3M_AQUEOUS_FILM_FORMING_FOAM.pdf

MATERIAL SAFETY 3M

DATA SHEET 3M Center St. Paul, Minnesota 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours)

Copyright, 1999, Minnesota Mining and Manufacturing Company.

All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that:

1) the information is copied in full with no changes unless prior agreement is obtained from 3M, and

2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

DIVISION: 3M SPECIALTY MATERIALS

TRADE NAME:

FC-203CF LIGHT WATER(TM) AFFF 3%

ID NUMBER/U.P.C.:

98-0211-5617-3 00-51135-10152-0 98-0211-5618-1 00-51135-10153-7 98-0211-5619-9 00-51135-10154-4 98-0211-5620-7 00-51135-10155-1 98-0211-5621-5 00-51135-10156-8 98-0211-5622-3 00-51135-10157-5 98-0211-5623-1 - - - 98-0211-9304-4 00-51135-11130-7

ZF-0002-0554-0 - - - ZF-0002-0620-9 - - -

ZF-0002-0789-2 - - -

ISSUED: December 17, 1999 SUPERSEDES: March 17, 1999

DOCUMENT: 10-4322-3

1. INGREDIENT C.A.S. NO. PERCENT

WATER................................... 7732-18-5 69.0 - 71.0

DIETHYLENE GLYCOL BUTYL ETHER........... 112-34-5 20.0

AMPHOTERIC FLUOROALKYLAMIDE DERIVATIVE

+(5803P).............................. TradeSecret 1 - 5 ALKYL SULFATE SALTS(2) +(5805P, 5806P).. TradeSecret 1.0 - 5.0

PERFLUOROALKYL SULFONATE SALTS(5)

+(5804P).............................. TradeSecret 0.5 - 1.5

TRIETHANOLAMINE......................... 102-71-6 0.5 - 1.5

TOLYL TRIAZOLE.......................... 29385-43-1 0.05

RESIDUAL ORGANIC FLUOROCHEMICALS........ Mixture Unknown

The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS.

New Jersey Trade Secret Registry Number (EIN) 04499600-+

This product contains the following toxic chemical or chemicals subject to the reporting requirements of Section 313 of Title III of the Emergency Planning and Community Right-To-Know Act of 1986 and 40 CFR Part 372:

DIETHYLENE GLYCOL BUTYL ETHER

Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately

MSDS: FC-203CF LIGHT WATER(TM) AFFF 3%

December 17, 1999 PAGE 2

2. PHYSICAL DATA

BOILING POINT:................. 100 C

(Typical) VAPOR PRESSURE:................ ca. 17.4 mmHg Calc @ 20C VAPOR DENSITY:................. ca. 0.77 Air=1 Calc @ 20C EVAPORATION RATE:.............. < 1 BuOAc=1 SOLUBILITY IN WATER:........... Miscible SPECIFIC GRAVITY:.............. 1.0 Water=1 PERCENT VOLATILE:.............. 90 % by wt pH:............................ 8.5

VISCOSITY:..................... N/D

MELTING POINT:................. N/A

APPEARANCE AND ODOR:

Clear, amber colored liquid.

3. FIRE AND EXPLOSION HAZARD DATA

FLASH POINT:................... None (Setaflash CC)

FLAMMABLE LIMITS - LEL:........ N/A

FLAMMABLE LIMITS - UEL:........ N/A

AUTOIGNITION TEMPERATURE:...... N/A

EXTINGUISHING MEDIA:

Product is a fire-extinguishing agent.

SPECIAL FIRE FIGHTING PROCEDURES:

Not applicable

UNUSUAL FIRE AND EXPLOSION HAZARDS:

See Hazardous Decomposition section for products of combustion.

4. REACTIVITY DATA

STABILITY: Stable

INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID:

Not applicable.

HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.

