Qualification
1.4.4 Safety and Health Provisions
1.4.5 Medical Status
1.4.6 Change in Medical Status
1.5 DELIVERY, STORAGE, AND HANDLING
1.6 ENVIRONMENTAL REQUIREMENTS
PART 2 PRODUCTS
2.1 SPECIAL PAINT FORMULAS
2.2 PAINT FORMULATIONS
2.2.1 Formula V-766e
2.2.2 Formula VZ-108d
2.3 INGREDIENTS FOR SPECIAL PAINT FORMULAS
2.3.1 Pigments and Suspending Agents
2.3.1.1 Carbon Black
2.3.1.2 Zinc Dust
2.3.1.3 Iron Oxide
2.3.1.4 Titanium Dioxide
2.3.1.5 Suspending Agent E
2.3.1.6 Suspending Agent F
2.3.2 Resins, Plasticizer, and Catalyst
2.3.2.1 Diisodecyl Phthalate
2.3.2.2 Vinyl Resin, Type 3
2.3.2.3 Vinyl Resin, Type 4
SECTION 09 97 02 Page 1
2.3.2.4 Ortho-phosphoric Acid
2.3.3 Solvent and Thinners
2.3.3.1 Methanol
2.3.3.1 Methyl Ethyl Ketone
2.3.3.2 Methyl Isobutyl Ketone
2.3.3.3 Methyl Isoamyl Ketone
2.3.3.4 Toluene
2.3.4 Silane B
2.4 TESTING
2.4.1 Chromatographic Analysis
2.4.2 Vinyl Paints
PART 3 EXECUTION
3.1 CLEANING AND PREPARATION OF SURFACES TO BE PAINTED
3.1.1 General Requirements
3.1.2 Ferrous Surfaces Subject to Atmospheric Exposures
3.1.3 Ferrous Surfaces Subject to Severe Exposure
3.1.4 Damp and Wet Ferrous Metal Surfaces
3.1.5 Concrete Surfaces
3.2 PAINT APPLICATION
3.2.1 General
3.2.2 Mixing and Thinning
3.2.3 Time Between Surface Preparation and Painting
3.2.4 Method of Paint Application
3.2.5 Coverage and Film Thickness
3.2.5.1 Measurement on Ferrous Metal
3.2.6 Progress of Painting Work
3.2.7 Contacting Surfaces
3.2.8 Drying Time Prior to Immersion
3.2.9 Protection of Painted Surfaces
3.2.10 Vinyl Paints
3.2.10.1 General
3.2.10.2 Vinyl Zinc-Rich Primer
3.2.10.3 Vinyl Paints
3.3 PAINT SYSTEMS APPLICATION
3.3.1 Fabricated and Assembled Items
3.3.2 Surface Preparation
3.3.3 System No. 1
3.3.4 System No. 5-E-Z
3.3.5 Protection of Nonpainted Items and Cleanup
3.4 INSPECTION
3.5 PAINTING SCHEDULES
-- End of Section Table of Contents --
SECTION 09 97 02 Page 2
SECTION 09 97 02
PAINTING: HYDRAULIC STRUCTURES
PART 1 GENERAL
1.1 REFERENCES
The publications listed below form a part of this specification to the extent referenced. The publications are referred to within the text by the basic designation only.
AMERICAN SOCIETY OF SAFETY ENGINEERS (ASSE/SAFE)
ASSE/SAFE Z87.1 (2003) Standard for Occupational and Educational Eye and Face Protection
ASTM INTERNATIONAL (ASTM)
ASTM D 1045 (2008) Sampling and Testing Plasticizers Used in Plastics
ASTM D 1152 (2006) Methanol (Methyl Alcohol)
ASTM D 1153 (2006) Methyl Isobutyl Ketone
ASTM D 1200 (1994; R 2005) Viscosity by Ford Viscosity Cup
ASTM D 1210 (2005) Fineness of Dispersion of Pigment-Vehicle Systems by Hegman-Type Gage
ASTM D 153 (1984; R 2008) Specific Gravity of Pigments
ASTM D 281 (1995; R 2007) Oil Absorption of Pigments by Spatula Rub-Out
ASTM D 2917 (2007) Methyl Isoamyl Ketone
ASTM D 3721 (2005) Synthetic Red Iron Oxide Pigment
ASTM D 4417 (2003) Field Measurement of Surface Profile of Blast Cleaned Steel
ASTM D 520 (2000; R 2005) Zinc Dust Pigment
ASTM D 561 (1982; R 2008) Carbon Black Pigment for Paint
ASTM D 7091 (2005) Standard Practice for Nondestructive Measurement of Dry Film Thickness of Nonmagnetic Coatings Applied to Ferrous Metals and Nonmagnetic, Nondestructive Coatings Applied to Non-Ferrous Metals
SECTION 09 97 02 Page 3
ASTM D 740 (2005) Methyl Ethyl Ketone
ASTM D 841 (2002e1; R 2008) Nitration Grade Toluene
ASTM E 1347 (2006) Color and Color Difference Measurement by Tristimulus (Filter) Colorimetry
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA)
NFPA 70 (2008; AMD 1 2008) National Electrical Code - 2008 Edition
NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH (NIOSH)
NIOSH 98-119 (1998; 4th Ed) Supplement 2 to NIOSH Manual of Analytical Methods
THE SOCIETY FOR PROTECTIVE COATINGS (SSPC)
SSPC PS 26.00 (2000; E 2004) Aluminum Pigmented Epoxy Coating System Materials Specification, Performance-Based (Type I for use over Blast Cleaned Steel and Type II for use over Hand Cleaned Steel)
SSPC QP 1 (1998; E 2004) Standard Procedure for Evaluating Painting Contractors (Field Application to Complex Industrial Structures)
SSPC SP 1 (1982; E 2004) Solvent Cleaning
SSPC SP 5 (2007) White Metal Blast Cleaning
SSPC SP 6 (2007) Commercial Blast Cleaning
U.S. ARMY CORPS OF ENGINEERS (USACE)
EM 385-1-1 (2008) Safety and Health Requirements Manual
U.S. GENERAL SERVICES ADMINISTRATION (GSA)
FED-STD-595 (Rev C) Colors Used in Government Procurement
U.S. NATIONAL ARCHIVES AND RECORDS ADMINISTRATION (NARA)
29 CFR 1910 Occupational Safety and Health Standards
29 CFR 1910.134 Respiratory Protection
29 CFR 1910.146 Permit-required Confined Spaces
29 CFR 1910.20 Access to Employee Exposure and Medical Records
SECTION 09 97 02 Page 4
29 CFR 1910.94 Ventilation
29 CFR 1926 Safety and Health Regulations for Construction
29 CFR 1926.62 Lead
40 CFR 50.6 National Primary and Secondary Ambient Air Quality Standards for PM10
40 CFR 58 Ambient Air Quality Surveillance
40 CFR 60 Standards of Performance for New Stationary Sources
1.2 SYSTEM DESCRIPTION
Allow at least 30 days for sampling and testing. Sampling may be at the jobsite or source of supply. Notify the Contracting Officer when the paint and thinner are available for sampling. Sampling of each batch will be witnessed by the Contracting Officer unless otherwise specified or directed. Submit a 1-quart sample of paint and thinner for each batch proposed for use. The sample shall be labeled to indicate formula or specification number and nomenclature, batch number, batch quantity, color, date made, and applicable project contract number. Testing will be performed by the Government. Costs for retesting rejected material will be deducted from payments to the Contractor at the rate of 300 dollars for each paint sample retested and 200 dollars for each thinner retested.
1.2.1 Surface Preparation Procedures
For abrasive blasting comply with the requirements in Section 06.H of
EM 385-1-1.
1.2.1.1 Hoses And Nozzles
In addition to the requirements in Section 20 of EM 385-1-1, use hoses and hose connections of a type to prevent shock from static electricity. Hose lengths shall be joined together by approved couplings of a material and type designed to prevent erosion and weakening of the couplings. The couplings and nozzle attachments shall fit on the outside of the hose and designed to prevent accidental disengagement.
1.2.1.2 Workers Other Than Blasters
Protect workers, other than blasting operators working in close proximity to abrasive blasting operations, by utilizing MSHA/NIOSH-approved half-face or full-face air purifying respirators equipped with high-efficiency particulate air (HEPA) filters, eye protection meeting or exceeding ASSE/SAFE Z87.1 and hearing protectors (ear plugs and/or ear muffs) providing a noise reduction rating of at least 20 dBA or as needed to provide adequate protection. Personal protective equipment shall be provided where required by 29 CFR 1910.146 and in accordance with 29 CFR 1910, Subpart I.