December 17, 1999 PAGE 3

4. REACTIVITY DATA (continued)

HAZARDOUS DECOMPOSITION PRODUCTS:

Carbon Monoxide and Carbon Dioxide, Oxides of Nitrogen, Oxides of Sulfur, Hydrogen Fluoride

Thermal decomposition of usage concentrations does not present a hazard.

5. ENVIRONMENTAL INFORMATION

SPILL RESPONSE:

Observe precautions from other sections. Ventilate area. Contain spill. Cover with absorbent material. Collect spilled material.

Clean up residue with water. Place in a closed container.

RECOMMENDED DISPOSAL:

Discharge spent solutions and small quantities (less than 5 gal.(19 L)) to a wastewater treatment system. Reduce discharge rate if foaming occurs. Large quantities may adversely affect biological wastewater treatment systems. Incinerate large quantities in an industrial or commercial incinerator. Combustion products will include HF.

ENVIRONMENTAL DATA:

A Product Environmental Data Sheet (PED) is available.

5-Day Biochemical Oxygen Demand (BOD5): 0.35 g/g; 20-Day Biochemical Oxygen Demand (BOD20): 0.75 g/g; 20-Day BOD/COD: 0.96; Chemical Oxygen Demand (COD): 0.75 g/g; 96-Hr LC50, Fathead minnow (Pimephales promelas): >1,000 mg/L; 48-Hr EC50, Water flea,(Daphnia magna): >1,000 mg/L; 96-Hr EC50, Algae (Selenastrum capricornutum):

143 mg/L (130-156); 30-Min EC50, Photobacterium phosphoreum (Microtox System): 280 mg/L (260-300); 3-Hr, 20C EC50, Activated Sludge Respiration (OECD Method #209): >1,000 mg/L.

REGULATORY INFORMATION:

Volatile Organic Compounds: 200 gms/liter South Coast Air Quality Mgmt Dist Method Calc. @ 20 C..

VOC Less H2O & Exempt Solvents: N/A.

Since regulations vary, consult applicable regulations or authorities before disposal. In the event of an uncontrolled release of this material, the user should determine if the release qualifies as a reportable quantity. U.S. EPA Hazardous Waste Number = None (Not U.S. EPA Hazardous).

The components of this product are in compliance with the chemical registration requirements of: TSCA, EINECS, CDSL, AICS, MITI.

December 17, 1999 PAGE 4

5. ENVIRONMENTAL INFORMATION (continued)

OTHER ENVIRONMENTAL INFORMATION:

This product contains one or more organic fluorochemicals that have the potential to resist degradation and persist in the environment.

EPCRA HAZARD CLASS:

FIRE HAZARD: No PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: No

6. SUGGESTED FIRST AID

EYE CONTACT:

Immediately flush eyes with large amounts of water. Get immediate medical attention.

SKIN CONTACT:

Immediately wash skin with soap and large amounts of water. Remove contaminated clothing. If signs/symptoms occur, call a physician.

Wash contaminated clothing before reuse and dispose of contaminated shoes.

INHALATION:

If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician.

IF SWALLOWED:

If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person.

7. PRECAUTIONARY INFORMATION

EYE PROTECTION:

Avoid eye contact with vapor, spray, or mist. Wear vented goggles.

SKIN PROTECTION:

Avoid skin contact. Wear appropriate gloves when handling this material. A pair of gloves made from the following material(s) are recommended: butyl rubber.

RECOMMENDED VENTILATION:

If exhaust ventilation is not adequate, use appropriate respiratory protection. Provide ventilation adequate to control vapor concentrations below recommended exposure limits and/or control spray or mist.

December 17, 1999 PAGE 5

7. PRECAUTIONARY INFORMATION (continued)

RESPIRATORY PROTECTION:

Avoid breathing of airborne material. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half-mask organic vapor respirator with dust/mist prefilter.

PREVENTION OF ACCIDENTAL INGESTION:

Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Wash hands after handling and before eating.

RECOMMENDED STORAGE:

Store away from areas where product may come into contact with food or pharmaceuticals. Store at temperatures below 120 degrees F (49 degrees C). Store at temperatures above 32 degrees F (O degrees C).