SECTION 09 97 02 Page 5
1.2.2 Paint Application
1.2.2.1 Explosion Proof Equipment
Electrical wiring, lights, and other equipment located in the paint spraying area shall be of the explosion proof type designed for operation in Class I, Division 1, Group D, hazardous locations as required by the NFPA 70. Electrical wiring, motors, and other equipment, outside of but within 20 feet of any spraying area, shall not spark and shall conform to the provisions for Class I, Division 2, Group D, hazardous locations.
Electric motors used to drive exhaust fans shall not be placed inside spraying areas or ducts. Fan blades and portable air ducts shall be constructed of nonferrous materials. Motors and associated control equipment shall be properly maintained and grounded. The metallic parts of air-moving devices, spray guns, connecting tubing, and duct work shall be electrically bonded and the bonded assembly shall be grounded.
1.2.2.2 Further Precautions
a. Workers shall wear nonsparking safety shoes.
b. Place and ground solvent drums, taken into the spraying area, on nonferrous surfaces. Maintain metallic bonding between containers and drums when materials are being transferred.
c. Inspect insulation on all power and lighting cables to ensure that the insulation is in excellent working condition and is free of all cracks and worn spots. Cables shall be further inspected to ensure that no connections are within 50 feet of the operation, that lines are not overloaded, and that they are suspended with sufficient slack to prevent undue stress or chafing.
1.2.2.3 Ignition Sources
Ignition sources, to include lighted cigarettes, cigars, pipes, matches, or cigarette lighters shall be prohibited in area of solvent cleaning, paint storage, paint mixing, or paint application.
1.2.3 Cleaning
Cleaning with compressed air shall be in accordance with Section 20.B.5 of EM 385-1-1 and personnel shall be protected as specified in 29 CFR 1910.134.
When cleaning with solvents, provide ventilation where required by 29 CFR 1910.146 or where the concentration of solvent vapors exceeds 10 percent of the Lower Explosive Limit (LEL). Ventilation shall be in accordance with 29 CFR 1910.94, paragraph (c)(5).
1.2.4 Environmental Protection
In addition to the requirements of Section 01 57 20.00 10 ENVIRONMENTAL PROTECTION comply with the following environmental protection criteria.
1.2.5 Waste Classification, Handling, and Disposal
The Contractor is responsible for assuring the proper disposal of all hazardous and nonhazardous waste generated during the project. Store nonhazardous waste in closed containers separate from hazardous waste storage areas. All nonhazardous waste shall be transported in accordance with local regulations regarding waste transportation.
SECTION 09 97 02 Page 6
1.2.6 Visible Emissions Monitoring
Measure the time of emissions in accordance with 40 CFR 60, App A, Mtd 22.
Monitor visible emissions for not less than 15 minutes of every hour.
Calculate visible emissions for each hour by extrapolation. In no case shall visible emissions extend greater than 150 feet in any direction horizontal from the containment. In no case shall visible emissions be observed in the area of any sensitive receptor. If such emissions occur the job shall be shut down immediately and corrective action taken. Notify the foreman whenever visible emissions exceed 40 seconds in a 1 hour period. The foreman shall be notified and the job shall be shut down and corrective action taken whenever visible emissions exceed 75 seconds in a 2 hour period. Total observed visible emissions from the containment shall not exceed 5 percent of the work day. Shutdown and corrective action shall be taken to prevent such an occurrence. Document each time that the work is halted due to a violation of the visible emissions criteria.
Documentation shall include the cause for shutdown and the corrective action taken to resolve the problem.
1.2.7 Air Quality Monitoring
1.2.7.1 PM-10 Monitoring
Perform PM-10 monitoring. The positioning of air monitoring equipment shall be in accordance with 40 CFR 58, App E, Subpart (8). In addition, a minimum of two PM-10 monitors shall be used at the project site, one down wind from the project and one in the area of greatest public access (e.g., playground, school yard, or homeowner's yard). When the project is in an area where there are critical receptors nearby, monitoring shall be conducted throughout the entire period that abrasive blasting and cleanup operations are performed. Otherwise, monitoring shall be performed 4 of the first 8 days and on a regular basis thereafter for a sum total of 25 percent of the time surface preparation and debris cleanup are performed.
Failure to meet air quality regulatory limits shall require air monitoring to be repeated immediately after corrective actions have been taken. Also conduct preproject PM-10 monitoring. The preproject PM-10 monitoring shall be conducted a minimum of 2 weeks prior to the beginning of the project.