Keep container closed when not in use. Keep container in well-ventilated area.

FIRE AND EXPLOSION AVOIDANCE:

Not applicable.

HMIS HAZARD RATINGS: HEALTH: 2 FLAMMABILITY: 0 REACTIVITY: 0

PERSONAL PROTECTION: X (See precautions, section 7.)

EXPOSURE LIMITS

INGREDIENT VALUE UNIT TYPE AUTH SKIN*

WATER................................ NONE NONE NONE NONE

DIETHYLENE GLYCOL BUTYL ETHER........ 35 PPM TWA CMRG

AMPHOTERIC FLUOROALKYLAMIDE

DERIVATIVE +(5803P)................ NONE NONE NONE NONE

ALKYL SULFATE SALTS(2) +(5805P,

5806P)............................. NONE NONE NONE NONE

PERFLUOROALKYL SULFONATE SALTS(5)

+(5804P)........................... 0.1 MG/M3 TWA 3M Y

TRIETHANOLAMINE...................... 5 MG/M3 TWA ACGIH

TOLYL TRIAZOLE....................... NONE NONE NONE NONE

RESIDUAL ORGANIC FLUOROCHEMICALS..... 0.1 MG/M3 TWA 3M Y

* SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption.

SOURCE OF EXPOSURE LIMIT DATA:

- 3M: 3M Recommended Exposure Guidelines

- ACGIH: American Conference of Governmental Industrial Hygienists

- CMRG: Chemical Manufacturer Recommended Exposure Guidelines

December 17, 1999 PAGE 6

EXPOSURE LIMITS (continued)

INGREDIENT VALUE UNIT TYPE AUTH SKIN*

- NONE: None Established

8. HEALTH HAZARD DATA

EYE CONTACT:

Moderate Eye Irritation: signs/symptoms can include redness, swelling, pain, tearing, and hazy vision.

SKIN CONTACT:

Mild Skin Irritation (after prolonged or repeated contact):

signs/symptoms can include redness, swelling, and itching.

Prolonged or repeated exposure may cause:

Allergic Skin Reaction: signs/symptoms can include redness, swelling, blistering, and itching.

INHALATION:

Single overexposure, above recommended guidelines, may cause:

Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness.

Irritation (upper respiratory): signs/symptoms can include soreness of the nose and throat, coughing and sneezing.

IF SWALLOWED:

Animal studies conducted on organic fluorochemicals which are present in this product indicate effects including liver disturbances, weight loss, loss of appetite, lethargy, and neurological, pancreatic, adrenal and hematologic effects. There are no known human health effects from anticipated exposure to these organic fluorochemicals when used as intended and instructed.

Ingestion may cause:

Aspiration Pneumonitis: signs/symptoms can include coughing, difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE

INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE

INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD,

THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT.

Ingestion may cause:

December 17, 1999 PAGE 7

8. HEALTH HAZARD DATA (continued)

Irritation of Gastrointestinal Tissues: signs/symptoms can include pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and blood in feces.

Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, muscular weakness, incoordination, slowed reaction time, fatigue, blurred vision, slurred speech, giddiness, tremors and convulsions.

OTHER HEALTH HAZARD INFORMATION:

A Product Toxicity Summary Sheet is available.

This product contains one or more organic fluorochemicals that have the potential to be absorbed and remain in the body for long periods of time, either as the parent molecule or as metabolites, and may accumulate with repeated exposures. There are no known human health effects from anticipated exposure to these organic fluorochemicals when used as intended and instructed.

The presence of organic fluorochemicals in the blood of the general population and subpopulations, such as workers, has been published dating back to the 1970's. 3M's epidemiological study of its own workers indicates no adverse effects.

SECTION CHANGE DATES

PRECAUTIONARY INFO. SECTION CHANGED SINCE March 17, 1999 ISSUE

December 17, 1999 PAGE 8

The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR

IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF

MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF

PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers.

Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.