The monitoring shall continue for a minimum of 3 days to establish background levels. A report of the results shall be submitted to the Contracting Officer within 48 hours and shall include:
a. Name and location of jobsite.
b. Date of monitoring.
c. Time of monitoring (i.e., time monitoring begins and ends each day).
d. Identification and serial number of monitoring units.
e. Drawing showing specific location of monitoring units.
f. Drawing showing specific location of paint removal operation and the method of removal or work activity being performed.
g. Wind direction and velocity.
h. A flow chart verifying the rate of air flow across the filter throughout the sampling period.
SECTION 09 97 02 Page 7
i. Name and address of laboratory.
j. Laboratory test procedure.
k. Laboratory test results.
l. Signatures of field and laboratory technicians conducting the work.
1.3 SUBMITTALS
Government approval is required for submittals with a "G" designation;
submittals not having a "G" designation are for information only. When used, a designation following the "G" designation identifies the office that will review the submittal for the Government. Submit the following in accordance with Section 01 33 00 SUBMITTAL PROCEDURES:
SD-03 Product Data
Safety and Health Provisions; G
An Accident Prevention Plan in accordance with the requirements of Section 01 of EM 385-1-1, including, but not limited to, each of the topic areas listed in Appendix A therein and the specified requirements; each topic shall be developed in a concise manner to include management and operational aspects.
Respirators; G
A comprehensive written respiratory protection program in accordance with 29 CFR 1910.134, 29 CFR 1926.62, and Section 05.E of EM 385-1-1.
Certified Laboratory; G
An Airborne Sampling Plan detailing the NIOSH 98-119, Factory Mutual, or Underwriters Laboratories approved equipment, equipment calibration procedures, sampling methods, sampling to be performed, and analytical procedures to be used based on the type of work to be performed and anticipated toxic contaminants to be generated. Include the name of the accredited laboratory, listed by the American Industrial Hygiene Association (AIHA), to be used to conduct the analysis of any collected air samples.
Medical Status; G
A Medical Surveillance Plan and a statement from the examining physician indicating the name of each employee evaluated and any limitations which will preclude the employee from performing the work required. The statement shall include the date of the medical evaluation, the physician's name, signature, and telephone number.
Visible Emissions Monitoring; G
A Visible Emissions Monitoring Plan. The plan shall include the provisions for halting work and correcting the containment in the event unacceptable emissions are observed. General statements shall not be used; specific methods, procedures, and details are
SECTION 09 97 02 Page 8 required.
PM-10 Monitoring; G
A plan for monitoring emissions of particulate matter 10 microns or less in size (PM-10). The plan shall comply with the requirements of EPA regulation 40 CFR 50.6 and paragraph PM-10 Monitoring. The plan shall also include provisions for halting work and correcting the containment in the event unacceptable emissions occur.
SD-04 Samples
Special Paint Formulas; G Paint Formulations; G
Samples of all special paint formula, Military, Master Painter Institute, Commercial Item Description, and SSPC paints. For products that are specified to be applied in accordance with the manufacturer's recommendations also submit the paint producers product data sheet or other written instructions for those products.
Solvent and Thinners; G
Samples of the thinners or solvents used to reduce the viscosity of the paint.
SD-06 Test Reports
PM-10 Monitoring; G
Reports of the PM-10 monitoring tests.
Certified Laboratory; G
Reports of airborne sampling tests.
Inspection; G
Records of inspections and operations performed. Submittals shall be made on a daily basis.
SD-07 Certificates
Qualifications; G
Certification for all job sites. Submittal of the qualifications and experience of any additional qualified and competent persons employed to provide onsite environmental, safety, and health shall also be provided. Obtain acceptance of this submission prior to the submission of other required environmental, safety, and health submittal items.
Qualified Painting Contractor; G
A copy of their current SSPC QP 1 certification.
Coating Thickness Gage Qualification; G
SECTION 09 97 02 Page 9
Documentation of manufacturer's certification shall be submitted for all coating thickness gages.
1.4 QUALITY ASSURANCE
Qualifications and experience shall comply with the following.
1.4.1 Certified Professional
Utilize a qualified and competent person as defined in Section 01 of EM 385-1-1 to develop the required safety and health submittal and to provide onsite safety and health services during the contract period. The person shall be a Certified Industrial Hygienist (CIH), an Industrial Hygienist (IH), or a Certified Safety Professional (CSP) with a minimum of 3 years of demonstrated experience in similar related work. Certify that the Certified Industrial Hygienist (CIH) holds current and valid certification from the American Board of Industrial Hygiene (ABIH), that the IH is considered board eligible by written confirmation from the ABIH, or that the CSP holds current and valid certification from the American Board of Certified Safety Professionals. The CIH, IH, or CSP may utilize other qualified and competent persons, as defined in EM 385-1-1, to conduct on-site safety and health activities as long as these persons have a minimum of 2 years of demonstrated experience in similar related work and are under the direct supervision of the CIH, IH, or CSP. For lead containing jobsites, the competent and qualified person shall have successfully completed an EPA or state accredited lead-based paint abatement Supervisor course specific to the work to be performed and shall possess current and valid state and/or local government certification, as required.
1.4.2 Qualified Painting Contractor
Provide a Contractor certified SSPC-QP 1 Painting Contractor.
1.4.3 Coating Thickness Gage Qualification
Submit documentation of certification for all coating thickness gages.
Magnetic flux thickness gages as described in ASTM D 7091 shall be used to make all coating thickness measurements on ferrous metal substrates. .
Gages shall have an accuracy of +/- 3 percent or better. Gages to be used on the job shall be certified by the manufacturer as meeting these requirements.
1.4.4 Safety and Health Provisions
Perform work in accordance with the requirements of 29 CFR 1910, 29 CFR 1926, EM 385-1-1, and other references as listed herein. Submit matters of interpretation of the standards to the Contracting Officer for resolution before starting work. Where the regulations conflict, the most stringent requirements shall apply. This paragraph supplements the requirements of EM 385-1-1, paragraph (1). In any conflict between Section 01 of EM 385-1-1 and this paragraph, the provisions herein shall govern.
1.4.5 Medical Status
Prior to the start of work and annually thereafter, medically evaluate all Contractor employees working with or around paint systems, thinners, blast media, those required to wear respiratory protective equipment, and those
SECTION 09 97 02 Page 10 who will be exposed to high noise levels for the particular type of exposure they may encounter. Maintain medical records as required by 29 CFR 1910.20. The evaluation shall include:
a. Audiometric testing and evaluation of employees who will work in a noise environment with a time weighted average greater than or equal to 90 dBA.
b. Vision screening (employees who use full-facepiece respirators shall not wear contact lenses).
c. Medical evaluation shall include, but shall not be limited to, the following:
(1) Medical history including, but not limited to, alcohol use, with emphasis on liver, kidney, and pulmonary systems, and sensitivity to chemicals to be used on the job.
(2) General physical examination with emphasis on liver, kidney, and pulmonary system.
(3) Determination of the employee's physical and psychological ability to wear respiratory protective equipment and to perform job-related tasks.
(4) Determination of baseline values of biological indices for later comparison to changes associated with exposure to paint systems and thinners or blast media, which include: liver function tests to include SGOT, SGPT, GGPT, alkaline phosphates, bilirubin, complete urinalysis, EKG (employees over age 40), blood urea nitrogen (bun), serum creatinine, pulmonary function test, FVC, and FEV, chest x-ray (if medically indicated), blood lead and ZPP (for individuals where it is known there will be an exposure to materials containing lead), other criteria that may be deemed necessary by the Contractor's physician, and Physician's statements for individual employees that medical status would permit specific task performance.
1.4.6 Change in Medical Status
Any employee whose medical status has changed negatively due to work related chemical and/or physical agent exposure while working with or around paint systems and thinners, blast media, or other chemicals shall be evaluated by a physician, and obtain a physicians statement as described in paragraph MEDICAL STATUS prior to allowing the employee to return to those work tasks. Notify the Contracting Officer in writing of any negative changes in employee medical status and the results of the physicians reevaluation statement.
1.5 DELIVERY, STORAGE, AND HANDLING
Process and package paints to ensure that within a period of one year from date of manufacture, they will not gel, liver, or thicken deleteriously, or form gas in the closed container. Paints, unless otherwise specified or permitted, shall be packaged in standard containers not larger than 5 gallons, with removable friction or lug-type covers. Containers for vinyl-type paints shall be lined with a coating resistant to solvents in the formulations and capable of effectively isolating the paint from contact with the metal container. Each container of paint or separately
SECTION 09 97 02 Page 11 packaged component thereof shall be labeled to indicate the purchaser's order number, date of manufacture, manufacturer's batch number, quantity, color, component identification and designated name, and formula or specification number of the paint together with special labeling instructions, when specified. Paint shall be delivered to the job in unbroken containers. Paints that can be harmed by exposure to cold weather shall be stored in ventilated, heated shelters. All paints shall be stored under cover from the elements and in locations free from sparks and flames.
1.6 ENVIRONMENTAL REQUIREMENTS
Paint shall be applied only to surfaces that are above the dew point temperature and that are completely free of moisture as determined by sight and touch. Paint shall not be applied to surfaces upon which there is detectable frost or ice. Except as otherwise specified, the temperature of the surfaces to be painted and of air in contact therewith shall be not less than 45 degrees F during paint application nor shall paint be applied if the surfaces can be expected to drop to 32 degrees F or lower before the film has dried to a reasonably firm condition. During periods of inclement weather, painting may be continued by enclosing the surfaces and applying artificial heat, provided the minimum temperatures and surface dryness requirements prescribed previously are maintained. Paint shall not be applied to surfaces heated by direct sunlight or other sources to temperatures that will cause detrimental blistering, pinholing, or porosity of the film.
PART 2 PRODUCTS
2.1 SPECIAL PAINT FORMULAS
Special paints shall have the composition as indicated in the formulas listed herein. Where so specified, certain components of a paint formulation shall be packaged in separate containers for mixing on the job. If not specified or otherwise prescribed, the color shall be that naturally obtained from the required pigmentation.
2.2 PAINT FORMULATIONS
Special paint formulas shall comply with the following:
2.2.1 Formula V-766e
This formula is for Vinyl-Type White (or Gray) Impacted Immersion Coating, the ingredients are shown below.
INGREDIENTS PERCENT BY MASS
Vinyl Resin, Type 3 5.6 Vinyl Resin, Type 4 11.6 Titanium Dioxide and (for Gray) Carbon Black 13.0 Diisodecyl Phthalate 2.9 Methyl Isobutyl Ketone 32.0 Toluene 34.7 Ortho-Phosphoric Acid 0.2 100.0
a. The dispersion of pigment shall be accomplished by means of pebble
SECTION 09 97 02 Page 12 mills or other approved methods to produce a fineness of grind ( ASTM D 1210) of not less than 7 on the Hegman scale. Grinding in steel-lined or steel-ball mills will not be permitted. No grinding aids, antisettling agents, or any other materials except those shown in the formula will be permitted. The paint shall show the proper proportions of specified materials when analyzed by chromatographic and/or spectrophotometric methods. The ortho-phosphoric acid shall be measured accurately and diluted with at least four parts of ketone to one part of acid and it shall be slowly incorporated into the finished paint with constant and thorough agitation.
b. The viscosity of the paint shall be between 60 and 90 seconds using ASTM D 1200 and a No. 4 Ford cup.
c. The white and gray paints shall be furnished in the volume ratio designated by the purchaser. The gray paint shall contain no pigments other than those specified. Enough carbon black shall be included to produce a dry paint film having a reflectance of 20-24 (ASTM E 1347).
The resulting gray color shall approximate color 26231 of FED-STD-595.
2.2.2 Formula VZ-108d
This formula is for Vinyl-Type Zinc-Rich Impacted Immersion Coating, the ingredients are shown below.
INGREDIENTS PERCENT BY WEIGHT POUNDS GALLONS
COMPONENT A
Vinyl Resin, Type 3 16.6 109.2 9.65 Methyl Isobutyl Ketone 80.6 528.9 79.30 Suspending Agent E 0.7 4.6 0.28 Suspending Agent F 0.4 2.7 0.19 Methanol 0.5 3.3 0.50 Synthetic Iron Oxide (Red) 1.2 7.9 0.19
100.0 656.6 90.11
COMPONENT B
Silane B 100.0 4.1 0.47
COMPONENT C
Zinc Dust 100.0 550.0 9.42 100.00 (mixed paint)
a. The iron oxide and suspending agents shall be dispersed into the vehicle (Component A) to a fineness of grind of not less than 4 on the Hegman scale (ASTM D 1210). Grinding in steel-lined containers or using steel-grinding media shall not be permitted. The sole purpose of the iron oxide pigment is to produce a contrasting color. A red iron oxide-type 3 vinyl resin vehicle paste may be used in place of dry iron oxide provided compensating adjustment are made in the additions of Type 3 resin and methyl isobutyl ketone. The finished product with zinc dust added shall produce a paint which has a red tone upon drying
SECTION 09 97 02 Page 13 and a reflectance of not more than 16 (ASTM E 1347).
b. VZ-108d paint shall be supplied as a kit. Each kit shall consist of
4.5 gallons ( 33.1 pounds) of Component A in a 5-gallon lug closure type pail, 27.5 pounds of zinc dust (Component C) packaged in a 1-gallon plastic pail, and 3 fluid ounces of silane (Component B) packaged in a glass bottle of suitable size having a polyethylene lined cap. The bottle of silane shall be placed on the zinc dust in the 1-gallon pail. In addition to standard labeling requirements, each container of each component shall be properly identified as to component type and each container label of Component A shall carry the following: MIXING AND APPLICATION INSTRUCTIONS: WARNING - THIS PAINT WILL NOT ADHERE TO STEEL SURFACES UNLESS COMPONENT B IS ADDED. Remove the 3 ounces of bottled Component B (silane) from the Component C (zinc dust) container and add to the base paint Component A) with thorough stirring. Then sift the zinc dust into the base paint while it is being vigorously agitated with a power-driven stirrer and continue the stirring until the zinc dust has been dispersed. The mixed paint shall at some point be strained through a 30-60 mesh screen to prevent zinc dust slugs from reaching the spray gun nozzle. The paint shall be stirred continuously during application at a rate that will prevent settling. If spraying is interrupted for longer than 15 minutes, the entire length of the hose shall be whipped vigorously to redisperse the zinc. If the spraying is to be interrupted for more than 1 hour, the hose shall be emptied by blowing the paint back into the paint pot.
Thinning will not normally be required when ambient temperatures are below about 80 degrees F, but when the ambient and steel temperatures are higher, methyl isoamyl ketone (MIAK) or methyl isobutyl ketone (MIBK) should be used. If paint is kept covered at all times, its pot life will be about 8 days.
2.3 INGREDIENTS FOR SPECIAL PAINT FORMULAS
The following ingredient materials and thinners apply only to those special paints whose formulas are shown above in detail.
2.3.1 Pigments and Suspending Agents
2.3.1.1 Carbon Black
Carbon black shall conform to ASTM D 561, Type I or II.
2.3.1.2 Zinc Dust
Zinc dust pigment shall conform to ASTM D 520, Type II.
2.3.1.3 Iron Oxide
Iron oxide, (Dry) synthetic (red), shall conform to ASTM D 3721. In addition, the pigment shall have a maximum oil absorption of 24 and a specific gravity of 4.90 to 5.20 when tested in accordance with ASTM D 281 and ASTM D 153, Method A, respectively. When the pigment is dispersed into specified vinyl paint formulation, the paint shall have color approximating FED-STD-595 color 10076 (dark red paint), and shall show no evidence of incompatibility or reaction between pigment and other components after 6 months storage.
SECTION 09 97 02 Page 14
2.3.1.4 Titanium Dioxide
Titanium dioxide in vinyl paint Formula V-766e shall be one of the following: Kronos 2160 or 2101, Kronos, Inc.; Ti-Pure 960, E.I. Dupont DeNemours and Co., Inc.
2.3.1.5 Suspending Agent E
Suspending Agent E shall be a light cream colored finely divided powder having a specific gravity of 2 to 2.3. It shall be an organic derivative of magnesium aluminum silicate mineral capable of minimizing the tendency of zinc dust to settle hard without increasing the viscosity of the paint appreciably. MPA-14, produced by RHEOX, Inc., has these properties.
2.3.1.6 Suspending Agent F
Suspending Agent F shall be a light cream colored finely divided powder having a specific gravity of approximately 1.8. It shall be an organic derivative of a special montmorillonite (trialkylaryl ammonium hectorite).
Bentone 27, produced by RHEOX, Inc., has these properties.
2.3.2 Resins, Plasticizer, and Catalyst
2.3.2.1 Diisodecyl Phthalate
Diisodecyl Phthalate shall have a purity of not less than 99.0 percent, shall contain not more than 0.1 percent water, and shall have an acid number (ASTM D 1045) of not more than 0.10.
2.3.2.2 Vinyl Resin, Type 3
Vinyl resin, Type 3, shall be a vinyl chloride-acetate copolymer of medium average molecular weight produced by a solution polymerization process and shall contain 85 to 88 percent vinyl chloride and 12 to 15 percent vinyl acetate by weight. The resin shall have film-forming properties and shall, in specified formulations, produce results equal to Vinylite resin VYHH, as manufactured by the Union Carbide Corporation.
2.3.2.3 Vinyl Resin, Type 4
Vinyl resin, Type 4, shall be a copolymer of the vinyl chloride-acetate type produced by a solution polymerization process, shall contain (by weight) 1 percent interpolymerized dibasic acid, 84 to 87 percent vinyl chloride, and 12 to 15 percent vinyl acetate. The resin shall have film-forming properties and shall, in the specified formulations, produce results equal to Vinylite resin VMCH, as manufactured by the Union Carbide Corporation.
2.3.2.4 Ortho-phosphoric Acid
Ortho-phosphoric acid shall be a chemically pure 85-percent grade.
2.3.3 Solvent and Thinners
2.3.3.1 Methanol
Methanol (methyl alcohol) shall conform to ASTM D 1152.
SECTION 09 97 02 Page 15
2.3.3.1 Methyl Ethyl Ketone
Methyl ethyl ketone (MEK) shall conform to ASTM D 740.
2.3.3.2 Methyl Isobutyl Ketone
Methyl isobutyl ketone (MIBK) shall conform to ASTM D 1153.
2.3.3.3 Methyl Isoamyl Ketone
Methyl isoamyl ketone (MIAK) shall conform to ASTM D 2917.
2.3.3.4 Toluene
Toluene shall conform to ASTM D 841.
2.3.4 Silane B
Silane B for Formula VZ-108d shall be N-beta-(aminoethyl)-gamma-aminopropyltrimethoxy silane. Silane A-1120, produced by the C.K. Witco Corporation, and Silane Z-6020, produced by Dow Corning Corporation, are products of this type.
2.4 TESTING
2.4.1 Chromatographic Analysis
Solvents in vinyl paints and thinners shall be subject to analysis by programmed temperature gas chromatographic methods and/or spectrophotometric methods, employing the same techniques that give reproducible results on prepared control samples known to meet the specifications. If the solvent being analyzed is of the type consisting primarily of a single chemical compound or a mixture or two or more such solvents, interpretation of the test results shall take cognizance of the degree of purity of the individual solvents as commercially produced for the paint industry.
2.4.2 Vinyl Paints
Vinyl paints shall be subject to the following adhesion test. When V-766 or V-106 formulations are tested, 5 to 7 mils (dry) shall be spray applied to mild steel panels. The steel panels shall be essentially free of oil or other contaminants that may interfere with coating adhesion. The test panels shall be dry blast cleaned to a White Metal grade which shall be in compliance with SSPC SP 5. The surface shall have an angular profile of
2.0 to 2.5 mils as measured by ASTM D 4417, Method C. When V-102 or V-103 formulations are tested, they shall be spray applied over 1.5 to 2.5 mils (dry) of V-766 or V-106 known to pass this test. When VZ-108 is tested, the coating shall be mixed in its proper proportions and then spray applied to a dry film thickness of 1.5 to 2.5 mils above the blast profile. The VZ-108 shall be top coated with a V-766 known to pass this test. In all cases, the complete system shall have a total dry film thickness of 5 to 7 mils above the blast profile. After being air dried for 2 hours at room temperature, the panel shall be dried in a vertical position for 16 hours at 120 degrees F. After cooling for 1 hour, the panel shall be immersed in tap water at 85 to 90 degrees F for 48 to 72 hours. Immediately upon removal, the panel shall be dried with soft cloth and examined for adhesion as follows: With a pocket knife or other suitable instrument, two parallel cuts at least 1 inch long shall be made 1/4 to 3/8 inch apart through the
SECTION 09 97 02 Page 16 paint film to the steel surface. A third cut shall be made perpendicular to and passing through the end of the first two. With the tip of the knife blade, the film shall be loosened from the panel from the third cut between the parallel cuts for a distance of 1/8 to 1/4 inch. With the panel being held horizontally, the free end of the paint film shall be grasped between the thumb and forefinger and pulled vertically in an attempt to remove the film as a strip from between the first two cuts. The strip of paint film shall be removed at a rate of approximately 1/10 inch per second and shall be maintained in a vertical position during the process of removal. The adhesion is acceptable if the strip of paint breaks when pulled or if the strip elongates a minimum of 10 percent during its removal. Paints not intended to be self-priming shall exhibit no delamination from the primer.
PART 3 EXECUTION
3.1 CLEANING AND PREPARATION OF SURFACES TO BE PAINTED
3.1.1 General Requirements
Clean surfaces to be painted before applying paint or surface treatments.
Remove deposits of grease or oil in accordance with SSPC SP 1, prior to mechanical cleaning.
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